Nanomaterials/Nanotechnology: Nanoelectronics to Improve Energy Efficiency
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Accomplishments in Nanotechnology
U.S. Department of Commerce Carlos M. Gutierrez, Secretaiy Technology Administration Robert Cresanti, Under Secretaiy of Commerce for Technology National Institute ofStandards and Technolog}' William Jeffrey, Director Certain commercial entities, equipment, or materials may be identified in this document in order to describe an experimental procedure or concept adequately. Such identification does not imply recommendation or endorsement by the National Institute of Standards and Technology, nor does it imply that the materials or equipment used are necessarily the best available for the purpose. National Institute of Standards and Technology Special Publication 1052 Natl. Inst. Stand. Technol. Spec. Publ. 1052, 186 pages (August 2006) CODEN: NSPUE2 NIST Special Publication 1052 Accomplishments in Nanoteciinology Compiled and Edited by: Michael T. Postek, Assistant to the Director for Nanotechnology, Manufacturing Engineering Laboratory Joseph Kopanski, Program Office and David Wollman, Electronics and Electrical Engineering Laboratory U. S. Department of Commerce Technology Administration National Institute of Standards and Technology Gaithersburg, MD 20899 August 2006 National Institute of Standards and Teclinology • Technology Administration • U.S. Department of Commerce Acknowledgments Thanks go to the NIST technical staff for providing the information outlined on this report. Each of the investigators is identified with their contribution. Contact information can be obtained by going to: http ://www. nist.gov Acknowledged as well, -
Nanomaterial Safety
Nanomaterial Safety What are Nanomaterials? Nanomaterials or nanoparticles are human engineered particles with at least one dimension in the range of one to one hundred nanometers. They can be composed of many different base materials (carbon, silicon, and various metals). Research involving nanomaterials ranges from nano-particle synthesis to antineoplastic drug implants to cell culture work. Material Scientists, Chemists, Biologists, Biochemists, Physicists, Microbiologists, Medical-related disciplines and many engineering disciplines (Mechanical, Chemical, Biological and Environmental, etc.) perform research using nanomaterials. Naturally created particles of this size range are normally called ultra-fine particles. Examples are welding fumes, volcanic ash, motor vehicle exhaust, and combustion products. Nanomaterials come in many different shapes and dimensions, such as: • 0-dimensional: quantum dots • 1-dimensional: nanowires, nanotubes, • 2-dimensional: nanoplates, nanoclays • 3-dimensional: Buckyballs, Fullerenes, nanoropes, crystalline structures Nanoparticles exhibit very different properties than their respective bulk materials, including greater strength, conductivity, fluorescence and surface reactivity. Health Effects Results from studies on rodents and in cell cultures exposed to ultrafine and nanoparticles have shown that these particles are more toxic than larger ones on a mass-for-mass basis. Animal studies indicate that nanoparticles cause more pulmonary inflammation, tissue damage, and lung tumors than larger particles Solubility, shape, surface area and surface chemistry are all determinants of nanoparticle toxicity There is uncertainty as to the levels above which these particles become toxic and whether the concentrations found in the workplace are hazardous Respiratory Hazards: • Nanoparticles are deposited in the lungs to a greater extent than larger particles • Based on animal studies, nanoparticles may enter the bloodstream from the lungs and translocate to other organs and they are able to cross the blood brain barrier. -
Best Practices for Handling Nanoparticles in Laboratories
Best Practices for Handling Nanoparticles in Laboratories Introduction The purpose of this document is to provide a readily-accessible summary of information currently available on safe work practices for research laboratories working with engineered nanomaterials at Missouri State University. This interim guidance has been compiled from guidance from governmental agencies and universities currently engaged in nanomaterial research sources such as: The Center for Disease Control (CDC), The National Institute for Occupational Safety and Health (NIOSH), The Occupational Safety and Health Administration (OSHA), Department of Energy (DOE), Massachusetts Institute of Technology (MIT), Virginia Tech, and University of Florida. A list of sources can be found in the References section at the end of this document. It should be recognized that rapid changes in the understanding of these risks and management techniques may occur in this field, and researchers are strongly encouraged to stay abreast of these developments. It is anticipated that the internal MSU documents will be used in conjunction with the researcher’s Departmental (or University general) Chemical Hygiene Plan (CHP), and that this guidance is subject to revision as new information or regulatory guidance becomes available. Nanomaterial Definitions Nanoparticles are particles having a diameter of 1 to 100 nanometers (nm) that may or may not have size-related intensive properties. The precise definition of particle diameter depends on particle shape as well as how the diameter is measured. These materials often exhibit unique physical and chemical properties as compared to their parent compounds. They may be suspended in a gas as a nanoaerosol, suspended in a liquid as a colloid or nanohydrosol, or embedded in a matrix as a nanocomposite. -
Fundamentals of Nanoelectronics (Fone)
ESF EUROCORES Programme Fundamentals of NanoElectronics (FoNE) Highlights European Science Foundation (ESF) Physical and Engineering Sciences (PESC) The European Science Foundation (ESF) is an The Physical and Engineering Sciences are key drivers independent, non-governmental organisation, the for research and innovation, providing fundamental members of which are 78 national funding agencies, insights and creating new applications for mankind. research performing agencies, academies and learned The goal of the ESF Standing Committee for Physical societies from 30 countries. and Engineering Sciences (PESC) is to become the The strength of ESF lies in its influential membership pan-European platform for innovative research and and in its ability to bring together the different domains competitive new ideas while addressing societal of European science in order to meet the challenges of issues in a more effective and sustainable manner. the future. The Committee is a unique cross-disciplinary Since its establishment in 1974, ESF, which has its group, with networking activities comprising a good headquarters in Strasbourg with offices in Brussels mix of experimental and theoretical approaches. and Ostend, has assembled a host of organisations It distinguishes itself by focusing on fundamental that span all disciplines of science, to create a research and engineering. PESC covers the following common platform for cross-border cooperation in broad spectrum of fields: chemistry, mathematics, Europe. informatics and the computer sciences, physics, ESF is dedicated to promoting collaboration in fundamental engineering sciences and materials scientific research, funding of research and science sciences. policy across Europe. Through its activities and instruments ESF has made major contributions to science in a global context. -
Enhancing the Thermal Stability of Carbon Nanomaterials with DNA
University of Rhode Island DigitalCommons@URI Chemical Engineering Faculty Publications Chemical Engineering 2019 Enhancing the Thermal Stability of Carbon Nanomaterials with DNA Mohammad Moein Safee University of Rhode Island Mitchell Gravely University of Rhode Island Adeline Lamothe University of Rhode Island Megan McSweeney University of Rhode Island Daniel E. Roxbury University of Rhode Island, [email protected] Follow this and additional works at: https://digitalcommons.uri.edu/che_facpubs Part of the Chemical Engineering Commons Citation/Publisher Attribution Safaee, M.M., Gravely, M., Lamothe, A. et al. Enhancing the Thermal Stability of Carbon Nanomaterials with DNA. Sci Rep 9, 11926 (2019). https://doi.org/10.1038/s41598-019-48449-x Available at: https://doi.org/10.1038/s41598-019-48449-x This Article is brought to you for free and open access by the Chemical Engineering at DigitalCommons@URI. It has been accepted for inclusion in Chemical Engineering Faculty Publications by an authorized administrator of DigitalCommons@URI. For more information, please contact [email protected]. www.nature.com/scientificreports OPEN Enhancing the Thermal Stability of Carbon Nanomaterials with DNA Mohammad Moein Safaee , Mitchell Gravely, Adeline Lamothe, Megan McSweeney & Daniel Roxbury Received: 31 January 2019 Single-walled carbon nanotubes (SWCNTs) have recently been utilized as fllers that reduce the Accepted: 6 August 2019 fammability and enhance the strength and thermal conductivity of material composites. Enhancing Published: xx xx xxxx the thermal stability of SWCNTs is crucial when these materials are applied to high temperature applications. In many instances, SWCNTs are applied to composites with surface coatings that are toxic to living organisms. -
Molecular and Polymer Nanodevices (Paper)
Molecular and Polymer Nanodevices Nikolai Zhitenev National Institute of Standards and Technology Over past years, the research and engineering community has been intensively looking for possibilities to extend of the information processing technologies into post- CMOS era. Recently, Nanotechnology Research Initiative formed by leading semiconductor companies has formulated a set of research vectors (Welser et al., 2008) to guide and to coordinate these efforts. Based on the analysis of the ultimate limitations of the present technology and on the observations of the research and development trends, one of the recommendations is the search of devices operating with the state variables different from an electronic charge. A solid-state switch where the computational state is defined by the spatial locations of heavy particles such as ions, atoms or molecular conformations is one of such possibilities. Possible advantage of heavier information carriers can be easily illustrated (Cavin et al., 2006). Scaling of CMOS devices operating with electronic charge will eventually reach the limit when logic or memory state decays because of electron tunneling under the barriers. For a given barrier height and width that is limited by the material constraints and the device size and by the requirement of the minimal power dissipation, carriers such as ions or atom that are thousands time heavier than electron offer much greater stability to the computational state. Ironically, the use of heavy carriers is absolutely impractical in larger devices because of much lower mobility. However, in a device of a few nanometer size, the ion/atom transport can be fast enough for practical applications. Short molecules and macromolecules can be used as active material for such switching devices. -
A Bipolar Electrochemical Approach to Constructive Lithography: Metal
ARTICLE pubs.acs.org/Langmuir A Bipolar Electrochemical Approach to Constructive Lithography: Metal/Monolayer Patterns via Consecutive Site-Defined Oxidation and Reduction † † ‡ † † Assaf Zeira, Jonathan Berson, Isai Feldman, Rivka Maoz,*, and Jacob Sagiv*, † ‡ Departments of Materials and Interfaces and Chemical Research Support, The Weizmann Institute of Science, Rehovot 76100, Israel bS Supporting Information ABSTRACT: Experimental evidence is presented, demonstrat- ing the feasibility of a surface-patterning strategy that allows stepwise electrochemical generation and subsequent in situ metallization of patterns of carboxylic acid functions on the outer surfaces of highly ordered OTS monolayers assembled on silicon or on a flexible polymeric substrate. The patterning process can be implemented serially with scanning probes, which is shown to allow nanoscale patterning, or in a parallel stamping configuration here demonstrated on micrometric length scales with granular metal film stamps sandwiched between two monolayer-coated substrates. The metal film, consisting of silver deposited by evaporation through a patterned contact mask on the surface of one of the organic monolayers, functions as both a cathode in the printing of the monolayer patterns and an anodic source of metal in their subsequent metallization. An ultrathin water layer adsorbed on the metal grains by capillary condensation from a humid atmosphere plays the double role of electrolyte and a source of oxidizing species in the pattern printing process. It is shown that control over both the direction of pattern printing and metal transfer to one of the two monolayer surfaces can be accomplished by simple switching of the polarity of the applied voltage bias. Thus, the patterned metal film functions as a consumable “floating” stamp capable of two-way (forwardÀbackward) electrochemical transfer of both information and matter between the contacting monolayer surfaces involved in the process. -
Carbon Nanomaterials: Building Blocks in Energy Conversion Devices
Mimicking Photosynthesis Carbon nanostructure-based donor- acceptor molecular assemblies can be engineered to mimic natural photo- synthesis. Fullerene C60 is an excellent electron acceptor for the design of donor-bridge-acceptor molecular systems. Photoinduced charge transfer processes in fullerene-based dyads and triads have been extensively investigated by several research groups during the last decade. In these cases the excited C60 accepts an electron from the linked donor group Carbon Nanomaterials: to give the charge-separated state under visible light excitation. Photoinduced charge separation in these dyads has Building Blocks in Energy been achieved using porphyrins, phtha- locyanine, ruthenium complexes, ferro- cene, and anilines as electron donors. Conversion Devices The rate of electron transfer and by Prashant Kamat charge separation efficiency is dependent on the molecular configuration, redox Carbon nanotubes, fullerenes, and mesoporous carbon potential of the donor, and the medium. Clustering the fullerene-donor systems structures constitute a new class of carbon nanomaterials with provides a unique way to stabilize properties that differ signifi cantly from other forms of carbon electron transfer products. The stability of C anions in cluster forms opens such as graphite and diamond. The ability to custom synthesize 60 up new ways to store and transport nanotubes with attached functional groups or to assemble photochemically harnessed charge. fullerene (C60 and analogues) clusters into three-dimensional Novel organic solar cells have (3D) arrays has opened up new avenues to design high surface been constructed by quaternary area catalyst supports and materials with high photochemical self-organization of porphyrin and fullerenes with gold nanoparticles. and electrochemical activity. -
Titanium Dioxide Nanoparticles: Prospects and Applications in Medicine
nanomaterials Review Titanium Dioxide Nanoparticles: Prospects and Applications in Medicine Daniel Ziental 1 , Beata Czarczynska-Goslinska 2, Dariusz T. Mlynarczyk 3 , Arleta Glowacka-Sobotta 4, Beata Stanisz 5, Tomasz Goslinski 3,* and Lukasz Sobotta 1,* 1 Department of Inorganic and Analytical Chemistry, Poznan University of Medical Sciences, Grunwaldzka 6, 60-780 Poznan, Poland; [email protected] 2 Department of Pharmaceutical Technology, Poznan University of Medical Sciences, Grunwaldzka 6, 60-780 Poznan, Poland; [email protected] 3 Department of Chemical Technology of Drugs, Poznan University of Medical Sciences, Grunwaldzka 6, 60-780 Poznan, Poland; [email protected] 4 Department and Clinic of Maxillofacial Orthopedics and Orthodontics, Poznan University of Medical Sciences, Bukowska 70, 60-812 Poznan, Poland; [email protected] 5 Department of Pharmaceutical Chemistry, Poznan University of Medical Sciences, Grunwaldzka 6, 60-780 Poznan, Poland; [email protected] * Correspondence: [email protected] (T.G.); [email protected] (L.S.) Received: 4 January 2020; Accepted: 19 February 2020; Published: 23 February 2020 Abstract: Metallic and metal oxide nanoparticles (NPs), including titanium dioxide NPs, among polymeric NPs, liposomes, micelles, quantum dots, dendrimers, or fullerenes, are becoming more and more important due to their potential use in novel medical therapies. Titanium dioxide (titanium(IV) oxide, titania, TiO2) is an inorganic compound that owes its recent rise in scientific interest to photoactivity. After the illumination in aqueous media with UV light, TiO2 produces an array of reactive oxygen species (ROS). The capability to produce ROS and thus induce cell death has found application in the photodynamic therapy (PDT) for the treatment of a wide range of maladies, from psoriasis to cancer. -
Nanoionics-Based Resistive Switching Memories
REVIEW ARTICLES | INSIGHT Nanoionics-based resistive switching memories Many metal–insulator–metal systems show electrically induced resistive switching effects and have therefore been proposed as the basis for future non-volatile memories. They combine the advantages of Flash and DRAM (dynamic random access memories) while avoiding their drawbacks, and they might be highly scalable. Here we propose a coarse-grained classification into primarily thermal, electrical or ion-migration-induced switching mechanisms. The ion-migration effects are coupled to redox processes which cause the change in resistance. They are subdivided into cation-migration cells, based on the electrochemical growth and dissolution of metallic filaments, and anion-migration cells, typically realized with transition metal oxides as the insulator, in which electronically conducting paths of sub-oxides are formed and removed by local redox processes. From this insight, we take a brief look into molecular switching systems. Finally, we discuss chip architecture and scaling issues. 1,2 3,4 RAINER WASER * AND MASAKAZU AONO ‘M’ stands for a similarly large variety of metal electrodes including 1Institut für Werkstoffe der Elektrotechnik 2, RWTH Aachen University, 52056 electron-conducting non-metals. A first period of high research Aachen, Germany activity up to the mid-1980s has been comprehensively reviewed 2Institut für Festkörperforschung/CNI—Center of Nanoelectronics for elsewhere2–4. The current period started in the late 1990s, triggered Information Technology, Forschungszentrum Jülich, 52425 Jülich, Germany by Asamitsu et al.5, Kozicki et al.6 and Beck et al.7. 3Nanomaterials Laboratories, National Institute for Material Science, Before we turn to the basic principles of these switching 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan phenomena, we need to distinguish between two schemes with 4ICORP/Japan Science and Technology Agency, 4-1-8 Honcho, Kawaguchi, respect to the electrical polarity required for resistively switching Saitama 332-0012, Japan MIM systems. -
A Nanoscale Study of Mosfets Reliability and Resistive Switching in RRAM Devices
ADVERTIMENT. Lʼaccés als continguts dʼaquesta tesi queda condicionat a lʼacceptació de les condicions dʼús establertes per la següent llicència Creative Commons: http://cat.creativecommons.org/?page_id=184 ADVERTENCIA. El acceso a los contenidos de esta tesis queda condicionado a la aceptación de las condiciones de uso establecidas por la siguiente licencia Creative Commons: http://es.creativecommons.org/blog/licencias/ WARNING. The access to the contents of this doctoral thesis it is limited to the acceptance of the use conditions set by the following Creative Commons license: https://creativecommons.org/licenses/?lang=en Universitat Autònoma de Barcelona Escola d’Enginyeria Electronic Engineering Department A nanoscale study of MOSFETs reliability and Resistive Switching in RRAM devices A dissertation submitted by Qian Wu in fulfillment of the requirements for the Degree of Doctor of Philosophy in Electronic and Telecommunication Engineering Supervised by Dr. Marc Porti i Pujal Bellaterra, November 2016 Universitat Autònoma de Barcelona Escola d’Enginyeria Electronic Engineering Department Dr. Marc Porti i Pujal, associate professor of the Electronic Engineering Department of the Universitat Autònoma de Barcelona, Certifies That the dissertation: A nanoscale study of MOSFETs reliability and Resistive Switching in RRAM devices submitted by Qian Wu to the School of Engineering in fulfillment of the requirements for the Degree of Doctor in the Electronic and Telecommunication Engineering Program, has been performed under his supervision. Dr. Marc Porti Bellaterra, November of 2016 To my family Acknowledgement The four years’ doctoral study is a significant and unforgettable experience for me. Many kind-hearted people give me a great amount of help, professional advice and encouragement. -
Engineered Carbon Nanotubes and Graphene for Nanoelectronics And
Engineered Carbon Nanotubes and Graphene for Nanoelectronics and Nanomechanics E. H. Yang Stevens Institute of Technology, Castle Point on Hudson, Hoboken, NJ, USA, 07030 ABSTRACT We are exploring nanoelectronic engineering areas based on low dimensional materials, including carbon nanotubes and graphene. Our primary research focus is investigating carbon nanotube and graphene architectures for field emission applications, energy harvesting and sensing. In a second effort, we are developing a high-throughput desktop nanolithography process. Lastly, we are studying nanomechanical actuators and associated nanoscale measurement techniques for re-configurable arrayed nanostructures with applications in antennas, remote detectors, and biomedical nanorobots. The devices we fabricate, assemble, manipulate, and characterize potentially have a wide range of applications including those that emerge as sensors, detectors, system-on-a-chip, system-in-a-package, programmable logic controls, energy storage systems, and all-electronic systems. INTRODUCTION A key attribute of modern warfare is the use of advanced electronics and information technologies. The ability to process, analyze, distribute and act upon information from sensors and other data at very high- speeds has given the US military unparalleled technological superiority and agility in the battlefield. While recent advances in materials and processing methods have led to the development of faster processors and high-speed devices, it is anticipated that future technological breakthroughs in these areas will increasingly be driven by advances in nanoelectronics. A vital enabler in generating significant improvements in nanoelectronics is graphene, a recently discovered nanoelectronic material. The outstanding electrical properties of both carbon nanotubes (CNTs) [1] and graphene [2] make them exceptional candidates for the development of novel electronic devices.