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Electrons, Life and the Evolution of Earth's Chemical Cycles
Electrons, Life and the Evolution of Earth’s Chemical Cycles OCN 623 – Chemical Oceanography 23 April 2013 Adaption of Brian Glazer lecture (based on Falkowski and Godfrey (2008) Phil. Trans. R. Soc. B, 363: 2705-2716) © 2013 F.J. Sansone Outline Earth’s geological, geochemical and biological co- evolution since formation - Early Earth - Origins of life - The great oxidation event - Linkage between global O and N cycles - Alternate explanations for the great oxidation event - The rise of oxygen and the evolution of life - The Phanerozoic How Does the Earth Work as a Biosphere? All organisms derive energy for growth and maintenance by moving electrons from a substrate to a product All substrates and products must ultimately be recycled All metabolic processes on Earth are prokaryotic and were developed in the Archean and/or Proterozoic Eons Earth’s Geological, Geochemical and Biological Co-evolution Since Formation Earth, ~3.5 Ga Ago • Earth cools to <100˚C • Shallow sea environment – Land covered by low egg- shaped hills and pillow lavas – Silt layers – Scattered volcanic islands and evaporite lagoons • Tides higher – Moon closer to Earth, days shorter • Atmosphere –CO2-rich, no O2 – UV-drenched landscape Faint Sun Paradox High atmospheric CO2 and CH4 important in early Earth -- balanced weak Sun to maintain temp Recycling of Atmospheric CO2 Liquid water on early Earth allowed a hydrologic cycle, carbonate and silicate mineral weathering to develop: 2+ - CaCO3 + CO2 + H2O = Ca + 2HCO3 2+ - CaSiO3 +2CO2 +3H2O = Ca + 2HCO3 + H4SIO4 Uptake -
Is Extraterrestrial Organic Matter Relevant to the Origin of Life on Earth?
IS EXTRATERRESTRIAL ORGANIC MATTER RELEVANT TO THE ORIGIN OF LIFE ON EARTH? D. C. B. WHITTET Department of Physics, Applied Physics and Astronomy, Rensselaer Polytechnic Institute, Troy, NY 12180, U.S.A. (Received 19 August 1996) Abstract. I review the relative importance of internal and external sources of prebiotic molecules on Earth at the time of life's origin 3.7 Gyr ago. The ef®ciency of synthesis in the Earth's atmosphere was critically dependent on its oxidation state. If the early atmosphere was non-reducing and CO2- dominated, external delivery might have been the dominant source. Interplanetary dust grains and micrometeorites currently deliver carbonaceous matter to the Earth's surface at a rate of 3 5 7 10 kg/yr (equivalent to a biomass in 2 Gyr), but this may have been as high as 5 10 kg/yr (a biomass in only 10 Myr) during the epoch of late bombardment. Much of the incoming material is in the form of chemically inactive kerogens and amorphous carbon; but if the Earth once had a dense (10-bar) atmosphere, small comets rich in a variety of prebiotic molecules may have been suf®ciently air-braked to land non-destructively. Lingering uncertainties regarding the impact history of the Earth and the density and composition of its early atmosphere limit our ability to draw ®rm conclusions. 1. Introduction In at least one sense, a connection between the Universe at large and life in our small corner of it is inevitable. The hydrogen, carbon, nitrogen, oxygen, and other elements that make up our bodies and other living things were created billions of years ago in the interiors of stars and, in the case of hydrogen, in the the Big Bang itself (see Trimble, 1997, in this volume for an eloquent review). -
Life in the Outer Solar System Jupiter
Life in the Outer Solar System Jupiter Big R = 11R⊕ Massive M = 300 M⊕ = 2.5 all the rest Thick Atmosphere Mostly H2, He But also more complex molecules Colors, storms Like Miller - Urey Life in Jupiter Atmosphere? Sagan-Salpeter, etc. Sinkers (Plankton) Floaters (Fish) Hunters (Fish) Galileo Results on Jupiter Reached Jupiter Dec. 1995 Sent probe into Jupiter’s atmosphere at 100,000 mile/hour Decelerated at 230 g Lasted for 57 min. Found: Strong winds Turbulence, little lightning Life less likely? Surprise: Little or no H2O May have entered in an unusual place (fewer clouds) Europa (Moon of Jupiter) Surface: Fractured Ice Subsurface Oceans? (Heated from Inside) Close-up of “ice floes” Galileo - Jupiter’s Moons http://www.jpl.nasa.gov/galileo/index.html Europa has a (THIN!) atmosphere UV H H H O=O T hin O O2 H2O ATM Pressure ~ 10–11 Earth More evidence for resurfacing along cracks by “ice geysers” fluid ice or liquid water Organic molecules on Callisto & Ganymede, maybe Europa? Saturn • Big (9.4 R⊕) • Massive (95 M⊕) • Year 29.5 years • Day 0.43 days • Composition similar to Jupiter Titan • Moon of Saturn • Diameter ~0.4 Earth • Atmospheric Pressure = 1.5 × Earth • 85% Nitrogen BUT • Cold (~90 K) • Reducing atmosphere • Haze • Lab for prebiotic chemistry The Cassini-Huygens Mission • Launched 10/13/97 • Arrived Saturn 7/2004 • Cassini studies – Saturn – Moons • Huygens – Dropped onto Titan – Study atmosphere – Surface CASSINI SPACECRAFT Huygens Probe • Released from Cassini • Slowed by heat shield • Parachute deploys • Soft landing • Sample -
REOXIDATION of SPONGE IRON IS an EXOTHERMIC PROCESS DUE to REMOVAL of HYDROGEN‖ Prof
International Journal Of advance research in Science and Engineering http://www.ijarse.com (IJARSE) 2012, Vol. No.1, Issue No. I, July ISSN-2319-8354 ―REOXIDATION OF SPONGE IRON IS AN EXOTHERMIC PROCESS DUE TO REMOVAL OF HYDROGEN‖ Prof. Pushpendra Kumar Sharma1, Neeraj Singh Rajput2, Prof. Sachin Jain3 1Head Mechanical Engineering Department, NIIST, Bhopal 2Post Graduate Student, NIIST, Bhopal 3Asst. Professor, NIIST, Bhopal [email protected] Abstract— In the present era scarcity of high grade coal, high valuable process of coke production is a headache. So to get release from this problem huge amount of electric arc furnace and sponge iron production is increased. Sometimes Sponge iron transportation is a problematic situation, because during transportation chances of spontaneous burning of sponge iron are found, that is the effect of re-oxidation of sponge iron. Re-oxidation of sponge iron phenomenon refers to oxidation of metallic sponge iron in moisture condition. Metallic iron forms a strongly bonded Fe (OH)2 compound which causes increase in mass of sponge iron. The re-oxidation phenomenon is an exothermic process. Sponge iron is spongy in structure having large in porous area. Thus it is very much reactive and seeks for high oxidation. So the sponge iron produced is highly susceptible to re-oxidation. So it is important to study the kinetic of sponge iron re-oxidation. Keywords—Sponge iron, Iron ore, Coal, Dolomite, Power unit for initial power consuming unit. INTRODUCTION The conventional route for making steel consists of sintering/pelletization plants, ovens, blast and basic oxygen furnaces. Such plants need huge capital expenses and raw materials as they are the stringent requirements. -
(5) Field: Session Topic: Speaker
(5) Field: Earth Science/Geoscience/Environment Session Topic: Stable Isotopes in Earth and Space Science Speaker: Shogo Tachibana, The University of Tokyo 1. Introduction The present Earth’s atmosphere is made up of 78% of nitrogen, 21% of oxygen (we breathe oxygen to live!), and 1% of other gases. However, the present oxygen-rich atmosphere is not the Earth’s original atmosphere. The atmosphere changed its chemical composition in the history of Earth. The present oxygen-rich atmosphere was built up by photosynthesis of cyanobacteria, and it has been known that the Earth’s atmosphere contained almost no oxygen in the Archean (>2.5 billion years ago (Ga)). There have been several geological indicators for the atmospheric oxygen level such as presence of detrital pyrite and uraninite in sedimentary rocks for the reducing atmosphere and presence banded iron formations and red beds for the oxidizing atmosphere. Geological records for transition from the reducing atmosphere to the oxidation atmosphere (Great Oxygenation Event) have been found in the Paleoproterozoic sedimentary rocks. 2. Mass-independent fractionation of sulfur isotopes and its relation to the atmospheric chemistry Sulfur has four stable isotopes (32S, 33S, 34S, and 36S). Their average relative abundances in the solar system are 95.02%, 0.75%, 4.22%, and 0.017% for 32S, 33S, 34S, and 36S, respectively, but they can be varied by various physical, chemical, and/or biological processes. The variations of relative abundances of 32S and 34S in minerals or rocks have been used to understand geological and biological processes on the Earth. Other two minor isotopes (33S and 36S) had not been measured intensively because their relative abundances were assumed to vary with following the mass-dependent fractionation law. -
Laboratory-Scale Investigation of the Removal of Hydrogen Sulfide From
Laboratory-scale investigation of the removal of hydrogen sulfide from biogas and air using industrial waste-based sorbents Olumide Wesley Awe, Doan Pham Minh, Nathalie Lyczko, Ange Nzihou, Yaqian Zhao To cite this version: Olumide Wesley Awe, Doan Pham Minh, Nathalie Lyczko, Ange Nzihou, Yaqian Zhao. Laboratory- scale investigation of the removal of hydrogen sulfide from biogas and air using industrial waste- based sorbents. Journal of Environmental Chemical Engineering, Elsevier, 2017, 5 (2), p.1809-1820. 10.1016/j.jece.2017.03.023. hal-01619255 HAL Id: hal-01619255 https://hal.archives-ouvertes.fr/hal-01619255 Submitted on 20 Oct 2018 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Laboratory-scale investigation of the removal of hydrogen sulfide from biogas and air using industrial waste-based sorbents a,b, b, b b Olumide Wesley Awe *, Doan Pham Minh **, Nathalie Lyczko , Ange Nzihou , a Yaqian Zhao a Dooge Centre for Water Resources Research, School of Civil Engineering, University College Dublin, Newstead, Belfield, Dublin 4, Ireland b Universite’ de Toulouse, Mines Albi, CNRS UMR 5302, Centre RAPSODEE, Campus Jarlard, Albi, F-81013 cedex 09, France A B S T R A C T Biogas is a valuable renewable energy that can be used as a fuel or as raw material for the production of hydrogen, synthesis gas and chemicals. -
What Are the Health Effects from Exposure to Carbon Monoxide?
CO Lesson 2 CARBON MONOXIDE: LESSON TWO What are the Health Effects from Exposure to Carbon Monoxide? LESSON SUMMARY Carbon monoxide (CO) is an odorless, tasteless, colorless and nonirritating Grade Level: 9 – 12 gas that is impossible to detect by an exposed person. CO is produced by the Subject(s) Addressed: incomplete combustion of carbon-based fuels, including gas, wood, oil and Science, Biology coal. Exposure to CO is the leading cause of fatal poisonings in the United Class Time: 1 Period States and many other countries. When inhaled, CO is readily absorbed from the lungs into the bloodstream, where it binds tightly to hemoglobin in the Inquiry Category: Guided place of oxygen. CORE UNDERSTANDING/OBJECTIVES By the end of this lesson, students will have a basic understanding of the physiological mechanisms underlying CO toxicity. For specific learning and standards addressed, please see pages 30 and 31. MATERIALS INCORPORATION OF TECHNOLOGY Computer and/or projector with video capabilities INDIAN EDUCATION FOR ALL Fires utilizing carbon-based fuels, such as wood, produce carbon monoxide as a dangerous byproduct when the combustion is incomplete. Fire was important for the survival of early Native American tribes. The traditional teepees were well designed with sophisticated airflow patterns, enabling fires to be contained within the shelter while minimizing carbon monoxide exposure. However, fire was used for purposes other than just heat and cooking. According to the historian Henry Lewis, Native Americans used fire to aid in hunting, crop management, insect collection, warfare and many other activities. Today, fire is used to heat rocks used in sweat lodges. -
THE 6 MAJOR BODY SYSTEMS and How They Interact with Each Other to Keep the “Body Machine” Alive and Working Well
THE 6 MAJOR BODY SYSTEMS And how they interact with each other to keep the “body machine” alive and working well. CIRCULATORY SYSTEM / CARDIOVASCULAR SYSTEM PRIMARY PURPOSE: transport blood throughout the body by circulating PRIMARY ORGANS/PARTS: Heart, blood vessels (arteries, veins, capillaries) (1) Transports/carries nutrients and oxygen through the blood to most parts of the body (2) Transports/carries waste in cells and carbon-dioxide (CO2) away from the parts: (a) Cell waste goes to the kidneys for filter and disposal (b) Carbon-dioxide (CO2) goes to the lungs to exhale (breathe out) Kidneys and Lungs have a close relationship with Cardiovascular system Kidneys: filter through blood to take out the waste and get it eventually out of the body Lungs: breathes in oxygen and gives it to the blood for Circulatory system to carry throughout the body; and takes unneeded carbon-dioxide (CO2) from the blood and breathes that out. Circulatory/Cardiovascular System through the blood to most parts of the body provides nutrients and oxygen which is needed for our bodies to have ENERGY! RESPIRATORY SYSTEM PRIMARY PURPOSE: Breathing - taking in Oxygen, pushing out Carbon-Dioxide (CO2) PRIMARY ORGANS: Lungs, trachea (tube going from lungs to nose/mouth) (1) Inhales (breathes in) Oxygen - good for the body - gives it to the Circulatory System to be transported throughout the body through the blood. (2) Exhales (breathes out) Carbon-Dioxide (CO2) - lungs get this gas from the blood (Circ. Sys.) and pushes it out of the body DIGESTIVE SYSTEM PRIMARY PURPOSE: take in food; break down food into nutrients (good) and waste (unneeded) PRIMARY ORGANS: Stomach, large and small intestines, esophagus (tube from stomach to mouth) (1) Digestive System gets nutrients (good) from food and hands it over to the blood and Circulatory System then carries those nutrients where they need to go. -
Overview of the Circulatory System Fill in the Blank
Overview Of The Circulatory System Fill In The Blank If orthotropic or rheumatoid Bernardo usually Germanising his erotica euphemize contractually or expect centrally and Malaprop, how pessimum is Tore? Obcordate Darius hale meltingly. Liberating and aerobatic Marco vandalise, but Lynn quickly unlives her margins. LESSON 1. Bio 104 Chapters 17 20 Cardiovascular System 33. Short-Answer Questions About Circulatory and Lymphatic System Infections. Circulatory system the concept to blood pressure and available and flake the currency of William Harvey II Overview the Concept Objectives The student will 1. Cardiovascular System Higher Education Pearson. Outline The Digestive System develop your textbook to one you clock in the blanks Where do. As the pulmonary circulation at the remaining circles from each blank to fill the in humans and cocaine affect the pulmonary vein in. Circulatory and Lymphatic System Infections GALILEO Open. The vascular diseases that red blood comes with their amazing heart failure occurs most of ingested food pieces of circulatory system, resulting pattern of the. 7 Circulatory System Diseases Symptoms Risks and More. For each definition given below fill date the inmate with the crate part that completes the term. The respiratory system access in blanks worksheet answers human digestive. FREE Circulatory System Activities and Classroom Resources Teacher Planet. Blood and Circulation Webquest Gates Chili. Then to pass through the systemic artery is vital for developing this system circulatory system is blood pressure, where they extend like you can adjust their understanding its chambers. Blood cannot flow diagrams a particular part in the circulatory system blank to. There are separated by which vitamins, fill the vessels that makes cells found, body and describing the. -
High Temperature, Reducing Atmosphere, Continuous Furnaces to 1800°C (3272°F)
industrial and laboratory furnaces www.cmfurnaces.com HIGH TEMPERATURE, REDUCING ATMOSPHERE, CONTINUOUS FURNACES TO 1800°C (3272°F) The CM 300 Series furnaces are available in a variety the 300 Series muffle design furnaces. When automated of configurations from manually loaded lab-scale units the pusher plates (carrier trays) form a train and are to fully automated production systems. These furnaces pushed through the furnace by an external stoker employ a molybdenum wound aluminum oxide muffle, device. All automation is located outside the heat typically D-shaped, designed to operate from 800°C envelope for ease of maintenance and long life. (1472°F) to 1700°C (3100°F) on the standard models Hydrogen, dissociated ammonia, forming gas or any and as high as 1800°C (3272°F) for special applications. other reducing atmosphere compatible the refractory The base model includes inclined doors with protective metal heating elements can be employed. The standard atmosphere flushes, high heat section, and a cooling gas panel includes all necessary pressure regulators, section. Depending on application requirements other flow meters, solenoids and pressure switches for both features are added such as preheat sections, binder primary processing atmosphere and standby safety removal sections, multiple zone controls, low or high nitrogen. All furnaces come complete with the CM dewpoint features, and turn-key automated pusher combustion atmosphere safety system. Full details are systems. available on request. The furnaces are constructed of heavy gauge steel that Temperature control is by microprocessor based is welded and reinforced. All power components and setpoint controllers operating in conjunction with controls are located on the main frame assembly. -
Atmospheric Nitrogen Evolution on Earth and Venus
Atmospheric nitrogen evolution on Earth and Venus The Harvard community has made this article openly available. Please share how this access benefits you. Your story matters Citation Wordsworth, R.D. 2016. “Atmospheric Nitrogen Evolution on Earth and Venus.” Earth and Planetary Science Letters 447 (August): 103–111. doi:10.1016/j.epsl.2016.04.002. http://dx.doi.org/10.1016/ j.epsl.2016.04.002. Published Version doi:10.1016/j.epsl.2016.04.002 Citable link http://nrs.harvard.edu/urn-3:HUL.InstRepos:27846862 Terms of Use This article was downloaded from Harvard University’s DASH repository, and is made available under the terms and conditions applicable to Open Access Policy Articles, as set forth at http:// nrs.harvard.edu/urn-3:HUL.InstRepos:dash.current.terms-of- use#OAP Atmospheric nitrogen evolution on Earth and Venus R. D. Wordsworth Harvard Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, MA 02138, Department of Earth and Planetary Sciences, Harvard University, Cambridge, MA 02138 Abstract Nitrogen is the most common element in Earth’s atmosphere and also appears to be present in significant amounts in the mantle. However, its long-term cycling between these two reservoirs remains poorly understood. Here a range of biotic and abiotic mechanisms are evaluated that could have caused nitrogen exchange between Earth’s surface and interior over time. In the Archean, biological nitrogen fixation was likely strongly limited by nutrient and/or electron acceptor constraints. Abiotic fixation of dinitrogen becomes efficient in strongly reducing atmospheres, but only once temperatures exceed around 1000 K. -
I960 DISSERTATION Ohio Ohio State University the Ohio State University Kenneth Rae Coburn, B
THE CARDIOVASCULAR AND RESPIRATORY RESPONSES OF DOGS TO LETHAL CONCENTRATIONS OF CARBON MONOXIDE DISSERTATION Pi Q Pi resented in Partial Fulfillment of the Requirements for the egree Doctor of Philosophy in the Graduate School of the Ohio State University BY Kenneth Rae Coburn, B. S. The Ohio State University i960 Approved by AdvisorA r ^ T ri Department of Physiology ACKNOWLEDGMENTS I wish, to express my sincere appreciation for the guidance, enthusiasm and invaluable aid of Doctors Fred A0 Hitchcock, Earl T. Carter and Joseph F„ Tomashefski without whose assistance this study could never have been carried out. I am grateful to all those of the Cardiopulmonary Laboratory of the Ohio State Tuberculosis Hospital for the aid and assistance which they offered. CONTENTS Introduction ........................................................................ 1 Survey of the Literature A. Early History of CO Poisoning............................................ 4 B. Absorption and Excretion of C O...................................................... 5 C. Oxygen, Carbon Monoxide and Hemoglobin........ 8 D. Blood and Circulatory Changes in CO Poisoning...............................15 a. Blood Changes . 15 b. Blood Vessels and CO ................................................16 c. Behaviour of the Heart ...................................................16 E. Effect of CO on Respiration .............. 18 F. Recent Integrated Studies.............................................................................. 19 Methods and Procedures A. Anesthesia