RUSSIAN CHEMICAL BULLETIN International Edition Volume 60, Number 12, December, 2011

2011 Contents

Issue 1, 2011

Version

Engl./Russ.

On the 75th anniversary of the Journal xiii xi Salambek Naibovich Khadzhiev (on his seventieth birthday) xv xiii

Reviews

Supramolecular systems as a bridge between nonliving A. I. Konovalov 1 1 and living matter

Full Articles

Lattice model of a polar liquid S. V. Titov and Yu. K. Tovbin 11 12 On the mechanism of increasing ion conductivity E. Yu. Safronova, A. A. Lysova, 20 21 in hybrid membranes S. A. Novikova, and A. B. Yaroslavtsev Mechanism of singlet oxygen generation during catalytic M. Yu. Ovchinnikov, S. L. Khursan, 28 29 decomposition of methyl(trifluoromethyl)dioxirane and D. V. Kazakov by chloride ions Bond energies and the enthalpies of formation of mono E. A. Miroshnichenko, 36 37 and polyradicals in nitroakanes. 3. Nitroalkanes T. S. Kon´kova, C4—C7 Ya. O. Inozemtsev, and Yu. N. Matyushin Adsorption of ethanol on the modified ruthenium O. V. Korchagin, M. R. Tarasevich, 42 42 catalysts in alkaline media and V. T. Novikov Uncommon oxidative transformations of acetic Е. G. Chepaikin, А. P. Bezruchenko, 49 49 and propionic acids G. N. Menchikova, N. I. Моiseevа, А. Е. Gekhmаn, and I. I. Моisееv Dry reforming of methane on porous membrane M. V. Tsodikov, V. V. Teplyakov, 55 54 catalytic systems A. S. Fedotov, N. Yu. Kozitsyna, V. Yu. Bychkov, V. N. Korchak, and I. I. Moiseev Electrochemical hydrogenation of 3(methoxyphenyl) L. M. Korotaeva, T. Ya. Rubinskaya, 63 62 propenoic acids I. A. Rybakova, and V. P. Gultyai

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2573—2599, December, 2011. 10665285/11/60122627 © 2011 Springer Science+Business Media, Inc. 2628 Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2011 Contents

Version Engl./Russ. Vibrational spectra and structural features of carbene analogs R. R. Aysin, L. A. Leites, 69 68 II II El (OCH2CH2NMe2)2 and ClEl OCH2CH2NMe2 S. S. Bukalov, V. N. Khrustalev, (ElII = Ge, Sn, Pb) I. V. Borisova, N. N. Zemlyanskii, A. Yu. Smirnov, and M. S. Nechaev Composition and structure of heteroassociates formed in E. G. Tarakanova 81 79 the HF—N,Ndimethylformamide binary liquid system and G. V. Yukhnevich Heteroassociates of singly and doublycharged anions S. A. Shapovalov 89 87 of alizarin red S with the pinacyanol cation

Cp2ZrCl2Catalyzed cycloalumination of acetylenic I. R. Ramazanov, R. N. Kadikova, 99 96 alcohols and propargylamines by Et3Al and U. M. Dzhemilev Synthesis and transformations of metallacycles. 37. V. A. D´yakonov, O. A. Trapeznikova, 107 103 Сp2ZrCl2Catalyzed cycloalumination of and U. M. Dzhemilev substituted methylidenecyclopropane with Et3Al New polydentate ligands based on sterically hindered G. A. Abakumov, V. K. Cherkasov, 112 108 obenzoquinones (pyrocatechols) containing N. O. Druzhkov, the 1,4diazadiene group T. N. Kocherova, and A. S. Shavyrin Triruthenium complexes obtained in the thermal reaction S. V. Osintseva, N. A. Shtel´tser, 118 114 of Ru3(CO)12 with dibenzylideneacetone P. V. Petrovskii, A. Z. Kreindlin, and F. M. Dolgushin Photochromic properties of phenanthrolineannulated V. F. Plyusnin, E. M. Glebov, 124 119 spirooxazine in the solid state V. P. Grivin, V. V. Korolev, A. V. Metelitsa, N. A. Voloshin, and V. I. Minkin Thermodynamic properties of pyridinecontaining N. N. Smirnova, A. V. Markin, 132 127 polyphenylene dendrimers of the first—fourth Yu. A. Zakharova, generations N. V. Kuchkina, A. L. Rusanov, and Z. B. Shifrina Acylation of Meldrum´s acid with arylacetic acid A. A. Shimkin, V. Z. Shirinian, 139 134 imidazolides as a convenient method for A. K. Mailian, D. V. Lonshakov, the synthesis of 4aryl3oxobutanoates V. V. Gorokhov, and M. M. Krayushkin Reactions of 3,3,3trichloro(trifluoro)1nitropropenes V. Yu. Korotaev, A. Yu. Barkov, 143 137 with 2morpholinoalk1enes P. A. Slepukhin, and V. Ya. Sosnovskikh Reactions of 2diaminomethylidenecyclohexane1,3diones V. A. Voronkova, A. V. Komkov, 148 141 with diethyl malonate A. S. Shashkov, and V. A. Dorokhov 3Hydroxy and 3alkoxy2sulfanylquinazolin4(3H)ones: P. S. Khokhlov, V. N. Osipov, 153 146 synthesis and reactions with alkylating and acylating agents and A. V. Roshchin Synthesis and basecatalyzed cleavage of 1aryl4,9dioxo L. M. Gornostaev, L. V. Dolgushina, 157 150 1Hnaphtho[2,3d][1,2,3]triazole 2oxides Yu. G. Khalyavina, G. A. Stashina, and S. I. Firgang NTrifluoroacetyl3a,4,5,9btetrahydro3Hcyclo A. G. Tolstikov, R. G. Savchenko, 160 153 penta[c]quinoline ozonides D. V. Nedopekin, S. R. Afon´kina, E. S. Lukina, and V. N. Odinokov 2011 Contents Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2629

Version Engl./Russ. Synthesis and photochromic properties of O. G. Karamov, V. P. Rybalkin, 168 161 N2alkyl5furyl4thienylpyridazinones N. I. Makarova, A. V. Metelitsa, V. S. Kozyrev, G. S. Borodkin, L. L. Popova, V. A. Bren´, and V. I. Minkin

Brief Communications

Sorbents based on calix[4]arenes for extraction of N. N. Popova, V. P. Morgalyuk, 175 167 technetium(VII) from acidic and alkaline media I. G. Tananaev, S. E. Solovieva, E. V. Popova, and I. S. Antipin

Ionic liquid [BMIM]PF6 as a medium for the selective E. A. Tarasenko, V. I. Isaeva, 179 171 hydrogenation of 1,4diacetoxybut2yne on I. P. Beletskaya, the Pdcontaining catalysts and L. M. Kustov Titaniumcatalyzed cyclocodimerization of cyclohepta V. A. D´yakonov, G. N. Kadikova, 182 174 1,3,5triene with spiro[cyclopropane1,7´nor L. M. Khalilov, borna2,5diene] and U. M. Dzhemilev Oxidation of organic sulfides and disulfides with a tertbutyl E. A. Zaburdaeva and V. A. Dodonov 185 177 hydroperoxide—aluminum tritertbutoxide system

New transformation of acetylеnic ketones under M. P. Davydova, S. F. Vasilevsky, 188 180 the action of 1,2diaminoethane and G. A. Tolstikov

Letters to the Editor

Template synthesis of nanocomposite CdS with nonlinear I. M. Nassar, I. G. Galyaviev, 191 182 optical properties G. M. Safiullin, V. G. Nikiforov, V. S. Lobkov, and Yu. G. Galyametdinov The Mumm—Hesse rearrangement in the synthesis of Nphenyl V. G. Kotlyarov, V. F. Burdukovskii, 194 185 substituted polydiacylamines and D. M. Mognonov Regioselective dehydrobromination reaction of 5bromo V. A. Potapov, E. O. Kurkutov, 196 187 2bromomethyl1,3thiaselenolane 1,1dioxide S. V. Amosova, and Yu. Yu. Rusakov

Aminoselenenation of alkenes with arylselenenamides A. N. Chernysheva, R. L. Antipin, 198 189 in the presence of sulfamic acid A. A. Borisenko, E. K. Beloglazkina, and N. V. Zyk Information 200 193 Issue 2, 2011

Full Articles

Intra and interring haptotropic rearrangements in (naphthalene Yu. F. Oprunenko and I. P. Gloriozov 213 207 and anthracene)nickel complexes: a DFT study On calculations of the ion hydration free energy within M. V. Fedotova and S. E. Kruchinin 223 218 the framework of the RISM approach Collapse of an AB copolymer single chain with I. V. Neratova, P. V. Komarov, 229 224 alternating blocks of different stiffness A. S. Pavlov, and V. A. Ivanov 2630 Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2011 Contents

Version Engl./Russ. Biophysical chemistry of macrocycles for drug delivery: B. Khalili Hadad, F. Mollaamin, 238 233 a theoretical study and M. Monajjemi Silica gelimmobilized aluminum phthalocyanine complex E. D. Matveeva, M. V. Shuvalov, 242 237 as a heterogeneous catalyst for the synthesis and N. S. Zefirov of amino phosphonates

Synthesis of hydrazino phosphonates from Lamino acid E. D. Matveeva, I. N. Kolesnikova, 248 243 and Lglutathionederived hydrazones and N. S. Zefirov

Synthesis of pyridinecontaining hydrazino phosphonates E. D. Matveeva, T. A. Podrugina, 254 249 by twocomponent catalytic procedure I. N. Kolesnikova, and N. S. Zefirov Application of the ferrocenecontaining chelated palladacycles L. A. Bulygina, N. S. Khrushcheva, 258 252 as catalysts in the Suzuki reaction and V. I. Sokolov New organic picolylaminetype ligands and electrochemical A. G. Majouga, R. B. Romashkina, 261 255 study of their complexation with Cu(MeCN)4ClO4 A. S. Kashaev, Е. К. Beloglazkina, А. А. Moiseeva, and N. V. Zyk

Europium(III) phthalocyanine complexes with 8oxyquinoline K. N. Maksimova, N. L. Bazyakina, 269 263 O. N. Suvorova, and D. Wöhrle Formation of cobalt and lithiumcontaining heterometallic N. V. Zauzolkova, M. E. Nikiforova, 273 267 pyridonate carboxylate coordination polymers M. A. Kiskin, A. S. Bogomyakov, A. A. Sidorov, and I. L. Eremenko Selforganization of crowncontaining hetarylphenylethenes, Yu. V. Fedorov, E. Yu. Chernikova, 280 274 phthalic acid, and potassium cations into supramolecular A. S. Peregudov, N. E. Shepel´, assemblies E. N. Gulakova, L. G. Kuz´mina, and O. A. Fedorova Synthesis and optical properties of copolymers of 4aminostyrene M. Ya. Goikhman, L. I. Subbotina, 295 288 with the side styrylquinoline chromophore groups A. A. Martynenkov, M. A. Smirnov, R. Yu. Smyslov, E. N. Popova, and A. V. Yakimanskii Synthesis of organosilicon polymers with cyclohexasilane A. I. Chernyavskii, D. Yu. Larkin, 304 297 fragments in the main chain M. I. Buzin, and N. A. Chernyavskaya Selective oxidation of primary alkanols into the "symmetrical" G. I. Nikishin, L. L. Sokova, 310 303 esters with the H2O2—MBr—HCl system and N. I. Kapustina

Cyclopropanation of alkynols with the CH2I2—R3Al system I. R. Ramazanov, A. V. Yaroslavova, 313 306 U. M. Dzhemilev, and O. M. Nefedov Synthesis of substituted cyclopentanes based on intramolecular A. V. Lozanova, A. V. Stepanov, 319 312 [3+2] cycloaddition of trimethylsilyl nitronates generated O. D. Osipova, A. N. Vinnikova, from 6nitrohex1ene derivatives and V. V. Veselovsky gemDichloro(alkyl)cyclopropanes in reactions with NOCl•2SO3: N. V. Zyk, O. B. Bondarenko, 328 321 synthesis of alkyl5chloroisoxazoles A. Yu. Gavrilova, A. O. Chizhov, and N. S. Zefirov Nitration of primary aminofurazans with aqueous nitric acid V. P. Zelenov and A. A. Lobanova 334 327 Synthesis of isomeric 1,3 and 1,4bis[3(4)nitrofuroxan A. O. Finogenov, M. A. Epishina, 339 332 4(3)yl]nitrobenzenes by nitration of the corresponding I. V. Ovchinnikov, A. S. Kulikov, isomeric 1,3 and 1,4bis[3(4)nitrofuroxan4(3)yl]benzenes I. V. Anan´ev, and N. N. Makhova 2011 Contents Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2631

Version Engl./Russ. Cascade reactions of diazocarbonyl compounds with pyridinium D. V. Dorokhov, D. N. Platonov, 345 338 aroylmethylides accompanied by water or benzoic acid K. Yu. Suponitskii, elimination in the cyclocondensation step and Yu. V. Tomilov 2Aminothiophene derivatives in a novel synthesis L. Yu. Ukhin, E. N. Shepelenko, 352 345 of phthalimidines L. V. Belousova, Zh. I. Orlova, G. S. Borodkin, and K. Yu. Suponitskii Reactions of polyfluorinated chalcones with oamino K. S. Shmuilovich, N. A. Orlova, 361 353 benzenethiol and its zinc salt I. V. Beregovaya, and V. V. Shelkovnikov Benzimidazoles and related heterocycles. 10. A novel acid V. A. Mamedov, E. A. Khafizova, 368 359 catalyzed rearrangement in the system 3(amino A. T. Gubaidullin, benzyl)quinoxalin2(1H)one—ethyl acetoacetate A. M. Murtazina, as a simple and efficient method for synthesizing D. I. Adgamova, A. I. Samigullina, 2(pyrrol3yl)benzimidazoles and I. A. Litvinov

Brief Communications

Chemiluminescence during interaction of 1,2,4trioxolanes D. V. Kazakov, M. Yu. Ovchinnikov, 373 364 and 1,2,4,5tetraoxanes with iron compounds F. E. Safarov, and A. R. Timerbaev

Letters to the Editor

Elution on adsorbent beds of short length. Analytical solution A. V. Larin 376 367 Issue 3, 2011

Vladimir Yaroslavovich Shevchenko (on his seventieth birthday) xiii ix Vilen Vagarshovich Azatyan (on his eightieth birthday) xv x

Reviews

The chemistry of 2,3dihydroisoxazole derivatives N. V. Chukanov and V. A. Reznikov 379 371

Full Articles

Molecular modeling of hydration properties of hydrophobic T. Yu. Dolinina, N. S. Rusova, 400 392 + + ions Li @C60 and K @C60 and V. B. Luzhkov Synthesis of carbon nanofibers by catalytic pyrolysis of ethylene A. A. Volodin, E. V. Gerasimova, 407 398 in the presence of vapors of volatile components and B. P. Tarasov Effect of high pressures and temperatures on carbon nanoonion G. A. Dubitsky, N. R. Serebryanaya, 413 404 structures: comparison with C60 V. D. Blank, E. A. Skryleva, B. A. Kulnitsky, B. N. Mavrin, V. V. Aksenenkov, R. Kh. Bagramov, V. N. Denisov, and I. A. Perezhogin Dielectric properties of sols of silver nanoparticles capped G. F. Novikov, M. V. Gapanovich, 419 410 by alkyl carboxylate ligands E. V. Rabenok, L. M. Bogdanova, and L. I. Kuzub 2632 Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2011 Contents

Version Engl./Russ. Synthesis and study of gold nanoparticles stabilized L. A. Levchenko, S. A. Golovanova, 426 417 by bioflavonoids N. V. Lariontseva, A. P. Sadkov, D. N. Voilov, Yu. M. Shul´ga, N. G. Nikitenko, and A. F. Shestakov Formation of nanocomposite platinum catalysts N. A. Yashtulov, S. S. Gavrin, 434 425 on porous silicon V. P. Bondarenko, K. I. Kholostov, A. A. Revina, and V. R. Flid New mixed palladium—lead and palladium—tin tellurides E. Yu. Zakharova, A. A. Isaeva, 440 431 of the NiAs type A. N. Kuznetsov, and A. V. Olenev ESR study of structural characteristics and intramolecular I. R. Nizameev, V. I. Morozov, 446 437 motions of tris(3,5ditertbutyl4hydroxybenzyl) and M. K. Kadirov amine free radical in toluene Investigation of cobalt (1,10phenanthroline)bis(3,6di M. P. Bubnov, N. A. Skorodumova, 449 440 tertbutylobenzosemiquinolate) by Xray diffraction, A. S. Bogomyakov, IR and ESR spectroscopy, magnetochemistry, G. V. Romanenko, A. V. Arapova, and precision calorimetry K. A. Kozhanov, N. N. Smirnova, G. A. Abakumov, and V. K. Cherkasov Spiropyrans and spirooxazines. 6. The spectral and kinetic A. V. Chernyshev, I. V. Dorogan, 456 447 properties of 5(4,5diphenyl1,3oxazol2yl)substituted N. A. Voloshin, A. V. Metelitsa, spironaphthopyrans: an experimental and theoretical study and V. I. Minkin Association of anions of phenolsulfonephthalein and its alkyl S. A. Shapovalov 465 455 substituted derivatives with singlecharged cations of polymethines A dependence of electrical conductivity and some properties A. A. Durgaryan, N. A. Durgaryan, 474 464 of paramagnetic centers on the doping level of and R. A. Arakelyan poly(4aminoazobenzene) with iodine Synthesis of azacrown ethers and benzocryptands by macrocyclization M. S. Oshchepkov, V. P. Perevalov, 478 468 of podands at high concentrations of reactants L. G. Kuzmina, A. V. Anisimov, and O. A. Fedorova Unusual functionalization of the lower rim of thiacalix[4]arene: S. E. Solovieva, E. V. Popova, 486 476 competition of alkylation and transalkylation A. O. Omran, A. T. Gubaidullin, S. V. Kharlamov, Sh. K. Latypov, I. S. Antipin, and A. I. Konovalov

TiCl4—Et2AlClCatalyzed cycloaddition of 1,2dienes V. A. D´yakonov, G. N. Kadikova, 499 489 to 1,3,5cycloheptatriene L. M. Khalilov, and U. M. Dzhemilev Solidstate Suzuki reaction catalyzed by ferrocene N. S. Khrushcheva, L. A. Bulygina, 503 493 palladacycles without solvent and V. I. Sokolov Unusual direction in the alkylation of 1naphthol with camphene I. Yu. Chukicheva, O. A. Shumova, 506 496 in the presence of aluminum phenoxide and isopropoxide K. Yu. Suponitskii, and A. V. Kuchin Synthesis of N(2hydroxyphenyl)1,8naphthalimide and I. I. Ponomarev, M. Yu. Zharinova, 512 501 its derivatization at the hydroxy group Z. S. Klemenkova, P. V. Petrovskii, and Z. A. Starikova Synthesis of N,Ndisubstituted (Z)Omethylnicotinamide oximes A. M. Martsynkevich, 521 510 V. V. Zakharychev, and N. I. Sharanina 2011 Contents Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2633

Version Engl./Russ. 3(2Methylthiopyridin3yl)3oxopropionic esters A. A. Zubarev, V. K. Zav´yalova, 526 514 and A. M. Shestopalov Regioselective orthoformylation of hydroxysubstituted N. L. Zaichenko, L. S. Kol´tsova, 533 520 spironaphthooxazine I. M. Shcherbakova, O. Yu. Os´kina, V. N. Voznesenskii, I. R. Mardaleishvili, and A. I. Shienok Generation of oxodiazonium ions. 1. Synthesis of M. S. Klenov, M. O. Ratnikov, 536 523 [1,2,5]oxadiazolo[3,4c]cinnoline 5oxides A. M. Churakov, V. N. Solkan, Yu. A. Strelenko, and V. A. Tartakovsky Synthesis of Nunsubstituted 2arylpyrazolo[1,5a] T. A. Kuz´menko, L. N. Divaeva, 548 535 benzimidazoles from 1benzylideneamino2methyl and A. S. Morkovnik benzimidazole and the role of acylotropic and acylotropicprototropic isomerization On the features of reactivity of 8[(1E)2phenylethenyl] S. K. Moiseev, I. V. Shishkov, 557 544 substituted thebaine and codeinone derivatives and V. N. Kalinin New acid photogenerators based on thioxanthen9one V. V. Shelkovnikov, V. A. Loskutov, 561 548 sulfonium derivatives for detritylation in E. V. Vasil´ev, N. V. Shekleina, the oligonucleotide synthesis V. A. Ryabinin, and A. N. Sinyakov Dibromotyrosine derivatives from the ethanol extract E. A. Santalova, V. A. Denisenko, 570 557 of the marine sponge Aplysina sp.: structures, V. P. Glazunov, A. I. Kalinovskii, transformations, and origin S. D. Anastyuk, and V. A. Stonik

Brief Communications

Thermodynamic properties of titanium selenides with L. N. Zelenina, T. P. Chusova, 581 568 variable composition TiSe2—TiSe1.80 and A. N. Titov

Aromatization of a C3—C4 alkane mixture over Znpentasil A. L. Lapidus, A. M. Kozlov, 585 572 modified with tin and lead D. S. Khudyakov, and A. A. Dergachev RhCatalyzed asymmetric hydrogenation of (Z)ethyl S. E. Lyubimov, E. A. Rastorguev, 587 574 3acetamido2butenoate in supercritical carbon P. V. Petrovskii, dioxide: the effect of cosolvents and V. A. Davankov The rate of cyclization of 2´ and 4´substituted diphenyl N. A. Pelevin, Yu. D. Markovich, 590 577 amine2carboxylic acids in sulfuric acid as a function G. V. Nazarov, S. E. Galan, of the electronic properties of substituents T. N. Kudryavtseva, and M. I. Brylev Adamantyl derivatives of pyrogallol W. A. Sokolenko, N. M. Svirskaya, 593 580 N. I. Pavlenko, and A. I. Rubailo A specific intramolecular interaction in a bis(2thienyl) M. M. Krayushkin, L. G. Vorontsova, 595 582 maleimide derivative A. A. Shimkin, and Z. A. Starikova

Letters to the Editor

Dehydrochlorination of chloroform by NmethylN,Nbis N. F. Lazareva and I. M. Lazarev 598 585 (silatranylmethyl)amine 2634 Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2011 Contents

Version Engl./Russ. Issue 4, 2011

Gennadii Viktorovich Sakovich (on his eightieth birthday) xi viii

Reviews

Metal complexes with Nalkenylimidazoles: synthesis, structures, L. N. Parshina and B. A. Trofimov 601 589 and biological activity N(Silylmethyl)amines, amides, and amino acids: biological N. F. Lazareva 615 603 activity and prospects in drug synthesis Antiarrhythmic agents based on diterpenoid alkaloids M. S. Yunusov 633 620

Full Articles

7Ethyl2,3,5,6,8pentahydroxy1,4naphthoquinone (echino D. V. Berdyshev and V. P. Glazunov 639 625 chrome A): a DFT study of the mechanism of the antioxidant action. 4. Migration of protons and the Na+ cation in echinochrome A monosodium salts Electrochemical method in determination of antioxidative activity V. Yu. Tyurin, N. N. Meleshonkova, 647 633 using ferrocene derivatives as examples A. V. Dolganov, A. P. Glukhova, and E. R. Milaeva Colorimetric detection of immobilized horseradish peroxidase based М. М. Ulyashova, М. Yu. Rubtsova, 656 642 on the cooxidation of benzidine derivatives and 4chloro1naphthol and А. М. Egorov

Covalent binding of fullerene C60 to pharmacologically A. R. Tuktarov, L. L. Khuzina, 662 648 important compounds and U. M. Dzhemilev Protective properties of gold in the composition of nanoparticles A. P. Sadkov, S. A. Golovanova, 667 653 and Au—rutin complexes N. V. Lariontseva, and L. A. Levchenko Antimicrobial activity of silver—poly(1vinyl1,2,4triazole) G. F. Prozorova, S. A. Korzhova, 671 657 nanocomposites T. V. Kon´kova, A. S. Pozdnyakov, T. G. Ermakova, T. V. Fadeeva, S. A. Vereshchagina, and B. A. Trofimov Cefalosporin complexes with the methylene blue dye and their I. Yu. Ponedel´kina 676 662 use in the surgery of infectious endocarditis and N. G. Sibagatullin Inhibition of the procoagulant activity of blood platelets by vinyl K. V. Kudryavtsev, N. A. Podoplelova, 679 665 sulfonyl derivatives of pyrrolidine2carboxylic acid A. A. Novikova, M. A. Panteleev, D. V. Zabolotnev, and N. S. Zefirov Design of smallmolecule thrombin inhibitors based on K. V. Kudryavtsev, D. A. Shulga, 685 671 the cis5phenylproline scaffold V. I. Chupakhin, A. V. Churakov, N. G. Datsuk, D. V. Zabolotnev, and N. S. Zefirov Novel lupane triterpenoids containing allyl substituents in ring A: A. Yu. Spivak, E. R. Shakurova, 694 680 synthesis and in vitro study of antiinflammatory and D. A. Nedopekina, cytotoxic properties R. R. Khalitova, L. M. Khalilov, V. N. Odinokov, Yu. P. Bel´skii, A. N. Ivanova, N. V. Bel´skaya, M. G. Danilets, and A. A. Ligacheva 2011 Contents Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2635

Version Engl./Russ. A new approach to the synthesis of aliphatic triamines and diamino K. A. Kochetkov, A. N. Tavtorkin, 702 688 alcohols that are analogs of the antiTB drug ethambutol N. I. Vorozhtsov, L. A. Sviridova, A. M. Moroz, and I. R. Dorozhkova Modification of biologically active amides and amines with fluoro V. B. Sokolov, A. Yu. Aksinenko, 707 693 containing heterocycles. 5. Fluorocontaining heterocyclic T. A. Epishina, T. V. Goreva, derivatives of 2amino1,3,4thiadiazoles and I. V. Martynov Synthesis of N(phosphonomethyl)glycine derivatives and studies M. V. Shevchuk, L. A. Metelitsa, 712 698 of their immunotropic activity L. L. Charochkina, S. E. Mogilevich, E. B. Rusanov, A. E. Sorochinsky, V. P. Khilya, V. D. Romanenko, and V. P. Kukhar Synthesis of potential antitumor agents, dimeric and trimeric chlorins, D. V. Belykh, M. V. Mal´shakova, 719 704 from methylpheophorbide a Yu. A. Yudina, K. A. Zavadskaya, V. M. Khudyaev, and A. V. Kuchin Synthesis of the [2H,15N]labeled antiviral drug "triazavirine" T. S. Shestakova, 729 714 I. A. Khalymbadzha, S. L. Deev, O. S. El´tsov, V. L. Rusinov, Z. O. Shenkarev, A. S. Arseniev, and O. N. Chupakhin Synthesis of new fluorinecontaining pyrazolo[3,4b]pyridinones A. S. Golubev, G. S. Starostin, 733 718 as promising drug precursors K. S. Chunikhin, A. S. Peregudov, K. C. Rodygin, S. A. Rubtsova, P. A. Slepukhin, A. V. Kuchin, and N. D. Chkanikov Preliminary structural characterization, antiinflammatory and V. B. Krylov, A. A. Grachev, 746 731 anticoagulant activities of chondroitin sulfates from N. E. Ustyuzhanina, marine fish cartilage N. A. Ushakova, M. E. Preobrazhenskaya, N. I. Kozlova, M. N. Portsel, I. N. Konovalova, V. Yu. Novikov, H. Ch. Siebert, A. S. Shashkov, and N. E. Nifantiev Conjugates of hyaluronic and carboxy hyaluronic acids and their I. Yu. Ponedel´kina, E. S. Lukina, 754 739 in vitro biodegradability upon the action of testicular E. A. Khaibrakhmanova, hyaluronidase E. V. Sal´nikova, and V. N. Odinokov

Brief Communications

4Methoxy3methylgoniothalamin from marinederived fungi O. F. Smetanina, A. N. Yurchenko, 760 744 of the genus Penicillium A. I. Kalinovskii, M. A. Pushilin, N. N. Slinkina, E. A. Yurchenko, and Sh. Sh. Afiyatullov

Letters to the Editor

1(2Chloro1,1,1,3,3,3hexafluoroprop2yl)ferrocene as V. I. Dyachenko, A. S. Peregudov, 764 748 the first stable representative of chloromethylferrocenes I. V. Anan´ev, M. Yu. Antipin, Yu. S. Nekrasov, V. I. Sokolov, and S. M. Igumnov 2636 Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2011 Contents

Version Engl./Russ. A rearrangement in the reaction of 2bromomethyl1,3thiaselenole S. V. Amosova, M. V. Penzik, 766 750 with ethanol: synthesis of 2ethoxy2,3dihydro1,4thiaselenine V. A. Potapov, and A. I. Albanov Annulation of phenyl propargyl ether with selenium dichloride M. V. Musalov, V. A. Potapov, 767 751 and S. V. Amosova Reaction of selenium dichloride with trimethylpropargylsilane M. V. Musalov, V. A. Potapov, 769 753 and S. V. Amosova Synthesis of 1H1,5,7triazacyclopenta[c,d]phenalenes involving A. V. Aksenov, A. S. Lyakhovnenko, 771 755 electrophilic amination of 1Hperimidines with sodium azide and A. V. Andrienko in polyphosphoric acid Synthesis of quinolines involving electrophilic amination of arenes A. S. Lyakhovnenko, M. M. Kugutov, 773 757 with sodium azide in polyphosphoric acid and A. V. Aksenov Information 775 759 Issue 5, 2011

Valerii Nikolaevich Charushin (on his sixtieth birthday) xiii xi Kirill Mikhailovich Dyumaev (on his eightieth birthday) xv xiii Valerii Vasil´evich Rybin (on his seventieth birthday) xvii xiv Boris Yakovlevich Spivakov (on his seventieth birthday) xix xv

Full Articles

Modeling of NMR spectra and signal assignment using P. A. Belyakov and V. P. Ananikov 783 765 realtime DFT/GIAO calculations Extraction of lanthanide ions from acidic and strongly Yu. G. Elistratova, A. R. Mustafina, 790 772 acidic media by phosphine oxide derivatives using D. A. Tatarinov, V. F. Mironov, temperatureinduced phase separation V. A. Burilov, I. G. Tananaev, and A. I. Konovalov 3D Coordination polymers with vanadyl fragments E. S. Bazhina, M. E. Nikiforova, 797 779 and alkaline earth metal ions G. G. Aleksandrov, V. V. Minin, N. N. Efimov, A. A. Sidorov, V. M. Novotortsev, and I. L. Eremenko New potentially tridentate amidinate ligand V. Yu. Rad´kov, G. G. Skvortsov, 803 785 – {oMeOC6H4NC(Ph)N(SiMe3)} . Synthesis and G. K. Fukin, K. A. Lyssenko, molecular structures of amidinate complexes of lithium M. Yu. Antipin, [{oMeOC6H4NC(Ph)N(SiMe3)}Li]2 and yttrium and A. A. Trifonov [{oMeOC6H4NC(Ph)N(SiMe3)}YCl2(THF)2]2 Heterospin complexes based on cobalt semiquinolate E. Yu. Fursova, O. V. Kuznetsova, 809 791 with nitroxides E. V. Tretyakov, G. V. Romanenko, A. S. Bogomyakov, V. I. Ovcharenko, R. Z. Sagdeev, V. K. Cherkasov, M. P. Bubnov, and G. A. Abakumov Bis(1,1,1,3,5,5,5heptafluoro4iminopent2ene2aminato) S. V. Fokin, V. I. Ovcharenko, 816 798 copper(II) — a new metalcontaining matrix in G. V. Romanenko, E. V. Tretyakov, the design of heterospin systems A. S. Bogomyakov, L. V. Saloutina, T. I. Filyakova, V. I. Saloutin, V. N. Charushin, and O. N. Chupakhin 2011 Contents Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2637

Version Engl./Russ. Preorganization of diarylideneacetonyl crownophanes in I. G. Ovchinnikova, D. K. Nikulov, 824 805 single crystals to photochemical transformations E. V. Bartashevich, E. G. Matochkina, M. I. Kodess, P. A. Slepukhin, A. V. Druzhinin, O. V. Fedorova, G. L. Rusinov, and V. N. Charushin

Inclusion compounds of the copper(II) and zinc(II) complexes E. A. Kovalenko, D. A. Mainichev, 841 821 with cyclam in cucurbit[8]uril: synthesis and structure O. A. Gerasko, D. Yu. Naumov, and V. P. Fedin

Trinuclear zinc naphthoate complexes: synthesis and structure A. E. Goldberg, M. A. Kiskin, 849 829 A. A. Sidorov, and I. L. Eremenko A study of the reaction mechanism of 3nitro4Rfuroxans I. V. Ovchinnikov, Yu. A. Strelenko, 855 835 formation by nitrosation of dipotassium salts of N. A. Popov, A. O. Finogenov, 1hydroxyimino2,2dinitro1Rethanes and N. N. Makhova Synthesis of hybrid photochromes containing fulgimide and S. I. Luyksaar, I. V. Platonova, 861 841 salicylidenaniline fragments and study of their properties M. M. Krayushkin, V. A. Barachevskii, and S. P. Molchanov Synthesis of novel methanofullerenes spirocoupled with I. P. Romanova, 867 847 the indolinone fragment and prospects of their use G. R. Shaikhutdinova, in lightabsorbing layers of plastic solar cells G. G. Yusupova, A. V. Bogdanov, L. I. Musin, D. G. Yakhvarov, M. I. Valitov, I. R. Nizameev, V. F. Mironov, and O. G. Sinyashin Synthesis of the (2S,4S)stereoisomers of 4(indol1yl) and A. Yu. Vigorov, I. A. Nizova, 873 853 4arylamino derivatives of 5oxoproline, proline, and K. E. Shalunova, A. N. Grishakov, 2hydroxymethylpyrrolidine L. Sh. Sadretdinova, I. N. Ganebnykh, M. A. Ezhikova, M. I. Kodess, and V. P. Krasnov Synthesis of imidazolyl dithiocarbamates and their reactions O. S. El´tsov, V. S. Mokrushin, 882 862 with phenacyl bromides M. V. Smirnova, and M. Z. Shafikov Reactions of 2arylhydrazonoacetamidoximes with orthoesters N. P. Belskaya, A. V. Koksharov, 889 869 S. G. Lesogorova, P. A. Slepukhin, and V. A. Bakulev Oxidative cyclization of Nalkyl2arylhydrazonothioacetamides N. P. Belskaya, A. I. Bolgova, 896 876 M. L. Kondrat´eva, O. S. El´tsov, and V. A. Bakulev Regiospecific Oalkylation of 4polyfluoroalkyl1Hpyrimidin2ones O. G. Khudina, A. E. Ivanova, 901 881 Ya. V. Burgart, M. I. Kodess, and V. I. Saloutin Synthesis, crystal structures, and properties of 5(het)aryl E. V. Verbitskiy, M. V. Berezin, 906 886 3cyano1ethyl2(1H)pyrazinones P. A. Slepukhin, O. N. Zabelina, G. L. Rusinov, and V. N. Charushin Synthesis of isobornylphenolcontaining 3aryl1,2,4triazin5(4H)ones I. N. Egorov, O. N. Chupakhin, 914 893 M. V. Berezin, G. L. Rusinov, V. L. Rusinov, E. V. Buravlev, I. Yu. Chukicheva, and A. V. Kuchin 2638 Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2011 Contents

Version Engl./Russ.

Reactions of pyrazinium salts with phenols: from Нadducts E. V. Verbitskiy, Yu. A. Kvashnin, 919 898 Н to SN products and transformations into benzo[b]furans P. A. Slepukhin, A. V. Kuchin, G. L. Rusinov, O. N. Chupakhin, and V. N. Charushin Structure of diethyl (polyfluorobenzoyl)malonates and their D. N. Bazhin, E. V. Schegol´kov, 929 907 thermal intramolecular cyclization Yu. S. Kudyakova, Ya. V. Burgart, and V. I. Saloutin Benzimidazoles and related heterocycles. 11. A novel acidcatalyzed V. A. Mamedov, N. A. Zhukova, 933 911 rearrangement in the system 3benzoylquinoxalin2(1H)one— T. N. Beschastnova, aldehyde—ammonium acetate as a simple and efficient route and A. T. Gubaidullin to 2(imidazol4yl)benzimidazoles Synthesis of regioisomeric N and Oalkylated 3polyfluoroalkyl A. E. Ivanova, O. G. Khudina, 937 915 1,2dihydroquinoxalin2ones Ya. V. Burgart, and V. I. Saloutin Fluorinecontaining quinoline and quinoxaline styryl derivatives: E. V. Nosova, T. V. Trashakhova, 942 920 synthesis and photophysical properties V. S. Ustyugov, N. N. Mochul´skaya, M. S. Valova, G. N. Lipunova, and V. N. Charushin 2Arylpropionyl chlorides in kinetic resolution of racemic 3methyl E. N. Chulakov, D. A. Gruzdev, 948 926 2,3dihydro4H[1,4]benzoxazines G. L. Levit, L. Sh. Sadretdinova, V. P. Krasnov, and V. N. Charushin Structures of the racemate and (S)enantiomer of 7,8difluoro P. A. Slepukhin, D. A. Gruzdev, 955 932 3methyl2,3dihydro4H[1,4]benzoxazine E. N. Chulakov, G. L. Levit, V. P. Krasnov, and V. N. Charushin Regioselective reaction of orthopiperidinobenzaldehydes A. Yu. Platonova, E. V. Deeva, 961 937 with pyrazolone O. A. Zimovets, D. V. Shatunova, O. S. El´tsov, P. A. Slepukhin, T. V. Glukhareva, and Yu. Yu. Morzherin Unusual heterocyclization of chalcone podands with I. G. Ovchinnikova, M. S. Valova, 965 941 3amino1,2,4triazole E. G. Matochkina, M. I. Kodess, A. A. Tumashov, P. A. Slepukhin, O. V. Fedorova, G. L. Rusinov, and V. N. Charushin

HAdducts of 1alkyl1,4diazinium salts as the sources E. V. Verbitskiy, P. A. Slepukhin, 975 951 of biradicals in the synthesis of tetraazaphenanthrenes M. A. Ezhikova, M. I. Kodess, Yu. N. Shvachko, D. V. Starichenko, G. L. Rusinov, and V. N. Charushin Phosphorus pentachlorideinduced transformation of T. A. Kalinina, P. E. Prokhorova, 981 957 (1,2,3thiadiazol5yl)hydrazones of acetophenone T. V. Glukhareva, and Yu. Yu. Morzherin Reactions of 1,2,4,5tetrazines with Snucleophiles S. G. Tolshchina, R. I. Ishmetova, 985 961 N. K. Ignatenko, A. V. Korotina, I. N. Ganebnykh, V. A. Ol´shevskaya, V. N. Kalinin, and G. L. Rusinov Synthesis of macrobicyclic compounds containing azacrown M. V. Anokhin, A. D. Averin, 992 968 ether fragments and study of their complexation with A. K. Buryak, zinc and cadmium nitrates and I. P. Beletskaya 2011 Contents Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2639

Version Engl./Russ. A new synthesis of the 3,6branched hexasaccharide fragment D. A. Argunov, A. A. Karelin, 1004 980 of the cell wall mannan in Candida albicans, A. A. Grachev, Yu. E. Tsvetkov, corresponding to the antigenic factor 4 and N. E. Nifantiev

Brief Communications

Binuclear zinc naphthoate complex with 1,10phenanthroline: A. E. Goldberg, M. A. Kiskin, 1012 987 synthesis, structure, and photoluminescence properties S. A. Kozyukhin, A. A. Sidorov, and I. L. Eremenko Reactions of malonodithioamides with acetylenedicarboxylic esters K. L. Obydennov, M. F. Kosterina, 1016 991 E. L. Klimareva, V. A. Bakulev, and Yu. Yu. Morzherin Structuring of starlike multiarm polydimethylsiloxanes O. V. Novozhilov, N. G. Vasilenko, 1019 994 M. I. Buzin, M. A. Scherbina, S. N. Chvalun, and A. M. Muzafarov

Letters to the Editor

Synthesis of crownophane with the bicyclo[2.2.2]octane core I. G. Ovchinnikova, 1022 997 E. G. Matochkina, M. I. Kodess, P. A. Slepukhin, O. V. Fedorova, G. L. Rusinov, and V. N. Charushin Issue 6, 2011

Vladimir Borisovich Kazanskii (on his eightieth birthday) xv xii Institute of Problems of Chemical Physics of the Russian xvii xiii Academy of Sciences (55 years from the foundation)

Reviews

Structure and properties of nanostructured films based R. A. Andrievskii 1025 1001 on refractory compounds and G. V. Kalinnikov Detection and investigation of oscillations of the rate of radiation D. P. Kiryukhin 1032 1008 induced solidstate chain reactions at low temperatures

Full Articles

Magnetic exchange coupling in transition metal complexes with D. V. Korchagin, A. N. Utenyshev, 1040 1016 bidentate bridging ligands: a quantum chemical study K. V. Bozhenko, N. A. Sanina, and S. M. Aldoshin Electrocatalytic properties of the catalysts based on carbon E. V. Gerasimova, N. G. Bukun, 1045 1021 nanofibers with various platinum contents and Yu. A. Dobrovolsky Nano and heterostructures of magnetic semiconductors for spintronics A. I. Dmitriev, A. D. Talantsev, 1051 1027 S. V. Zaitsev, O. V. Koplak, and R. B. Morgunov Trifluoromethyl derivatives of cerium endohedral metallofullerenes I. E. Kareev, V. P. Bubnov, 1058 1034 and E. B. Yagubskii 2640 Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2011 Contents

Version Engl./Russ. Ionic complexes simultaneously containing fullerene anions and D. V. Konarev, L. V. Zorina, 1063 1038 coordination structures of metal phthalocyanines with I– S. S. Khasanov, and EtS– anions E. U. Khakimova, and R. N. Lyubovskaya The role of the medium in electrochemical functionalization A. G. Krivenko, N. S. Komarova, 1071 1046 and dispersion of carbon nanotubes A. G. Ryabenko, A. V. Naumkin, E. V. Stenina, L. N. Sviridova, and S. N. Sul´yanov Photochromic singlemolecule magnets based on oxocarboxylate L. A. Kushch, V. D. Sasnovskaya, 1078 1053 Mn12 clusters and mononitrosyl Ru complexes E. B. Yagubskii, A. I. Dmitriev, R. B. Morgunov, V. A. Emel´yanov, and T. Woike Platinum and palladiumcontaining carbon nanomaterials as N. A. Magdalinova, M. V. Klyuev, 1085 1060 catalysts for hydrogenation and hydrogenating amination T. G. Volkova, N. N. Vershinin, V. A. Bakaev, O. N. Efimov, and I. I. Korobov Synthesis, structures, and photochromic properties of N. I. Makarova, P. V. Levchenko, 1090 1065 3[(E)alk1enyl]4(1alkyl5methoxy2methyl V. V. Tkachev, E. N. Shepelenko, 1Hindol3yl)furan2,5diones A. V. Metelitsa, V. P. Rybalkin, L. L. Popova, V. A. Bren´, S. M. Aldoshin, and V. I. Minkin Structures of polymer electrolytes based on polyester diacrylate: A. A. Marinin, K. G. Khatmullina, 1096 1071 an NMR study V. I. Volkov, O. V. Yarmolenko, and V. A. Zabrodin Platinum electrocatalysts based on oxide supports for hydrogen L. A. Frolova and Yu. A. Dobrovolsky 1101 1076 and methanol fuel cells

On the state of СH4 molecule in the octahedral void of С60 fullerite Yu. M. Shul´ga, A. F. Shestakov, 1112 1087 V. M. Martynenko, S. A. Baskakov, N. Yu. Trifonov, E. M. Anokhin, and A. V. Maksimychev Femtosecond dynamics of photocyclization of 1[(4{5[4chloro S. M. Aldoshin, E. A. Yurieva, 1118 1093 methyl2,5dimethyl3thienyl]2oxo1,3dioxol4yl} N. A. Sanina, M. M. Krayushkin, 2,5dimethyl3thienyl)methyl]pyridinium chloride D. V. Tsyganov, F. E. Gostev, I. V. Shelaev, O. M. Sarkisov, and V. A. Nadtochenko The regularities of reversible chain reactions in the equilibrium state V. T. Varlamov 1128 1103 Thermal decomposition of cis2,4,6,8tetranitro1H,5H T. K. Goncharov, V. V. Dubikhin, 1138 1113 2,4,6,8tetraazabicyclo[3.3.0]octane G. M. Nazin, V. G. Prokudin, and Z. G. Aliev Effect of the solvent on the hydrolysis of the iron nitrosyl complex L. A. Syrtsova, N. A. Sanina, 1144 1119 {Fe2[S(CH2)2NH3]2(NO)4}SO4•2.5H2O: spectroscopic and B. L. Psikha, A. V. Kulikov, kinetic investigations of its monomer and dimer forms A. V. Chernyak, N. I. Shkondina, T. N. Rudneva, O. V. Shaposhnikova, A. I. Kotel´nikov, and S. M. Aldoshin Parametric domain of the stationary filtration combustion wave I. I. Amelin, E. A. Salgansky, 1150 1125 in the charge with a low carbon content N. N. Volkova, A. F. Zholudev, A. P. Alekseev, E. V. Polianczyk, and G. B. Manelis 2011 Contents Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2641

Version Engl./Russ. Kinetic regularities of ethylene oligomerization in the presence I. I. Khasbiullin, G. P. Belov, 1158 1133 III of the catalytic system Cr —AlR3—2,5dimethylpyrrole— and A. I. Vilms modifying agent On the possibility of the nitric oxide formation upon T. N. Bogatyrenko, Z. V. Kuropteva, 1162 1137 biotransformation of hydroxamic acids L. M. Baider, V. R. Bogatyrenko, B. S. Fedorov, and N. P. Konovalova Cytostatic action of triazole and oxazolidinone derivatives V. A. Derevkova, I. V. Balalaeva, 1166 1141 R. I. Papina, A. G. Korepin, N. M. Glushakova, and A. A. Terent´ev Antioxidant properties of watersoluble amino acid derivatives R. A. Kotel´nikova, I. I. Faingol´d, 1172 1146 of fullerenes and their role in the inhibition of herpes D. A. Poletaeva, virus infection D. V. Mishchenko, V. S. Romanova, V. N. Shtol´ko, G. N. Bogdanov, A. Yu. Rybkin, E. S. Frog, A. V. Smolina, A. A. Kushch, N. E. Fedorova, and A. I. Kotel´nikov A spectroscopic study of the reaction of the iron thiosulfate E. A. Saratovskikh, B. L. Psikha, 1177 1151 nitrosyl complex with adenosine triphosphoric acid and N. A. Sanina New method for the synthesis of metal complexes based on PtIV B. S. Fedorov, M. A. Fadeev, 1181 1155 and substituted nicotinamides and isonicotinamides and G. I. Kozub, A. N. Chekhlov, investigation of their antimetastatic activity N. P. Konovalova, T. E. Sashenkova, E. N. Berseneva, O. V. Dobrokhotova, and L. V. Tatyanenko Hydrates and ammonium salts of 4nitrobenzenesulfonic acid: P. Yu. Barzilovich, K. A. Lyssenko, 1185 1159 supramolecular organization and its relation to proton M. Yu. Antipin, conductivity and S. M. Aldoshin Dye Jaggregate—semiconductor nanocrystal hybrid nanostructures L. M. Nikolenko, S. B. Brichkin, 1196 1170 in reverse micelles: an experimental study and V. F. Razumov Can reverse micelle shells limit nanoparticle growth? S. A. Tovstun and V. F. Razumov 1203 1177 Phenazineoxonium chloranilatomanganate and chloranilatoferrate: G. V. Shilov, Z. K. Nikitina, 1209 1183 synthesis, structure, magnetic properties, and Mössbauer spectra N. S. Ovanesyan, S. M. Aldoshin, and V. D. Makhaev

Brief Communications

A new method for the synthesis of 2,4diazido6trinitro A. V. Shastin, T. I. Godovikova, 1220 1194 methyl1,3,5triazine and B. L. Korsunskii Issue 7, 2011

Reviews

Structure and properties of iron nitrosyl complexes with N. A. Sanina and S. M. Aldoshin 1223 1199 functionalized sulfurcontaining ligands Chemical methods of dispergation of metallic phases B. P. Tarasov, E. E. Fokina, 1252 1228 and V. N. Fokin 2642 Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2011 Contents

Version Engl./Russ. Synthesis, properties, and examples of the use of carbon B. P. Tarasov, V. E. Muradyan, 1261 1237 nanomaterials and A. A. Volodin Aromatic polyazides and highspin nitrenes S. V. Chapyshev 1274 1250 Nonlinear traveling wave mechanisms of fast solidphase V. V. Barelko, D. P. Kiryukhin, 1286 1262 cryochemical reactions I. M. Barkalov, G. A. Kichigina, and A. Pumir Structuralfunctional modeling of nonheme oxygenases A. A. Shteinman 1290 1267 Filtration combustion of solid fuel in countercurrent G. B. Manelis, S. V. Glazov, 1301 1278 reactors D. B. Lempert, and E. A. Salgansky Structural and dynamic aspects of electron transfer in proteins — A. I. Kotel´nikov, E. S. Medvedev, 1318 1295 highly organized natural nanostructures and N. S. Goryachev Synthesis, reactions with DNA, and antitumor activity of V. D. Sen´, A. A. Terent´ev, 1342 1319 platinum complexes with aminonitroxyl radicals and N. P. Konovalova

Full Articles

Redox potentials of iron—nitrosyl complexes: DFT calculations N. S. Emel´yanova, A. F. Shestakov, 1352 1329 and N. A. Sanina Quasitwodimensional organic metals with differently oriented E. I. Zhilyaeva, O. A. Bogdanova, 1357 1334 conducting layers A. M. Flakina, G. V. Shilov, R. B. Lyubovskii, and R. N. Lyubovskaya Features of interlayer electron transport in quasitwodimensional R. B. Lyubovskii, S. I. Pesotskii, 1363 1340 organic metal (ET)4HgBr4(C6H4Cl2) O. A. Bogdanova, E. I. Zhilyaeva, A. M. Flakina, and R. N. Lyubovskaya Structure and properties of 3,6´dimethyl2,3dihydrospiro S. M. Aldoshin, E. L. Mukhanov, 1366 1344 [naphtho[1,3]oxazine2,2´[2H]chromen]4ones B. S. Lukyanov, S. O. Bezuglyi, M. B. Lukyanova, A. N. Utenyshev, V. V. Tkachev, and V. I. Minkin Synthesis and molecular structure of 7H12oxa3,7diaza S. M. Aldoshin, Yu. A. Sayapin, 1372 1350 pleiadenesubstituted 1,3tropolones Zyong Ngia Bang, I. O. Bondareva, V. N. Komissarov, I. V. Dorogan, V. V. Tkachev, G. V. Shilov, and V. I. Minkin New photochromic 1,1,3trimethylspiro[benzo[e]indoline S. M. Aldoshin, V. V. Tkachev, 1380 1358 2,3´[3H]pyrano[3,2f]quinoline] K. N. Khalanskii, B. S. Lukyanov, V. I. Minkin, A. N. Utenyshev, Yu. S. Alekseenko, and S. O. Bezuglyi New 2(benzothiazol2yl)1,3tropolones derived from I. O. Bondareva, Yu. A. Sayapin, 1384 1362 3,4,5,6tetrachloro1,2benzoquinone V. N. Komissarov, V. V. Tkachev, G. V. Shilov, S. M. Aldoshin, and V. I. Minkin Thermally induced paramagnetism of spiropyran salts F. B. Mushenok, R. B. Morgunov, 1387 1365 N. A. Sanina, S. M. Aldoshin, and E. A. Yurieva 2011 Contents Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2643

Version Engl./Russ. New conformer of 2,4,6,8,10,12hexanitro2,4,6,8,10,12hexaaz S. M. Aldoshin, Z. G. Aliev, 1394 1372 isowurtzitane (CL20). Crystal and molecular structures of T. K. Goncharov, the CL20 solvate with glyceryl triacetate D. V. Korchagin, Yu. M. Milekhin, and N. I. Shishov

1Benzyl3,3,5´,6´tetramethylspiro[indoline2,2´[2H]pyra E. A. Yurieva, S. M. Aldoshin, 1401 1379 no[3,2b]pyridinium] iodide, its hydrate, and a neutral L. A. Nikonova, G. V. Shilov, precursor of the salts: synthesis, crystal structure, and V. A. Nadtochenko photochromic transformations in solutions and in crystals

Structure and photochromic properties of the crystalline E. A. Yurieva, V. V. Tkachev, 1409 1386 1,3dimethyl2(3phenylnorbornadienyl)benz S. M. Aldoshin, imidazolium tetrafluoroborate V. A. Chernoivanov, V. A. Bren´, and V. I. Minkin

Features of the initiated oxidation mechanism of nheptadecane T. A. Bazanov, B. L. Psikha, 1414 1391 at low concentrations of oxygen and V. V. Kharitonov

Hydroxyl mechanism of the antimalarial effect of artemisinin E. T. Denisov and T. G. Denisova 1421 1398 and its analogs

Kinetics of the  structural reorganization in 1,3,5,7tetranitro V. V. Zakharov and B. L. Korsunskii 1436 1413 octahydro1,3,5,7tetrazocine

Models for unimolecular reactions in the solid phase and stability G. B. Manelis, G. M. Nazin, 1440 1417 prediction of energetic compounds in the condensed state and V. G. Prokudin

Isothermal waves of hydrogen oxidation A. N. Ivanova and Z. S. Andrianova 1448 1425

Effect of the nature of an organoaluminum activator on catalytic N. M. Bravaya, E. V. Mukhina, 1452 1429 properties of phenoxyimine zirconium complexes in homo A. N. Panin, E. E. Faingol´d, and copolymerization reactions of ethylene V. D. Makhaev, L. A. Petrova, S. Ch. Gagieva, V. A. Tuskaev, and B. M. Bulychev

Effect of trimethylaluminum on the formation of active sites of N. M. Bravaya, E. E. Faingol´d, 1461 1438 the catalytic system bis[N(3,5ditertbutylsalicylidene) O. N. Babkina, L. A. Petrova, 2,3,5,6tetrafluoroanilinato]titanium(IV) dichloride— V. D. Makhaev, S. Ch. Gagieva, MAO and catalytic isomerization of hex1ene V. A. Tuskaev, and B. M. Bulychev

Synthesis and study of photochromic properties of copolymers V. P. Grachev, G. M. Bakova, 1469 1446 based on functionalized chromenes L. I. Makhonina, E. A. Yurieva, S. M. Aldoshin, A. M. Gorelik, and V. A. Barachevskii

Reactivity of metalcontaining monomers. 70. Preparation and A. D. Pomogailo, 1476 1453 magnetic properties of metalcontaining nanocomposites G. I. Dzhardimalieva, A. S. Rozenberg, V. A. Shershnev, and M. Leonowicz

Cytotoxic properties of the nitrosyl iron complex with phenylthiyl T. S. Stupina, I. I. Parkhomenko, 1488 1464 I. V. Balalaeva, G. V. Kostyuk, N. A. Sanina, and A. A. Terent´ev Synthesis of photoactive bichromophoric dyads containing T. N. Gavrishova, V. M. Li, 1495 1470 2styrylquinoline and 2naphthol moieties K. F. Sadykova, and M. F. Budyka 2644 Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2011 Contents

Version Engl./Russ. Topological structure and molecular mobility of linear and T. P. Kulagina, S. V. Kurmaz, 1500 1475 branched poly(meth)acrylates studied by NMR relaxation V. P. Grachev, and V. P. Tarasov

Brief Communications

Polymerization of [60]fullerene activated with butyllithium E. G. Atovmyan, A. A. Grishchuk, 1505 1480 and T. N. Fedotova

Information

Application of Grid technology in computational chemistry V. M. Volokhov, D. A. Varlamov, 1508 1483 A. V. Pivushkov, and A. V. Volokhov Issue 8, 2011

Nikolai Pavlovich Aleshin (on his seventieth birthday) xv xiii Valerii Pavlovich Meshalkin (on his seventieth birthday) xvii xv

Full Articles

Carbon and silicon triangulenes: searching for molecular magnets O. A. Gapurenko, A. G. Starikov, 1517 1493 R. M. Minyaev, and V. I. Minkin Stability and properties of oligomeric organoboron structures with V. E. Avakyan, R. M. Minyaev, 1525 1501 sixcoordinate carbon atoms at centers of hydrocarbon frameworks and V. I. Minkin Quantum chemical simulation of silicon tetrachloride hydrogenation A. V. Vorotyntsev, S. V. Zelentsov, 1531 1507 and V. M. Vorotyntsev Influence of hydration on the optical properties of 2,2difluoro E. V. Fedorenko, I. B. L´vov, 1537 1513 4methylnaphtho[1,2e]1,3,2dioxaborine. Quantum V. I. Vovna, D. Kh. Shlyk, chemical modeling and experimental study and A. G. Mirochnik Quantum chemical study of the charged gold atom influence D. F. Mukhamedzyanova, 1545 1521 on the mechanism of allylbenzene double bond migration D. А. Pichugina, М. S. Askerka, А. F. Shestakov, and N. Е. Kuz´menko Modeling of the molecular and electronic structures of some E. G. Gal´pern, A. R. Sabirov, 1556 1532 mono and biosmium complexes of fullerene C60 Yu. N. Novikov, and I. V. Stankevich Optimization of the solution composition for laserinduced V. A. Kochemirovsky, S. V. Safonov, 1564 1540 chemical liquid phase deposition of copper I. I. Tumkin, Yu. S. Tver´yanovich, I. A. Balova, and L. G. Menchikov Zinc sulfide nanoparticles: a mechanism of formation in aqueous T. N. Shcherba, К. V. Lupandina, 1571 1547 solutions and optical properties M. P. Zhilenko, G. P. Muravieva, H. V. Ehrlich, and G. V. Lisichkin Surface complexation onto nanosized lanthanum fluoride A. V. Safronikhin, H. V. Ehrlich, 1576 1552 T. N. Shcherba, and G. V. Lisichkin 2011 Contents Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2645

Version Engl./Russ. Metallopolymer nanocomposites based on platinum nanoparticles N. A. Yashtulov, A. N. Bol´shakova, 1581 1557 for chemical fuel cells A. A. Revina, and V. R. Flid Reduction of the groups C=O and C=N with neodymium and M. E. Burin, A. A. Logunov, 1586 1562 dysprosium diiodide hydrides N. O. Druzhkov, G. K. Fukin, and M. N. Bochkarev

Neodymium(III) and dysprosium(III) naphthalene hydride complexes M. E. Burin, A. A. Logunov, 1591 1566 V. I. Faerman, and M. N. Bochkarev

The complex Eu(phen)L3•5CH2Cl2 (HL is 1,3bis(1,3dimethyl I. V. Taydakov, B. E. Zaitsev, 1595 1570 1Hpyrazol4yl)propane1,3dione): synthesis, crystal S. S. Krasnosel´skiy, structure, and luminescent properties Z. A. Starikova, and R. S. Borisov Electrochemical investigation of complexation of polymer ligands T. V. Magdesieva, O. M. Nikitin, 1601 1576 containing 2,2´biquinolyl fragments with NiII ions in solution S. M. Masoud, A. V. Yakimansky, M. Ya. Goikhman, and I. V. Podeshvo

2– – Boron cluster anions B10H10 and B10H11 in complexation A. E. Dziova, V. V. Avdeeva, 1608 1583 reactions of copper(I). Positional isomers of the complex I. N. Polyakova, L. V. Goeva, [Cu2(9Nphen)4B10H10] E. A. Malinina, and N. T. Kuznetsov New biionic transition metal complexes based on the salen ligands: P. M. Bolotov, V. N. Khrustalev, 1612 1587 synthesis and application as synthons in the preparation and V. I. Maleev of chiral homo and heterobimetallic systems Biscatecholate complexes of the IV group elements in the radical L. B. Vaganova, A. V. Maleeva, 1620 1594 polymerization of styrene: ESR studies A. V. Piskunov, and D. F. Grishin

The Cp2ZrCl2catalyzed cycloalumination of functionally I. R. Ramazanov, R. N. Kadikova, 1628 1602 substituted olefins with triethylaluminum and U. M. Dzhemilev

Synthesis and transformations of metallacycles. 38. The Cp2ZrCl2 V. A. D´yakonov, R. A. Tuktarova, 1633 1607 catalyzed cyclometallation of ,diynes upon the action and U. M. Dzhemilev of RMgR´ or RnAlCl3–n Polyvinyl and polyphenylsilsesquioxanes and their films: N. P. Shapkin, Yu. N. Kul´chin, 1640 1614 an investigation by Xray diffractometry, positron V. I. Razov, S. S. Voznesenskii, diagnostics, and 29Si NMR spectroscopy V. V. Bazhenov, M. V. Tutov, N. N. Stavnistyi, V. G. Kuryavyi, and A. B. Slobodyuk Synthesis of bimetallic cagelike metalloorganosiloxanes B. G. Zavin, N. V. Sergienko, 1647 1621 from polymeric metallosiloxanes N. V. Cherkun, A. N. Bilyachenko, O. M. Starikova, A. A. Korlyukov, M. S. Dronova, M. M. Levitskii, and G. I. Timofeeva Phenoxazine polymers: synthesis and structure S. Zh. Ozkan, G. P. Karpacheva, 1651 1625 and G. N. Bondarenko Effect of different types of radiation on the composition A. V. Naumkin, I. O. Volkov, 1657 1631 of poly(phosphazene) surface A. A. Lapchenko, A. S. Lapchenko, and D. R. Tur 2646 Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2011 Contents

Version Engl./Russ. Synthesis and structures of the CH acid salts obtained in Yu. G. Gololobov, S. V. Barabanov, 1663 1637 the reactions of malonic acid esters and malononitriles A. S. Peregudov, P. V. Petrovskii, with 2,4,6trinitrohalobenzenes in the presence Z. A. Starikova, V. N. Khrustalev, of triethylamine and I. A. Garbuzova Nucleophilic substitution of the acetoxy group in 3methyl L. Labanauskas, R. Mazeikaite, 1672 1646 benzoylaminomethyl acetate R. Striela, O. Gedrimaite, G. Urbelis, and A. Zilinskas Generation of 1aryl3methoxycarbonylnitrilimines and Yu. V. Tomilov, D. N. Platonov, 1677 1651 their reactions with unsaturated hydrocarbons G. P. Okonnishnikova, and O. M. Nefedov Reactions of 4phenyl1,2,4triazoline3,5dione with 2pyrazolines R. A. Novikov, V. A. Korolev, 1685 1660 and Yu. V. Tomilov Synthesis and some properties of Nunsubstituted pyrrolo[2,1c] G. V. Mokrov, A. M. Likhosherstov, 1694 1669 1,3diazacycloalkano[1,2a]pyrazinones V. P. Lezina, T. A. Gudasheva, I. S. Bushmarinov, and M. Yu. Antipin

NitroalkylONNazoxyfurazanes and some of their derivatives O. A. Luk´yanov, G. V. Pokhvisneva, 1703 1678 T. V. Ternikova, N. I. Shlykova, and M. E. Shagaeva Synthesis of 3nitramino4(1H1,2,3triazol1yl) V. Yu. Rozhkov, L. V. Batog, 1712 1687 1,2,5oxadiazoles and their salts and M. I. Struchkova Reduction of 3carbonylsubstituted 5,6dicyanobenzofurans Zh. V. Chirkova, S. I. Filimonov, 1719 1693 with sodium borohydride I. G. Abramov, S. I. Firgang, and G. A. Stashina Thermal transformations of 2Hbenzimidazole 1,3dioxides V. A. Samsonov, 1723 1697 I. Yu. Bagryanskaya, Yu. V. Gatilov, and V. A. Savel´ev A new polycyclic system containing the 1,4benzodiazepine L. Yu. Ukhin, K. Yu. Suponitskii, 1729 1703 and isoindolinone fragments: synthesis and structure E. N. Shepelenko, L. V. Belousova, Zh. I. Orlova, and G. S. Borodkin Design of crystal packings of styrylheterocycles and [2+2] photo L. G. Kuz´mina, A. I. Vedernikov, 1734 1708 cycloaddition reactions in their single crystals. 7. Crystal S. K. Sazonov, N. A. Lobova, structures of 4styrylpyridine hydroperchlorates and solidstate A. V. Churakov, [2+2] autophotocycloaddition reactions of these compounds E. Kh. Lermontova, J. A. K. Howard, M. V. Alfimov, and S. P. Gromov

Brief Communications

Cagelike manganesephenylsiloxane with an unusual structure A. N. Bilyachenko, M. S. Dronova, 1762 1735 A. A. Korlyukov, M. M. Levitsky, M. Yu. Antipin, and B. G. Zavin Volume change on the formation of the complex EDTA—Mg2+ V. D. Kiselev, E. A. Kashaeva, 1766 1739 in water at 25 C I. I. Shakirova, and A. I. Konovalov Dialkyl (1ethoxycarbonyl2,2,2trifluoro1phenylsulfonyl A. Yu. Aksinenko, V. B. Sokolov, 1769 1741 aminoethyl)phosphonates T. V. Goreva, and G. F. Makhaeva 2011 Contents Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2647

Version Engl./Russ.

Dehydration of nitro alcohols catalyzed by Bu2SnO V. V. Veselovsky and A. V. Lozanova 1772 1744 Alkylation of bromoarenes with 4methylbicyclo V. V. Mezhnev and R. Kh. Geivandov 1774 1746 [2.2.2]octan1ol and 8methyltricyclo [4.4.0.03,8]decan1ol in methanesulfonic acid New rearrangement in the adamantylation reaction W. A. Sokolenko, N. M. Svirskaya, 1776 1748 of 4iodophenol and 4iodoanisole and A. I. Rubailo Synthesis of polyfluorochalcone acryloyl derivatives K. S. Shmuilovich, N. A. Orlova, 1778 1750 and V. V. Shelkovnikov Unusual ozonolysis pattern for 28oxo2,3indoloallobetulin O. B. Kazakova, E. F. Khusnutdinova, 1781 1753 A. N. Lobov, T. I. Zvereva, Yu. V. Legostaeva, G. A. Tolstikov, and V. N. Khrustalev

Letters to the Editor

Acid catalysis in the oxidative nucleophilic alkoxylation I. V. Borovlev, O. P. Demidov, 1784 1755 of 1,3,7triazapyrenes and N. A. Saigakova Information 1786 1757 Issue 9, 2011

Nikolai Timofeevich Kuznetsov (on his eightieth birthday) xi viii Oleg Aleksandrovich Bannykh (on his eightieth birthday) xiii ix

Full Articles

Theoretical analysis of hydrogen atom abstraction reactions A. A. Kunitsa, A. F. Shestakov, 1791 1761 by radicals within the framework of generalized and I. P. Kim Polanyi—Semenov relationship taking into account the formation of pre and postreactive complexes Simulation of gas detonation in a constantcrosssection channel S. V. Kulikov and O. N. Ternovaya 1797 1767 initiated by instantaneous heating at its closed end for an O+O3+He mixture Lowtemperature wave conversion of energetic compounds Yu. M. Mikhailov and V. V. Aleshin 1802 1772 in filled condensed systems Standard enthalpies of formation of some Nspiranes A. G. Korepin, A. I. Kazakov, 1810 1780 N. A. Plishkin, O. G. Ivanova, L. S. Kurochkina, V. A. Garanin, V. P. Kosilko, and D. A. Nesterenko Adsorption of isomeric aryl and diadamantane molecules on S. N. Yashkin, D. A. Svetlov, 1814 1784 the surface of graphitized thermal carbon black and V. S. Sarkisova Effect of the acidic treatment on the adsorption and structural L. I. Bel´chinskaya, O. V. Voishcheva, 1820 1789 properties of the natural mineral sorbent M45C20 G. A. Petukhova, Lu Thi Ien, V. Yu. Khokhlov, and V. F. Selemenev 2648 Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2011 Contents

Version Engl./Russ.

Anionic composition of precursors of the Co/Al2O3 catalysts I. I. Simentsova, A. A. Khassin, 1827 1796 for the Fischer—Tropsch synthesis G. A. Filonenko, G. K. Chermashentseva, O. A. Bulavchenko, S. V. Cherepanova, and T. M. Yurieva Nature of active sites in the cobalt—zirconium oxide catalyst D. A. Grigoryev and M. N. Mikhailov 1835 1804 Ammonia synthesis from dinitrogen and dihydrogen over S. M. Yunusov, E. S. Kalyuzhnaya, 1842 1811 the catalysts based on supported mononuclear B. L. Moroz, A. S. Ivanova, potassium carbonyl ruthenate. Promoting effect and V. B. Shur of alkyllithium compounds Hydrogenation of nanostructured alloys and composites P. V. Fursikov, D. N. Borisov, 1848 1816 based on magnesium and B. P. Tarasov

Effect of protic agents on the catalytic activity of supported K. A. Alferov, O. M. Chukanova, 1858 1825 palladium catalysts in the copolymerization of ethylene and G. P. Belov with carbon monoxide

Studies on the effect of the stabilizer activity on the structure A. V. Vinogradov, A. V. Agafonov, 1862 1829 and properties of titaniabased hybrid films and V. V. Vinogradov

Reactivity of metalcontaining monomers. 71. Synthesis of S. M. Aldoshin, G. I. Dzhardimalieva, 1871 1837 nanosized quasicrystals and related metallopolymer A. D. Pomogailo, composites and Yu. A. Abuzin

Reactions of methylaluminoxane and trimethylaluminum with I. V. Sedov, P. E. Matkovskii, 1880 1847 zirconium and titanium tetracyclopentadienyl derivatives L. N. Russiyan, E. I. Knerel´man, and I. G. Shunina

First example of the interaction of fullerene C60 with hydrazoic acid A. R. Akhmetov, A. R. Tuktarov, 1885 1852 U. M. Dzhemilev, I. R. Yarullin, and L. A. Gabidullina

Polyadducts of fullerene C60 with tertbutyl groups E. A. Rychagova, L. V. Kalakutskaya, 1888 1855 S. N. Titova, G. A. Domrachev, and S. Yu. Ketkov

Synthesis and photochromic properties of new nonsymmetric N. I. Makarova, P. V. Levchenko, 1899 1866 dihetarylethenes — indole and thiophene derivatives E. N. Shepelenko, A. V. Metelitsa, V. S. Kozyrev, V. P. Rybalkin, V. A. Bren´, and V. I. Minkin

Structure and condensation reactions of 2,3di N. A. Kondratova, O. N. Kazheva, 1906 1873 hydrofuro[3,2c]coumarin3one G. G. Aleksandrov, A. N. Chekhlov, O. A. D´yachenko, and V. F. Traven

Spiropyrans and spirooxazines. 7. Novel spirobipyrans and E. V. Solov´eva, S. O. Bezuglyi, 1917 1884 their cationic derivatives N. A. Voloshin, A. V. Metelitsa, and V. I. Minkin

Spiropyrans and spirooxazines. 8. 5´(1,3Benzothiazol2yl) N. A. Voloshin, A. V. Chernyshev, 1921 1888 substituted spiro[indoline2,3´naphthopyrans]: synthesis A. V. Metelitsa, E. B. Gaeva, and spectral and photochromic properties and V. I. Minkin 2011 Contents Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2649

Version Engl./Russ. Photostimulated synchronous chlorination of polymers at low S. I. Kuzina, A. A. Kozlovskii, 1927 1894 temperatures and A. I. Mikhailov

Synthesis and physicochemical properties of polyurethane block Yu. M. Mikhailov, L. V. Ganina, 1933 1900 copolymers and their compositions with plasticizers V. V. Tereshatov, E R. Badamshina, V. S. Smirnov, Yu. B. Kalmykov, and Yu. M. Lotmentsev

New polynitrogen hyperbranched polymers G. V. Malkov, A. V. Shastin, 1940 1907 Ya. I. Estrin, E. R. Badamshina, and Yu. M. Mikhailov

Synergistic antitumor effect of cisplatin and the platinum(IV) S. A. Goncharova, T. A. Raevskaya, 1944 1911 nitroxyl complex BC118 and the development of T. N. Yakushchenko, resistance to their combined action S. V. Blokhina, N. P. Konovalova, and V. D. Sen´ tertButylthiacalix[4]arene monolayers as a biomimetic N. B. Mel´nikova, E. N. Kochetkov, 1948 1915 model for the oxidation of antioxidants with S. E. Solov´eva, E. V. Popova, cytochrome с I. S. Antipin, A. E. Bol´shakova, O. E. Zhil´tsova, and A. I. Konovalov

Brief Communications

Reactions of trialkyl(aryl)phosphoniumsubstituted acetals I. R. Knyazeva, A. R. Burilov, 1956 1922 with resorcinol and its derivatives and M. A. Pudovik Synthesis, crystal structure, and antitumor activity of B. S. Fedorov, M. A. Fadeev, 1959 1925 the cadmium dichloride complex with semicarbazide A. N. Utenyshev, G. V. Shilov, N. P. Konovalova, L. V. Tatyanenko, T. E. Sashenkova, S. V. Blokhina, and E. N. Berseneva To the memory of Leon Vladimirovich Backinowsky 1963 1929

Issue 10, 2011

Valerii Grigor´evich Kulichikhin (on his seventieth birthday) xiii ix Yurii Dmitrievich Tret´yakov (on his eightieth birthday) xv xi

Full Articles

Fragmentation of valine and proline in resonant free electron M. V. Muftakhov 1965 1931 capture reactions and P. V. Shchukin An XPS and STM study of the size effect in NO adsorption A. V. Bukhtiyarov, R. I. Kvon, 1977 1943 on gold nanoparticles A. V. Nartova, and V. I. Bukhtiyarov 2650 Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2011 Contents

Version Engl./Russ. Catalase activity of coarsegrained and nanosized oxide tungsten S. V. Vakarin, A. A. Melyaeva, 1985 1951 bronzes obtained by electrolysis of molten salts O. L. Semerikova, V. S. Kondratyuk, A. A. Pankratov, S. V. Plaksin, N. M. Porotnikova, Yu. P. Zaikov, L. A. Petrov, Yu. V. Mikushina, A. B. Shishmakov, and O. N. Chupakhin 1Arylideneamino2,2,2trichloroethanols as synthetic equivalents N. A. Lozinskaya, S. E. Sosonyuk, 1989 1955 of arylideneimines in the reaction with cyclopropenone Yu. N. Firsova, derivatives M. V. Proskurnina, and N. S. Zefirov Triethylamineassisted reaction between 2,4dinitrofluorobenzene I. R. Golding, Z. A. Starikova, 1995 1960 and malononitrile N. G. Senchenya, P. V. Petrovskii, I. A. Garbuzova, and Yu. G. Gololobov Synthesis of novel phosphoruscontaining sterically hindered phenols T. R. Shaekhov, E. M. Gibadullina, 1999 1964 by the reaction of diphenyl (3,5ditertbutyl4oxocyclohexa Yu. K. Voronina, V. V. Syakaev, 2,5dienylidene)methylphosphonate with phenols D. R. Sharafutdinova, A. R. Burilov, and M. A. Pudovik Synthesis of hydrophilic and lipophilic 4arylcoumarin phosphates A. N. Selikhov, Y. B. Malysheva, 2003 1968 A. V. Nyuchev, N. S. Sitnikov, E. A. Sharonova, A. S. Shavyrin, S. Combes, and A. Yu. Fedorov Optically active diastereomers of Nmethyl1´(–)myrtenyl N. V. Abramova, K. K. Babievskii, 2010 1974 pyrrolidino[3´,4´:1,9](C60Jh)[5,6]fullerenes: S. M. Peregudova, synthesis, electrochemical and chiroptical properties A. S. Peregudov, and V. I. Sokolov

Synthesis and properties of crossconjugated ,´bisdimethylamino Zh. A. Krasnaya, E. O. Tret´yakova, 2014 1978 ketones and dinitriles with Nacetyl and Nbenzylpiperidine cycles V. V. Kachala, and S. G. Zlotin Acidcatalyzed polyfluoroarylation of arenes with polyfluorinated mono V. N. Kovtonyuk and L. S. Kobrina 2021 1984 and tris(phenoxy)1oxaspiro[2.5]octa4,7dienes Synthesis of quinolizin2one and pyrido[1,2a]azepin2one I. V. Kravtsov, S. V. Baranin, 2027 1990 derivatives from difluoroboron complexes of aroylacetones P. A. Belyakov, and Omethyllactims and V. A. Dorokhov Oxidation of 1amino4,5bis(dimethylamino)naphthalene as a route M. P. Vlasenko, V. A. Ozeryanskii, 2030 1993 to the double "proton sponges" based on dibenzo[a,h]phenazine and A. F. Pozharskii and 1,1´azonaphthalene Generation of oxodiazonium ions. 2. Synthesis of benzotetrazine M. S. Klenov, V. P. Zelenov, 2040 2003 1,3dioxides from 2(tertbutylNNOazoxy)Nnitroanilines A. M. Churakov, Yu. A. Strelenko, and V. A. Tartakovsky Generation of oxodiazonium ions. 3. Synthesis of [1,2,5]oxadiazo V. P. Zelenov, A. A. Voronin, 2046 2009 lo[3,4c]cinnoline1,5dioxides A. M. Churakov, M. S. Klenov, Yu. A. Strelenko, and V. A. Tartakovsky Generation of oxodiazonium ions. 4. Nitramine Oalkyl derivatives M. S. Klenov, A. M. Churakov, 2051 2014 in the synthesis of benzotetrazine1,3dioxides Yu. A. Strelenko, and V. A. Tartakovsky 2011 Contents Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2651

Version Engl./Russ. Cycloaddition of di(2pyridyl) diselenide to styrene activated with A. V. Borisov, Zh. V. Matsulevich, 2057 2020 antimony pentachloride V. K. Osmanov, G. N. Borisova, G. Z. Mammadova, A. M. Maharramov, and V. N. Khrustalev Diastereomeric P,Nbidentate amidophosphites based on (S,S) K. N. Gavrilov, I. V. Chuchelkin, 2063 2026 and (R,R)hydrobenzoin as ligands in the Pdcatalyzed S. V. Zheglov, N. N. Groshkin, asymmetric allylation I. M. Novikov, E. A. Rastorguev, and V. A. Davankov The use of new chiral phosphite and amidophosphite ligands in S. E. Lyubimov, E. A. Rastorguev, 2068 2031 the Rhcatalyzed hydrogenation of dehydroamino P. V. Petrovskii, acid derivatives and V. A. Davankov The use of carboranylphosphite ligands in Rhcatalyzed S. E. Lyubimov, P. V. Petrovskii, 2074 2037 hydroformylation of alkenes in supercritical carbon E. A. Rastorguev, dioxide T. A. Verbitskaya, V. N. Kalinin, and V. A. Davankov Reaction of 3methoxy2methylphenol with 2ethoxy Yu. M. Sadykova, N. V. Dalmatova, 2078 2041 vinylphosphonic dichloride A. R. Burilov, M. A. Pudovik, and A. B. Dobrynin Reactions of ferricinium salts with Lewis bases V. N. Babin, Yu. A. Belousov, 2081 2044 T. A. Belousova, Yu. A. Borisov, V. V. Gumenyuk, and Yu. S. Nekrasov

Synthesis and structure of binuclear iron(II) complex with the cage E. A. Turitsyna, V. M. Trukhan, 2088 2051 like ligand as a model of methane monooxygenase and A. A. Shteinman

Structure and oxygenase activity of the iron(II) complex with E. A. Turitsyna and A. A. Shteinman 2094 2057 pyridylcarboxamide ligand Germylated steroids. 3. Synthesis of trialkylgermylated steroids R. G. Karpenko, I. V. Krylova, 2100 2063 and A. V. Kamernitskii

[2+4] Cycloaddition of 6(styrene)chromium tricarbonyl A. N. Artemov, E. V. Sazonova, 2103 2066 and conjugated dienes M. V. Revin, K. V. Rybkin, M. A. Lazarev, and V. I. Faerman

Brief Communications

Reactivity of fullerene С60 towards peroxy radicals generated D. I. Galimov, R. G. Bulgakov, 2107 2070 by liquidphase oxidation of cumene and ethylbenzene and D. R. Gazeeva with oxygen

Cyclotrimerization of alkynes catalyzed by the naphthalene D. S. Perekalin, E. A. Trifonova, 2110 2073 + ruthenium complex [CpRu(С10H8)] P. V. Petrovskii, and A. R. Kudinov

A new synthetic approach towards 7substituted 2alkyl V. V. Mezhnev and R. Kh. Geivandov 2114 2077 2,3,4,9tetrahydro1Hfluorenes

Chiral 1,3,2dioxaphospholane amidophosphite in the palladium K. N. Gavrilov, I. V. Chuchelkin, 2117 2080 catalyzed enantioselective allylation S. V. Zheglov, M. N. Gavrilova, E. A. Rastorguev, and V. A. Davankov

Unusual result of the reaction of 4(1methyl1Himidazol2yl) A. V. Yudina, A. G. Majouga, 2120 2083 methylenesubstituted 2alkylthioimidazol5(4H)one E. K. Beloglazkina, I. V. Yudin, with copper(II) chloride I. A. Rodin, and N. V. Zyk 2652 Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2011 Contents

Version Engl./Russ.

Synthesis and molecular structure of the cobalt(II) chloride V. I. Sokol, N. M. Kolyadina, 2124 2086 complex with bis(pyridyl)substituted bispidino V. B. Kvartalov, V. S. Sergienko, aza14crown4 A. T. Soldatenkov, and V. V. Davydov

Letters to the Editor

Synthesis of 2,6bis(chloromethyl)1,4diselenane V. A. Potapov, S. V. Amosova, 2128 2089 K. A. Volkova, M. V. Musalov, and A. I. Albanov Issue 11, 2011

Oleg Matveevich Nefedov (on his eightieth birthday) xv xiii Aleksandr Grigor´evich Merzhanov (on his eightieth birthday) xvii xv Mikhail Fedorovich Churbanov (on his seventieth birthday) xix xvii

Reviews

Chalcogennitrogen heterocyclic radical anion salts: N. P. Gritsan and A. V. Zibarev 2131 2091 the synthesis and properties

Phase transfer catalysis in dichlorocarbene chemistry: M. Ma, kosza and M. Fedoryn´ski 2141 2101 basic principles and specific features

Full Articles

Quantum chemical study of interactions of carbenes and their S. E. Boganov, V. M. Promyslov, 2147 2107 analogs of the EH2 and EHX types (E = Si, Ge, Sn; V. I. Faustov, M. P. Egorov, X = F, Cl, Br) with HX and H2, respectively: the and O. M. Nefedov insertion and substituent exchange reactions The nature of chemical bonding in nitramide I. V. Anan´yev, Yu. V. Nelyubina, 2161 2120 A. A. Korlyukov, P. Yu. Barzilovich, M. Yu. Antipin, S. M. Aldoshin, and K. A. Lyssenko

The reaction energies of ethylene, CO, and N2 with proton, A. A. Markov, G. F. Sharifullina, 2175 2133 hydrogen atom, and hydride ion S. P. Dolin, N. I. Moiseeva, A. E. Gekhman, and I. I. Moiseev The electronic structure of 5methylhexa1,2,4triene1,3diyl, E. Ya. Misochko, A. V. Akimov, 2180 2138 the first representative of highly delocalized triplet ethynyl A. A. Masitov, D. V. Korchagin, vinylcarbenes, from ESR spectroscopy data and quantum S. M. Aldoshin, S. E. Boganov, chemical calculations K. N. Shavrin, V. D. Gvozdev, M. P. Egorov, and O. M. Nefedov Twodimensional lattice oligomers of diboraspiropentadiene: V. I. Minkin, V. E. Avakyan, 2188 2146 a quantum chemical study and R. M. Minyaev Quantum mechanical/molecular mechanical analysis S. V. Lushchekina, I. A. Kaliman, 2196 2154 of mechanisms of enzyme action. Human B. L. Grigorenko, acetylcholinesterase A. V. Nemukhin, and S. D. Varfolomeev 2011 Contents Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2653

Version Engl./Russ. Electrophile affinity and positional selectivity in electrophilic L. I. Belen´kii, N. D. Chuvylkin, 2205 2163 substitution reactions of Nsubstituted pyrroles and I. D. Nesterov Sidewall alkylcarboxylation of carbon nanotubes through reactions O. V. Kuznetsov, A. Cole, 2212 2170 of fluoronanotubes with functional free radicals M. Pulikkathara, and V. N. Khabashesku Synthesis and photophysical properties of silica nanoparticles S. V. Fedorenko, A. R. Mustafina, 2222 2180 based on europium(III) complexes V. V. Skripacheva, M. V. Pinus, D. A. Tatarinov, V. F. Mironov, A. Yu. Men´shikova, K. V. Kholin, M. K. Kadirov, and A. I. Konovalov

Novel titanium(IV) complexes with 2,4ditertbutyl M. V. Solov´ev, S. Ch. Gagieva, 2227 2185 6(1,1,1,3,3,3hexafluoro2hydroxypropan2yl) V. A. Tuskaev, N. M. Bravaya, phenol in ethene polymerization O. E. Gadalova, V. N. Khrustalev, A. O. Borissova, and B. M. Bulychev Binuclear heterometallic {M—Ln} pivalate complexes (M = Co, E. V. Orlova, A. E. Goldberg, 2236 2195 Ni, Cu; Ln = Sm, Gd): synthesis, structure, and thermolysis M. A. Kiskin, P. S. Koroteev, A. L. Emelina, M. A. Bykov, G. G. Aleksandrov, Zh. V. Dobrokhotova, V. M. Novotortsev, and I. L. Eremenko

New crownsubstituted aluminum(III) porphyrinate as an advanced A. Yu. Tsivadze, A. Yu. Chernyad´ev, 2251 2209 fluorescent sensor to potassium cations in aqueous media and Yu. A. Plachev A novel efficient approach to heteronuclear tripledecker complexes A. Yu. Tsivadze, A. G. Martynov, 2258 2216 of rare earth elements with phthalocyanines M. A. Polovkova, and Yu. G. Gorbunova The formation of aryloxenium ion in the reaction of Nnitro M. S. Klenov, A. M. Churakov, 2263 2221 O(4nitrophenyl)hydroxylamine with strong acids V. N. Solkan, Yu. A. Strelenko, and V. A. Tartakovsky

Reactions of 1,4enynes with the system CH2I2—Et3Al I. R. Ramazanov, A. V. Yaroslavova, 2275 2223 U. M. Dzhemilev, and O. M. Nefedov Synthesis of nitrocyclopropanedicarboxylic acid derivatives by addition G. V. Kryshtal, G. M. Zhdankina, 2279 2237 of bromonitroalkanes to methylidene malonic, methylidene A. S. Shashkov, cyanoacetic or maleic acid derivatives and S. G. Zlotin Synthesis of cyclopropane1,1,2,2tetracarboxylic acid derivatives G. V. Kryshtal, G. M. Zhdankina, 2286 2244 n from aldehydes and CHacids in the K2CO3/Bu 4NPF6/toluene and S. G. Zlotin heterogeneous system Reaction of 3,6di(tertbutyl)4chloro1,2benzoquinone V. A. Kuropatov, V. K. Cherkasov, 2291 2248 with N,Ndisubstituted dithiocarbamates G. K. Fukin, and G. A. Abakumov Regioselective addition of cyclic nitrones to Feist´s acid dimethyl ester A. P. Molchanov, T. Q. Tran, 2296 2253 and R. R. Kostikov Nitrene—carbene rearrangement during photolysis of 2azido S. V. Chapyshev 2301 2257 1,3,5triazines in argon matrices Furazancontaining bromoarenes in the Suzuki—Miyaura reaction A. A. Vasil´ev, M. I. Struchkova, 2306 2262 A. B. Sheremetev, F. S. Levinson, R. V. Varganov, and K. A. Lyssenko 2654 Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2011 Contents

Version Engl./Russ. Electronic structure and reactivity of 3acetyl2methylben V. N. Yarovenko, L. V. Khristoforova, 2315 2270 zo[b]thiophene: a quantum chemical study L. I. Belen´kii, N. D. Chuvylkin, and M. M. Krayushkin New tricyclic compounds with pyrimido[4,5d]pyrimidine fragment, V. A. Dorokhov, V. A. Voronkova, 2320 2275 the 7,8dihydro1Hpyrimido[4,5,6de]quinazoline derivatives A. V. Komkov, and A. S. Shashkov A novel route to spinlabeled dihydrooxepines and obenzoquinones E. V. Tretyakov, S. E. Tolstikov, 2325 2280 G. V. Romanenko, A. S. Bogomyakov, V. K. Cherkasov, D. V. Stass, and V. I. Ovcharenko Synthesis of (5S*,4aS*,7aS*)5hydroxyhexahydro A. V. Lozanova, A. O. Chizhov, 2331 2286 cyclopenta[c]pyran3(1H)one and V. V. Veselovsky Stereospecific synthesis of endoendo3,7dioxabicyclo[3.3.0]octane A. N. Anfimov, S. Yu. Erdyakov, 2336 2291 lignans using 1,6bis(dipropylboryl)2,4hexadiene M. E. Gurskii, and Yu. N. Bubnov New method for the preparation of 3diazo1,3dihydroindol2ones V. M. Muzalevskiy, E. S. Balenkova, 2343 2298 A. V. Shastin, A. M. Maharramov, N. G. Shikhaliev, and V. G. Nenajdenko 2Hydroxybenzaldehyde (2phenylquinazolin4yl)hydrazones and T. V. Trashakhova, E. V. Nosova, 2347 2302 their ZnII complexes: synthesis and photophysical properties P. A. Slepukhin, M. S. Valova, G. N. Lipunova, and V. N. Charushin Synthesis of heterosubstituted derivatives of cobalt bis(1,2dicarbollide) I. D. Kosenko, I. A. Lobanova, 2354 2308 I. B. Sivaev, P. V. Petrovskii, and V. I. Bregadze Conjugates of polyhedral boron compounds with carbohydrates. L. M. Likhosherstov, O. S. Novikova, 2359 2312 8. Synthesis and properties of nidoorthocarborane glyco A. O. Chizhov, I. B. Sivaev, conjugates containing one to three lactosylamine residues and V. I. Bregadze Thermodynamics of fluorinated derivatives of carbosilane A. V. Markin, Ya. S. Samosudova, 2365 2318 dendrimers of high generations N. N. Smirnova, N. A. Sheremet´eva, and A. M. Muzafarov

(±)1,1´Binaphthalene2,2´diolderived phosphoric diester: I. P. Beletskaya, 2370 2323 immobilization on polyethylene glycol support and L. S. Patrikeeva, application in the Pudovik reaction and F. Lamaty Efficient catalytic systems based on paramagnetic closoruthena I. D. Grishin, E. S. Turmina, 2375 2328 carboranes for the controlled synthesis of polymers D. I. D´iachihin, D. S. Vinogradov, A. V. Piskunov, A. F. Smolyakov, F. M. Dolgushin, I. T. Chizhevsky, and D. F. Grishin Condensation of methylphenylalkoxysilanes in an active medium A. A. Bychkova, F. V. Soskov, 2384 2337 as a selective method for synthesis of cyclic or linear A. I. Demchenko, methylphenylsiloxanes P. A. Storozhenko, and A. M. Muzafarov Synthesis of phosphodiesterase IVb inhibitors. 2. Stereoselective P. A. Zhmurov, A. A. Tabolin, 2390 2343 synthesis of hexahydro3Hpyrrolo[1,2c]imidazol3one A. Yu. Sukhorukov, A. V. Lesiv, and tetrahydro1Hpyrrolo[1,2c][1,3]oxazol3one derivatives M. S. Klenov, Yu. A. Khomutova, S. L. Ioffe, and V. A. Tartakovsky 2011 Contents Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2655

Version Engl./Russ. Synthesis of polyfluoroalkylcontaining 1(4acetoxybutyl) A. E. Ivanova, O. G. Khudina, 2396 2349 and 1(4hydroxybutyl)pyrazoles and their tuberculostatic Ya. V. Burgart, V. I. Saloutin, activity and M. A. Kravchenko 1,3Сycloaddition synthesis of 1,2,3triazole conjugates A. I. Govdi, S. F. Vasilevsky, 2401 2354 of betulonic acid with peptides V. G. Nenajdenko, N. V. Sokolova, and G. A. Tolstikov Synthesis of chalcones derived from (+) and (–)usnic acids D. N. Sokolov, O. A. Luzina, 2406 2359 M. P. Polovinka, N. F. Salakhutdinov, and G. A. Tolstikov Structure, 1H and 13C NMR spectra, and biological activity A. S. Shashkov, D. E. Tsvetkov, 2412 2365 of the antibiotic INA1278 related to irumamycin and O. A. Lapchinskaya, produced by the experimental Streptomyces sp. V. V. Kulyaeva, G. B. Fedorova, strain No. 1278 A. S. Trenin, E. G. Gladkikh, V. V. Pogozheva, M. O. Makarova, G. I. Orlova, G. S. Katrukha, and N. E. Nifantiev Oneclass approach: models for virtual screening of nonnucleoside P. V. Karpov, I. I. Baskin, 2418 2371 HIV1 reverse transcriptase inhibitors based on the concept N. I. Zhokhova, M. B. Nawrozkij, of continuous molecular fields A. N. Zefirov, A. S. Yablokov, I. A. Novakov, and N. S. Zefirov

Brief Communications

Synthesis and structure of homochiral polymeric praseodymium tartrate M. S. Zavakhina, M. P. Yutkin, 2425 2378 D. G. Samsonenko, D. N. Dybtsev, and V. P. Fedin Reaction of NnitroO(4nitrophenyl)hydroxylamine with M. S. Klenov, A. M. Churakov, 2429 2382 phosphorus pentoxide in the presence of nitriles. New Yu. A. Strelenko, method for the generation of aryloxenium ion and V. A. Tartakovsky New tetrasubstituted thioureas containing the 1iminoethyl moiety A. N. Proshin, T. P. Trofimova, 2432 2385 and S. O. Bachurin

Letters to the Editor

1,2Disila3germacyclopenta2,4dienes: cyclopentadiene analogs V. Ya. Lee, R. Kato, 2434 2387 based on heavier group 14 elements Sh. Aoki, and A. Sekiguchi Novel spiroderivatives of isothiourea of the 1,3thiazine series A. N. Proshin, I. V. Serkov, 2436 2389 as promising neuroprotectors L. N. Petrova, and S. O. Bachurin

Issue 12, 2011

Mikhail Grigor´evich Voronkov (on the ninetieth birthday) xi viii Renad Zinnurovich Sagdeev (on his seventieth birthday) xiii ix 2656 Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2011 Contents

Version Engl./Russ. Reviews

Molecular ferromagnets A. L. Buchachenko 2439 2393

Full Articles

Exchange coupling in polynuclear nickel(II) complexes M. M. Petrova, E. M. Zueva, 2443 2397 with pivalate and hexafluoroacetylacetonate ligands: and E. Yu. Fursova a quantum chemical analysis

Reaction between phenylalanine and 4hydroxy V. A. Shagun, V. I. Smirnov, 2451 2405 4methylpent2ynenitrile: a spectroscopic and L. M. Sinegovskaya, quantum chemical study V. V. Nosyreva, A. P. Borisova, O. A. Shemyakina, and A. G. Mal´kina "Jumping" crystals: structures and properties of CuII complexes V. I. Ovcharenko, E. V. Tretyakov, 2457 2411 with Nmethylimidazolyl and Nmethyltriazolyl S. V. Fokin, E. Yu. Fursova, substituted nitronyl nitroxides O. V. Kuznetsova, S. E. Tolstikov, G. V. Romanenko, A. S. Bogomyakov, and R. Z. Sagdeev

Molecular magnets based on chain polymer complexes of copper(II) S. V. Fokin, S. E. Tolstikov, 2470 2423 bis(hexafluoroacetylacetonate) with isoxazolylsubstituted E. V. Tretyakov, nitronyl nitroxides G. V. Romanenko, A. S. Bogomyakov, S. L. Veber, R. Z. Sagdeev, and V. I. Ovcharenko A matrix method for calculating the magnetic properties E. F. Kustov, V. M. Novotortsev, 2485 2437 of Co2+ complex ions I. L. Eremenko, and E. O. Goncharov Synthesis, structure, and magnetic properties of heterometallic N. P. Burkovskaya, E. V. Orlova, 2490 2442 trinuclear complexes {MII—LnIII—MII} (MII = Ni, Cu; M. A. Kiskin, N. N. Efimov, LnIII = La, Pr, Sm, Eu, Gd) A. S. Bogomyakov, M. V. Fedin, S. V. Kolotilov, V. V. Minin, G. G. Aleksandrov, A. A. Sidorov, V. I. Ovcharenko, V. M. Novotortsev, and I. L. Eremenko Freeradical reactions of the trisdioximate clathrochelates: synthesis A. B. Burdukov, M. A. Vershinin, 2504 2455 and Xray structure of the first cyclohexylsubstituted monoribbed N. V. Pervukhina, S. G. Kozlova, functionalized macrobicyclic iron(II) complex I. V. El´tsov, and Ya. Z. Voloshin

Reactions of dichlorosubstituted iron(II) clathrochelate with M. A. Vershinin, A. B. Burdukov, 2510 2461 1,4dioxane radical derivatives: synthesis, structure, and Z. A. Starikova, V. V. Novikov, spectral characteristics of the dioxane ring opening product and Ya. Z. Voloshin in the ribbed fragment of the macrobicyclic ligand

First example of the ribbedfunctionalized iron(II) clathrochelate N. T. Kuznetsov, I. G. Belaya 2518 2469 with six pendante closoborate substituents (Makarenko), A. V. Dolganov, G. E. Zelinskii, E. Yu. Matveev, K. Yu. Zhizhin, Ya. Z. Voloshin, and Yu. N. Bubnov Group II metal complexes with the N(2oxy3,5ditertbutylphenyl) A. V. Piskunov, O. Yu. Trofimova, 2522 2473 4,6ditertbutyloiminobenzoquinone ligand: an ESR study S. Yu. Ketkov, G. K. Fukin, V. K. Cherkasov, and G. A. Abakumov 2011 Contents Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2657

Version Engl./Russ. Direct C—Ccoupling of ferrocenyl and cymantrenyllithium with I. A. Utepova, A. A. Musikhina, 2531 2482 5(het)aryl1,2,5oxadiazolo[3,4b]pyrazines Yu. A. Kvashnin, M. A. Shcherbakova, P. O. Serebrennikova, G. L. Rusinov, and O. N. Chupakhin The synthesis and study of multilayer polymer structures based on M. M. Krayushkin, V. N. Yarovenko, 2536 2487 1,2bis(2methylbenzo[b]thiophen3yl)cyclopent1ene L. V. Khristoforova, A. S. Shashkov, E. P. Grebennikov, A. G. Devyatkov, G. E. Adamov, K. S. Levchenko, P. S. Shmelin, V. A. Barachevskii, T. M. Valova, and O. I. Kobeleva Synthesis of thioether derivatives of hyperbranched carbosilane polymer A. N. Tarasenkov, E. V. Getmanova, 2544 2495 M. I. Buzin, N. M. Surin, and A. M. Muzafarov Synthesis of boroncontaining tyrosine derivatives based on A. V. Prikaznov, Yu. N. Las´kova, 2550 2501 the closodecaborate and closododecaborate anions A. A. Semioshkin, I. B. Sivaev, A. V. Kisin, and V. I. Bregadze Synthesis and properties of ZnII and CdII complexes with chiral S. V. Larionov, T. E. Kokina, 2555 2506 Nderivatives of aminoacetic acid based on natural mono A. M. Agafontsev, K. S. Marenin, terpenes (+)3carene and (–)pinene. Crystal structure L. A. Glinskaya, I. V. Korol´kov, of coordination polymer [Zn(HL)Cl•2H2O]n M. I. Rakhmanova, E. M. Uskov, P. E. Plyusnin, and A. V. Tkachev Copper complexes with nitronylnitroxyl radicals as lipoxygenase E. R. Milaeva, S. I. Orlova, 2564 2514 inhibitors with antioxidant activity D. I. Osolodkin, V. A. Palyulin, E. Yu. Fursova, V. I. Ovcharenko, and N. S. Zefirov Synthesis of sulfated dendrimers and studies of their anticoagulant V. B. Krylov, N. E. Ustyuzhanina, 2572 2522 and antiinflammatory activity A. A. Grachev, N. A. Ushakova, M. E. Preobrazhenskaya, Yu. A. Shchipunov, J. Wang, M. H. Kim, I. Kim, and N. E. Nifantiev 1H CIDNP study of the kinetics and mechanism of the reversible N. N. Saprygina, O. B. Morozova, 2579 2529 photoinduced oxidation of tryptophyltryptophan dipeptide N. P. Gritsan, O. S. Fedorova, in aqueous solutions and A. V. Yurkovskaya Structural studies of nanosized porous membrane catalytic systems M. V. Tsodikov, V. V. Teplyakov, 2588 2537 highly active in dry reforming of biomass conversion products A. S. Fedotov, V. I. Uvarov, D. Roizard, A. Kiennemann, C. Courson, and I. I. Moiseev Influence of the strong electrolyte on the aggregation behavior E. I. Yackevich, A. B. Mirgorodskaya, 2597 2546 and catalytic properties of dicationic surfactants L. Ya. Zakharova, and A. I. Konovalov

Brief Communications

A SEM study of nanosized metal films and metal nanoparticles A. S. Kashin and V. P. Ananikov 2602 2551 obtained by magnetron sputtering 2658 Russ.Chem.Bull., Int.Ed., Vol. 60, No. 12, December, 2011 2011 Contents

Version Engl./Russ. Method for the synthesis of a stable heteroatom analog E. V. Tretyakov, S. E. Tolstikov, 2608 2557 of trimethylenemethane G. V. Romanenko, A. S. Bogomyakov, D. V. Stass, A. G. Maryasov, N. P. Gritsan, and V. I. Ovcharenko Poly(Nvinylimidazole) as efficient recyclable catalyst for E. A. Tarasenko, V. S. Tyurin, 2613 2561 the Michael addition of CHacids to electron F. Lamaty, and I. P. Beletskaya deficient alkenes in water Reaction of 2aza1,3,5trienes with superbases: an unexpected N. A. Nedolya, O. G. Volostnykh, 2617 2565 approach towards exomethylene tetrahydroazepines O. A. Tarasova, A. I. Albanov, and B. A. Trofimov Kinetic analysis of the search for damaged DNA bases by N. N. Lukzen, K. L. Ivanov, 2621 2569 repair enzymes: theoretical investigation of and V. V. Koval diffusioncontrolled steps Information 2625 2573