June 2015 Npdes Biomonitoring Report, Chronic Survival and Reproduction Toxicity with Ceriodaphnia Dubia (07/23/2015 Report Cert

NPDES BIOMONITORING REPORT

GENERAL ELECTRIC COMPANY Pittsfield, MA NPDES PERMIT MA 0003891

Chronic Survival and Reproduction Toxicity Test with Ceriodaphnia Dnbia

June2015

WHOLE EFFLUENT TOXICITY TEST REPORT CERTIFICATION

I certify under penalty of law that this document and all ATTACHMENTS were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false infonnation, including the possibility of fine and imprisonment for knowing violations. a. Executed on 1 f.n /10 1$' !:Jv T ~ ' (Date) (Authorized Signature)

Andrew T. Silfcr

General Electric Co.-Pittsfield, MA Pennit MA0003891

Prepared by: Tracy Christ & Matt Calacone

July 16, 2015 .f:fl:Ua."''~-:.c..,;~ft.u.t:r.J

July 20, 2015

Mr. Sean Coyle Veolia Water North America 1000 East Street Pittsfield, MA 01201

Re: NPDES Chronic Biomonitoring Report for June 2015 Submission #s: R1504743, R1504879, R1504948

Dear Mr. Coyle:

Enclosed is our report on the Chronic Whole Effluent Toxicity testing conducted in June 2015. The 64G Composite samples were collected on 6/15/15, 6/17/15 and 6/19/15 at 7:00am. The Housatonic River samples were collected on 6/15/15 at 8:50am, 6/17/15 at 8:20am and 6/19/15 at 8:45am. The 64G Composite and Housatonic River samples were analyzed at ALS Rochester for ammonia, total organic carbon, total solids, total dissolved solids, alkalinity and total metals. Results are presented in Appendix 2. The 64G Composite and Housatonic River samples were sent directly by Veolia to Aquatec Biological Services for the chronic aquatic toxicity testing including the analysis of alkalinity, hardness, specific conductance, and pH. Results are presented in Appendix 1.

Should you have any questions please contact me at (585)672-7473.

Thank you for allowing us to provide this service.

Sincerely,

ALS Environmental ~l}jw.dJ- Tracy Christ Project Manager en c. TABLE OF CONTENTS

PAGE

I. Summary 1

II. Review of Toxicity Analytical Results 2

III. Review of Wastewater Sampling Procedures 3

Table I- Summary of Analytical Test Results

Appendices:

1. Chemical and Acute Toxicity Data from Aquatec Biological Sciences

2. Laboratory Reports from Columbia Analytical Services, Inc. and Veolia, Inc.

3. Chain of Custody Forms Table I-Summary ofAnalytical re!Uits for NPDES Outfall Composite Sample and Housatonic River Dilution Wak:r June 611 S/1 S • 6/19/1 S

Chronic Toxicity Results: C-NOEC• 100% ICJ5 >tOO%

Acute Toxicity Results: A-NOEC 100% LC~ >100%

ICbcmical_~,lalll!!eS : fAll r~<~ulL• m maiL unless gJh~~is iodi!

June IS June 15 June 17 June 17 June 19 June 19 Effluent Housatonic Effiucnl Housatonic Effluent Housatonic Parnmcter Tested <~hnntftrv Coml!osjt~ Rim rompasitc rum &in!: Ammonia ALS ND(O.DS) ND(D.DS) ND(O.DS) ND(O.OS) ND(O.OS) ND(O.OS) Total Alkalinity ALS 420 84 410 57 415 68.3 Total Organic Carbon ALS s.s 6.3 5.9 6.1 5.7 5.4 Total Solids ALS 694 144 718 106 709 114 Total Dissolved Solids ALS 637 99 686 102 515 95 Hardness Aquatcc 370 76 370 60 360 74 Spec. Conductance (umhos) Aquatec 1309 218 1298 174.4 1268 205 IPH (SU) Aquatcc 8.1 7.9 8.2 7.9 8.2 8.1 TRC (start of toxicity test) Aquatc:c NO ND NO NO NO ND Aluminum, total ALS ND(0.03) 0.20 ND(0.03) 0.04 ND(0.03) ND(0.03) Cadmium, total ALS ND (0.00003) 0.00003 ND (0. 00003) ND (0.00003) NO (0.00003) 0.0002 Copper, total ALS 0.0016 0.0019 0.0013 0.0006 0.0017 0.0006 Lead, total ALS NO (0.00003) 0.0019 NO(O.OOOOJ) ND (0.00003) NO {0.00003) 0.0010 Nickel, total ALS 0.0015 0.0010 0.0014 0.0006 0.0016 0.0006 Zinc, total ALS ND(0.00\2) 0.0044 ND(0.001l) 0.0016 ND(0.0012) 0.0016 IPH (SU) Veolia 7.78 7.43 7.92 7.76 7.89 7.90

NA - Not analyttd NO - Not detected (Number in parentheses is detection limit.) I. Summary

On June 15-19. 2015 sampling of wastewater discharges from the General Electric Company facility in Pittsfield, MA was conducted in accordance with the chronic toxicity testing requirement of the GE NPDES Permit MA0003891. Three composite samples were collected from the GE 64G final effluent (which discharges through the outfall serial number 005 to the Housatonic River) over a 5-day period. Sampling dates were June 15. June 17 and .Ttu1e 19. The 64G effluent composite sample was shipped via courier to Aquatec Biological Sciences in Williston, Vermont for chronic toxicity testing. Grab samples of Housatonic River water, to be used as dilution water in the toxicity testt were collected upstream of the GE discharges on June 15, 17, and June 19 and shipped to Aquatec along with the 64G composite. Veolia, Inc. and ALS Rochester tested the composite effluent sample and the dilution water sample for chemical constituents. The analytical results are summarized in Table I and the detailed laboratory reports are included as Appendices to this report.

The results from Aquatec Biological Sciences for the chronic toxicity test on the 640 final effluent discharge sample indicated a Chronic-No Observed Effect Concentration (C-NOEC) of 100% with an IC2s of> 100% Acute toxicity results were as follows- A NOEC was 100% and an LCso of> 100%.

Page 1 II. Review of Toxicity Test Results

The effluent discharge samples collected at Outfall 640 on .hme 15, June 17 and June 19 were tested for 7-day chronic toxicity using Ceriodaphnia dubia organisms. The samples did not require dechlorination with sodium thiosulfate (Na2S203) prior to toxicity testing. Aquatec Biological Sciences reported the results of this toxicity testing as follows:

Chronic Reproductive Toxicity Effiuent toxicity as C-NOEC= 100% Effluent toxicity as IC2s = >100%

No limit is established for N-NOEC in the GE NPDES permit.

Acute Survival Toxicity Effluent toxicity as A-NOEC 100% Effluent Toxicity as LC so >100%

The following table summarizes the results of the control sample analyses performed by Aquatec during the chronic toxicity bioassay:

Control Analysis Result Acceptable Limit Survival in 100% dilution water 100% ~80% Reproduction in 100% dilution water (average# of offspring/female/day) 27 ~15 Reproduction in 100% dilution water (%of females having three broods) 90% :;:60%

The survival and reproduction rate of Ceriodaphnia dubia in the upstream dilution water control samples was within acceptable limitst indicating that the results of the toxicity test are valid.

Page2 Ill. Review of Wastewater Sampling Procedures

Three composite effluent samples from Outfall 640 were collected over a 24-hour period.

The 24-hour composite sample was collected as follows:

An automatic sampler at outfall 64G was programmed to collect approximately 7 liters of effluent into a 10-liter glass container in a time-proportioned manner over a 24-hour period. The sample container was refrigerated to keep the effluent sample cold during the 24-hour collection period. Flow meter readings were taken at the beginning and end of the 24-hour collection period to determine the total 24-hour flow for the 64G effluent discharge.

At the end of the 24-hour collection period, Veolia personnel packaged this sample for the chronic toxicity test and the chemical analyses. The effluent discharge sample was then split into various containers for toxicity testing and chemical analyses. These containers were shipped by vendor courier to Aquatec for toxicity testing and by FedEx (overnight) to ALS Environmental for chemical analyses. All samples were chilled with ice packs during shipment.

A grab sample of Housatonic River water was collected on the second day of each 24- hour period at the Lyman Road Bridge in Hinsdale, MA, upstream of the GE site. This sample was split for chemical analysis and toxicity testing in a similar manner as the combined effluent sample (see above).

Details of the times and dates of sample collection as well as the names of the individuals collecting and transporting the samples are provided on the chain of custody forms in Appendix 3 of this report.

Page 3 APPENDIX!

Chemical and Acute Toxicity Data

Aquatec Biological Sciences Aquate·c Biological Sciences

~e~ .. ~ ~~'=!.~ a~

July 16, 2015

Ms. Tracy Christ, Project Chemist ALS Life Sciences Division, Environmental 1565 Jefferson Road, Building 300, Suite 360 Rochester, NY 14623-3190 [email protected]

Dear Ms. Christ:

Attached please find the electronic copy (PDF) of our report on the results of a whole effluent toxicity test (chronic Ceriodaphnia dubio survival and reproduction test, EPA Method 1002.0 with acute data reported) for samples received from GE Pittsfield, Massachusetts during June 2015.

If you have any questions regarding the report, please call Dr. Philip C. Downey or me.

anager, Environmental Toxicology

This report consists of the following numbered pages: SDG: 14382 Pages: 1- 37

273 Commerce Street, WUUston, VT 05495 Tel: 802.860.1€138 Fax: 602.658.3189 Aquatec Biological Sciences~ Inc. SDG: 14382 273 Commerce Street Project: 15014 Williston, vr 05495 Tel: (1102) 860- 1638 Fax: (802) 658- 3189

Toxicity Summary Report

ALS Environmental Tel: (585) 672-7470 1565 Jefferson Road Fax: Building 300, Suite 360 Rochester, NY 14623 E-Mail: -·································-····-·························································································-····························································· Project: GE Pittsfield NPDES Permit No. MA0003891

Sample Name: Outfall Composite (64G-A10287) Sample ID: 46930

ACUTE CHRONIC r-%- , r-%--, Method Species A-NOEC A-L.c&O C·NOEC C-L.OEC ·------··------1002.0 Cerfodaphnia dub/a 100 >100 100 >100 .... ·-·· . . -·-. ·------

Samples Received

Number Sample Name Date Time and Collected Type ····---- 46930 Outfall Composite (64G-A10287) 6/15/2015 7:00:00AM Effluent 46931 Housatonic River (A10288R) 6115/2015 6:50:00AM Receiving 46942 Outfall Composite (64G-A-10289) 6/17/2015 7:00:00AM Effluent 46943 Housatonic River (A10290R) 6117/2015 8:20:00 AM Receiving 46953 Outfall Composite 64G-A 10291 6/19/2015 7:00:00AM Effluent 46954 Housatonic River A1 0292R 6/1912015 8:45:00AM Receiving ---··· .. --·· - .

1 of 1

1 Thursday, July 16, 2015 r

Aquatec Biological Sciences, Inc. SOG: 14382 15014 273 Commerce Street Project: Williston, VT 05495 Tel: (802) 860 • 1638 Fax: (802) 658- 3189

Toxicity Detail Report

ALS Environmental Tel: (585) 672-7470 1565 Jefferson Road Fax: Building 300, Suite 360 Rochester, NY 14623 E-Mail: ...... _...... __ ,.,._ ...... -...... ~ ......

Project: GE Pittsfield NPDES Permit No. MA0003891 Sample 10: 46930 Outfall Composite (64G-A10287) -·-··· Method: 1002.0 Cerlodaphnla dub/a

Response: Survival (%) ,--- . Additional % -----, Day Control 0 6.25 12.5 25 50 75 100 2 100 100 100 100 100 100 100 100 6 100 100 100 100 100 100 100 100 Response: Reproduction (mean neonates per female) Additional % Control 0 6.25 12.5 25 50 75 100 6 32.8 26.5 29.9 27.2 27.5 28.7 30.7 27.5

1 of 1 2 Thursday, July 16, 2015 \~ ACCo., Aquatec Biological Sciences, Inc. 0 rt() 273 Commerce Street ~ (t' Williston, VT 05495 0 ~ 0 ..... Tel: (802) 860 ~ 1838 Fax: (802) 858 • 3189 < % Aquatec Biological Sciences Certification Number 1737 Toxicity Quality Assurance Report SDG: 14382 Project: 15014 ...... ························- ..-·········· ...... ALS Environmental Tel: (585) 672~7470 1565 Jefferson Road Fax: Building 300, Suite 360 ...... Rochester, NY 14623 E~Mall:

Project: GE Pittsfield NPOES Permit No. MA0003891

Method: 1002.0 Cerfodaphnia dub/a --·. ·····---·- .. ··------Response: Survival (%)

Day Sample ID Dilution Control Additional Control

2 46930 100 100 6 46930 100 100

Response: Reproduction (mean neonates per female)

Day Sample 10 Dilution Control Additional Control

6 46930 26.5 32.8

Percent Minimum Significant Difference (PMSD) SensltlvJty Determination

PMSD Comparison: PMSD: 16.9% PMSD Criteria Range: 13%-47% The calculated test PMSD was within the acceptable boundary range indicating test data with acceptable variability and statistical sensitivity. The chronic values (C-NOEC, C-LOEC) were reported as calculated by the statistical program.

3 Thursday, July 16, 2015 SDG: 14382 Project: 15014 ············;:Ls.. e~~i~~~;;;~~i;i···· · .... ·································~····························· ·· ·····:r~i;···csasfs72:747a··················· .. ·······-···· 1565 Jefferson Road Fax: Building 300, Suite 360 Rochester, NY 14623 E-Mail: ...... -..... -"...... -· ...... ·-.....- .. ·-.... ·-...... --...... Project: GE Pittsfield NPDES Pennit No. MA0003891 Special Conditions and Qualifiers To the best our knowledge, there were no special conditions or qualifiers that relate to the samples In this report, with the following exceptions:

A total residual chlorine analysis (Hach Kit) was not perfonned on the June 19, 2015 effluent sample. A titrimetric check for presence of residual chlorine for this sample did not detect chlorine.

On Day 3, the initial chemistry data showed that the conductivity of the lab water control was low. The laboratory control consisted of a mix of lake water and moderately hard water. It appears that on Day 3, the laboratory control was renewed with lake water (without mixing with moderately hard water). This did not affect the outcome of this test

4 Thursday, Juty 16, 2015 SDG: 14382 Project: 15014 ...... - ...... _. ____ ·········-························································· ALS Environmental Tel: (585) 672-7470 1565 Jefferson Road Fax: Building 300, Suite 360 Rochester, NY 14623 E-Mail: ··················································-·····································································-···································-·····························-·· Project: GE Pittsfield NPDES Pennit No. MA0003891 WHOLE EFFLUENT TOXICITY TEST REPORT CERTIFICATION The results reported relate onlv to the the samples submitted as received. I certify under penalty of law that this document and all ATTACHMENTs were prepared under my direction or supervision In accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my Inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the lnfonnatlon, the Information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, lnclud e possibility of fine and Imprisonment for knowing violations. .· · ···· ·' ,/ Executed on: "'? ~/ £~..J . ~· John Wllllams oxicity Laboratory Manager Aquatec Biological Sciences, Inc.

5 Thursday, July 16, 2015 Aquatec Biological Sciences, Inc. SDG: 14382 273 Commerce Street Project: 15014 Williston, VT 05495 Tel: (802) 860- 1638 Fax: (802) 658 -3189

Project: GE Pittsfield NPDES Test Start Date: Tuesday, June 16, 2015 Client ID: ALS Environmental Pennit No. MA0003891 Pipe No. 1 .. :': :· ...-: ... ..-: ..: .. :"':": ...... ~ ...~ . ..:-:-: . .-:-:- .. -:-:-.. -~...... ~ ...... ~ ...... ~ ...... ~ ...... ~...... ~ ..:-::. ..~ ...~.::-: ...:-.:: ..::-: . .~ ... ::-: .. ~ ... 1002.0 Daphnid, C. dubia, Survival and Reproduction Test Species: Cerlodaphnia dub/a Reference: EPA-821~R-02-013 SOP: TOX2-002 .. .. .- --·...... -- ...... ' ...... i: .. ·;.:...... - ·"••;.;;.;;•·,;..;.;·· ·;..;..;· •.;.:.·. ;,;..!" " •.:.:.;·.·;.;;;·-;;.;.;··:;;;; · ·.:..;.;·. •;.;.;;• · .:..;.;·.·~ · . ·;.;.;;··==·-;.;.;;· ·~·· ·:.=..:·•.:.;;• ••;,;,;·..... ··=· .. TOXICITY TEST SUMMARY SHEET Daphnld, C. dubla, Survival and Reproduction Test

Test Type Test Species Sample Type Sampling Method . · ------~------~~~ ------~~~----- Modified Chronic Ceriodsphn/a dub/a Effluent Composite

Dilution Water: Housatonic River

Additional Control: 1:1 Lake Champlaln/MHW

Effluent Sampling Dates: June 15, 17, and 19, 2015 Effluent Concentrations Tested(%): 0, 0, 6.25, 12.5, 25, so. 75, 100

Was Effluent Salinity Adjusted? No If yes, to what value?

With Sea Salts? Hypersaline Brine Solution?

Reference Toxicant Date: June 9-16, 2015 Reference Toxicant Test Acceptable? Yes

Age and Age Range of Test Organisms: < 24h collected within an 8-hour period Source of Organisms: In-house cultures, Aquatec Biological Sciences, Inc.

------~ ---~ ·· --··------6:;:"~ ------~~----T-hu-r-sd-a-y,-J-ul-y -16-,-2-0-15- Aquatec Biological Sciences, Inc. SDG: 14382 273 Commerce Street Project: 15014 Williston, VT 05495 Tel: (802) 880 ~ 1838 Fax: (802) 658 • 3189

Project: GE Pittsfield NPDES Test Start Date: Tuesday, June 16, 2015 Client 10: ALS Environmental Permit No. MA0003891 Pipe No. 1

~ :: :::.:- •• ··· ·~ · . •• • • • ...... • 0 • - • ...... :"::":':"'.'•••• :-: • • '"'"'· ··..,..,..· ••~ • • ..,..,.. • • , ..,..,.. •••~ ••- ••~• • - • • ~••..,..,.. •• •~ • • ....,.. • .....,. _ .,...... _ . -:-••= ...... ,...... - .. -:-:...,-- ...=.. = .. .= .. ...= = ... = .. ...= = .. .=.. -- ..... - - .. . 1002.0 Daphnidl C. dubia, Survival and Reproduction Test Species: Cerioc/aphnia dubia Reference: EPA-B21-R.02-013 SOP: TOX2-002

...... ~ •••••• •,:.:..: .:.!'". • . _ ,:..:...... ~ - ···· · ·· ...... ~++..._6 ...... !:.·. ~ - · ·· ·· · · · · · · · · ·-"· ···· · ·~··· ···· ··· · · · ...... ~ ...... TEST RESULTS AND PERMIT LIMITS Oaphnld, C. dubla, Survival and Reproduction Test Test Acceptability Criteria A. Dilution Water Control: Housatonic River Mean Control Survival (%): 100 Mean Control Reproduction (neonates): 26.5 B. Additional Control: 1:1lake ChamplalnJMHW Mean Control Survival {%): 100 Mean Control Reproduction (neonates): 32.8

C. lab Control: See Babove D. Thiosulfate Control: N/A

Test Variability Test PMSD Reproduction(%): 16.9

PERMIT LIMITS AND TEST RESULTS Daphnld, C. dubla, Survival and Reproduction Test

LIMITS(%) RESULTS(%) ------48-Hour LC50: 48-Hour LC50: > 1 00 Upper Value: lower Value: Data Analysis Linear interpolation, Fisher

Method(s): Exact/Bonferroni-Holm Test1 Dunnett Multiple Comparison Test A-NOEC: A-NOEC: 100 C-NOEC: C-NOEC: 100 C-LOEC: > 100 IC25: IC25: > 100 ICSO Limit: IC50:

_ ...... ~--

-·- · ---- Thursday, July 16, 2015 Aquatec Biological Sciences, Inc. SOG: 14382 273 Commerce Street Project: 15014 Williston, VT 05495 Tel: (802) 860 - 1638 Fax: (802) 658 • 3169

Project: GE Pittsfie!d NPDES Test Start Date: Tuesday, June 16, 2015 Client ID: ALS Environmental Permit No. MA0003891 Pipe No. 1 ... :-:.:-.. -.-..~ ~--...-.. ~ ...... -... - ..- ..-:- .. .. ~ ...... -: ...... · .. ::-:: ..":":" .. .:":": ..':': ..~... ~ ... -.~---·· ·· ...... ····-····-:.: ..... ··············-- .. ······· ··· · ····~ ·· 1002.0 Daphnid, C. dubia, Survival and Reproduction Test Species: Ceriodaphnla dubia Reference: EPA-821-R~02-013 SOP: TOX2-002 .. ~ . ---- ...... ·...:...:.:.:.:.·...... _··:.... ·.·...... ·:· ... ····· ' .. ······..:·::.:·········· ···.-.:·····...... :.:...... -:· - ~ · ··· -·~ ...... _...... :~ Reported Test Results Justification, PMSD Comparison Discuyion and Concentration-Response Evaluation: Control Results: The statistical control (receiving water) met survival and growth acceptability criteria. The additional non statistical control (laboratory water) also met test acceptability requirements.

PMSO Comparison: Statistical analysis of the test data resulted In a Percent Minimum Significant Difference {PMSD, a measure of statistical sensitivity) within the boundaries (13%-47%) outlined in Table 6 of EPA-821-R-02-013 for Cerlodaphnla dubla reproduction indicating test data with normal variability. The chronic values (C-NOEC, C-LOEC) were reported as calculated by the statistical proram.

Concentration-Response Comparison: The concentration-response pattern reflected a relationship where significant reductions In Cerlodaphnla dubla survival or reproduction were not detected. The chronic values (C-NOEC and C-LOEC) were reported as calculated by the statistical program.

_.... -- ____,.___ -- a Thursday, July 16, 2015 Supportive Documentation ---·- ·--··-·-·---

Chain-Of-Custody Toxicity Test Methods 1002.0- Daphnid, C. dubia, Survival and Reproduction Test Standard Reference Toxicant Control Charts

ALS Environmental

9 Chain-Of-Custody

AlS Env!~Qmental Page --1 of 2 ·-·· . ., 273 Cominerce Sl:rel t • ~"' • !-. ' '·. .. .Aq~a -~ec . ~iolog _ical : $~iences - WRllston, VT.05495 .. ·, TEL:{~~) a6o-t63B - ,. .. . L . ' .¢hai ,n.~f-Cu~t~y RecQrd ~i!O~> 658-3189 VOLUME/CONTAINER TYPE/ COMPANY INFORMATION COMPANY'S PROJECT INFORMATION SHIPPING INFORMATION PRESERVATIVE Carrier: Priority Express Name: Geneml Eledric Company Project Name: GE PITTSFIELD 4CIC 40C 40C 40C ..oc ..oc I H2S04 Hz so. HNO, Address: Veolia Watar NA Outfall Composite - INITIAL SAMPLE 1000 Eut Strut. Gate 64 Project Number: 15014 Alrbill Number: - - - - - Plastic Plastic Plastic Glass -Glass Plastic City/State/Zlp: Pittsfield, MA 01201 Sampler Name(s): Telephone: (413) 494-6709 NPDES Pennlt #1:: MA0003891 Date Shipped: ~5 FacsimHe: Ship these samples on Monday cr~ant Code: ALSIChrist - - Contact Name: Sean Coyle Hand Delivered: 0 Yes No 1 gal 112 gal 40ml -- 1iJ --1L 40ml 0.5 L SAMPLE COLLECTION SAMPLE Start date Completion GRAB COMPOSJTE MATRIX ANALYSIS NUMBER OF CONTAINERS IDENTIFICATION andtlme date and)ime Effluent Renewal1 (R1): Ceriodaphnia dubia o~~~.lrAsHe /,/.6/$.,..._ v 1 ~ - ld28 1 o/:ftft_ chronic suvival and reoroduction Effluent Total Residual Chlorine OUtfal C.j/r;stte ,.l!fil~ ~ft: 1 ~- ,.,0~ ~- ...,_ v (See Note fn Comment Box below)

Housa}lfj~!iR '{~~- v Receiving Receiving (Dilution Water) 1

~ DATE 11M~ TamparabJre blank at time of dellvary (Aquatec): /, 8' ·c. , ~nza~re~#. -rrr;c.;;;~ ~-Is--; V3d;, ~,,,.>" WWTP OJ2erators: , Relinquislm'tiby: (signature) DATE Is your final affluent chlorinated? ~tu/6 ;;,et ~~~ If so, Is it dechlorinated prior to shlpmentfortoldclty testing? Relinquished by: (signature) DATE TIME R~ by: (signature) Please record TRC concentratiOn, mgll. (ff available):

Sample acceptance policy: Chain-of-Custody completed. Sample botUe labels should be completed and covarad with waterproof tape. Sample should be received at 0~-60C and/or within 6 hours of collection. Samples should be received with In specified holding times based on controlling regulations (e.g., less than 36 hours for effluent samples under NPDES regulation). Samples not meeting the above conditions (per applicable regulatory protocol&) will be qualified In the raport.

... Page 1 of L,

~73 Commerce StnH Aqu~tec E$jol~;gica:~ Sciences Williston, VT- 05495 . 11;1.: (802) ~1638 -.. Chain~o.f~Cu§tody. Record f.AX; .(~~1~~1~ - " VOLUME/CONTAINER TYPE/ COMPANY INFORMATION COMPANY'S PROJECT INFORMATION SHIPPING INFORMATION PRESERVATIVE Carrier. Priority Express Name: Genen~l Electric Company Project Name: GE PnTSFIELO <40C 40C 40C 40C 40C 40C H250, Address: Veolla Water NA Outfall Composite- RENEWAL SAMPL.E ~o. HNO:~ 1000 East Stmet. Gate 64 Project Number. 15014 Airbill Number: - Plastic - Glau - Plastic- Plastic -- Glass -Plastic City/Stale/Zip: Pittsfield, MA. 01201 Sampler Name(s): Telephone: (413) 494-6709 NPOES Pennit#; MA0003891 Date Shipped: t;,Jrh • I Facsimile: Shlp these samples on Wedne&day Client Code: ALS/Chrtst - Contact Name: Sean Coyle Hand Delivered: 0 Yes -1 gal 112 gal 40ml 1L -- 40ml-- - I ~ 0.5L SAMPLE COLLECTION SAMPLE Start date Completion GRAB COMPOSITE MATRIX ANALYSIS NUMBER OF CONTAINERS IDENTIFICATION and tio'le date 6nd time Outfall Co*site St;' 'r?-!ff v Effluent Ronewal1 {R1): Ceriodaphnia dub/a 1 ~~ (02 )'~~ ~4~:. chronic suvlval and mDroduclion Outtal C~sile t'f t,./ Effluent Total Residual Chlorine 1 tpt'G- toz ~~ ~ {See Note In Comment Box below) ....a. 1\) I Hous~~~R "~{~ v Recelving Receiving (Dilution Water) 1

TIME Temperature blank at time of delivery {Aquatec):O, 7·c. Relin~"~••l~reJ # O~TE ~ ~sign~re) .- ~ .1.1~~-~ ~/r116 (.53< ~ -p WWTP Oeerators: "Relinquished by: (slgnatute) TIME_, ra) ~ 11 your final effluent chlorinated? ~ ~itJb 0 9; f"l ;rv, If so, is it dec:hkJrinated prior to shipment fw toldc;Jty testing? Relinquished by: (signature) DATE TIME ~d by: (signature) Please record TRC concentration, mg/L (If available):

/ ------

Sample acceptance policy: Chain-of-Custody completed. Sample bottle labels should be completed and covered with waterproof tape. Sample shoufd be received at oo-a•c andlorwlthin 6 hours of coUec:ifon. Samples should be received with in specified holding tlmes based on controlling n.gulations (e.g., leas than 36 hours for effluent samples under NPDES regulation). Samples not meeting the above conditione (per applicable regulatory protocols) will be qualified In the report Pago 1 of 2 .. .. - 273 Commerce~ Aqua.tec ~:~ol~g.i-cal Sci~nces Wils~, VT 054?5. TEL: (802) 860-1638 .. -- - .Chalri~of~stod~ -~~cor.d-.. . . . F~ (802)!358.3UI9 VOLUME/CONTAINER TYPE/ COMPANY INFORMATION COMPANY'S PROJECT INFORMATION SHIPPING INFORMATION PRESERVATIVE

Name: General Electrk Company Project Name: GE PITTSFIELD Carrier: Priority Express 40C 400 40C 40C 411C 40C Address: Veola Water NA Outfall Composite - RENEWAL SAMPLE HNO• H~. liN<>3 1ooo East S1met Gato 84 Project Number: 15014 Alrbil Number. - - - - -, Plastic Plastic Plastic- Glass Glass Plastic City/Slate/Zip: Pittsfield, MA 01201 Sampler Name(s): Telephone: (413) 494-6709 NPDES Pennlt tl: MA0003891 Date Shipped: qd_l/t~ Facsimne: Ship these aamples on Friday. - - Contact Name: Sean Coyle - Client Code: AlS/Chrbt Hand Delivered: Yes 1 gal 112gal- 1L 40ml 40ml I D ~ - - O.SL COLLECTION SAMPLE Start date Cornpletlon GRAB COMPOSITE MAlRIX ANALYSIS NUMBER OF CONTAINERS IDENTIFICATION and time date and time ow~~mposite g,~q~ Emuent Renewal 2 (R2): Ceriodaphnla dubis 2 -AJNJ!il ~~: '7 ~~ 1/ chronic survival and reproduction "/lfll* Effluent Total Residual Chlorine 1 ~1£~10~1 t,(lv/t~,IA'l 1--'..... V' (See Note In Comment Box below)

HousatJ!I~piuar- t./11h'i. 'd Receiving Receiving (Dilution Water} 2 ".l"f";u( ' ·n1·1: t/

/ J. Temperature blank at lime of delivery (Aquatec): ·c. Re~s~~tum);- . .Ky:~ l ,3 ~ A#)- 1-: --./'{ "· ..... IJ$ir ~~ V,Y, 'Y WWTP Oe!rators: "ReHnqulshed by: (signature) Is your final effluent chlorinabtd? (q .~ ~t~!nf:?'§ If &o, I& It dechlorinated prior to ahlpment for toxicity testfng? ti 0~ ..... ~w~_,.~ Relinquished by: (.signature) DATE TIME Re~vedby:(m~~J Please record TRC concentration, mgll (If available):

Sample accepJance policY: Chain-of-Custody completed. Sample bottle labels should be completed and covered with waterproof tape. Sample should be received at 0"-8"C and/or within 6 hours of colloctfon. Samples should be received with In specified holding times based on controlling regulations (e.g., less than 36 hours for effluent samples under NPDES regulation). Samples not meeting the above conditions (per applicable regulatory protocols} will be qualified In the report. Toxicity Test Methods

ALS Envfro~~ental Daphnid, C. dubla, Survival and Reproduction Test Method: 1002.0 Ceriodaphnia dub/a Associated Protocol: EPA-821-R-02-013 SOP: TOX2-002 GE Pittsfield NPDES Permit: MA0003891 Pipe 1 Project: 15014

1 Testtype: Static renewal

2 Temperature: 25 +/-1 C; Test temperatures must not deviate (I.e. maximum minus minimum temperature) by more than 3C during the test 3 Ught quality: Ambient laboratory Illumination

4 Ught Intensity: 10-20uE/m"2/s or 50-1 OOft-c (ambient laboratory levels) 5 Photoperiod: 16h light, 8h dark

6 Test chamber size: 30mL 7 Test solution volume Nominal15mL 8 renewal of test solutions: Daily

9 Age of test organisms: Less than 24h; and all released within a Bh period

10 No. neonates per test chamber: 11 No. replicate test chambers per 10 concentration: 12 No. neonates per test concentration: 10 13 Feeding regime: Feed 0.1 mL each of YCT and algal suspension per test chamber 14 Cleaning: Use new plastic cups dally 15 Aeration: None 16 Dllutlon water: Housatonic River 17 Test concentrations(%): o. 0, 6.25, 12.5, 25, 50, 75, 100 18 Additional control: 1:1 Lake Champlaln!MHW 19 Test duration: Until 60% or more of surviving control females have three broods (maximum test duration 8 days) 20 Endpoints: Survival and reproduction 21 Test acceptability criteria: 60% or greater survival of all control organisms and an average of 15 or more young per surviving female In the control solutions. 60% of surviving control females must produce three broods 22 Sampling requirements: For off-sHe tests, a minimum ofthrae samples (e.g., collected on days one, three, and five) with a maximum holding time of361l before first use 23 Sample volume required: 11Jday

Tuesday, June 16, 2015 15 Pase I of I 1002.0- Daphnid, C. dubia, Survival and Reproduction Test

ALS Env!roWnental CETIS Summary Report Report Date: 15 Jul-15 11:33 (p 1 of 3) Test Code: 694291 08-8375-8351 Cerlodaphnla 7-d Survival and Reproduction Test Aquatec Biological SclencH, Inc

BalchiD: 02-4397.g893 Test Type: Reprocluct/on-SuiVfval (2-Bd) Analyst John Wllllams Start Date: 18 Jun-1510:65 Protocol: EPA/821/R-02-013 (2002) Diluent Receiving Water Ending Date: 22Jun-15 14:00 Species: Cer!odaphnla dubla Brine: DuraUon: 6d 3h source: In-House Culture Age:

SamplelD: 07-1268-9197 Coda: 14382 Client: GE Pittsfield Sample Date: 15 Jun-15 07:00 Material: Industrial Effluent Project: VVET Quarterly Compllance Test (2Q) Receipt Date: 16 Jun-15 09:00 Sourc:e: NPDES Permit# MA0003891 (GE PmS) samplo Age: 28h StaUon: GE Plttslle!d

Multiple Comparison Summary AnalyslsiD Endpoint Comparfaon Method NOEL LOEL TOEL TU PMSD 14-7031-9728 2d SuiVIval Rate Fisher Exact/Bonferroni-Holm Test 100 >100 n/a n/a 01-4533--3152 6d Survival Rate Fisher Exact/Bonferroni-Holm Test 100 >100 nla nla 04-4569-8563 Reproduction Dunnett Multiple Comparison Test 100 >100 nla 16.9%

Point Estimate Summary Analysis ID Endpoint Point Estimate Method Laval % 95"/• LCL 95%UCL TU 16-3521-6271 2d Survival Rate Unear lnlerpolallan (ICPIN) EC5 >100 nla nla <1 EC10 >100 nfa nla <1 " EC15 >100 n/e nla <1 "../ EC20 >100 nfa nla <1 ../ EC25 >100 nfa nla <1 ../ EC40 >100 nla nla <1 EC50 >100 n/a nla <1 "' 08-9999-2903 Reprodudlan llnear lnt&rpofatlon (ICPIN) IC5 >100 n/a n/a <1 "../ IC1D >100 n/a nla <1 JC15 >100 n/a nla <1 ./"' 1020 >100 nla nfa <1 ./ 1025 >100 nla nfa <1 ./ IC40 >100 n/a n/a <1 1050 >100 nla n/a <1 "

007-372-159·8 CETIS~.9.0.6 Analyst: ~ OA:J/dU CETIS Summary Report Report Date: 15 Jul-1511:33 (p 2 or 3) Test Code: 69429 106-8375-8351 Corfodaphnla 7-d Survival and Reproduction Test Aquatae Biological Sciences, Inc

2d Survival Rate Summary

Cone-"• Code Count Mean 95%LCL 85%UCL Min Max Std Err StdDev CV% %Effect 0 0 10 1.0000 1.0000 1.0000 1.0000 1.0000 0.0000 0.0000 0.00% 0.00% 0 L 10 1.0000 1.0000 1.0000 1.0000 1.0000 0.0000 0.0000 o.oo•.t. 0.00% 6.25 10 1.0000 1.0000 1.0000 1.0000 1.0000 0.0000 0.0000 0.00% 0.00% 12.5 10 1.0000 1.0000 1.0000 1.0000 1.0000 0,0000 0.0000 0.00% 0.00% 25 10 1.0000 1.0000 1.0000 1.0000 1.0000 0.0000 0.0000 0,00% 0.00% 50 10 1.0000 1.0000 1.0000 1.0000 1.0000 0.0000 0.0000 0.00% 0.00% 75 10 1.0000 1.0000 1.0000 1.0000 1.0000 0.0000 0.0000 0.00% 0,00% 100 10 1.0000 1.0000 1.0000 1.0000 1.0000 0.0000 0.0000 0.00% 0.00"..1.

Bd Survival Rate Summary Cone-% Code Count Mean 95% LCL gs,-, UCL Min Max Std Err StdDev CV% %Effect 0 D 10 1.0000 1.0000 1.0000 1.0000 1.0000 0.0000 0.0000 0.00% 0.00% 0 l 10 1.0000 1.0000 1.0000 1.0000 1.0000 0.0000 0.0000 0.00% 0.00% 6.25 10 1.0000 1.0000 1.0000 1.0000 1.0000 0.0000 0.0000 0.00% 0.00% 12.5 10 1.0000 1.0000 1.0000 1.0000 1.0000 0.0000 0.0000 0.00% 0.00% 25 10 1.0000 1.0000 1.0000 1.0000 1.0000 0.0000 0.0000 0.00% 0.00% 50 10 1.0000 1.0000 1.0000 1.0000 1.0000 0.0000 0.0000 0.00% 0.00% 75 10 1.0000 1.0000 1.0000 1.0000 1.0000 0.0000 0.0000 0.00% 0.00% 100 10 1.0000 1.0000 1.0000 1.0000 1.0000 0.0000 0.0000 0.00% 0.00%

Reproduction Summary Cone-% Code Count Mean 115% LCL IJ5%UCL Min Max Std Err Sld Dev CV% %Effect 0 D 10 26.5 22.93 30.07 18 35 1.579 4.994 18.85% 0.00% 0 L 10 32.8 30.96 34.64 29 38 0.8138 2.573 7.85% -23.77% 6.25 10 29.9 27.53 32.27 25 36 1.048 3.315 11 .09% -12.83% 12.5 10 27.2 22.75 31 .65 18 37 1.965 8.215 22.85% -2.64% 25 10 27.5 24.95 30.05 22 33 1.128 3.687 12.97% -3.n% 50 10 28.7 26.91 30.49 24 33 0.7895 2.497 8.70% -8.30% 75 10 30.7 28.49 32.91 28 35 0.9781 3.093 10.07% -15.85% 100 10 27.5 23.9 31 .1 16 34 1.593 5.039 18.32% -3.n%

CETIS'~'~~'tie.0.6 Analyet: d1.J CETIS Summary Report Report Date: 15 Jul-1511;33 (p 3 of 3) Test Code: 694291 011-8375-8351 Corlodaphnla 7-d Survival and Reproduction Test Aquatec Biological Sciences, Inc

2d Survival Rate Detail Cone-% Code Rep1 Rep2 Rop3 Rep4 Rep6 RepS Rep7 RepS Rept Rep10 0 0 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 0 L 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 8.25 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 12.5 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 25 1.0000 1.0000 1,0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 50 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 75 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 100 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000

8d SUC'VIval Rate Detail Cone-% Code Rep1 Rep2 Rep3 Rap4 Rep5 RapS Rap7 Rep B Rep9 Rep10 0 0 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 0 L 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 6.25 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 12.5 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 25 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 50 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1,0000 1.0000 1.0000 1.0000 75 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 100 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000

Reproduction Detail Conc-o/e Coda Rapt Rap2 Rep3 Rep4 RepS RepS Rap7 RepS Rap 8 Rep10 0 0 35 27 27 28 29 28 23 23 16 29 0 L 38 33 33 31 34 33 32 35 29 30 6.25 32 36 29 28 25 30 28 30 ZT 34 12.5 25 25 37 23 24 33 35 30 22 18 25 27 27 28 33 22 31 30 28 22 29 50 30 28 27 27 31 28 33 30 24 29 75 33 33 33 33 27 35 29 26 28 30 100 34 28 24 25 30 ' 30 32 ZT 16 29

007--372-159-8 CETIS111 ~Q9 . 0. 6 Analyst: at.J QA:~ CETIS Analytical Report Report Dat.: 15 Jul-15 11:32 (p 1 of 2) Test Code: f594291 06-3375-8351 Ceriadaphnla 7-d Survival and Reproduction Test Aquatec Biological Sc:lancn, Inc

AnalyalsiD: 0+-4569-8583 Endpoint Reproduction CETIS Veralon: CETISV1.9.0 Analyzed: 15 Jul-15 11:32 Analysis: Parametric-Control va Treatments Offlclal Rnult8: Yes

Datil Tranafonn Alt Hyp Tr1ala Seed TSTb NOEL LOEL TO!L TU PMSD Untransformed C>T n/a n/a n/a 100 >100 n/a 18.9%

Dunnett Multiple Comparison Test Control vs Cone-% Test Stat Critical MSD OF P·TYP• P.Value Declslon(a:&%) Dilution Water 8.25 -1.775 2.342 4.487 18 COF 0.9992 Non-Significant Effect 12.5 .0.3654 2.342 4.487 18 COF 0.9343 Non-Significant Effect 25 .0.522 2.342 4.487 18 COF 0.9551 Non-Significant Effect 50 -1.148 2.342 4.487 18 COF 0.9928 Non-SignlRcant Effect 75 -2.192 2.342 4.487 18 COF 0.9999 Non-Significant Effect 100 .0.522 2.342 4.487 18 COF 0.9551 Non-Signlncant Effect

ANOVATabCe Source Sum Squares Mean Square OF FStat P-Value Oeclslon(a:5'Yo) Between 142.086 23.681 6 1.29 0.2747 Non-Significant Effect Error 1158.2 18.3524 83 Total 1298.29 69

Distributional Testa Attribute Test Teat Stat Critical P-Value Oeclslon(a:1%) Variances Bartlett Equality of Variance Teat 10.68 18.81 0.0993 Equal Variances Distribution Shaplro-WIIk W Normality Test 0.9829 0.9526 0.4563 Normal Distribution

Reproduction Summary Cone-.,. Code Count Mean 95%LCL 96%UCL Median Min Max Std En' CV% %Effect 0 D 10 26.5 22.93 30.07 27.5 16 35 1.579 18.85% 0.00% 6.25 10 29.9 27.53 32.27 29.5 25 36 1.048 11.09% -12.83% 12.5 10 27.2 22.76 31.65 25 18 37 1.!165 22.85% ·2.84% 25 10 27.5 24.95 30.05 27.5 22 33 1.128 12.97% -3.77% 50 10 28.7 28.91 30.49 28.5 24 33 0.'7895 8.70'Yt -8.30% 75 10 30.7 28.49 32.91 31 .5 26 35 0.9781 10.07% ·15.85% 100 10 27.5 23.9 31.1 28.5 16 34 1.593 18.32% -3.77%

Reprodu~on Dotall

Cone··~ Code Rapt Rep2 Rep3 Rep4 Rep5 RepS Rep7 Rep8 Rep9 Rep10 0 0 35 27 27 28 29 28 23 23 16 29 6.25 32 38 29 28 25 30 28 30 . Zl 34 12.5 25 25 37 23 24 33 35 30 22 18 25 27 27 28 33 22 31 30 26 22 29 50 30 28 27 27 31 28 33 30 24 29 75 33 33 33 33 27 35 29 28 28 30 100 34 28 24 25 30 30 32 27 16 29

007-372-159-8 cmswea .9.0.8 Analyst: (]'-' CETIS Analytical Report Report Date: 15Jul-1511:32 (p 2 of 2) Test Code: 694291 06-8375-8351 Cerfodaphnla 7-d Survival and Reproduction Test Aquatic Biological Sc:Jenc:ea, Inc

Analysis ID: 04-4569-8583 Endpoint: Reproduction CETIS Veralon: CETI5v1.9.0 Analyzed: 15 Jul-1511:32 Analyala: Parametrle-Control vs Treatments Official Ruultl: Yes Grapblca

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007-372-159-8 CETIS~~ .9.0.6 Analyst (fV' CETIS Analytical Report Report Date: 15 Jul-15 11:32 (p 1 of 2) Test Coda: 69429 l 06-8375-8351 Cerlodaphnla 7-d Survival and Reproduction Test Aquatac Biological Sciences, Inc

Analysis ID: 16-3521-6271 Endpoint: 2d Survival Rate CETIS Veralon: CETISv1.9.0 Analyzed: 15 Jul-15 11:32 Analysis: Linear lnterpolaUon (ICPIN) Officlill Results: Yes Linear Interpolation Options XTransfonn YTransform Seed Renmples Exp 115% CL Method Log(X+1) Linear 1151568 200 Yes Two-Point Interpolation Point EsUmates Level 95% LCL 95%UCL TU 95%LCL 95%UCL EC5 '"'>100 nla nla <1 n/a n/a EC10 >100 n/a nfa <1 nfa n/a EC15 >100 n/a nla <1 nfa n/a EC20 >100 n/a nla <1 nla n/a EC25 >100 n/a nfa <1 n/a n/a EC40 >100 n/a n/a <1 nla n/a EC50 >100 n/a n/a <1 n/a n/a

2d Survival Rate Summary Calculatad Varlata{AIB) Cone-% Coda Count Mean Min Max StdErr StdDev CV% %Effect A B 0 D 10 1.0000 1.0000 1.0000 0.0000 0.0000 0.00% 0.00% 10 10 6.25 10 1.0000 1.0000 1.0000 0.0000 0.0000 0.00% 0.00% 10 10 12.5 10 1.0000 1.0000 1.0000 0.0000 0.0000 0.00% 0,00% 10 10 25 10 1.0000 1.0000 1.0000 0.0000 0.0000 0.00% 0.00% 10 10 50 10 1.0000 1.0000 1.0000 0.0000 0.0000 0.00% 0.00% 10 10 75 10 1.0000 1.0000 1.0000 0.0000 0.0000 0.00% 0.00% 10 10 100 10 1.0000 1.0000 1.0000 0,0000 0.0000 0.00% 0.00% 10 10 2d Survival Rate Detail Cone-% Code Rep1 Rep2 Rep3 Rop4 Rep5 Rep8 Rep7 Rep8 Rep9 Rep 10 0 D 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 6.25 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 12.5 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 25 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 50 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 75 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 100 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 Graphics

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007-372·169-8 CETIS~.9.0.6 Analyst (11-V CETIS Analytical Report Report Data: 15 Jul-1511:32 (p 2 or 2} Test Code: 8114291 06-837&-8351 Ceriodaphnla7-cl Survival and Reproduction Test Aquatac Biological Sclenca, Inc

Analysis 10: 08-9999-2903 Endpoint: Reproduction CETIS Ve111lon: CET1Sv1 .9.0 Analyzed: 15 Jul-1511:32 Analysis: Linear lnterpolaUon (ICPIN) Official Results: Yea Linear Interpolation OpUons X Transform YTIWISfonn Seed Resamples Exp 9!%CL Method Log(X+1) Linear 30099 200 Yes Two-Point lnterpolaUon

Point Estlmale!l

~vel % 9!1%LCL 95% UCL TU 96-!oLCL 95%UCL IC5 >100 n/a n/a <1 n/a n/a 1010 >100 n/a nla <1 n/a n/a 1015 >100 n/a nla <1 n/a nla 1020 >100 n/a nla <1 nla nla 1025 >100 n/a nla <1 nla nla 1040 >100 n/a n/a <1 nla nla 1050 >100 n/a n/a <1 nla nla Reproduction Summary Calculated Variate Cone-% Code Count Mean Min Max stdErr Std Dev CV% %Effect 0 0 10 26.5 16 35 1.579 4.1194 18.85% 0.00% 6.25 10 211.9 25 36 1.048 3.315 11.09% -12.83% 12.5 10 27.2 18 37 1.985 6.215 22.85% -2.64% 25 10 27.5 22 33 1.128 3.567 12.97% -3.77% 50 10 28.7 24 33 0.7895 2.-497 8.70% -8.30% 75 10 30.7 26 35 0.9781 3.093 10.07% -15.85% 100 10 27.5 16 34 1.5113 5.039 18.32% -3.n% Raproductlon Detail Conc-•.4 Code Rep 1 Rap2 Rep3 Rep4 RepS Rep& Rap7 RepS Rep9 Rtp10 0 D 35 27 27 28 29 28 23 23 18 29 6.25 32 36 29 28 25 30 28 30 27 34 12.5 25 25 37 23 24 33 35 30 22 18 25 27 27 28 33 22 31 30 26 22 29 50 30 28 27 27 31 28 33 30 24 29 75 33 33 33 33 27 35 29 26 28 30 100 34 28 24 25 30 30 32 27 HI 29

Graphics

007-372-159-8 CET1S~~.9 .0.8 Analyst: ;/1tJ CETIS Analytical Report Report Data: 15 Jul-15 11:32 (p 1 of 2) Teat Code: 69429106-8375-8351

Carlodaphnla 7-d Survival and Reproduction Test Aquate~ Biological S~lences, Inc

Analysis ID: 14-7031-9728 Endpoint: 2d Survival Rate ems Version: CETI~v1.9.0 Analyud: 15 Jul-1511:31 Analysis: STP 2x2 Contingency .Tables Offl~lal Results: Yes Data Transform Alt Hyp Trials Seed TSTb NOEL LOEL TOEL TU PMSD Untransformad C>T n/a n/a n/a 100 >100 n/a 1 n/a Fisher Exact/Bonferroni-Holm Test Control vs Group Tes1Stat P-Type P-Valua Daclslon(a:S%) Dilution Water 6.25 1.0000 Exact 1,0000 Non-Significant Effect 12.5 1.0000 Exact 1.0000 Non-Significant Effect 25 1.0000 Exact 1.0000 Non-Significant Effect 50 1.0000 Exact 1.0000 Non-significant Effect 75 1.0000 Exact 1.0000 Non-Signlllcant Effect 100 1.0000 Exact 1.0000 Non-Significant Effect Data summary Cone-% Coda NR R NR+R Prop NR PropR %Effect 0 D 10 0 10 1 0 0.0~ 6.25 10 0 10 1 0 0.0~ 12.5 10 0 10 1 0 0.0~ 25 10 0 10 1 0 0.0% 50 10 0 10 1 0 0.0% 75 10 0 10 1 0 0.0% 100 10 0 10 1 0 0.0% 2d Survival Rate Detail Cone-% Code Rep 1 Rep2 Rep3 Rep4 Rep& Rep& Rep7 RepS Rep9 Rep 10 0 D 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 6.25 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 12.5 1.0000 1.0000 1.0000 1,0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 25 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 50 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 75 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 100 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000

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007·312·159-8 CETIS-Q4t .9.0.6 Analyst tJV CETIS Analytical Report Report Date: 15Jul-1511:32(p 2 of 2) Teat Code: 694291 06·8375-8351 Canodolphnla 7-d Survival and Reproduction ToBt Aquatec Biological Sciences, Inc

Analysis ID: 01-4533-3152 Endpoint: 6d Survival Rate CETIS Vorslon: CETISv1 .9.0 Analyzed: 15 Jul-15 11:32 Anllysls: STP 2x2 Contlngeney Tables Official Re•ults: v.. Data Tran•form AltHyp Trial• SHd TSTb NOEL LOEL TOEL TU PMSD Untranaformed C>T n/a nla n/a 100 >100 n/a 1 nla

Fisher Exaci/Bonferroni-Holm Test ContraI vs Group Teat Stat P·Typa P-Value Declslon{a:6%) Dilution Water 6.25 1.0000 Exact 1.0000 Non-Signlftcant Effect 12.5 1.0000 Exact 1.0000 Non-significant Effect 25 1.0000 Exact 1.0000 Non.Signlftc:ant Effect 50 1.0000 Exact 1.0000 Non-significant Effect 75 1.0000 Exact 1.0000 Non-Signmcant Effect 100 1.0000 Exact 1.0000 Non-Significant Effect

Data Summal)' Cone·% Codo NR R NR+R PropNR PropR %Effect 0 D 10 0 10 1 0 0.0% 6.25 10 0 10 1 0 0.0% 12.5 10 0 10 1 0 0.0% 25 10 0 10 1 0 0.0% 50 10 0 10 1 0 0.0% 75 10 0 10 1 0 0.0% 100 10 0 10 1 0 0.0%

6d Survival Rate Detail Cone-% Code Rep1 Rap2 Rep3 Rep4 RepS Rep& Rep7 RepS Rapt Rep10 0 D 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 6.25 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 12.5 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 25 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 50 1.0000 1,0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 75 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 100 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000

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007-372-159-8 CET1S~61.9.0.6 Analyst

Start Date: 16 Jun-1510:55 Species: Ceriodaphnla dubla Sample Code: 14382 End Date: 22 Jun-1514:00 Protocol: EPN8211R..02.013 (2002) Sample Source: NPOES Pennlt f MA0003891 Sample Date: 15 Jun-15 07:00 Material: Industrial Effluent Sample Station: GE Pittsfield

I i I Con~% Code . Rep Pos I &posed I ,d Surv I 2d Surv 3dSUrv 4dSitrV Sd&lrv i 6dS ~~ NfcM6w 8d Surt i 2d Neo 3dNeo Cd Neo ! Sci Neo &dNeo d~ 0 0 1 26 1 1 ! , . 1 r;; 2 r 0 11 22 ' ' I 0 . D i 1 t 1 1 c 2 7 0 18 2 4 . i _!_ 0 0 3 46 1 ; 1 I 1 (i I 0 4 9 I 14 I ' ' I 0 D 4 23 1 1 1 ~ 4 8 ! 0 16 I 0 1 4 I 5 16 0 5 148 1 l 1 I ~ 4 r;; 0 0 6 41 1 1 1 J 3 0 11 14 I 0 0 7 : 65 1 ' 1 I 1 c 5 I 0 8 10 0 D 8 66 1 1 1. (I l 4 4 0 15 0 D 9 6 1 1 1 (I 3 0 9 4 1 (I 5 0 12 0 0 10 2 1 I 1 I 12 0 L 1 19 1 1 1 (I ' 5 10 1 22 I f 0 L 2 54 1 1 ! 1 Cl 7 0 12 14 ~ 0 L 3 58 1 1 1 c 4 0 13 16 0 L 4 57 1 1 1 (I 5 8 0 18 I 0 . L 5 34 1 1 1 (I 5 11 0 18 i ! ' 0 L 6 3 1 1 I 1 c 6 10 0 I 17 i I 0 L 7 68 1 1 1 (I 6 5 0 21 0 L 8 45 1 : 1 1 0 5 11 0 ! 19 0 L 9 28 1 1 1 Cl 5 9 0 15 0 L 10 53 1 I 1 1 (I 2 0 14 I 14 8 .25 1 9 1 1 1 (l 5 7 0 20 6.25 2 50 1 1 1 (I 2. 0 15 19 6.25 3 43 1 1 1 c 3 0 12 14 6.25 4 35 1 1 1• 0 4 6 0 18 6.25 5 59 1 1 1 (I 6 4 0 15 6.25 6 62 1 1 i 1 c 4 10 0 16 6.25 7 74 1 1 1 ( 4 6 0 18 6 .25 8 27 1 1 I 1 ( 4 0 14 12 6.25 9 39 1 1 1 c 3 8 0 16 6.25 10 31 1 1 1 c 5 0 14 15 . - - - - ·L··av ~·:'7ht.ur CETIS Test Data Worksheet Report Date: 15 Jul-1511:31 (p2 of 3) Test Code/10• 06-8375-8351/69429 ' Cone-% Code ' Rip ! Pos #Exposed ! 1d surv 2d lkKv :ldSurv <4d Surv 5d8urv IdS Jrvlc NieMI trY ld surv ZdNco 3dNeo <4d Neo 1 6d Neo 6dNeo dNI 12.5 1 . 69 1 1 1 0 1 6 • 0 18 2 1 12.5 16 1 1 0 I 2 8 ! 0 ! 15 i 3 '73 (I I 12.5 1 1 : 1 I 8 i 0 15 16 I 12.5 4 63 1 : 1 1i (f ' 5 3 0 15 ~ D 12.5 5 • 61 1 1 I 1!• 5 5 0 14 ' 12.5 6 70 1 1 t 1; D. 4 10 0 19 12.5 7 . 72 1 . I 1 t: [) 4 1 14 16 ~ ' i ; . 12.5 8 i 7 1 I 1 : •' 1: ~ 4 8 0 18 ! 12.5 9 _j 77 1 J 1 ! 1! q 4 5 0 13 12.5 10 ! 1 1 • I 1 i t! a 5 0 13 0 1 ; 15 1 1 I 11 3 8 0 16 25 ! I c I 25 1 1 c 5 3 4 15 I 2 33 1 I ! 25 3 8 1 I 1 1 0 4 0 1 12 12 l 25 4 67 1 J 1 1 (J 4 13 16 I !' 0 1 1 l (J 6 3 I 0 13 25 5 52 1 I ' 1 25 6 5 1 1 1 (] : 4 11 0 16 ~ 25 7 22 1 1 1 (] 3 10 0 17 ! ' 25 8 18 1 1 1 (J 5 8 0 ' 13 ' I 25 9 55 1 1 ' f ' (J ~ 4 3 1 . 14 j 25 ; 1(1 47 1 1 I 1 ( 4 0 13 • 12 50 1 80 1 1 I 1 ( 5 8 0 17 50 2 71 1 1 1 ( . j 5 7 0 16 0 0 10 I 50 3 29 1 1 1 3 I 14 • 50 4 30 1 1 1 (J 4 0 11 12 ! . ( 50 5 54 1 1 1 4 4 7 16 : 50 6 ; 36 1 : 1 ' 1 ( i 4 2 10 12 50 7 112 1 1 11 ( 6 0 10 17 50 8 14 1 1 1! ( 4 8 0 18 50 9 21 1 1 I 1, ( 5 5 0 1.( . I 50 10 78 1 i 1 • 1 ( 3 2 12 12 75 1 13 1 I 1 1 c 4 0 13 16 75 2 79 1 1 1 ( 5 B . 1 19 75 3 25 1 1 1 c 3 0 ' 14 16 I 75 4 24 1 1 1 (] 5 0 11 17 (}::!. : '7bl..il.~ CETIS Test Data Worksheet Report Date: 15 JuJ.1511:31 (p 3of 3) Test Code/10: D6-8375-83511S9429

cane·% Code! Ret~ PO$ • ExDOHd I 1d &urv 2d surv :sdSurv 4cl Surv ~ 5d Surv SciS lrvSil NldBI lw ldsurv 2dNeo 3dNea AdN.o Sci Neo ! 5d Neo d ... 75 5 <42 1 ! 1 : 1 c 6 6 0 I 15 75 6 76 1 I 1 (] 13 I 17 1 l 5 0 ! 75 7 60 1 L 1 '• 1• 0 4 0 10 15 ' . ! 75 8 38 l 1 Oi 6 6 0 . 1 I 1! I 14 I 75 9 32 1 I 1 1 0 3 7 3 15 ' 75 10 37 1 . 1 t 1, c 4 0 13 13 I 100 1 11 1 1 1! ( 4 2 9 19 ' ! I ! 100 2 51 1 'j 1 1 c 2 0 11 15 100 3 17 1 1 1 c 2 0 9 13 100 4 44 1 1 1• ( 2 · o 9 14 100 5 75 1 1 l 1! ( 5 0 10 15 100 8 49 1 1 1· c 6 0 8 16 I ~ 100 7 56 1 1 1' c I 5 0 12 15 • l I 100 8 20 1 1 1 c .. I 8 0 15 I . I I ! 100 9 10 1 1 I 11 c 3 0 13 0 ; 100 10 40 1 1 1 c 5 0 13 11 N . CD

007·372-159-8 CEllS"' v1.9.0.6 Analyst~ Qk~ Project: GE Pittsfield NPDES Permit No. MA0003891 Pipe No. 1 ·········································-··········-··············· ················--········-·····················-··············································-···················-·· 1002.0 Daphnid, C. dubia, Survival and Reproduction Test Species: Ceriodaphnia dub/a Reference: EPA-821-R-02-013 SOP: TOX2-002 ··············-·························- ···································-············-···································································································· TOXICilYTEST DATA: Test 10: 69429 % Effluent Rep. Day 0 Day 1 Day 2 Day 3 Day 4 Day 5 Day 6 Day 7 0% 1 Lab CTRL 2 3 4 5 6 7 8 9 10 0 - 0 --1\ 0% 6- r--o-- ...... ,_ -· :;2...- 1 t--···· · · 1- --::- ~-- · 2 -·7r - ··- Receiving 3 o --·% -- _g_ - t-- -··1-- + --_ 1'1 _ _g_ - ' ··- - iJ"- 1---:,:>-- 4 f-_JL_- .Q__ D . · _ _lQ _ _ 0 __ I I) _ 1-----1 5 1-0...... o _Q '-'" 4' s 1 ~ 6 L-.• 0_ - -()-- 0 - ~ -· ·- n I\ I '( -· ··- ,-- 0 f-· ~- - 7 - -c;- s 8 ~-- -o- -·- o T -· · ! -~ Y.~- ~- - 9 ~ - -o- _0 ~ - 0 ~ - --q- r-- ·- 10 0 ___o _ ___ ··· o_ _ ~ -~ r~ __/l. - - -·· 6.25% 1 - (i" - r--t? .. _ - 0 ~ t--3:- ~- l.J.j - -- 2 Effluent 3 _J_ . -1-- ~~ ·- ~.t .._: -~ ~+1 · - r · J;~ .--- 4 0 _ .£._ n !.f .. ~ --· .~ E._ 1-----1 5 --Jl.- o -~ ~ •. Lot c _ ./S.- t----t 6 . JL_ ~-~ - .. o L 'L- •o _. o 1_7i_ -····-··- 7 ~ .·. ,- 0 0 r 4 ·-- & Q J~ .----::-- -- o -Q ... ~ . .:;t-- i-f·'- -LI-1!..z:.-- 8 .• _.!>____ 0 --···-r- ~ - " . u - '"f - .:.-r- ---·-- 9 ~--- · b·-- 0 --~-- ~ --- ~0 - ib - - 10 .... _9 - __.(2 - _Q__ \ t.t - - ~ 12.5% 1 _..!L _ o - cf ·- ,__J__.... -ro u q - 2 Effluent 0 --~- ~~ 3 -9.. ... ····-*- -- g r-\1i:- - ·- ·- fs- --'fl,- -~--- 4 . __ .JL_ ~ -. ·- ...JL... ~ _ .3_ -· 00 - ..(.~ ,--·· ··- 5 ··· 0 '-· _o_ ~-- ~ _$.. - · 0 --1~r- 6 ,__- -~ ~ !~- 1'-t 7 --%------.. .. -- -g----=---- - .-.-,- "J""7-- .. - 8 __Q__ __ g.. _ ~ -- - ~ .- -~ ~-- 11'l- ····- 9 0 __Q__o o··- o ~ - C:i- J~ ~) r--- ·- 10 - .. L-...S! ••• _ ~ - - ~- Sample No. Fed: Renewal (D!T/1)

0 = Original organism surviving, No young; D • Original organism dead; f • Number young released; • • Lab-lnducad mortality Aquatec Biological Sclen;zs, Inc. SOG: 14382 Reviewed by: (JJ 2iate: t.ft C . Project 15014 Project: GE Pittsfield NPDES Permit No. MA0003891 Pipe No. 1

.. .~_,...... ·- 0. ·. 0.-.... -····.-- ... 0 . .· -·. ... -. ·. .- ...... · .-----. -. - .• . .• ...... -~ .....· ----·-- 0.... . 0...... 0...·--...... ~ •·-.-.. ' . . .• ...... ~ .-----...... 0.. .. -... .-- . -·..- . . .. . p . ...- .. 1002.0 Daphnid, C. dubia, Survival and Reproduction Test Species: Cerlodaphnia dub/a Reference: EPA-821-R-02-013 SOP: TOX2-002

I ooo oo o o o oooo •• • • o• t • o oooooooo o ' " ' oo oo o '''' "'' ' ••••••• o o ooooo • · ••••••• ttoooo•oo o • ••••••• O' • • o ••• o• o o •• .o.a.ooo •••••• ••• .ooeot"o o.o ••••• •• • , • ..,,,. ..,,,,,.,.., , ··--·-.-. ·-· - .. ---·---·------~- TOXICITY TEST DATA CONTINUED: Test ID: 89429 %Effluent Rep. Day 0 Day1 Day4 Day 6 Day7 25 % 1 Effluent 2 3 4 5 6 7 B 9 10 50% 1 2 Effluent 3 4 5 6 7 8 9 10 75 % 1 2 Effluent 3 4 5 6 7 8 9 10 100 % 1 2 Effluent 3 4 5 6 7 8 9 10 Sample No. Fed: Renewal (Dfr/1)

YCT Lot Number: _0{519/S y_c_ ___ Selenastrum Lot Number: • Ole/JJS Se/ __ _

0 =Original organism suMvlng, No young; 0 • Orfglnal organism dead;# • Number young released; •,.. Lab-Induced morta!Ky Aquatec Biological Sclencellnc. SOG: 14382 Reviewed by: OV ~te: 'r4pt(. ProJect: 15014 Documentation of Collection of Ceriodaphnia dubla

Culture Date I Time I lnlt Date I Time /lnit Number of Cups Fod VC I Selenastrurn 10 Cleared of Neonates Neonate Collection Collected (Lot ll's)

,c~ ..,..""~ ~7f,.;;Jr::tn.... '"" . u/Js/15 11'/S tP uhsl;(\ Jr. '3D IU' 1..!::k_ V D~IIISSe} _t;)J51I5 I laS ( 34 ') t'1lblnJ5l3tJ ~ ~t/ls);s IIP'3S k - ./ 05/CJISJC

Project Doscrlplion I ·re!>t U sc:--.:G-..ufi"'-....:P,.:..;,u;m~il..lfi~.~oah...... ,il------

'"eut~ale :.:. colh:cted must number at lenst eight per cup. ond be from a healthy adult female.

31 Project: GE Pittsfield NPDES Permit No. MA0003891 Pipe No. 1 - .. ····-·· .-...... ·...... --.. '.. ... - ·- .-... --. ··-- · ...·. -...... ·----- ...... ···-·...... -. ..-.. -·· ...·--...... - ...... - . .·.. - ....---...... ·...... -··-. 1002.0 Daphnidl C. dubia, Survival and Reproduction Test Species: Cerlodaphnla dub/a Reference: EPA-821-R-02-013 SOP: TOX2-002 ...... ······ ...... ······ ...... ······ -··· ··· ...... ······ ...... - ·- - ·--·- - · - · ·- ---·------·--- INITIAL CHEMISTRY DATA: Test 10: &9429 % Effluent Analysis [Day D @ay 2j [ oa£[] r Day4j []ay 5 1L~ay sl O?.!l. u ~

0% ~._L ~pHDO: ~ ...2.9_.. ~=d_~ :f.~~ -=l_ ~r=_±; L._. l_~~. ,1.. T i_d 10 ?Jt:S. Lab CTRL Tem_L _ (p . 1 ,£~ ~. ~- ~" • \£ "]..te .. s- ,,., Cond_. ~Z. . 2 70 ~·"" \SO . ~ '1.-3!1 ·1,.4. "'\- ~ pH _71l_ 7~ ~ .. \ _I 0% ~ DO_-~-~ _E.~ 7_!f._ ~ 1-.~ ~:t 8~ 0 _Temp._ _ ?5.?- 15~ 1.£,"'- ~(,.'t- . ~,t:t- ~.0 - - Receiving ~-- · - ~~~ - ~~~~r~ ·,~lp- Cond... _ Z.lg tf -.,....~-- u::!!'.:: VJ? c;· - 'I) .. 1. 6.25% __:_ - -- DO r,J .Q [li:1- ---·.::...... - . --··-- ~1-~; . ~-~·tJ_8.~ Temp. 1S..7_ . ~s ,'\- 1.-C... '-l •3 1.-S: 0 Effluent ~PH~[~=ll - · - r-·-·- Cond. z.ql · 33 {, "Jb.Cf 0 ~- ~ ~ ~ .3 . 12.5% -·- DO f.o {, .. (, ;J~o~ -:+--~e-~·- ~~g.. 0 u_ -·1·· '- ··-=- - U.\ Effluent emp.. .. 7: .z.r. ~ ~"~- 1.--if.~ '2-'t."' ~pl~~mrCond. _JU(L_ ,~ 'tS.L 31B l~~ _ 5S l 'T~ ·r 25 % {,.(9 r--DO __ ~ • 0 :3:.~ ft_ ~'+ ~ - (J =-pHTemp~. ~~~~lSlP '1.'»•\) '1..-C.t.,'\ ~ ,'t 1.S'. 0 Effluent ---=--- .=-:. ·-·-·- ~-0~~~~- f-- Cond. ._ S1tl. . ill_ ~ - -~~ t.t8q ' ~ pH t.~ 50% -·- ·- -- ~. DO ... ~~ ~tJ.o - - _k.~ _Temp _,_. ZS.lP- 1 5"'. ~ '1,.$"'. 0 1.h ~ \ Vt .-s- 1..'S • Effluent - -- ~- · - Con d. . '7~3. \03~ }.~m~~_1-a.t "t 1 S' ' 8.!1_ • ~.~ 75 % 2.. . _j\1_. .i:!_ s _o 1!1. ..1.~L lt..~ ~" ·L- :±j;""""~ 't. +--~. mp. _ ].Sll ~~'Vt 1> . '\ 1,.\..\ • 1.. 'l.S • g Effluent JS..£. ·'l ·---- ·- ~~~~ - ~105~~-- otf !\~..: tooq ~ Jooct

100% - ·- ...... ,; ~ - L !l.(Q -:, ~ Temp. 5 lJ' z.c; ,{, v-t.~S _kS~.o~lj·, u OZ.:_2 ~·m~ • "! ~ Effluent 6~~ - ~r~~E i~ ~ CornL I 'tJ_ zft ;o~ a ..Lf-.3:..L ~ t-\fo.'ll!>1 4 L f s'~ 4L 9~ El ~te ~ ~ t). t; - i(i.LUhS hi1~iJ~~~Initials __]£_ _ ec,. _ ~~ ~::~_: ~~ ~ NOTES:

Aquatec Biological Sclencps! Inc. SOG: 14382 Reviewed by: d,J ~te : 7f"'t..1( Project 15014 Project: GE Pittsfield NPDES 1 .. Permit No. MA0003B91 Pipe No. ------o o • • • o • • • • • • • • •· - o o -o - • • •-- o • -•-• • o- • ---o o o • ' o I • • • • • o______o • •• o 0 • • • • • •• o p e • • • o • • • ••• ~ o ooo___ o • • • • • o • • o • • o o o • • • • • • • • • • ••------• o • • • , o. o • • 0 • o • ~ • • • 0 ,. ., •o ... • o • • o o • o ,.._,. •, o o o o • • • • • ••• 1002.0 Daphnid, C. dubia, Survival and Reproduction Test Species: Cerlodsphnia dubia Reference: EPA-821-R-02-013 SOP: TOX2-002 ' •------• o • • o • • • •• o •• • • •• • ' • • • • • • • • • • • • • • • ------• • • o • ' • • • • • •'" • •• • • • • • • • • • ••• • ••••·----·-• • • • • • • • •• • • o • • o o •• • r • • • -• ---• • •• • • • •• • •• o • • •• • • - ~ ·· • • • • • • • ' " • o "' '" •• o • • • • • o • ...... + ' • -o FINAL CHEMISTRY DATA: Teat ID: &9419 % Effluent Analysis [Day 1] [pay 2 I[DaY[] [Day 'D [Jiay~ [Day 611DaYfl .--1

0% _Q_O_ ~~ ~ .:b~ . 1--- ~- Temp. 'l-~~ ZS. ~ "1. 5'. ~ 1..'> :l._ Lab CTRL ~pH~~~~g ~~~r . Cond. CJ 0 zrfr_ 14.3_ (S"' ...a _ ~~~·z.~ 3 0% DO . 0 7.~ 'l" o '7 t ._ ~ • 1. 'l:J. Receiving llpH~~,~~~ooTem~ ~. ~ -. u. ·o T~;~~~ ZS.3 Cond. ~ ~ ~ . _ \ . ·\ 8 '"{ . ~..ll.

6.25% ~- Q_ . DC?_. 1'1. ~ . -~ '1.3 1·0 'h~ 1·\ 7 rTemp --~. 1$· 0 Effluent }·'- ~!~ ?S -t,! ~ Z52- -- Cond~- .~ (,_!...._ ~m~~~~~~ 12.5% - ·- DO "+~ ~·2-,_?S ~-t-~~"s~~~~ · · -' . T_:l 1...3= \ - ~~ ,.(.\ _ffi,IJ?_ _ts"..J2.. 2,'(. ~ -~ .~ Effluent Tern~ - ·--- Cond.--- r8'L._ --~5... ~- ~~ M.. pH 25% - ·'- -DO·- .~ ~~ ~~ ~~ '2- - _3.-.. 1:-_ ...2.':L - Temp. ~~~~~g.~~ ~§ Effluent t- ~~-s .\- ·-' ~IL t.~. o '"Z)J{.. 9 .J;-l\ '~- . . _ Con d. -1~ .. _ . Soj_ q. ~~ ~ P.!L.. ·- ·- ·- &.. \ -· - _....;:. ____ 50% --~- - ~pHDO 3._:-.iL m~~-!!·U~1 .'l ~"1- -0-~-·:t· '2.- - Temp.- -· __- Effluent ,.< ·...2-. ~ """"i1:1_ ._ 1- t.t • ~ 1.~ '3 • Con d. -- ...Jlll:.... 1- 1-(, ~ l':U l-5" 61 ~~ ~ .q t, e. s . s. 75 % -- r-~- - - -· ..'.:£ ~--,--- ~5 -~ ~~--- ·-- --_i_. ~ - . -m~:=J-i_ .b . ~- ~~- 1-·?.f Temp. ~~ · 0 Z5.lJ L .q ~ 1J.t, 3 zs.~ Effluent - ·------z..lf.- Cond. ~ ~ _981 '). f.\ u~ '\~l 959_ t~ 100% ~pHDO _~r .3_.- _~~~=\- ?, ~~=7 • l Effluent Temp. 1.-~ • a z.+.S ~· '\: _ffi.S -- \\.S\ Jl _ ~- - llo liJ J.!..lS_ J[J\1- ~~~~~-

NOTES:

Aquatec Biological Sclencl lnt SDG: 14382 Reviewed by: ()'d 3iate: ir1' 'f". Project: 15014 Aquatec Biological Sciences, Inc. SDG: 14382 Project: 15007 273 Commerce Street Williston, VT 05495 Tel: (802) 860 -1638 Fax: (802) 658- 3189 ...... _...... - ..- ...... -.-·-····-···· MarionWWTP Tel: (774) 263-3083 50 Benson Brook Rd. Fax: (508)748-3864

...... Marion, MA 02738 E-Mail:...... fcooper@marfonma...... gov ALKALINITY AND HARDNESS ANALYSIS

Sample 10: Analysis Date: Alkalinity: Hardness: (mgll) (mgll)

46932 MarionWWTP 6/16/2015 372.0 370.0 46933 Brook to Aucott Cove 6/16/2015 68.0 76.0 46942 Outfall Composite (64G-A-10289) 6/18/2015 376.0 370.0 46943 Housatonic River (Al0290R} 6/18/2015 56.0 60.0 46953 Outfall Composite 64G-A10291 6/20/2015 380.0 360.0 46954 Housatonic River A10292R 6/20/2015 72.0 74.0

TOTAL RESIDUAL CHLORINE (TRC) ANALYSIS

SampleiD: Analysis Date: TRC: Dechlorinated (mgll) (YJN)

46930 Outfall Composite {64G-A10287) 6/16/2015 0.02 N

46942 Outfall Composite (64G-A-10289) 6/18/2015 0.02 N

NOTES: Y =The sample(s) was dechlorinated with sodium thiosulfate before use In toxicity tests. N = Dechlorination was not necessary.

Page 1 of1 34 Reviewed by: ~ Date: ,jrti (" . -- ~· Aquatec Biological Sciences, Inc. 273 Commerce Street Williston, VT 05495 Tel: (802) 860- 1638 Fax: (802) 658 • 3189

.... _. . ._. ...._. . ..._...-...... -- ··· ~- ...-..--. ·-- ...•.- ~ ··-·· · - ·~--- -·-··· ·-·-·-·-···- ...... ~ - · ...... - -·--··- .... .--...... --. . .-...... --...... -..-.-...... ------...... · ALS Environmental Tel: (585} 672-7470 1565 Jefferson Road Fax: Building 300, Suite 360 Rochester, NY 14623 E-Mail: :.:.....:.:...... :.· .:...;..·· ~· · .. ·- · ·.:.;..:.....;~~~::.:.;.:.:;;.·.:.:..:,._· · ~ -~-·~--~:.:.:.:..:::..::.:.:.:::.:. ·. :;,;:;,:,;:.:.:~··~ -..;:.;,: -···- .. ···· ···· ·· · -·· ·· ···-~:..:.::.:.~· · --· .. ··················· ... ---· Project: GE Pittsfield NPDES Permit No. MA0003891 Pipe No. 1

SAMPLE PREPARATION: _§econd SamP.~ - ,....---Third Sa_m_,_p_le ___ .--·------. ·---·---EFFLUENT RECEIVING EFFLUENT RECEIVING LAB CONTROL (,942- 4t,'tSj j_(,9)'4 60 Micron o/ 60 Micron v N I A ---If------+----- N/A --+---·---1------1 N/A --·-1-·---+-·------1 N/A ----·1------+------t--,---i------1 Original/Final- -- - - N/A N/A N/A N/A Salinity: -·-J.-----·-+------1 N/A N/A N/A N/A FF Lot No _____ ,______~ ate I Initials: tDI~\\s 1, ----(j\/--

(1) Record vol. 0.025 N sodium thiosulfate to dechlorinate 100ml sample or record "ND" (Not Detected) (2) Dechlorination required If detected. Record val. 0.25 N sodium thiosulfate added per gallon effluent.

Aquatec Biological Sclen:_er;,'"f: ./ SDG: 14382 Reviewed by: ~te:~. Project: 15014 Standard Reference Toxicant Control Charts ~dubt. C~dubla Rehr.nce ConiiOI Chart fDf NaCI Acuta TOidclty Relennca CDntrol Clwt b NaCI Cllronlc TCilliclty baed on ret~!Difucllon

TKI Test LCSO C&lculllld llmlls Tat Test IC-21 Mean cilCu~ated llmltl ---·-cv of per Ava. Repro. Avg. Hutnbw Oatil 191LI I.C50 UP I!!,! Low.r ::Humber Date (giL} IC.:l5 uee•r l.oOIIw teatiC15 cv PMSO('J.l PMSO('J.I 1 812MU/22113 2.1115 --Z,2Q 1 812M3-8128f13 0.325 0,33 2t.2 2 WZCIIS.1112!11J 2.319 2.26 2.43 2..08 z 9n4113-ltt30N3 1.021 O.S7 1.88 ..0.31 0.48 0.48 11 21.2 3 11!1221'1S.1DI24113 2.4a 2.S2 2.58 2.111 3 11!1221'1S.10121113 0.557 0.83 1.34 ..0.07 CUI4 0.511 2UI 18.1 4 u111t1s.t1m13 2.311 2.32 %.53 2.11 4 111511S.11112113 0.815 0.83 1.21 O.DS IIA7 11.53 15.1 111.3 5 1V411S.12/Ill13 2.4a 2.3:1 2.58 2.13 5 121411 3-1211M3 0.724 OJl5 1.18 0.14 0.35 0.49 10.2 17.5 8 tn/14-119114 2.311 2.34 2.53 2.15 8 tnl14-11i3114 O.tr7 OJI9 1.17 0.20 0.28 OM 14.5 111.1 7 2J4114-m114 2.318 2.34 2.&1 2.16 7 214114-211 M4 UJ12 0.74 1.27 0.21 0.211 0A1 11.74 15.8 II 3111114-3113114 2.342 2.34 2.Sll 2.11 8 3111114-3118114 o.sa:; 0.72 1.23 0.21 0.43 0.41 1z.7 14.11 t 418/14-4111lt14 2.4011 2.35 2.51 2.19 9 418114-4116114 0.569 0.70 1.19 0.22 0.43 OA2 14.5 14.7 10 !lrZB/14-&»'14 2.484 2.38 %.S3 2.19 10 S/4al14.e/3114 0.7311 0.71 1.18 IUS 0.31 OAO 1.18 1U 1\ 7115114-7117114 2.401 2.38 2.&3 2.20 11 7115114-7121114 1.141 0.75 1.211 0.24 0.22 0.39 12.5 14.1 12 81Uit1~1114 2.484 2.37 2.54 2.21 12 811111~4 OJIT 0.77 1.27 Q.26 D.28 0.37 11.1 13JI 13 IW/14-8111114 2.147 2.:15 2.58 2.16 13 llllll14-9118114 0 .450 0.74 1.25 0.23 D.58 0.39 24.1 14.3 14 1017114-1019114 2.257 U5 1.55 !.15 14 100114-10113114 0.469 0.72 1.23 0.21 D.55 OAO 40.2 16.0 15 11111114-11113114 2.414 2.38 2.58 2.15 16 11111114-111171t4 0.817 0.72 1.21 0.22 0.40 0.40 22.2 18.8 111 121111114-12118/14 2.257 2.35 2.58 2.15 16 12118114-1.2122114 0.208 0.611 1.23 0.14 1.30 OAB 48.9 17.2 17 1MnS.111115 2.!00 2.311 2.57 2.111 17 1/1111$.1113115 1.227 0.72 1.30 0.13 0.24 0.45 8D.1 18.1 18 41Z111~5 2.115 2.35 2.58 2.13 18 4/l1115-41281t5 o.et 0.73 1.30 0.1& 0.:12 OA4 23.9 215 111 51111/is.a/21115 :uJ83 2.33 2.58 2.08 19 !118115-5125115 0.7131 0.73 1.21 0.17 0.35 0.44 40.7 21.8 ZD Mltl$.11111115 2.450 2.34 2.58 2.10 20 lillltt~B/15 0.52 0.72 1.27 0.11 0.53 0.44 111.1 22.4 Ocvutt.m. 5oun:e: Aqu-~ Scletlcn,lnc..ln.tlou.. cullures Oopnisnle Source: AqUalllc: Blologlclll Sc:leftCH, Inc. IMtau&e cullurH !Reference Control Chart! Reference COntrol Chart! c:ndlplrio-~IC25 -·.I C!!l!!!pl!!! --u:6ll :l25ll ·~r------,.. u . ' ..& & ... .., , A ... _ -...... _ _ .,. __..,. ·--6- ... _. .. It ·-· ·- ~- ...... ~ - .-& ~ ... It z.Jia .. - --.r·· w t.1 ...... It ,...... " • • " u • -I • " • r i Ill i- j X u X II z '1.7111 u 1.sll ...- ,_...-...... --•-··o- ..... ----.. -•., ...II .. ·-.--__... .-- D.1 .- 1.2511 , .•~ ·

~1 • t~L------~------~1 2 2 4 s • f 1 • ,~... ft o a ~ ~ ~ ~ u w a 3 4 S I 7 I I 1011 13U141i1G11.8211 _ Tal-

I " 1.1* ---IJ:M --u..ertw --~Ud I [ X ~ ---~ --"""'IJd _.._u.tl ~

Assessment of tilt precision a.nciMrai!Mty: The averap CV of per-test ICS w!UM was near the 75th Qlla1'111e (0.41 presented In Table 3-2 of EPA 833-11.()().0()3) lndlatlnuorne vatlablllly or IClS valuiJ Nported for these tests. The per-tut PMSO values were less than the EPA upper lmlt ol4~ lndlcatlna a.capbbte WIW!IIIty of test 11m. The cumulative avvap PMSO nlua -re near the EPA lower boundil'f (mfL llldicallnc ~UHnoderate st31btlcal $a!SitMtyfot this tm IIICihod whalaveraced for the most recent 20 I2SIS.

~ lillie dw'Ocllc SRT h*ldlng r:v llld PMSD APPENDIX2

Laboratory Reports

ALS-Rochester V eolia, Inc. ALS Group VSA, Corp. dba ALS Environmental Analytic:al Report Client: General Electric Company Service Request: Rl 504743 Project: GE-Pinsficld NPDES Chronic Biomonitoring/Day I Date Collected: 6/15/15 0700 Sample Matrix: Water Date Received: 6/16/1 5

Sample Na~ne: 64G-A10287 Lab Code: RIS04743-003 Basis: NA

General Chemistry Parameters

Dilution Date Date Analyte Name Method Re1ult Q Units MRL Factor Extracted Analyzed Note Alkalinity, Total as CaC03 SM2320 4l0 mg/L 2.0 NA 6122/IS lO:lS B-1997(201 I) Ammonia as Nitrogen, undistilled 350.1 0.050 u mg,IL 0.050 NA 6119/IS 15:47 Carbon, Total Organic (TOC) SMSJJO 5.5 mg/L 1.0 NA 6124/1 s 22:40 C-2000(2011) Solids, Total SM2S40 694 mgiL 10 NA 6122115 II :28 B-1997('2011) Solids, Total Dissolved (TDS) SM2S40 637 mgiL 10 NA 6118/JS 09:25 C-1997('2011)

Prlnced 7niiS 10:04 Fonn lA

\lalprcwsOOI\slarlbnsS\LIMSRcpJ\AnalytkaiRcpon.rpt SupcJS~tltcfcrcnec; 15.00DO)l6UO rev 00 ALS Group USA, Corp. dba ALS Environmental Analytical Report Client: General Electric Company Service Reqaat: R I 504743 Project: GE-Pittsficld NPDES Chronic Biomonitoring/Day 1 Date Collected: 6/15/JS 0700 Sample Matrix: Water Date Received: 6it6/15 Sample Name: 640-A 10287TM Lab Code: RJ504743.001 Basis: NA

lnoJ'ianlc Parameters

Dilution Date Date Analyte Name Method Result Q Uaits MRL MDL Factor Extracted Analyzed Note Aluminum, Total 200.7 0.10 u mgiL 0.10 0.03 6/17/15 6124/IS 21:51 Cadmium, Total 200.8 0.0010 u mfiL 0.0010 0.00003 6/18/IS 612211 s 19:05 Copper, Total 200.8 0.0016 B m&fL 0.0010 0.0002 6/18/I.S 612211!1 19:05 Lead, Total 200.8 0.0010 u mg/L 0.0010 0.0003 6118m 612211519:05 Nickel, Total 200.8 0.0015 mg/L 0.0010 0.00006 6118/IS 612211 s 19:0!1 Zinc, Total 200.8 0.0050 u mg/L 0.0050 0.0012 6118115 6122115 19:0.S

Prinled 1n!U 10:04 Fonn lA aa:e·es SuperScl Rcfc~ 1~16111- 00 ALS Group USA, Corp. dba ALS Environmental Analytical Report Client: General Electric Company Service Request: Rl504743 Project: GE-P ittsfield NPDES Chronic Biomonitoring/Day I Date Collected: 6/IS/15 os'so Sample Matrix: Water Date Received: 6/16/IS Sample Name: Al0288R Lab Code: Rl504743-004 Basis: NA

General Chemistry Parameters

Dilution Date Date Analyte Name Method Result Q UnUs MRL Factor Extracted Analyzed Note Alkalinity, Total as CaC03 SM2320 84.0 mg/1.. 2.0 NA 6122/IS 10:15 B-1997{2011) Ammonia as Nitrogen, undislillc:d 3SO.l 0.050 u mg/L 0.050 NA 6/19/IS 15:49 Carbon, Total Organic (TOC) SM.SJIO 6.3 mgiL 1.0 NA 6124/IS 23:01 C-2000(201 I) - Solids, Total SM2S40 144 mg/L 10 NA 6122/1 s 11;28 0·1997(201 I) Solids, Total Dissolved (TDS) SM2S40 99 mg/L 10 NA 6/18/tS 09:25 vi997{20IJ)

Printed 7n/IS 10:04 Form lA

\\alpre~~>aOO l \stallirnsS\l.IMSRqn\AnalyticalRepon rpt SapcrSct Refcmocc: l$.0000336110 rev 00 ALS Group USA, Corp. dba ALS Environmental Anafytic:al Report Client: General Electric Company Service Request: RJS04743 Project: GE·Pittsfield NPDES Chronic 9iomonitoring/Day I Date Colleeted: 6/lS/1 S 0850 Sample Matrix: Water Date Received: 6116/1 S Sample Name: AI0288RTM Lab Code: RIS04743·002 Basis: NA

lnOf'i•nic: Parameters

Dilution Date Date Analyte Nante Method Res•lt Q Units MRL MDL Faetor Extracted Analyzed Note Aluminum, Total 200.7 0.20 mgll. 0.10 0,03 6/17/IS 6124/IS2l :S8 Cadmium, Total 200.8 0.00003 J mg/L 0.()010 0.00003 6/18/IS 6122/15 19:12 Copper, Total 200.8 0.0019 B mg/L 0.0010 0.0002 6/18115 6/22/IS 19:12 Lead, Total 200.8 O.tol9 mgiL 0.0010 0.0003 6/18/JS 6122/IS 19:12 Nickel, Total 200.8 0.0010 J mg/L 0.0010 0.00006 6/18/15 6122/U 19:12 Zinc, Total 200,8 0.0044 J mgll. 0.0050 0.0012 6/18/IS 6122/JS 19:12

Prinled 7ntl5 10:04 Fonn lA

SuperSet Rcr"'"ce: U.OOOOJJ6110 qv 00 GE Pittsfield Toxicity pH

Date: 6/15/15

Chronic Day 1

Effluent Composite

Sample # 64G-A10287 Date ~~ Time~-- pH 17K su temp. EEL:.

River /Dilu.tfon Water I • Sample # A10288R Date ;;~ Time : 0 ~A-- pH 1:/!isu temp. fl3a (.,

~Jqd$=Sigi}ature & Date ~oc4«/_,r / Signature & Date

913017 ALS Group USA, Corp. dba ALS Environmental Analytical Report Client: General Electric Company Senolce Request: Rl504879 Project: GE-Pittsfield NPOES Chronic Biomonitoring/Day 2 Date Collede4: 6/17/lS 0700 Sample Matrix: Water Date Received: 6/18/15 Sample Name: 64G-At0289 Lab Code: Rl504879·003 Basis: NA

General Chemistry Parameters

Dilution Date Date Analyte Name MethOd Result Q Units MRL Factor Extracted Analyzed Note Alkalinity, Total as CaC03 SM2320 410 mgiL 2.0 NA 6124115 09:36 B-1997(l01 I) Ammonia as Nitrogen, undlslilled 350.1 0.050 u mgll. o.oso NA 6130/15 17:16 Carbon, Total Organic (TOC) SM5310 5.9 mgll. 1.0 NA 6129/15 II :44 C-2000(2011) Solids, Tocal SM2S.CO 718 mg/L 10 NA 6122/1 S I J :28 8-1997(2011) Solids, Total Dissolved (TOS) SM 2540 686 mgft, 10 NA 6/19/IS 08:59 C-1997(2011)

Printc:d 7/2/JS 10;22 Fonn lA a.ee·%.e \lalpmnOO 1\stulilllsS"ILIMSReps\Anal)'lallltpon.tJ>I SuJII!fSel Rd"crencc: IM000336964 rcvOO ALS Group USA, Corp. dba ALS Environmental Analytical Report Client: General Electric Company Service Request: RlS04879 Project: OE·Pittsfield NPDES Chronic Biomonitoring/Oay 2 Date Collected: 6/17/15 0700 Sample Matrix: Water Date Recdnd: 6/18/15 Sample Name: 64G·A10289TM Lab Code: RIS04879-00 I Basis: NA

lnor£anlc Parameters

Dilution Date Date Analyte Name Method Result Q Units MRL MDL Factor Extracted Analyzed Note Aluminum, Total 200.7 0.10 u mg.IL 0.10 0.03 6/19115 6126/15 ol:32 Cadmium, Total 200.8 0.0010 u mg/L 0.0010 0.00003 6/19/IS 6/23/IS 23:48 Copper, Total 200.8 0.0013 mg/L 0.0010 0.0002 6/19/IS 6123/15 23:48 Lead, Total 200.8 0.0010 u m(V'L 0.0010 0.0003 6/19/lS 6123115 23:48 Nickel, Total 200.8 0.0014 mgll. 0.0010 0.00006 6/19/JS 6123/15 23:48 Zinc, Total 200.8 0.0050 u mgiL 0.0050 0.0012 6119115 6124/15 18:50

Printed 7n/IS I 0:22 Form lA aa·.ee:s· \\alprcwsOO I \swllmsS\I..IMSReps\1\n~lytlcalltcportJlll SuperSc1 Re(e~et~Ce: I 5..0000336964 rrv 00 ALS Group USA, Corp. dba ALS Environmental Analytical Repon Client: General Electric Company Service Request: RIS04879 Project: GE-Pittsfield NPDES Chronic Biomonitoring!Day 2 Date Collected: 6/17/IS 0820 Sample Matrix: Water Date Received; 6/J 8/l S Sample Name: A10290R Lab Code: RI504B79·004 Basis: NA

General Chemistry Panmeters

Dilution Dale Date Analyte Name Method Result Q Unlu MRL Factor Extracted Analyzed Note Alkalinity, Total as CaCOJ SM2Jl0 51.0 mg/L 2.0 NA 6124/1 s 09:36 8·1997(2011} Ammonia as Nitrogen, undistillcd 350.1 0.050 u mgJL 0.050 NA 6130/IS 17:34 Carbon, Total Organic (TOC) SM 5310 6.1 mgiL 1.0 NA 6129115 12.:05 C-2000(20 II} Solids, Total SM2S41J 106 mgiL JO NA 612VlS 11 :28 B·1997(l0ll) Solids, Total Dissolved (TDS) SM 2540 102 mg.IL JO NA 6119/U 08:59 C-1997(21Jll)

Prln1ed 712/lS 10:22 Form lA

\\alprcw$00 IutariltMS\UMSReps\Ailalyti~IRcpnrpl SapcrSo:l Rcfcrcncr. U.0000336!>6.c rev 00 ALS Group USA, Corp. dba ALS Environmental Analytical Report Client: General Electric Company Service Req11est: RIS04879 Project: GE-Piusfield NPDES Chronic Blomonitoring/Day 2 DaCe Collected: 6/17/15 0820 Sample Ma1rlx: Water Date Recelvtd: 6/18/JS Sample Name: AI0290RTM Lab Code: R 1504879-002 Basis: NA

lnorgaolc Parameters

Dilution Date Date Analyte Name Method Result Q UnilJ MRL MDL Factor Extracted Analyzed Note

Aluminum, Total 200.7 0.04 J mgiL 0.10 O.OJ 6/1~/IS 6126115 02:38 Cadmium, Total 200.8 0.0010 u mg/L 0.0010 0.00003 6/19/15 6123115 23:53 Copper, Total 200.8 0.0006 J mg/L 0.0010 0.0002 6/19/IS 6123/1.513:$3 Lead, Total 200.8 0.0010 u mgiL 0.0010 0.0003 6119115 6123/IS23 :53 Nickel, Total 200.8 0.0006 J ms'L 0.0010 0.00006 6/19/IS 612311S 23:53 Zinc, Total 200.8 0.0016 J mgiL 0.0050 0.0012 6/19/IS 6124/U 18:55

Printed 7/l/1 S I0:22 Form lA ~uJ.e.e; s. \lalprcwrOOI\sl•rliiRSS\I.IMSReps\AneiJ!IcaiRcpcM1.rpt SuperSet RcfiR11CC IS.00003l6964 rev 00 GE Pittsfield Toxicity pH

Date: 6/1z/15 ' ~

Chronic Day 2

Effluent Composite

Sample # 64G-A10289 Date '' L>z /,:; ·· • ' l .( ..i ~ Ttme 7 · · /I''' pH 7, •:f.l.. su temp. 7. ,;.)_ ~ L

River/Dilution Water ' Sample# A10290R . ~~ee 11~-- pH 1.1&, su temp._LL2~

,,. Signature & ~te' Al.S Group USA. Corp. dba ALS Environmental Analytical Report Client: General El~tric Company Servk:e Request: RIS04948 Project: GE-Pittsfreld NPDES Chronic Biomonitoring/Day 3 Date Collected: 6119115 0100 Sample Matrix: Water Date Received: 6/20fl S Sample Name: 640-A10291 Lab Code: Rl 504948-003 Basis: NA

General Chemistry Parameters

Dilution Dale Date Analyte Name Method Result Q Units MRL Faetor Extracted Analyzed Note Alkalinity, 1otal as CaC03 SM 2320 415 mgll. 2.0 NA 6123/15 08: 15 8·1997{2011). Ammonia as Nitrogen, undlstlllcd 350.1 0.050 u mgiL 0.050 NA 613011 s 16:48 Carbon. Total Organic CfOC) SM5310 5.1 mg/L 1.0 NA 612411 S 21 :S& C.lOOO(lOII) Solids, Total SM2S40 109 mgll. JO NA 6125/IS II :28 0·1997(1011) Solids, Total Dissolved (fDS) SM 2540 575 mgiL 10 NA 6124/IS 14:32 C-1997(2011)

Printed 7/911S IO :SS Fonn lA e·eO=t:.a· \'-lprcwsOOIIIwtinuS\UMSRtps\AIIII IyllcaiRcporiJ)II SupctSct Rcfmnct: U..{)()OO)l7018 rev OD ALS Group USA, Corp. dba ALS Environmental Analytical Report Client: General Electric Company Service Request: RJ504948 Project: GE-Pinsfield NPDES Chronic Biomonitoring/Day 3 Date Collected: 6/19/15 0700 Sample Matrix: Water Date Received: 6120/1 S Sample Name: 64G-AI0291TM Lab Code: RI504948-00J Basis: NA

Inorganic Parameters

Dilution Date Date Analyte Name Method Result Q UnUs MRL MDL Fa£tor Extracted Analyzed Note Aluminum, Total 200.7 0.10 u mg/L 0.10 0.03 1 6124/IS 6126/IS 21:46 Cadmium. Total 200.8 0.0010 u mgiL 0.0010 0.00003 l 6129/IS 6/30/IS 10:S7 Copper. Total 200.8 0.0017 mgiL 0.0010 0.0002 l 6129/lS 6/JOm to:57 Lead, Total 200.8 0.0010 u mF/L 0.0010 0.0003 1 6129115 6130/IS 10:S7 Nickel, Total 200.8 0.0016 mg/L 0.0010 0.00006 1 6129/IS 6130/1.5 10:S7 Zinc, Total 200.8 0.0050 u mgfL 0.0050 0.0012 I 6129/IS 6130/IS IO:S7

PriniCd 7/9115 10:55 Form lA

\\;ltprcwsOOI\starlimsS\UMSRcpMn.llytlcaiReport.rpt SuperSet Reference: 1$.0000337018 n:v 00 ALS Group USA, Corp. dba ALS Environmental Analytical Report Client: Oeneral Electric Company Servk:e Req ..est: R I!504948 Project: OE-Pittsfield NPDES Chronic BiomonitoringiDay 3 Date Collected: 6/19/15 0845 Sample Matrix: Water Date Received: 612011 S Sample Name: AI0292RTM Lab Code: R 1504948-002 Basis: NA

Inorganic: Parameters

Dilution Date Date Analyte Name Method Result Q Units MRL MDL Factor Extracted Analyzed Note Aluminum, Total 200.7 0.10 u mafl. 0.10 0.03 6/24/IS 6/26/IS 21:.52 Cadmium, Total 200.8 0.0001 J m~ 0.001 b 0.00003 6129/IS 6/3011.5 I I :04 Copper, Total 200.8 0.0006 J mg/L 0.0010 0.0002 612911!5 6/3011 S I J :04 Lead, Total 200.8 0.0010 J mg!L 0.0010 0.0003 6129/IS 6130115 11:04 Nickel, Total 200.8 0.0006 J mafl. 0.0010 0.00006 6129/JS 6/30/15 I 1:04 Zinc, Total 20D.8 0.0016 J mg/L 0.0050 0.0012 6129/IS 6130/IS 11:04

Printed 7/9115 IO:SS Form lA eeae·s. \\alprcwtOOI\s1atlimsSILIMSilcps\Aulyticalllcporl.rpl SuperSet llcfctenU: Is.GOOCI337011 rev 00 ALS Group USA, Corp. dba ALS Environmental

Anal)1i~al Report Client: General Electric Company Servlee Request: R I 504948 Project: GE-Pittsfield NPDES Chronic Biomonitoring/Day 3 Date Collected: 6/19115 0845 Sample Matrix: Water Date Received: 6/20115 Sample Name: AI0292R Lab Code: R1 504948-004 Basis: NA

General Che~nistry Parameters

Dilution Date Date Analyfe Name Method Result Q Units MRL Factor Extracted Analyzed Note Alkalinity, Total as CaC03 SM2320 68.3 mg!L 2.0 NA 6123/ISOB:lS 8·1997(201 I) Ammonia as Nitro&cn, undistillcd 350.1 0.050 u mg!L o.oso NA 6130n5 16:49 Carbon, Total Organic (TOC) SMSJIO 5.4 mgiL 1.0 NA 6124/IS 22:19 C·2000(2011) Solids, Total SM 2S40 114 mg/L 10 NA 6125115 II :28 8·1997{201 I) Solids, Total Dissolved (TDS) SM1!40 95 mg/L 10 NA 6/24/IS 14:32 C·1997(201 I)

Printed 7/9/1 S l0:5S Form lA

\\llp..-sOO\IslllrlimsS\UMSReps~k:aiRcport .l)lt SuperSet Refaau:c: l$-00003l702S rev 00 GE Pittsfield Toxicity pH

Date: 6/19/15

Chronic Day 3

Effluent Composite

... River/Dilution Water '

Sample# A10292R Date reA¢5 Time k:'f~"- pH Z9t'su temp.~0 ~~ c:;~o/_s Signature & Date

~ Signature & Date APPENDIX3

Chain of Custody Forms Page --1 of 2 ~ · ·v.3·COmmen:e Stree .. ,.· .. .l .... "' . : -·- :.:~Aq~Jatec .. ai.ologlcal:· s:~ien'ces WilstOil. ' Vt .0549S TS.:·({J02). 860-1638 .. . · ·- ·. -.·;J: · · .Qhai.n~f..Cu~~Qd.Y. R.e~Qtd ·. . ., ...~~~~ 651$-3'\8\l VOLUME/CONTAINER 1YPEI COMPANY INFORMATION COMPANY'S PROJECT INFORMATION SHIPPING INFORMATION PRESERVATIVE Carrier. Prioflty Express Name: Geneml Electric; Company Project Name: GE PITISFIELO 40C 40C 40C 40C 40C 1itS04 tbSO• HND3 Address: Veolla Wale! NA Outfall Composite -INITIAL SAMPLE 1000 East Street. Gale 64 Project Number:_1_50_1_4______Airbill Number. ------Plastic Plastic Plastic- Glass Glass - - Plastic City/State/Zip: Pittsfield, MA 01201 Sampler Name(s): ------ -,- Tetephone: (413) 494-6709 NPOES Permit#: MA0003891 Date Shipped: uf_¢5 Facsimile: Ship th"e samples on Monday Contact Name: _s_e_an_c_o_y_re______Client Code: Al.S/Christ Hand Delivered: 0 Yes -·-1 gal No 112 gal --40ml liJ --1L 40ml-- --0.5 L

GRAB I COMPOSITE I MATRIX I ANALYSIS NUMBER OF CONTAINERS v Effluent Renewal1 (R1): Ceriodaphnia dub/a 1 chronic suvival and reduction I I I I Effluent Total Residual Chlorine 1 v See Note In Comment Box below

HousatS~DiYAW.~iR._ ~-i,j v Receiving Receiving (Dilution Water) 1 , Temperature blank at time of delivery {Aquatee): ;.S" ·c. ~~;1;.~~-~~~~~~~~?::j~~Utt.,~~~:=:_JwwrP Operators: bo your final effluent chlorinated? k-::----:-:--:-:-~--:---:----~!;;~;::..g~~:....t,~~~¢~~~~=----1 If so, Is It dechlorinated prior to shipment for toxk:lty testing? Relinquished by; (sfgnature) DATE Please record TRC concentration, mg/L (If available):

Sample acceptance policy: Chain-of-Custody completed. Samplo bottle labels should be completed and coventd with walarproof tapo. Sample should be received at ~-6"C and/or within 6 hours of collection. Samples should be received with In specified holding times based on controlling regulations (e.g., less than 36 hours for effluent samples under NPDES regulation). Samples not meeting the above conditions (per applicable regulatory protocols) will be qualified In the report.

.. Page 1 of L 1 . -- - 273 Commerce StreE Aq'u_a_tec alo o~G~gi~.al S~ioences Wil~on, VT- 05495 ~{802)~1638 . R~cord :.. Chain:-oof;Cu§iody. 0 0 f.n.: l~~~~189 VOLUME/CONTAINER TYPE/ COMPANY INFORMATION COMPANY'S PROJECT INFORMATION SHIPPING INFORMATION PRESERVATIVE Carrier. Priority Expntss Name: General Electric Company Project Name: GE PITTSFIELD .o40C 40C 40C 40C 40C 40C ~o. H%50. HND3 Address: Veolla Water NA Outfall Composite- BENEWAL SAMPLE 1000 East Street. Gate 64 Project Number: 15014 Alrbill Number: -- - - - Plastic Plastic Plastic Glass Glass -Plastlc City/State/Zip: Plttsf~eld, MA 01201 Sampler Name(s): Telephone: (413) 494-6709 NPDES Pennit 1: MA0003891 Date Shipped: c,}?)s • I Facsimile: Ship these samples on Wodnellday Client Code: ALSIChrist Hand Delivered: Yes -- Contact Name: Sean Coyle 0 - 40ml ~ 1 gal 112 gal fL - 40ml- -0.5L SAMPLE COLLECTION SAMPLE Start date Completion GRAB COMPOSITE MATRIX ANALYSIS NUMBER OF CONTAINERS IDENTIFICATION and ti[J'le date 00_d ti_me II ~ '»'ljj; Effluent Renewal1 (R1): Ceriodaphnia dubia 1 Outfall Co;+osite B7' ~'~ v G,~ (02 ·7~~ ~ ....._ chronic suvival and reproduction Outfall Com~ ile t'f ,.,/ Effluent Total Residual Chlorine 1 tp rG -",1/taz ~~ . (See Note In Comment Box belowJ ~ ~ N / Hou~~~R (,~/~ v Receiving Receiving (Dilution Water) 1

D1J'E TIME Temperature blank at time of delivery (Aquatec):O, "} "C. ~t.~lit 'J.~ig~~re) ~.-'-~"'\.- ~~rure~~./~ .... - 6/rfl~ (33< WWTP O~rators : Ia your final effluent chlorinated? ~elinquished by: (signarure) TIME f.. ~L7-=re) ...... ~1JJ. o9:f.:. If so, is it dechlorinated prior to shipment for toxicity testing? Relinquished by: (signature) 'DATE TIME ~ed by: (signature) Please record TRC concenll'ation. mgiL ('rf available):

- -·- ,; - - .

Sample acceptance policy: Chain-of-Custody completed. Sample bottle labels should be completed and covered with waterproof tape. Sample should be received at 0°-&0C and/or within 6 hours of collection. Samples should be received with in specified holding times based on controlling regulations (e.g., less than 36 hours for effluent samples under NPDES regulation). Samples not meeting the above conditions [per applicable regulatory protocols) will be qualified In the report. Page 1 of 2 . Aqu·atec B1ologlcal Sciances ~:~s;; .. .· •. -· ,.. .· . TEL.: (802) eeo-1saa ...... Cham~of~$tod¥ - ~r~L . . . F~(8o2).~5&3-t89 VOLUME/CONTAINER TYPE/ COMPANY INFORMATION COMPANY'S PROJECT INFORMATION SHIPPING INFORMATION PRESERVATIVE

Name: General Elec!ric Company Project Name: GE PnTSAELD Carrler. Priority Express 40C 40C 4oc 40C 40C 40C 2504 Address· Veolia Water NA Outfall Composite - RENEWAL SAMPLE H H~O• HNOs . ------1QQQ East Street. Gats 64 Project Number: 15014 Alrbill Number. ------City/State/Zip: Pltlsf~eld, MA01201 SamplerName(s): ------Plastic Plastic Plastic Glass Glass Plastic Telephone: (413)494--6709 NPDES Pannlt#: MA0003B91 Date Shipped: t,fl/t& Facsimne: Ship these samples on Friday. / ------Contact Name: Sean Coyle Client Code: AlS/Chrlst Hand Delivered: D Yes (E'No 1 gal 1/2 gal 1 l 40 ml -40 mL 0.6 l COLLECTION SAMPLE Startdate Completion GRAB COMPOSITE MATRIX ANALYSIS NUMBEROFCONTAINERS IDENTIFICAnON and time date al\d time O~~'Gomposite ~f/f/1,5 U,~fi~ t/ Effluent Renewal2 (R2): Cerlodaphnia dubia 2 h4{;-A-JI12t:'fl ...p;,__ '7,~ chronic suiVival and-reproduction outraR Composite ~ 'Jv/t.~ "/If.~ V Effluent Total Residual Chlorine 1 ~~~/D2.R/ ~I ~,....., 1~~ j_See Note in Comment Box below)

Housa)¥1~~ '-/11/q V t/ Receiving Receiving (Dilution Water) 2

~ / 1. Reli~s~ature} ./; ~AJE/ I/. ~E 1~y : (~~)... .h.-. 4#'1 _!-!Temperature blank at time of delivery (Aqualec): \ ,3 ·c. ~~- ~...... _R- ot9J5r17'3"~~_i ~~4t_vr WWTPOperators: ;Relinquished by: (signature) IOAl'E ~ Recaljle;J.. bf:Jrlf!rtup .// Is your final effluent cfllorinated? (QJtoj \c;- 0~ _ ~1.. ~.(' ~Jif'~_,.v-- If so, Ia It dechlorinated prior to shipment for toxicity tMtiog? Relinquished by: (signature) DATE TIME Received by: (m~t5) Please record TRC concenttation, mgll (if available):

Sample acceptance policy: Chain--of-Custody completed. Sample bottle labels should be completed and covered with waterproof tape. Sample should be received at0°-6"C andforwithln 6 hours of collection. Samples should be received with In specified holding times based on controlling regulations (e.g., less than 36 hours for effluent samples under NPDES regulation). Samples not meeting the above conditions (per applicable regulatory protocols) wiU be qualified In the report. 26002 ,A,Enulranmental CHAIN OF CUSTODY/LABORATORY ANALYSIS REQUEST FORM 1565 Jefferson Road, Building 300, Suite 360 • Rochester, NY 146231 +1 585 288 53BO +1 585 288 8475 (fax) PAGE I OF :l. Pooject Nomo NPDES Permit ANALYSIS REQUESTED (Include Method Number and Container Prssetvative)

PllljoctMinogw Sean Coyle

~eKey ~-- Veolia Water (GE CEP) 0. NONE 1. HCL. 2. HNOa 1000 East St. 3. H:!SOo~ 4. N&OH 5. Zn. Acetate 8. M&OH 7. NaHSO.t B. Other __

..,....SPECW.INSTRUCTlONSICOMENTS TUANAROUND REQUIREMENTS REPORT REQUIREMENTS INVOfCE INFOAMAT10N --RUSH CS\IRCHAAGE8 APPLY) __L Reails Oti'f Total Metals (5)- EPA Method 200.8 Cu,Zn,Pb,Cd,Ni II. RIISiliiJ +QC Slmnltles POt --1 dlly-2doJ-3d-r __ .. day45dlly (LCS, DIP, MSIMSO• ~ Total Metals (1)- EPA Method 200.7 Aluminum BILL TO: __ m. FlallDa + oc n Clfbnlllan Toxicity pH sheet Included with COC's &.mlwtea REQUESTED REPORT DATE Samples packed in ice __)( IY. D.1la Valclflion Aepart wlltl Raw 011a I I

Edala __ Yes _ _ No

RECEIVED nv AeLINQUISHED BY AECCIVEOBY REUNOUISHEO BY REC6V£08Y R1504743 5 Veolla w.••r North Amettca 1iiitiio1iiiiii Dlllilmt

Dislrlbullon: 'Mile • Ulb Copy; Yellow - Altum to Origlnalor 0 2012 by ALS Group 26003 AEnUiranmental CHAIN OF CUSTODY/LABORATORY ANALYSIS REQUEST FORM 1565 Jefferson Road, Building 300, Suite 360 • Rochester, NY 146231 +1 585 288 5380 +1 585 288 8475 (fax) PAGE )_ OF b

PlojeetNome ,.,.,..... NPDES Permit ANALYSIS REQUESTED (lncluds Method Number and Conlainer PnJssnnJtlve) .,,.,...,u...,agor Sean Coyle

Preservative Key Company/-... Veolia Water (GE CEP) 0. NONE 1. HCL 2. HN03 1000 East St. 3. H2S04 4. NaOH 5. Zn. Acetate 6. MeOH 7. NaHS04 8. Other __

SPECIAL INsmtJCllONSfCOMMENTS TURNAROUND REQUIREMENTB I REPORT REQUIREMENTS I INVOICE lHFOflMATION ...... __L Resulta RUSH CSUIICHNIGES APPI.V) eM¥

ll n..na. oc &mn~r~~~ IPO. --1 dly:::id8y~d8y __ 4dly da, ~--11-CS. OUP, NSIMSO., ,.quir8d) llltU. TO: Samples packed in ice __IR. ~ + OC IWid Cllblallarl Sumnlarlell REQUEBTa) AllPORT DATE I ---* 1\1. Da1a llaldaliln Report \llilll Raw Data

&lata __Yes __No

REUNQUISHED BY I RECEM:DFSY I REUNOUISHED BY I RECaVEDFSY

OlslrlbuCion: While · lab Copy; 'talow • Aell.m to Origlnatot C 2012 by ALS Group A R1504743 5 ~ •coot~r 11-ipt and Preservation Cheek Form · iiU\miiimm'ifuii Projcct/Cilent §t- ~Pi1f.sf, dtY Folder Number 7;}...-~s Cciolerrectivedm6:16 · 1~ by; (1[ COUIUER: ALB F l • ~ • iEX OCITY CLIENT - .. - .-?1 ...1 I - I _ _ . _ . _ .... • - I -· 1 Were Custody seals en outsl~e ot cOOler'/ :>a 2 Custody papers properly completed (ink, signed)? ISb 3 Did all bottles arrive ia good contijtlOD (uobrokm) 6 Wbcro did the bottl~ aiginate? 4 Circle: 7 Soil VOA received u: Bulk

S . Tanp=atttteR~ ID: IRi#3 Frcm: Observed Temp (OC) Correction Factor·eC) Corrected Temp (OC) Withln o-s'C? N y N. y N y N Y N I Y N y N If out ofTemperature, note pacldDWfce condition:. lee melted Poorly Paaked Same Day Rule. &Client Approval to Ran. Samples: Standing Approval Client aware at drop-oft" Client noti1ied by:

All samples held in storage location: H.:OV.,L by \TC.t Ull l?"'l~fJ tu ~J.-.:.7 ~ 5035 samples placed mstorage location: by on _;...... _ __

PC Secondary Rmew:

Cooler Breakdown: Dito: ~jJJr Time: 111~ py:_--Jt;{;:fiOI:::i..,=~~"""""':- 1. Were aU bottle labels txJI4'1etl(i.s. analysis, preservatioo, etc.)? ~ NO 1' 2. Did all bottle labels and tags agree with custody papers? , NO 3. Were correct containers used fur the tests mdlcated? • NO .· 4. Air Samples: Cassettes I Tubes Intact Canisters Pres~ized · Tedlar® Bags Inflated ~. •( EXPlain any di ... ~...... • . :• pH Reagent Yes No Lot Received Exp SamplclD . Vol Lot Added Pinal Yes=All Added oH samples OK >12 NaOH S2 HNO, j,/ Jll> /01 :J I. ,t/n ':" td.~ No=Samplcs S2 · IUS04 ,/ I~Jf\ IV/l ;Kf~ unt. were <4 NaHS04 T preserved at Residual PorCN If+, CODtactPMto The lab as Chlorine Phenol add Na2Sz0l (CN). listed (·) and522 ucorbic (pbmlol). Nlb~OJ . . PM OK to ~ ,• I ZnAcotate . - **Not to be tested before inalysis -pH tested and Adjust: rec«ded by VOAA on a separate worksheet HCl ·••-- ••~ -

Bmtlel~num~ :------~------~---- Other Comments:

• I PC Secondary Review: :rfl'\VCd- *signifiCBDt air bubbles: VOA > S-6 mm : WC >1 ia. diameter • ·~. . P:\INTRAN5'I"QAQC\Ponb Conlroltedicooler Recelptr8.doc 3/27n5 08rJ26 l ' •. - CHAIN OF ,CUSTODY/LABORATORY ANALYSIS REQUEST FORM ~ouo.q. AEnuiranmantal 1565 Jefferson Road, Building 300, Suite 360 • Rochester, NY 14623 I +1 585 288 5380 +1 585 288 8475 (fax} PAGE I OF ,_

""'~act Name NPDES Permit ANALYSIS REQUESTED (Include Method Number and Container Preservative} ""'~act~ cc Sean Compony/Adlha Preservative Key 0. NONE 1. HCL 2. HNO:! 3. H2S04 4. NaOH 5. Zn. Acetate 6. MeOH 7. NaHS04 8. Other __

SPECIAL INSTRUCTIONS/COMMENTS TURNAROUND REQUIREMENTS REPORT REQUIREMENTS I INVOICE INFORMATION Melala Total Metals (5)- EPA Method 200:8 Cu,Zn,Pb,Cd,Ni RUstt (SURCHARGES AI'PI.Y) __ L~Orly

__II. Res~ • QC !bNnar111s I PO • ---1day--Zdef--3day Total Metals (1)- EPA Method 200.7-Aiuminum (lCS. DUP, MM.ISO as reql&led} --4 day-5 cS.y BILl. TO: Toxicity pH sheet included with COC's --Ill. Resulb + QCand C411b'allon ~ Samples packed in ice REQUESTED REPORT DATE __ IV. Dllla 'lllllllllon Allport wilh Raw Dalll!------1

Edala __Yes __ No

RECEIVED BY REUNQUISHED BY RECEIVED BY

Signalunl R1504879 5 Vtolla wat.r North Amel1ca GE.Pntlfl•kl NPOES AeUteJChroniC BIOfTIOni!Dring \~~~ \l\ ~~\ lll\ 1~\ II\ \II\ 11\lll~ ll\ e 2012 by AlS Group CHAIN OF CUSTODY/LABORATORY ANALYSIS REQUEST FORM 26005 A Enulranmental 1565 Jefferson Road, Building 300, Suite 360 • Rochester, NY 146231 +1 585 288 5380 +1 585 288 8475 (fax) PAGE 2,_ OF :2-.

Project Name IPra~oet Num~ NPDES Permit ANALYSIS REQUESTED (Include Method Number Slid Container Preservative) AIJ>DrtCC ~Manager sean Coyle PRESERVATIVE T Ql I I T eornp..yt-.. Preservative Key Veo\ia Water (GE CEP) 0. NONE ffi 1. HCL z 2. HNO:l 1000 East St. 3. H;!S04 ~ 4. NaOH 8 5. Zn. Acctato o;ttMiol.f MA 01201 1&. 6. MeOH - --·· ------1 0 ~. I"'-• 0 7. NaHS04 I! 8. Othsr __ . . • • 4~94-j;JQ9~r..... ~s2 7ZI S'• ! REMAAI-~ . A1n')QOR • • ~JIJ ~~ai/1'... ~-o!:.:..r:: 6/17/15 I l~2j,_j H,O I 1 X -:~~..__~~ '~t!

I t~~~~~t~ I I 1111111111111111 I ~~ .111111111111111111 I

SPECIAI..INSTRUC'nOHSICOMMENTS TURNAROUND REQUIREMENTS REPORT A!QUIAEMENTS INVOICE INFORMATION Metals __L ReNts 0..,. . 1-- RUSH ~£S APPI.Y) _ _ II. AesUts. oc SlltnmatiM PO• - - 1 day --6dwr -.3 day (lCS. OUP. MS/MSO u reqli.ed) --4deV_§octwr BILL TO: __ Ill. ReWIS+ 0C end Callr.dlon Samples packed In ice Sonmaries REQUESTED AEJ>ORT DATE --X-1'1. Data Vaadation Report with Raw Ooat------1

...... APP 0 Edata __Yes fi§.lE WHERE SAM~ WERE COj.LECTED No BY 1 m~~av /A- RECEJVEDav RELINQUISHED BY BY REUNOUISHED BY ~'lL" ~,.. J.l._ ~ ./ fSignaom SlgMiue ~,A~~~~2l -----__qz. IS~p!ift IS~p!!A 1Printed rl'iiiiia'if~ -- ~~_77/,:Z: IPme.dt~ame IPrtUdN4me Name I~b-7/J.~ ~U2:;:::JFim A t7 -~ IFirm Rnn lfnn ~~r- { -~~//r.M- 11-'hr -loawnme IDI!Wline !DaJenme IDaleff11111 OioiTi..tlM: 'Miile- Lab COW.~-~~~~~ 0 2012 by ALS Group A Cooler Receipt and Preservation Check Form Project/Client- Gt /IL~;. FolderNumber J?,s- -k:r2 - vvun.... a -wa .. """""on ~IIF"IIJ., , "'J• e: ~ 1 Were Custody seals on outside of cooler? Q')N Sa Perchlorate samples have required headspace? y N~ 2 Custody papers properly completed (ink, signed)? C/)N 5b Did VOA vials, Alk,or Sulfide have sig* bubbles? YUl) NA 3 Did all bottles arrive in good condition (wbrokcn)? P?N 6 Where did the bottles originate? KL~IROQ- CLIENT 4 Circle: ~)- Dry Ice Gel packs present? p?N 7 Soil VOA received as: Bulk Encore 5035set @) 8. Temperature Readings Date: l.i:.£.,., Time: IJ.~ ID: IR#3 <:@!) From:~ caiDEle Botifi Observed Temp (0 C) o:?.\ Correction Factor eq -a.1 Corrected Temp (0 C) /./'() Within 0·6°C? y y y y y y ('l)N N N N N N - N If out of Temperature, note pacldngllce condition: Ice melted Poorly Packed Same Day Rule &CJient Approval to Run Samples: Standing Approval Client aware at drop-off Client notified by: ------All samples held in storage location: Z--a1z by /4 on t;bd- at AW 5,035 samples placed in storage location: by on 7 at __

PC Secondary Review:

CoolerBreakdown: Date: WH.fir... Time: /-lJ.f'- by:.__ ~(!g'~v~=~-~::-- 1. Wc:e all bottle labels comf,ied(t.e. analysis, preservation, etc.)? =~ NO 2. Did all bottle labels and tags agree with custody papers? NO 3. Were correct containers used for the tests indicated? ~ NO 4. Air Samples: Cassettes I Tubes Intact Canisters Pressurized Tedlar® Bags Inflated @

Exolain-- anv d.·--· ~t'' ·-·--· pH Reagent Yes No Lot Received Exp Sample ID Vol. Lot Added Final Yes= All Added PH samples OK >12 NaOH S2 HNOJ ../ 'J!}·u1.;;b ,~.~~; /Jl;;r No=Samples S2 lbS04 1/ Lt.lt!.ir.iD/)9.> H ,fhJ."', were <4 NaHS04 preserved at Residual ForCN If+, contact PM to The lab as Chlorine Phenol add Na:.SIDl (CN), listed (-) and522 ascorbic (phenol). Na2S2~ - . PMOKto ZnAcctate - - UNot to be tested before analysis -pH tested and Adjust: HCI .. •• recorded by VOA5 on a separate worksheet

Bottle lot numbers: ti)l) k ;.:.;.. ttO;ttl /1..12(! IS& riVf1/i) Other Comments:'

PC Secondary Review: ~ 4=· •significant air bubbles: VOA > 5·6 mm : WC > 1 in. diameter P:\INTRANET\QAQC\Fonns Controlled\Cooler Receipt rS.doc 3!1.7115 0GfJ21 CHAIN OF CUSTODY/LABORATORY ANALYSIS REQUEST FORM . C.:bUUn A Enulronmentat 1565 Jefferson Road, Building 300, Suite 360 • Rochester, NY 146231 +1 585 288 5380 +1 585 288 8475 (fax) PAGE I OF J._

Pn>jeclN- NPDES Permit ...... ANALYSIS REQUESTED (Include Method Number and Container Praservalille) cc Pn>jeclMonagar Sean Coyle

Preservative Key Company/Add,_ Veolia Water (GE CEP) 0. NONE 1. HCL ; 2. HNO:J 1000 £ast St. 3. H250<4 4. NaQH § 5. Zn. Acetate 6. Me<>H 7. NaHS0-4 8. Other __ REMAAi

SPECW.INSTRUC'nONSICOMMafl"S TURNAROUND REQUIREMENTS REPORT R&QUIREMENTS I INVotCE lNf'OftMAT10N Metals Total Metals (5}- EPA Method 200.8 Cu,Zn,Pb,Cd,Ni RUSH (SURCHARGES APPI.'Y) _L Red~~ Orly __I. II8IUia i OC SurnrnlriM I PO I 1 dey --3 dey .sa,.--x! (lCS. DUP. MSIMSD as~ Total Metals (1) -EPA Method 200.7 Aluminum --4 d8y -!!.t..., BILL TO: Toxicity pH sheet included with COC's __lit RaWta + ac and C&ibral!on ~...... Samples packed in ice REQUESTED IW'OAT DATE __!l'l DU Vlllcl8lion "-'wtlhRiw Data 1------f

~~EdD __Yes __No~~

~~RELINgU~t:D BY BY REUNQUISHEO BY RECEIVED BY R1504948 5 v-. w.t..--America GE.PIItlflelct HPDES AcllltiChronlc Blomonllonng IIDII fll ~HI 111111 lffil Y~f IHI ~~ lUI OIWTmt~~

Dillrlluticn: White - Lib Copy; Vlllow - Relllm to OrigWialllr e 2012 by AlS Group 26007 AEnulranm•nt•l CHAIN OF CUSTODY/LABORATORY ANALYSIS REQUEST FORM 1565 Jefferson Road, Building 300, Suite 360 • Rochester, NY 146231 +1 585 288 5380 +1 585 288 8475 (fax) PAGE 'J-oF 5l-

~~l'l'ojoct ,..,., IProjectN...... NPDES Permit ANALYSIS REQUESTED (Include Method Number and Container Preservalive)~~

""'feet~ IAes~a~tcc Sean Coyle PRESERVATIVE I I n Tc.? I I I I Company/- Preservative Key Veolia Water {GE CEP) 1/) 0. NONE 15 1. HCL z 2. HN03 1000 East St. 3. H2S04 4. NaOH ~ 5. Zn. Acetate Pittsfield MA 01201 6. McOH 7. NaHS04 I PhOne' lEmar ffi~ ~ ~ 8. Other __ - .J" 4134Q4-6709 _, I 413-494-7052 'li fi l ~~ ! ~ ~-AIY:J-- ~~~.SY!;;~.~~ REMARKS/ .. ~ ~1/ll/tl/1! I.!/Iii ALTERNATE _Q_ESCF --1 - ,- FOR OFFIC:r; UIE I SAMPUHG CUENT SAMPLE 10 OM.Y LAIIID DATE llME • ~-~~·· ~Fl~. ,>-:e;~~~· ;::~. &;Jilt::_.!\ 1 n?q1 ;c,,._{:.:/f ,.; .~..;;· ;•· .;.~:. l 6/19/l.S I 7·00;<~ml H~O 1 X f.~ :i .•r, .. ~, .. -.., .· .~ ~ - .---:: ..r, I A 1ll"JQ"JR ~ ~~it

I Bfl I I 1111111111111111 I ,;~'~1': SPECIAL INSTRUCTIONS/COMMENTS TURNAROUND REQUIREMENTS I REPORT REQUIREMENTS INVOICE INFORMATION Mllbll5 [ --IIUIIH (SUf!CHAAGESAPPLY) --L Relulls ON( __ 11. Resulta + 0C llummarill POt - -1 dar -~cJ.r --3 dal' (LCS. Dll'. MSIMSO 111 Rlqli:al) -·dooy~ DIU. TO: __ Ill. Results+ ac .-1 CwJmuan Samples packed in ice St.rmwlal REQUESTED REPORT DATE ~w.~~~~~~~------~

~~~QAPP D tATE WHER_j SAMPLES WERE r.nu 1=r.n:n Edalll __'1\!s No RE\.INQUISHEO BY ... ~,w~;.DBY RBJNQUISHEDB'f RECeVEDBY~~

~~ISignalln l9onllln ~~l ~ ISlgnltln ~ mug- IPr1nted Name r~H~/;.::;1)/J. ("'~~ [Aiiil IArm IFmi I~§Qptt; 2.!6&,__I FmiG/~'ff /lr;f"r lArin I~ I I Dala'Tlme [liWnme I~>~~~ ~ lo.wr-~~

DilbbAion: Yf'lh • Ub Copy: Yellow - ReiLm to Olt!;ni!Dr e 2012 by AL5 Group R1504948 5 Vtolla Wlltr North AmtriC& rrmuii\\\i\i~,fit\iiii\\\i\ii\1\\m\ A Cooler Receipt and Preservation Check Form Project/Client (;E~ Pi~~/d n Folder Number Lj. Cit{ Nl Sa I Percltlorate samples have required headspace? 2 Custody papers properly completed (ink, signed)? let> N' Sb I Did VOA vials, Alk,or Sulfide have sig* bubbles? 3 Did all bottles arrive in good condition (unbroken)? 0) Nl 6 I Where did the bottles originate? A~ 4 Circle: W~ Dry Ice GeJ paw present? ON 7 I Soil VOA received as: Bulk Encore 5035set

8. Temperature Readings Date: t,(ZIJI'l- Time: jlCI~i ID: IR#3 ~ From: Temp Blank Sam~e Observed Temp (cC) z,, Correction Factor (0 C) :!ov1 Corrected·Temp (cC) '2.,,,; Within 0-6°C? ()[N y N y N y N y N y N y N If out of Temperature, note pacldnW!ce condition: Ice melted Poorly Packed Same Day Rule &Client Approval to Run Samples: Standing Approval Client aware at drop-off Client notified by: ------" All samples held in storage location: ~-r):'z byQW-- · ~lto/t} at 1/US 5035 samples placed in stora'j location: by on at --

PC Secondiry Review:-d\EU?Y• - .... i:!!!B MMiWMWJZS· CoolerBreakdown: Date:·~/."" ~-'.· :- Time: C>1'2D 1. Were all bottle labels complete (i.e. analysis, preservation, etc.)? by: &~~ NO 2. Did all bottle labels and tags agree with custody papers? . NO 3. Were correct containers used for the tests indicated? NO 4. Air Samples: Cassettes I Tubes Intact Canisters Pressurized Tedlar® Bags Inflated NIA Exolain·•Y anv dl- _ __ ...... ,. --·' . pH Reagent Yes No Lot Received Exp Sample ID Vol. Lot Added Final ' Yes:::: All Added pH samples OK ;:::12 NaOH S2 HN

~~PC Secondary Re>iew: ~A,lc:j. *significant air bubbles: VOA > 5-6 mm : WC >1 in. diameter P:\INTRANEnQAQC\Forms Controlled'Cooler Receipt rB.doc 3127/IS .,13021~~