M2794.001800 M A T E R I A L A N D M A N U F A C T U R I N G P R O C E S S E S

Chapter 5. Metal- Processes and Equipment; Heat Treatment

Prof. Ahn Sung-Hoon ( )

School of Mechanical and Aerospace Engineering Seoul National University 2 Historical casting parts

Korean bronze dagger( ( )) Bronze bell( ) & molds( )

© Prof. Ahn, Sung-Hoon 3 Casting

. Casting is a manufacturing process by which a molten material such as metal or plastic is introduced into a mold made of sand or metal, allowed to solidify within the mold, and then ejected or broken out to make a fabricated part.

. Advantages . Making parts of complex shape in a single piece. . Producing large number of identical within specified tolerances. . Good bearing qualities and jointless product.

. Disadvantages . Limitations of mechanical properties because of the polycrystalline grain structure. . Poor dimensional accuracy due to shrinkage of metal during solidification. . If the number of parts cast is relatively small, the cost per casting increases rapidly.

. Fundamental aspects in casting operations . Solidification of the metal from its molten state. . Flow of the molten metal into the mold cavity. . Heat transfer during solidification and cooling of the metal in the mold. . Mold material and its influence on the casting process.

© Prof. Ahn, Sung-Hoon 4 Solidification of Metals

© Prof. Ahn, Sung-Hoon 5 Solid solution

. Solute( ) . Solvent( )

. When the particular crystal structure of the solvent is maintained during alloying, the alloy is called solid solution. . Substitutional solid solution( ) . Interstitial solid solution( )

. 5.2.2 Intermetallic compound( ) . Complex structures in which solute atoms are present among solvent atoms in certain specific proportions.

. 5.2.3 Two-phase system( ) . Phase: a homogeneous portion of a system that has uniform physical and chemical characteristics

© Prof. Ahn, Sung-Hoon 6 Polycrystalline alpha brass

© Prof. Ahn, Sung-Hoon 7 Phase diagram ( )

Graphically illustrates the relationships among temperature, composition, and the phase present in a particular alloy system.

Lever Rule S C  C  O L S  L CS  CL L C  C  S O S  L CS  CL

© Prof. Ahn, Sung-Hoon 8 Lever-Rule ( )

© Prof. Ahn, Sung-Hoon 9 Eutectic system, Pb-Sn

© Prof. Ahn, Sung-Hoon 10 Types of 3-phase invariant reactions

© Prof. Ahn, Sung-Hoon 11 Iron-carbon system (1)

. Pure iron( ) : 0.008% C . Steels( ) : 2.11% C . Cast irons( ) : ~6.67% C . a-ferrite( ): BCC, soft and ductile . d-ferrite: BCC, stable only at very high temperatures . Austenite( ) : FCC, ductile

. Cementite( ): Fe3C, C 6.67%, iron carbide( ), brittle

© Prof. Ahn, Sung-Hoon 12 a-ferrite & austenite

a-ferrite (x 90) Austenite (x325)

© Prof. Ahn, Sung-Hoon 13 Iron-carbon system (2)

© Prof. Ahn, Sung-Hoon 14 Eutectoid steel

. a- ferrite: white

. Fe3C: dark

. Lamellar structure (pearlite)

. (x 500)

© Prof. Ahn, Sung-Hoon 15 1% carbon (hypereutectoid) pearlite steel

. a- ferrite - white . eutectoid - cementite - blue . proeutectoid - cementite - violet

. (x 500)

© Prof. Ahn, Sung-Hoon 16 Classification of ferrous alloys

© Prof. Ahn, Sung-Hoon 17 Composition and naming steels

© Prof. Ahn, Sung-Hoon 18 Amount of phases in carbon steel

Casting 1040 steel 10kg, calculate a phase and g phase at (a) 900 C, (b) 728 C and (c) 726 C

(a) Austenite:100% g

 Cg  Co   0.77  0.40  (b) a(%)   100  100  50%, that is 5kg,      Cg  Ca   0.77  0.022   C  C   0.40  0.022  g (%)   o a 100  100  50%, that is 5kg,      Cg  Ca   0.77  0.022 

 6.67  0.40  (c) a   100  94%, that is 9.4kg  6.67  0.022 

© Prof. Ahn, Sung-Hoon 19 Cast irons

. Fe, C 2.11~4.5%, Si ~3.5%

. According to solidification morphology :

Gray cast iron( ) . Flake graphite( ) . Gray fracture surface( ) . Damping( ) Ductile(nodular) iron( ) . Ductile White cast iron( ) . Large amount of Fe3C . Brittle . White fracture surface( ) Malleable cast iron( ) . Obtained by annealing white cast iron Compact graphite iron( )

© Prof. Ahn, Sung-Hoon 20 Cast irons

© Prof. Ahn, Sung-Hoon 21 Cast irons

© Prof. Ahn, Sung-Hoon 22 Ternary phase diagram

. Fe-Cr-Ni

© Prof. Ahn, Sung-Hoon 23 Cast structures

. Pure metal vs. alloys

© Prof. Ahn, Sung-Hoon 24 Dendrites ( )

© Prof. Ahn, Sung-Hoon 25 Dendrites

© Prof. Ahn, Sung-Hoon 26 Fluid flow

v  c 2gh p v2 h    constant g 2g p v 2 p v 2 h  1  1  h  2  2  f 1 g 2g 2 g 2g

Q  A1v1  A2v2 A h 1  2 A2 h1 vD Re  

© Prof. Ahn, Sung-Hoon 27 Solidification time & shrinkage

. Chvonrinov’s rule Solidification time = C(volume/surface area)2

. Shrinkage occurs at . Molten metal . Phase change . Solid metal

. Cast iron expands . Graphite has high volume/mass . Net expansion during precipitation

. Similarly Bi-Sn alloys expand

© Prof. Ahn, Sung-Hoon 28 Defects/DFM

© Prof. Ahn, Sung-Hoon 29 Casting alloys

© Prof. Ahn, Sung-Hoon 30 Applications

© Prof. Ahn, Sung-Hoon 31 Properties

© Prof. Ahn, Sung-Hoon 32 Casting processes

. Expendable mold, permanent . . Shell-mold casting . . Ceramic mold casting . Vacuum casting

© Prof. Ahn, Sung-Hoon 33 Casting processes (2)

. Expendable mold, expendable pattern . Evaporative-pattern casting (lost foam) . (lost wax)

© Prof. Ahn, Sung-Hoon 34 Investment casting

© Prof. Ahn, Sung-Hoon 35 Casting processes (3)

. Permanent mold . In permanent-mold casting, a mold are . Slush casting made from materials such as steel, bronze, refractory metal alloys, or . Pressure casting graphite. Because metal molds are better . casting heat conductors than expendable molds, . Centrifugal casting the solidifying casting is subjected to a . Squeeze casting higher rate of cooling, which turn affects . Semisolid metal the microstructure and grain size within . Casting for single crystal the casting. . Rapid solidification . Cooling methods : water, air-cooled fin . Used for aluminum, magnesium, and copper alloys due to their lower melting points . Pros : good surface finishing, close dimensional tolerances, and uniform and good mechanical properties . Cons : not economical for small production runs, not good for intricate shapes

© Prof. Ahn, Sung-Hoon 36 Pressure casting/centrifugal casting

© Prof. Ahn, Sung-Hoon 37

. Hot-chamber process . Cold-chamber process

© Prof. Ahn, Sung-Hoon 38 Squeeze casting/single crystal

© Prof. Ahn, Sung-Hoon 39 Casting for single crystal

Crystal-pulling method floating-zone (Czochralski process) method

© Prof. Ahn, Sung-Hoon 40 Heat treatment-ferrous alloys

. Pearlite . Spheroidite . Bainite . Martensite . Quenching( ) . Body Centered Tetragonal(BCT) . Retained austenite . Tempered martensite

© Prof. Ahn, Sung-Hoon 41 Transformation-ferrous alloys

Austenite

Slow cooling Quenching

Moderate cooling Pearlite Martensite (a+Fe3C) (+proeutectic a) Bainite reheat (a+Fe3C) Tempered martensite

© Prof. Ahn, Sung-Hoon 42 Ferrous alloys

© Prof. Ahn, Sung-Hoon 43 Shape memory alloy (SMA)

© Prof. Ahn, Sung-Hoon 44 Quenched AISI 9310 steel

. The white strikes are excess proeutectoid cemetite . Cream color is retained austenite . Gray area is bainite . Blue/brown regions are martensite

. (x 320)

© Prof. Ahn, Sung-Hoon 45 Nonferrous alloys/ (1)

Precipitation hardening Age hardening( ) ( ), Al-Cu alloy

© Prof. Ahn, Sung-Hoon 46 Nonferrous alloys/stainless steel (2)

. Solution treatment . Precipitation hardening . Aging . Maraging(martensite + aging)

© Prof. Ahn, Sung-Hoon 47 Case hardening

. Surface hardening . Carburizing ( ) . Carbonitriding ( ) . Cyaniding ( ) . Nitriding ( ) . Boronizing ( ) . Flame hardening ( ) . Induction hardening ( )

© Prof. Ahn, Sung-Hoon 48 Annealing ( )/ tempering ( )

. Normalizing( )

© Prof. Ahn, Sung-Hoon 49 Design consideration (1)

© Prof. Ahn, Sung-Hoon 50 Design consideration (2)

© Prof. Ahn, Sung-Hoon 51 Design consideration (3)

© Prof. Ahn, Sung-Hoon 52 Economics of casting

© Prof. Ahn, Sung-Hoon 53 Case study

© Prof. Ahn, Sung-Hoon 54 Bridge design

© Prof. Ahn, Sung-Hoon 55 Material of the bridge

Another bridge

© Prof. Ahn, Sung-Hoon