M2794.001800 M A T E R I A L A N D M A N U F A C T U R I N G P R O C E S S E S
Chapter 5. Metal-Casting Processes and Equipment; Heat Treatment
Prof. Ahn Sung-Hoon ( )
School of Mechanical and Aerospace Engineering Seoul National University 2 Historical casting parts
Korean bronze dagger( ( )) Bronze bell( ) & molds( )
© Prof. Ahn, Sung-Hoon 3 Casting
. Casting is a manufacturing process by which a molten material such as metal or plastic is introduced into a mold made of sand or metal, allowed to solidify within the mold, and then ejected or broken out to make a fabricated part.
. Advantages . Making parts of complex shape in a single piece. . Producing large number of identical castings within specified tolerances. . Good bearing qualities and jointless product.
. Disadvantages . Limitations of mechanical properties because of the polycrystalline grain structure. . Poor dimensional accuracy due to shrinkage of metal during solidification. . If the number of parts cast is relatively small, the cost per casting increases rapidly.
. Fundamental aspects in casting operations . Solidification of the metal from its molten state. . Flow of the molten metal into the mold cavity. . Heat transfer during solidification and cooling of the metal in the mold. . Mold material and its influence on the casting process.
© Prof. Ahn, Sung-Hoon 4 Solidification of Metals
© Prof. Ahn, Sung-Hoon 5 Solid solution
. Solute( ) . Solvent( )
. When the particular crystal structure of the solvent is maintained during alloying, the alloy is called solid solution. . Substitutional solid solution( ) . Interstitial solid solution( )
. 5.2.2 Intermetallic compound( ) . Complex structures in which solute atoms are present among solvent atoms in certain specific proportions.
. 5.2.3 Two-phase system( ) . Phase: a homogeneous portion of a system that has uniform physical and chemical characteristics
© Prof. Ahn, Sung-Hoon 6 Polycrystalline alpha brass
© Prof. Ahn, Sung-Hoon 7 Phase diagram ( )
Graphically illustrates the relationships among temperature, composition, and the phase present in a particular alloy system.
Lever Rule S C C O L S L CS CL L C C S O S L CS CL
© Prof. Ahn, Sung-Hoon 8 Lever-Rule ( )
© Prof. Ahn, Sung-Hoon 9 Eutectic system, Pb-Sn
© Prof. Ahn, Sung-Hoon 10 Types of 3-phase invariant reactions
© Prof. Ahn, Sung-Hoon 11 Iron-carbon system (1)
. Pure iron( ) : 0.008% C . Steels( ) : 2.11% C . Cast irons( ) : ~6.67% C . a-ferrite( ): BCC, soft and ductile . d-ferrite: BCC, stable only at very high temperatures . Austenite( ) : FCC, ductile
. Cementite( ): Fe3C, C 6.67%, iron carbide( ), brittle
© Prof. Ahn, Sung-Hoon 12 a-ferrite & austenite
a-ferrite (x 90) Austenite (x325)
© Prof. Ahn, Sung-Hoon 13 Iron-carbon system (2)
© Prof. Ahn, Sung-Hoon 14 Eutectoid steel
. a- ferrite: white
. Fe3C: dark
. Lamellar structure (pearlite)
. (x 500)
© Prof. Ahn, Sung-Hoon 15 1% carbon (hypereutectoid) pearlite steel
. a- ferrite - white . eutectoid - cementite - blue . proeutectoid - cementite - violet
. (x 500)
© Prof. Ahn, Sung-Hoon 16 Classification of ferrous alloys
© Prof. Ahn, Sung-Hoon 17 Composition and naming steels
© Prof. Ahn, Sung-Hoon 18 Amount of phases in carbon steel
Casting 1040 steel 10kg, calculate a phase and g phase at (a) 900 C, (b) 728 C and (c) 726 C
(a) Austenite:100% g
Cg Co 0.77 0.40 (b) a(%) 100 100 50%, that is 5kg, Cg Ca 0.77 0.022 C C 0.40 0.022 g (%) o a 100 100 50%, that is 5kg, Cg Ca 0.77 0.022
6.67 0.40 (c) a 100 94%, that is 9.4kg 6.67 0.022
© Prof. Ahn, Sung-Hoon 19 Cast irons
. Fe, C 2.11~4.5%, Si ~3.5%
. According to solidification morphology :
Gray cast iron( ) . Flake graphite( ) . Gray fracture surface( ) . Damping( ) Ductile(nodular) iron( ) . Ductile White cast iron( ) . Large amount of Fe3C . Brittle . White fracture surface( ) Malleable cast iron( ) . Obtained by annealing white cast iron Compact graphite iron( )
© Prof. Ahn, Sung-Hoon 20 Cast irons
© Prof. Ahn, Sung-Hoon 21 Cast irons
© Prof. Ahn, Sung-Hoon 22 Ternary phase diagram
. Fe-Cr-Ni
© Prof. Ahn, Sung-Hoon 23 Cast structures
. Pure metal vs. alloys
© Prof. Ahn, Sung-Hoon 24 Dendrites ( )
© Prof. Ahn, Sung-Hoon 25 Dendrites
© Prof. Ahn, Sung-Hoon 26 Fluid flow
v c 2gh p v2 h constant g 2g p v 2 p v 2 h 1 1 h 2 2 f 1 g 2g 2 g 2g
Q A1v1 A2v2 A h 1 2 A2 h1 vD Re
© Prof. Ahn, Sung-Hoon 27 Solidification time & shrinkage
. Chvonrinov’s rule Solidification time = C(volume/surface area)2
. Shrinkage occurs at . Molten metal . Phase change . Solid metal
. Cast iron expands . Graphite has high volume/mass . Net expansion during precipitation
. Similarly Bi-Sn alloys expand
© Prof. Ahn, Sung-Hoon 28 Defects/DFM
© Prof. Ahn, Sung-Hoon 29 Casting alloys
© Prof. Ahn, Sung-Hoon 30 Applications
© Prof. Ahn, Sung-Hoon 31 Properties
© Prof. Ahn, Sung-Hoon 32 Casting processes
. Expendable mold, permanent pattern . Sand casting . Shell-mold casting . Plaster mold casting . Ceramic mold casting . Vacuum casting
© Prof. Ahn, Sung-Hoon 33 Casting processes (2)
. Expendable mold, expendable pattern . Evaporative-pattern casting (lost foam) . Investment casting (lost wax)
© Prof. Ahn, Sung-Hoon 34 Investment casting
© Prof. Ahn, Sung-Hoon 35 Casting processes (3)
. Permanent mold . In permanent-mold casting, a mold are . Slush casting made from materials such as steel, bronze, refractory metal alloys, or . Pressure casting graphite. Because metal molds are better . Die casting heat conductors than expendable molds, . Centrifugal casting the solidifying casting is subjected to a . Squeeze casting higher rate of cooling, which turn affects . Semisolid metal forming the microstructure and grain size within . Casting for single crystal the casting. . Rapid solidification . Cooling methods : water, air-cooled fin . Used for aluminum, magnesium, and copper alloys due to their lower melting points . Pros : good surface finishing, close dimensional tolerances, and uniform and good mechanical properties . Cons : not economical for small production runs, not good for intricate shapes
© Prof. Ahn, Sung-Hoon 36 Pressure casting/centrifugal casting
© Prof. Ahn, Sung-Hoon 37 Die casting
. Hot-chamber process . Cold-chamber process
© Prof. Ahn, Sung-Hoon 38 Squeeze casting/single crystal
© Prof. Ahn, Sung-Hoon 39 Casting for single crystal
Crystal-pulling method floating-zone (Czochralski process) method
© Prof. Ahn, Sung-Hoon 40 Heat treatment-ferrous alloys
. Pearlite . Spheroidite . Bainite . Martensite . Quenching( ) . Body Centered Tetragonal(BCT) . Retained austenite . Tempered martensite
© Prof. Ahn, Sung-Hoon 41 Transformation-ferrous alloys
Austenite
Slow cooling Quenching
Moderate cooling Pearlite Martensite (a+Fe3C) (+proeutectic a) Bainite reheat (a+Fe3C) Tempered martensite
© Prof. Ahn, Sung-Hoon 42 Ferrous alloys
© Prof. Ahn, Sung-Hoon 43 Shape memory alloy (SMA)
© Prof. Ahn, Sung-Hoon 44 Quenched AISI 9310 steel
. The white strikes are excess proeutectoid cemetite . Cream color is retained austenite . Gray area is bainite . Blue/brown regions are martensite
. (x 320)
© Prof. Ahn, Sung-Hoon 45 Nonferrous alloys/stainless steel (1)
Precipitation hardening Age hardening( ) ( ), Al-Cu alloy
© Prof. Ahn, Sung-Hoon 46 Nonferrous alloys/stainless steel (2)
. Solution treatment . Precipitation hardening . Aging . Maraging(martensite + aging)
© Prof. Ahn, Sung-Hoon 47 Case hardening
. Surface hardening . Carburizing ( ) . Carbonitriding ( ) . Cyaniding ( ) . Nitriding ( ) . Boronizing ( ) . Flame hardening ( ) . Induction hardening ( )
© Prof. Ahn, Sung-Hoon 48 Annealing ( )/ tempering ( )
. Normalizing( )
© Prof. Ahn, Sung-Hoon 49 Design consideration (1)
© Prof. Ahn, Sung-Hoon 50 Design consideration (2)
© Prof. Ahn, Sung-Hoon 51 Design consideration (3)
© Prof. Ahn, Sung-Hoon 52 Economics of casting
© Prof. Ahn, Sung-Hoon 53 Case study
© Prof. Ahn, Sung-Hoon 54 Bridge design
© Prof. Ahn, Sung-Hoon 55 Material of the bridge
Another bridge
© Prof. Ahn, Sung-Hoon