US 2007004 1925A1 (19) United States (12) Patent Application Publication (10) Pub. No.: US 2007/0041925 A1 Picano et al. (43) Pub. Date: Feb. 22, 2007

(54) SKIN AND HAIR CARE PREPARATION (30) Foreign Application Priority Data CONTAINING ACOMBINATION OF PROTEIN HYDROLYZATES Sep. 11, 2004 (DE)...... 103 44 1662 Nov. 20, 2003 (DE)...... 103 54 3.16.3 (75) Inventors: Roger Picano, Seerzach (CH); Sven Gohla, Hamburg (DE) Publication Classification Correspondence Address: (51) Int. Cl. GREENBLUM & BERNSTEIN, P.L.C. 46R 8/97 (2006.01) 1950 ROLAND CLARKE PLACE A61K 8/64 (2006.01) RESTON, VA 20191 (US) (52) U.S. Cl...... 424/70.14; 424/74 (73) Assignee: BEIERSDORF AG, Hamburg (DE) (57) ABSTRACT (21) Appl. No.: 10/572,751 The invention relates to cosmetic preparations, especially hair care preparations or hair care products, containing (22) PCT Filed: Sep. 11, 2004 protein hydrolysates of silk, pashmina, cashmere wool, merino wool and/or mohair, mussel thread extracts, so (86). PCT No.: PCT/EP04/10185 called by Suss threads, and sericin and/or sericin hydroly sates. The preparations are mild for skin and hair and lead to S 371(c)(1), an improvement of hair structure and physical-optical hair (2), (4) Date: Oct. 4, 2006 properties. US 2007/004 1925 A1 Feb. 22, 2007

SKN AND HAR CARE PREPARATION restore it. A silky shine, low porosity and a pleasant, Smooth CONTAINING ACOMBINATION OF PROTEIN feel are features of natural healthy hair. HYDROLYZATES 0008 Since the end of the previous century, hair care 0001. The invention relates to cosmetic preparations, in products have been developed specifically. This led to a particular hair care preparations or hair care compositions, large number of preparations both for general hair care and comprising protein hydrolyzates from silk, pashmina, cash also for overcoming the anomalies of hair and of the scalp. mere wool, merino wool and/or mohair, extract from the In general, use is nowadays made of hair care cosmetics mussel threads of mussels, the so-called by SSuS threads, and which, after they have worked, are either intended to be sericin and/or sericin hydrolyzates. The preparations are washed out of the hair again, or which should remain on the mild to skin and hair and lead to an improvement in the hair hair. The latter can be formulated such that they not only structure and also in the physical-optical hair properties. serve to care for the individual hair, but also improve the appearance of the hairstyle overall. Hair groomed in Such a 0002 The entire human body, with the exception of the way is characterized by a pleasant feel, natural shine, lips, the palms of the hands and the soles of the feet, is increased fullness, Suppleness and thus good styleability and covered in hair, albeit for a large part with barely visible hold and thus good hairstyle sit. down. Because of the many nerve endings at the hair root, hair reacts sensitively to external influences such as wind or 0009 Products which serve exclusively to care for the touch and is therefore a component of the sense of touch that hair are generally referred to as hair conditioning agents or should not be underestimated. The most important function conditioners. After a greater or lesser residence time on the of human head hair must, however, nowadays be in helping hair, these can be rinsed out (rinse-off products, e.g. rinses, to create the appearance of the person in a characteristic hair treatments) or they remain following application to the manner. Similarly to the skin, it fulfils a social function hair (leave-on products). The products can have various since, via its outward appearance, it contributes considerably consistencies, meaning that they can be applied in very to interpersonal relations and to the self-esteem of the different ways. They may be emulsions or gels or low individual. Viscosity Solutions which are applied, for example, by means of spray applications, or foams, which are generated, for 0003. The hair consists of the hair shaft which protrudes example, by Suitable pressurized-gas packaging or a special freely from the skin the keratinized (dead) section which foam pump during application. Creamy, opaque and clearly represents the actual visible hair and the hair root which transparent products can be found on the market. sticks in the skin the living section, in which the visible hair is continually renewed. The hair shaft is in turn made up 0010 Depending on the intended use, quite diverse active of three layers, a central section—the so-called hair marrow ingredients or combinations of active ingredients are found (medulla), although in humans this has retrogressed and is in such conditioners. Some, which serve more to protect the often missing altogether—also the marrow (cortex) and the hair, such as antioxidants or UV filters, others which make outer horny layer which is up to ten layers thick (cuticle), the hair supple, Such as, for example, cationic Surfactants. which surrounds the entire hair. Achieving ever greater importance are polymeric active ingredients which have very diverse properties depending on 0004 Provided there are no pathological changes, it is their nature, molecular weight and charge. However, an virtually impossible to improve upon human hair in its improvement in the nature of the surface of the hair is clearly freshly grown state. The section of the hair in the vicinity of at the forefront. the scalp accordingly has a virtually closed horny layer. In particular, the horny layer, being the external sheath of the 0011. Despite a great diversity of products which are hair, but also the inner region below the cuticle are subjected available to the consumer, Some disadvantages have still not to particular stress by environmental influences. been completely overcome. For example, polymers which give the hair a certain hold and thus volume often exhibit a 0005 Significant influences for the loss in quality of a poor feel sensation and poor combability; polymers which hair during its aging are the influence of Sunlight, mechani make the hair Supple often lead to it being weighed down, cal stresses by intensive combing or brushing, but also hair which is associated with lack of volume. The use of starch treatments, such as hair colorations and in particular, bleach derivatives has in the past also been unable to overcome the ing, and also hair shaping, for example permanent waving described disadvantages of the prior art. methods. Accordingly, oxidative stresses in particular often lead to hair damage. 0012 Gel-like preparations of the prior art also have a number of other disadvantages: in most cases carbomers, i.e. 0006 Both UV-A and also UV-B radiation have a harm polyacrylates or cellulose derivatives are used for thickening ful effect on the hair, which is evident, for example, from the the preparations. However, Such preparations usually have a fact that certain amino acids, such as cystine and methion cloudy appearance. Virtually no salt-like care Substances and ine, are degraded, or sulfur-sulfur bonds of the keratin are no ionic film formers can be incorporated into the prepara cleaved, which, in the worst case scenario, can result in tions of the prior art either since this leads to incompatibili destruction of the hair. Furthermore, hair and scalp are parts ties (Substance deposits, precipitations, viscosity losses, of the body which, on account of their position, are exposed etc.). The sensory and tactile properties of conventional to a considerable amount of UV radiation when out and preparations thickened with carbomers or cellulose deriva about outdoors. tives also do not correspond to consumers' requirements since they are perceived as greasy and slippery. 0007 One aim of hair care and thus also of the present invention is to retain the natural state of freshly grown hair 0013. It is also an object of the present invention to over as long a period as possible and, in the case of loss, to provide formulation variants which have improved sensory US 2007/004 1925 A1 Feb. 22, 2007

and tactile properties compared with preparations of the The hair is also less sensitive to electrostatic charging. The prior art. In particular, it was also to provide preparations most important hair-conditioning Substances, generally cat whose biopolymer constituents can be released to a consid ionic polymers, are the polymeric quaternary ammonium erable degree from the formulations for hair and scalp care. compounds. Cationic cellulose derivatives and polysaccha rides can also be used. Furthermore, silicone compounds are 0014 Hair washing also plays a central role in human also used for conditioning. body care. The cleansing of the hair and of the scalp of grease produced by the body, skin peeling, dirt and odors is 0020. However, hair washing with aggressive surfactants a basic human requirement. can also stress the hair, at least reduce its appearance or the appearance of the hairstyle overall. For example, certain 0.015 To satisfy this requirement, until into the 20th water-soluble hair constituents (e.g. urea, uric acid, Xan century, man only had soap at his disposal which, on account thine, keratin, glycogen, citric acid, lactic acid) can be of its alkaline pH, was not well tolerated by the scalp and the leached out as a result of hair washing. eye mucosa and often left behind deposits of lime soaps in the hair. The 1930s saw the first alkyl sulfate-containing 0021. The prior art lacks shampoo formulations which shampoo. Since the middle of the 1960s, alkyl ether sulfates care for damaged hair in a satisfactory way. It is therefore an and other Surfactants have captured the shampoo market. object to also overcome these disadvantages of the prior art. Using these, it is possible to avoid the disadvantages of 0022. The object of the present invention is therefore also soap-containing preparations. Nowadays modern shampoos to provide an alternative cosmetic cleansing and care prepa not only have to cleanse the hair and be well tolerated, but ration which is characterized in particular by good skin and they should also care for the hair and increase its styleability hair compatibility, good foaming behavior and pleasant hair and optical attractiveness. care and styling. 0016 Hair shampoos comprise a large number of differ 0023 This bundle of objects is achieved by a cosmetic ent components in order to meet the individual requirements and/or dermatological preparation corresponding to the placed on the product. main claims. Preferred embodiments of the preparation are 0017. The cleaning power of the shampoo is brought disclosed in the dependent claims. Moreover, the invention about by the presence of anionic, amphoteric and nonionic also covers the use of the preparations on the skin and/or the Surfactants as Surface-active compounds in the preparations. hair. Moreover, Surfactants ensure the foaming ability of the 0024. It has surprisingly been found, and herein lies the hair-cleansing compositions. Moreover, when choosing the attainment of these objects, that a cosmetic preparation surfactants, their insensitivity to water hardness, their bio comprising degradability, their compatibility with other components of the preparation and also their price are important. A much 0025 a.) protein hydrolyzates from silk, pashmina, used shampoo Surfactant is, for example, alkyl ether Sulfate. cashmere wool, merino wool and/or mohair, 0018 Moreover, shampoos comprise a series of consis 0026 b.) extract from the mussel threads of mussels, tency regulators which give the preparation the desired the so-called byssus threads, and Viscosity. These thickeners bring about an enlargement of 0027 c.) sericin and/or sericin hydrolyzates and the surfactant micelles and/or swelling of the water phase of optionally the preparation. Thickeners can be chosen from classes of substances which are chemically very different. For 0028 d.) additionally biogenic and/or functional example, electrolytes (e.g. sodium chloride), alkanolamides amino acids, such as carnithine, creatine, taurine and/or (e.g. fatty acid monoethanolamide), fatty alcohols with low glutathione degrees of ethoxylation (e.g. diethylene glycol monolauryl ether), ethers with high degrees of ethoxylation, esters and perceptibly and visibly improves the skin and hair prop diesters, and polymeric thickeners, inter alia, are used. The erties. polymeric thickeners include, for example, cellulose ethers. Moreover, polyacrylates and hydrocolloids are also used as 0029. In this connection, the interplay and the resulting thickeners. Polymeric thickeners have the major advantage synergistic effect of the special protein hydrolyzates from that the Viscosity produced by them is largely temperature the biogenic fibers. Such as, for example, pashmina or independent. merino wool, silk and mussel byssus with osmolytic amino acids, e.g. taurine, for hair care, skin care and, in particular, 0.019 Besides perfumes and dyes and a series of com Scalp care is to be emphasized. pounds which increase the shelf-life of the preparations, different types of active ingredients have been added to hair 0030. In particular, the combinations of a.) cashmere shampoos in more recent times. Besides UV absorbers, wool preparations, b.) by SSus silk preparations and c.) silk Vitamins or plant extracts, these also include so-called hair bast sericin, and optionally the biogenic amino acids d.) conditioners, which care for the hair and improve its referred to above obtain a clearly detectable improvement in combability and its feel, and increase its shine. In contrast to the hair structure and sensory properties. most other constituents of shampoos, conditioners attach to 0031. The combination according to the invention of the the hair and remain there after rinsing. On account of their constituents a.-c. and optionally d. shows a synergism which molecular structure, they deposit themselves at the damaged is responsible for the Surprisingly extremely positive prop sites of the hair cuticle and smooth the hair. As a result, the erties of the cosmetic preparation. The individual constitu hair becomes less rough and brittle, the hairstyle is given ents are bound in a cosmetic preparation to give an active considerably more shine and can be combed more easily. ingredient complex and only develop their advantageous US 2007/004 1925 A1 Feb. 22, 2007 positive properties on the hair and the scalp in the compo 0045. As shampoo, surprisingly positive properties were sition according to the invention. also found, thus the hair treated with the preparations 0032. In internal studies, it was shown that the prepara according to the invention looks extremely well cared for tions according to the invention bring about a tactile advan and can be styled easily. This is evident, for example from tage, in particular with regard to hair fullness, Suppleness the combability, the appearance and the fullness of the hair. and shine. These advantages are not observed through 0046) The constituent a.) according to the invention is cosmetic preparations which each comprise one or two of chosen from protein preparations from silk, pashmina, cash the individual components according to the invention. mere wool, merino wool and/or mohair. 0033. The combinations according to the invention 0047 Pashm is the Persian word for wool and pashmina stimulate the metabolism in the scalp and promote the and describes the fine, fleecy pashmina wool which origi moisture enrichment on the scalp and in the hair and are nates and is obtained from the heights of the Tibetan characterized in particular by good skin and hair compat Himalaya. As cosmetic product, Pashmisilk(R), for example ibility. In addition, the amino acid constituents deliver the is known, comprising a hydrolyzate from pashmina, merino factors back to skin and hair which, like “magnets, lead to wool and natural silk. the ideal moisture in the skin and its appendages. This has a positive effect particularly on the styleability of the hair, 0048 Protein hydrolyzates of cashmere wool have which threatens to lose its styleability as a result of electro already been described. They are manufactured and sold, for static charging as a result of too little moisture or moisture example by Laboratoires Serobiologiques, France and sold which is too rapidly volatile. as “Cashmilan'. 0034. As a result of the topical application of the prepa 0049 Protein hydrolyzates of merino wool or mohair ration on the skin and/or the hair, the following positive wool are likewise intended as constituents essential accord properties of the treated hair and/or skin, in particular, are ing to the invention. Mohair wool is obtained from the found: angora goat. 0035) improvement in the styleability of the hair, 0050. The protein hydrolyzate from pashmina, cashmere wool, merino wool and/or mohair essentially comprise 0036) avoidance of the negative effect of static charg amino acid, peptide and keratin hydrolyzates. ing of the hair, 0051 Preference is given to using hydrolyzed silk pro 0037 stabilizing effect on the hair structure, tein, for example as SilkproR) from Ikeda Corp. (CAS No.: 0038 caring for hair and scalp, particularly over a 96690-41-4). prolonged period following application, 0052 Known to a lesser degree is the fact that some types 0039 structure-smoothing effect, of mussel produce raw material for cosmetics. For example, mussel silk or byssus silk, also called golden sea wool or sea 0040 imparts natural shimmer and attractive volume silk, was in the past raw material for fashion, the legendary to the hair, “Golden Fleece'. However, the word “byssos' applies to 0041 the hair is easier to comb and easier to style, different fine fabrics, meaning that only with additional 0042 protects the hair and the scalp during blow designations or the circumstances can mussel silk be drying, inferred. 0053 For example, Mythuline(R), is known, an extract of 0043 protects against electrostatic charging by balanc the mussel threads of mussels produced by Laboratoires ing and equalizing the moisture level in the hair. Seporga. The extract contains microfibers with alternating 0044 Preferably, the preparations according to the inven groups of collagen and elastin which are held together by tion are prepared and sold in silicone-free form. fibroin, as the diagram below shows. US 2007/004 1925 A1 Feb. 22, 2007

a Part close to rock Pa?t close to mussel

Collagen Fibroin Easti

Representatio of the russed thread US 2007/004 1925 A1 Feb. 22, 2007

0054 The most significant subspecies of mussels are the protein preparations each constitute hydrolyzates of the North Sea mussels, Mediterranean mussels, sea dates and individual constituents a., b. and c. preferred according to New Zealand mussels. All of these types are found predomi the invention. The combination leads to a significantly nantly in shallow water where, with the help of their byssus, improved softness and Suppleness of the hair. In addition, they cling to rocks or to one another. The name mussels the shine of the hair is significantly improved, and by arose from this byssus, also the so-called moss, which they anchoring moisturizing factors in the hair, the styleability is use as tentacles, and which, as a result of a shift in Sound, significantly improved. gives not moss, but mussels. 0062) The preparation preferably comprises an amount of 0055. In the course of our life, many small movements from 0.001 to 50% by weight, based on the total mass of the cause great mechanical stress to our skin and hair. The preparation, in particular, 0.01 to 15%, preferably 0.05 to repetition of these stresses together with the deorganization 5%, of functional or biogenic amino acids, preferably with of the connective fibers (glycolization, elastin degradation, the amino acids taurine and/or creatine. collagen polymerization) leads to a loss in the elasticity and firmness of the skin, accelerates the aging process and thus 0063. The weight fractions of components a.-d. among wrinkling. Mussels have to overcome very similar physical one another can preferably assume the following ranges. stress situations to our skin and our hair. Their threads have 0064) a. 0.025-99% by weight, preferably 0.5-50% by to ensure firm hold to the substrate in order to be able to weight withstand the changing conditions of their environment (waves, becoming dry, fighting for space with other mussels, 0065 b. 0.025-99% by weight, preferably 0.5-50% by algae). Since nature can solve problems in exemplary fash weight ion, the mussel thread of Mytilus edulis, the mussel, consists 0.066) c. 0.025-99% by weight, preferably 0.5-50% by of three strong protein micro-fibers (elastin, exocollagen, weight fibroin) whose specific structure and biomechanical proper ties of the fibers simultaneously impart resistance and elas 0067 d. 0-50% by weight, preferably 0.01-15% by ticity. weight. 0068. On account of the constituents obtainable from the 0056. Here, elastin and exocollagen peptide alternate various protein preparations, it has proven particularly pre within the thread. The filament is completely covered by ferred for the cosmetic preparations to comprise a combi fibroin (silk from the sea). As a result of the refraction of nation of HYDROLYZED COLLAGEN (constituent b.), light at their surface, the silk fibers also appear shiny. Fibroin CAS No. 92113-31-0), HYDROLYZED ELASTIN (con is the essential constituent of silk, a thread-like, flexible and stituent b.), CAS No. 100085-10-7), HYDROLYZED lustrous Substance. Similarly to a prism, it gives the silk the KERATIN (constituent d.), CAS No. 69430-36-0), characteristic silky effect. The main effect of the silk threads HYDROLYZED SERICIN (constituent c.), CAS No. is to ensure the resistance and elasticity of the mussel 96690-41-4) and HYDROLYZED SILK (constituent al.), threads. CAS No. 73049-73-7). 0057 Elastin can be stretched up to 160% of its length 0069 Particular preference is given to a cosmetic prepa without tearing. Elastin is co-responsible for the elasticity of ration comprising 0.005-0.03% by weight of HYDRO the mussel threads. LYZED COLLAGEN, 0.005-0.03% by weight of HYDRO 0.058 An extract of these threads, referred to as mussel LYZED ELASTIN, 0.05-0.5% by weight of threads of mussels, the byssus threads, leads, in combination HYDROLYZED KERATIN, 0.01-0.5% by weight of with the constituents a.) and c.) according to the invention to HYDROLYZED SERICIN and 0.01-0.5% by weight of a moisturizing and strengthening effect of the hair. In HYDROLYZED SILK. addition, the synthesis of collagen I and III is increased. 0070 Preferably, the preparation according to the inven 0059) The additional effect of the silk shimmer improves tion additionally comprises taurine. Through the addition of the shine of the hair. taurine, its osmolyte effect is utilized, which brings about an 0060 Sericin has proven to be a third essential constitu increase in the amount of moisture on the scalp and the hair. ent of the preparations according to the invention. Sericin is This additional effect leads to a further improvement in the a protein substance from the cocoon of the silk spider which styleabilty of the hair. surrounds the raw silk thread. For example, Setakol(R), a 0071. Through the addition of taurine in the preparation hydrolyzate of the silk protein sericin, which is manufac according to the invention, an increase in moisture of the tured and sold by Pentapharm, Basle, is known. This is an scalp and/or of the hair is established. aqueous solution of the silk protein sericin. The advanta 0072. In particular, through the addition of taurine it is geous properties of sericin which are used according to the possible to avoid the annoying effect of static charging of the invention in combination with the properties of the constitu hair. ents a. and b. is that sericin binds with creatine in the skin and the hair and thus enables a protective effect. Sericin thus 0073. In this connection, this invention provides that leads to a protective function for the hair or skin treated with Surprisingly, in particular, products or preparations of prod the preparation according to the invention. ucts of biogenic amino acids, for example, taurine, together with preparations of sea silk, pashmina and silk bast sericin 0061 Preferably, the preparations according to the inven are to be regarded as being particularly advantageous. tion comprise PashmisilkR), SilkproR) and/or “Cashmilan as constituent a. according to the invention, Mythulinee as 0074 Taurine is to a limited extent an essential amino constituent b. and Setakol(R) as constituent c. These three acid which is found in the tissues of most types of animal. US 2007/004 1925 A1 Feb. 22, 2007

It does not serve as a building block of proteins but is present carbon atoms in the molecule. In cosmetics, preferably in many tissues in free form. Taurine is involved in a series straight-chain fatty alcohols with a chain length of 12-18 of physiological processes, e.g. the conjugation of bile acids, carbon atoms are used. These fatty alcohols are soft, color osmoregulation, detoxification of Xenobiotics, stabilization less masses, virtually nontoxic and well tolerated by the of cell membranes, control of the cellular calcium stream skin. Fatty alcohols are preferably used for producing hair and modulation of neuronal excitability. Taurine (2-amino treatments and styling creams, with cetyl alcohol and Stearyl ethanesulfonic acid) differs from other amino acids in that alcohol being attributed particular importance. the carboxyl group is replaced by a Sulfonic acid group and 0085 Waxes are fatty acid esters which occur in animal in that it is not incorporated into proteins. Taurine is thus not and vegetable products, but can also be produced syntheti an amino acid in the narrower sense. cally. Probably the best known naturally occurring wax is 0075. The production or provision of constituents a.-d. is beeswax, which comprises ceresin and myricin as main known to the person skilled in the art. The cosmetic and constituents. However, wax is a generic term for a series of dermatological preparations according to the invention can naturally or synthetically obtained substances which are comprise cosmetic auxiliaries as are customarily used in generally semi-solid, white, odorless masses which are Such preparations. insoluble in water. 0.076 For example, the cashmere hydrolyzate can be 0086. In the cosmetics sense, paraffins are white, odorless obtained by enzymatic hydrolysis of cashmere wool, sub masses of Straight-chain high molecular weight hydrocar sequent filtration and preservation. bons. Due to their properties being comparable with those of waxes, they are often also referred to as petroleum waxes. 0077. The extract from mussel threads, the so-called byssus threads, is preferably obtained from the mussel 0087 Vaseline is a mixture of branched-chain paraffins Mytilus edulis. The mussel threads are hydrolyzed for sev with a low content of cyclic paraffins. It is a soft, transparent eral hours at at least 70° C. in an acidic aqueous solution. mass which is insoluble in water and has a low intrinsic odor The pH is adjusted to 5-6 and the liquid product is decolored which is produced during petroleum processing. by filtering with activated carbon and then centrifuged. The 0088 Paraffin oil is a mixture of saturated liquid hydro product is then sterilized by means of sterile filtration and carbons. It is insoluble in water, but miscible with fatty Stored for 12 h at 65° C. alcohols and waxes. It is used as additive in hair color 0078. An additional content of antioxidants is generally compositions for regulating consistency. preferred in cosmetic and/or dermatological preparations. 0089 Solvents play a considerable role in cosmetics. Of 0079 The compositions according to the invention can, the large number of solvents which are available, ethanol is for example, be in the form of preparations sprayable from of greatest importance. It is used for producing hair tonics in aerosol containers, squeezable bottles or by a pump, spray or which, on account of its disinfecting properties, at the same foaming device, but also in the form of a composition which time fulfils the function of an active ingredient. can be applied from standard bottles and containers. 0090 Auxiliaries can be used in order to improve certain 0080 For the purposes of the present invention, suitable properties of hair care compositions, e.g. consistency, ther propellants for cosmetic or dermatological preparations mal stability and photostability, appearance and odor, and to which are sprayable from aerosol containers are the custom facilitate their production. For example, the following are ary known, readily Volatile, liquefied propellants, for added as required: example dimethyl ether, hydrocarbons (propane, butane, 0091 emulsifiers, in order to reduce the interfacial isobutane), which can be used on their own or in a mixture tension between two immiscible phases so much that with one another. Compressed air, nitrogen, nitrogen dioxide their fine mixing is possible, or carbon dioxide or mixtures of these Substances are also to be used advantageously. 0092 thickeners in order to increase the stability of the emulsions and to adjust their viscosity, 0081. The person skilled in the art is of course aware that there are propellant gases which are nontoxic per se, which 0093 UV absorbers in order to improve the photosta would in principle be suitable for realizing the present bility of the dyes present in hair care compositions and invention in the form of aerosol preparations, but which other photosensitive components. In addition, they nevertheless have to be dispensed with due to an unaccept serve to protect the hair against the effects of light. able effect on the environment, or other accompanying 0094 Preservatives, in order to prevent microbial circumstances, in particular fluorinated hydrocarbons and decomposition. chlorofluorocarbons (CFCs). 0082 Hair care compositions refers to a large number of 0.095 Antioxidants, in order to prevent changes in odor products, the most important representatives of which are which can be caused by oxidation processes. pretreatment compositions, hair tonics and hair treatment 0096. Dyes, in order to impart a pleasing appearance to compositions. hair care compositions. 0.083 Basic substances for hair care compositions are, for 0097 Perfume oils in order to impart a pleasant odor to example, fatty alcohols, waxes, paraffins, Vaseline, paraffin hair treatment compositions and to conceal secondary oil and solvents. odors of the raw materials. 0084. Fatty alcohols are, for example, straight- or 0098 Quaternary ammonium compounds are an impor branched-chain aliphatic monohydric alcohols having 6-22 tant group of the special active ingredients which are used US 2007/004 1925 A1 Feb. 22, 2007 for producing hair care compositions. Hair care composi 0105. A cosmetic preparation in the form of a lotion tions, in particular hair treatments, are given essential prop which is not rinsed out, in particular a lotion for arranging erties such as improving combability and feel and prevent the hair, a lotion which is used while blow-drying the hair, ing static charging of the hair, primarily through the use of a styling and treatment lotion, is generally an emulsion and quaternary ammonium compounds. This property can addi comprises the combinations according to the invention. tionally be improved through the content of taurine. However, it is in Some cases advantageous if the lotion according to the invention is in the form of a microemulsion 0099. The properties of quaternary ammonium com for an aqueous or aqueous-alcoholic solution. pounds are determined by the cationic group on the one hand and by the type of lipophilic radicals of this group on the 0106 According to the invention, cosmetic preparations other hand. Of suitability are, for example, the compounds for the treatment and care of the hair can be in the form of in which one to two radicals are longer-chain alkyl groups, gels which comprise organic thickeners, e.g. gum arabic, Such as lauryl, cetyl or Stearyl groups, and the remaining Xanthan gum, Sodium alginate, cellulose derivatives, pref radicals are methyl groups. Products of this type are pref erably methylcellulose, hydroxymethylcellulose, hydroxy erably used as chlorides, bromides and methosulfates. ethylcellulose, hydroxypropylcellulose, hydroxypropylm ethylcellulose or inorganic thickeners, e.g. aluminum 0100 Also suitable are polymeric quaternary ammonium silicates, such as, for example, bentonites, or a mixture of compounds, macromolecules whose essential feature is the polyethylene glycol and polyethylene glycol Stearate or presence of a plurality of quaternary ammonium groups in distearate. The thickener is present in the gel e.g. in an the molecule. As a result, their ability to adhere to the hair amount between 0.1 and 30% by weight, preferably between is considerably increased. 0.5 and 15% by weight. 0101 Cationic surfactants to be used particularly advan 0.107 The percentages given above refer to the total tageously are weight of the preparations. 1. alkylamines 0108. The preparations according to the invention can ... alkylimidazoles comprise cosmetic auxiliaries, as are customarily used in Such preparations, e.g. preservatives, perfumes, Substances ... ethyoxylated amines and for preventing foaming, foam stabilizers, dyes, pigments ... quaternary surfactants which have a coloring effect, thickeners, surface-active Substances, emulsifiers, softening, moisturizing and/or 5. ester quats. humectant Substances, re-fatting agents, fats, oils, waxes, 0102 Quaternary surfactants contain at least one Natom alcohols, polyols and the toxicologically compatible ethers which is covalently bonded to 4 alkyl or aryl groups. and esters thereof, branched and/or unbranched hydrocar Irrespective of the pH, this leads to a positive charge. The bons, further antioxidants, stabilizers, pH regulators, con cationic Surfactants used according to the invention can also sistency regulators, bactericides, deodorants, antimicrobial preferably be chosen from the group of quaternary ammo Substances, antistats, UV absorbers, complexing and seques nium compounds, in particular benzyltrialkylammonium tering agents, pearlescent agents, polymers, electrolytes, chloride, also alkyltrialkylammonium salts, for example organic solvents, silicone derivatives, plant extracts, Vita cetyltrimethylammonium chloride or bromide, alkyldimeth mins and/or other active ingredients or other customary ylhydroxyethylammonium chlorides or bromides, dialky constituents of a cosmetic or dermatological formulation. ldimethylammonium chlorides or bromides, alkylamide eth Solubility promoters, e.g. for incorporating hydrophobic yltrimethylammonium ether Sulfates, alkylpyridinium salts, components, such as, for example perfume preparations, for example lauryl- or cetylpyrimidinium chloride, imida may also be present. Zoline derivatives and compounds with cationic character, Such as amine oxides, for example alkyldimethylamine 0.109 The total amount of the auxiliaries is, for example, oxides or alkylaminoethyldiemthylamine oxides. In particu 0.001 to 15% by weight, preferably 0.01 to 10% by weight, lar, cetyltrimethylammonium salts are to be used advanta in each case based on the total weight of the preparation. geously. 0110. The amount of thickeners is, for example, 0.05 to 0103 Monomeric or polymeric quaternary ammonium 5.0% by weight, preferably 0.1 to 3.0% by weight, in compounds are used widely in hair rinses and hair treat particular 0.15 to 2.0% by weight, in each case based on the ments, e.g. in concentrations of 0.5-5% by weight. These total weight of the preparation. include cetrimonium chloride, as is Supplied under the name 0111. The water content of the preparations is, for Dehyduart A by Henkel, or distearoylethylhydroxyethyl example, 60 to 95% by weight, preferably 75 to 95% by monium methosulfate, as is Supplied under the name Dehy weight, in particular 80 to 90% by weight, in each case based quart F 75 by Henkel. on the total weight of the preparation. 0104. If the cosmetic or dermatological preparations are 0112 To protect the formulation and/or the hair to be present in the form of a lotion which is rinsed out and used, treated, all antioxidants which are customary or suitable for for example, before or after bleaching, before or after cosmetic and/or dermatological applications can be used. shampooing, between two shampooing steps, before or after permanent wave treatment, then these are here, for example, 0113. The total amount of the antioxidants is, for emulsions which optionally comprise Surface-active Sub example, 0.001 to 2% by weight, preferably 0.01 to 1% by stances whose concentration can be between 0.1 and 10% by weight, in each case based on the total weight of the weight, preferably between 0.2 and 5% by weight. preparation. US 2007/004 1925 A1 Feb. 22, 2007

0114. Further antioxidants are advantageously chosen 0119) sulfonic acid derivatives of 3-benzylidenecam from the group consisting of amino acids (e.g. glycine, phor, Such as, for example, 4-(2-oxo-3-bornylidenem histidine, tyrosine, tryptophan) and derivatives thereof, imi ethyl)benzenesulfonic acid, 2-methyl-5-(2-oxo-3- dazoles (e.g. urocanic acid) and derivatives thereof, pep bornylidenemethyl)sulfonic acid and its salts. tides, such as D.L-carnosine, D-carnosine, L-carnosine and derivatives thereof (e.g. anserine), carotenoids, carotenes 0.120. It may also be advantageous to add UV-A filters (e.g. C-carotene, B-carotene, lycopene) and derivatives which have hitherto usually been present in cosmetic prepa thereof, chlorogenic acid and derivatives thereof lipoic acid rations to preparations according to the invention. The and derivatives thereof (e.g. dihydrolipoic acid), aurothio glucose, propylthiouracil and other thiols (e.g. thioredoxin, amounts used for the UV-B combination can be used. glutathione, cysteine, cystine, cystamine and the glycosyl, 0121 The preparations according to the invention can be N-acetyl, methyl, ethyl, propyl, amyl, butyl and lauryl, palmitoyl, oleyl, Y-linoleyl, cholesteryl and glyceryl esters prepared in the usual manner by mixing the individual thereof) and salts thereof, dilauryl thiodipropionate, dis constituents. The active ingredients of the combinations tearyl thiodipropionate, thiodipropionic acid and derivatives according to the invention or else the premixed constituents thereof (esters, ethers, peptides, lipids, nucleotides, nucleo of the combinations according to the invention can be added sides and salts), and Sulfoximine compounds (e.g. buthion in the mixing operation. ine Sulfoximine, homocysteine Sulfoximine, buthionine Sul fones, penta-, hexa-, heptathionine Sulfoximine) in very low 0.122 The pH of the preparations can be adjusted in a tolerated doses (e.g. pmol to Lmol/kg), also (metal) chelat known manner by adding acids or bases, preferably by ing agents (e.g. C-hydroxy fatty acids, palmitic acid, phytic adding buffer Substances, e.g. based on citric acid/citrate or acid, lactoferrin), C-hydroxy acids (e.g. citric acid, lactic phosphoric acid phosphate buffer mixtures. The pH is pref acid, malic acid), humic acid, bile acid, bile extracts, biliru erably below 10, e.g. in the range 2-7, in particular in the bin, biliverdin, EDTA, EGTA and derivatives thereof, unsat range 3-5. urated fatty acids and derivatives thereof (e.g. Y-linolenic acid, linoleic acid, oleic acid), folic acid and derivatives 0123 The examples below are intended to illustrate the thereof, vitamin C and derivatives (e.g. ascorbyl palmitate, present invention without limiting it. Unless stated other Mg ascorbyl phosphate, ascorbyl acetate), tocopherols and wise, all amounts, proportions and percentages are based on derivatives (e.g. vitamin E acetate), Vitamin A and deriva the weight and the total amount or on the total weight of the tives (vitamin A palmitate) and coniferyl benzoate of ben preparations. Zoin resin, rutinic acid and derivates thereof, C-glycosylru tin, ferulic acid, furfurylideneglucitol, carnosine, 0.124 Protein hydrolyzates from silk, pashmina, cash butylhydroxytoluene, butylhydroxyanisole, nordihydroguai mere wool, merino wool and/or mohair, extract from the acic acid, nordihydroguaiaretic acid, trihydroxybutyrophe mussel threads of mussels, the so-called by SSuS threads, and none, uric acid and derivatives thereof mannose and deriva sericin and/or sericin hydrolyzates and optionally tives thereof, zinc and derivatives thereof (e.g. ZnO, ZnSO), selenium and derivatives thereof (e.g. selenom ethionine), stilbenes and derivatives thereof (e.g. stilbene EXAMPLES oxide, trans-Stilbene oxide) and the derivatives (salts, esters, ethers, Sugars, nucleotides, nucleosides, peptides and lipids) Example 1 Suitable according to the invention of these specified active ingredients. Cleansing Gel 0115 Furthermore, preparations according to the inven 0125) tion can advantageously comprises Substances which absorb UV radiation in the UV-B region, where the total amount of the filter substance is, for example, 0.001% by weight to 30% by weight, preferably 0.05% to 10% by weight, in % by wt. particular 0.1 to 1.0% by weight, based on the total weight of the preparations in order to provide cosmetic preparations Protein hydrolyzate (silk, pashmina, S.OO which protect the hair and/or the skin from the entire range byssus threads, sericin) of ultraviolet radiation. They can also be used as Sunscreens Sodium laureth Sulfate 13.00 for the hair or the skin, in particular the scalp. Sodium cocoamphoacetate 2.OO 0116. If the emulsions according to the invention com Citric acid OSO prise UV-B filter substances, these may advantageously be Dicaprylyl ether 8.OO water-soluble. Advantageous water-soluble UV-B filters are, Glyceryl linoleate 2.50 for example: Glycerin S.OO 0.117 salts of 2-phenylbenzimidazole-5-sulfonic acid PEG-150 Distearate O.82 and its sodium, potassium or triethanolammonium salt, Sodium chloride 1.62 and the 2-phenylbenzimidazole-5-sulfonic acid itself: Antioxidants C.S. Preservative C.S. 0118 sulfonic acid derivatives of benzophenones, Water ad 100.000 preferably 2-hydroxy-4-methoxybenzophenone-5-sul fonic acid and its salts; US 2007/004 1925 A1 Feb. 22, 2007

Example 2 Example 5 Bath Preparation Cleansing Gel 0126)O126 0129

% by wt. % by wt. Protein hydrolyzate (cashmere, byssus 7.50 threads, sericin) Protein hydrolyzate (silk, merino wool, 12.75 Sodium laureth Sulfate 13.00 Cocoamidopropylbetaine 2.OO pashmina, byssus threads, sericin) Citric acid OSO Sodium laureth Sulfate 13.00 Dicaprylyl ether 8.OO Disodium cocoylglutamate 2.00 Glyceryl linoleate 2.50 Citric acid O.65 Glycerin S.OO PEG-150 Distearate O.82 Cococaprylate caprate 8.00 Sodium chloride 1.62 Glyceryl linoleate 2.50 Antioxidants C.S. Glycerin S.OO Preservative C.S. PEG-150 Distearate 1.00 Water ad 100.000 Sodium chloride 1.63 Antioxidants C.S. Preservative C.S. Example 3 Shower Gel Example 6 O127) p Shampoo % by wt. O130 Protein hydrolyzate (silk, pashmina, 1S.OO byssus threads, sericin) Sodium laureth sulfate 13.00 % by wt. Sodium cocoamphopropionate 2.OO Citric acid O.23 Protein hydrolyzate (pashmina, byssus 8.00 Dicaprylyl ether 8.OO threads, sericin) Glyceryl linoleate 3.00 Sodium laureth Sulfate 9.00 Glycerin S.OO Sodium cocoamphoacetate 6.OO PEG-150 Distearate O.85 Citric acid 1.20 Sodium chloride 1.63 Paraffinum liquidum 2.00 Antioxidants C.S. Glyceryl linoleate 1.00 Preservative C.S. Glycerin S.OO Water ad 100.000 PEG-150 Distearate O.30 Antioxidants C.S. Preservative C.S. Water ad 100.000 Example 4 Cleansing Preparation Example 7 0128 Foaming Shower Gel O131 % by wt. Protein hydrolyzate (silk, merino wool, 2.75 pashmina, byssus threads, sericin) Sodium laureth Sulfate 9.OO % by wt. Sodium cocoamphopropionate 6.OO Citric acid O4O Protein hydrolyzate (pashmina, byssus 3.00 Dicaprylyl ether 8.OO threads, sericin) Glyceryl linoleate 2.50 Sodium laureth Sulfate 9.OO Glycerin S.OO Sodium cocoamphoacetate 6.OO PEG-150 Distearate O.83 Citric acid 1.20 Sodium chloride O.81 Paraffinum liquidum 2.OO Antioxidants C.S. Glyceryl isostearate 1.OO Preservative C.S. Glycerin S.OO Water ad 100.000 PEG-150 Distearate O.30 US 2007/004 1925 A1 Feb. 22, 2007 10

Example 8 Examples 9, 10, 11 Conditioner Shampoo with Pearlescence Shampoo 0133) 0132)

9 10 11 Protein hydrolyzate % by wt. (Cashmere, silk, byssus 5.5 4.5 9.O threads, sericin, taurine) Polymer JR 400 O.S O.S O.S Protein hydrolyzate (pashmina, byssus 7.00 Texapon K 14 S special 4.0 S.O 4.5 threads, sericin, taurine, creatine) Plantacare 2000 9.0 8.0 8.5 s s s Pearlizing agent 2.0 2.0 2.O Sodium laureth Sulfate 9.00 Rewopol SBCS 50 6.O 5.5 6.2 Atlas G-4280 3.2 3.5 3.0 Sodium cocoamphoacetate 6.OO Preservative, perfume, C.S C.S C.S Citric acid 120 thickener, pH adjustment and solubilizer Paraffinum liquidum 2.00 Water, completely de- ad 100.0 ad 100.0 ad 100.0 mineralized Sorbitanisostearate 1.00 Glycerin S.OO PEG-150 Distearate O.30 Examples 12-16 PIT Emulsions 0134)

Examples

12 13 14 15 16 Protein hydrolyzate 1S.O 8.5 2.0 17.0 12.0 (Pashmina, silk, byssus threads, sericin) Glyceryl monostearate Self-emulsifying O.SO 3.00 2.OO 4.OO Polyoxyethylene(12) cetylstearyl ether S.OO 1.OO 1...SO Polyoxyethylene(20) cetylstearyl ether 2.OO Polyoxyethylene(30) cetylstearyl ether S.OO 1.OO Stearyl alcohol 3.00 O.SO Cetyl alcohol 2.50 1.00 1...SO 2-Ethylhexyl methoxycinnamate S.OO 8.OO 2,4-Bis-(4-(2-ethylhexyloxy-)-2- 1...SO 2.OO 2.50 hydroxy)phenyl)-6-(4-methoxyphenyl)- (1,3,5)-triazine -(4-tert-Butylphenyl)-3-(4- 2.OO methoxyphenyl)-1,3-propanedione Diethylhexyl Butamindotriazone 1.00 2.00 2.OO Ethylhexyl Triazone 4.OO 3.00 4.OO 4-Methylbenzylidene camphor 4.OO 2.OO Octocrylene 4.OO 2.50 Phenylene-1,4-bis(monosodium, OSO 1.60 benzimidazyl-5,7-disulfonic acid Phenylbenzimidazole sulfonic acid O.SO 3.00 C12–15 Alkyl benzoate 2.50 S.OO Titanium dioxide O.SO 1.00 3.00 2.OO Zinc oxide 2.00 3.00 OSO 1.OO Dicaprylyl ether 3.SO Butylene glycol dicaprylatedicaprate S.OO 6.OO Dicaprylyl carbonate 6.OO 2.OO Dimethicone polydimethylsiloxane OSO 1.OO Phenylmethylpolysiloxane 2.00 OSO O.SO Shea butter 2.00 O.SO PVP hexadecene copolymer O.SO OSO 1.OO Glycerin 3.00 4.OO 3.00 2.OO Tocopherol acetate O.SO O.25 1.OO Serinol 2.00 S.OO 1.OO 2.OO 3.00 Lactic acid 2.40 6.OO 1.2O 3.60 Taurine O.3 O.S Sea salt S.OO 2.50 alpha-Glucosylrutin O.10 O.2O Preservative C.S. C.S. C.S. C.S. C.S. US 2007/004 1925 A1 Feb. 22, 2007 11

-continued Examples

12 13 14 15 16

Ethanol 3.00 2.00 1...SO 1.OO Perfume C.S. C.S. C.S. C.S. C.S. Water ad ad ad ad ad 100 100 100

Examples 17-21 O/W Cream 0135)

Examples

17 18 19 21

Protein hydrolyzate 4.OO 13.5 26.OO 7.OO (mohair, cashmere, silk, byssus threads, sericin) Glyceryl Stearate citrate 2.OO 2.OO Glyceryl Stearate, self-emulsifying 4.OO 3.00 PEG-40 stearate 1.OO Polyglycerol-3-methylglucose distearate 3.00 Sorbitan stearate 2.OO Stearic acid 1.OO Polyoxyethylene(20) cetylstearyl ether Stearyl alcohol S.OO Cetyl alcohol 3.00 2.OO 3.00 Cetylstearyl alcohol 2.OO C12–15 Alkyl benzoate Caprylicicapric triglyceride S.OO 3.00 4.OO 3.00 3.00 Octyldodecanol 2.OO 2.OO Dicaprylyl ether 4.OO 2.OO 1.OO Paraffinum liquidum S.OO 2.OO 3.00 Titanium dioxide 1.OO 4-Methylbenzylidene camphor 1.OO -(4-tert-Butylphenyl)-3-(4- OSO methoxyphenyl)-1,3-propanedione Serinol S.OO 4.OO S.OO 1.OO 2.OO Lactic acid 4.80 6.OO 1.2O Sea salt S.OO Taurine O.3 O.3 Betaine Tocopherol O.1 Biotin O.OS Ethylenediamine tetraacetic acid trisodium O.1 O.10 O.1 Preservative C.S. C.S. C.S. C.S. C.S. Xanthan gum Polyacrylic acid 3.00 Sodium hydroxide solution 45% C.S. C.S. C.S. C.S. C.S. Glycerol 1.OO 1.OO S.OO 3.00 Butylene glycol 3.00 Perfume C.S. C.S. C.S. C.S. C.S. Water ad ad ad ad ad 100 1OO 100 100 US 2007/004 1925 A1 Feb. 22, 2007 12

Example 22 -continued Care Preparation % ww Protein Hydrolyzate METHYLPARABEN O.2056 (pashmina, cashmere, silk, byssus threads, sericin) in the NIACINAMIDE O.1OOO form of a mixture of Pashmisilk(R, SilkproR), Mythuline(R), ORYZANOL O.OSOO Setakol(R) and water PANTHENOL O.6OOO PHENOXYETHANOL O.O161 PHYTANTROL O.1OOO Example 23 PROPYLPARABEN O.1008 SODIUM CITRATE O.O3SO Shampoo TAURINE O.2OOO WATER (AQUA) 84.2046 0136 Example 25 0.% ww Styling Spray BENZOIC ACID 0.1375 CALCIUM CHLORIDE O.O378 0.138) CITRIC ACID OSOOO DISODIUMPEG-S LAURYLCITRATE 2.2320 SULFOSUCCINATE FRAGRANCE (PERFUME) O.6OOO % Wiw HYDROLYZED COLLAGEN O.O166 HYDROLYZED ELASTIN O.O167 CALCIUM CHLORIDE O.O151 HYDROLYZED KERATIN O.1500 CETEARETH-20 O.1500 HYDROLYZED SERICIN O.O700 CETRIMONIUM CHLORIDE O.OSOO HYDROLYZED SILK O.0667 CITRIC ACID O.O100 METHYLPARABEN O.OO38 FRAGRANCE (PERFUME) O.3OOO NIACINAMIDE O.1OOO HYDROLYZED COLLAGEN O.OO83 ORYZANOL O.OSOO HYDROLYZED ELASTIN O.OO84 PANTHENOL O3OOO HYDROLYZED KERATIN 0.0750 PEG-2OO HYDROGENATED O4SOO HYDROLYZED SERICIN O.O3SO GLYCERYL PALMATE HYDROLYZED SILK O.O334 PEG-3 DISTEARATE 2.OOOO LAURTRIMONIUM CHLORIDE 0.0075 PEG-4O HYDROGENATED CASTOR O3OOO METHYLPARABEN O.OO19 OIL NIACINAMIDE O.O2OO PEG-7 GLYCERYL COCOATE O.OSOO PANTHENOL 0.3750 PHENOXYETHANOL O.O107 PEGPPG-15, 15 DIMETHICONE 1.OOOO POLYQUATERNIUM-10 OSOOO PEG-4O HYDROGENATED CASTOR O.6OOO SODIUM BENZOATE O.2950 OIL SODIUM CHLORIDE 1.2000 PHENOXYETHANOL O.OOS4 SODIUM COCOAMPHOACETATE 2.1900 POLYQUATERNIUM-11 O.O600 SODIUM LAURETH SULFATE 10.218O SODIUM BENZOATE O.2OOO SODIUM SALICYLATE O4(OOO SODIUM BISULFITE O.O150 TAURINE O.1OOO TAURINE O.OSOO TETRASODIUM IMINODISUCCINATE OSOOO VPVA COPOLYMER 3.7500 WATER (AQUA) 77.5052 WATER (AQUA) 93.23OO

Example 24 Example 26

Rich Mask Conditioner 0137) 0139)

% Wiw % Wiw

CALCIUM CHLORIDE O.O378 ALPHA-ISOMETHYLIONONE O.O276 CETEARYLALCOHOL 6.OOOO BENZYL SALICYLATE O.O131 CETRIMONIUM CHLORIDE 1.OOOO BIS-DIGLYCERYL 1.6000 FRAGRANCE (PERFUME) O.SOOO POLYACYLADIPATE-2 GLYCERIN 3.87OO BUTYLPHENYLMETHYLPROPIONAL O.O104 HYDROLYZED COLLAGEN O.O249 CALCIUM CHLORIDE O.O378 HYDROLYZED ELASTIN O.O2S1 CETEARYLALCOHOL 2.OOOO HYDROLYZED KERATIN O.22SO CETRIMONIUM CHLORIDE 1.OOOO HYDROLYZED SERICIN O.1 OSO CITRONELLOL O.OO91 HYDROLYZED SILK O.1 OO1 COUMARIN 0.0075 LANOLIN 2.OOOO EUGENOL O.OO8O LANOLINALCOHOL O.SOOO FRAGRANCE (PERFUME) O.2970 US 2007/004 1925 A1 Feb. 22, 2007 13

17. The preparation of claim 14, wherein the preparation -continued comprises, based on a total weight of (a) to (d), from 1% to 25% by weight of (a), from 1% to 25% by weight of (b), % Wiw from 1% to 25% by weight of (c), and from 0.1% to 10% by GERANIOL O.O113 weight of (d). GLYCERIN 3.87OO 18. The preparation of claim 12, wherein the preparation HYDROLYZED COLLAGEN O.OO83 HYDROLYZED ELASTIN O.OO84 further comprises from 0.001% to 30% by weight of at least HYDROLYZED KERATIN 0.0750 one antioxidant, based on a total weight of the preparation. HYDROLYZED SERICIN O.O3SO 19. The preparation of claim 13, wherein the preparation HYDROLYZED SILK O.O334 further comprises from 0.05% to 20% by weight of at least HYDROXYISOHEXYL 3- 0.0075 CYCLOHEXENE CARBOXALDEHYDE one antioxidant, based on a total weight of the preparation. HYDROXYPROPYL O.2SOO 20. The preparation of claim 14, wherein the preparation METHYLCELLULOSE further comprises from 0.1% to 10% by weight of at least LINALOOL O.OO81 one antioxidant, based on a total weight of the preparation. METHYLPARABEN 0.2527 NIACINAMIDE O.1OOO 21. The preparation of claim 12, wherein the preparation ORYZANOL O.OSOO comprises HYDROLYZED COLLAGEN, HYDROLYZED PANTHENOL O3OOO ELASTIN, HYDROLYZED KERATIN, HYDROLYZED PHENOXYETHANOL O.OOS4 SERICIN, and HYDROLYZED SILK. PROPYLENE GLYCOL OSOOO PROPYLPARABEN O.10O3 22. The preparation of claim 12, wherein the preparation SODIUM CITRATE 0.0375 is suitable for topical application to at least one of hair and TAURINE O.1OOO skin. WATER (AQUA) 89.2366 23. A cosmetic preparation comprising HYDROLYZED Cationic cellulose derivate from Amerchol, COLLAGEN, HYDROLYZED ELASTIN, HYDRO ‘Myreth sulfate 70% from Cognis (AES) LYZED KERATIN, HYDROLYZED SERICIN, and Decyl glucoside 50% from Cognis (APG) HYDROLYZED SILK. 'Citric acid alkyl polyglycol ester sulfosuccinate, disodium salt 38% from Goldschmidt (ACS) 24. The preparation of claim 23, wherein the preparation PEG-80 sorbitan laurate 73% from Uniqema (PSE) comprises from 0.005% to 0.03% by weight of HYDRO LYZED COLLAGEN, from 0.005% to 0.03% by weight of HYDROLYZED ELASTIN, from 0.05% to 0.5% by weight 1-11. (canceled) of HYDROLYZED KERATIN, from 0.01% to 0.5% by 12. A cosmetic preparation comprising weight of HYDROLYZED SERICIN, and from 0.01% to 0.5% by weight of HYDROLYZED SILK, in each case (a) a protein hydrolyzate from at least one of silk, pash based on a total weight of the preparation. mina, cashmere wool, merino wool and mohair, 25. The preparation of claim 24, wherein the preparation (b) an extract from mussel threads of mussels, further comprises from 0.001% to 30% by weight of at least one antioxidant, based on a total weight of the preparation. (c) at least one of sericin and a hydrolyzate of sericin, and 26. The preparation of claim 12, wherein the preparation (d) optionally, one or more amino acids which are at least is present as at least one of a hydrous preparation, an one of biogenic and functional. emulsion, a gel, a hydrodispersion, an aqueous Surfactant 13. The preparation of claim 12, wherein the preparation Solution, a microemulsion. comprises (d) and (d) comprises at least one of carnitine, 27. A hair care composition which comprises the prepa creatine, taurine and glutathione. ration of claim 12. 14. The preparation of claim 13, wherein the preparation 28. A shampoo which comprises the preparation of claim comprises taurine. 12. 15. The preparation of claim 12, wherein the preparation 29. A hair care composition which comprises the prepa comprises, based on a total weight of (a) to (d), from 0.025% ration of claim 23. to 99% by weight of (a), from 0.025% to 99% by weight of 30. A method of cleansing or caring for at least one of hair (b), from 0.025% to 99% by weight of (c) and from 0% to and scalp, wherein the method comprises applying to at least 50% by weight of (d). one of hair and scalp the preparation of claim 12. 16. The preparation of claim 15, wherein the preparation 31. A method of cleansing or caring for at least one of hair comprises, based on a total weight of (a) to (d), from 0.5% and scalp, wherein the method comprises applying to at least to 50% by weight of (a), from 0.5% to 50% by weight of(b), one of hair and scalp the preparation of claim 23. from 0.5% to 50% by weight of (c), and from 0.01% to 50% by weight of (d). k k k k k