Clark Magnet High School Preparation for AP Chemistry SUMMER ASSIGNMENT ( 5 P a r t s )

 Familiarize yourself with the Periodic Table. In general Chemistry you were given a periodic table with the names of all the elements included. In AP Chemistry you are given only the symbols. You should recognize quickly the symbols (and be able to name them, spelling counts) and their positions on the Periodic Table of the first 20 elements. The last page of this packet has a Periodic Table for your reference.

 Memorize the list of sixty useful ions. You should be able to write the symbol of the ion given the name and vice versa. • Included in this packet are: (1) a list of ions by name, (2) a list of ions by grouping, and 3) four practice ions quizzes. • Included in a separate document are ion flash cards. • You should be able to complete an ions quiz in less than ten minutes without trouble. • There will be a quiz on all the ions during the first week of school. A Periodic Table will be provided. • You may want to print out and cut the flashcards of the ions, and then arrange them by groups based on patterns you observe. (For example, which ones are made of only one element / several elements? Which ones have positive charges vs. negative charges? If it’s an ion from a single element, where are they on the periodic table? Which ones have several possible charges? How are they named, e.g. –ium, -ide, -ate, -ite, hypo-, per-, bi-, thio-, -ous, -ic?)

 Complete the Three Review Problems. THIS IS HOMEWORK AND IS DUE ON THE FIRST DAY WE MEET. Please complete these problems neatly, showing your work when appropriate. These are the types of problems that I expect you to be able to do with confidence and accuracy. There will not be enough time to re-teach these particular topics, so you should take some time before we meet to make sure you can name compounds, write formulas, balance equations, and identify types of reactions. I will assume that anyone interested in taking AP Chemistry liked balancing equations and using formulas for compounds in general Chemistry. If you didn’t “get” it this year, take some time over the summer to “google” some tutorial videos and make sure you do get it before we meet in August. I want to meet students who have completed this not because it earns you points in the class, but because you want to make positive steps to be prepared for AP Chem. If you do a sloppy job or just copy from someone, you are hurting yourself. On the other hand, the better you are able to do these problems, the more prepared you will be to succeed in AP Chemistry.

 Safety Contract For one of the Universities or Colleges you are interested in attending, do some Google searching to see if you can access (for free) a copy of their Chemistry laboratory safety contract. Print it out, read it, sign it and I will collect it (yes, I will give you points for participating) during our second class meeting.

 Chemistry in the News Colloquia preparation Look out for an article in a magazine or online source that you find interesting and that has some connection to Chemistry. By the end of the first week of school I will require you to submit a one page summary of the article, including your reasons for choosing that article in an MLA formatted paper, including the MLA formatted work you cite. Once I have had a chance to review your topic for academic suitability, you will do some additional research on the topic to find out more about the chemistry involved in the topic and connections to our course (you can start that over the summer if you wish) and prepare a short presentation (5 – 10 minutes) to give to your peers during our bi-weekly Colloquia sessions. Some of our Colloquia last year were fascinating and gave students an opportunity to talk about Chemistry that they were interested in not that I assigned. (Scientists working in large organizations often give and attend Colloquia in order to share the work they are doing and to find out about what others in the organization are doing.) To give you an idea of what we want to be looking for, I find a lot of interesting things on the BBC website, for example here is a link to a story about how not using so much plastic might impact us all: http://www.bbc.com/capital/story/20180705-whats-the-real-price-of-getting-rid-of-plastic-packaging and something else about plastic from earlier in the summer, https://www.bbc.com/news/science-environment- 44359614 And Here is another article about e-waste mining that caught my eye recently: https://www.bbc.com/news/business-44642176’

Clark Magnet High School

Preparation for AP Chemistry IONS LIST BY NAME

− − 2− Acetate, ethanoate C2H3O2 or Hydrogen sulfate, HSO4 Oxide O − CH3COO bisulfate 3+ + − Aluminum Al Hydronium H3O Perbromate BrO4

+ − − Ammonium NH4 Hydroxide OH Perchlorate ClO4

2+ − − − Barium Ba Hypobromite BrO or OBr Periodate IO4

− − − − Bromate BrO3 Hypochlorite ClO or OCl Permanganate MnO4

− − − 2− Bromide Br Hypoiodite IO or OI Peroxide O2

− − 3− Bromite BrO2 Iodate IO3 Phosphate PO4

2+ − 3− Calcium Ca Iodide I Phosphite PO3

2− − + Carbonate CO3 Iodite IO2 Potassium K

− 2+ + Chlorate ClO3 Iron (II), ferrous Fe Silver Ag

Chloride Cl− Iron (III), ferric Fe3+ Sodium Na+

− 2+ 2+ Chlorite ClO2 Lead (II), plumbous Pb Strontium Sr

2− 4+ 2− Chromate CrO4 Lead (IV), plumbic Pb Sulfate SO4

Copper (I), cuprous Cu+ Lithium Li+ Sulfide S2−

2+ 2+ 2− Copper (II), cupric Cu Magnesium Mg Sulfite SO3

− 2+ − Cyanide CN Mercury (I), mercurous Hg2 Thiocyanate SCN

2− 2+ 2− Dichromate Cr2O7 Mercury (II), mercuric Hg Thiosulfate S2O3

Fluoride F− Nickel Ni2+ Tin (II), stannous Sn2+

+ − 4+ Hydrogen H Nitrate NO3 Tin (IV), stannic Sn

− − 2+ Hydrogen carbonate, HCO3 Nitrite NO2 Zinc Zn bicarbonate,

Clark Magnet High School

Preparation for AP Chemistry IONS LIST BY SET Set 1 Aluminum Al3+ Fluoride F− Oxide O2− Barium Ba2+ Hydrogen H+ Potassium K+ Bromide Br− Iodide I− Sodium Na+ Calcium Ca2+ Lithium Li+ Strontium Sr2+ Chloride Cl− Magnesium Mg2+ Sulfide S2−

Set 2

+ 3+ 2+ Ammonium NH4 Iron (III), ferric Fe Nickel Ni Copper (I), cuprous Cu+ Lead (II), plumbous Pb2+ Silver Ag+ Copper (II), cupric Cu2+ Lead (IV), plumbic Pb4+ Tin (II), stannous Sn2+

+ 2+ 4+ Hydronium H3O Mercury (I), mercurous Hg2 Tin (IV), stannic Sn Iron (II), ferrous Fe2+ Mercury (II), mercuric Hg2+ Zinc Zn2+

Set 3

− − − Acetate, ethanoate C2H3O2 or Chlorite ClO2 Nitrite NO2 − CH3COO − − 3− Bromate BrO3 Hydroxide OH Phosphate PO4

− − 3− Bromite BrO2 Iodate IO3 Phosphite PO3

2− − 2− Carbonate CO3 Iodite IO2 Sulfate SO4

− − 2− Chlorate ClO3 Nitrate NO3 Sulfite SO3

Set 4

2− − − − Chromate CrO4 Hypobromite BrO or OBr Periodate IO4

− − − − Cyanide CN Hypochlorite ClO or OCl Permanganate MnO4

2− − − 2− Dichromate Cr2O7 Hypoiodite IO or OI Peroxide O2

− − − Hydrogen carbonate, HCO3 Perbromate BrO4 Thiocyanate SCN bicarbonate, − − 2− Hydrogen sulfate, HSO4 Perchlorate ClO4 Thiosulfate S2O3 bisulfate

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Clark Magnet High School

Preparation for AP Chemistry PRACTICE IONS QUIZ - 1

Name Formula Name Formula Name Formula Hypobromite Hydrogen Dichromate

Iodate Thiocyanate Nitrate

Permanganate Perbromate Bromate

Sodium Nitrite Bicarbonate,

Ammonium Hypoiodite Chromate

Bisulfate Nickel Hydronium

Phosphite Chlorate Peroxide

Iodite Stannic Ferric

Silver Oxide Chloride

Cuprous Fluoride Strontium

Phosphate Cyanide Periodate

Iodide Thiosulfate Potassium

Sulfite Hydroxide Chlorite

Lithium Mercuric Ferrous

Calcium Cupric Bromide

Sulfide Hypochlorite Perchlorate

Acetate Plumbic Sulfate

Mercurous Stannous Zinc

Bromite Plumbous Barium

Aluminum Carbonate Magnesium

Clark Magnet High School

Preparation for AP Chemistry PRACTICE IONS QUIZ - 2

Name Formula Name Formula Name Formula Ferrous Hydronium Iodate

Plumbous Nitrite Cupric

Calcium Iodite Phosphite

Bromite Perbromate Oxide

Thiosulfate Bicarbonate, Chlorate

Sodium Zinc Hypochlorite

Chlorite Barium Permanganate

Chromate Perchlorate Dichromate

Strontium Peroxide Plumbic

Sulfite Periodate Nickel

Stannous Mercuric Mercurous

Hydroxide Silver Fluoride

Nitrate Phosphate Potassium

Cyanide Thiocyanate Sulfate

Aluminum Bromate Lithium

Sulfide Carbonate Ammonium

Bromide Bisulfate Acetate

Magnesium Chloride Stannic

Hypobromite Hydrogen Hypoiodite

Iodide Cuprous Ferric

Clark Magnet High School

Preparation for AP Chemistry PRACTICE IONS QUIZ - 3

Name Formula Name Formula Name Formula Perchlorate Cuprous Mercurous

Iodide Zinc Silver

Plumbous Perbromate Thiosulfate

Calcium Bicarbonate, Fluoride

Thiocyanate Oxide Ferric

Bromate Stannic Hypochlorite

Nitrite Nickel Potassium

Sulfide Hydronium Nitrate

Chromate Ferrous Peroxide

Sulfite Hypobromite Cyanide

Sulfate Iodite Mercuric

Phosphate Lithium Hydrogen

Phosphite Ammonium Permanganate

Barium Strontium Chlorate

Sodium Dichromate Chloride

Hypoiodite Plumbic Chlorite

Cupric Acetate Carbonate

Periodate Magnesium Hydroxide

Aluminum Iodate Bisulfate

Stannous Bromite Bromide

Clark Magnet High School Preparation for AP Chemistry PRACTICE IONS QUIZ - 4

Name Formula Name Formula Name Formula Aluminum Sodium Peroxide

Perbromate Bromite Phosphate

Sulfide Lithium Hypochlorite

Cuprous Chloride Nitrate

Nitrite Thiocyanate Phosphite

Calcium Nickel Ferric

Potassium Oxide Strontium

Sulfite Bromate Fluoride

Hydroxide Sulfate Stannic

Chlorite Hydronium Chromate

Chlorate Bicarbonate, Ferrous

Zinc Hydrogen Plumbous

Mercuric Thiosulfate Carbonate

Stannous Silver Bisulfate

Periodate Perchlorate Hypoiodite

Bromide Mercurous Permanganate

Magnesium Iodite Iodide

Cyanide Iodate Cupric

Barium Hypobromite Dichromate

Ammonium Plumbic Acetate

Review Problems: Naming Compounds, 2. For each of the following compounds, classify it as an Writing Formulas Ionic Compound, Covalent Compound, or Acid. Then write its formula.

Name Type Formula 1. For each of the following compounds, classify it as an hydrofluoric acid Ionic Compound, Covalent Compound, or Acid. Then write its name. silver nitrate Formula Type Name cupric cyanide H2SO4 aluminum oxide LiNO3 potassium dichromate Na2S sulfurous acid Fe2O3 dinitrogen tetroxide Pb(BrO3)2 carbonic acid P4O10 hypobromous acid BaBr2 manganese(IV) oxide HBr cobalt(III) sulfate CaO lithium bicarbonate Zn(C2H3O2)2 stannic oxide HNO2 perioidic acid CuI iodine heptafluoride N2O oxygen difluoride KClO3 rubidium chloride H3PO3 hydrocyanic acid PCl5 plumbic bromide HBrO4 ammonium carbonate Al2(CO3)3 magnesium fluoride Na2S2O3 chromium(III) chloride Hg2Cl2 chlorous acid HI potassium iodide SO3

Cs2O2

Sn3(PO3)2

Review Problems: Chemical Reactions and c. A gaseous sample of butane is burned in air. C H (g) + O (g) )  CO (g) + H O(g) Balancing Equations 4 10 2 2 2

For each of the following reactions, identify the type of Type: reaction (i.e. Balanced Molecular Equation 3. For each of the following reactions, identify the type

of reaction (i.e. combustion, decomposition, double

replacement, single replacement, or synthesis), write Possible observations the balanced molecular equation and state observations you would expect to make when carrying out each d. Solutions of lead(II) acetate and hydrochloric acid reaction (e.g. precipitate formed, bubbles of gas are mixed. observed, heat and light produced etc.) Pb(CH3COO)2 (aq) + HCl(aq )  PbCl2(s) + a. Solutions of potassium chromate and silver nitrate CH3COOH(aq) are mixed. Type: K2CrO4(aq) + AgNO3(aq) )  KNO3(aq) + Balanced Molecular Equation Ag2CrO4(s) Type:

Balanced Molecular Equation Possible observations

e. Aluminum metal reacts completely with chlorine Possible observations gas.

Al (s) + Cl2 (g)  AlCl3 (s) Type:

Balanced Molecular Equation

b. Propane gas is burned in oxygen. Possible observations C3H8(g) + O2(g) )  CO2(g) + H2O(g)

Type: Balanced Molecular Equation f. Silver metal is combined with oxygen gas.

Ag(s) + O2(g)  Ag2(O(s)

Type:

Balanced Molecular Equation

Possible observations Possible observations

g. A piece of zinc metal is placed in a solution of hydrochloric acid.

Zn (s) + HCl(aq)  ZnCl2 (s) + H2 (g)

Type: j. Solid copper(II) oxide is strongly heated.

Balanced Molecular Equation CuO  Cu (s) + O2 (g)

Type:

Balanced Molecular Equation

Possible observations

Possible observations

h. Water is electrolyzed.

H2O (aq)  H2 (g) + O2 (g) Type: Balanced Molecular Equation

Possible observations

i. Phosphorus and sulfur are heated together.

P4 (s) + S8 (s)  P4 S3 (s) Type:

Balanced Molecular Equation

: Possible observations

1 PERIODIC TABLE OF THE ELEMENTS 2 H He 1.008 4.00 3 4 5 6 7 8 9 10 Li Be B C N O F Ne 6.94 9.01 10.81 12.01 14.01 16.00 19.00 20.18

11 12 13 14 15 16 17 18 Na Mg Al Si P S Cl Ar 22.99 24.30 26.98 28.09 30.97 32.06 35.45 39.95 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr 39.10 40.08 44.96 47.87 50.94 52.00 54.94 55.85 58.93 58.69 63.55 65.38 69.72 72.63 74.92 78.97 79.90 83.80 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe 85.47 87.62 88.91 91.22 92.91 95.95 (97) 101.1 102.91 106.42 107.87 112.41 114.82 118.71 121.76 127.60 126.90 131.29 55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 Cs Ba *La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn 132.91 137.33 138.91 178.49 180.95 183.84 186.21 190.2 192.2 195.08 196.97 200.59 204.38 207.2 208.98 (209) (210) (222) 87 88 89 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 Fr Ra †Ac Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og (223) (226) (227) (267) (270) (271) (270) (277) (276) (281) (282) (285) (285) (289) (288) (293) (294) (294)

58 59 60 61 62 63 64 65 66 67 68 69 70 71 *Lanthanide Series Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu 140.12 140.91 144.24 (145) 150.4 151.97 157.25 158.93 162.50 164.93 167.26 168.93 173.05 174.97 90 91 92 93 94 95 96 97 98 99 100 101 102 103 †Actinide Series Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr 232.04 231.04 238.03 (237) (244) (243) (247) (247) (251) (252) (257) (258) (259) (262)