ON SITE EMERGENCY PLAN Document No

NAVIN FLUORINE INTERNATIONAL LIMITED,DEWAS

ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

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NAVIN FLUORINE INTERNATIONAL LIMITED,DEWAS

ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

INDEX

Sr. No. Content Page No. 1.0 Introduction 1 2.0 Objectives of Emergency Management Plan 1 3.0 Elements of Emergency Plan 1 2 4.0 Types of Emergencies 2 2 5.0 Emergency Action 2 5.0 6.0 Emergency Organogram 7 7.0 Emergency Communication System 10 8.0 Duties of Plant Personnel 11

9.0 Map of Dewas city showing NFIL location 17 Appendix Appendix 1 NFIL Block Plan / Site plan, Emergency Control Centre, As- 18 sembly Points, Fire hydrant line, Fire hydrant pump room, Water storage, Fire bucket stand, Fire extinguisher. as an annexures. Appendix 2 Fire fighting facility and plant location, List of fire extin- 19 guisher and Fire Alarm System.

Appendix 3 Safety Personal Protective Equipment’s at NFIL 22 Appendix 4 Location of the manual call points in the respective areas. 23 Appendix 5 Emergency Control Centre 25 Appendix 6 NFIL Products and Packaging Description 27 Appendix 7 Manufacturing process in brief and process flow chart 28 as an annexures. Appendix 8 list of key chemicals / gases with storage 30 capacity & mode of storage in bulk quantity Appendix 9 List of Licences as an annexures 31 Appendix Fire Hazard Properties and EAC of Chemicals at NFIL. 32 10 Appendix Medical Assistance 35 11 Appendix Following is the list of hospitals in Dewas, their contact 36 12 numbers. Appendix Guidelines For Safe Handling Of AHF Cylinder / Tonner 37

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NAVIN FLUORINE INTERNATIONAL LIMITED,DEWAS

ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

13 Appendix List Of Trained First Aider 44 14 Appendix Telephone Numbers of Important Outside Agencies 45 15 Appendix Telephone Numbers of Key People in organisation 46 16 Appendix Department wise Manpower in NFIL 47 17 Appendix Mock Trial Review 48 18 Appendix Risk and consequence analysis report with preventive 50 19 measures of toxic & critical raw material

Appendix Emergency Preparedness for Uncontrolled Situation 53 20 Appendix Emergency procedure for natural disaster 55 21 Appendix Food poisoning Emergency 57 22 Appendix Transport Emergency due to Accident of vehicle carrying 60 23 hazardous cargo, Leakage of cylinder / container

Appendix Utilities failure emergency management 62 24 Appendix Proposal to liquidate residue 66 25 Appendix Last Mock drill observation and action plan 69 26 Appendix Integrated Management System Policy As an annexure 69 27 Appendix List of Antidote 70 28 Distribution list 74

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NAVIN FLUORINE INTERNATIONAL LIMITED,DEWAS

ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

APPROVAL:

Signing of this approval page indicates agreement with approach de- scribed in this document.

Prepared By: Functional Name Designation Signature & Area Date

Environment, Health and Pravin Thakor Asst. Manager Safety

Reviewed By:

Functional Name Designation Signature & Area Date

Environment, Shashikant Pawar Sr. Manager Health and Safety

Production Shailendra Chaudhari Sr. Manager

Maintenance Shashikant Prajapati Manager Administra- tion& Secu- Saket Sharma Sr. Manager rity

Manufactur- Subba Reddy GM Technical ing

Approved By:

Functional Name Designation Signature & Area Date

Site Head Anil Birari Site Head

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NAVIN FLUORINE INTERNATIONAL LIMITED,DEWAS

ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

1. INTRODUCTION A major emergency in industry is the one which has a potential to cause serious injuries to people, extensive damage to property and serious disruption to normal activity both inside and outside the factory area. It can also lead to major environmental pollution.

It is likely that in the event of an emergency, there may be a panic and the response action could be chaotic and ineffective causing confusion. To avoid such a situation, it is desirable to plan in advance and design an emergency response action that is well co-ordinated between the plant personnel as well as outside agencies.

This emergency management plan specifically deals with "On-site Emergency" i.e. with respect to accidents which take place in the industry and their effects are con- fined to the factory premises involving only the people working in the factory.

2. OBJECTIVES This emergency management plan aims at the following objectives.

1. Careful evaluation of all possibilities that can lead to an emergency 2. Preparing an action plan and making plant personnel aware about method of communication, their duties and how to co-ordinate with outside agencies 3. Controlling the incident, and localising the emergency 4. Minimising the damage to property, health and environment 5. Giving speedy treatment to the injured

3. ELEMENTS OF EMERGENCY PLAN This emergency management plan has been prepared with the involvement of the experienced operating staff, members of the safety committee, line managers as well as other management staff who will play a key role in the emergency management.

1. Since most of the emergencies in a chemical plant arise out of handling of hazardous chemicals, the plan has dealt in details with hazardous properties of the chemicals and their inventory levels. 2. It has contemplated the probable emergency scenarios and immediate containment action with respect to each one of them. 3. The use of fire-fighting as well as safety equipments is essential during containment. This plan gives the details of fire fighting facilities, safety equipments and its location. 4. The plan has elaborated the system of communicating the emergency situation to various people working within the plant as well as to the external authorities. It has a list of the key people and external agencies who may be contacted in case of emergency. 5. It has laid down the duties of the individuals involved in emergency action.

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ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

6. It includes information on the first-aid treatment for chemical injuries. It also contains the information on hospitals and Doctors who may be called for help for the treatment of injured persons. 7. The emergency plan also contains the location map of NFIL, Dewas. This will be help- ful in judging which areas are threatened depending on weather conditions and by the spread of the emergency, so that off-site emergency action can be initiated.

Dy. Directorate of Industrial Health & Safety Dewas. Directorate of Industrial Health & Safety, Indore. Police Commissioner Dewas. Chief Fire Officer, Dewas Corporation.

The plan document has been loaded on the main network server in NFIL and can be accessed by all the network users. This facility also lends easy and rapid updating of the document, as soon as the content changes.

4. TYPES OF EMERGENCIES At NFIL, Dewas; following types of emergencies can occur:- 4.1. Release of toxic gases (AHF / Sulfur Tetrafluoride / Chlorine / Ammonia etc.) due to: The corrosion of pipelines, equipment’s, nozzles of reactor/vessels. Failure of gaskets of the flange joints, during loading/unloading of chemicals, Failure of stuffing boxes or mechanical seals in pumps, Failure of scrubber, Leakage of AHF/SF4 from cylinder valve or body, Leakage of toxic gases from neighbouring industry, Power failure, which result to release of toxic gases from different process stages. 4.2 Fire emergency involving:- LDO/Furnace oil / Diesel oil, Fluoro benzene, Hydrogen gas, Organic chemicals & solvents, Other combustibles like dry grass, Electric short circuits etc. 4.3 Structural Failures due to Corrosion/ Ageing. 4.4 Transport Emergency due to Accident of vehicle carrying hazardous cargo, Leakage of cylinder / container etc. 4.5 Emergency Procedure for Diversion of Storm Water Drain to ETP. 4.6 Emergency procedure for natural disaster. 4.7 Emergency procedure for natural disaster and food poisoning. 4.8 Emergency procedure for utilities failure. 4.9 Liquid nitrogen (Cryogenic Liquids) leakage 4.10 Process Scrubber failure.

5.0 EMERGENCY ACTION The Emergency Action in case of toxic gas leakage or fire is listed below. 5.1 Toxic gas leaking from process equipment’s/ Pipelines: − Determine the point of leakage. − Identify the leaking gas (AHF / Chlorine/ SF4/ Ammonia etc.) and estimate the quantity of toxic fluid hold-up in the leaking equipment. In case of major leakages, stop the production plant immediately.

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ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

− Isolate the equipment by shutting off the valves of supply lines. This should be done after the person has adequately protected himself with proper Personal Protective Equipment’s. − Stop supply of steam to the leaking equipment’s (like reboilers) immediately to re- duce its Temperature. − Depressurise (vent) the contents of leaking equipment in to the scrubber, if possible. − Transfer the contents of the equipment to other process vessel, if possible. − In case of leakage of acids, neutralise the leaking liquid by hydrated lime or soda ash. − Activate the fire squad and call fire tender. If required. - Check wind direction. - Neutralised material packed into proper container and send to TSDF Site, and fire / cooling Water flow divert to ETP drainage. 5.2 Emergency Actions to be taken in case of fire: − Identify source/ type of fire. − Assess the severity of fire. − Isolate the equipment by shutting off the valves of supply line (carrying flammable material). This should be done after the person has adequately protected himself with proper PPEs or by auto control system. − Immediately isolate all electric supply of affected area. − Extinguish fire with suitable fire extinguisher (as per class A, B, C or D) and call fire tender. If required. − Activate fire squad. - Water which is used for fire fighting is to be collected into ETP through open drainage Potential causes of Fire:

5.3 In case of structure failure: − Cordon off the area and restrict the entry to people. − Stop all the normal activity of affected area. − In the event of major release of toxic gas/ liquid due to structure failure stop plant activities/ critical processes. − Evacuate the plant personnel from the affected area and initiate medical assistance if required. 5.4 Transport emergency due to accident of vehicle carrying hazardous material: − Try to control leakage at source. − Cordon off the area and restrict the entry to people. − If possible park the vehicle away from populated area (if incident happened inside the factory premises; park vehicle away from main plant area). − In case of fire, extinguish the fire with water/ hydrant water or with suitable fire extinguisher. − In case of toxic release; curtain the vapour with water spray. − Neutralize the leaking liquid by hydrated lime or soda ash. − Driver has to inform consigner, transporter, police and fire brigade telephone number. − Act according to emergency procedure written in TREM card. − Fire emergency due to accident of vehicles. 7 | P a g e

NAVIN FLUORINE INTERNATIONAL LIMITED,DEWAS

ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

− Fire emergency due Leakage, spillage and toxic release. − Explosive due to cylinder.

5.5 Steps to be taken by Public in case of Emergency: − NFIL is conscious of its responsibilities and is committed to words safety in totality. NFIL has adopted the best and advanced technology which is supported with latest safety devices. The plant is run by qualified, Skilled and well trained personnel who ensures smooth and safe and safe operation all the times. NFIL is always ready combat any emergency that may arise Periodic training and regular mock drills are a part of our process. We have ON-SITE emergency plan and we are regular rehearsal, Hence there is rare chance for emergency. − However in spite of all possible precautionary measures, If emergency occur one should know the steps to be by him. 1. Chemical leakage and spillage. 2. Gas leakage. 5.5.1 Emergency Procedure. − Come out to open. Check the wind direction. Move away quickly in the perpendicular of the wing direction. − Decide wind direction. Move away perpendicular to the wind direction. − On indication of gas leakage, cover nose and mouth with wet cloth and quickly to the safe location. − Men, Women and children should come out from house, Keeping piece of wet cloth on face. − On getting information about gas leakage, Use available mode of transport to move away quickly from the place. − Life is more precious the property. Immediately move away from the place, As and when you get information about any emergency. − Set the cattle free. They will reach to safe place on their natural way. − Wake up your neighbours by making loud noise if the incident occurs at night. Brief them about the occurrence. − Do not leave the safe place where you have assembled without instruction from authorised person.

5.6 Liquid nitrogen (Cryogenic Liquids) leakage: − Identify source/ type of leakage. − Assess the severity of leakage. − Shut off all sources of ignition. − Barricade the area and restrict the entry of plant personnel. − Immediately isolate all electric supply of affected area. − Isolate the equipment by shutting off the valves of supply line. This should be done after the person has adequately protected himself with proper PPEs − Allow liquid to evaporate, ensuring adequate ventilation − Evacuate the plant personnel from the affected area and initiate medical assistance if required.

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NAVIN FLUORINE INTERNATIONAL LIMITED,DEWAS

ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

5.7 Process Scrubber Failure: − Immediately start the stand by scrubber system. (If Leakage) − Identify source/ type of leakage. − Assess the severity of leakage. − Shut off all sources of ignition. − Barricade the area and restrict the entry of plant personnel. − Immediately isolate all electric supply of affected area. − Isolate the equipment by shutting off the valves of supply line. This should be done after the person has adequately protected himself with proper PPEs.

5.8 In case of leakage, rupture and Fire on solvent Storage tank (Tank Farm Area) − Identify source / type of leakage. − Assess the severity of leakage & Fire. − Shut off all sources of ignition. − Immediately isolate all electric supply of affected area. − If small fire Extinguish fire with suitable fire extinguisher (mechanical foam type) − If fire not extinguished by fire extinguisher then use fire hydrant system with AFFF foam solution. − Keep adjacent tanks cool by water spray through hydrant system. − Activate fire squad. − Barricade the area and restrict the entry of unauthorized personnel. − Call fire tender. If required.

5.9 In case of Fire in Sulphur Storage − Identify source − Assess the severity of Fire. − Shut off all sources of ignition. − Immediately isolate all electric supply of affected area. − Activate fire squad. − If small fire Extinguish fire with suitable fire extinguisher (mechanical foam type) − If fire not extinguished by fire extinguisher then use fire hydrant system − Barricade the area and restrict the entry of unauthorized personnel. − Call fire tender. If required.

GENERAL

− Raise the Emergency Siren. Inform Key Persons on telephone. − Emergency leader will activate the Emergency control centre. 9 | P a g e

NAVIN FLUORINE INTERNATIONAL LIMITED,DEWAS

ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

− Arrange for rescue of trapped people and, arrange for immediate medical treatment. − Cordon off the area and restrict the entry to people. − In the event of major release of toxic gas, stop other plants and evacuate other plant personnel and contract workmen to assembly point. − Carry out the head count. − Check the level of oxygen using multi gas detector tube in the plant area and down wind direction. The concerned person should do this only after wearing SCBA. − Site main controller and Emergency leader to decide on outside help and communication.

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NAVIN FLUORINE INTERNATIONAL LIMITED,DEWAS

ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

6. EMERGENCY ORGANOGRAM 6.1 The Emergency organisation is given below.

SITE MAIN CONTROLLER, Factory Manager

INCIDENT CONTROLLER, (Production Manager)

EMERGENCY LEADER, Head EHS

Communication Team Advisory Team Admin & security Head QA, Head SCM, head Head QC

Action team A Action Team B Action Team C Action Team D

(PD lab, cGMP -1 & Same as Medical officer All staff not cGMP -2) Advisory male nurse listed Team (from in team A,B,C Officer of Apex should be affected hospital present and contract first aid team for any

labour. arrangement emergency of vehicle / duty when Ambulance called Rescue team (Security by emergency (Production head) leader manager, main- all contractor tenance workmen’s. officer and all contract workers)

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ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

6.2 The emergency organization is second shift (after 18:00) and night shift given below

SITE MAIN CONTROLLER

Plant In Charge/ Shift In Charge

INCIDENT CONTROLLER

Shift Supervisor (Maintenance, QC, Electrical))

EMERGENCY LEADER

Maintenance Executive/Officer

COMMUNICATION TEAM ADVISORY TEAM

Security Supervisor/Officer QC Persons

Action team B Action team A Action team C Action team D

Officer of Same as First aid team All staff not affected Advisory arrangement listed and contract Team in team A,B,C labor. of vehicle / should be pre- Rescue team Ambulance sent (Production offi- (Security su- for any cer, mainte- emergency nance pervisor) duty when officer and called contract by emergency Workmen’s) leader

all contractor

workmen’s.

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COMMUNICATION THROW

cGMP- 01, Site Main Controller cGMP- 02, Kilo lab, PD Lab, Rambo Incident Controller Utility 1 & 2, Warehouse 1 & 2

Emergency Security / OHC Advisory Drivers Leader Executive HR Team

Other dept. Apex Hospital Manual Call Heads.( Account, point QC,WH, MT, )

Contractor Workmen & others

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ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

7. EMERGENCY COMMUNICATION SYSTEM

Following modes of communications are provided in the plant.

7.1 Communication in the plant and departments

Manual Call :-Manual call points have been installed in Pilot plant, Kilo lab, cGMP Plant-2, points Warehouse, New warehouse, Admin & PD lab, Q.C for communicating emergency to the security room. Manual call points switches are provided on all the operating floors as indicated in the annexure. Any workmen in the plant who notices the dangerous event (like leakage or fire) should press the nearest manual call point. He should stay put at the site of a switch (or near by area at a safe position) and wait for Supervisor to arrive at the site. Pressing of the switch will raise the alarm in control room and indicate the location of switch from where the alarm was activated. The shift incharge in absence of Produc- tion manager will immediately rush to the site, talk to the person raising the alarm to get to know the reason, assess the situation and take corrective action to contain the incident.

7.2 Communication with plant & other department.

Intercom: This facility has been provided in the entire plant area, Exclusive number “707” is provided on board of Security main gate to be used as Emergency Number.

Mobile In the event of failure of Intercom system, Walk talky provided to operational Phone: persons including Production, maintenance, Instrument & electrical and mobile phone will be used as an alternative means of communication. All key persons are provided with Mobile phones. They will be used their mobile phone inside office.

Emergency Security and OHC room have been provided with Emergency siren (A wob- Siren: bling sound in 10 sec. cycle up to 3 mins). This Siren will be activated on the instruction of plant supervisor only when the situation is out of his control. Its range is about 2 km.

All Clear It is a continuous long sound for 1 minute). This Siren will be activated on the Siren: instruction of Emergency Leader when he decides that situation has been re- stored to normal, signalling the end of Emergency. This siren will last for 1 min and its range is about 3 km.

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ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

7.3 Communication with Outside Agencies: This will be done strictly as per the instructions of Emergency Leader, incident controller & site Main controller by the person nominated by him at the time of Emer- gency. Telephone communications will be used for getting assistance from Local agencies.

8. DUTIES OF PLANT PERSONNEL

8.1 Emergency Leader Head Environment, Health & Safety will be the Emergency Leader. He will have following duties: − Activate Emergency Control Centre at the main gate and co-ordinate all the activities in fighting the Emergency. − Consult the advisory team and decide on evacuating plant people. − Decide about the evacuation point depending on the wind direction. − Get assistance from external agencies like Fire Brigade / Police and provide advice on possible effects on areas outside the factory premises. − Liaise with external agencies and give them an update on emergency. − To decide to end the emergency and to commence normal operations. Site Main Controller (Factory Manager) − Assess the magnitude of the situation and decide whether the evacuation of staff from the plant is needed. − Exercise and direct operational control over areas other than those affected. − Maintain a continuous review of possible development and assess in consultation with work incident controller and other Key Personnel. − He will inform all Key Personnel and all outside agency for help. − Liaison with Police, Fire Service, Medical Services, Factory Inspectorate and other Govt. Agencies. − Direct and control rehabilitation of affected area after emergency. − Intimate Off-site Emergency controller if the emergency spreads beyond the factory premises and likely to affect the surrounding area. − Ensure that evidence is preserved for enquiries to be conducted by statutory authorities. − The Site Main Controller will declare the emergency and he will instruct gate office to operate the emergency siren after assessing the gravity of the situation.

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ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

8.2 Incident Controller (Plant Manager & Shift In charge) - In case of emergency he will rush to the place of occurrence and take overall charge and report to the Site Main Controller by personnel communication system like cell phones and inform about the magnitude of emergency. - He will assess the situation and considering the magnitude of emergency he will take decision and inform Communication Officer to communicate the news of emergency to different agencies. - He will give direction to stop all operations within the affected area. - He will take the charge of Main Controller till the Main Controller arrives.

- He will order for shutdown and evacuation of workers and staffs from affected area. - He will inform security and fire officers and State Fire Services. - He will ensure that all non-essential workers/staff are evacuated to assembly point and areas searched for casualties. - He will report all significant development to Communication Officer. − Moreover he will advise to preserve evidence of emergency into the cause of emergency. Duties of communication team 8.2.1 Telephone operator (or Person nominated by Emergency Controller): − To receive the messages from the scene of incident and transmit same to the key people. − Do not entertain any calls which are not connected with emergency. − On instruction of emergency leader, communicate with external agency.

8.2.2 Head of HR/ Personnel Department:

To liaise with external agencies as per the directive of emergency leader. − District Magistrate and Disaster Management control room. − Dewas municipal Commissioner. − Officials of Factory Inspectorate (DISH Office) − Pollution Control Board. − PESO office. − District and Municipal Health Department. − Local Sarpanch / Municipal Corporate of the village / in the nearby area which might be affected. − To arrange external medical assistance from local hospitals / doctors. − To communicate to the relatives of the injured person. − To assist Emergency Leader in preparing written communication for Press and handling media personnel. 8.2.3 Executive HR / P & A Manager: − To arrange refreshments for the emergency team. − To get extra vehicles of the senior managers and deploy them for emergency transport needs. − Look after rehabilitation of affected people on discontinuation of Emergency. − Issue authorised statements to media and ensure that evidence is preserved for further enquiries. − To arrange vehicles from outside sources.

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− To arrange for photographer, if needed. − To arrange for personal messengers for communication. − Head count after all clear siren. 8.3 Duties of advisory team:

- This team includes the experts in each field such as Head QA, Head SCM and Head Q.C etc. − Rush to emergency control centre on hearing emergency siren. − Should understand the incident and advise the Emergency Leader in their field of expertise. − They have to take-up any additional responsibility as per the instructions of Emer- gency Leader. 8.4 DUTIES OF TEAM - A 8.4.1 Shift officer / Executive − To find out the exact nature of incidence. − To ascertain the chemical involved. Assess its quantity. − To search if any person is trapped in the accident or injured by it. − To call the ambulance and send the injured person to medical centre. − To control / contain the incident with the help of shift incharge / operators by taking appropriate steps. − Containment action may include isolation / depressurisation / safe transfer of the contents etc. − To take care of Safety of persons working in the affected area will be his prime con- cern and he will ensure use of proper Personal Protective Equipments. − To stop the plant and raise Emergency Alarm depending on the situation. − To communicate with Production Manager, Emergency leader, Factory manager, on walky-talky /Telephone , Mobile handsets / by intercom and appraise the incident. − To find out the wind direction and guide incoming helping people on rescue, fire fighting and other mitigating operations by staying upwind. − On arrival of the Production manager, he shall appraise him fully and act on his advice. 8.4.2 Area Manager / Production Manager: − On getting message from shift incharge or on hearing the sound he should proceed to the plant and take charge from incident controller (shift officer). − He will communicate to Emergency leader/ Area and constantly in touch with emergency leader. − He will give direction to control the emergency situation. − He will direct emergency team such as ambulance, rescue team, fire squad with the coordination of other supporting team /person. − After successfully controlling of emergency situation; he will inform to emergency leader for the end emergency. − After the confirmation from emergency leader; he will declare emergency is over. 8.4.3 HR/Admin Manager: − On hearing the Emergency siren, he will find out the location of incident. − He will send the fire security guard to the site. − He will visit the site and arrange fire fighting, rescue operation of trapped personnel in consultation with shift incharge or Production manager.

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− Instruct the main gate guard to prevent the entry of unauthorised personnel at the main gate and inform the location to all essential personnel entering the premises. − Direct trained fire fighters to contain the fire / gas cloud. He will take advice from production manager / shift incharge for the method of fire fighting and use of hydrant water for containment of toxic gases.

− To call the external Fire brigade for fire fighting if required; as per direction of emergency leader, incident controller and Main site controller in their operations. − To get help from Police as per direction of Emergency leader; to strengthen security and control the external on road. − To ensure that all fire fighting equipments are properly placed in position after ser- vicing / replenishing when the emergency has been brought under control. 8.4.4 Duties of Shift Security supervisor: On getting the message or hearing the Emergency Siren, − He will perform the duty of security officer until security officer arrives. − Inform Security officer on Intercom / Mobile phone. − To open the factory gate for easy entry of ambulance or other emergency services Vehicles. − Ask the main gate guard to prevent the entry of unauthorised personnel at the main gate and inform the location to all essential personnel entering the premises. − To depute a guard to control the traffic at the scene of incident and cordon off the area. − To carry out the fire fighting / hydrant operations as per the advise of Shift / plant incharge. 8.4.5 Rescue team: − On hearing emergency siren and finding the incident site with the help of Security officer he should rush to incident site. − To stay upwind and help in extinguishment of fire. − To use Personal protective equipments and rescue the trapped people as per the advice of Production Manager / Shift incharge. − To assist fire fighter in extinguishing operation. 8.4.6 Head Maintenance / Executive -Electrical: − To assist in electrical/ mechanical isolation of equipments/ valves/ piping. − To assist in the working of hydrant pump/ valves. − To carry out repairs job like sealing/ welding/ cutting as per the instructions of Shift Incharge/ Production manager. − Provide manpower to Shift Incharge for containment operations. − Bring additional portable extinguishers/ safety equipments/ lime for neutralisation to the site for fighting emergency. − Depute guards to ensure the operations of Jockey pump / Hydrant pump, water sprinklers or fire fighting as the situation may demand. − Provide tools for emergency operations. − Assist Shift Incharge/Production Manager on need basis. 8.5 DUTIES OF TEAM – B 8.5.1 Executive Maintenance/ Electrical Officer • Arrest the leakage and then Isolate the cylinder valve. • Provide tools for emergency operations. 18 | P a g e

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• Provide manpower for rescue operations. • Assist the incident controller 8.5.2 Team HR • Receive the message from production manager and transmit same to the driver, all Department Heads, • On instruction of emergency leader, communicate with external agency. (Apex care hospital Dewas) • To deploy the vehicle for emergency transport need. • To arrange photographers. • Head count. • Keep the list of Drivers with their mobile nos. • Keep updated list of key personnel. • Keep all employees contact numbers. • To liaise with external agencies as per the direction of Emergency Leader. • To arrange medical assistance from Apex care hospitals Dewas. • To communicate to the relatives of the injured person. • Deploying one officer at assembly point (near Main gate). 8.5.3 Communication Team Executive Accounts Arrange the fund to provide assistance to take care on and after of emergency operation like as: Medicine requirements Hire Vehicles Refreshment Miscellaneous 8.5.4 Emergency Leader • On getting the message from Incident controller he shall Activate OHC. • Consult the advisory team to evacuate plant people. • Decide about the evacuation point depending on the wind direction. • Get assistance from external agencies like as: Police, External Experts, mutual aids, neighboring companies etc. • Liaise with external agencies and give them an update on emergency. • To decide to end the emergency and to commence normal operations. 8.5.5 Advisory Team Head QA, Head SCM, Head QC • All should rush to OHC and security department on hearing emergency siren. • Understand the situation and advise the Emergency Leader in their respective field. 8.5.6 Other Department Heads • Stop all jobs in individual respective area safely. • Ready to take actions as directed by Emergency Leader • Direct to employee to emergency assembly point. 8.6 DUTIES OF TEAM - C 8.6.1 Male Nurse / Doctors of Apex care hospital • Send the Ambulance after the call of Executive HR / Security Head to the site to bring injured persons to Hospital. • Provide artificial respiration. • Take patient to the hospital. With trained first aiders. • All First Aiders to report to OHC on hearing Emergency siren. 19 | P a g e

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• Assist male nurse / Doctors of Apex care. • First Aider working in Plant shall report to Emergency site on hearing Emergency siren. 8.6.1 Medical Officers of Apex care Hospital • To Organize medical treatment to the affected people. • Inform first aider about his urgent medicinal requirements. • As per requirement transfer the patient's to outside hospitals for special treatment if any. • Consult with other Specialists/doctors to handle serious injury. 8.6.1 Drivers • On hearing Emergency Siren Company drivers shall report to Security Gate with their vehicles. 8.7 DUTIES OF TEAM - D • All contractor workmen and other employee shall rush to assembly point.

9. Map of Dewas region showing NFIL location

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APPENDIX -1

NFIL LAYOUT SHOWING, EMERGENCY CONTROL CENTRE, ASSEMBLY POINT, OCCUPATIONAL HEALTH CENTRE, FIRE HYDRANT LINE, FIRE HYDRANT PUMP ROOM AND WATER STORAGE, FIRE BUCKETS & FIRE EXTINGUISHERS.

(SHEET ATTACHED AS AN ANNEXURE-1)

APPENDIX -2

FIRE FIGHTING FACILITY AND PLANT LOCATION LIST OF FIRE EXTINGUISHERS, FIRE HYDRANT POINT, FIRE BUCKETS, FIRE ALARM SYSTEM & SCBA SETS.

1. Water Source - Hydrant Tank. 22 | P a g e

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2. Quantity of Fire Water Storage - 1321 KL. 3. No. of hours of storage - 7 Hrs. 4. Make-up water arrangement from - Welspun project. 5. Hydrant pumps - 1 No. Jockey Pump (maintaining pressure between 5 to 7 Kg / cm2) 1 No. Electrically driven pump, Head 30 Meters

6. Capacity of Jockey Pump - 23 M3/Hrs. 7. Capacity of Main Pump - 187.92 M3/Hrs

Fire Extin- guisher Fire alarm Sys- C M W Fire Hydrant Eme tem o DCP . at r. Fi F er S O Eye 2 re G C H was b W a B S h k H Loca- a s A foun Plant 5 t. o H tion 4 9 t P D Ai tain / st N s C o . 2 9 H e o S e S d & 6 a o e . o Pa 5 k L Li . r i . t e B Bod n z r P t nel k g i t P m n D e t ox y k d. . e . e g t o t c sho g a r n t wer l i. o r Office & Main Park- - 1 - - - 1 ------1 - 1 - 1 - gate ing area Near Secu- OHC ------1 1 - rity office Can- inside - 2 ------teen Gr 2 - - 4 - - - 2 4 - 2 2 2 5 1 1 - - floor 7 1st 2 1 - - 6 3 - - 2 4 - 2 2 2 2 - - - 1 Admi Floor 6 1 n & 2nd 2 1 - - 5 3 - - 2 4 - 2 - 2 2 - - - 2 PD Floor 8 1 lab terrace - - 1 - - - 1 2 - 1 ------Out ------1 2 1 1 - Side Near ------1 2 - 1 ------

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Tree planta- tion Area Office En- - 1 ------1 ------1 - - trance WH 2 1 3 3 ------9 4 4 - - - 1 1 inside WH back ------1 2 - 1 ------side Drum room store - - 1 2 ------( near transformer) Gas cylinder - - 1 ------stor. room Sol- Ware vent 2 - - - - 1 ------hous Stor- e age Tolu- ene & benzene - - - 2 - - 1 2 - 1 ------ne storage room Engi- neer- - - 1 - - 1 1 2 1 1 ------1 ing - Store Diesel stor------1 1 2 - 1 ------age yard Fur- nace - - - - - 1 ------Oil Stor-

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age tank LDO Stor------1 - - 1 ------age tank Liquid Nitro- gen - - 1 - - 1 ------Stor- age tank Metha nol Stor------1 1 2 - 1 ------age tank Out New ------3 6 - 3 ------Side Ware En- hous ------trance e Inside 2 - 3 1 ------1 1 1 Qual- En- - - 2 ------ity trance Con- 1 Inside 2 4 3 2 ------2 2 - - - 1 1 trol 8 & Mi- cro- Out biol------3 6 - 3 ------Side ogy

Out NMR - - 1 ------Side En- - - 1 1 ------trance Kilo - - 2 ------2 ------lab Kilo cGM lab ------1 2 - 1 ------P back Plant side -1 Gr - - 4 1 ------3 3 - - 1 - 1 floor Hydro- ganeti - - - 1 ------on Room

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1st - - 6 1 ------7 3 3 - - 1 1 2 floor 1st floor - - - - - 1 2 - 1 ------stair 1st floor stair clean ------1 2 - 1 ------room back side 2nd 1 2 2 ------7 ------floor 2nd floor ------1 2 - 1 ------stair 2nd floor stair clean ------1 2 - 1 ------room back side Clean Room ------1 2 - 1 ------Back side Clean Room Back side ------1 - - - Gr. floor stair Gr High 2 - 3 1 ------1 - - - - 1 - 1 floor pres- 1st sure 2 - 2 - - - 1 2 - 1 - 5 - - - - 1 - 1 floor facil- 2nd ity 2 - - 1 - - 1 2 - 1 - 1 ------floor Gr 1 6 2 1 2 - 4 8 - 4 2 6 6 - - 1 1 3 cGM floor - 5 4 P 1st 1 1 5 5 2 5 2 5 - 5 2 5 5 - 1 1 1 3 Plant Floor - 4 0 0 -2 2nd 1 4 4 1 - 3 6 - 3 2 5 5 - - 1 1 3 Floor - 3 - 1

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3rd 2 2 1 - 2 4 - 2 - 3 1 1 - - - 1 - Floor - - mez-

zanine 1 1 - - 7 1 1 ------Floor

terrace - - 1 2 - 1 ------Out - - 3 6 - 3 ------Side - - - - - En- Util- - - 1 - 1 1 4 - 1 ------1 - - trance ity -1 Inside 1 ------En- Util------2 4 - 2 ------1 trance ity -2 Inside 1 ------1 ------En- - 1 ------trance Inside - 2 ------QA Com- pactor - 2 ------room Fire Extin- Fire alarm Sys- Fire Hydrant guisher tem C M W Eme o DCP . at r. Fi F er S O Eye 2 re G C H was b W a B S h 9 k H Loca- a s A foun Plant 5 / t. o H tion 4 t P D Ai tain / 5 st N s C o . 2 9 H e o S e S d & 6 0 a o e . o Pa 5 k Li . r i . t e B Bod n z r P t nel k g t P m n D e t ox y k L d. . e . e g o t c sho g i a r n t wer t l i. o r Office & Main Park- - 1 - - - 1 ------1 - 1 - 1 - gate ing area

IT serve - - 1 ------r En- Roo trance 27 | P a g e

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m MCC En------1 ------Roo trance m Inside 2 ------PCC En- 1 - - - - 1 ------Roo trance m Inside 1 ------Old En- 1 - - - - 1 ------PCC trance DG En- 1 - 1 1 - 1 1 2 1 1 ------Roo trance m Inside ------Elect . Inside ------1 - Roo m Haz. En- - - - 1 - 1 ------Wast trance e Sto.R Inside - - - 1 ------oom Fire Hy- drant En- Pum 1 ------trance p Roo m En- HT trance 1 - - - - 1 ------yard Gate Tank 2 - Foam Inside - - 1 - - 1 ------1 1 2 - Area Pro- ject Inside - - 1 ------office En- ETP 1 - - - - - 1 2 - 1 ------1 - trance Incin era- En- 1 - - 2 - - 1 2 - 1 ------tor trance

Ram Plant 1 - 3 ------bo 4 1 1 3 1 1 5 1 5 1 2 3 3 2 1 1 Total 6 4 23 2 6 0 2 0 7 4 0 2 0 9 6 7 7 2 2 28 | P a g e

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3 8 6

APPENDIX -3

SAFETY PERSONAL PROTECTIVE EQUIPMENTS AT NFIL

Departments

Addi- Name of Personal Protective tional Admin Main- Equipment Prod. To- Qty. QC WH & tenan tal available PD lab ce with EHS** SCBA 45 min 6 lit, 300 bar 8 - 2 1 1 12 2

Emergency eye wash fountain & 14 1 2 3 - 20 2 body shower Air pressure Suit 12 - 4 - - 16 5 PVC Suit 5 2 2 - - 9 2 Proximity suit 1 - - - - 1 1 Full body Harness - - - - 3 3 10 Full face organic mask with car- 16 2 4 2 2 26 6 tridge Half face organic mask with car- 3 2 2 - 2 9 5 tridge Ear muff 2 - - - 5 7 4 Acid / Alkali proof Hand gloves 25 5 5 5 5 45 50

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ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

Cryo hand gloves 2 - - - - 2 1 Face shield 8 - 2 2 2 14 6 Multi gas detector 1 - - - - 1 1 Gum boots 3 - 1 - 2 6 6 Rope ladder - - - - 1 1 1

** - The Quantities mentioned in this column is available on 27.07.15 it may vary.

NOTE: Addition to above following PPEs are provided to all employees individually.

1. Safety helmet 2. safety shoes 3. Safety goggles

APPENDIX -4

LOCATION OF THE MANUAL CALL POINTS IN THE RESPECTIVE AREAS.

Sr. Zone Manual Call Fire Alarm Locations Remark No Number Point Number 1 Raw Material Stores Rejected/Return Zone No-1 01 No Material room. First Floor 2 Raw Material Entrance GR. Floor Zone No-2 02 No 3 Raw Material Stores entrance near Ap- Zone No-2 03 No proved Material Room GR. Floor 4 Raw Material stores finished goods Zone No-2 04 No sores room GR. Floor 5 Micro Lab Entrance GR. Floor Zone No-3 05 No 6 QC Lab. GR. Floor Zone No-3 06 No 7 Above Fall sealing Admin and QC Block Zone No-4 --- 8 Administration Block Entrance Zone No-5 07 No GR. Floor 9 Account Office GR. Floor Zone No-5 08 No 10 Pilot Plant Service Area Near Hoist First Zone No-6 09 No Floor 11 Pilot Plant Service Area Near GLR-111 Zone No-6 10 No First Floor 12 Pilot Plant service Area First Floor Zone No-6 11 No

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13 Hot Water Tank Opp. Utility GR Floor Zone No-7 12 No 14 Trey Drier backside Near Kilo lab GR. Zone No-7 13 No Floor 15 Pilot plant material Entry room Zone No-8 14 No GR. Floor 16 HPF Gr. floor and 1st floor Zone No-9 --- 17 HPF 2nd Floor Zone No- --- 10 18 Near reception , Gr. Floor, Admin --- 15 No 19 Near Lift, Gr. Floor, Admin --- 16 No 20 Training Room, Gr. Floor, Admin --- 17 No 21 Future Development Area, Back side --- 18 No Gr. Floor, Admin 22 Near wash room, 1st Floor, Admin & PD --- 19 No lab. 23 Future Development Area, 1st Floor, --- 20 No Admin & PD lab. Sr. Zone Manual Call Fire Alarm Locations Remark No Number Point Number 24 Near Chemical Store room 1st Floor, --- 21 No Admin & PD lab. 25 PD lab inside, 1st Floor, Admin & PD --- 22 No lab. 26 Passage near staff room, 2nd Floor, --- 23 No Admin & PD lab. 27 Synthesis Lab Inside, 2nd Floor, Admin --- 24 No & PD lab. 28 Instrumentation Lab Inside, 2nd Floor, --- 25 No Admin & PD lab. 29 QA side stair , Gr floor, cGMP-2 --- 27 No. 30 WH side stair , Gr floor, cGMP-2 --- 28 No. 31 Mid Stair, Gr floor, cGMP-2 --- 29 No. 32 Near Goods Lift, Gr floor, cGMP-2 --- 30 No. 33 Emergency stair, Gr floor, cGMP-2 --- 31 No. 34 QA side stair , 1st floor, cGMP-2 --- 32 No. 35 WH side stair , 1st floor, cGMP-2 --- 33 No. 36 Mid Stair, 1st floor, cGMP-2 --- 34 No. 37 Near Goods Lift, 1st floor, cGMP-2 --- 35 No. 38 Emergency stair, 1st floor, cGMP-2 --- 36 No. 39 QA side stair , 2nd floor, cGMP-2 --- 37 No. 40 WH side stair , 2nd floor, cGMP-2 --- 38 No. 41 Mid Stair, 2nd floor, cGMP-2 --- 39 No. 42 Near Goods Lift, 2nd floor, cGMP-2 --- 40 No. 43 Emergency stair, 2nd floor, cGMP-2 --- 41 No.

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ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

APPENDIX -5

EMERGENCY CONTROL CENTRE

Location - Near Factory Main gate (see NFIL site layout plan). It is marked with red colour. Main emergency centre has been equipped with, Communication Facilities: 1) One line is exclusively for Outgoing calls. 2) Intercom facility. Drawings / Documents: Map of surrounding area of Navin Fluorine Int. Ltd. Dewas. Block Plan / Plant Layout / Site Plan. Map of Fire hydrants. List of important Telephone numbers. On-site emergency plan. TREM cards / MSDS. EHS Guide & First aid Manual.

List of safety equipment’s /PPE’s available in Emergency control Centre:

Sr. No Item Quantity Remark 1 SCBA set 01 Nos. 2 Gumboots 04 Pairs 3 Fire Proximity suit 01 nos. 4 PVC Full body suit 04 Nos. 5 Safety Helmet (Yellow) 05 Nos. 6 Safety Goggles 05 Nos. 7 Full face Respirators 04 Nos. 8 Ear Muffs 04 Nos. 9 Full Body Harness 02 Nos. 10 Face Shields 08 Nos. 11 Full body Airline suit 02 Nos. 12 DCP (5 kg), CO2 (4.5 kg), Mechani- 03 Nos. each cal Foam (9 lit) fire extinguishers

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ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

13 Emergency Torch 02 Nos. 14 Dust Masks 10 Nos. 15 Spades / Shovels 01 Nos. 16 Acid / Alkali Hand gloves 05 pairs 17 Hand Lorry 03 Nos. 18 Barricade Tape 02 Nos. 19 Mega phone 01 Nos. 20 Multi gas detector 01 Nos. 21 Foam making branch nozzle 01 Nos. 22 AFFF Solution Bottle (Capacity 3 03 Nos. Ltr.)

List of Personal Protective Equipment’s available at site

Sr. No Name of PPE’s Purpose Applicable Area/ De- partments

1. Safety Helmet Protection against fall ob- Entire Plant Premises. jects, sharp edges, pipes, angles etc.

2. Safety Shoes Protection against sharp Entire Plant Premises. edges, Glass, Acid /Alkali electric shock etc.

3. Safety Goggle Protection against fine Entire Plant Premises. particles, flying objects, chemicals, etc.

4. Face Shield Protection against fine Production, Ware particles, flying objects, house, QC, Mainte- chemicals, etc. nance, ETP.

5. Dust Masks Protection against dusts. Production, Ware Organic vapours, etc. house, QC, ETP, Incin- erator. 6. PVC Full Suit / PVC Protection against Production, Ware Aprons Acid/Alkali’s , Chemicals, house, QC. etc. 7. Ear Plug / Ear Muff Protection against high DG Room, Utility area, noise. Production.

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8. Self-Contained Protection against Toxic Production, Ware Breathing Apparatus Gas release, Low oxygen % House. (SCBA) area etc.

9. Full Face Masks- Protection against Organic Production, Ware Cartridge Type vapours, Chemical house, QC. splashes, Fumes, etc.

10. Full body harness Protection against fall dur- Maintenance, Electri- ing working at Height cal, Contractors.

11. Acid/Alkali proof Production against Acid / Production, Ware Hand gloves Alkali Handing, Burns etc. house, QC, Mainte- nance ETP, Incinera- tor.

APPENDIX -6

NFIL PRODUCTS AND PACKINGS DESCRIPTION

Sr. No Name of Materials Type of packing 1. XFE UN Approved HDPE Drum 2. CFP Jerry can, Bloom plastic bag 3. DBT Jerry can 4. FGH HDPE Container 5. DFA UN Approved Jerry can 6. MIT HDPE container and UN Approved HDPE container 7. CBT UN Approved HDPE container 8. AMB HDPE Jerry can 9. MTP UN Approved Jerry can 10. CDO UN Approved HDPE container 11 TFL UN Approved HDPE container 12 BFB UN Approved HDPE container 13 CDA UN Approved HDPE container 14 EBA MS/HDPE Drum 15 MBA MS/HDPE Drum 16 MEOT MS/HDPE Drum 17 PA/ES MS/HDPE Drum

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ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

18 DEMT MS/HDPE Drum 19 PTAC UN Approved Jerry can 20 TFMA MS/HDPE Drum 21 TFEA MS/HDPE Drum 22 BIPHENYL MS/HDPE Drum

** Manufacturing product list is provided in above is frequently changed due to nature of our business and manufacturing production blocks are multi product process plants, these plants will be operated based on customer specific requirement vs list of products are changed in a campaign production , We have listed above limited list only, these are will be our regular repeated orders.

APPENDIX -7

MANUFACTURING PROCESS IN BRIEF AND PROCESS FLOW CHART

1. Manufacturing process of Xtalfluor. a. Charge Dichloromethane, magnesium sulphate, Decant, Liquid Nitrogen and purge Sulphur tetra fluoride at temperature -65Oc in Reactor SSR-105 (capacity 500 Lit.). b. Charge Dichloromethane at temperature 20Oc to 30Oc in Addition tank -101. c. Charge Dietylaminotrimethyl Silane, Dichloromethane, and Dichloromethane at temperature 15Oc to 25Oc in Addition tank -101. d. Charge BF3 Complex and Dichloromethane at temperature 15Oc to 25Oc in Addi- tion tank -101. e. Chilled Dichloromethane (-15Oc to 25Oc) Washing given to wet cake in Centrifuge (CF-103). f. Remove dried material from centrifuge bag and packed.

2. Manufacturing process of 4 - Methyl 1-2 (2,2,2-trifluoro-1,1-Dimethylethyl Pridine. a. Charge THF, N- butyl lithium in hexane, 2,4 lutidine, Diethyl carbonate, Methyl Iodide, Ammonium Chloride and DM water in Reactor. Extracts Organic layer and Aqua layer. b. Charge Ammonium Chloride and Ethyl acetate in Aqua layer Extraction 1st . c. Charge Ethyl acetate in extraction with Ethyl acetone. Extracts Aq. Spent To ETP. d. Fractional distillation to pure Stage I. Extracts residue. e. Charge hexane in Recovery of organic from residue. Extracts Tarry mass f. Final product and packed.

3. Manufacturing Process of 3,5 Difluobenzonethiol [ Stage I ]. a. Charge Water, HCl and 3,5 Difluoroaniline in Reactor. b. Charge Sodium Nitrite Solution in white slurry. Extracts Nitrous oxide fumes to scrubber 35 | P a g e

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c. Charge Potassium Ethyl Xanthate solution in water in Reaction. Extracts Nitro- gen gas to scrubber d. Make crude Product. Extracts Aqueous Layer to ETP.

4. Manufacturing Process of 3,5 Difluobenzonethiol [ Stage II ]. a. Charge Stage I crude, Isopropyl Alcohol, Potassium hydroxide Solution in water in Reaction after Distillation. Isopropyl Alcohol recycle to reaction. b. Reaction mass to Extracts HCL, ethyl acetate & Aqueous layer acidic to ETP. c. Organic layer (distillation) to extracts Residue g. Organic layer distillation to make Final product and packed.

5. Manufacturing Process of Ethyl benzyl aniline. a. Charge Monoethyl aniline(MEA), Benzyl chloride and water in Mixing tank & Reaction vessel. b. Charge caustic in Neutralizer & Aqueous seprator. Extracts Water to ETP h. Distillation to make Final product and packed.

6. Manufacturing Process of methyl benzyl aniline (MBA). a. Charge Toluene, Monomethyl Aniline, Benzyl chloride and water in Mixing tank & Reaction vessel. b. Charge Caustic Lye in Neutralizer & Aqueous separator. Extracts Water to ETP. c. Distillation unit to make Final product and packed.

7. Manufacturing Process of Monomethyl Ortho Toluidine (MMOT). a. Charge Ortho Toluidine and Ethyl alcohol in mixing tank . b. After mixing transfer through pump in falling film evaporator. c. Pre heating done. Organic tank to extracts Water to ETP. d. Distillation column to distillation. e. Distillation to make Final product and packed.

8. Manufacturing Process of Pyrazinnoic Acid / Pyrazinnoic Ester (PA/PE). a. Charge 2 Methyl Pyrazine, Catalyst and C.S. Lye in reactor b. Separator to extracts Catalyst. c. Charge Butanol, Sulphuric Acid, Pyrazionic Acid and Water 467 Kl for acid washing in Reactor. d. Separator to extracts water to ETP. f. Distillation during butanol to recycle. g. Distillation final product and packed.

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APPENDIX -8

LIST OF KEY CHEMICALS / GASES WITH STORAGE CAPACITY & MODE OF STORAGE IN BULK QUAINTY

NAME OF RAW MATERIAL MAX. MODE OF STORAGE STORAGE CAPACITY SULPHURIC ACID 5.0 MT HDPE CAN HYDROCHLORIC ACID 5.0 MT HDPE CAN HYDROGEN GAS 60 Cylinder CYLINDER LIQ. NITROGEN 4.0 KL SS TANK ETHYL ACETATE 10.0 MT SS TANK ACETIC ACID 10.0 MT SS TANK TETRAHYDROFURAN (THF) 5.0 MT MS BARREL HEXANE 5.0 MT MS BARREL TERT -BUTYL METHYL ETHER 5.0 MT MS BARREL POTABLE WATER 500.0 KL HDPE CAN SULFUR TETRAFLUORIDE (SF4) 2.5 MT CYLINDER

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ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

N-BUTYL LITHIUM in 2.5 M 2.5 MT BOTTLE HEXANE BROMINE 2.0 MT BOTTLE ETHANOL 20.0 MT PLASTIC BOTTLE / MS TANK PARA FLUORO ACETOPHENONE 2.0 MT MS BARREL ISO PROPYLMAGNESIUM 2.0 MT MS BARREL CHLORIDE 2 M IN THF / MS TANK METHANOL 135.0 KL PP DRUM ACETONE 2.0 MT MS BARREL IRON POWDER 2.0 MT PP BAG DIETHYL ETHER 3.0 MT PP DRUM TOLUENE 4.0 KL MS BARREL BENZENE 4.0 KL MS BARREL 2,4, DICHLORO FLUORO 2.0 MT MS BARREL BENZENE N-BUTYL LITHIUM 2.5 MT CYLINDER /BOTTLE SULPHUR 1.5 MT OPEN DIESEL 20 MT MS TANK

APPENDIX -9

LIST OF LICENCES

SN Licence Number Type of Premises

1 14/5339/DWS/2m(i) Factory Licence

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2 P/CC/MP/16/9 (P157691) Storage of Toluene and Benzene

3 P/HQ/MP/15/532 (P14266) Storage of Diesel

4 P/HQ/MP/15/93 (P13083) Storage of Methanol and Ethanol

5 G/CC/MP/06/1159 Storage of SF4 gas cylinders (G31599) 6 A/P/CB/MP/15/236 Storage of LDO (P275440) 7 S/HO/MP/03/245 Storage of Liquid Nitrogen (S52180) 8 P/HQ/MP/15/81 (P13070) Storage of Furnace Oil

9 G/CC/MP/06/907 Storage of Ammonia & Hydrogen Cylinder (G19984) 10 01/DWS/MP/2016 Sulphur

APPENDIX -10 HAZARD PROPERTIES OF CHEMICALS AT NFIL.

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ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

Auto S UN Flas LE UE MP Vap. NFPA igni- T r. UN Haz- h L L /B Den- Chemical tion L N No. ard Poi % % P sity H r o Tem V o Class nt v v .c (Air=1) H F R O p .c 1 DIETHYL 115 - -40 - - 170 34 3 - - - - - 2 DICHLOROMETETHER 1595 6.1 - 13 23 556 40 2.93 - 2 1 0 0 3 METHYLHANE 1233 3 11 6 36 464 64. 1.11 - 1 3 0 0 4 NITRICALCOHOL ACID 2030 8 NA - - - 127 2.5 - 3 0 0 0 5 HYDROCHLORI 1781 8 - - - - 101 1.26 - 3 0 1 0 C ACID 9 8.5 6 SODIUM 182 8 - - - - 814 0.62 - 3 0 1 0 7 LIQUIDHYDROXIDE 1974 ------0 0.967 - - - - - 8 BORONNITROGEN 3267 8 - - - 68.19 ------TRIFLUORIDE 5 35 9 TETRAHYDROFFLUOROBENZE 238 3 -15 - - - 85 ------1 URANE4NE- 3097 8 82 - - - 82 - - 3 2 0 0 0 FLUOROBENZO 4 1 YLSULFUR CHLORIDE TETRA 241 2.3 ------4 0 2 W 1 FLUORIDE 8 40. 4 1 SODIUM - - - - - 85 - - 2 0 1 0 2 CARBONATE 1 1 METHYLENE 159 6.1 - 12 23 556 39. 2.9 - 2 1 0 0 13 MAGNESIUMCHLORIDE -3 ------8 - - 1 0 0 0 4 SULFATE 1 HYFLO ------1 0 0 0 HEPTAHYDR 5 SUPERCEL 1 CHARCOALATE , 136 - - - - 452 - - - 1 3 0 0 6 ACTIVATED 2 POWDER 1 MONOCHLORO 133 - 28 - - 593 1 3.9 - 2 2 3 3 7 BENZENE 4 32 1 POTASSIUM ------2 0 1 0 8 CARBONATE 1 SODIUMANHYDROUS ------11 - - 2 0 0 0 9 SULFATE 00 2 ALLUMINUM 172 ------3 0 0 0 ANHYDROUS 0 CHLORIDE 6 - 2 ANHYDROUSTOLUENE 129 - 4.4 - - 480 11 3.1 - 2 3 0 0 1 4 4 0.6 2 POTASSIUM 181 - - - - - 13 - - 3 0 2 0 2 HYDROXIDE 3 84 2 SODIUM 142 ------1.3 - 3 4 2 0 3 BOROHYDRIDE 6 2 HYDROFLUORI 8, - - - - 19. 2.21 - 4 - - - 4 C ACID 6.1 4 2 ANHYDROUSTRIETHYL 129 - -8.3 - - 215 89. 3.48 - 3 3 0 0 5 AMINE 6 7

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Auto Vap. Sr UN Fla LE MP NFPA U- igni- Deni TL . UN Haz- sh L / Chemical EL tion ty V N No. ard Poi % BP H r o % tem (Air= o Class nt v .c H F R O p .c 1) 2 DIMETHYL - - 89 - - 215 189 2.71 - 1 2 0 0 6 SULFOXIDE 2 TETRA 205 - - - - 321 65 2.5 - 2 3 0 0 7 HYDROFURAN 6 14. 5 2 BORAN 260 - 65 - - 185 125 4.9 - 3 3 2 0 8 TRIFLUORIDE 4 .7 ETHERATE 2 SULFUR ------9 TRIOXIDE PYRIDINE 3 MAGNESIUM ------1 0 0 0 0 SULFATE ANHYDROUS 3 1,2- 118 - 13 - - 413 83. 3.42 - 2 3 0 0 1 DICHLOROETH 4 5 ANE 3 CHLOROACITIC 175 - 126 - - 470 189 3.2 - 3 1 0 0 2 ACID 1 3 ETHYLENE 118 - 13 - - 775 182 3.42 - 2 3 0 0 3 DICHLORIDE 4 .3 3 ETHYLENE - - 111 - - 398 197 2.14 - 1 1 0 0 4 GLYCOL .6

3 BORON ------2.3 - 4 3 0 1 5 TRIFLUORIDE 148 3 BROMINE 174 8, - - - - 56. 5.51 0. 4 - - O 6 4 6.1 5 1 X 3 N-BUTYL - 4.2 -20 ------7 LITHIUM 3 SULPHUR 135 4.1 207 0.1 6. 240 118 - - 2 1 2 0 9 0 7 83 3 Diesel 120 3 32 0.6 6 225 215 - - 1 2 0 - 9 2 - 376

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NAVIN FLUORINE INTERNATIONAL LIMITED,DEWAS

ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

EMERGENCY ACTION CODE

Emergency Action Code Scale for Fire and Spillages

1 JETS 2 FOG / SPRAY 3 FOAM 4 DRY AGENT

P V FULL R - S V BA DILUTE S BA for Fire only SPILLAGE T - BA T - BA for Fire only W V X - FULL CONTAIN Y V BA SPILLAGE Y BA for Fire only Z - BA Z - BA for Fire only

E Consider Evacuation ( Get Police assistance)

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NOTE FOR GUIDANCE

FOG : In the absence of FOG equipment, Fine spray may be used. DRY AGENT : Water must not be allowed to come in to contact with substance V : Can be violently or explosively reactive. FULL : Full body protective clothing with Breathing Apparatus. BA : Breathing Apparatus plus protective Gloves. DILUTE : May be washed in to drains with large quantities of Water. CONTAIN : Prevent spillage entering drains / water course by any means available, like sand, earth etc. E : consider evacuation.

APPENDIX -11

MEDICAL ASSISTANCE

Emergency Number Police -100, Fire– 101 & Ambulance – 102, 108

In the event of a Medical Emergency occurring inside the plant, resulting in 05 or even 10 casualties, the victims will be immediately brought to the medical centre by the ambulance and other vehicles whatsoever is available at that time inside the plant.

1. In the medical Centre, we have One bed in the OHC room, the patients will be made comfortable and immediate first aid will be rendered to all the victims from trained first aiders.

2. The victims requiring intensive medical care and hospitalization will be immediately shifted to the nearby hospitals (as per appendix-XII).

3. Depending on the number of casualties, the extent and nature of injuries sustained, the victims will be immediately shifted to any one of the above mentioned hospitals by our ambulance or any vehicle that is available at that time.

4. First aiders will be accompanying the injured persons to the hospitals and will stay there until the victim is comfortable and treatment has commenced.

5. In case of minor AHF/SF4 burns especially, attempt will be made to treat the victim in our OHC. But if the number of casualties is more or the injury is serious, then they will be shifted to the nearby hospitals as per the above plan. Arrangement will be made to collect urine samples of the victims as and when required and these samples will be brought to the medical centre to estimate the fluoride content in the urine. This will enable us to monitor the amount of Calcium Gluconate that is to be given to the patient intravenously.

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6. The above mentioned doctors and hospitals have already been informed about the hazards and hazardous nature of the products during the Doctor’s Meet. A First Aid Manual highlighting the hazards and side effects and required first aid and treatment to be given is also distributed among all the attended doctors.

APPENDIX -12

FOLLOWING IS THE LIST OF HOSPITALS IN DEWAS, THEIR CONTACT NUMBERS.

TITAL TELEPHONE NUMBER APEX CARE HOSPITAL. 07272 – 251128 ,251127 SANSKAR HOSPITAL. 07272 – 253939, 253940, 253980 M.G. HOSPITAL. 07272 – 253323 , 253408 ESIC HOSPITAL. -- DEWAS HOSPITAL. 07272 – 220600 , 220601 AMBULANCE 102, 108 APEX CARE HOSPITAL 07272 – 251128 ,251127 MR.UMESH 09893666319 M.G. HOSPITAL 07272 – 253323 , 253408 SANSKAR HOSPITAL 07272 – 253939 , 09893532565 BLOOD BANKS DISTRICT HOSPITAL DEWAS. 07272- 254620 M.G.HOSPITAL BLOOD BANK DEWAS. 07272 – 253323 , 253408

Special note about Apex care Hospital: We have a tie-up with this hospital which has all the specialities and super- specialities. This hospital as per our tie-up gives priority and immediate treatment to our employees as and when required.

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APPENDIX -13

GUIDELINES FOR SAFE HANDLING OF AHF/SF4 / Ammonia / Chlorine CYLINDER / TONNER

1. All operation of connecting to process should be undertaken only by experienced and competent personnel. 2. After moving the cylinder / tonner to the desired location for connection, the same is to be appropriately secured so that it does not roll or trip. 3. Tonners should be kept a horizontal position in such a way that the two valves are in a vertical plane. In this position, AHF in gases form can be drawn from upper valve, where as liquid AHF can be drawn from the lower valve. 4. In case of cylinders, AHF gas will come out from the valve when the cylinder is kept in an upright position. Liquid AHF can be withdrawn from the cylinder by inverting it with the help of inverting rack. This operation calls for special and skill and training. 5. It is advisable to kept the cylinder loaded on to a weighing platform so that the extent of AHF remaining in cylinder can be readily known. 6. Only approved tools should be used for making connections and valve operations. Never force connections that do not fit. 7. Flexible connections of seamless copper tubes/SS braided Teflon tubes having no kink. Brass yoke clamps, adaptors, and Teflon washers are to be used between the cylinder/Tonner and reactors. Teflon diaphragm type pressure gauges are to be used with appropriate valve (Teflon valves).The pressure gauge is to be checked frequently for its accuracy. While withdrawing the liquid, the Pressure should be regulated by a separate valve in the line which is also to be secured with proper support. 8. For giving connection, remove the valve outlet nut and attach the flexible tube to the nut. The other end of the flexible tube is attached with pipeline going to receiving tank. 9. Open the valve slowly using the appropriate size spindle spanner, never use loose or worn out spanner or pipe wrench, as this might damage valve spindle. Do not apply too much force while operating the valve. It may twist and damage the spindle lead- ing to gas leakage. If valve is jammed and is not opening by applying a little force on the spindle spanner, loosen the valve gland nut by about maximum one round and then try again. After the valve is opened, the gland nut should be retightened. 10. Open the valve slightly and check the connections and found to be safe, the valve can be opened fully, by giving one complete turn to the valve stem in a counter clockwise direction with the spindle spanner. This is sufficient to permit maximum discharge of HF. Additional turn of the valve stem will not increase the rate of flow. It will only damage the valve. 11. Keep the spindle spanner fitted on to the valve on which connection has been given. This helps in closing the valve immediately in case of any sudden leakage develops. 12. The container should be used only as a storage vessel and not as a process vessel. 13. The container valve is not to be used for controlling the flow of HF acid. Frequent operations will cause damage to the valve. A separate regulating valve on the process side should therefore be used for this purpose.

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ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

FIRST – AID OF SF4/AHF (ANHYDROUS HYDRO FLUORIC ACID) INJURIES

Hydrofluoric acid is a strong acid with highly caustic and corrosive effect on organic tissues. The resulting burns with weak acid often do not become painful until several hours later.

I INHALATION

A SYMPTOMS of acute poisoning 1. Irritation of mucous membranes (nose, eyes, mouth, throat) 2. Watering of eyes 3. Salivation 4. Fits of coughing 5. Ulceration of mucous membranes (nose and throat) 6. Pain in throat 7. Thoracic congestion 8. Difficulty in breathing 9. Bronchitis 10. Headache 11. Fatigue 12. Giddiness 13. Nausea 14. Stomach pains 15. Pale or Bluish face 16. State of shock * weak and rapid pulse * cold sweat - pale complexion * tendency to fainting * cold hands and feet 17. Chemical pneumonia (diagnosis can only be made by a physician) 18. Coma 19. Acute pulmonary edema (Diagnosis can only be made by a physician) 20. Death

IB First Aid in case of Inhalation of HF/SF4

Note: Same First Aid is also recommended for following chemicals

Boron Trifluoride Ammonia Chloroform Chlorine Hydrochloric acid Hydrofluoric acid. Nitric acid Nitro amino compounds Bromine Sulphur Dioxide Sulphur Trioxide 46 | P a g e

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− First aiders must take precautions for their own safety if they must enter the contaminated area to help the victims. − Always remove the victim from the contaminated area. − Notify a physician immediately and inform him of the nature of the substance in- haled and the state of victim and if possible, his symptoms. − Prevent the victim from making any unnecessary exertion or movement. − Never give an unconscious person anything to drink.

IB 1 If the victim is conscious 1 Remove him from the contaminated area to a quiet, cool and well-ventilated area. 2 Lay him down with his legs raised. 3 Loosen his collar and belt 4 Cover him with a blanket 5 Calm and reassure him.

IB 2 If the victim coughs a great deal (in addition to the measures recommended in A)

6 Make him inhale from a gauze pad soaked with a little ethyl alcohol or a few drops of ether (CAUTION: These liquids are flammable) 7 Make him inhale oxygen under low pressure with a Pulmotor or similar type of equipment.

IB 3 If the victim is unconscious but breathing (in addition to the measures recommended in A)

8 Remove dentures or partial plates 9 Make him inhale oxygen under low pressure with a Pulmotor or similar type of equipment until physician arrives.

IB 4 If the victim has stopped breathing 1 Remove him as quickly as possible from the contaminated area. 2 Quickly - lay him down on his stomach on a blanket loosen his collar and belt begin artificial respiration (Holger-Nielsen method); be very gentle to avoid injuring his lungs. 3 As soon as possible administer oxygen under low pressure with a Pulmotor or similar type of equipment. 4 Continue this treatment until the physician arrives or the victim begins to breathe unaided. 5 As soon as the victim begins to breathe or to move lay him down with his body raised and continues to administer oxygen.

Note: The physician will keep the victim under medical supervision for at least 2 days as there is risk of acute pulmonary edema or microbial infection.

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II INGESTION

IIA SYMPTOMS of acute poisoning 1. Irritation and painful burning sensation of lips, mouth and throat 2. Ulceration of mucous membranes 3. Pain in swallowing 4. Edema of the glottis (diagnosis can only be made by a physician) 5. Intense thirst 6. Violent burning sensation in the oesophagus and stomach 7. Painful stomach cramps with distension of stomach 8. Difficulty in breathing

9. Muscular fatigue and general weakness 10. Coughing 11. Acute pulmonary edema 12. Perforation of stomach (diagnosis can only be made by a physician) 13. Nausea and vomiting, occasionally of blood (digestive haemorrhage) 14. Pale or Bluish face 15. State of shock * weak and rapid pulse * cold sweat - pale complexion * tendency to fainting * cold hands and feet 16. Convulsions 17. Coma 18. Death

II B First Aid in case of ingestion of HF /SF4 Note : Same First Aid is also recommended for following chemicals Boron Trifluoride Ammonia Chloroform Chlorine Hydrochloric acid Hydrofluoric acid. Nitric acid Nitro amino com- -pounds Bromine Sulphur Dioxide Sulphur Trioxide Sulphuric Acid

− Never give the victim sodium bicarbonate in powder or solution and never attempt to neutralise the acid with a strong base (ammonia or soda, etc.) − Never try to make the victim vomit if he has swallowed acid. − Never give an unconscious person anything to drink.

In all cases, notify a physician and inform him of the nature of the ingested product and the state of the victim and, if possible, his symptoms.

IIB1 If the victim is conscious 1. Remove him from the contaminated area to a quiet, cool and well ventilated area where he can rest. 2. Make him rinse his mouth liberally with cold water. 48 | P a g e

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3. Loosen his collar and belt. 4. Never give him water to drink if he has swallowed a strong acid (such as Sul- phuric acid) but give him as much water as he wants if he has swallowed a weak acid solution. 5. He can be given either - * Milk (as much as he wants) or * Milk of magnesia or * Milk of lime or * Calcined magnesia in water or * Emollients such as table oil or fresh eggs. 6. Lay him down with his legs raised 7. Cover him with a blanket. 8. Prevent him from moving or speaking unnecessarily.

IIB2 If the victim's face is blue 1. Lay him down on his back with his head turned to one side. 2. Administer oxygen under low pressure with a Pulmotor or similar type of equipment (never Carbogen [mixture of oxygen and carbon dioxide]), if necessary, until physician arrives.

In the case of ingestion of FLUORINE compounds - * Do not let the victim vomit. * Give him large doses of effervescent Calcium Gluconate tablets (6 tablets Calcio- fon/Ostocalcium Calglucon/Ebucim/Glucal or Glubiogen availability of tablets any one brand should be always available at site) diluted in copious amounts of fluid (water or milk) to drink. * Take him to the hospital immediately.

IIB3 If the victim is unconscious but still breathing 1. Lay him down on his back (except if he is vomiting, when he should lie with his head lowered and turned to one side to prevent him from suffocating). 2. Remove dentures or partial plates 3. Loosen his collar and belt 4. Cover him with a blanket 5. Administer oxygen under low pressure with a Pulmotor or similar type of equipment (never use Carbogen (mixture of oxygen and carbon dioxide if his face is blue) if necessary, until physician arrives.

IIB4 If the victim has stopped breathing 1. Lay him down and immediately begin artificial respiration or mouth-to-mouth resuscitation or use an Ambu-type bellow. 2. At the same time, loosen his collar and belt. 3. Cover him with a blanket.

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4. Continue artificial respiration with a Pulmotor or similar type equipment admin- istering oxygen under low pressure, until the victim begins to breathe unaided and, if necessary, until the physician arrives.

III SKIN CONTACT

IIIA IMMEDIATE SYMPTOMS 1. Burning sensation and inflammation 2. Irreparable damage to skin, which gradually turns white and becomes very painful 3. Blisters 4. Profound damage to the tissues 5. Shock may occur as a result of pain Weak and rapid pulse Cold sweat - pale complexion Tendency to fainting Cold hands and feet. III B First Aid in case of skin contact with HF

Note: Same First Aid is also recommended for following chemicals Fluorine Fluosilisic Acid Potassium Fluoride Pot.Fluoro Silicate Sodium Fluoride Sodium Fluosilicate Bromine Nitro amino compounds

− It is vital to apply first aid without delay. − In the case of extensive splashing of the substance, wash the victim down under a cold shower or a hand held hose, at the same time protecting his eyes. − First aiders must take precautions for their own safety when handling contaminated clothing. − Notice a physician and inform him of the nature of the chemical and of the accident. − Never apply an oily substance on affected areas without medical advice.

1. Remove the victim from the source of contamination and take him immediately to the nearest shower. 2. First aiders, wearing rubber gloves and air-tight safety goggles, should remove the clothing from the affected area under the shower (clothing can be cut away, if necessary). Care should be taken not to contaminate healthy skin or eyes. If the victim is already wearing air-tight safety goggles, do not remove them. 3. Wash him down with cold water for 15 minutes or longer 4. Dry the skin very gently with a clean, soft towel. 5. Apply Calcium Gluconate gel 2.5% on the affected skin. 6. Massage the gel gently into every burnt area with clean fingers. 7. Dress the victim in clean clothes. In the case of burns (inflammation, blisters, or painful lesions) and in the absence of a physician 8. If these are no Calcium Gluconate gel on hand, rub a clean cube of ice on the painful areas and apply a dry, sterile dressing. 9. Take the victim, wrapped in a blanket to the hospital as soon as possible. 50 | P a g e

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If the victim shows signs of shock, 10. Cover him with a blanket. 11. Make him lie down in a quiet place on his back with his head down and legs raised until the physician arrives.

Note Oral administration of 6 tablets of effervescent calcium gluconate (Calciofon, Calgucon, Ebucim, Glucal and Glubiogen tablets) dissolved in water is recommended in case of burns.

IV SPLASHING OF LIQUID IN OR CONTACT OF VAPOUR WITH EYES

IV A Immediate Symptoms 1. Intense stinging and burning sensation 2. Watering of eyes 3. Conjunctivitis (inflammation of eyes) 4. Burning sensation in eyelids and eyes, with ulceration of the tissues 5. Irreparable damage to cornea 6. Loss of vision IV B First Aid Note : Same First Aid is also recommended for following chemicals Sulphuric Acid Ammonia Chloroform Chlorine Hydrochloric acid Hydrofluoric acid. Nitric acid Nitro amino compounds Bromine Oleum Hydrobromic Acid

− It is imperative to wash eyes as soon as possible − Never introduce oil or ointment into the eyes without medical advice. − Notify a physician and inform him of the Name of chemical Nature of accident

1. Remove the victim from the source of contamination and take him to the nearest eyewash i.e. shower 2. Immediately wipe away any excess of chemical (liquid or powder) very gently and quickly. 3. Wash affected eye under slowly running water for 15 min. or longer, making sure that the victims eyelids are held wide apart and he moves his eyes slowly in every direction. 4. If grate pain persists after washing, the nurse can put one or two drops of anaes- thetising eye salve, or better still, one drop of Benoxinate ( Novesine ) at 0.4 % into the eye. 5. If the pain persists, repeat washing the eye for 15 min or until the pain is relieved or the pH of the eye returns to normal (touch the white of the eye with litmus pa- per).

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In case of splashing of Fluorine compounds, several drops of sterile calcium Glu- conate (10% sol. Sandoze or equivalent) in the eye is highly recommended after washing.

Note The Medical service refers the victim to Ophthalmologist and inform him the nature of accident and the chemical.

APPENDIX -14

LIST OF TRAINED FIRST AIDER

Sr. NAME OF FIRST CONTACT DEPARTMENT EXT.NUMBER No AIDERS NUMBER 1 MAYANK SONI HR & ADMIN 07272-666785 785 UMENDRA 2 HR 07272-666784 784 UPADHYAY 3 VIJAY PANKAR MT 07272-666791 791

4 AMIT CHOUHAN MT 07272-666793 793

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ISHWAR 5 MT 07272-666794 794 CHOUDHARY PRASHANT 6 MT 07272-666794 794 DUNGARWAL 7 SATISH YADAV PR 07272-666736 736

8 RAVINDRA KOUSHAL PR 07272-666736 736

9 SACHIN VADJE IT 07272-666755 755

10 YOGESH VAIDHYA PROJECT 07272-666744 744 SURESHCHANDRA 11 SECURITY 07272-666780 780 MALVIYA

APPENDIX -15

IMPORTANT TELEPHONE NUMBERS OF OUTSIDE AGENCIES

TITAL TELEPHONE NUMBER POLICE 100 FIRE 101 POLICE COMMISSIONER 07272 -252124 SUPRITENDENT OF POLICE 07272 – 223000

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POLICE STATION NEW INDUSTRIAL AREA 07272 – 259340 NO-2 , DEWAS M.P.E.B. DEWAS 07272 – 252039 DIRECTOR, INDUSTRIAL SAFETY & 0731 – 2533482 HEALTH, INDORE Dy. DIRECTOR, INDUSTRIAL SAFETY & 07272 – 253336 HEALTH, DEWAS. BANK NOTE PRESS, DEWAS 91-7272-255222 SUN PHARMACEUTICAL INDUSTRIES 07272 306 100 LTD, DEWAS M.P.P.C.B DEWAS. 07272 – 252039 *ASSOCIATION OF INDUSTRIES DEWAS 07272 – 258012 *NATIONAL SAFETY COUNCIL MUMBAI 022-27579924/25/26/27 *M.P WASTE MANAGEMENT PROJECT 07292 – 326906/05 PVT. LTD. (RAMKY) PITHAMPUR DHAR M.P FIRE STATION NAGAR NIGAM LTD. 07272 – 223000,220333 PRABHUPRASAD CHIKESTYALAYAY. 07272 – 222721 GOVERNMENT M.G HOSPITAL DEWAS. 07272 - 253323, 253408 APEX CARE HOSPITAL. 07272 – 251128 ,251127 SANSKAR HOSPITAL. 07272 – 253939, 253940, 253980 DEWAS HOSPITAL. 07272 – 220600 , 220601 AMBULANCE 102, 108 APEX CARE HOSPITAL 07272 – 251128 ,251127 MR.UMESH 09893666319 M.G. HOSPITAL 07272 – 253323 , 253408 SANSKAR HOSPITAL 07272 – 253939 , 09893532565 BLOOD BANKS DISTRICT HOSPITAL DEWAS. 07272- 254620 M.G.HOSPITAL BLOOD BANK DEWAS. 07272 – 253323 , 253408

*Lifetime membership with Association of Industries Dewas, National safety council Mumbai, M.P Waste Management project Pvt. Ltd. (RAMKY) Pithampur, Dhar, M.P APPENDIX -16

TELEPHONE NUMBERS OF KEY PERSONS

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ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

Mr. Rajesh Thete Mr. Ritesh Sharma Site Main Controller, 210, Casa Green, 34, Sangrila Talwali Chanda, Indore. Indore Cell :7875808125 Cell: 8790995666 Speed dial Number : 2101 Speed dial Number : 2100

Mr. Shashikant Pawar Mr. Hitendra Patil Safety Coordinator, DGM – SCM Sun City-I Indore, Madhya pradesh Dewas, M.P – 455 001. Cell : 8889026333 Cell: 07049112340 Speed dial Number : 2102 Speed dial Number : NA

Mr. Saket Sharma Mr. Shailendra Chaudhri Admin & HR sr. Manager Sr. Manager - Production Dewas, M.P – 455 001. Jawahar Nagar, Dewas, Cell: 08085549079 M.P - 455001. Speed dial Number : 2110 Cell: 08966995444 Speed dial Number : 2109

Mr. Umendra Upadhyay Mr. Shashikant Prajapati First Aid Coordinator, Manager – Maintenance Navin Fluorine Apartment, Ganga Nagar, A.B. Road, Dewas Quarter No: J-3, Mill Road, Madhya Pradesh -455 001 Balgarh Road, Dewas. Cell: 07770869929. M.P. 455 001. Speed dial Number : 2111 Cell : 09826528231 Speed dial Number : NA

APPENDIX -17

DEPARTMENT WISE MANPOWER STRENGTH IN NFIL

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Site Head 1 0 0 1 HR 2 4 9 15 Production 31 6 19 56 Project Management 1 0 0 1 Quality Control 7 1 2 10 Analytical Development 2 0 0 2 Lab Process Development Lab 5 0 1 6 Maintenance 12 17 0 29 SCM / Warehouse Stores 4 2 3 9 Quality Assurance 3 1 0 4 EHS 5 3 4 12 Accounts 1 2 0 3 Project 3 2 0 5 Security 0 5 20 25 IT 1 0 0 1 Total 79 43 58 179

APPENDIX -18

MOCK TRIAL REVIEW

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As soon as wobbling siren starts following norms shall be strictly adhered to:-

− All department first-aiders should report to the site of disaster and will work as per the instruction of Incident Controller. − First-aider from Administration Block, Warehouse shall report to Medical attendance (Apex care Hospital) in OHC and shall work as per his instructions. − All the contract workmen shall evacuate from the site and will gather at assembly point No- 1. Or No-2 as per opposite of the wind direction. − While evacuating all workmen shall make use of yellow strips on the road. − Before evacuation everybody should ensure that they have stopped their work safely. − In extreme emergency there will be a head count and contract workmen will have to co-operate during head count. − Employees detailed for the job of combating (those attending to emergency) shall ensure that in case of toxic release, leakage they shall approach the site with some suitable respiratory protection. (Preferably SCBA, cartridge type full face & half respiratory protection, cotton gauze mask, in extreme cases even use of wet handkerchief would also suffice). − Trained fire fighters / EHS designee should immediately connect the fire hoses at nearest point and wait for instruction of Incident Controller. − During emergency security gates will be kept open. − No visitors will be allowed entry during emergency. − Obstruction on the road has to be cleared during emergency so that Ambulance can have free access to the site. − If emergency is at any other location than Pilot plant, Kilo lab, High pressure facility, warehouse then care shall be taken by respective plant in charge that they depute sufficient persons at strategic locations so that location of disaster could be traced by Emergency Squad. − Minimum 2 First-aiders should accompany the ambulance while shifting the causal- ity from the site of incident to OHC. − Manager of Maintenance, Safety and Administration shall report to Incident Control- ler and shall advise the incident controller with their expertise. − Visitors inside the plant premises shall immediately report to HOD of respective area. − Emergency Leader & Incident Controller shall carry cell phone/ mobile phone set during the time of crisis. − Employees from team B should not enter team A area.

TYPICAL MOCK-TRIAL REPORT

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DATE OF MOCK TRIAL PLANNED TIME LOCATION OF OBSERVER INCIDENT INCIDENT CONTROLLER START TIME FINISH TIME

CHECK LIST FOR OBSERVER:- SN. CHECK POINTS OBSERVATIONS / Timing REMARKS 1. Start of mock drill 2. Communications by manual call point 3. Time of emergency siren raising

4. Other activities stopped at high pressure facility 5. Production manager reached at site 6. Time of start Evacuation of affected area 7. No of persons evacuated and guided to assembly point 8. Incident Controller Reporting at site 9. Emergency leader reporting at site 10. Time of starting Combating Exercise by plant personnel & maintenance person 11. Use of PPE by combating staff

12. Security reported outside of site 13. Time of Area cordoned off 14. Entire area was checked and Emergency leader was con- sulted before giving all clear at site 15. Time of All clear Siren after head counting.

Others Remarks:-

Neutral Observer Name: Mr. :- Signature

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APPENDIX -19

RISK AND CONSEQUENCE ANALYSIS REPORT WITH PREVENTIVE MEASURES OF TOXIC & CRITICAL RAW MATERIAL

First Aid In case of HF or SF4 Exposure

General Prompt medical attention is required in all cases. Remove the victim to an uncontaminated area and keep them warm and rested. If breathing has stopped, apply artificial respiration if available. Phone the Apex care hospital phone number (07272-251127) and request an ambulance. Eye Contact Seek medical treatment immediately. Rinse the eye with water. Keep the eye wide open while rinsing. Rinse for at least 15 minutes, or until help arrives. Skin Con- Seek medical treatment immediately. Use the emergency shower to tact flush the affected area with copious amounts of water for at least 5 minutes to remove excess HF. SPEED AND THOROUGHNESS ARE ESSENTIAL as after 5 minutes the tissue will begin to absorb HF. Remove contaminated clothing. Apply 2.5% calcium gluconate gel to the bum area using a surgical hand gloves. Ingestion Drink 1 to 3 glasses of water or milk. Do not induce vomiting. Seek medical attention immediately. Inhalation Move to fresh air. If breathing has stopped or is laboured give assisted respiration. Do not give mouth-to-mouth resuscitation - use a mechanical respirator. If necessary, oxygen may be administered by a trained person. If unconscious, place in the recovery position. Seek medical attention immediately by Phoning the Apex care hospital phone number (07272-251127).

Air Extract Failure In the event of a failure of the air extraction system. Any procedures being undertaken in the bay should be halted, the bay evacuated and the door closed. The electrical supply to the reactor should be stopped if possible. Inform to safety manager on 786 / 07272-666786 and maintenance in-charge (08223997999). Re-entry to the bay should not be attempted before the fault is repaired unless wearing self-contained breathing apparatus.

Reaction Overheating Over- pressurizing In the event of a reaction overheating or over-pressurizing, the system shall automatically cut of the utility ( steam ) and start supply of cooling system by applying utility like brine. After de-pressurizing and cooling the vessel is emptied. The audio/visual alarm is provided to indicate high pressure high temperature situation to the operator. The reactor operations are controlled through the computerized system to avoid manual operational error. The operating parameters are monitored from the screen of computer. Rapture disc, safety valves are provided to the reactor to control the runaway reaction due to high pressure or temperature. Dump tank is provided to contain the runaway reaction. Pressure gauges, tempera- 59 | P a g e

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ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date : ture gauges are installed on reactors. Experienced executives, officers are appointed to handle the reaction.

Dealing with a Ruptured Burst-Disc If the burst-disc has ruptured. The electrical supply to the heating reactor stops automatically. If not this is done manually. The vessel is allowed to cool to room temperature before entering the bay. The reaction mixture should have been contained within the reaction vessel, the dump tank and the connective pipework. These must be emptied and cleaned using the following procedure.  Put on a SF4/HF resistant suit. Boots and gloves. Connect the air hood to the air supply. Put on the hood and ensure that an adequate flow of air is flowing through the hood.  Enter the bay.  Another person should prepare the KOH scrubbing solution and fill it in the alkali scrubber located outside of the plant.  Open the vent of reactor to release pressure from the system.  Flush the reactor and transfer line with plenty of nitrogen gas.  Dismantle all contaminated pipework and clean out.  Dismantle the dump tank and clean out.  Open the reactor and clean out.  Ensure that the set-up is pressure tested before recommencing work.

Gas Leakage An audio alarm will activate in case of leakage of gas when the SF4 content on the bay is more 0.001 ppm. In such cases do not enter the area without air suit. Arrest the leakage from cylinder. Inform to safety manager on 786 / (07509744635) and maintenance incharge 790 / (08223997999). Re-entry to the bay should not be attempted before the fault is repaired unless wearing self-contained breathing apparatus.

Leaks from the Pressure Vessel In the event of leakage of hazardous materials from the pressure vessel, evacuate the bay and close the door. Tum off the electrical supply to the pressure vessel. Inform to safety manager on 786 / (07509744635) and maintenance in-charge on 790 / (08223997999). of the likelihood of excess hazardous material flowing up. Do not return to the bay until the vessel has cooled to room temperature and venting of the vessel has ceased. Only return while wearing a Mask-Air hood and protective suit. Release the pressure and evacuate the vessel. Do not re-use the vessel until the cause of the leak has been established and the vessel has passed a pressure test.

Leaks from SF4/HF connective tubing. In the event of any leaks of SF4/HF from faulty connections, if safe to do so the supply of SF4/HF must be stopped immediately by closing the cylinder valve. If the leak results in escape of SF4/HF into the area. It must be evacuated and the fire alarm activated. Inform to safety manager on 786 /666786 Any further attempts at cutting off the supply of SF4/HF must only be made by an experienced SF4 user while wearing a Mask-Air hood and protective suit.

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Seized Cylinder Valve A secondary valve will be attached to the cylinder connections so that, in the event of the cylinder valve seizing, SF4 flow can be stopped by closing the secondary valve. Any faults with the cylinder must be reported to the cylinder supplier.

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APPENDIX -20

EMERGENCY PREPAREDNESS FOR UNCONTROLLED SITUATIONS

DEVIATION CONSEQUENCE PRESENT PRECAUTIONS / ACTIONS S High wind Structure failure High wind is considered during plant design. Structure stability test carried out regularly. Plant inspection, maintenance and painting carried out regularly. Action plan for different equipment / system failure available with all the plants. On site emergency plan is available and Mock Trials are carried out regularly. Offsite emergency plan is available. Well equipped, full time fire fighting facilities available. Well equipped, full time medical facilities are available. Safe shutdown procedures, available for all the plants. Employees are educated for emergency preparedness

Dust Pollution Lime powder is used in the ETP for the removal of fluoride content from the effluent. The dust mask is used at the time of addition/ preparation of lime solution. ETP sludge is stored in wet cake form which gets harden on drying. Operating staff is trained and PPE are given to them.

Raw material / Majority of the RM/FP are in liquid form at or above Finished prod- atmospheric pressure. All such chemicals are stored in ucts well designed tanks. Special care is taken to store hazardous chemicals. Separate dedicated area is provided for the storage of finished goods. All the cylinders and tonners are stored in closed shed approved by PESO. Fencing is provided to the gas cylinder like SF4 shade.

High rains Water clogging Separate outlet lines are provided for effluent and storm water to final disposal to avoid any mix-ups. All the plants are connected to ETP for effluent and floor washings. All the plants and roads are provided with storm water trenches, the common outlet of which is connected to the city storm water outlet. Enough care

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is taken during electrical installations.

ETP failure Untreated efflu- Effluent of pilot plant, Kilo lab, CGMP Plant-2, ware- ent house-I and warehouse-II are going to ETP, in common collection put by gravity. The collection pit is big enough to store hours of effluent without outlet. Spares are kept ready for all the critical drives. For long shutdown of ETP.

EMERGENCY PROCEDURE FOR DIVERSION OF STORM WATER DRAIN TO ETP

 In case of incidental leakage or spillage or acid / alkali in any area, check the pH of nearest storm water trench.  Check presence of chemical and if so pH is acidic (below 6.5) or basic (above 8.5) in nature immediately block the area and inform superior about the same.  Inform about the leakage / spillage to ETP people.  After attending leakage / spillage at source, check pH of storm drain.  If pH is neutral (Between 6.5 to 8.5), inform the superior accordingly.

APPENDIX -21

EMERGENCY PROCEDURES FOR NATURAL DISASTERS

Only two natural disasters are Investigation based on geography. 1. Floods

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2. Earthquake Emergency Procedures for flood situation: Precautions taken before flood situation: 1. Food, drinking water storage arrangement for minimum three days. 2. All critical medical supplies (prescriptions, insulin, etc.) inventory is maintained. 3. Have a portable flashlights with extra batteries are kept in plant. 4. Elevation of all plants in relation to flood plains is determined and escape route to safe locations are identified. 5. Connection to District Disaster Control Centre. 6. Mobile phone is provided to all key persons for direct. 7. Chemicals especially drums storage is secured. Precautions taken during Flood: 1. Listen to local radio or TV for weather information. 2. Follow instructions of local civic bodies like shut off power, main gas valve and water valve. 3. Ensure that those plants generating effluents are stopped. Precautions taken after the Flood: 1. Test drinking water for portability. 2. Check for structural damage to plant and buildings especially to electrical installations 3. Do not use an open flame as a light source because of possibility of escaping gas. Use flashlights. Beware of dangerous sparks. 4. Do not use food that has been contaminated by flood water. As soon as information regarding worsening of flood situations comes from civic authorities, Onsite disaster plan shall be activated.

EMERGENCY PROCEDURES – EARTHQUAKE

Precautions taken before hand for Earthquake 1. Drinking water Storage and Food Supply stock of minimum three days shall be available 2. Organize portable emergency kit consisting of gas cutting sets, hacksaws, hammers, spanner sets, spades, shovel, scoops etc is available at emergency control centre During an Earthquake 1. STAY CALM 2. If you are indoors, stay inside and find protection in a doorway, or crouch under a desk or table, away from windows or glass dividers; avoid masonry wall (brick) and chimneys ). 3. Outside: Stand away from buildings, trees, telephone and electric lines. 4. On the Road: Drive away from underpasses/overpasses; stop in a safe area; stay in vehicle. 5. In an Office Building: Stay next to a pillar or support column or under a heavy table or desk. After an Earthquake 64 | P a g e

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1. Immediately take plant and building facility round 2. While taking round wear full body protection PPE and keep respiratory aid handy 3. Check for injuries. Provide first aid. 4. Check for safety - gas, water, sewage breaks; check for downed electric lines; turn off interrupted utilities as necessary; check for plant building damage and potential safety problems during aftershocks, such as cracks around chimney and foundation. 5. Check for the fires, pipeline leakages, tank foundation damages. 6. Clean up dangerous spills. 7. Tune radio to an emergency station and listen for instructions from public safety agencies. 8. Use the telephone only for emergencies. 9. As soon as possible, notify your family that you are okay. 10. Do not use matches or open flames until you are sure there are no gas leaks. 11. Do not turn light switches off and on. Sparks created by the switch contacts can ig- nite gas fumes. 12. In public buildings, follow evacuation procedures immediately and return only after the building has been declared safe by the appropriate authorities. 13. Report damages or needs to your Site Head, Project Leader, Head EHS, Head HR & Admin immediately. Immediately after getting information from civic authorities that earth quake is over, onsite disaster plan shall be activated.

APPENDIX -22

FOOD POISONING EMERGENCY: Definition Food poisoning comes from eating food or drinking water that is the contaminated with a virus, bacterium, parasite, or chemical that causes illness. It is also called gastroenteritis. The organisms and chemicals that cause food poisoning can contaminate food at any point during the production process. Animal products cause the majority of food poisonings. Causes and symptoms Food poisoning can be divided into two basic types: illness caused by infectious organisms and illness caused by chemicals. The infectious organisms (pathogens) that cause food poisoning are bacteria, viruses, and parasites. Chemicals can be either natural toxins (poi- sons) found in plants (e.g. poisonous mushrooms) or they can be man-made chemicals such as pesticides or herbicides. Symptoms of food poisoning usually develop anywhere within 1- 48 hours after eating contaminated food. Symptoms of chemical food poisoning often appear very quickly. The type of symptoms and their severity depend on the cause of the food poisoning, the amount of contaminated food eaten, and the health of the individual. Symptoms usually develop sud- denly. Some common symptoms of food poisoning include: . nausea followed by forceful vomiting . Frequent diarrhoea. Stools can be extremely watery and may or may not contain blood . painful stomach cramps 65 | P a g e

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. fever . headache . dizziness . blurred vision, difficulty breathing, tingling in hands and feet (chemical food poisoning) Food poisoning is caused by many different organisms, but identifying the exact organism is not usually necessary. Most mild food poisoning is diagnosed by the symptoms of vomiting, diarrhea, and stomach cramps coupled with information about that the individual has recently eaten. The length of time between eating the suspect food and the start of symptoms gives physicians a clue about what particular organism may be causing the food poisoning. Blood and urine tests may be ordered to determine the individual’s degree of dehydration and electrolyte (chemical) imbalances. In most cases, determining the exact patho- gen that is causing the food poisoning is relatively unimportant, as treatment tends to be the similar for most causes. However, if diarrhea is persistent, a stool culture may be done to provide more specific information. When chemical or natural toxin poisoning is suspected, determining the exact cause is more important, and treatment is specific to the cause. The stomach may be pumped and the contents tested. Extensive blood tests are usually needed. Sometimes activated charcoal is used to help absorb the poison in the stomach.

Treatment The main goal of treatment for food poisoning is to keep the individual from becoming dehydrated. A loss of 20% of a person’s body fluid is fatal, and 10-15% is serious. In food poisoning, huge amounts of both water and electrolytes can be lost quite rapidly. Mild cases of food poisoning can usually be treated at NFIL, especially if they are not accompanied by a fever. Dehydration be prevented or treated by giving them oral rehydration solutions. NFIL has kept sufficient stock of such electrolytes. Oral rehydration solutions have the proper balance of salts and sugars to restore fluid and electrolyte balance. In food poisoning avoid drinking coffee, tea, and soft drinks, especially soft drinks that contain caffeine, as these liquids promote dehydration. Over-the counter medications to stop or slow diarrhea will not shorten the duration of the disease, but may give the individual some control over his or her bowels. Individuals of all ages who are seriously dehydrated need to be treated promptly by a medical professional. In the case of severe dehydration, the individual may be hospitalized and fluids given intravenously (IV; directly into the vein). Drugs may also be prescribed to stop persistent vomiting. Although bacteria cause many cases of food poisoning, antibiotics are not routinely used in treatment. Some studies have shown that antibiotics are necessary only in about 10% of cases. Individuals who think their food poisoning symptoms are caused by chemicals or natural toxins should seek emergency medical care immediately. Prevention Certain foods are more commonly associated with food poisoning than others. All such food are identified and prevented from serving at canteen. These include:  Mushrooms / Meat / Poultry / Fish /Eggs  Unpasteurized milk products or unpasteurized fruit juice  Ready-to-eat raw fruits and vegetables  Improperly canned foods (homemade or commercial).  Left over food

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Appropriate food handling procedures at every level of the production process is established. All utensils and processors are cleaned and disinfected regularly.

Management of Food Poisoning:

 Rest  No Food Per Mouth  If Diarrhoea without Vomiting- Tab Lopamide is given for control of Diarrhoea.  For Nausea or Vomiting- Tab Domstal, Tab Reglan or Cap Omez-DM is given  For Bacterial or Amoebic infection- Tab Normetrogyl is given.  For Symptomatic relief - Tab Cyclopam & other medicines are given  For Fluid loss & for replenishment-Either Clear Fluid in beginning and then electro ion powder is given in water.(ORS)  The treatment is tailored to the need of individual patient’s condition, type of poisoning. Severity and degree of dehydration. Serious patient with marked dehydration is required to be hospitalized.  In case of moderate to severe dehydration patients should be admitted in hospital without delay.  Above medicines are given after consultation with Apex care hospital Doctors only.

Medicines available at OHC and First Aids Boxes. Sr. No Particulars /Medicine Usage of Particulars /Medicine Name 1. Gentamycin Eye/Ear Drops Eye/ Ear Use 2. Soframycin Minor cuts, wounds and Burn etc. 3. Povidone-Iodine Ointment Minor cut Injury 4. Burn Heal Minor skin Burn 5. Iodex Pain of muscles 6. Dettol Antiseptic liquid 7. Real Pain Relief Spray Muscles Pains 8. Dettol Medicated Plaster Small cut injury 9. Calcium gluconate gel Burns of AHF & SF4 10. Cotton Dressing 11. Cotton Gauze Dressing

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APPENDIX -23

TRANSPORT EMERGENCY DUE TO ACCIDENT OF VEHICLE CARRYING HAZARDOUS CARGO, LEAKAGE OF CYLINDER / CONTAINER.

A major road transportation emergency could be caused by an accident by any one of these carriers. In addition, it may not just affect those on the road, but if carrying hazardous materials could require closure of businesses and either sheltering in place or evacuation as necessary. There are two type of emergency for carrying hazardous goods vehicle of NFIL products during transportation on road out site the NFIL site:

1. Leakage of gas 2. Leakages of liquid

1. Leakages of gas: Type of Gas: Toxic, Corrosive and Flammable A. Toxic B. Corrosive Filled container: a. Cylinder Filled container: a. Cylinder b. Tonner b. Tonner c. Tanker

C. Flammable: NO

2. Leakages of liquid: A. Toxic B. Corrosive Filled container: Filled container: a. Carboys a. Cylinder b. Tanker c. Drums

C. Flammable: a. Carboys b. Drums

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Main Causes are Traffic accidents are influenced by weather conditions, speed of traffic and number of vehicles occupying the road. Conditions that usually lead to accidents include, but are not limited to, rain, fog, high speed and heavy traffic congestion.

Effects Transportation accidents, depending on the type, can have a profound effect on the community at large. Some involve quantities of hazardous materials requiring evacuation and/or hospitalization of large numbers of people. Even when no hazardous materials are involved, they may become mass casualty incidents. As such they can overtax the medical, fire, police and volunteer response agencies. They may damage private property, destroy businesses, close roads, highways, shipping lanes or airports. They may cause long term ecological damage to some portions of the environment.

Procedure to mitigation of consequences in case of road transportation emergency Duties of Driver;

 In case of leakage vehicle take the vehicle to some open place to ensure exposure to minimum no. of people or should be parked in such a way that the leaking gas will not affect the moving traffic and the affected area should be cordoned off.  In emergency situation immediately inform the Police, Fire Brigade, Consigner, Con- signee and other specified emergency nos.  If you think after consulting with the consigner that you can tackle the situation ensure your Safety by using PPEs in correct manner.

Duties of NFIL representative’s team:

As massage received from the transporter or other way, following procedure to be ma- naged:

 Get complete information regarding location , material and condition etc  Assess the situation as per communication with driver , transporter or other persons  Form a trained team which can handle the critical situation  Collect following items : - Acid / Organic mask with cartridge - Ansell type / Super nitrile / cotton gloves - Set of spanner - Cutter - SCBA - Neutralizer powder like lime , Soda ash - Full body suit - Required tools like lid opener , Spade , Axe , Rope , Hammer, Chain etc

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- Container lid like CAP with lock - List of emergency contact number - Digging equipments - Empty Drums / Carboy - Others as per requirements depends on situation All above required items collect and kept with the team in a vehicle

APPENDIX -24

UTILITIES FAILURE EMERGENCY MANAGEMENT Following utilities are covered for steps to be taken in case of emergency due to failure: UTILITIES: A. Electricity Supply failure B. Water Service including Chilled and Brine water supply failure D. Steam Supply Failure A. Utility Failures: Electricity supply Failure

1. Purpose: The purpose of this procedure is to provide guidance regarding the response to a building / plant electricity utility failure.

2. Primary Responsible Unit: The primary responsible unit is the maintenance department.

3. Secondary Responsible Units: The secondary responsible unit is the Officer or Head EHS.

4. Employee Responsibility: The employee(s) that discover an electrical service failure should notify maintenance by using intercom facility or mobile.

5. Policy and Procedure Overview: With the receipt of the call to maintenance that electrical supply failure, the following actions will be expected to occur: 70 | P a g e

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A. Maintenance Department (during normal working hours) will:

1) The maintenance/electrical person shall start D.G set. 2) Contact the Electrical officer / executive on 790, 793 & 794 by phone or mobile and inform him of the emergency situation. Personnel required to correct the emergency condition would be assigned. 3) Call the security at 780 / 07272-666780 to inform them of the emergency. 4) Contact the Head EHS by phone or mobile informing that an emergency condition exists in company.

B. Shift Supervisor (during off hours coverage) when discovering or informed of an electrical service failure will:

1) Contact by telephone the on-call high voltage electrician and direct him to respond to the emergency condition.

C. Administratively:

1) In the event of a loss of electrical services to a plant building, Site Main controller (SMC) representative will talk to the appropriate company administrator to assess the impact that the loss of electric service will have on building operations.

2) A Site Main Controller representative will contact Risk Management to coordinate insurance services to handle related property damage or loss.

6. Company Resources:

The following company resources are available to assist with the electrical service failure.

a. Maintenance Department b. Engineering Services and Experts c. Fire and Security d. Environmental Health and Safety

7. Resources: The following external Resources are available to assist with the electrical service failure:

a. Mutual Aid Members b. Dewas Nagar Nigam c. District Disaster Management d. On-call contractors.

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1. Purpose: The purpose of this procedure is to provide guidance regarding the response to a plant building water service including brine and chilled water failure.

2. Primary Responsible Unit: The primary responsible unit is Maintenance department.

3. Secondary Responsible Units: The secondary responsible units are the Admini- stration.

4. Employee Responsibility: The employee(s) that discover a water service failure shall notify Operations and Maintenance by dialling 790, 793 & 794.

5. Policy and Procedure Overview: With the receipt of the call to concerned plant that a water service failure exists, the following actions will be expected to occur,

a. Work Control (during normal working hours) will:

1) Contact the Manager / officer Electrical/Mechanical in maintenance department by phone and inform them of the emergency situation. Personnel required to correct the emergency condition would be assigned. 2) Call Fire and security at 780 / 07272-666780 to inform them of the emergency. 3) Contact the Admin Manager by phone or mobile, informing the an emergency condition exists in plant.

b. Shift Supervisor (during off hours coverage) when discovering or informed of an electrical service failure will:

1) Contact by telephone to Maintenance Manager on mobile and Mechanical shift officer direct him to respond to the emergency condition.

2) Contact the Admin Manager by phone or mobile informing them that an emergency condition exists in plant.

3) Call Fire and security at 780 / 07272-666780 to inform them of the emergency.

c. Administratively:

1) In the event of a loss of water services to a building an Site Main Controller representative will talk to the appropriate company administrator to assess the impact that the loss of water service will have on building operations.

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6. Company Resources: The following company’s resources are available to assist with the water service failure. a. Division of Maintenance department. b. Water supply management c. Administration Department d. Fire and Security department

7. External Resources: The following external resources are available to assist with the water service failure: a. On-call contractors b. Mutual Aid Members c. Dewas Nagar Nigam d. District Disaster Management e. Association of industries

C. Utility Failures: Steam

1. Purpose: The purpose of this procedure is to provide guidance regarding the response to a plant steam service failure.

2. Primary Responsible Unit: The primary responsible unit is the Maintenance De- partment.

3. Secondary Responsible Units: The secondary responsible units are Safety and Environmental Health and Safety.

5. Employee Responsibility: The employee(s) that discover a steam service failure shall notify Operations and Maintenance by dialling at 790, 793 & 794.

4. Policy and Procedure Overview: With the receipt of the call to plant Control room that a steam service failure exists, the following actions will be expected to occur:

a. Work Control (during normal working hours) will:

1) Contact the HOD, Electrical/Mechanical by intercom or phone and inform them of the emergency situation. Personnel required to correct the emergency condition would be as signed.

2) Call Fire and Security department at 780 / 07272-666786 to inform them of the emergency.

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b. Shift Supervisor (during off hours coverage) when discovering or informed of steam service failure will:

1) Contact by telephone or Mobile to the HOD and direct him to respond to the emergency condition.

2) Contact the Head EHS of by phone or mobile informing them that an emergency condition exists on campus.

3) Call Fire and Security department at 780 to inform them of the emergency.

6. Administratively:

a. In the event of a loss of steam services to a plant building an Site Main Controller Representative will talk to the appropriate Site Main Controller to assess the Impact the loss of steam service will have on building operations and effect to plant

7. Company Resources: The following company resources are available to assist with the water Service failure. a. Division of Administration, SCM & Maintenance Department. b. Office of Fire and Security department c. Environmental Health and Safety

8. External Resources: The following external resources are available to assist with the steam Service failure:

a. On-call contractors b Mutual Aid Members c. Dewas Nagar Nigam d. District Disaster Management e. Association of Industries, Dewas.

APPENDIX -25

PROPOSAL TO LIQUIDATE RESIDUE

The NFIL has a well-established procedure for handling of hazardous waste. Hazardous waste generation is from the following sources. 1. Manufacturing Process 2. ETP 3. DG set and Transformer 4. Incinerator operation Tar waste (1.2) : This is a tarry mass subject to solidification after some time. This has a good calorific 74 | P a g e

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value and incineration is easy. This is generated during last step of manufacturing operation. The tarry mass is collected in drums and then transferred to incinerator by forklift. Safety is ensured in all operations. Discarded containers (33.3 ) : Discarded containers are generated after the use of raw material in process. The containers are cleaned properly and send to the hazardous waste storage area. Finally it sold to the authorized recycler / Vendor. ETP sludge (36.4 ): The sludge is collected from sludge drying pits and from cleaning operation of solar ponds. Sludge is then transferred to incinerator. It is having organic mass as one of the component. It is collected and stored in HDEP bags / Drums. Sludge is combustible and incinerated easily. Used Oil (5.1) : Waste oil is collected from DG sets/ Transformer. After certain use of oil as lubricant, it is waste. This oil has good calorific value. It is collected and stored in drums. This is used as a fuel in incinerator. Incinerated Ash (36.2): Ash is generated in incineration operation. Ash is collected in HDPE/LDPE bags and stored in hazardous waste storage area.

19.1 TREATMENT: Tar waste: No treatment is given. It is sent to incinerator as it is. Waste oil: No treatment is given. It is sent to incinerator as it is. Sludge: Dewatering is done under atmospheric condition. Ash: No additional treatment is given.

19.2 TRANSPORT: Tar waste: Tar waste is transported by the forklift from plant/process to incinerator. Waste oil: Waste oil is transported by the forklift from DG sets to incinerator. Sludge: After dewatering sludge is collected in drums and then transported to incinerator Ash: Bags of ash is transported by forklift to ash storage pit. Process waste: Tar waste is transported by the forklift from plant/process to incinerator.

19.3 DISPOSAL: The NFIL is life time member of Madhya Pradesh waste management project, Pithmpur, Dhar, Madhya Pradesh. (Common hazardous waste treatment storage and disposal facility). The Incinerated ash and ETP sludge is directly send to CHWTSDF for disposal. All hazardous waste are stored in contained on concrete platform in dedicated hazardous waste storage area. The disposal method for the waste is as below. Tar waste: Tar waste is incinerated. Waste Oil : Waste oil is used as a fuel in incinerator. Discarded containers: Sold to authorize recycler. Sludge: ETP Sludge is incinerated / Send to CHWTSDF, Ash: Ash is send to CHWTSDF for disposal. Process waste: Process waste is incinerated.

Type and quantity of hazardous waste as per authorization.

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Sr. Type of Haz. Cat. No Existing Qty. Source of generation No Waste (Sch-1) MT/A 1 Tar Waste Manufacturing proc- 1.2 0.2 ess 2 Used oil DG set, Plant machin- 5.1 0.4 ery 3 ETP sludge ETP 34.3 35 4 Spent Carbon Manufacturing proc- 35.3 2 ess 5 Incinerated Ash Incinerator 36.2 5 6 Discarded Con- Used Raw material 33.3 1.2 tainers container

APPENDIX -26

LAST MOCK DRILL OBSERVATIONS AND ACTION PLAN

Opportunities for Improvement:

Other equipment running Nearby equipment of inci- Dr. Dhiraj 1. around incident spot were Done dent spot to be shut off. Singh not shut off.

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Medical Oxygen Cylinder rota meter to be repaired or Medical Oxygen Cylinder Saket 2. replaced. Check should pre- Done rota meter not working. Sharma pare & maintain on regularly.

APPENDIX -27

(QUALITY, ENVIRONMENTAL, OCCUPATIONAL HEALTH & SAFETY POLICY)

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APPENDIX -28

LIST OF ANTIDOTES

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NAVIN FLUORINE INTERNATIONAL LIMITED,DEWAS

ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

SR. CHEMICALS ANTIDOTES NO. 01 Acetonitrite, Acr- Cobalt EDTA ( Calocyonor), Nitrite/Thiosulphate lonitrile, Lactoni- trile 02 Acid & Sulphur Sodium Hydro- Carbonate (4% Conc.) Milk, Lime Juice, Milk Oxide of Magnesia. 03 Alkali Phos- Gluconate Solution (10%) phates, Ammonia ( Intravenous Administer 5 ml) Prednisolone ( oral or intravenous). 04 Ammonia Skin : Wash with Lactic Acid, Apply soframycin Eye : Benoxynate (Novacin?0.4% Conc. Throat : Smelling Ethanol or Ether 05 Aniline, Toluene, Mitholene Blu- 1% Nitro - Benzene Excartic Acid- 5% 06 Antimony and Dyeser Krepol stibine 07 Arsine ( Hydro- Merkeptide (40% solution, dyperkrepol, penisilamine) gen arsenide) 08 Atropine Pilokarpin (1 % solution, proserine 0.5%) 09 Barbiturates Bemigride(0.5% Solution) 10 Benzene, Xylene Diazem – 1 mg/kg. (Intravenous),Epenephia, Efidrine & Toluene 11 Benzene, Xylene, Wash the skin area plenty of water if affected. Fresh air or Toluene. Oxygen, 0.1 mg/kg slowly through injection rest in bed. Don’t apply Epinefrin, Ifridin etc. Don’t apply milk, vegetable oil or alcohol. 12 Barium and its Magnesium sulphate (30 grams in 250 ml. water) morefin (5 salts to 10 mg) 13 Bleaching Solu- Milk, Ice cream, eggs, milk of magnesia, aluminium hydrox- tion ide gel. Do not give acid antidotes. 14 Boric acid and Epicake solution and activated charcoal. If vomited give 5% boron derivatives dextrose through injection. 15 Bromates or Sodium thio sulphate 1ml/ kg 10% solution through injec- Cosmetics tion. 16 Bromides Wash the skin area plenty of water if affected. 1 gm salt through oral at every hour. Milk and water. 17 Cadmium Calcium dysodium editate through injection. 18 Carbon monoxide Pure oxygen through mask. 20% mennytole(1gm/ kg) prednisolone 1 mg/kg through injection. 19 Carbonyls Sodium di-ethyle di-thio carbomates tablets. If trouble for respiration give oxygen. Don’t give alcohol) 20 Chlorates Epikake solution, activated charcoal, milk. Give through oral 2 yo 5 gm solution thiosulphate in 5% sodium bi carbonates solution in 200ml. Methylene blue is dangerous

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NAVIN FLUORINE INTERNATIONAL LIMITED,DEWAS

ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

SR. CHEMICALS ANTIDOTES NO. 21 Chloride, Bro- Wash the skin plenty of water. Apply sodium bi carbonate mine, Phosgene and again wash the skin plenty of water. If gone in eye, wash plenty of water through spray up to 15 minutes. Put two or three drops of pontocane (0.5 solution) or benoxinate ( novesine) 0.4%. if problem in respiration, give milk, butter milk or lemon juice or make a small cotton ball and drench with ethanol or ether solution drops and put it near victim’s nose for smell. Apply pure oxygen. If go in the intestine give milk, Milk butter and milk of magnesia. 22 Chromium Dymerkrepole, high protein, vitamins and carbohydrates in foods. 23 Cyanides and Methylene blue or kelocynere injection. If go through respira- thio cynates in- tion smelling amyl nitrite (3% solution) and sodium thio sul- secticides phate (25% solution) through injection. But if the blood pressures go low than stop the medicine. 24 DDT Epicake syrup, Activated charcoal, saline cathartic diazepam ( Helogenated In- (10 mg slowly through injection, wash the skin through wa- secticides) ter and soap). Give pure oxygen if problem in respiration. 25 Di- chloro- Hydrocortisone (200mg at every 4 hrs.) Aspirin and if pneu- methane monia gives antibiotics. 26 Di- mythylsul- If skin injury, magnesium oxide pest. Cotirco steroid injec- phate tion. If problem in respiration give oxygen 27 Di- nytrophenol 5% glucose saline through injection. or cresol 28 Ethanol 2 gm sodium bi carbonate in 250ml water. Diazepam 10mg through injection. I injury in eye or skin wash plenty of water. 29 Ethylene or Ethanol, Calcium gluconate Di-ethylene glycol 30 Florin, hydrogen Calcium gluconate 10ml in 10% solution through injection. fluoride and de- If the level of Sirum Magnesium is low than give 10ml Milk of rivatives. Magnesia Milk and liquid food should be given more. If the eye got injury than wash plenty of water and put the drops of calcium gluconate (10% 31 Dichromate No specific antidotes other than neutralizing & chelating agent. General line of treatment, removal, immediate induc- tion of vomiting followed by quick referral to emergency ward of hospital. 32 Ethanol Methanol 33 Ethyl Acetate Novesine, Eye Drops 34 Ethyl Marcap- Oxygen 35 F.D.tans Charcoal 36 Formaldehyde Fresh Air/ Milk / Water

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NAVIN FLUORINE INTERNATIONAL LIMITED,DEWAS

ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

37 HCI Eno, Milk of Magnesia, Cordinol Tab, Eye Drops 38 Hydrochloric Drink Large quality of water 39 HydrochloricAcid Milk of Magnesia SR. CHEMICALSAcid ANTIDOTES NO. 40 Iso Propyl Alco- Novasine Eye Drops 41 Leadhol Nitrate No specific antidotes other than neutralizing & chelating agent. General line of treatment, removal, immediate induc- tion of vomiting followed by quick referral to emergency ward of hospital. 42 Life Saving Medi- Adrenaline cine 43 Liquid So2 Milk of Magnesia 4% Sodium Hydro Carbonate Solution Milk 44 Liquid So3 Milk of Magnesia 4% Sodium Hydro Carbonate Solution Milk 45 Acetic Acid Milk of magnesia 46 Maleic Anhydride Oxygen 47 Mercuric Acetate No specific antidotes other than neutralizing & chelating agent. General line of treatment, removal, immediate induc- tion of vomiting followed by quick referral to emergency ward of hospital. 48 Mercuric Chlo- No specific antidotes other than neutralizing & chelating ride agent. General line of treatment, removal, immediate induc- tion of vomiting followed by quick referral to emergency ward of hospital. 49 Methanol Oxygen 50 Methanol Baking Soda in a glass of water 51 Methanol Ethanol 52 Methanol Novasine Eye Drops 53 Mono-chloro Oxygen Treatment Benzene 54 Monochloro Ace- Silver Sulphadiazine tic Acid 55 Nitric Acid Milk of magnesia 56 Nitro Benzene Methylene Blue 57 Oleum Milk of Magnesia 4% Sodium Hydro Carbonate Solution Milk 58 Organo Chloride Atropine 59 Organo Phos- Atropine Injection, Atropin Tab., Pam Inj. Charcoal Tab. 60 Organophates Phospho- Atropine Injection, Diazepam Injection 61 Organorus Phospho- Atropine Injection, Diazepam Injection, Methylene Blue In- 62 Organorus Phospho- Atropinejection Winopam Inj. 63 P.C.A.rus Compounds Methylene Blue

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NAVIN FLUORINE INTERNATIONAL LIMITED,DEWAS

ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

64 Para Anisic Alde- - 65 Parahyde Anisic Alco- - 66 Parahol Cresidine - 67 Phorate Ethion Atropine Sulphate Injection & Neaopam Injection. 68 PhorateTerbufos Tarba- Atropine, Pam tos, P.D., DDVP & Acephate 69 Phosphorus Pen- Oxygen tasulfide SR. CHEMICALS ANTIDOTES NO. 70 Potassium No specific antidotes other than neutralizing & chelating agent. General line of treatment, removal, immediate induc- tion of vomiting followed by quick referral to emergency ward of hospital. 71 Potassium No specific antidotes other than neutralizing & chelating Chromate agent. General line of treatment, removal, immediate induc- tion of vomiting followed by quick referral to emergency ward of hospital. 72 Quanal Phose Injection Pam Amp. 73 Quanal Phose Injection Atropine Amp 74 Radent Bailt ( Injection of Kaplin ( Vitamin-K) Racumin) 75 Selenium Metal No specific antidotes other than neutralizing & chelating agent. General line of treatment, removal, immediate induc- tion of vomiting followed by quick referral to emergency ward of hospital. 76 Silver Nitrate No specific antidotes other than neutralizing & chelating agent. General line of treatment, removal, immediate induc- tion of vomiting followed by quick referral to emergency ward of hospital. 77 Silver Sulphate No specific antidotes other than neutralizing & chelating agent. General line of treatment, removal, immediate induc- tion of vomiting followed by quick referral to emergency ward of hospital. 78 Snake Venom Antisnake Venom Serum 79 Snake Poisoning Antisnake Venom Amp. 80 SO3 Milk of Magnesia Liquid 81 HF/H2SO4 Skin Calcium Gluconate GEL (HF/H2SO4 Gel) Contact 82 HF/H2SO4 Eye Calcium Gluconate Eye Wash Bottle (HF/ H2SO4 Eye Wash Contact Bottle) 83 HF/H2SO4 Inha- Calcium Gluconate Injection lation/ Ingestion

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NAVIN FLUORINE INTERNATIONAL LIMITED,DEWAS

ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

84 KCN Amyl Nitrate, Sodium Nitrate and Sodium thio sulphate

DISTRIBUTION LIST:

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NAVIN FLUORINE INTERNATIONAL LIMITED,DEWAS

ON SITE EMERGENCY PLAN Document No. : NF/OEP/01/04 Supersedes : NF/OEP/01/03 Effective Date :

Distribution List: Copy No. Department Name 01 Environment, Health & Safety 02 Emergency Control Center 03 Quality Assurance 04 Production Blocks (cGMP-1, cGMP-2 & Rambo) 05 Quality Control 06 Process Development Lab 07 Analytical Development Lab 08 Electrical & Instrument 09 Maintenance 10 Ware house 11 Microbiology 12 Sales/ Commercial / SCM 13 Human Resource & Administration

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