EC-SAFETY DATA SHEET
ALCAT TEAL - 94 Version: 1.08 Revision Date 07.02.2019
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1 Product identifier Trade name ALCAT TEAL - 94
REACH No. 01-2119432993-32-0000 Substance name (REACH / CLP) triethylaluminium
1.2 Relevant identified uses of the substance or mixture and uses advised against Use Research and development Intermediate Used in closed system raw material for synthesis processes in the chemical industry Uses advised against
1.3 Details of the supplier of the safety data sheet Company SASOL Germany GmbH Anckelmannsplatz 1 20537 Hamburg
Telephone: +49 40 63684-1000 Telefax: +49 40 63684-3700
Information (Product safety): Telephone: + 49 (0) 23 65 - 49 47 05 Telefax: + 49 (0) 23 65 - 49 92 40
E-mail address [email protected]
1.4 Emergency telephone number Emergency telephone number +1 703-741-5970 (CHEMTREC World Wide)
SECTION 2: HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
Classification (REGULATION (EC) No 1272/2008) Pyrophoric liquids, Category 1 Catches fire spontaneously if exposed to air. Substances and mixtures, which in contact with In contact with water releases flammable gases which may ignite water, emit flammable gases, Category 1 spontaneously. Skin corrosion, Category 1B Causes severe skin burns and eye damage.
2.2 Label elements Labelling (REGULATION (EC) No 1272/2008)
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Hazard pictograms
Signal word Danger
Hazard statements H250 Catches fire spontaneously if exposed to air. H260 In contact with water releases flammable gases which may ignite spontaneously. H314 Causes severe skin burns and eye damage.
Precautionary statements P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P302 + P334 IF ON SKIN: Immerse in cool water/ wrap in wet bandages. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER/doctor. P422 Store contents under nitrogen. Supplemental Hazard Statements EUH014 Reacts violently with water.
2.3 Other hazards No hazards to be specially mentioned.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
This product is a substance in the meaning of regulation (EC) 1907/2006.
COMPONENTS TO BE NAMED IN ACCORDANCE WITH REGULATION (EC) 1907/2006 AS WELL AS OTHER HAZARDOUS INGREDIENTS AND CONTAINED SUBSTANCES WITH WORK PLACE LIMIT VALUES
Triethylaluminium
content: > 94 % component type: Active ingredient
EC-No.: 202-619-3 Index-No.: 013-004-00-2 CAS-No.: 97-93-8 REACH No.: 01-2119432993-32-0000 Substance name (REACH / CLP): triethylaluminium Classification (Regulation Pyr. Liq. 1 H250 (EC) No 1272/2008): Water-react. 1 H260 Skin Corr. 1B H314
Tributylaluminium
content: < 6 % component type: Impurity
EC-No.: 214-240-0 Index-No.: 013-004-00-2 CAS-No.: 1116-70-7
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EC-SAFETY DATA SHEET
ALCAT TEAL - 94 Version: 1.08 Revision Date 07.02.2019
Classification (Regulation Pyr. Liq. 1 H250 (EC) No 1272/2008): Water-react. 1 H260 Skin Corr. 1B H314
For the full text of the H-Statements mentioned in this Section, see Section 16.
SECTION 4: FIRST AID MEASURES
4.1 Description of first aid measures General advice Get medical attention immediately. Move out of dangerous area. Take off all contaminated clothing immediately. Show this safety data sheet to the doctor in attendance. If inhaled Remove to fresh air. If breathing has stopped, apply artificial respiration. If breathing is difficult, give oxygen. Call a physician immediately. In case of skin contact Wash off immediately with plenty of water for at least 15 minutes. Destroy contaminated shoes. Wash contaminated clothing before re-use. Call a physician immediately. In case of eye contact In case of eye contact, remove contact lens and rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Call a physician immediately. If swallowed Oral ingestion of the product is practically not possible because of the spontaneous flammability.
4.2 Most important symptoms and effects, both acute and delayed Most important symptoms and Symptoms: No information available. effects, both acute and delayed Risks: No information available.
4.3 Indication of any immediate medical attention and special treatment needed Indication of any immediate Treatment: No information available. medical attention and special treatment needed
SECTION 5: FIREFIGHTING MEASURES
5.1 Extinguishing media Suitable extinguishing media Dry chemical, Dry sand Unsuitable extinguishing media Foam, Halons, Carbon dioxide (CO2), Do NOT use water jet.
5.2 Special hazards arising from the substance or mixture Specific hazards during Dangerous gases or fumes may occur in case of fire. firefighting Reacts violently with water.
5.3 Advice for firefighters Special protective equipment In the event of fire, wear self-contained breathing apparatus. Use personal for firefighters protective equipment. Aluminized complete fire proximity suit (Form 3 according DIN EN 1486) Further information Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Cool closed containers exposed to fire with water spray. No standard methods have been developed for extinguishing large-scale metal alkyl fires. Small fires may be extinguished using dry powder (ABC or M).
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ALCAT TEAL - 94 Version: 1.08 Revision Date 07.02.2019
CAUTION: reignition may occur. Water often strongly reacts with metal alkyl! Water based foams, chemical foams, and halogenated extinguishers may NOT be used. Waterspray may only be used by experienced fire fighters. Water reacts violently with metal alkyls but has been found to be an effective fire control treatment if one is thoroughly familiar with the violent reaction and personnel are properly protected from explosion. Remove unnecessary personnel from the danger area. Consider to let it burn out completely.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Personal precautions Handle in accordance with good industrial hygiene and safety practice. Remove unnecessary personnel from the danger area. Remove all sources of ignition. Use personal protective equipment. Do not breathe vapours or spray mist. Avoid contact with skin, eyes and clothing. Drying of this product on clothing or combustible materials may cause fire. Special precautions Only qualified personnel equipped with suitable protective equipment may intervene. The danger areas must be delimited and identified using relevant warning and safety signs.
6.2 Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up Methods for cleaning up Keep away from water strictly. Cleaning procedures can not be defined as the product itself is flammable in air.
6.4 Reference to other sections For personal protection see section 8.
SECTION 7: HANDLING AND STORAGE
7.1 Precautions for safe handling Advice on safe handling Do not allow contact with air. Triethylaluminium and it solutions must be handled under a dry, inert atmosphere e.g. nitrogen or argon. Keep away from water. Protect from moisture. Ensure adequate ventilation. Avoid spark promoters. Ground/bond container and equipment. These alone may be insufficient to remove static electricity. During sampling, disconnecting lines or opening connections, flame/fire resistant clothing or an aluminised suit should be worn. Do not get on skin or clothing. This substance should be handled under strictly controlled conditions as specified in REACH regulation article 18(4). Site documentation to support safe handling arrangements in accordance with risk-based management system should be available at each manufacturing site. During the whole lifecycle all necessary measures should be undertaken to minimize emissions and any resulting exposure. Advice on protection against Use explosion-proof equipment. fire and explosion Keep away from heat and sources of ignition. Reacts violently with water, liberating highly flammable gases. Print Date 03.12.2019 000000013893 CONEUSDBUS E 4/14
EC-SAFETY DATA SHEET
ALCAT TEAL - 94 Version: 1.08 Revision Date 07.02.2019
Water must be scrupulously removed from process equipment prior to putting it into metal alkyl service. Failure to do so may result in fire or explosion. For aluminium alkyls such as triethylaluminium, any contact with air - even for very small amounts - will lead to generation of smoke or spontaneous ignition. Fire-fighting class B: Fires involving liquids or liquid containing substances. Also includes substances which become liquid at elevated temperatures. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas Store under inert gas (nitrogen). Keep container tightly closed. Protect from and containers moisture. Optimal storage temperature is ca. 20°C. Store in original container. Further information on storage Store under inert gas (nitrogen). conditions Other data No decomposition if stored and applied as directed. container material suitable materials: Steel, Copper, bronze unsuitable materials: Lead, Aluminium 7.3 Specific end use(s) Specific use(s) This information is not available.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Control parameters COMPONENTS WITH WORKPLACE CONTROL PARAMETERS National occupational exposure limits
Control parameters / Typ Control Update Basis Substance name parameters ALUMINUM (SOLUBLE REL 2 mg/m3 2005 NIOSH Pocket Guide to SALTS AND ALKYLS, AS AL) Chemical Hazards
measured as: as Al
ALUMINUM, AS /AL/, ALKYLS TWA 2 mg/m3 1989 OSHA Table Z-1-A
measured as: as Al
ALUMINUM (SOLUBLE REL 2 mg/m3 2005 NIOSH Pocket Guide to SALTS AND ALKYLS, AS AL) Chemical Hazards
measured as: as Al
ALUMINUM, AS /AL/, ALKYLS TWA 2 mg/m3 1989 OSHA Table Z-1-A
measured as: as Al
EUROPEAN OCCUPATIONAL EXPOSURE LIMITS No data available
DERIVED NO EFFECT LEVEL (DNEL) Substance name: triethylaluminium
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EC-SAFETY DATA SHEET
ALCAT TEAL - 94 Version: 1.08 Revision Date 07.02.2019
No data available
PREDICTED NO EFFECT CONCENTRATION (PNEC) Substance name: triethylaluminium No data available
8.2 Exposure controls
ENGINEERING MEASURES Provide sufficient air exchange and/or exhaust in work rooms. If possible, use material transfer/filling, metering and blending plants that are closed. Triethylaluminium and it solutions must be handled under a dry, inert atmosphere e.g. nitrogen or argon. Handle under inert gas. Protect from moisture.
PERSONAL PROTECTIVE EQUIPMENT Hand protection The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other., Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time., Be aware that in daily use the durability of a chemical resistant protective glove can be notably shorter than the break through time measured according to EN 374, due to the numerous outside influences (e.g. temperature).
gloves suitable for splash protection: Material: butyl-rubber Break through time: 30 min Layer thickness: 0,5 mm
Material: heat protective gloves (aluminum coated)
Material: Leather gloves (chemically resistant)
unsuitable gloves Material: Leather gloves (untreated)
Eye protection Goggles, Face-shield Skin and body protection Aluminized complete fire proximity suit (Form 3 according DIN EN 1486), Protective helmets, Neck shroud, Safety shoes Hygiene measures Avoid contact with skin, eyes and clothing. Keep working clothes separately. Wash hands before breaks and at the end of workday.
ENVIRONMENTAL EXPOSURE CONTROLS General advice Do not flush into surface water or sanitary sewer system. Do not let product enter drains.
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ALCAT TEAL - 94 Version: 1.08 Revision Date 07.02.2019
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Physical state liquid; 20 °C; 1.013 hPa Form Liquid Colour colourless Odour No information available. Odour Threshold No valid method available
pH Not applicable, Justification:, Decomposes in contact with water. Melting point/range ca. -46 °C Boiling point/boiling range 128 - 130 °C; ca. 67 hPa ca. 185 °C; 1.013 hPa Flash point Not applicable auto-flammable Evaporation rate No data available Flammability (solid, gas) not applicable (liquid)
Lower explosion limit No data available Upper explosion limit No data available Vapour pressure 67 hPa; 128 - 130 °C ca. 0,03 hPa; 25 °C Relative vapour density ca. 4 Density 0,834 g/cm3; 20 °C Water solubility Decomposes in contact with water. Partition coefficient: n- Obtaining data is technically impossible. octanol/water Justification: Decomposes in contact with water. Ignition temperature No data available Auto-ignition temperature Catches fire spontaneously if exposed to air. Viscosity, dynamic 2,6 mPas; 20 °C Explosive properties Not explosive; Method A.14, Directive 92/69/EEC Oxidizing properties No data available
9.2 Other data None known.
SECTION 10: STABILITY AND REACTIVITY
10.1 Reactivity Note Reacts violently with water. Risk of violent reaction. Spontaneously flammable in air.
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10.2 Chemical stability Note Decomposes upon contact with air. Decomposes on heating.
10.3 Possibility of hazardous reactions Hazardous reactions Triethylaluminium (TEAL) reacts very violently and under significant evolutions of heat with compounds like: water, oxidizing agents, halogenated hydrocarbons, alcohols, amines, acids, oxygen (air!), oxides of sulfur, nitrogen and carbon, halogens, inorganic hydroxides, phenols, paper, saw dust, cotton and other organic substances.
10.4 Conditions to avoid Conditions to avoid Direct heating, dirt, chemical contamination, sunlight, UV or ionising radiation. Exposure to moisture Exposure to air. Heat, flames and sparks.
10.5 Incompatible materials to avoid Materials to avoid Water; Strong oxidizing agents; Alcohols; Halogenated compounds; Acids
10.6 Hazardous decomposition products Hazardous decomposition Hazardous decomposition products due to incomplete combustion products Reacts violently with water, liberating highly flammable gases.
Thermal decomposition If heated at tmore than 120°C decomposition and pressure increase may occur. Thermal decomposition results in the production of hydrogen, ethylene and elemental aluminum (Caution: pressure increase, risk of fire and explosion!). Decomposition reactions can be catalyzed via dispersed metals (especially aluminum or titanium). Further information Spontaneously flammable in air.
SECTION 11: TOXICOLOGICAL INFORMATION
Triethylaluminium: Due to the known reactivity, testing this category of highly reactive chemicals would not generate meaningful data.
11.1 Information on toxicological effects Acute toxicity Acute oral toxicity Triethylaluminium: No data available Acute inhalation toxicity Triethylaluminium: No data available Acute dermal toxicity Triethylaluminium: No data available
Skin corrosion/irritation Skin irritation Triethylaluminium: Based on strong reactivity of aluminium alkyls with water, these compounds are expected to cause thermal burns to eye and skin.
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Serious eye damage/eye irritation Eye irritation Triethylaluminium: Based on strong reactivity of aluminium alkyls with water, these compounds are expected to cause thermal burns to eye and skin.
Respiratory or skin sensitisation Sensitisation Triethylaluminium: No data available
Germ cell mutagenicity Genotoxicity in vitro Triethylaluminium: No data available Genotoxicity in vivo Triethylaluminium: No data available
Carcinogenicity Carcinogenicity Triethylaluminium: This information is not available.
Reproductive toxicity Reproductive toxicity Triethylaluminium: This information is not available. Teratogenicity Triethylaluminium: This information is not available.
STOT - single exposure Remarks Triethylaluminium: This information is not available.
STOT - repeated exposure Remarks Triethylaluminium: This information is not available.
Aspiration hazard Aspiration toxicity Triethylaluminium: Not applicable
SECTION 12: ECOLOGICAL INFORMATION
Triethylaluminium: It is concluded that it is not feasible or necessary to perform environmental fate, mammalian or ecotoxicity tests based on the highly reactive nature of these chemicals when in contact with air and water.
12.1 Toxicity Toxicity to fish Triethylaluminium: No data available Toxicity to fish - Chronic Triethylaluminium:
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toxicity No data available Toxicity to daphnia and other Triethylaluminium: aquatic invertebrates No data available Toxicity to daphnia and other Triethylaluminium: aquatic invertebrates - Chronic No data available toxicity Toxicity to aquatic plants Triethylaluminium: No data available Toxicity to bacteria Triethylaluminium: No data available Toxicity to soil dwelling Triethylaluminium: organisms No data available Toxicity to terrestrial flora Triethylaluminium: No data available Toxicity for other terrestrial Triethylaluminium: non-mammalian fauna No data available
12.2 Persistence and degradability Biodegradability Triethylaluminium: No data available
12.3 Bioaccumulative potential Bioaccumulation Triethylaluminium: No data available
12.4 Mobility in soil Mobility Triethylaluminium: No data available
12.5 Results of PBT and vPvB assessment Results of PBT assessment Triethylaluminium: No data available
12.6 Other adverse effects General advice Triethylaluminium: None known.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Product Dispose of in accordance with local regulations. Contaminated packaging Empty containers and tanks should be returned to the supplier. waste code of the European A waste code in accordance with the European Waste Catalogue (EWC) may not Union: EWC be assigned to this product since it admits of a classification only when the consumer uses it for some purpose.
SECTION 14: TRANSPORT INFORMATION
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14.1 UN number ADR 3394 RID 3394 ADN 3394 IMDG 3394 ICAO/IATA 3394 Not permitted for transport
14.2 Proper shipping name ADR ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC, WATER-REACTIVE (Triethylaluminium) RID ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC, WATER-REACTIVE (Triethylaluminium) ADN ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC, WATER-REACTIVE (Triethylaluminium) IMDG ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC, WATER-REACTIVE (Triethylaluminium) ICAO/IATA Organometallic substance, liquid, pyrophoric, water-reactive Not permitted for transport
14.3 Transport hazard class ADR 4.2 RID 4.2 ADN 4.2 IMDG 4.2 ICAO/IATA Not permitted for transport
14.4 Packing group ADR I RID I ADN I IMDG I ICAO/IATA Not permitted for transport
14.5 Environmental hazards ADR Environmentally hazardous no RID Environmentally hazardous no ADN Environmentally hazardous no IMDG Marine pollutant no ICAO/IATA Environmentally hazardous no
14.6 Special precautions for user ADR Hazard Identification Number X333 Labels 4.2 (4.3) Tunnel restriction code (B/E) IMDG Labels 4.2 (4.3) EmS Number 1 F-G EmS Number 2 S-M Air transport forbidden.
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
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Remarks No information available.
SECTION 15: REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Occupational restrictions Employment restrictions for children and young workers in accordance with Directive 94/33/EC and the respective national provisions are to be observed.
NATIONAL/OTHER REGULATIONS Legislation on the control of Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on major-accident hazards the control of major-accident hazards involving dangerous substances. involving dangerous substances list entry in the directive:: PYROPHORIC LIQUIDS AND SOLIDS; P7 Qualifiying quantity 1: 50 t; Qualifiying quantity 2: 200 t; Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. list entry in the directive:: OTHER HAZARDS; O1 Qualifiying quantity 1: 100 t; Qualifiying quantity 2: 500 t; Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. list entry in the directive:: OTHER HAZARDS; O2 Qualifiying quantity 1: 100 t; Qualifiying quantity 2: 500 t;
NOTIFICATION STATUS Switzerland. Consolidated Inventory CH INV listed (product or constituents are listed) US. Toxic Substances Control Act TSCA listed (product or constituents are listed) Canada. Canadian Environmental Protection Act (CEPA). DSL listed (product or constituents Domestic Substances List (DSL) are listed) Australia. Industrial Chemical (Notification and Assessment) Act AICS listed (product or constituents are listed) Japan. Kashin-Hou Law List ENCS (JP) listed (product or constituents are listed) Japan. Industrial Safety & Health Law (ISHL) List ISHL (JP) listed (product or constituents are listed) Korea. Existing Chemicals Inventory (KECI) KECI (KR) listed (product or constituents are listed) Philippines. The Toxic Substances and Hazardous and Nuclear PICCS (PH) listed (product or constituents Waste Control Act are listed) China. Inventory of Existing Chemical Substances (IECSC) INV (CN) listed (product or constituents are listed)
Please note: the names and CAS numbers which are used for this product in the stated inventories may deviate from the information which is listed in chapter 3.
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ALCAT TEAL - 94 Version: 1.08 Revision Date 07.02.2019
15.2 Chemical safety assessment
triethylaluminium A chemical safety assessment has not been carried out (substance registered as intermediate or production volume < 10 t/a).
SECTION 16: OTHER INFORMATION
Full text of H-Statements referred to under sections 2 and 3. H250 Catches fire spontaneously if exposed to air. H260 In contact with water releases flammable gases which may ignite spontaneously. H314 Causes severe skin burns and eye damage.
Safety datasheet sections which have been updated: 1. Identification of the substance/mixture and of the company/undertaking
Further information: The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. This safety datasheet only contains information relating to safety and does not replace any product information or product specification.
Key or legend to abbreviations and acronyms used in the safety data sheet
ADN Accord européen relatif au transport international des marchandises dangereuses par voie de navigation intérieure ADR Accord européen relatif au transport international des marchandises Dangereuses par Route AICS Australian Inventory of Chemical Substances ANSI American National Standards Institute ASTM American Society of Testing and Materials (US) BCF Bioconcentration factor CLP Regulation on Classification, Labelling and Packaging of Substances and Mixtures DIN Deutsches Institut für Normung DNEL Derived No-Effect Level DSL Domestic Substances List EC… Effect concentration ... % ENCS Existing Notified Chemical Substances (Japan) EWC European Waste Catalogue IATA International Air Transport Association IBC Intermediate Bulk Container ICAO International Civil Aviation Organization IMDG International Maritime Dangerous Goods IMO International Maritime Organization ISHL Industrial Safety and Health Law (Japan) ISO International Organization for Standardization IUAPC International Union of Pure and Applied Chemistry KECI Korea Existing Chemicals Inventory LC… Lethal Concentration, ...% LD… Lethal Dose, ...% MARPOL International Convention for the Prevention of Pollution From Ships NDSL Non-Domestic Substances List NOAEL no observable adverse effect level NOEL/NOEC No Observed-effect level/concentration NZIoC New Zealand Inventory of Chemicals Print Date 03.12.2019 000000013893 CONEUSDBUS E 13/14
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OECD Organisation for Economic Co-operation and Development PBT persistent, bioaccumulative, toxic PICCS Philippine Inventory of Chemicals and Chemical Substances PNEC Predicted No-Effect Concentration REACH Registration, Evaluation, Authorisation and Restriction of Chemicals RID Règlement concernant le transport international ferroviaire de marchandises dangereuses TG Test Guideline TRGS Technische Regeln für Gefahrstoffe TSCA Toxic Substances Control Act vPvB very persistent, very bioaccumulative WGK Wassergefährdungsklasse
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