RISK ASSESSMENT

INTRODUCTION Industrial plants deal with materials, which are generally hazardous in nature by virtue of their intrinsic chemical properties or their temperature or pressure of operation or a combination of these. Fire, explosion, hazardous release or a combination of these are the hazards associated with industrial plants. These have resulted in the development of more comprehensive, systematic and sophisticated methods of safety engineering such as hazard analysis and risk assessment to improve the integrity, reliability and safety of industrial plants. The primary emphasis in safety engineering is to reduce risk to human life and environment. The broad tools attempt to minimize the chances of accidents occurring. Yet, there always exists, no matter how remote, that small probability of a major accident occurring. If the accident involves highly hazardous materials in sufficiently large quantities, the consequences may be serious to the plant, to surrounding areas and the populations therein.

RISK ASSESSMENT AND HAZARD IDENTIFICATION Hazard identification, HAZOP and risk assessment for proposed LPG plant have been carried and risk mitigation measures have been spelled to enhance safety for proposed LPG Plant and same is presented in RRA Report attached to EIA Report Disaster Management Plan for the unlikely event of an emergency is available and same is presented in RRA Report attached to EIA Report.

RISK REDUCTION MEASURES Risk Assessment study provides a quantitative technique for assessing the significance of the impact of any facility on its external environment, highlights key areas for greater attention and provides a tool for comparing alternative options. Though, it cannot substitute for close attention to the fundamentals of safety throughout the design process or for design reviews. For risk reduction, attempts should be made to either reduce inventories that could get released in the event of loss of containment or failure likelihood or both as far as feasible. Risk Assessment identifies the dominant risk contributors, which enables prioritization of plants/section that deserve special attention in terms of inspection and maintenance in particular and overall safety management as a whole.

Risk Mitigation Measures The LPG bottling plant is major accident hazard installations under Manufacture, Storage, Import of Hazardous Chemicals. Rule, 1989 and subsequent amendments. During design, construction and operation of the facilities, numbers of safety provisions and risk reduction measures will need to be implemented and followed meticulously in compliance with applicable acts, rules, regulations, codes, standards, guidelines and best industry practices. This also includes provisions for not only state-of-the-art equipment, control and instrumentation to enhance safety but also high-level induction and refresher safety training from senior management to contractual workers levels at the facilities. Risk mitigation measures for the LPG bottling plant are described below:

Mounded Bullets The mounded storage of LPG has proved to be safer as compared to above ground storage vessels since it provides intrinsically passive and safe environment and eliminates the possibility of Boiling Liquid Expanding Vapour Explosion (BLEVE). The cover of the mound protects the vessel from fire engulfment, radiation from a fire in close proximity and acts of sabotage or vandalism. The area of land required to locate a mounded system is minimal compared to conventional storage. The following measures are suggested during design, erection and operation of mounded storage bullets for LPG. i. Provisions of “OISD Standards 150: Design and Safety Requirements for Liquefied Petroleum Gas Mounded Storage Facility” shall be included in design and operation. ii. Each mound bullet shall have accessibility to fire tender from at least two sides. iii. The minimum separation distance between mounded LPG storage and any other (other than LPG pump/compressor house) facility associated with LPG plant shall be 15 meters. This distance to be measured from the edge of the mound at the finished ground level and also from the first valve on the vessel i.e. ROV. iv. The minimum inter-distance between the edges of the vessel in a mound shall not be less than 2 meters. v. Proper provision shall be made for countering the consequences of the settlement of the vessel under the mound. The surrounding of the bottom connection should be filled with such material that can absorb such settlement. vi. Provision shall be made to monitor the settlements of the mound by providing a permanent reference point. A minimum of three reference points shall be installed to be able to also identify possible vessel bending (One each near the vessel ends and one in the middle.) vii. The fire safe Remote Operated Shutdown Valve (ROV) on liquid drain line from the vessel shall be either from the bottom of the vessel or from the top of the vessel as per the design considerations. viii. In the case of liquid drain line from the bottom of the vessel, the minimum distance of 3 meters from the vessel to ROV shall be maintained. The nozzle pipe shall have a slope of 1.5 Deg. ix. There shall not be any other flanges or any other tapping up-to-the ROV except in the case of liquid drain line from the top of the vessels. x. Each vessel shall have at least two pressure relief valves. The full flow capacity of Pressure Relief Valves (PRV) on mounded vessels may be reduced to not less than 30% of the capacity required for an equivalent size of above ground vessel. For safety reasons, the discharge of Pressure Relief Valves shall be connected to the flare system. In this case, Pressure Relief Valves (PRVs) shall have lock open (or car seal open) type isolation valves on both sides of Pressure Relief Valve. xi. The Pressure Relief valves shall be tested and calibrated every year by a competent person and records shall be maintained. xii. Cathodic protection system shall be provided, maintained and tested routinely. xiii. Any change in the system will be marked on P&ID. The system of “Management of Changes” may be developed as per “Guidelines on Management of Change” (OISD GDN 178). xiv. Any repairs or modifications should be undertaken after statutory approval from the applicable authority. xv. Each storage vessel shall have minimum two different types of level indicators and one independent high-level switch. High-level alarms shall be set at not more than 85% level of the volumetric capacity of the vessel. xvi. Audiovisual indication shall be at local panel and control room. xvii. Automatic fire detection and /or protection (Fixed) system based on heat detection through thermal fuses/ quartz bulbs shall be employed. Sensors shall be installed at all critical places including as described below: • Minimum 1 detector shall be provided on each exposed portion of the vessel. However, if the nozzles are covered in a dome, each group shall have 2 numbers of detectors. • At least one near each liquid line ROV to take care of failure of flanges. xviii. Suitable gas detectors shall be placed at critical locations in the LPG storage area such as, near the ROV, in inspection tunnel, near water draining/ sampling points, etc. Audiovisual alarms showing the location of gas leakage shall be provided on the control panel in the control room. The first level alarm can be set at 20% LEL and second level alarm at 40 % LEL of LPG. xix. All mounded storage vessels, LPG Pump Houses, Bullet Tanker Gantries shall be fully covered by medium velocity water spray system. LPG storage area, automatic detection of heat for automatic actuation of medium velocity sprinkler system having remote/ local operated deluge valve with spray density of 10 lpm/m2 of surface area shall be provided. xx. Hydrant and monitor coverage shall also be provided on all four sides of the mounds for adequate coverage of unprotected portions exposed to thermal radiation including for top of the mound and for piping, in the immediate vicinity of the mound. In view of accessibility of unprotected portions of the vessels, for effectiveness, installation of remotely operated monitors at appropriate height shall be considered. xxi. Hydrant /monitors shall be located at a safe place around the mound. In any case, and/or monitors shall not be installed within 15 meters from the facilities/equipment to be protected.

Maintenance Schedules The proper preventive maintenance schedule should be prepared to facilitate the maintenance service to be rendered in a planned manner covering the necessary work to be done, mentioning the periodicity i.e. daily, weekly, monthly, half yearly and yearly schedules. Electrical Hazards Some Important measures to minimize electrical hazards are as given below: • The classification of the area for electrical installations at LPG storage and handling facilities shall be as per OISD Standards 113. • Inspection of electrical equipment shall be carried out as per OISD Standards 137. • All electrical equipments shall be provided with proper earthing. • Earth pits shall be periodically tested and maintained in good condition. • Emergency lighting shall be available at all critical locations including fire pump room, control room, etc. • All electrical equipments shall be free from carbon dust, oil deposits, and grease. • All electrical cable will be tagged for easy identification and cable routing shall be planned away from heat sources, gas, water, oil, drain piping and air conditioning ducts. • All lights in LPG storage area, pump house, unloading bays, etc will be flameproof. • Provisions shall be made for approved insulated tools, rubber mats, shockproof gloves and boots, tester, fuse tongs, discharge rod, hand lamp, insulated ladder. • Flame and shock detectors and central fire announcement system for shall be provided in MCC control panel room. • Temperature sensitive alarm and protective relays to make alert and disconnect equipment before overheating shall be provided. • Danger from excess current due to overload or short circuit should be prevented by providing fuses, circuit breakers, thermal protection, etc. • Only carbon dioxide and dry chemical fire extinguishers shall be used for electrical fires.

Fire Fighting Facilities Fire protection system shall be designed in accordance with the requirements of OISD, NFPA standards, design requirements and safe engineering practices. facilities should have full capability for early detection and suppression of fire. The firefighting system will primarily consist of: • Hydrant system • Foam protection system • Deluge sprinkler system • Portable • Fire detection and alarm system Occupational Health, Safety & Environmental Features in the Project Process Safety & Safety Features Process Safety focuses on the prevention of fires, explosions and accidental chemical releases at LPG Bottling facilities. Safety Management Systems The Safety Officer in coordination with Shift-in-Charge review all plant operations to identify potential unsafe conditions and/or potential problems which may lead to health or safety exposures. Plant personnel shall work with the Safety Officer to identify potential problems and to identify proper operational procedures and the operational areas of the plant. Actions to be taken include equipment or procedural changes, development of exposure monitoring strategies, and the inclusion of warning statements in procedures. Hazard Analysis by the Team QRA studies are conducted at the plant before commissioning and also applied to the proposed installation and modification of buildings, equipments, mechanical and electrical systems, utilities, fire protection system, grounds etc. Plans or specifications on designated projects shall be submitted to an acceptance committee consisting of Operations Manager, Engineering. Manager, Safety Manager for review prior to project implementation. Recommendations will be submitted with the final plans and specifications to the Departmental head for review. If the departmental head finds that plans and specifications are not meeting the recommendations of the acceptance committee, he shall return the final plans to the originator for modifications or a justification of deviations. Inspections The officer in charge of each function is responsible for ensuring the timely completion of periodic inspections and correction of problems. The frequency of specific inspections is as follows: Safety Facilities in the Plant • Leak detection, prevention • Elimination of source of ignition • Fire prevention / fighting • Communication, First aid, Rescue and Personnel protection equipment. Leak Detection: Gas Monitoring System: The system consists of gas detecting sensors with a control panel and audio / visual alarms. Currently, 34 gas sensors are installed in the plant, the location of the sensors are given in the below table. Two additional gas sensors will be installed for the proposed expansion, the new carousel in and new carousel out. The sensors give an initial alarm at 20% LEL and continuous alarm at 40% LEL.

Location of Existing GMS Sensors

1 Bullet 1 ROV 2 Bullet 1 Access Tunnel 3 Bullet 1 Man Hole 1 4 Bullet 1 Man Hole 2 5 Bullet 2 ROV 6 Bullet 2 Access Tunnel 7 Bullet 2 Man Hole 1 8 Bullet 2 Man Hole 2 9 Bullet 3 ROV 10 Bullet 3 Access Tunnel 11 Bullet 3 Man Hole 1 12 Bullet 3 Man Hole 2 13 47.5 Kg Filling Machine 14 LPG P/H Pump 15 LPG P/H Compressor 16 Carousel In 17 Carousal Out 18 Evacuation 19 ICU 20 Valve Change Shed 21 Filled Cylinder Shed 22 TLD BAY No.1 23 TLD BAY No.2 24 TLD BAY No.3 25 TLD BAY No.4 26 TLD BAY No.5 27 TLD BAY No.6 28 TLD BAY No.7 29 TLD BAY No.8 30 TLD BAY END 31 Filled Cylinder Shed 32 Bullet 1 Drain 33 Bullet 2 Drain 34 Bullet 3 Drain

Proposed Leak Prevention / Minimizing: Air / Vapour Extraction System: It is basically a blower with ducts extended to different operating points in filling shed. The blower extracts any leaking LPG vapour from the floor level and cold flares the same to the free atmosphere at LPG cylinder filling shed. Remote Control Valves: These are electro-pneumatically operated quick shut off valves provided on LPG pipelines with actuating points located remotely and nearer to operating facilities in the plant. When actuated, the valves will close within 25 seconds, starving the LPG flow in pipelines. The ROV’s are installed at the following locations: • Storage bullets Liquid & Vapour lines • TLD liquid lines • LPG Pump outlet lines near filling shed ROV’s Interlock with High-Level Alarm All LPG bulk mounded vessels are fitted with High-Level Alarm switches which give an alarm when the product reaches 85% of its volume. A signal has been taken from HLA to actuate the ROV to close which will stop the flow of liquid into vessels. This stops the overfilling/flowing of LPG into vessels.

Ignition Sources Another identified potential source for Fire accidents is “Ignition”. To eliminate such sources, following the following firefighting Equipments are installed in the plant.

Fire Fighting Equipments Location/ Equipment Equipments Nos. Bulk Storage Area-Vessel DCP EXTINGUISHER 10 KG 10.00 Bulk Storage Area DCP EXTINGUISHER 75 KG 1.00 Cyl. Filling / Storage shed-10 Kg DCP DCP EXTINGUISHER 10 KG 52.00 Cyl. Filling / Storage shed-75 Kg DCP DCP EXTINGUISHER 75 KG 5.00 LPG Pump House DCP 10 KG DCP EXTINGUISHER 10 KG 5.00 LPG Pump House DCP 75 KG DCP EXTINGUISHER 75 KG 1.00 TTL BAY DCP 10 KG DCP EXTINGUISHER 10 KG 8.00 TTL BAY DCP 75 KG DCP EXTINGUISHER 75 KG 1.00 Air Compressor house DCP EXTINGUISHER 10 KG 2.00 Fire Pumps DCP EXTINGUISHER 10 KG 3.00 Office / stores DCP EXTINGUISHER 10 KG 2.00 Canteen DCP EXTINGUISHER 10 KG 3.00 Computer Room CO - FIRE EXTINGUISHER 2 2.00 2.0 KG MCC/DG room/ HT room CO 4.5 CO - FIRE EXTINGUISHER 2 2 12.00 KG 4.5 KG MCC/DG room/ HT room SAND 9 LIT SAND BUCKET & 8.00 BUCKET 9 LIT STAND Firewater Hoses IN HOSE BOXES FIRE HOSES 64.00 Jet noz_store JET NOZZLE 2.00 Jet noz_Hose Box JET NOZZLE 16.00 Jet noz_Fire Trolley JET NOZZLE 2.00 Water curtain nozzles WATER CURTAIN NOZZLES 2.00 Triple Purpose nozzle TRIPPLE ACTION NOZZLE 2.00 UNIVERSAL NOZZLE UNIVERSAL NOZZLES 2.00 box HOSE BOXES 36.00 Safety helmets SAFETY HELMET 64.00 Stretcher with blanket STRETCHER 1.00 First Aid Box FIRST AID BOX WITH ANTI 2.00 SNAKE Rubber Hand Gloves RUBBER HAND GLOVES 2.00 (PAIR) Low Temp Rubber Hand Gloves LOW TEMP HAND GLOVES 4.00 (PAIR) Low Temp Prot Clothing LOW TEMP PROTECTIVE 0.00 CLOTHING Fire Proximity Suit FIRE PROXIMITY SUIT 1.00 Resuscitators RESUSCITATORS 1.00 Red flags for Fire drill RED FLAG 2.00 Green flags for Fire drill GREEN FLAG 2.00 SCABA with spare cylinder SCABA WITH SPARE 1.00 CYLINDER PORTABLE GAS DETECTOR Portable 2.00 Hand operated HAND OPERATED SIREN 4.00 Electrical siren (1 km range) ELECTRIC SIREN 1 KM 1.00 RANGE Mobile trolley for FF FIRST AID FIRE TROLLEY 1.00 CO2 cartridges # 10 kg DCP (200 CO crtdg 200GM_10KG DCP 2 94.00 gms.) FE

CO2 cartridges # 75 kg DCP(2 Kg) CO2 crtdg 2KG_75KG DCP FE 4.00 DCP bags for 10 kg F.Es DCP POWDER (Kg) 840.00 DCP bags for 75 kg F.Es DCP POWDER (Kg) 160.00 Hazardous area WATER MONITORS WATER MONITOR 16.00 Non-Hazardous area WATER WATER MONITOR 7.00 MONITORS Hazardous area DBL HEADED HYD DOUBLE HEADED 24.00 POINTS HYDRANT POINT Non-Hazardous area DBL HEADED DOUBLE HEADED 7.00 HYD POINTS HYDRANT POINT Firewater as per OISD # 144 FIRE WATER STORAGE (KL) 7,400.00 Fire pump as per OISD # 144 FIRE PUMP CAPACITY 415 5.00 m3 /hr

Control Room • Control room shall be located at a sufficient distance from operating areas • All control room should be blast proof and shockproof. • Critical switches and alarm should be always kept in line. • A minimum number of doors shall be provided in the control room while at least two doors should be provided for the safe exit during an emergency. • Smoke detection system shall be provided for the control room.

Safety Audit and Inspection Checklist based routine inspection and safety audits should be carried out in line with OISD -144 for mounded bullets, pumps, piping and unloading bays, etc. Any gap or noncompliance should be implemented on priority in time bound manner.

Induction and Refresher Safety Trainings The provision shall be made for structured induction and refresher safety training for LPG handling system from senior management to contractual workers levels at the facilities. Emergency Response Plan Anticipating and planning for various contingencies is crucial for ensuring the success of any emergency response actions in an actual Emergency Situation. The on-site Emergency response plan shall be prepared for LPG Storage and filling facilities, to take the action in an unlikely event of an emergency due to the accidental release of LPG. Emergency Response Plan should be updated based on findings of mock drills.

Mock Drill Exercises The mock drill should be conducted once in six months. Exercises or drills have two basic functions, namely training and testing. While exercises do provide an effective means of training in response procedures, their primary purpose is to test the adequacy of the emergency management system and to ensure that all response elements are fully capable of managing an unlikely emergency situation. Mock drills are best means of accomplishing the following goals and objectives: • To reveal weaknesses in the plans and procedures before emergencies occur. • To identify deficiencies in resources (both in manpower and equipment). • To improve the level of coordination among various response personnel, departments and agencies. • To clarify each individual’s role and areas of responsibility.