Prefeasibility Report
ON
PROPOSED PROJECT FOR THE MANUFACTURE OF AGRO CHEMICALS & ORGANIC INTERMEDIATES
Category – 5 (b) of
M/S YASHASHVI RASAYAN PVT. LIMITED (UNIT-D2)
Located at: Plot No. Z/111/B, DAHEJ SEZ II, Dahej Industrial Estate, Tal: Vagra, Dist: Bharuch, Gujarat
New Project: 1 Manufacturing: Agro Chemicals & Organic Int.
Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
Project prefeasibility report for obtaining prior Environmental Clearance in terms of provisions of EIA Notification ‐2006
1. Executive Summary : Name & Location: Name of the Project : M/s. Yashashvi Rasayan Pvt. Limited (Unit D‐2) Location : Plot No.‐ Z/111/B, SEZ II, Dahej Industrial estate, Ta: Vagra, Di: Bharuch, Gujarat. Project
Ö M/S YRPL intends to set up a plant for the manufacture of Agro Chemicals & Organic intermediates at Plot. No. Z/111/B, SEZ:II, Dahej Industrial estate, Ta: Vagra, Di: Bharuch, Gujarat. The unit has already obtained offer cum plot allotment letter. The unit is falling under medium Scale category. Ö Proposed Project Cost: Rs. 64.25 Crore. Applicability of EIA notification – 2006 Ö Category as per the amended EIA notification‐ 2006: as proposed products (i.e. Agro Chemicals & Organic intermediates) are covered under the Category 5 (b) A. Hence, Environmental Clearance is required. Project Proponent • The company in India comprising 2 Directors • medium Scale Unit • List of finished products & by‐ products Sr. No. Group No. Main process step Name of the product Capacity, TPM
1 1 CHLORINATION Ortho 2000 DICHLOROBENZENE
Para DICHLOROBENZENE
2 1:2:4 TRICHLOROBENZENE
1:2:3 TRICHLOROBENZENE
3 MONOCHLOROBENZENE
4 o‐ CHLORO PHENOL
p‐CHLORO PHENOL
5 2,4 DICHLORO PHENOL
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Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
2,6 DICHLORO PHENOL
6 2 ‐ Hydro chloric acid 4712/2275 (30%)/Calcium Chloride
7 3 Chlorination 3 CHLORO 100 NITROBENZENE
8 2,4,6 TRICHLORO ANILINE
9 2,6 DICHLORO 4 NITRO ANILINE
10 4 Chlorination N‐ Valeroyl Chloride 75
11 Butyryl Chloride
12 5 DEAMINATION & 3:5 DICHLORO NITRO 150 ISOMERISATION BENZENE
13 1:3:5 TRICHLOROBENZENE
14 meta‐ DICHLOROBENZENE
15 6 NITRO COMPUUNDS ORTHO & PARA NITRO 1250 CUMENE
16 NITRO NAPHTHALENE
17 1:5 & 1:8 DINITRO NAPHTHALENE
18 2,4 DIMETHYL NITRO BENZENE ( 2,4 DMNB)
19 2,6 DIMETHYL NITRO BENZENE (2,6 DMNB)
20 2,3 DIMETHYL NITRO BENZENE (2,3 DMNB)
21 3,4 DIMETHYL NITRO BENZENE (3,4 DMNB)
22 2,5 DIMETHYL NITRO BENZENE (2,5 DMNB)
23 2,5 DICHLORO NITRO BENZENE (25 DCNB)
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Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
24 3,4 & 2,3 DICHLORO NITRO BENZENE ( 3,4 & 2,3 DCNB )
25 2,4 & 2,6 DICHLORO NITRO BENZENE
26 2,4,5 TRICHLORO NITRO BENZENE
27 2,3,4 TRICHLORO NITRO BENZENE
28 2,6 DICHLORO 4 NITRO PHENOL
29 2,3 DICHLORO 4 NITRO PHENOL
30 2,5 DICHLORO 4 NITRO PHENOL
31 7 HYDROGENATION ORTHO CHLORO 750 ANILINE
32 PARA CHLORO ANILINE
33 ORTHO CUMIDINE
34 PARA CUMIDINE
35 ALPHA NAPHTHYL AMINE
36 2,4 XYLIDINE
37 2,6 XYLIDINE
38 2,3 XYLIDINE
39 3,4 XYLIDINE
40 2,5 XYLIDINE
41 ORTHO ANISIDINE
42 PARA ANISIDINE
43 OTBCHA
44 PTBCHA
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Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
45 PHENYL ETHYL ACETATE
46 CITRONELLOL
47 DIMETHYL OCTANOL
48 CISPINANE
49 IPPCA
50 ORTHO TOLUDINE
51 PARA TOLUDINE
52 META TOLUDINE
53 3,5 DIAMINO BENZOIC ACID
54 3,5 DIMETHYL N ISO PENTYL AMINE
55 4:4 DISEC BUTYL PARA PHENYLINE DIAMINE
56 3 AMINO 9 (N ETHYL) CARBAZOLE
57 3,4 DIMETHYL N‐ISO PENTYL AMINE
58 4 AMINO 2,5 DICHLORO PHENOL
59 4 AMINO 2,3 DICHLORO PHENOL
60 4 AMINO 2,6 DICHLORO PHENOL
61 PHENYL EHYL ALCOHOL ( 2‐PEA )
62 2,5 DICHLORO ANILINE
63 2,3 DICHLORO ANILINE
64 3,4 DICHLORO ANILINE
65 2,4 DICHLORO ANILINE
66 2 CHLORO 1,4 DIAMINO
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Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
BENZENE
67 2,4,5 TRICHLORO ANILINE
68 2,5 DICHLORO 1,4 DIAMINOBENZENE
69 3,5 DICHLORO ANILINE
70 3 CHLORO ANILINE
71 p‐TERTIARY BUTYL CYLCOHEXANONE
72 p‐TERTIARY BUTYL CYLCOHEXANOLE
73 O‐TERTIARY BUTYL CYLCOHEXANONE
74 O‐TERTIARY BUTYL CYLCOHEXANOLE
75 MPBALCOHOL
76 2,4 DIMETHOXY 5 CHLORO ANILINE
77 8 PHENOLS 2,5 DICHLORO PHENOL 150
78 2,3 DICHLORO PHENOL
79 3,4 DICHLORO PHENOL
80 3,5 DICHLORO PHENOL
81 3 CHLORO PHENOL
82 2,5 DICHLORO 4 BROMO PHENOL
83 2,3 DICHLORO ANISOL
84 2,5 DICHLORO ANISOL
85 9 ACETYLATED 2':5' DICHLORO 200 COMPOUND ACETOPHENONE
86 2':4' DICHLORO ACETOPHENONE
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Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
87 2':4' DICHLORO VELEROPHENONE
88 2':4' DICHLORO 5 FLUORO ACETOPHENONE
89 2':4' DICHLORO PHENACYLCHLORIDE
90 2':4' DICHLORO BUTEROPHENONE
91 10 CONAZOLE AZACONAZOLE 200 FUNGICIDES 92 BROMUCONAZOLE
93 DIFENOCONAZOLE
94 ETACONAZOLE
95 HEXACONAZOLE
96 PROPICONAZOLE
97 PENCONAZOLE
98 PROTHIOCONAZOLE
99 IMAZALIL
100 TEBUCONAZOLE
101 DITHIANON
102 11 ETHERS ( IRON) AMINORESORCINE 100 DIORTHO CRESYL ETHER
103 2 AMINO 2',4,4' TRICHLORO DIPHENYL ETHER (TADE)
104 2 AMINO 4 CHLORO DIPHENYL ETHER
105 4 AMINO 2,4' DICHLORO DIPHENYL ETHER
106 2 AMINO 2'‐4 DICHLORO DIPHENYL ETHER
107 2 AMINO 4‐4' DICHLORO
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DIPHENYL ETHER
108 1,3 BIS (3‐AMINO PHENOXY) BENZENE
109 5 AMINO 2,2'‐3 TRICHLORO 4‐NITRO DIPHENYL ETHER
110 12 AMINATION ORTHOCHLORO 75 PARANITRO ANILINE
111 PARACHLORO ORTHONITRO ANILINE
112 ORTHO NITRO ANILINE
113 PARA NITRO ANILINE
114 2,3 DICHLORO 6 NITRO ANILINE
115 3,4, DICHLORO 6 NITRO ANILNE
116 5 CHLORO 2 NITRO ANILINNE
117 13 Speciality compound CUMAC 50
118 NITRO RF
119 DIETHYL DIPROPYL MALONATE
120 MALONIC ACID
121 PARACHLORO ANILINE HYDROCHLORIDE
122 4 NITRO PHTHALO NITRILE
123 FHIA
124 MSTT
125 THISA
126 TBSA
127 4 CHLORO 2' AMINO
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Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
DIPENYLAMINE (NDPA)
128 BINOL
129 OXYQUINOLINE COPPER
130 2H‐HEXAFLUORO PROPOXY PROPYLENE‐ 2,5‐DICHLORO 4 AMINO BENZENE
131 2,4 DIMETHOXY 5 CHLORO NITROBENZENE
132 2,5 DICHLORO 4 NITRO ANILINE
133 4 CHLORO 2 AMINO DIPHENYLAMINE (ADPA)
134 AMINO RF
135 4 AMINO BENZONITRILE
136 1,5 DIAMINO NAPHTHALENE
137 1,8 DIAMINO NAPHTHALENE
138 4 CHLORO 2 AMINO PHENOL
139 2 CHLORO 4 AMINO PHENOL
140 2,4 DIHYDROXYBENZOPHEN ONE
141 3 HYDROXY ACETOPHENONE
142 14 HERBECIDES 2,4 D ACID 75
143 ACLONIFEN
144 FLURIDONE
145 DITHIANONE
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Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
146 FLUFENACET
147 QUINOCLAMINE ( CAN )
148 15 PESTICIDE Fenvalerate 75
149 ALPHA METHRIN
150 DELTA METHRIN
151 PER METHRIN
152 LAMDACY HELOTHRIN
153 CYPERMETHRIN
154 DEET
155 16 Sulphonated SODIUM 70 compound NAPHTHIONATE
156 17 Oxidation Compound META TOLUIC ACID 100
157 18 Advance MPBAD 70 Interermediate
Grand Total 8202
• List of by‐products with monthly generation:
Sr. No. By‐Products Quantity, TPM
1 Spent Sulphuric acid (55‐60%) 3896.4
2 Sodium sulphite (20% Solution) 679.1
3 Aluminum chloride (18‐20% Solution) 2254.8
4 Hydro Bromic acid (28% solution) 544.8
5 Sodium sulphate powder 393.4
6 Potassium bromide powder 84
7 Potassium chloride powder 159
8 Potassium bi carbonate powder 56
9 Acetic acid (80% solution) 65.2
10 Sodium Bromide (20‐25% solution) 336.8
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Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
11 Bromine (99%) liquid 39
Total 8508.5
Manufacturing process with chemical reaction & mass balance is attached as Annexure‐3
Resource Requirement
Components Proposed Resources availability
Power, KVA 2500 Will be sourced from Torrent Energy Ltd (TEL) / Dakshin Gujarat Vij Co. Ltd. Fresh Water, kl/Day 1282 Will be sourced from SEZ Dahej Limited Coal for boiler (20 TPH 8 Will be sourced Local x 2 Nos), MT/Hr Dealer Coal for 20 lacs kcal 0.6 Will be sourced Local Thermic fluid heater, Dealer MT/Hr Fuel (HSD) for D.G.Set 250 Will be sourced from (2500 KVA) , Kgs/Hr Local Dealer Cooling Tower, TR 4000 In house Chilling plant, TR 500 In house
• Raw material Consumption
Sr. No. Raw Materials MT/MT of Product MT/Month O & P‐ Dichlorobenzene 1 Benzene 0.542 1084 2 Chlorine 0.968 1936 3 Process Water For Hcl 1.159 2318 4 Recycle Monochlorobenzene 0.25 500 Tri chloro benzene 1 Benzene 0.444 888 2 Chlorine 1.174 2348 3 Process Water For Hcl 1.407 2814 4 Recycle Dichlorobenzene 0.25 500 Monochlorobenzene 1 BENZENE 0.73 1460 2 CHLORINE 0.664 1328 3 Process Water For HCL 0.705 1410 4 Recycle Benzene 0.5 1000 O & P CHLORO PHENOL
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Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
1 PHENOL 0.745 1490 2 CHLORINE 0.558 1116 3 Process Water For HCL 0.61 1220 4 Recycle Phenol 0.25 500 2,4 & 2,6 Dichlorophenol 1 PHENOL 0.588 1176 2 CHLORINE 0.89 1780 3 Process Water For HCL 1.067 2134 4 Recycle Monochloro Phenol 0.25 500 HCL Or CALCIUM CHLORIDE 1 Calcium Carbonate 950 2161 2 Hydrochloric Acid(30‐33 % ) 2080 4732 3 Water 90 205 4 Lime 10 23 M‐NITRO Chlorobenzene 1 NITRO BENZENE 0.865 86.5 2 CHLORINE 0.475 47.5 3 Process Water For HCL 0.52 52 4 Recycle NITRO BENZENE 0.835 83.5 5 Ferric Chloride 0.015 1.5 6 Water For Washing 0.5 50 7 Soda Ash 0.02 2 8 Water 1 100 2,4,6 Trichloro Aniline 1 Aniline 0.47 47 2 Monochlorobenzene 1.88 188 3 Dry Hcl 0.184 18.4 4 Chlorine 1.075 107.5 5 Soda Ash 0.013 1.3 6 NaOH 0.013 1.3 7 Water 2.4 240 8 Thiourea 0.01 1 2,6 Dichloro 4 Nitro Aniline 1 4 Nitro Aniline 0.67 67 2 Monochlorobenzene 8.637 863.7 3 Dry Hcl 0.252 25.2 4 Chlorine 0.69 69 5 Sodiumbicarbonate 0.01 1 6 Water 2.7 270 Valeroyl Chloride 1 Valeric Acid 0.86 64.5 2 Thionyl Chloride 1.025 76.875 3 Ethylenedichloride 2 150 4 Catalyst 0.01 0.75 5 Water For Hcl 0.708 53.1 6 Water For 15% NaOH 3.06 229.5 New Project: Page 12 Manufacturing: Agro Chemicals & Organic Int.
Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
7 48% Naoh Lye 1.39 104.25 Butryl Chloride 1 Butric Acid 0.84 63 2 Thionyl Chloride 1.125 84.375 3 Ethylenedichloride 2 150 4 Catalyst 0.01 0.75 5 Water For Hcl 0.79 59.25 6 Water For 15% NaOH 3.438 257.85 7 48% NaOH Lye 1.562 117.15 3:5 Dichloro Nitrobenzene 1 2,6 Dichloro 4 Nitro Aniline 1.35 202.5 2 NSA 39 % 2.4 360 3 Formaldehyde 37 % 0.676 101.4 4 Water For Decomposition 2.244 336.6 5 Water For Washing 2.287 343.05 6 Soda Ash 0.006 0.9 1,3,5 Trichlorobenzene 1 2,4,6 Trichloro Aniline 1.27 190.5 2 NSA 39 % 2.105 315.75 3 Sulphuric Acid 0.633 94.95 4 Formaldehyde 37 % 1.078 161.7 5 Water For Decomposition 3.745 561.75 6 Water For Washing 1.793 268.95 7 Soda Ash 0.024 3.6 M‐Dichlorobenzene 1 O‐DICHLOROBENZENE 1.01 151.5 2 Aluminim Chloride 0.1 15 3 Process Water 0.97 145.5 4 Soda Ash 0.05 7.5 Ortho & Para NITRO CUMENE 1 CUMENE 0.76 952.38 2 98% SULPHURIC ACID 1.33 1666.67 3 60% NITRIC ACID 0.73 912.70 4 FRESH WATER 0.46 575.40 5 Soda Ash 0.02 19.84 Nitronathalene 1 NAPHTHALENE 0.78 978.26 2 98% SULPHURIC ACID 0.32 396.74 3 98% NITRIC ACID 0.44 554.35 4 FRESH WATER 0.32 401.09 5 CAUSTIC FLAKES 0.02 27.17 6 55% SULPHURIC ACID FOR RECYCLE 0.64 799.46 7 WATER FOR RECYCLE 0.11 142.39 1,5 DNN & 1,8 DNN
1 Nitro Naphthalene 0.79 992.06 New Project: Page 13 Manufacturing: Agro Chemicals & Organic Int.
Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
2 98% SULPHURIC ACID 1.05 1309.52 3 60 % NITRIC ACID 0.66 823.41 4 FRESH WATER 0.40 496.03 5 Recycle Ethylene Dichloride 0.04 49.60 6 Ethylene Dichloride 1.35 1686.51 2,4 DMNB 1 META XYLENE 0.72 896.35 2 98% SULPHURIC ACID 0.23 290.26 3 98% NITRIC ACID 0.45 558.27 4 FRESH WATER 0.33 410.36 5 SODA ASH 0.01 16.68 6 65% SULPHURIC ACID FOR RECYCLE 0.84 1050.93 7 WATER FOR RECYCLE 0.12 145.69 2,6 DMNB 1 META XYLENE 0.72 896.35 2 98% SULPHURIC ACID 0.23 290.26 3 98% NITRIC ACID 0.45 558.27 4 FRESH WATER 0.33 410.36 5 SODA ASH 0.01 16.68 6 65% SULPHURIC ACID FOR RECYCLE 0.84 1050.93 7 WATER FOR RECYCLE 0.12 145.69 2,3 DMNB 1 ORTHO XYLENE 0.72 896.35 2 98% SULPHURIC ACID 0.23 290.26 3 98% NITRIC ACID 0.45 558.27 4 FRESH WATER 0.33 410.36 5 SODA ASH 0.01 16.68 6 65% SULPHURIC ACID FOR RECYCLE 0.84 1050.93 7 WATER FOR RECYCLE 0.12 145.69 3,4 DMNB 1 ORTHO XYLENE 0.72 896.35 2 98% SULPHURIC ACID 0.23 290.26 3 98% NITRIC ACID 0.45 558.27 4 FRESH WATER 0.33 410.36 5 SODA ASH 0.01 16.68 6 65% SULPHURIC ACID FOR RECYCLE 0.84 1050.93 7 WATER FOR RECYCLE 0.12 145.69 2,5 DMNB 1 PARA XYLENE 0.72 896.35 2 98% SULPHURIC ACID 0.23 290.26 3 98% NITRIC ACID 0.45 558.27 4 FRESH WATER 0.33 410.36 5 SODA ASH 0.01 16.68 6 65% SULPHURIC ACID FOR RECYCLE 0.84 1050.93 7 WATER FOR RECYCLE 0.12 145.69 2,5 DCNB New Project: Page 14 Manufacturing: Agro Chemicals & Organic Int.
Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
1 PARA DICHLORO BENZENE 0.80 1000.00 2 98% SULPHURIC ACID 0.58 724.43 3 98% NITRIC ACID 0.35 439.94 4 FRESH WATER 0.43 543.22 5 SODA ASH 0.02 28.41 6 85% SULPHURIC ACID FOR RECYCLE 1.07 1335.23 7 WATER FOR RECYCLE 0.02 24.96 3,4 & 2,3 DCNB 1 ORTHO DICHLORO BENZENE 0.89 1111.11 2 98% SULPHURIC ACID 0.64 804.92 3 98% NITRIC ACID 0.39 488.83 4 FRESH WATER 0.48 603.57 5 SODA ASH 0.03 31.57 6 85% SULPHURIC ACID FOR RECYCLE 1.19 1483.59 7 WATER FOR RECYCLE 0.02 27.74 2,4 & 2,6 DCNB 1 Meta‐ DICHLORO BENZENE 0.87 1086.42 2 98% SULPHURIC ACID 0.63 787.04 3 98% NITRIC ACID 0.38 477.96 4 FRESH WATER 0.47 590.16 5 SODA ASH 0.02 30.86 6 85% SULPHURIC ACID FOR RECYCLE 1.16 1450.62 7 WATER FOR RECYCLE 0.02 27.12 2,4,5 TCNB 1 124 TRICHLORO BENZENE 0.86 1075.00 2 98% SULPHURIC ACID 0.46 578.13 3 98% NITRIC ACID 0.31 390.63 4 FRESH WATER 0.48 594.03 5 CAUSTIC FLAKES 0.03 31.25 6 85% SULPHURIC ACID FOR RECYCLE 1.51 1890.63 7 WATER FOR RECYCLE 0.02 30.97 2,3,4 TCNB 1 123 TRICHLORO BENZENE 0.86 1075.00 2 98% SULPHURIC ACID 0.46 578.13 3 98% NITRIC ACID 0.31 390.63 4 FRESH WATER 0.48 594.03 5 CAUSTIC FLAKES 0.03 31.25 6 85% SULPHURIC ACID FOR RECYCLE 1.51 1890.63 7 WATER FOR RECYCLE 0.02 30.97 4 NITRO 2,6 DICHLORO PHENOL 1 2,6 DICHLORO PHENOL 0.82 1028.75 2 NITRIC ACID 0.30 375.00 3 SULPHURIC ACID 0.47 588.75 4 Solvent EDC 1.00 1250.00 5 Soda Ash 0.05 62.50 6 Water For Washing 0.45 562.50 New Project: Page 15 Manufacturing: Agro Chemicals & Organic Int.
Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
4 NITRO 2,3 DICHLOROPHENOL 1 2,3 DICHLORO PHENOL 0.82 1028.75 2 NITRIC ACID 0.30 375.00 3 SULPHURIC ACID 0.47 588.75 4 Solvent EDC 1.00 1250.00 5 Soda Ash 0.05 62.50 6 Water For Washing 0.45 562.50 4 NITRO 2,5 DICHLOROPHENOL 1 2,5 DICHLORO PHENOL 0.82 1028.75 2 NITRIC ACID 0.30 375.00 3 SULPHURIC ACID 0.47 588.75 4 Solvent EDC 1.00 1250.00 5 Soda Ash 0.05 62.50 6 Water For Washing 0.45 562.50 Ortho‐Chloroaniline 1 METHANOL 2.60 1948.05 2 ORTHO NITRO CHLOROBENZENE 1.30 974.03 3 HYDROGEN 0.05 40.82 4 CATALYST 0.006 1.41 Para‐Chloroaniline 1 METHANOL 2.60 1948.05 2 PARA NITRO CHLOROBENZENE 1.30 974.03 3 HYDROGEN 0.05 40.82 4 CATALYST 0.006 1.41 Ortho‐Cumidine 1 ORTHO NITRO CUMENE 1.25 937.50 2 HYDROGEN 0.05 37.50 3 CATALYST 0.006 2.31 Para‐Cumidine 1 PARA NITRO CUMENE 1.25 937.50 2 HYDROGEN 0.05 34.57 3 CATALYST 0.006 2.31 Alpha‐Naphthyl Amine 1 SOLVENT 2.53 1898.73 2 NITRO NAPHTHALENE 1.27 949.37 3 HYDROGEN 0.05 36.22 4 CATALYST 0.03 23.73 2,4 Xylidie 1 24 DIMETHYL NITROBENZENE 1.35 1013.51 2 HYDROGEN 0.06 44.30 3 CATALYST 0.02 12.06 2,6 Xylidine 1 26 DIMETHYL NITROBENZENE 1.35 1013.51 2 HYDROGEN 0.06 44.30 3 CATALYST 0.02 12.06 2,3 Xylidine
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1 23 DIMETHYL NITROBENZENE 1.35 1013.51 2 HYDROGEN 0.06 44.30 3 CATALYST 0.02 12.06 3,4 Xylidine 1 34 DIMETHYL NITROBENZENE 1.35 1013.51 2 HYDROGEN 0.06 44.30 3 CATALYST 0.02 12.06 2,5 Xylidine 1 25 DIMETHYL NITROBENZENE 1.35 1013.51 2 HYDROGEN 0.06 44.30 3 CATALYST 0.02 12.06 O‐Anisidine 1 ORTHO NITRO ANISOLE 1.28 959.94 2 HYDROGEN 0.06 41.41 3 CATALYST 0.02 11.42 P‐Anisidine 1 PARA NITRO ANISOLE 1.28 959.94 2 HYDROGEN 0.06 41.41 3 CATALYST 0.02 11.42 OTBCHA 1 ACETIC ANHYDRIDE ((CH3CO)2O) 0.54 405.47 2 ORTHO TERTIARY BUTYL PHENOL 0.79 593.75 3 HYDROGEN 0.03 25.00 4 CATALYST 0.00 2.34 5 FRESH WATER 0.10 78.12 PTBCHA 1 ACETIC ANHYDRIDE ((CH3CO)2O) 0.54 405.47 2 PARA TERTIARY BUTYL PHENOL 0.79 593.75 3 HYDROGEN 0.03 25.00 4 CATALYST 0.0031 2.34 5 FRESH WATER 0.10 78.12 PEA 1 ACETIC ACID 0.40 300.34 2 PHENYL ETHYL ALCOHOL 0.76 573.53 3 CATALYST 0.0038 2.87 4 ACETIC ANHYDRIDE 0.11 85.07 CITRONELLOL 1 CITRONELLAL 1.25 937.50 2 HYDROGEN 0.04 28.13 3 CATALYST 0.01 5.63 DIMETHYL OCTANOL 1 CITRAL 1.03 769.24 2 HYDROGEN 0.04 31.47 3 CATALYST 0.01 6.64 CIS‐PINANE 1 ALPHA PINANE 0.99 740.25 New Project: Page 17 Manufacturing: Agro Chemicals & Organic Int.
Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
2 HYDROGEN 0.02 12.00 3 CATALYST 0.0089 2.25 IPPCA 1 ACETONE 1.03 769.23 2 PARA NITRO CHLOROBENZENE 0.96 721.15 3 HYDROGEN 0.05 40.29 4 CATALYST 0.01 8.58 O‐TOLUDINE 1 ORTHO NITRO TOLUENE 1.33 997.34 2 HYDROGEN 0.06 48.05 3 CATALYST 0.02 11.87 P‐TOLUDINE 1 PARA NITRO TOLUENE 1.33 997.34 2 HYDROGEN 0.06 48.05 3 CATALYST 0.02 11.87 M‐TOLUDINE 1 META NITRO TOLUENE 1.33 997.34 2 HYDROGEN 0.06 48.05 3 CATALYST 0.02 11.87 3,5 DABA 1 35 DINITRO BENZOIC ACID 1.43 1071.43 2 HYDROGEN 0.09 66.71 3 CATALYST 0.02 12.75 3,5 DMNIPA 1 DEK 1.37 1027.40 2 3,5 DIMETHYL NITROBENZENE 0.82 616.44 3 HYDROGEN 0.05 35.92 4 CATALYST 0.01 7.34 44DBPPD 1 MEK 1.94 1458.33 2 PARA NITRO ANILENE 0.65 486.11 3 HYDROGEN 0.05 38.75 4 CATALYST 0.01 5.78 3 Amino 9 N Ethyl Carbazole 1 ODCB 0.82 615.38 2 3 NITRO‐9‐(N‐ETHYL)‐CARBZOLE 0.21 153.85 3 HYDROGEN 0.01 4.23 4 CATALYST 0.0024 1.83 3,4 Dimethyl N‐Iso Pentyl Amine 1 DEK 1.37 1027.40 2 PARA NITRO ORTHO XYLENE 0.82 616.44 3 HYDROGEN 0.05 35.92 4 CATALYST 0.01 7.34 4 Amino 2,5 Dichloro Phenol 1 Methanol 2.39 1789.98 2 4 NITRO 2,5 DICHLORO PHENOL 1.19 894.99 New Project: Page 18 Manufacturing: Agro Chemicals & Organic Int.
Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
3 HYDROGEN 0.08 56.80 4 CATALYST 0.01 10.65 4 Amino 2,3 Dichloro Phenol 1 Methanol 2.39 1789.98 2 4 NITRO 2,3 DICHLORO PHENOL 1.19 894.99 3 HYDROGEN 0.08 56.80 4 CATALYST 0.01 10.65 4 Amino 2,6 Dichloro Phenol 1 Methanol 2.39 1789.98 2 4 NITRO 2,6 DICHLORO PHENOL 1.19 894.99 3 HYDROGEN 0.08 56.80 4 CATALYST 0.01 10.65 2 Phenyl Ethyl Alcohol 1 Styrene Oxide 1.09 815.22 2 HYDROGEN 0.06 44.02 3 CATALYST 0.01 6.52 2,5 Dichloro Aniline 1 TOLUENE 0.66 496.66 2 25 DICHLORO NITRO BENZENE 1.28 961.54 3 HYDROGEN 0.04 33.05 4 CATALYST 0.0018 1.39 2,3 Dichloro Aniline 1 TOLUENE 0.65 488.72 2 23 DICHLORO NITRO BENZENE 1.28 961.54 3 HYDROGEN 0.04 33.05 4 CATALYST 0.0018 1.39 3,4 Dichloro Aniline 1 TOLUENE 0.65 488.72 2 3,4 DICHLORO NITRO BENZENE 1.28 961.54 3 HYDROGEN 0.04 33.05 4 CATALYST 0.0018 1.39 2,4 Dichloro Aniline 1 TOLUENE 0.65 488.72 2 2 4 DICHLORO NITRO BENZENE 1.28 961.54 3 HYDROGEN 0.04 33.05 4 CATALYST 0.0018 1.39 2 Chloro Paraphynelediamine 1 TOLUENE 0.67 503.11 2 2 CHLORO 4 NITRO ANILINE 1.30 974.03 3 HYDROGEN 0.05 37.27 4 CATALYST 0.0019 1.41 2,4,5 Trichloro Aniline 1 METHANOL 2.53 1898.73 2 245 TRICHLORO NITRO BENZENE 1.27 949.37 3 HYDROGEN 0.04 27.66 4 CATALYST 0.0018 1.37 New Project: Page 19 Manufacturing: Agro Chemicals & Organic Int.
Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
2,5 Dichloro Paraphenylenediamine 1 TOLUENE 0.65 487.29 2 2,5 Dichloro 4 Nitro Aniline 1.26 943.40 3 HYDROGEN 0.04 30.08 4 CATALYST 0.0018 1.36 3,5 Dichloro Aniline 1 TOLUENE 0.65 488.72 2 3,5 DICHLORO NITRO BENZENE 1.28 961.54 3 HYDROGEN 0.04 33.05 4 CATALYST 0.0019 1.39 3‐Chloroaniline 1 TOLUENE 0.69 516.53 2 3 CHLORO NITRO BENZENE 1.33 1000.00 3 HYDROGEN 0.06 41.90 4 CATALYST 0.0019 1.45 Para Tert Butyl Cyclohexanone 1 PARA TERTIARY BUTYL PHENOL 1.00 750.00 2 HYDROGEN 0.03 22.00 3 CATALYST 0.0015 1.08 Para Tert Butyl Cyclohexanol 1 PARA TERTIARY BUTYL PHENOL 0.99 738.92 2 HYDROGEN 0.04 32.51 3 CATALYST 0.0015 1.07 Ortho Tert Butyl Cyclohexanone 1 ORTHO TERTIARY BUTYL PHENOL 1.00 750.00 2 HYDROGEN 0.03 22.00 3 CATALYST 0.0015 1.08 Ortho Tert Butyl Cyclohexanol 1 ORTHO TERTIARY BUTYL PHENOL 0.99 738.92 2 HYDROGEN 0.04 32.51 3 CATALYST 0.0015 1.07 Meta Phenoxy Benzyl Alcohol 1 METHANOL 2.02 1515.15 2 M‐Phenoxy Benzaldehyde 1.01 757.58 3 HYDROGEN 0.01 10.58 4 CATALYST 0.0015 1.10 2,4 Dimethoxy 5 Chloro Aniline 1 METHANOL 2.60 1948.05 2,4 DIMETHOXY 5 CHLORO NITRO 2 BENZENE 1.30 974.03 3 HYDROGEN 0.05 40.82 4 CATALYST 0.0018 1.41 2,5 Dichlorophenol 1 2:5 Dichloro Aniline 1.22 182.93 2 85% Sulphuric Acid Recycle 2.21 331.03 3 98 % Nitric Acid 0.50 75.28
New Project: Page 20 Manufacturing: Agro Chemicals & Organic Int.
Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
4 Sulphur Dioxide 0.50 75.28 5 Orthodichloro Benzene 1.17 175.89 6 Water 3.28 492.50 7 NaOH 0.30 45.73 2,3 Dichlorophenol 1 2:3 Dichloro Aniline 1.22 182.93 2 85% Sulphuric Acid Recycle 2.21 331.03 3 98 % Nitric Acid 0.50 75.28 4 Sulphur Dioxide 0.50 75.28 5 Orthodichloro Benzene 1.17 175.89 6 Water 3.28 492.50 7 NaOH 0.30 45.73 3,4 Dichlorophenol 1 3:4 Dichloro Aniline 1.22 182.93 2 85% Sulphuric Acid Recycle 2.21 331.03 3 98 % Nitric Acid 0.50 75.28 4 Sulphur Dioxide 0.50 75.28 5 Orthodichloro Benzene 1.17 175.89 6 Water 3.28 492.50 7 NaOH 0.30 45.73 3,5 Dichlorophenol 1 3:4 Dichloro Aniline 1.22 182.93 2 85% Sulphuric Acid Recycle 2.21 331.03 3 98 % Nitric Acid 0.50 75.28 4 Sulphur Dioxide 0.50 75.28 5 Orthodichloro Benzene 1.17 175.89 6 Water 3.28 492.50 7 NaOH 0.30 45.73 3 Chlorophenol 1 3 Chloro Aniline 1.1 165.00 2 98 % Sulphuric Acid 1.4 210.00 3 Nitrosul Sulphuric Acid ( 40% ) 2.745 411.75 4 Solvent Mixed Xylene 2 300.00 5 Water 1.55 232.50 4 Bromo 2,5 Dichlorophenol 1 2,5 Dichloro Phenol 0.702 105.30 2 Bromine 0.69 103.50 3 Ethylene Dichloride 1.2 180.00 4 Water For HBr 0.897 134.55 5 2,3 Dichloroanisol 1 2:3 Dichloro Phenol 1.02 153.00 2 Dimethyl Sulphate 0.41 61.50 3 Sodium Hydroxide 0.26 39.00 4 Monochloro Benzene 1.8 270.00 5 Water 1.666 249.90 New Project: Page 21 Manufacturing: Agro Chemicals & Organic Int.
Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
6 Water For Washing 0.5 75.00 2,5 Dichloroanisol 1 2:5 Dichloro Phenol 1.02 153.00 2 Dimethyl Sulphate 0.41 61.50 3 Sodium Hydroxide 0.26 39.00 4 Monochloro Benzene 1.8 270.00 5 Water 1.67 249.90 6 Water For Washing 0.5 75.00 2’,5’ Dichloroacetophenone 1 P‐DICHLOROBENZENE 0.8 160 2 Aluminim Chloride 1.05 210 3 Ethylene Dichloride 2 400 4 Acetyl Chloride 0.43 86 5 Water For HCL 0.45 90 6 Water Fo Dumping 4.2 840 7 Water For Washing 0.45 90 8 Soda Ash 0.05 10 2’,4’ Dichloroacetophenone 1 M‐DICHLOROBENZENE 0.9 180 2 Aluminim Chloride 1.18 236 3 Ethylene Dichloride 2 400 4 Acetyl Chloride 0.485 97 5 Water For HCL 0.522 104.4 6 Water Fo Dumping 4.72 944 7 Water For Washing 0.45 90 8 Soda Ash 0.05 10 2’,4’ Dichlorovelerophenone 1 M‐DICHLOROBENZENE 0.67 134 2 Aluminim Chloride 0.88 176 3 Ethylene Dichloride 2 400 4 Valeryl Chloride 0.55 110 5 Water For HCL 0.388 77.6 6 Water Fo Dumping 3.52 704 7 Water For Washing 0.45 90 8 Soda Ash 0.05 10 2’,4’ Dichloro 5’ Fluoro Acetophenone 1 2,4 Dichloro Fluoro Benzene 0.84 168 2 Aluminum Chloride 1.092 218.4 3 Ethylene Dichloride 2 400 4 Acetyl Chloride 0.397 79.4 5 Water For HCL 0.431 86.2 6 Water For Dumping 4.368 873.6 7 Water For Washing 0.45 90 8 Soda Ash 0.05 10 2’, 4’ Dichloro Pheny Aceyl Chloride 1 M‐DICHLOROBENZENE 0.68 136 New Project: Page 22 Manufacturing: Agro Chemicals & Organic Int.
Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
2 Aluminum Chloride 0.877 175.4 3 Ethylene Dichloride 2 400 4 Chloroacetyl Chloride 0.505 101 5 Water For HCL 0.382 76.4 6 Water For Dumping 3.508 701.6 7 Water For Washing 0.45 90 8 Soda Ash 0.05 10 2’,4’ Dichlorobuterophenone 1 M‐DICHLOROBENZENE 0.715 143 2 Aluminum Chloride 0.935 187 3 Ethylene Dichloride 2 400 4 Butyl Chloride 0.52 104 5 Water For HCL 0.414 82.8 6 Water For Dumping 3.74 748 7 Water For Washing 0.45 90 8 Soda Ash 0.05 10 Azaconezole 1 M‐Dichlorobenzene 0.515 103 2 Acetyl Chloride 0.275 55 3 Aluminium Chloride 0.565 113 4 Solvent EDC 1.4 280 5 Potassium Hydroxide 0.195 39 6 Solvent Dimethyl Formamide 1.2 240 7 Bromine 0.56 112 8 Ethylene Gylcol 0.217 43.4 9 1,2,4 Triazole 0.24 48 10 Solvent Toluene 1.25 250 11 Water 3.852 770.4 Bromuconazole 1 M‐Dichlorobenzene 0.413 82.6 2 Acetyl Chloride 0.318 63.6 3 Aluminium Chloride 0.516 103.2 4 Solvent EDC 2 400 5 Potassium Hydroxide 0.157 31.4 6 Magnasium Metal 0.067 13.4 7 Solvent Dimethyl Formamide 1.2 240 8 Bromine 0.898 179.6 9 Allyl Bromide 0.339 67.8 10 1,2,4 Traizole 0.194 38.8 11 Solvent Tetrahydro Furan 2.1 420 12 Catalyst 0.018 3.6 13 Potassium Carbonate 0.388 77.6 14 Solvent Toluene 1 200 15 Water 4.245 849 Difenoconazole 1 M‐Dichlorobenzene 0.392 78.4 New Project: Page 23 Manufacturing: Agro Chemicals & Organic Int.
Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
2 Acetyl Chloride 0.208 41.6 3 Aluminium Chloride 0.49 98 4 Solvent EDC 2.4 480 5 Catalyst 0.01 2 6 Bromine 0.422 84.4 7 4 Chloro Phenol 0.34 68 8 Solvent Dimethyl Formamide 1.9 380 9 Potassium Hydroxide 0.288 57.6 10 1,2,4 Traizole 0.18 36 11 Proplyene Glycol 0.198 39.6 12 Water 3.24 648 13 Solvent Toluene 0.9 180 Etaconazole 1 M‐Dichlorobenzene 0.476 95.2 2 Acetyl Chloride 0.254 50.8 3 Aluminium Chloride 0.595 119 4 Solvent EDC 1.8 360 5 Catalyst 0.012 2.4 6 Bromine 0.516 103.2 7 1,2 Butanediol 0.29 58 8 Solvent Toluene 1.3 260 9 Potassium Hydroxide 0.178 35.6 10 1,2,4 Traizole 0.222 44.4 11 Solvent Dimethyl Formamide 1 200 12 Water 4.016 803.2 Hexaconazole 1 M‐Dichlorobenzene 0.51 102 2 Valeroyl Chloride 0.417 83.4 3 Aluminium Chloride 0.632 126.4 4 Solvent EDC 1.85 370 5 Methyl Triohenyl Phosphorane 0.944 188.8 6 Bromine 0.54 108 7 Solvent Tetrahydro Furan 1.2 240 8 Hydrogen Peroxide 0.116 23.2 9 Potassium Hydroxide 0.195 39 10 1,2,4 Traizole 0.22 44 11 Solvent Dimethyl Formamide 1.1 220 12 Water 3.875 775 Propiconazole 1 M‐Dichlorobenzene 0.452 90.4 2 Acetyl Chloride 0.238 47.6 3 Aluminium Chloride 0.558 111.6 4 Solvent EDC 1.6 320 5 Catalyst 0.01 2 6 Bromine 0.553 110.6 7 1,2 Pentanediol 0.32 64 New Project: Page 24 Manufacturing: Agro Chemicals & Organic Int.
Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
8 Solvent Toluene 1 200 9 Potassium Hydroxide 0.166 33.2 10 1,2,4 Traizole 0.21 42 11 Solvent Dimethyl Formamide 1 200 12 Water 3.672 734.4 Penconazole 1 2‐(2,4‐ Dichlorophenyl) Pentyl Alcohol 0.905 181 2 Methyl Sulphonyl Chloride 0.445 89 3 Sodium Hydroxide 0.155 31 4 Solvent Toluene 1.2 240 5 1,2,4 Triazole 0.264 52.8 6 Sodium Methoxide 0.208 41.6 7 Solvent DMF 1.2 240 8 Water 0.858 171.6 Prothioconazole 1 1,2 Dichlorobenzene 0.455 91 2 Chloro Cyclo Propane 0.236 47.2 3 2 Hydroxy Propanyl Chloride 0.295 59 4 Solvent Xylene 2 400 5 Catalyst 0.01 2 6 2,4 Dihydro 1,2,4 Triazole 5 Thione 0.315 63 7 Water 1.5 300 Imazalil 1 2,4 Dichloro Phenacyl Bromide 0.95 190 2 Imadazole 0.24 48 3 Catalyst 0.02 4 4 Allyl Chloride 0.263 52.6 5 Solvent Toluene 3 600 6 Water For Reaction 1.5 300 Tebuconazole 1‐(4‐Chlorophenyl)4‐4 Dimethyl 3‐ 1 Pentanoate 0.675 135 2 Sodium Methoxide 0.162 32.4 3 Dimethyl Sulphide 0.186 37.2 4 Solvent Toluene 1.4 280 5 1,2,4 Triazole 0.206 41.2 6 Water 1.69 338 7 Solvent Dimethyl Formamide 1.1 220 Dithianone 1 Dimethy Formamide ( DMF ) 3.387435 677.49 2 Sodium Cynide ( NaCN) 0.760471 152.09 3 CS2 1.558901 311.78 4 Dichlone 1.537958 307.59 5 Acetic Acid 2.336387 467.28 6 Soda Ash 1.014398 202.88 AMINORESORCINE DIORTHO CRESYL ETHER New Project: Page 25 Manufacturing: Agro Chemicals & Organic Int.
Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
1 2‐Methyl Phenol 0.95 95 2 2,4 Dichloro Nitrobenzene 0.844 84.4 3 Sodium Hydroxide 0.36 36 4 Solvent O‐Dichlorobenzene 1.1 110 5 Iron (Fe) Powder 0.84 84 6 Acetic Acid 0.02 2 7 Soda Ash 0.015 1.5 8 Water 0.8 80 2 AMINO 2’,4,4’ TRICHLORO DIPHENYL ETHER (TADE) 1 2,4 Dichloro Phenol 0.645 64.5 2 2,5 Dichloro Nitrobenzene 0.76 76 3 Sodium Hydroxide 0.162 16.2 4 Solvent O‐Dichlorobenzene 1.2 120 5 Iron (Fe) Powder 0.73 73 6 Acetic Acid 0.02 2 7 Soda Ash 0.015 1.5 8 Water 0.8 80 2 AMINO 4 CHLORO DIPHENYL ETHER 1 Phenol 0.54 54 2 2,5 Dichloro Nitrobenzene 1.103 110.3 3 Sodium Hydroxide 0.237 23.7 4 Solvent O‐Dichlorobenzene 1 100 5 Iron (Fe) Powder 0.888 88.8 6 Acetic Acid 0.02 2 7 Soda Ash 0.015 1.5 8 Water 0.8 80 4 AMINO 2,4’ DICHLORO DIPHENYL ETHER 1 4‐ Chloro Phenol 0.67 67 2 3,4 Dichloro Nitrobenzene 1 100 3 Sodium Hydroxide 0.214 21.4 4 Solvent O‐Dichlorobenzene 1.2 120 5 Iron (Fe) Powder 0.84 84 6 Acetic Acid 0.02 2 7 Soda Ash 0.015 1.5 8 Water 0.8 80 2 AMINO 2’‐4 DICHLORO DIPHENYL ETHER 1 2 Chloro Phenol 0.63 63 2 2,5 Dichloro Nitrobenzene 0.94 94 3 Sodium Hydroxide 0.204 20.4 4 Solvent O‐Dichlorobenzene 1 100 5 Iron (Fe) Powder 0.77 77 6 Acetic Acid 0.02 2 7 Soda Ash 0.015 1.5 2 AMINO 4‐4’ DICHLORO DIPHENYL ETHER 1 4 Chloro Phenol 0.64 64 2 2,5 Dichloro Nitrobenzene 0.956 95.6 New Project: Page 26 Manufacturing: Agro Chemicals & Organic Int.
Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
3 Sodium Hydroxide 0.205 20.5 4 Solvent O‐Dichlorobenzene 1 100 5 Iron (Fe) Powder 0.8 80 6 Acetic Acid 0.02 2 7 Soda Ash 0.015 1.5 8 Water 0.8 80 1,3 BIS (3‐AMINO PHENOXYL) BENZENE 1 3 Nitro Phenol 1.07 107 2 M‐Dichlorobenzene 0.566 56.6 3 Sodium Hydroxide 0.314 31.4 4 Solvent O‐Dichlorobenzene 1.8 180 5 Iron (Fe) Powder 1.18 118 6 Acetic Acid 0.03 3 7 Soda Ash 0.023 2.3 8 Water 1 100 9 Solvent Methanol 2.2 220 5 AMINO 2,2’‐3 TRICHLORO 4‐NITRO DIPHENYL ETHER 1 2,3 Dichloro Phenol 0.51 51 2 6 Nitro 3,4 Dichloro Aniline 0.64 64 3 Sodium Hydroxide 0.13 13 4 Solvent O‐Dichlorobenzene 1.8 180 ORTHOCHLORO PARANITRO ANILINE 1 3:4 Dichloro Nitrobenzene 1.2 90.00 2 Ammonia 0.3 22.50 3 Recovered Ammonia Liq 4.5 337.50 4 Water For Washing 4 300.00 PARACHLORO ORTHONITRO ANILINE 1 2:5 Dichloro Nitrobenzene 1.2 90.00 2 Ammonia 0.3 22.50 3 Recovered Ammonia Liq 4.5 337.50 4 Water For Washing 4 300.00 ORTHO NITRO ANILINE 1 ORTHO NITRO CHLORO BENZENE 1.204819 90.36 2 Ammonia ( Anhydrous) 0.259036 19.43 3 Recovered Ammonia Liq 4.560241 342.02 4 Water For Washing 3.012048 225.90 PARA NITRO ANILINE 1 PARA NITRO CHLORO BENZENE 1.204819 90.36 2 Ammonia ( Anhydrous) 0.259036 19.43 3 Recovered Ammonia Liq 4.560241 342.02 4 Water For Washing 3.012048 225.90 2,3 DICHLORO 6 NITRO ANILINE 1 2,3,4 Trichloro Nitrobenzene 1.15 86.25 2 Ammonia Anhydrous 0.175 13.13 3 Recovered Ammonia Liq 2 150.00 4 Catalyst 0.012 0.90 New Project: Page 27 Manufacturing: Agro Chemicals & Organic Int.
Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
5 Water 4 300.00 6 Orthodichlorobenzene 1 75.00 3,4, DICHLORO 6 NITRO ANILNE 1 2,4,5 Trichloro Nitrobenzene 1.15 86.25 2 Ammonia Anhydrous 0.175 13.13 3 Recovered Ammonia Liq 2 150.00 4 Catalyst 0.012 0.90 5 Water 4 300.00 6 Orthodichlorobenzene 1 75.00 5 CHLORO 2 NITRO ANILINNE 1 2,4, Dichloro Nitrobenzene 1.175 88.13 2 Ammonia Anhydros 0.21 15.75 3 Recovered Ammonia Liquor 1.92 144.00 4 Catalyst 0.012 0.90 5 Water 4 300.00 6 Orthodichlorobenzene 1 75.00 CUMAC 1 Potassium Hydroxide Solution 0.85 42.71 2 Water 0.96 47.92 3 Salicylic Acid 1.00 50.00 4 MTBE Solution 4.08 204.17 5 80 % Monochloro Acetic Acid Solution 1.56 77.92 6 30 % Hydrochloric Acid Solution 0.38 18.75 7 MTBE 3.38 168.75 8 Acetic Acid 1.00 50.00 9 Acetic Anhydride 2.71 135.42 10 Catalyst 0.03 1.25 NITRO RF 1 ACETONE 2.69 134.73 2 PNP 1.16 58.14 3 NaOH 0.67 33.72 4 PSCl3 0.80 39.84 5 DM Water 7.55 377.91 DIETHYL DIPROPYL MALONATE 1 DIETHYL MALONATE 0.67 33.33 2 SODIUM HYDROXIDE 0.34 17.00 3 N‐PROPYL BROMIDE 1.03 51.67 4 WATER 1.16 58.00 MALONIC ACID 1 DIETHYL DIPROPYL MALONATE 1.43 71.43 2 SODIUM HYDROXIDE 0.47 23.57 3 DM WATER 2.86 142.86 4 HCl 1.43 71.43 PARACHLORO ANILINE HYDROCHLORIDE 1 Parachloro Aniline 0.76 37.78 2 30 % Hcl 0.72 36.15 New Project: Page 28 Manufacturing: Agro Chemicals & Organic Int.
Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
4 NITRO PHTHALO NITRILE 0.00 1 4‐NITRO PHTHALIMIDE 1.34 67.24 2 Ammonia Liquor 0.91 45.26 3 Water For Ammonia 2.72 135.78 4 Water 2.36 118.10 5 DMF ( 1270 Recycle + 30 Fresh) 2.24 112.07 6 Methanol Recycle 1.83 91.38 7 Methanol Fresh 0.03 1.72 8 Pocl3 1.92 96.12 9 Soda Ash 3.41 170.69 10 Water 13.66 682.76 FHIA 1 TOLUENE 5.31 265.58 2 1‐Fluoro 4 Nitrobenzene 0.91 45.29 3 Acetone 1.25 62.46 4 CATALYST 0.01 0.72 5 Phosphoric Acid 0.01 0.43 6 Hydrogen Gas 0.06 3.19 7 Water 4.06 202.90 8 Triethyl Amine 0.79 39.35 9 Chloro Acetyl Chloride 0.75 37.46 10 Sodium Acetate 0.55 27.46 11 Methanol 2.50 124.93 12 Sodium Hydroxide 0.01 0.43 MSTT 1 Toluene 6.00 300.00 2 Hydrazine Hydrate 0.83 41.40 3 Carbon Disufide 1.00 50.00 4 Sodium Hydroxide 2.06 102.85 5 Dimethyl Sulfate 1.82 90.70 6 2,2,2 Trifluoro Acetic Acid 1.09 54.25 7 Phosphoryl Chloride 2.20 110.00 8 Formic Acid 1.71 85.74 9 Tugensten Dehydrate 0.02 0.85 10 Hydrogen Peroxide 1.27 63.55 11 Sodium By Sulfite 0.37 18.55 12 Water recycle 5.42 271.40 THISA 1 30 % Hcl 6.45 322.37 2 Sodium Nitrite (40%) 1.61 80.26 3 Water 1.05 52.63 4 Chlorobenzene 13.37 668.42 5 Acetone 7.21 360.53 6 Sulphur Dioxide 0.92 46.05 7 Ammonia ( 25 % Solution) 1.53 76.32 New Project: Page 29 Manufacturing: Agro Chemicals & Organic Int.
Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
8 Acetonitrie 6.31 315.79 9 Thiophanone 1.36 68.42 10 Hydroxylamine hydrochloride 0.55 27.63 TBSA 1 TFMA 0.8 40.00 2 30 % Hcl 1.66 83.00 3 Sodium Nitrite (40%) 0.9 45.00 4 Water 6.82 341.00 5 Sulphur Dioxide 0.35 17.50 6 Ammonia ( 25 % Solution) 0.8 40.00 NDPA 1 Soda Ash 0.3125 15.63 2 O‐Nitrochlorobenzene 0.78125 39.06 3 P‐Chloroaniline 0.625 31.25 4 Toluene 2.25 112.50 5 Water 0.90625 45.31 BINOL 1 BETA NAPHTHOL 1.190 59.52 2 XYLENE 4.167 208.33 3 Ferric Chloride Heptahydrate 4.524 226.19 4 DM WATER 7.61 380.95 5 Methanol 9.524 476.19 6 Activated Carbon 0.207 10.36 7 High Flow 0.24 11.90 OXYQUINOLINE COPPER 1 8 Hydroxy Quinoline 0.87 43.94 2 NaOH 0.242 12.12 3 DM water 3.03 151.52 4 Copper sulphate 0.754 37.73 2H‐HEXAFLUORO PROPOXY PROPYLENE‐2,5‐DICHLORO 4 AMINO BENZENE 1 2, 5 Dichloro Phenol 0.57 28.57 2 Acetonitrile 2.86 142.86 3 KOH ( Potassium Hydroxide) 0.11 5.71 4 Hexafluoro Propylene Gas 0.61 30.71 5 98% H2SO4 2.31 115.71 6 60 % HNO3 0.36 17.86 7 Toluene 3.14 157.14 8 Soda Ash 0.00 0.14 9 Catalyst 0.01 0.43 10 Hydrogen Gas 0.03 1.29 2,4 DIMETHOXY 5 CHLORO NITROBENZENE 1 2:4:5 Trichloro Nitro Benzene 1.09 54.50 2 Sodium Methoxide 0.521 26.05 3 Methanol 3 150.00 4 Catalyst 0.015 0.75 5 Water For Washing 1 50.00 New Project: Page 30 Manufacturing: Agro Chemicals & Organic Int.
Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
2,5 Dichloro 4 Nitroaniline 1 2,5 Dichloro Aniline 0.868 43.40 2 Acetic Anhydride 0.55 27.50 3 Nitric Acid 0.345 17.25 4 Sulphuric Acid 0.524 26.20 5 Recycl Acetic Acid 1 50.00 6 Solvent EDC 1 50.00 7 Water 1 50.00 8 Sodium Hydroxide 0.22 11.00 4 CHLORO 2 AMINO DIPHENYLAMINE (ADPA) 1 DMF 4 200.00 2 4 CHLORO 2 NITRO DIPHENYLAMINE 1.333333 66.67 3 HYDROGEN 0.035412 1.77 4 CATALYST 0.015867 0.79 AMINO RF 1 METHANOL 11.47776 573.89 THIOPHOSPHORIC TRI (4 NITROPHENYL) 2 ESTER (NITRO RF)(90%) 1.520803 76.04 3 HYDROGEN 0.056815 2.84 4 CATALYST 0.229555 11.48 5 WATER WASH 6.886657 344.33 4 AMINO BENZONITRILE 1 WATER 20 1000.00 2 4 NITRO BENZONITRILE 1.666667 83.33 3 HYDROGEN 0.074324 3.72 4 CATALYST 0.0125 0.63 1,5 DIAMINO NAPHTHALENE 1 XYLENE 3.225806 161.29 2 15 DINITRO NAPHTHALENE 1.612903 80.65 3 HYDROGEN 0.097662 4.88 4 CATALYST 0.019194 0.96 1,8 DIAMINO NAPHTHALENE 1 XYLENE 3.225806 161.29 2 18 DINITRO NAPHTHALENE 1.612903 80.65 3 HYDROGEN 0.097662 4.88 4 CATALYST 0.019194 0.96 4 CHLORO 2 AMINO PHENOL 1 2,5 Dichloro Nitrobenzene 1.634 81.70 2 Caustic Lye 1.83 91.50 3 Ammonia 0.032 1.60 4 D.M.Water 4.362 218.10 5 Catalyst 0.002 0.10 6 Hydrogen 0.05 2.50 7 Sulphuric Acid 0.65 32.50 8 D.M.Water 3.562 178.10 9 Sodium Dithionate 0.012 0.60
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Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
10 Hydrazine Hydrate 0.008 0.40 11 Charcoal 0.114 5.70 12 D.M.Water 0.787 39.35 2 CHLORO 4 AMINO PHENOL 1 3,4 Dichloro Nitrobenzene 1.634 81.70 2 Caustic Lye 1.83 91.50 3 Ammonia 0.032 1.60 4 D.M.Water 4.362 218.10 5 Catalyst 0.002 0.10 6 Hydrogen 0.05 2.50 7 Sulphuric Acid 0.65 32.50 8 D.M.Water 3.562 178.10 9 Sodium Dithionate 0.012 0.60 10 Hydrazine Hydrate 0.008 0.40 11 Charcoal 0.114 5.70 12 D.M.Water 0.787 39.35 2,4 DIHYDROXYBENZOPHENONE 1 Methanol 8.108108 405.41 2 Resorcinol 0.594595 29.73 3 Benzotrichloride 1.081081 54.05 4 Catalyst 0.054054 2.70 5 Water 8.108108 405.41 3 Hydroxy Acetophenone 1 3 AMINO ACETOPHENONE 1.219512 60.98 2 98% HNO3 0.592334 29.62 3 85% H2SO4 1.627968 81.40 4 SO2 0.601496 30.07 5 WATER 4.065041 203.25 6 ODCB 1.219512 60.98 7 LIME 0.954962 47.75 2,4 Dichlorophenoxy Acetic Acid 1 2,4 Dichloro Phenol 0.818182 61.36 2 Monochloro Acetic Acid 0.472727 35.45 3 48 % Naoh Lye 0.890909 66.82 4 Water For 20 % Naooh 1.245455 83.51 5 Hydrochloric Acid 0.727273 54.55 ACLONIFEN 1 2 Amino 3,4 Dichloro Nitro Benzene 0.756 56.70 2 Phenol 0.35 26.25 3 Sodium Hydroxide 0.15 11.25 4 Solvent DMSO 1.2 90.00 5 Water 0.64 48.00 6 Solvent Xylene 1 75.0 FLURIDONE TMPA(3‐Trifluoro methyl phenyl 1 acetonitrile) 0.858 64.35
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2 25% Sodium methoxide 0.603 45.23 3 Ethyl phenyl acetate 0.835 62.63 4 98% Sulphuric acid 1.28 96.00 5 Water 2.248 168.60 6 Acetic acid 0.875 65.63 7 Toluene 7.771 578.33 8 Sodium bicarbonate 2.207 165.63 9 Dimethyl formamide dimethyl actetal 0.891 66.83 10 Methyl amine 0.314 23.55 FLUFENACET 1 FHIA 0.69 51.75 2 DICHLORO METHANE 1.078 80.85 3 DIMETHYL CARBONATE 0.014 1.05 4 MSTT 0.754 56.55 5 SODIUM HYDROXIDE 0.603 45.23 6 Hcl 0.108 8.10 7 ETHANOL 1.078 80.85 8 WATER 0.647 48.53 QUINOCLAMINE 1 Dichloronaphthaquinone 1.538462 115.38 2 Methanol 5.769231 432.69 3 Methanol For Washing 2.307692 173.08 4 Liquor Ammonia (23 %) 1 75.00 5 DM Water 1.923077 144.23 FENVALERATE 1 Sodium Cyanide 0.116 8.70 2 PTC 0.016 1.20 3 Water 3.863 289.73 4 Hexane 5.789 234.18 5 M‐Phenoxy Benzaldehyde 0.495 37.13 6 CM Acid Chloride 0.6 45.00 7 8 % Soda Ash Solution 1.053 78.98 ALPHAMETHRINE 1 Sodium Cyanide 0.231 17.33 2 PTC 0.057 4.28 3 Water 3.011 225.83 4 Hexane 7.737 580.28 5 M‐Phenoxy Benzaldehyde 0.524 39.30 6 CM Acid Chloride 0.905 67.88 7 5 % Soda Ash Solution 0.958 71.85 8 Sodium Hypochloride 0.883 66.23 DELTAMETHRINE 1 Sodium Cyanide 0.126 9.45 2 PTC 0.016 1.20 3 Water 3.011 225.83 4 Hexane 5.789 434.18 New Project: Page 33 Manufacturing: Agro Chemicals & Organic Int.
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5 M‐Phenoxy Benzaldehyde 0.505 37.88 6 CM Acid Bromide ( DELTA) 0.611 45.83 7 12 % Soda Ash Solution 1.032 77.40 8 Sodium Hypochloride 0.553 41.48 PERMETHRINE 1 Sodium Cyanide 0.137 10.28 2 PTC 0.016 1.20 3 Water 3.011 225.83 4 Hexane 2.672 200.40 5 M‐Phenoxy Benzaldehyde 0.524 39.30 6 CM Acid Chloride 0.612 45.90 7 5 % Soda Ash Solution 0.958 71.85 8 Sodium Hypochloride 0.853 63.98 LAMDACYHALOTHRIN 1 Sodium Cyanide 0.126 9.45 2 PTC 0.016 1.20 3 Water 3.011 225.83 4 Hexane 5.789 434.18 5 M‐Phenoxy Benzaldehyde 0.505 37.88 6 Floro CM Acid Chloride 0.611 45.83 7 12 % Soda Ash Solution 1.032 77.40 8 Sodium Hypochloride 0.553 41.48 CYPERMETHRIN 1 Sodium Cyanide 0.142 10.65 2 PTC 0.016 1.20 3 Water 3.011 225.83 4 Hexane 3.158 236.85 5 M‐Phenoxy Benzaldehyde 0.484 36.30 6 CM Acid chloride 0.587 44.03 7 10 % Soda Ash Solution 1.053 78.98 8 Sodium Hypochloride 0.832 62.40 DEET Sodium Hypochl 1 M‐TOLUIC ACID 0.75 56.25 2 Thionyl Chloride 0.66 49.50 3 Ethylenedichloride ( 50 Kg Fresh) 2 150.00 4 Catalyst 0.01 0.75 5 Water For Hcl 0.47 35.25 6 Water For 15% Naoh 2.015 151.13 7 48% Naoh Lye 0.918 68.85 8 Toluene (50 Kg Fresh) 2 150.00 9 Dietyl Amine 0.402 30.15 SODIUM NAPHTHIONATE 1 ALPHA NAPHTHYLAMINE 0.663043 46.41 2 98% SULPHURIC ACID 0.608696 42.61 3 ORTHO DICHLORO BENZENE 2.478261 173.48 4 SODA ASH 0.317391 22.22 New Project: Page 34 Manufacturing: Agro Chemicals & Organic Int.
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5 WATER 3.326087 232.83 META TOLUIC ACID 1 M‐XYLENE 2.222222 222.22 2 CATALYST 0.088889 8.89 3 Air 1.481481 148.15 M‐Phenoxybenzaldehyde 1 Benzaldehyde 0.75 37.5 2 Ethylene Dichloride 2.2 110.00 3 Catalyst Alcl3 1.23 61.5 4 Bromine 0.55 27.5 5 Chlorine 0.26 13.0 6 Hcl Solution (30%) 0.02 1.0 7 Warer 7.53 376.5 8 Mono Ehylene Gylcol (MEG ) 0.57 28.5 9 Catalyst Copper 0.02 1.00 10 Toluene 2.09 104.5 11 Phenol 0.56 28.00 12 KOH 0.34 17.00 13 H2SO4 0.79 39.5 14 Caustic Lye 0.025 1.25 BROMINE 1 KBR solution 7.24 202.83 2 Chlorine 0.86 24.34 3 Steam 4.99 139.94
Water and Waste Water Management
• Total water requirement will be 1258 m3/day which is met through GIDC water supply, out of which 91 m3/day of RO permeate will be recycled hence total 1167 m3/day of fresh water will required.
• Total Industrial wastewater generation will be 272 m3/day. Out of which about 170 m3/day of effluent generated from the process will be collected separately, neutralized, extracted in solvent to remove organics, stripped in solvent stripper filtered & finally taken to MEE. Balance 102 m3/day of normal effluent from cooling tower, boiler blow down, scrubber & floor/container washing will be treated in Reverse Osmosis plant. 11 m3/day of RO rejection will be taken to MEE and 91 m3/day of permeate will be recycled. Total 151 m3/day of condensate from MEE will be treated in primary, secondary & tertiary treatment plant & discharge into under ground effluent drainage line of GIDC for ultimate disposal into Arabian Sea.
• Domestic Waste water (10 m3/day) will be disposed by septic tank & soak pit.
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Air Emission and its Control Measures
Flue gas emission:
Ö There will be flue gas emission from 20 TPH x 2 capacities of coal fired steam boiler and coal fired 20 lacs kcal/hr capacity of Thermic fluid heater in the form of PM, SOx & NOx. Adequate capacity of separate electro static precipitator along with separate 55 meters height of chimney will be provided to the boilers & thermopak. Ö Also the unit will install 2500 KVA capacity of D G set, as standby. It will be used only during power failure. 250 kgs/hr of HSD will be used as a fuel & 11 meters height of chimney will be provided.
Process gas emission: Ö Two stage alkali scrubbers will be provided to scrub Sulphur dioxide, nitrogen oxide, bromine and ammonia gases generated from the process. 11 meters height of vent will be provided. Ö Three stage water followed by alkali scrubber provided for the recovery of hydro chloric acid (30%). 11 meters height of vent will be provided. (Details of Air pollution control measures are attached as Annexure‐11).
Hazardous Wastes and its Management
No Type of waste Category Qty. MT/ Treatment Disposal month
1 ETP waste (34.3) 34.3 27 Dried, packed Dispose off in bags into TSDF, BEIL, Ankleshwar & SEPPL, Dahej & Kutch 2 ETP waste & salt 34.3 598 Dried, packed Dispose off from MEE (34.3) in bags into TSDF, BEIL, Ankleshwar & SEPPL, Dahej & Kutch 3 Used Oil (5.1) 5.1 0.2 Packed in sell to carboys registered recycler 4 Discarded containers 33.3 2.0 De‐ Sell to (33.3) contaminate authorized d, stored recycler 5 Process waste 29.1 845 Packed in Dispose off (Inorganic) bags into TSDF, BEIL, Ankleshwar & SEPPL, Dahej & Kutch 6 Distillation residue 29.1 609 Packed in Sent for co‐ drums processing or
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sent to SEPPL, Dahej & Kutch for incineration 7 Spent carbon 35.3 0.8 Packed in Sent for co‐ drums/bags processing or sent to SEPPL, Dahej & Kutch for incineration 8 Spent Catalyst 35.2 1.0 Packed in Sent for co‐ drum processing or TSDF BEIL, Ankleshwar & SEPPL, Dahej & Kutch 9 Used rubber hand X‐08 0.2 Packed in Sent for gloves/pipes etc drums/bags incineration to SEPPL, Dahej & Kutch 11 Iron sludge 26.1 231 Packed in Sent for co‐ drums/bags processing or TSDF BEIL, Ankleshwar & SEPPL, Dahej & Kutch 12 Date expired/off 29.3 1.0 Packed in Sent for specification drums/bags incineration pesticide 13 Fly ash ‐310 Packed in Sell to brick covered truck manufacturer
2. Introduction of Project / Back Ground Information : (i) Identification of Project and proponent. Name of the project Proponent: Yashashvi Rasayan Pvt. Limited
Yashashvi Rasayan Pvt. Limited is a Large scale proposed unit to be located at Plot. No. Z/111/B, SEZ: II, Dahej industrial estate, Ta: Vagra, di: Bharuch, Gujarat having total plot area 53449 m2 & total investment for the proposed project will be Rs. 64.25 Crore. The proposed Agrochemicals products & organic intermediates are especially used as Herbicide as per requirement.
The unit is managed by technocrats Mr. Nilesh Patel having 33 years of experience in manufacturing and marketing of various chemicals worldwide. Team members Mr. Harshad Mavani having 38 years of experience of chemical industries.
The company has prepared lay out & design well equips production plant which will be managed by dedicated, qualified & skilled persons.
The proponent proposes to set up a plant of Agro Chemicals & Organic intermediates with total capacity of 8202 MT per month.
The proposed project site lies on 21041’14.11” N Latitude & 72032’57.06”E Longitude. Yashashvi Rasayan Pvt. Limited is to be located at plot. No. Z/111/B, SEZ: II, Dahej New Project: Page 37 Manufacturing: Agro Chemicals & Organic Int.
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industrial estate, Ta: Vagra, di: Bharuch in Gujarat state.
No forests, national park, wild life sanctuary, etc. are envisaged in 15 Km from the nearest boundary of the project site.
Basic facilities of infrastructure like storage area, processing area, internal roads etc. shall be developed on the project site. Transportation of raw material and finished goods will be carried out through proposed internal roads and finally through existing state highway SH‐6. During the construction phase around 100 workers and during the operational phase around 100 workers including contractors will be required. Local skilled and semi‐skilled workers will be engaged during construction phase. The positives impact include enhanced direct employment for technical/administrative works and indirect employment opportunities for transporters of raw materials and finished goods.
Since the project will cater to industries in the region by providing a suitable source for import, export and coastal movement of pesticides, it will encourage industrial growth in the region and result in additional revenue for government.
Beside the rail connectivity, and also well connected by road transport. There is a good network of roads in the area and contributes for the development and economic growth of the area. The National Highway No. 8 (Ahemdabad – Mumbai) is now six lanes, double tracked, more elevated and Jam free highway, which is developed by M/s L & T Company. This highway has given a further boost to the economic growth of this area.
Yashashvi Rasayan Pvt. Limited is established in 2003 and managed by a professional board of directors. It manufactures and markets a wide range of Organic intermediates. Senior personnel are available for providing support to the manufacturing unit in the areas of technology, R&D, manufacturing, quality control and quality assurance. Organic intermediates manufactured at this location are for sale in local & international market. It was co‐founded by 2 technocrats.
(ii) Brief description of nature of the Project : Yashashvi Rasayan Pvt. Limited Proposes to set up a plant for the manufacturing of Agro chemicals at plot. No. Z/111/B, SEZ: II, Dahej industrial estate, Ta: Vagra, di: Bharuch in Gujarat state.
The proposed project involves the production of “Agro Chemicals & organic intermediates” which are especially used in herbicide manufacture etc. as per requirement. As per the EIA notification‐ 2006 as amended products are covered under any category 5(f) requires Prior Environmental Clearance. For the proposed project, the company intends to procure the available latest technology for manufacturing the products. This project will manufacture various Agro Chemicals products & organic intermediates.
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A typical plant consists of chlorinators, hydrogenator, distillation, reactors, agitated nutsche filter, fractionating columns, rotary vacuum paddle dryer, Distillation columns, HDPE absorbers for NOx, condensers, PTFE and stainless steel pumps, high vacuum steam ejectors and SS water ring vacuum pumps etc.
The industrial sector in the past 5 to 7 years has seen a drastic boom and also the keeping in mind the globalization trend, we have identified the demand for the product and with continuous R & D found that it can be developed in‐house and produce commercially for domestic market as well as an eye more on export markets.
(iii) Need for the project and its importance to the country and or region :
The proposed project provides a potential growth opportunity for the already running business of the company. The company is already engaged in the business of manufacturing of “Organic intermediates”. The project would increase the overall export and also increase the foreign revenue.
India produces about 80,000‐90,000 MT of pesticides a year. India’s Agro chemicals & pesticide industries are the largest in Asia and the twelfth largest in the world. With over 400 million acres under cultivation and over 60% of the country’s population dependent on agriculture, the country’s economy depends on the agricultural sector to a substantial extent. India loses nearly 30% of its potential crop to insects, weeds and rodent attacks. The Pesticides/Crop Protection/Agrochemicals industry plays a crucial role in protecting crops from damage by weeds, pests, insects and fungus, both before and after harvest. This helps to increase crop yields, which is important given the rate at which cultivable land is shrinking.
(iv) Demand –Supply Gap : The production of pesticides started in India in 1952 with the establishment of a plant for the production of BHC near Calcutta, and India is now the second largest manufacturer of pesticides in Asia after China. There has been a steady growth in the production of technical grade pesticides in India, from 5,000 metric tons in 1958 to 102,240 metric tons in 1998. In 1996–97 the demand for pesticides in terms of value was estimated to be around Rs. 22 billion (USD 0.5 billion), which is about 2% of the total world market. The products have very high specific demand as they are especially used as herbicide etc. as per requirement.
(v) Imports vs. Indigenous production : Proposed products manufacturing in the country will be very much economical compare to Imports of the same and also the export of the same will earn extra revenue generation for our county.
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(vi) Export Possibility : Proposed products have high export potential. Also there products have very good potential in local market. (vii) Domestic / export Markets : The company’s product is used as raw material to manufacture various herbicide and organic intermediates as per the required applications and having very good market in domestic and also having very good international markets. (viii) Employment Generation (Direct and Indirect) due to the project : During the construction phase around 100 workers and during the operational phase around 100 workers including contractors will be required. Local skilled and semi‐skilled workers will be engaged during construction phase. The positives impact includes enhanced direct employment for technical/administrative works and indirect employment opportunities for transporters of raw materials and finished goods. 3. Project Description : (i) Type of Project including interlinked and interdependent projects, If any : The proposed project is an interdependent project of the company. (ii) Location (map showing general location, Specific location, and project boundary & project site layout) with coordinates : The map showing general location, specific location and project boundary and project site lay out is enclosed as Annexure‐1.Plant layout is attached as Annexure‐2. (iii) Details of alternate sites considered and the basis of selecting the proposed site, particularly the environmental considerations gone into should be highlighted : The proposed activity will be accommodated in the notified industrial area having proper industrial infrastructure so; there is no alternate site consideration. (Land allotment letter is attached as Annexure‐9).
(iv) Size or magnitude of operation : As per the proposed project cost the project is covered under Large Scale category of manufacturing industries. (v) Project description with process details (a schematic diagram/ flow chart showing the project layout components of the project etc. should be given) : Detailed project description with process details is enclosed as Annexure‐3 (vi) Raw material required along with estimated quantity, likely source, marketing area of final products/s, mode of transport of raw Material and finished product : Detailed raw material requirement along with estimated quantity, likely source, marketing are of final products mode of transport of raw material and finish product & characteristics of hazardous chemicals are as below:
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DETAILS ON PRODUCT/BY‐PRODUCTS TRANSPORTATION
Sr. Product Physical Dispatch Means of No. State Transportation 1 Ortho DICHLOROBENZENE Liquid Local/Export Road/By sea
Para‐ DICHLOROBENZENE Solid Local/Export Road/By sea
2 1:2:4 TRICHLOROBENZENE Liquid Local/Export Road/By sea
1:2:3 TRICHLOROBENZENE Solid Local/Export Road/By sea
3 MONOCHLOROBENZENE Liquid Local/Export Road/By sea
4 o‐ CHLORO PHENOL Solid Local/Export Road/By sea
p‐CHLORO PHENOL Solid Local/Export Road/By sea
5 2,4 DICHLORO PHENOL Solid Local/Export Road/By sea
2,6 DICHLORO PHENOL Solid Local/Export Road/By sea
6 Hydro chloric acid Liquid Local/Export Road/By sea (30%)/Calcium Chloride
7 3 CHLORO NITROBENZENE Liquid Local/Export Road/By sea
8 2,4,6 TRICHLORO ANILINE Solid Local/Export Road/By sea
9 2,6 DICHLORO 4 NITRO Solid Local/Export Road/By sea ANILINE
10 N‐ Valeroyl Chloride Liquid Local/Export Road/By sea
11 Butyryl Chloride Liquid Local/Export Road/By sea
12 3:5 DICHLORO NITRO Solid Local/Export Road/By sea BENZENE
13 1:3:5 TRICHLOROBENZENE Solid Local/Export Road/By sea
14 meta‐DICHLOROBENZENE Liquid Local/Export Road/By sea
15 ORTHO & PARA NITRO Liquid Local/Export Road/By sea CUMENE
16 NITRO NAPHTHALENE Solid Local/Export Road/By sea
17 1:5 & 1:8 DINITRO Solid Local/Export Road/By sea NAPHTHALENE
18 2,4 DIMETHYL NITRO Liquid Local/Export Road/By sea BENZENE ( 2,4 DMNB)
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BENZENE (2,6 DMNB)
20 2,3 DIMETHYL NITRO Liquid Local/Export Road/By sea BENZENE (2,3 DMNB)
21 3,4 DIMETHYL NITRO Liquid Local/Export Road/By sea BENZENE (3,4 DMNB)
22 2,5 DIMETHYL NITRO Liquid Local/Export Road/By sea BENZENE (2,5 DMNB)
23 2,5 DICHLORO NITRO Solid Local/Export Road/By sea BENZENE (25 DCNB)
24 3,4 & 2,3 DICHLORO NITRO Solid Local/Export Road/By sea BENZENE ( 3,4 & 2,3 DCNB )
25 2,4 & 2,6 DICHLORO NITRO Solid Local/Export Road/By sea BENZENE
26 2,4,5 TRICHLORO NITRO Solid Local/Export Road/By sea BENZENE
27 2,3,4 TRICHLORO NITRO Solid Local/Export Road/By sea BENZENE
28 2,6 DICHLORO 4 NITRO Solid Local/Export Road/By sea PHENOL
29 2,3 DICHLORO 4 NITRO Solid Local/Export Road/By sea PHENOL
30 2,5 DICHLORO 4 NITRO Solid Local/Export Road/By sea PHENOL
31 ORTHO CHLORO ANILINE Liquid Local/Export Road/By sea
32 PARA CHLORO ANILINE
33 ORTHO CUMIDINE Liquid Local/Export Road/By sea
34 PARA CUMIDINE Liquid Local/Export Road/By sea
35 ALPHA NAPHTHYL AMINE Solid Local/Export Road/By sea
36 2,4 XYLIDINE Liquid Local/Export Road/By sea
37 2,6 XYLIDINE Liquid Local/Export Road/By sea
38 2,3 XYLIDINE Liquid Local/Export Road/By sea
39 3,4 XYLIDINE Liquid Local/Export Road/By sea
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40 2,5 XYLIDINE Liquid Local/Export Road/By sea
41 ORTHO ANISIDINE Liquid Local/Export Road/By sea
42 PARA ANISIDINE Liquid Local/Export Road/By sea
43 OTBCHA Liquid Local/Export Road/By sea
44 PTBCHA Liquid Local/Export Road/By sea
45 PHENYL ETHYL ACETATE Liquid Local/Export Road/By sea
46 CITRONELLOL Liquid Local/Export Road/By sea
47 DIMETHYL OCTANOL Liquid Local/Export Road/By sea
48 CISPINANE Liquid Local/Export Road/By sea
49 IPPCA Liquid Local/Export Road/By sea
50 ORTHO TOLUDINE Liquid Local/Export Road/By sea
51 PARA TOLUDINE Liquid Local/Export Road/By sea
52 META TOLUDINE Liquid Local/Export Road/By sea
53 3,5 DIAMINO BENZOIC ACID Solid Local/Export Road/By sea
54 3,5 DIMETHYL N ISO PENTYL Liquid Local/Export Road/By sea AMINE
55 4:4 DISEC BUTYL PARA Solid Local/Export Road/By sea PHENYLINE DIAMINE
56 3 AMINO 9 (N ETHYL) Solid Local/Export Road/By sea CARBAZOLE
57 3,4 DIMETHYL N‐ISO PENTYL Liquid Local/Export Road/By sea AMINE
58 4 AMINO 2,5 DICHLORO Solid Local/Export Road/By sea PHENOL
59 4 AMINO 2,3 DICHLORO Solid Local/Export Road/By sea PHENOL
60 4 AMINO 2,6 DICHLORO Solid Local/Export Road/By sea PHENOL
61 PHENYL EHYL ALCOHOL ( 2‐ Liquid Local/Export Road/By sea PEA )
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62 2,5 DICHLORO ANILINE Solid Local/Export Road/By sea
63 2,3 DICHLORO ANILINE Solid Local/Export Road/By sea
64 3,4 DICHLORO ANILINE Solid Local/Export Road/By sea
65 2,4 DICHLORO ANILINE Solid Local/Export Road/By sea
66 2 CHLORO 1,4 DIAMINO Solid Local/Export Road/By sea BENZENE
67 2,4,5 TRICHLORO ANILINE Solid Local/Export Road/By sea
68 2,5 DICHLORO 1,4 Solid Local/Export Road/By sea DIAMINOBENZENE
69 3,5 DICHLORO ANILINE Solid Local/Export Road/By sea
70 3 CHLORO ANILINE Liquid Local/Export Road/By sea
71 p‐TERTIARY BUTYL Liquid Local/Export Road/By sea CYLCOHEXANONE
72 p‐TERTIARY BUTYL Liquid Local/Export Road/By sea CYLCOHEXANOLE
73 O‐TERTIARY BUTYL Liquid Local/Export Road/By sea CYLCOHEXANONE
74 O‐TERTIARY BUTYL Liquid Local/Export Road/By sea CYLCOHEXANOLE
75 MPBALCOHOL Liquid Local/Export Road/By sea
76 2,4 DIMETHOXY 5 CHLORO Solid Local/Export Road/By sea ANILINE
77 2,5 DICHLORO PHENOL Solid Local/Export Road/By sea
78 2,3 DICHLORO PHENOL Solid Local/Export Road/By sea
79 3,4 DICHLORO PHENOL Solid Local/Export Road/By sea
80 3,5 DICHLORO PHENOL Solid Local/Export Road/By sea
81 3 CHLORO PHENOL Solid Local/Export Road/By sea
82 2,5 DICHLORO 4 BROMO Solid Local/Export Road/By sea PHENOL
83 2,3 DICHLORO ANISOL Solid Local/Export Road/By sea
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84 2,5 DICHLORO ANISOL Solid Local/Export Road/By sea
85 2':5' DICHLORO Solid Local/Export Road/By sea ACETOPHENONE
86 2':4' DICHLORO Solid Local/Export Road/By sea ACETOPHENONE
87 2':4' DICHLORO Solid Local/Export Road/By sea VELEROPHENONE
88 2':4' DICHLORO 5 FLUORO Solid Local/Export Road/By sea ACETOPHENONE
89 2':4' DICHLORO Solid Local/Export Road/By sea PHENACYLCHLORIDE
90 2':4' DICHLORO Solid Local/Export Road/By sea BUTEROPHENONE
91 AZACONAZOLE Solid Local/Export Road/By sea
92 BROMUCONAZOLE Solid Local/Export Road/By sea
93 DIFENOCONAZOLE Solid Local/Export Road/By sea
94 ETACONAZOLE Solid Local/Export Road/By sea
95 HEXACONAZOLE Solid Local/Export Road/By sea
96 PROPICONAZOLE Solid Local/Export Road/By sea
97 PENCONAZOLE Solid Local/Export Road/By sea
98 PROTHIOCONAZOLE Solid Local/Export Road/By sea
99 IMAZALIL Solid Local/Export Road/By sea
100 TEBUCONAZOLE Solid Local/Export Road/By sea
101 DITHIANON Solid Local/Export Road/By sea
102 AMINORESORCINE Solid Local/Export Road/By sea DIORTHO CRESYL ETHER
103 2 AMINO 2',4,4' TRICHLORO Solid Local/Export Road/By sea DIPHENYL ETHER (TADE)
104 2 AMINO 4 CHLORO Solid Local/Export Road/By sea DIPHENYL ETHER
105 4 AMINO 2,4' DICHLORO Solid Local/Export Road/By sea
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DIPHENYL ETHER
106 2 AMINO 2'‐4 DICHLORO Solid Local/Export Road/By sea DIPHENYL ETHER
107 2 AMINO 4‐4' DICHLORO Solid Local/Export Road/By sea DIPHENYL ETHER
108 1,3 BIS (3‐AMINO Solid Local/Export Road/By sea PHENOXYL) BENZENE
109 5 AMINO 2,2'‐3 TRICHLORO Solid Local/Export Road/By sea 4‐NITRO DIPHENYL ETHER
110 ORTHOCHLORO PARANITRO Solid Local/Export Road/By sea ANILINE
111 PARACHLORO ORTHONITRO Solid Local/Export Road/By sea ANILINE
112 ORTHO NITRO ANILINE Solid Local/Export Road/By sea
113 PARA NITRO ANILINE Solid Local/Export Road/By sea
114 2,3 DICHLORO 6 NITRO Solid Local/Export Road/By sea ANILINE
115 3,4, DICHLORO 6 NITRO Solid Local/Export Road/By sea ANILNE
116 5 CHLORO 2 NITRO Solid Local/Export Road/By sea ANILINNE
117 CUMAC Liquid Local/Export Road/By sea
118 NITRO RF
119 DIETHYL DIPROPYL Liquid Local/Export Road/By sea MALONATE
120 MALONIC ACID Solid Local/Export Road/By sea
121 PARACHLORO ANILINE Solid Local/Export Road/By sea HYDROCHLORIDE
122 4 NITRO PHTHALO NITRILE Solid Local/Export Road/By sea
123 FHIA Solid Local/Export Road/By sea
124 MSTT Solid Local/Export Road/By sea
125 THISA Solid Local/Export Road/By sea
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126 TBSA Solid Local/Export Road/By sea
127 4 CHLORO 2' AMINO Solid Local/Export Road/By sea DIPENYLAMINE (NDPA)
128 BINOL Solid Local/Export Road/By sea
129 OXYQUINOLINE COPPER Solid Local/Export Road/By sea
128 2H‐HEXAFLUORO PROPOXY Liquid Local/Export Road/By sea PROPYLENE‐2,5‐DICHLORO 4 AMINO BENZENE
129 2,4 DIMETHOXY 5 CHLORO Solid Local/Export Road/By sea NITROBENZENE
130 2,5 DICHLORO 4 NITRO Solid Local/Export Road/By sea ANILINE
131 4 CHLORO 2 AMINO Solid Local/Export Road/By sea DIPHENYLAMINE (ADPA)
132 AMINO RF Solid Local/Export Road/By sea
133 4 AMINO BENZONITRILE Solid Local/Export Road/By sea
134 1,5 DIAMINO Solid Local/Export Road/By sea NAPHTHALENE
135 1,8 DIAMINO Solid Local/Export Road/By sea NAPHTHALENE
136 4 CHLORO 2 AMINO Solid Local/Export Road/By sea PHENOL
137 2 CHLORO 4 AMINO Solid Local/Export Road/By sea PHENOL
138 2,4 DI HYDROXY BENZO Solid Local/Export Road/By sea PHENONE
139 3 HYDROXY Solid Local/Export Road/By sea ACETOPHENONE
140 2,4 D ACID Solid Local/Export Road/By sea
141 ACLONIFEN Solid Local/Export Road/By sea
143 FLURIDONE Solid Local/Export Road/By sea
144 CLORPROFAM Solid Local/Export Road/By sea
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145 DITHIANONE Solid Local/Export Road/By sea
146 FLUFENACET Solid Local/Export Road/By sea
147 QUINOCLAMINE ( CAN ) Solid Local/Export Road/By sea
148 Fenvalerate Solid Local/Export Road/By sea
149 ALPHA METHRIN Liquid Local/Export Road/By sea
150 DELTA METHRIN Solid Local/Export Road/By sea
151 PER METHRIN Solid Local/Export Road/By sea
152 LAMDA PSI HELOTHRIN Solid Local/Export Road/By sea
153 CYPERMETHRIN Solid Local/Export Road/By sea
154 DEET ( n,n‐diethyl‐3‐ Liquid Local/Export Road/By sea methylbenzamide) 134‐62‐3
155 SODIUM NAPHTHIONATE Solid Local/Export Road/By sea
156 META TOLUIC ACID Solid Local/Export Road/By sea
157 MPBAD Liquid Local/Export Road/By sea
DETAILS ON RAW MATERIAL TRANSPORTATION
Sr. Substance Physical Source of Means of Distance of No. State Supply Transportatio supplier n from project site (km) 1 Benzene Liquid Local Road Max 150
liquefie 2 Chlorine Local Road Max 60 d Gas
Imported 3 Phenol Solid Sea & Road ‐ & Local
Hydrochloric 4 Liquid In house ‐ ‐ Acid(30‐33 % )
5 Nitrobenzene Liquid Local Road Max 200
Ferric Chloride ( 6 Solid Local Road Max 200 Anhydrous)
7 Soda Ash Solid Local Road Max 60
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8 Aniline Liquid Local Road Max 60
9 NaoH ( Flacks) Solid Local Road Max 60
10 NaOh ( 48% Lye) Liquid Local Road Max 60
Imported 11 Thiourea Solid Sea & Road & Local
12 4 Nitro Aniline Solid Local Road Max.60
Sodiumbicarbonat 13 Solid Local Road Max 150 e Imported 14 Valeric Acid Liquid Sea & Road & Local
15 Thionyl Chloride Liquid Local Road Max 150
Ethylene Imported 16 Liquid Sea & Road Dichloride & Local
Imported 17 Butric Acid Liquid Sea & Road & Local
2,6 Dichloro 4 18 Solid In house ‐ ‐ Nitro Aniline
Formaldehyde 37 19 Liquid Local Road Max 200 %
2,4,6 Trichloro 20 Solid In house ‐ ‐ Aniline
21 Aluminim Chloride Solid Local Road Max 60
22 Cumene Liquid Imported Sea & Road
23 Sulphuric Acid 98% Liquid Local Road Max.60
24 Nitric Acid 60% Liquid Local Road Max.60
Imported 25 Naphthalene Solid Sea & Road & Local
26 98% Nitric Acid Liquid Local Road Max 60
27 Nitro Naphthalene Solid In house ‐‐
Ethylene Imported 28 Liquid Sea & Road Dichloride & Local
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Imported 29 Meta‐Xylene Liuid Sea & Road & Local
30 Ortho‐Xylene Liquid Local Road Max 500
31 Para‐Xylene Liquid Local Road Max 500
para‐ 32 Solid In house ‐ ‐ Dichlorobenzene
Ortho‐ 33 Liquid In house ‐ ‐ Dichloroobenzene
meta‐ 34 Liquid In house ‐ ‐ Dichlorobenzene
1,2,4 35 Liquid In house ‐ ‐ Trichlorobenzene
1,2,3 36 Liquid In house ‐ ‐ Trichlorobenzene
37 2,6 Dichlorophenol Solid In house ‐‐
38 2,3 Dichlorophenol Solid In house ‐ ‐ Imported 39 Methanol Liquid ‐ ‐ & Local
ortho‐ 40 Nitrochlorobenzen Liquid Local Road Max 250 e
41 Hydrogen Gas Gas Local Road Max 60
para‐ 42 Nitrochlorobenzen Solid Local Road Max.250
e
ortho‐ 43 Liquid In house ‐ ‐ Nitrocumene 44 para‐Nitrocumene Liquid In house ‐ ‐
2,4
45 Dimethylnitrobenz Liquid In house ‐ ‐ ene
2,6
46 Dimethylnitrobenz Liquid In house ‐ ‐
ene
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2,3 47 Dimethylnitrobenz Liquid In house ‐ ‐ ene 3,4 48 Dimethylnitrobenz Liquid In house ‐ ‐ ene 2,5 49 Dimethylnitrobenz Liquid In house ‐ ‐ ene
50 Ortho‐Nitroanisol Liquid Local Road Max‐250
51 Para‐Nitroanisol Liqiud Local Road Max‐250
52 Acetic Anhydride Liquid Local Road Max 100
ortho‐Tertiary 53 Liquid Local Road Max 600 Butyl Phenol
para‐Tertiary Butyl 54 Solid Local Road Max 600 Phenol
55 Acetic Acid Liquid Local Road Max 60
Phenyl Ethyl 56 Liquid Local Road Max 600 Alcohol
57 Citronellal Liquid Local Road Max 600
58 Citral Liquid Local Road Max 600
59 Alpha Pinane Liquid Local Road Max.600
60 ACETONE Liquid Local Road Max 250
ORTHO NITRO 61 Liquid Local Road Max 150 TOLUENE
PARA NITRO 62 Solid Local Road Max 150 TOLUENE
META NITRO Local & 63 Liquid Sea & Road TOLUENE Imported
3,5 DINITRO 64 Solid Local Road Max 300 BENZOIC ACID
65 Diethyl Ketone Liquid Local Road Max 500
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3,5 DIMETHYL 66 Solid Local Road Max 300 NITROBENZENE
Methy ethyl 67 Liquid Local Road Max 500 Ketone
PARA NITRO 68 Solid Local Road Max 150 ANILENE
3 NITRO‐9‐(N‐ 69 Solid Local Road Max 150 ETHYL)‐CARBZOLE
8,Hydroxy 70 Solid Local Road Max‐100 quinoline
71 Copper sulphate Solid Local Road Max‐100
PARA NITRO 72 Liquid In house ‐ ‐ ORTHO XYLENE
4 NITRO 2,5 73 DICHLORO Solid In house ‐ ‐ PHENOL
4 NITRO 2,3 74 DICHLORO Solid In house ‐ ‐ PHENOL
4 NITRO 2,6 75 DICHLORO Solid In house ‐ ‐ PHENOL 76 Styrene Oxide Liquid Local ‐ Max 600
2,5 DICHLORO 77 Solid In house ‐ ‐ NITRO BENZENE
3,4 Dichloro 78 Liquid In house ‐ ‐ Nitrobenzene
2,3 DICHLORO 79 Liquid In house ‐ ‐ NITRO BENZENE
80 TOLUENE Liquid Local Road Max 150
2,4 DICHLORO 81 Liquid In house ‐ ‐ NITRO BENZENE
2 CHLORO 4 NITRO 82 Solid In house ‐ ‐ ANILINE
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2,5 Dichloro 4 83 Solid In house ‐ ‐ Nitro Aniline
3,5 DICHLORO 84 Solid In house ‐ ‐ NITRO BENZENE
3 CHLORO NITRO 85 Solid In house ‐ ‐ BENZENE
m‐Phenoxy 86 Liquid In house ‐ ‐ Benzaldehyde
2,4 DIMETHOXY 5 87 CHLORO NITRO Solid In house ‐ ‐ BENZENE
2,5 Dichloro 88 Solid In house ‐ ‐ Aniline
89 Sulphur Dioxide Gas Local ‐‐
2,3 Dichloro 90 Liquid In house ‐ ‐ Aniline
3,4 Dichloro 91 Solid In house ‐ ‐ Aniline
92 3 Chloro Aniline Solid In house ‐ ‐
Solvent mixed 93 Liquid Local Road Max‐250 Xylene
2,5 Dichloro 94 Solid In house ‐ Phenol 95 Bromine Liquid Local Road Max‐500
96 Dimethyl Sulphate Liqiud Local Road Max‐200
Monochloro 97 Liquid In house ‐ ‐ Benzene 98 Acetyl Chloride Liuid Local Road Max 200
2,4 Dichloro Fluoro Imported 99 Liquid Sea & Road ‐ Benzene & Local
Chloroacetyl 100 Liquid Local Road Max 200 Chloride
101 Butryl Chloride Liquid In house ‐
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Potassium 102 Solid Local Road Max 60 Hydroxide
Dimethyl 103 Liquid Local Road Max‐600 Formamide
104 Ethylene Gylcol Liquid Local Road Max‐600
105 Allyl Bromide Liquid Local Road Max‐600
Solvent Tetrahydro 106 Liquid Local Road Max‐600 Furan
Potassium Local & 107 Solid Sea & Road Carbonate Imported
108 4 Chloro Phenol Solid In house ‐ ‐
109 Proplyene Glycol Liquid Local Road Max‐600
110 1,2 Butanediol Liquid Local Road Max‐600
111 Valeroyl Chloride Liquid In house ‐‐
Methyl Triphenyl 112 Solid Local Road Max‐600 Phosphorane
113 Hydrogen Peroxide Liquid Local Road Max‐250
Local & 114 1,2 Pentanediol Solid Sea & Road Imported
115 1,2,4 Traizole Solid Imported Sea & Road
Methyl Sulphonyl 116 Liquid Local Road Max‐250 Chloride
Local & 117 Sodium Methoxide Solid Sea & Road Imported
Chloro Cyclo 118 Liquid Local Road Max‐600 Propane
2 Hydroxy 119 Propanyl Chloride
2,4 Dihydro 1,2,4 120 Solid Imported Sea & Road Triazole 5 Thione
121 Imadazole Solid Local Road
122 Allyl Chloride Liquid Local Road Max‐600
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123 2‐Methyl Phenol Liqiuid Local Road Max 150
124 Iron (Fe) Powder Solid Local Road Max‐500
125 2‐ Chloro Phenol Liquid In house ‐‐
126 3 Nitro Phenol Solid In house ‐ ‐
6 Nitro 3,4 127 Solid In house ‐ ‐ Dichloro Aniline
3,4 Dichloro Semi 128 In house ‐ Nitrobenzene Solid Ammonia ( 129 Gas Local Road Max 150 Anhydrous)
2,3,4 Trichloro 130 Solid In house ‐ ‐ Nitrobenzene
2,4,5 Trichloro 131 Solid In house ‐ ‐ Nitrobenzene
2,4, Dichloro 132 Solid In house ‐ ‐ Nitrobenzene Local & 133 Salicylic Acid Solid Sea & Road Imported
Monochloro Acetic 134 Solid Local Road Max‐60 Acid
Methyl Tertary 135 Liquid Local Road Max‐600 Butyl Ether
136 Paranitro Phenol Solid Local Road Max‐150
N‐PROPYL 138 Liquid Local Road Max‐250 BROMIDE
DIETHYL DIPROPYL 139 Liquid In house ‐ ‐ MALONATE
2,2' 140 Dipropylmalonic Liquid In house ‐ ‐
Acid
141 Parachloro Aniline Solid In house ‐ ‐
4‐NITRO 142 Solid Loca Road Max 600 PHTHALIMIDE
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143 POCl3 Liquid Local Road Max‐200
1‐Fluoro 4 Semi 144 Imported Sea & Road Nitrobenzene Solid
145 Phosphoric Acid Liquid Local Road Max 600
Triethyl Amine 146 Liquid Local Road Max‐600 Solution
147 Sodium Acetate Solid Local Road Max‐150
148 Hydrazine Hydrate Liquid Local Road Max‐600 149 Carbon Disufide Liquid Local Road Max‐250
2,2,2 Trifluoro 150 Liquid Local Road Max‐600 Acetic Acid
Phosphoryl 151 Liquid Local Road Max‐600 Chloride
152 Formic Acid Liquid Local Road Max‐250
153 Sodium Bi Sulfite Liquid In house ‐ ‐
154 ATHIO Solid In house ‐ ‐
155 TFMA Liquid Imported Sea & Road
Ammonia ( 25 % 156 Liquid Local Road Max‐150 Solution)
Imported 157 BETA NAPHTHOL Solid Sea & Road & Local 158 Xylene Liquid Local Road
159 Acetonitrile Liquid Local Road Max‐600
Hexafluoro 160 Gas Local Road Max‐60 Propylene Gas
Local & 161 Sodium Methoxide Solid Sea & Road Imported
4 CHLORO 2 NITRO 162 Solid In house ‐ ‐ DIPHENYLAMINE
THIOPHOSPHORIC
163 TRI (4 Solid In house ‐ ‐
NITROPHENYL)
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ESTER (NITRO RF)(90%)
4 NITRO 164 Solid In house ‐ ‐ BENZONITRILE
1,5 DINITRO 165 Solid In house ‐ ‐ NAPHTHALENE
1,8 DINITRO 166 Solid In house ‐ ‐ NAPHTHALENE
Local & 167 Sodium Dithionate Solid Sea & Road Imported
Local & 168 Hydrazine Hydrate Liquid Sea & Road Imported
Local & 169 Resorcinol Solid Sea & Road Imported
Local & 170 BenzoTrichloride Liquid Sea & Road Imported
3 AMINO Local & 171 Solid Sea & Road ACETOPHENONE Imported
2,4 Dichloro Semi 172 In house ‐ ‐ Phenol Solid
Monochloro Acetic 173 Solid Local Road Max‐60 Acid
2 Amino 3,4 174 Dichloro Nitro Solid In house ‐ ‐
Benzene
175 Solvent DMSO Liquid Local Road Max‐600
176 FHIA Solid In house ‐ ‐
DICHLORO 177 Liquid Local Road Max‐600 METHANE
DIMETHYL 178 Liquid Local Road Max‐600 CARBONATE
179 MSTT Solid In house ‐ ‐
DichloroNaphthaq 180 Solid Local ‐ ‐ uinone
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181 Hexane Liquid Local Road Max‐600
182 CM Acid Chloride Liquid local Road Max‐600
183 Sodium Cyanide Solid Local Road Max‐250
CM Acid Bromide ( 184 Liquid local Road Max‐600 DELTA)
Sodium 185 Liquid Local Road Max‐60 Hypochloride
Floro CM Acid 186 Liquid Local Road Max‐600 Chloride
187 m‐TOLUIC ACID Solid In house
188 Dietyl Amine Liquid Local Road Max‐600
ALPHA 189 Solid In house NAPHTHYLAMINE
190 M‐XYLENE Liquid Imported Sea & Road
191 Benzaldehyde Liquid Local Road Max‐600
Mono Ehylene 192 Liquid Local Road Max‐600 Gylcol (MEG )
Local/ 193 Thiphanone Liquid Road/sea Max‐100 import
194 Acetonitrile Liquid Local Road Max‐200
Hydroxylamine 195 Solid Local Road Max‐100 hydrochloride
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DETAILS ON STORAGE & HANDLING OF HAZARDOUS CHEMICALS
No Name of Quantity Place State Possible Control the Raw stored, MT of its operati type of measures Materials BP. MP0C ng hazards provided Ma Actual Stora pressur 0C x ge e temper ature
1 Benzene 250 150 80 5.5 Explosi Atm & Fire & Separate ve Ambien Explosio approved Tank t n explosive Farm storage
area, Proper earthing lightening arrestor &
FFE
2 Chlorine 150 75 ‐101 ‐35 Appro 10 Toxic Gas Separate ved Kg/Cm2 Leakage approved Gas & storage & is Storag Ambien handled in e Area t close circuit with
emergency kit and appropriate PPE
provided.
3 Phenol 50 50 181. 40.5 Tank Atm & Spillage Tanks with
7 Farm Ambien bund walls t & used in liquid form in closed circuit.
4 Hydrochlo 100 250 110 ‐ Tank Atm & Hazardo Proper bund ric 0 Farm Ambien us area
Acid(30‐ t provided & 33 % ) handled in closed circuit.
5 Nitrobenz 25 25 210. ‐ Tank Atm & Spillage Tanks with ene 9 Farm Ambien bund walls t & used in closed circuit.
6 Soda Ash 50 40 ‐‐Solid Non‐ R.M. Hazardo New Project: Page 59 Manufacturing: Agro Chemicals & Organic Int.
Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
Storag us e 7 Aniline 25 20 14.1 ‐6.3 Tank Atm & Spillage Tanks with Farm Ambien bund walls t & used in
closed circuit.
8 NaoH ( 25 20 1388 318 Solid Non‐ PPE Flacks) R.M. Hazardo Provided Storag us e 9 NaOH ( 50 40 1388 318 Tank Atm & Spillage Tanks with 48% Lye) Farm Ambien bund walls t & used in
closed circuit.
10 Thiourea 5 4 182 Solid Non‐ R.M. Hazardo Storag us e 11 4 Nitro 20 15 332 Solid Atm & Hazardo PPE Aniline R.M. Ambien us Provided Storag t
e
12 Sodiumbi 25 20 ‐‐Solid Non‐
carbonate R.M. Hazardo Storag us e
13 Valeric 25 20 186 ‐34 Tank Atm & Spillage Tanks with Acid Farm Ambien bund walls t & used in closed
circuit.
14 Thionyl 25 20 74.6 ‐104.5 Tank Atm & Hazardo PPE
Chloride Farm Ambien us Provided / t Scrubbing System
15 Ethylene 50 40 84 ‐35 Tank Atm & Fire & Separate Dichloride Farm Ambien Explosio approved t n explosive storage
area, Proper earthing lightening New Project: Page 60 Manufacturing: Agro Chemicals & Organic Int.
Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
arrestor & FFE 16 Butric 20 15 164 ‐5.1 Tank Atm & Spillage Tanks with Acid Farm Ambien bund walls t & used in
closed circuit.
17 2,6 20 20 192 Solid Atm & Dichloro 4 R.N.St Ambien Nitro orage t Aniline 18 Formalde 20 15 98 ‐15 Tank Atm & Spillage Tanks with hyde 37 % Farm Ambien bund walls t & used in
closed circuit.
19 2,4,6 20 15 262 75 Soild Non‐ PPE Trichloro R.M.St Hazardo Provided Aniline orage us
20 Aluminim 100 50 ‐‐Soild Atm & Hazardo PPE Chloride R.M.St Ambien us Provided / orage t Scrubbing System
21 Cumene 25 20 152 ‐96 Tank Atm & Spillage Tanks with Farm Ambien bund walls
t & used in closed circuit.
22 Sulphuric 250 200 ‐ 10 Tank Atm & Hazardo Proper bund Acid 98% Farm Ambien us area t provided & handled in
closed circuit.
23 Nitric 200 180 ‐‐38 Tank Atm & Hazardo Proper bund Acid 60% Farm Ambien us area t provided & handled in
closed circuit.
24 Naphthal 50 40 218 80.2 Solid Atm & Hazardo PPE
ene 6 R.M. Ambien us Provided Storag t
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e
25 98% Nitric 150 125 83 ‐42 Tank Atm & Hazardo Proper bund Acid Farm Ambien us area t provided & handled in
closed circuit.
26 Nitro 50 40 304 57 Tank Atm & Spillage Tanks with Naphthal Farm Ambien bund walls ene t & used in liquid in closed circuit.
27 Meta‐ 100 80 139 ‐48 Tank Atm & Spillage Tanks with
Xylene Farm Ambien bund walls t & used in closed circuit.
28 Ortho‐ 100 80 144 ‐24 Tank Atm & Spillage Tanks with Xylene Farm Ambien bund walls t & used in closed circuit.
29 Para‐ 100 80 138. 13.2 Tank Atm & Spillage Tanks with Xylene 4 Farm Ambien bund walls t & used in closed
circuit.
30 para‐ 750 250 174 52 Tank Atm & Spillage Tanks with Dichlorob Farm Ambien bund walls enzene t & used in liquid in closed circuit.
31 Ortho‐ 750 250 178 ‐15 Tank Atm & Spillage Tanks with Dichloroo Farm Ambien bund walls
benzene t & used in liquid in closed circuit.
32 meta‐ 250 100 172 ‐24 Tank Atm & Spillage Tanks with Dichlorob Farm Ambien bund walls enzene t & used in liquid in closed New Project: Page 62 Manufacturing: Agro Chemicals & Organic Int.
Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
circuit.
33 1,2,4 250 100 214 17 Tank Atm & Spillage Tanks with Trichlorob Farm Ambien bund walls enzene t & used in liquid in
closed circuit.
34 1,2,3 500 100 218 52 Tank Atm & Spillage Tanks with Trichlorob Farm Ambien bund walls enzene t & used in liquid in closed circuit.
35 2,6 50 40 220 66 Tank Atm & Spillage Tanks with
Dichlorop Farm Ambien bund walls henol t & used in liquid in closed
circuit.
36 2,3 50 40 206 57 Tank Atm & Spillage Tanks with Dichlorop Farm Ambien bund walls henol t & used in liquid in closed circuit.
37 Methanol 60 50 64.7 ‐97.6 Explosi Atm & Fire & Separate ve Ambien Explosio approved
Tank t n explosive Farm storage area, Proper earthing
lightening arrestor & FFE
38 ortho‐ 25 20 245. 33 Tank Atm & Spillage Tanks with Nitrochlor 5 Farm Ambien bund walls obenzene t & used in liquid in
closed circuit.
39 Hydrogen 100 750 ‐252 On 50 bar Fire & Separate Gas ( 0 mobile at explosio approved NM3) rack Ambien n explosive truck t storage area, Proper
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earthing lightening arrestor & FFE
40 para‐ 25 20 242 83.6 Tank Atm & Spillage Tanks with
Nitrochlor Farm Ambien bund walls obenzene t & used in liquid in closed
circuit.
41 ortho‐ 50 40 121 Tank Atm & Spillage Tanks with Nitrocum Farm Ambien bund walls ene t & used in liquid in closed circuit.
42 para‐ 50 40 128 ( Tank Atm & Spillage Tanks with Nitrocum 12 Farm Ambien bund walls
ene mm) t & used in liquid in closed circuit.
43 2,4 60 40 244 Tank Atm & Spillage Tanks with Dimethyl Farm Ambien bund walls nitrobenz t & used in ene liquid in closed circuit.
44 2,6 25 20 225 Tank Atm & Spillage Tanks with Dimethyl Farm Ambien bund walls nitrobenz t & used in
ene liquid in closed circuit.
45 2,3 60 40 245 Tank Atm & Spillage Tanks with Dimethyl Farm Ambien bund walls nitrobenz t & used in ene liquid in
closed circuit.
46 3,4 60 40 255 Tank Atm & Spillage Tanks with Dimethyl Farm Ambien bund walls nitrobenz t & used in ene liquid in closed
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circuit.
47 2,5 25 20 240 ‐25 Tank Atm & Spillage Tanks with Dimethyl Farm Ambien bund walls nitrobenz t & used in ene liquid in
closed circuit.
48 Ortho‐ 10 10 273 10 Drum Atm & Spillage Bund wall Nitroanis / R.M. Ambien provided ol Wareh t ouse 49 Para‐ 10 10 260 54 Drum Atm & Non‐ PPE Nitroanis / R.M. Ambien Hazardo provided ol Wareh t us
ouse
50 Acetic 15 10 139. ‐73.1 Tank Atm & Spillage Tanks with
Anhydrid 8 Farm Ambien bund walls e t & used in liquid in closed circuit.
51 ortho‐ 20 20 224 ‐7 Tank Atm & Spillage Tanks with Tertiary Farm Ambien bund walls
Butyl t & used in Phenol liquid in closed circuit.
52 para‐ 20 20 238 101 Tank Atm & Spillage Tanks with Tertiary Farm Ambien bund walls Butyl t & used in Phenol liquid in closed circuit. 53 Acetic 25 20 118 16 Tank Atm & Spillage Tanks with Acid Farm Ambien bund walls t & used in
liquid in closed circuit.
54 Phenyl 25 20 221 ‐27 Tank Atm & Spillage Tanks with Ethyl Farm Ambien bund walls Alcohol t & used in liquid in closed
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circuit.
55 Citronellal 25 20 225 ‐20 Tank Atm & Spillage Tanks with Farm Ambien bund walls t & used in liquid in
closed circuit.
56 Citral 25 20 229 ‐10 Tank Atm & Spillage Tanks with Farm Ambien bund walls t & used in liquid in closed circuit.
57 Alpha 25 20 155 ‐64 Tank Atm & Spillage Tanks with
Pinane Farm Ambien bund walls t & used in liquid in closed
circuit.
58 ACETONE 25 20 56 ‐95 Explosi Atm & Fire & Separate ve Ambien Explosio approved Tank t n explosive Farm storage area, Proper earthing lightening arrestor & FFE
59 ORTHO 25 20 222 ‐10.4 Tank Atm & Spillage Tanks with NITRO Farm Ambien bund walls TOLUENE t & used in
liquid in closed circuit.
60 PARA 15 10 238. 51.6 R.M.W Atm & Non‐ PPE NITRO 3 3 are Ambien Hazardo Provided TOLUENE house t us
61 META 25 20 232 15.5 Tank Atm & Spillage Tanks with NITRO Farm Ambien bund walls TOLUENE t & used in
liquid in closed circuit.
62 3,5 15 10 207 R.M.W Atm & Non‐ PPE DINITRO are Ambien Hazardo New Project: Page 66 Manufacturing: Agro Chemicals & Organic Int.
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BENZOIC house t us Provided ACID 63 Diethyl 25 20 102 ‐39 Tank Atm & Spillage Tanks with Ketone Farm Ambien bund walls t & used in
liquid in closed circuit.
64 3,5 15 10 273 74 R.M.W Atm & Non‐ PPE DIMETHY are Ambien Hazardo Provided L house t us NITROBE NZENE
65 Methyl 25 20 79.6 ‐86 Tank Atm & Spillage Tanks with
ethyl Farm Ambien bund walls Ketone t & used in liquid in closed
circuit.
66 PARA 15 10 332 149 R.M.W Atm & Hazardo PPE NITRO are Ambien us Provided ANILENE house t
67 3 NITRO‐ 15 10 R.M.W Atm & Hazardo PPE
9‐(N‐ are Ambien us Provided ETHYL)‐ house t CARBZOL E
68 ALDOL 15 10 R.M.W Atm & Hazardo PPE are Ambien us Provided house t
69 ACETALD 15 10 20.2 ‐ R.M.W Atm & Hazardo PPE EHYDE 123. are Ambien us Provided
5 house t
70 PARA 15 10 255 29 R.M.W Atm & Hazardo PPE
NITRO are Ambien us Provided ORTHO house t XYLENE
71 4 NITRO 15 10 117 R.M.W Atm & Hazardo PPE 2,5 are Ambien us Provided DICHLOR house t O
PHENOL
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72 4 NITRO 15 10 120 R.M.W Atm & Hazardo PPE 2,3 are Ambien us Provided DICHLOR house t O PHENOL
73 4 NITRO 15 10 127 R.M.W Atm & Hazardo PPE 2,6 are Ambien us Provided DICHLOR house t O
PHENOL
74 Styrene 15 10 194 ‐37 R.M.W Atm & Hazardo PPE Oxide are Ambien us Provided house t
75 2,5 500 400 266 54 Tank Atm & Spillage Tanks with
DICHLOR Farm Ambien bund walls O NITRO t & used in BENZENE liquid in closed
circuit.
76 3,4 100 80 263 39 Tank Atm & Spillage Tanks with Dichloro Farm Ambien bund walls Nitrobenz t & used in ene liquid in closed circuit.
77 2,3 75 50 258 61 Tank Atm & Spillage Tanks with DICHLOR Farm Ambien bund walls
O NITRO t & used in BENZENE liquid in closed circuit.
78 TOLUENE 50 40 110. ‐95 Explosi Atm & Fire & Separate 6 ve Ambien Explosio approved Tank t n explosive Farm storage area, Proper earthing lightening
arrestor & FFE
79 2,4 75 50 258. 34 Tank Atm & Spillage Tanks with DICHLOR 5 Farm Ambien bund walls O NITRO t & used in BENZENE liquid in closed
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circuit.
80 2 CHLORO 25 20 107 Soild Atm & Hazardo PPE 4 NITRO R.M.St Ambien us Provided ANILINE orage t
81 2,5 25 20 158 Soild Atm & Hazardo PPE Dichloro 4 R.M.St Ambien us Provided Nitro orage t
Aniline
82 3,5 25 20 65 Tank Atm & Spillage Tanks with DICHLOR Farm Ambien bund walls
O NITRO t & used in BENZENE liquid in closed circuit.
83 3 CHLORO 50 40 236 47 Tank Atm & Spillage Tanks with NITRO Farm Ambien bund walls
BENZENE t & used in liquid in closed circuit. 84 m‐ 50 40 140 13 Tank Atm & Spillage Tanks with Phenoxy Farm Ambien bund walls Benzalde t & used in
hyde liquid in closed circuit.
85 2,4 15 10 52 Soild Atm & Spillage PPE DIMETHO R.M.St Ambien Provided XY 5 orage t CHLORO NITRO BENZENE
86 2,5 75 50 251 50 Tank Atm & Spillage Tanks with Dichloro Farm Ambien bund walls Aniline t & used in liquid in
closed circuit.
87 Sulphur ‐10 ‐72 Appro 8 Bar & Toxic Separate Dioxide ved 75 approved Gas storage & is Storag handled in e Area close circuit with emergency New Project: Page 69 Manufacturing: Agro Chemicals & Organic Int.
Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
kit and appropriate PPE provided.
88 2,3 25 20 252 23 Tank Atm & Spillage Tanks with
Dichloro Farm Ambien bund walls Aniline t & used in liquid in closed
circuit.
89 3,4 60 50 272 72 Tank Atm & Spillage Tanks with Dichloro Farm Ambien bund walls Aniline t & used in liquid in closed circuit.
90 3 Chloro 25 20 96 ‐11 Tank Atm & Spillage Tanks with Aniline Farm Ambien bund walls
t & used in liquid in closed circuit.
91 Solvent 25 20 138. ‐47.4 Tank Atm & Spillage Tanks with mixed 5 Farm Ambien bund walls Xylene t & used in liquid in closed circuit.
92 2,5 40 35 211 57 Tank Atm & Spillage Tanks with Dichloro Farm Ambien bund walls Phenol t & used in
liquid in closed circuit.
93 Bromine 15 10 58.8 ‐7.2 Tank Atm & Spillage/t Separate Farm Ambien oxic approved t storage & is handled in
close circuit with emergency kit and
appropriate PPE provided.
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94 Dimethyl 25 20 188 ‐32 Tank Atm & Spillage Tanks with Sulphate Farm Ambien bund walls t & used in liquid in closed circuit.
95 Monochlo 50 40 131 ‐45 Tank Atm & Spillage Tanks with ro Farm Ambien bund walls Benzene t & used in
liquid in closed circuit.
96 Acetyl 25 20 52 ‐112 Tank Atm & Spillage Tanks with Chloride Farm Ambien bund walls t & used in liquid in
closed circuit.
97 2,4 25 20 174 ‐23 Tank Atm & Spillage Tanks with Dichloro Farm Ambien bund walls Fluoro t & used in Benzene liquid in
closed circuit.
98 Chloroace 25 20 106 ‐22 Tank Atm & Spillage Tanks with tyl Farm Ambien bund walls Chloride t & used in liquid in closed
circuit.
99 Butryl 25 20 78 ‐ Tank Atm & Spillage Tanks with
Chloride 123. Farm Ambien bund walls 1 t & used in liquid in closed circuit.
100 Potassiu 40 25 1327 406 Solid Atm & Spillage PPE m R.M. Ambien Provided
Hydroxide Storag t e
101 Dimethyl 25 20 154 ‐60.5 Tank Atm & Spillage Tanks with Formamid Farm Ambien bund walls e t & used in liquid in closed
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circuit.
102 Ethylene 25 20 197. ‐12.9 Tank Atm & Spillage Tanks with Gylcol 3 Farm Ambien bund walls t & used in liquid in
closed circuit.
103 Allyl 25 20 71 ‐119 Tank Atm & Spillage Tanks with Bromide Farm Ambien bund walls t & used in liquid in closed circuit.
104 Tetrahydr 25 20 66 ‐ Tank Atm & Spillage Tanks with
o Furan 108. Farm Ambien bund walls 4 t & used in liquid in closed
circuit.
105 Potassiu 15 10 891 Solid Atm & Spillage PPE m R.M. Ambien Provided Carbonat Storag t e e
106 4 Chloro 25 20 220 45 Tank Atm & Spillage PPE Phenol Farm Ambien Provided t
107 Proplyene 25 20 188. ‐59 Tank Atm & Spillage Tanks with Glycol 2 Farm Ambien bund walls t & used in liquid in closed circuit.
108 1,2 25 20 196. ‐50 Tank Atm & Spillage Tanks with Butanedi 9 Farm Ambien bund walls ol t & used in liquid in
closed circuit.
109 Valeroyl 25 20 127 ‐110 Tank Atm & Spillage Tanks with Chloride Farm Ambien bund walls t & used in liquid in closed circuit.
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110 EDC 25 20 84 ‐35 Tank Atm & Spillage Separate Farm Ambien approved t storage & is handled in close circuit with emergency
kit and appropriate PPE provided.
111 Methyl 15 10 430 Solid Atm & Spillage PPE Triphenyl R.M. Ambien Provided
Phosphor Storag t ane e
112 Hydrogen 15 10 150. ‐0.43 Tank Atm & Spillage Tanks with
Peroxide 2 Farm Ambien bund walls t & used in liquid in closed
circuit.
113 1,2 15 10 206 104 Solid Atm & Spillage PPE
Pentanedi R.M. Ambien Provided ol Storag t e
114 1,2,4 15 10 260 121 Solid Atm & Spillage PPE Traizole R.M. Ambien Provided Storag t e
115 Methyl 15 10 60 Tank Atm & Spillage Tanks with Sulphonyl Farm Ambien bund walls
Chloride t & used in liquid in closed circuit. 116 Sodium 300 127 Solid Atm & Spillage PPE Methoxid R.M. Ambien Provided e Storag t
e
117 Chloro 15 10 65.5 Tank Atm & Spillage Tanks with
Cyclo Farm Ambien bund walls Propane t & used in liquid in closed circuit.
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118 2 Hydroxy 15 10 Solid Atm & Spillage PPE Propanyl R.M. Ambien Provided Chloride Storag t e
119 2,4 15 10 Solid Atm & Spillage PPE
Dihydro R.M. Ambien Provided 1,2,4 Storag t Triazole 5 e Thione
120 2,4 10 8 296 29 Drum Atm & spillage Bund wall Dichloro / R.M. Ambien provided Phenacyl Wareh t Bromide ouse
121 Imadazole 15 10 256 91 Solid Atm & Spillage PPE
R.M. Ambien Provided Storag t e
122 Allyl 15 10 45 ‐135 Explosi Atm & Fire & Separate Chloride ve Ambien Explosio approved Tank t n explosive Farm storage area, Proper earthing lightening arrestor & FFE
123 2‐Methyl 25 20 192 34 Tank Atm & Spillage Tanks with
Phenol Farm Ambien bund walls t & used in liquid in closed
circuit.
124 Iron (Fe) 25 20 ‐‐Solid Atm & Non‐ PPE Powder R.M. Ambien Hazardo Provided Storag t us e
125 2‐ Chloro 25 20 174. 9.4 Tank Atm & Spillage Tanks with Phenol 9 Farm Ambien bund walls t & used in liquid in
closed circuit.
126 3 Nitro 15 10 194 98 Solid Atm & Spillage Tanks with Phenol R.M. Ambien bund walls Storag & used in New Project: Page 74 Manufacturing: Agro Chemicals & Organic Int.
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e t liquid in closed circuit.
127 6 Nitro 10 5 Solid Atm & Spillage Tanks with 3,4 R.M. Ambien bund walls
Dichloro Storag t & used in Aniline e liquid in closed circuit.
128 3,4 50 40 263 41 Tank Atm & Spillage Tanks with Dichloro Farm Ambien bund walls Nitrobenz t & used in ene liquid in closed circuit. 129 Ammonia 5 4 ‐33 ‐77 Appro 10 Hazardo Separate ( ved Kg/Cm2 us approved Anhydrou Gas & storage & is
s) Storag Ambien handled in e Area t close circuit with emergency
kit and appropriate PPE provided. 130 2,3,4 25 20 53 Tank Atm & Spillage Tanks with Trichloro Farm Ambien bund walls Nitrobenz t & used in
ene liquid in closed circuit.
131 2,4,5 25 20 52 Tank Atm & Spillage Tanks with Trichloro Farm Ambien bund walls Nitrobenz t & used in ene liquid in closed circuit.
132 2,4, 25 20 263 34 Tank Atm & Spillage Tanks with Dichloro Farm Ambien bund walls Nitrobenz t & used in ene liquid in
closed circuit.
133 Salicylic 15 10 211 159 Solid Atm & Spillage PPE
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Acid R.M. Ambien Provided Storag t e
134 Monochlo 15 10 189. 63 Solid Atm & Spillage PPE ro Acetic 3 R.M. Ambien Provided
Acid Storag t e
135 Methyl 5 5 55.2 ‐109 Explosi Atm & Fire & Separate Tertary ve Ambien Explosio approved Butyl Tank t n explosive Ether Farm storage area, Proper earthing lightening arrestor & FFE
136 Para Nitro 15 10 279 114 Solid Atm & Spillage PPE Phenol R.M. Ambien Provided
Storag t e
137 DIETHYL 10 5 199 ‐50 Drum Atm & Spillage Bund wall MALONA / R.M. Ambien provided TE Wareh t ouse 138 N‐PROPYL 10 5 71 ‐ Drum Atm & Spillage Bund wall BROMIDE 110. / R.M. Ambien provided 5 Wareh t
ouse
139 DIETHYL 15 10 221 Drum Atm & Spillage Bund wall DIPROPYL / R.M. Ambien provided MALONA Wareh t TE ouse
140 2,2' 15 10 156 Solid Atm & Spillage PPE Dipropyl R.M. Ambien Provided malonic Storag t Acid e
141 Parachlor 15 10 232 70 Solid Atm & Spillage PPE o Aniline R.M. Ambien Provided
Storag t e
142 4‐NITRO 15 10 199 Solid Atm & Spillage PPE
PHTHALI R.M. Ambien Provided MIDE Storag t
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e
143 POCl3 15 10 105. 1.25 Tank Atm & Spillage Tanks with 8 Farm Ambien bund walls t & used in liquid in
closed circuit. PPE Provided
144 1‐Fluoro 4 15 10 205 21 Drum Atm & Spillage Bund wall Nitrobenz / R.M. Ambien provided ene Wareh t ouse
145 Phosphori 25 20 158 42.3 Tank Atm & Spillage Tanks with c Acid Farm Ambien bund walls
t & used in liquid in closed circuit.
146 Triethyl 15 10 Drum Atm & Spillage Bund wall Amine / R.M. Ambien provided Solution Wareh t ouse
147 Sodium 10 5 881. 324 Solid Atm & Spillage PPE
Acetate 4 R.M. Ambien Provided Storag t e
148 Hydrazine 25 20 114 2 Tank Atm & Spillage Tanks with Hydrate Farm Ambien bund walls t & used in liquid in closed circuit. PPE Provided 149 Carbon 5 5 46.3 ‐ Explosi Atm & Fire & Separate Disufide 110. ve Ambien Explosio approved 8 Tank t n explosive
Farm storage area, Proper earthing lightening
arrestor & FFE
150 2,2,2 15 10 72.4 ‐15.4 Drum Atm & Spillage Bund wall Trifluoro / R.M. Ambien provided Acetic Wareh New Project: Page 77 Manufacturing: Agro Chemicals & Organic Int.
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Acid ouse t
151 Phosphor 15 10 105. 1.25 Drum Atm & Spillage Bund wall yl 8 / R.M. Ambien provided Chloride Wareh t ouse
152 Formic 15 10 100. 8.4 Drum Atm & Spillage Bund wall Acid 8 / R.M. Ambien provided
Wareh t ouse
153 Sodium Bi 15 10 150 Solid Atm & Spillage PPE
Sulfite R.M. Ambien Provided Storag t e
154 Mono 25 20 197. ‐12.9 Tank Atm & Spillage Tanks with Ehylene 3 Farm Ambien bund walls Gylcol t & used in
(MEG ) liquid in closed circuit.
155 Bromine 10 5 58.7 ‐7.2 Isolate Atm & Leakage Separate d Tank Ambien approved Farm t storage and handling in
close circuit with emergency kit and
appropriate PPEs.
156 Ammonia 25 20 27 ‐57 Tank Atm & Spillage Tanks with ( 25 % Farm Ambien bund walls Solution) t & used in liquid in closed circuit.
157 BETA 15 10 285 123 Solid Atm & Spillage PPE
NAPHTHO R.M. Ambien Provided L Storag t e
158 Xylene 500 100 Tank Atm & Spillage Tanks with Farm Ambien bund walls t & used in liquid in closed
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circuit.
159 Acetonitri 15 10 82 ‐45 Drum Atm & Spilage Bund wall le / R.M. Ambien provided Wareh t ouse
160 Hexafluor 5 5 ‐ ‐153 Appro 7 Kg & Leackgag Separate o 29.4 ved Ambien e approved
Propylene Gas t storage & is Gas Storag handled in e Area close circuit with emergency kit and appropriate PPE provided.
161 Sodium 15 10 300 127 Solid Atm & Spillage PPE Methoxid R.M. Ambien Provided
e Storag t e
162 4 CHLORO 10 5 Solid Atm & Spillage PPE 2 NITRO R.M. Ambien Provided DIPHENYL Storag t AMINE e 163 THIOPHO 15 10 Solid Atm & Spillage PPE SPHORIC R.M. Ambien Provided TRI (4 Storag t
NITROPH e ENYL) ESTER (NITRO
RF)(90%)
164 4 NITRO 15 10 147 Solid Atm & Spillage PPE BENZONI R.M. Ambien Provided TRILE Storag t e
165 1,5 15 10 216 Solid Atm & Spillage PPE DINITRO R.M. Ambien Provided NAPHTHA Storag t LENE e
166 1,8 15 10 205 Solid Atm & Spillage PPE DINITRO R.M. Ambien Provided NAPHTHA Storag t LENE e
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167 Sodium 10 5 52 Solid Atm & Spillage PPE Dithionat R.M. Ambien Provided e Storag t e
168 Hydrazine 114 2 Tank Atm & Spillage Tanks with
Hydrate Farm Ambien bund walls t & used in liquid in closed
circuit.
169 Resorcino 15 10 277 110 Solid Atm & Spillage PPE l R.M. Ambien Provided Storag t e
170 BenzoTric 220. ‐5 hloride 8
171 3 AMINO 15 10 290 98 Solid Atm & Spillage PPE ACETOPH R.M. Ambien Provided ENONE Storag t e 172 2,4 210 43 Dichloro Phenol
173 Monochlo 15 10 189. 63 Solid Atm & Spillage PPE ro Acetic 3 R.M. Ambien Provided
Acid Storag t e
174 2 Amino 10 5 Solid Atm & Spillage PPE 3,4 R.M. Ambien Provided Dichloro Storag t Nitro e Benzene
175 Solvent 189 19 Tank Atm & Spillage Tanks with DMSO Farm Ambien bund walls
t & used in liquid in closed circuit.
176 FHIA 15 10 Solid Atm & Spillage PPE R.M. Ambien Provided Storag t
e
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177 DICHLOR 15 10 39.6 ‐96.7 Explosi Atm & Fire & Separate O ve Ambien Explosio approved METHANE Tank t n explosive Farm storage area, Proper earthing lightening
arrestor & FFE
178 DIMETHY 15 10 90 4 Tank Atm & Spillage Tanks with L Farm Ambien bund walls CARBONA t & used in TE liquid in
closed circuit.
179 MSTT
180 DichloroN 15 10 195 Solid Atm & Spillage PPE aphthaqui R.M. Ambien Provided
none Storag t e
181 Hexane 25 20 68 ‐94 Explosi Atm & Fire & Separate ve Ambien Explosio approved Tank t n explosive Farm storage area, Proper earthing lightening arrestor & FFE
182 CM Acid 15 10 Drum Atm & Spilage Bund wall Chloride / R.M. Ambien provided
Wareh t ouse
183 Sodium 10 8 1496 563. Isolate Highly Splilage Separate Cyanide 7 d oxic approved Appro storage ved area, with Stoora bund wall
ge .Adequate neutrilising media. PPE provided
184 CM Acid Drum Atm & Spilage Bund wall Bromide ( / R.M. Ambien provided DELTA) Wareh t
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ouse
185 Sodium 25 20 Tank Atm & Spillage Tanks with Hypochlor Farm Ambien bund walls ide t & used in liquid in
closed circuit.
186 Floro CM Drum Atm & Spilage Bund wall Acid / R.M. Ambien provided Chloride Wareh t ouse 187 m‐TOLUIC 15 10 263 113 Solid Atm & Spillage PPE ACID R.M. Ambien Provided Storag t
e
188 Dietyl
Amine
189 ALPHA 15 10 301 50 Solid Atm & Spillage PPE NAPHTHY R.M. Ambien Provided LAMINE Storag t e
190 M‐ 50 40 139 ‐48 Tank Atm & Tanks with XYLENE Farm Ambien bund walls t & used in liquid in
closed circuit.
191 Benzalde 25 20 178. ‐26 Tank Atm & Spillage Tanks with hyde 1 Farm Ambien bund walls t & used in liquid in closed
circuit.
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(vii) Resource optimization/ recycling and reuse envisaged in the project , if any , should briefly outlined :
Resource optimization/recycling and reuse envisaged in the project (Solvent recovery system & Reverse Osmosis Plant ) in detail are as mentioned below: • Average 91 m3/day of RO treated waste water will be recycled to minimize the fresh water consumption.
• The raw materials will be stored in closed containers and will be handled through closed system to avoid the handling losses.
• The Reactor shall be connected to an efficient condenser system with cooling/chilling water/brine circulation.
• Reactor and solvent handling pumps shall have mechanical seals to prevent leakages. Also provide with breather valve to prevent losses.
• Solvent will be taken from storage tank to reactors through closed pipe line. Storage tank shall be vented through trap receiver & condenser operated on cooling water.
• The condensers shall be provided with sufficient HTA and residence time so as to prevent any loss of solvent.
• Proper earthing shall be provided were ever solvent handling is done.
• Entire plant is flameproof.
• Solvent will be stored as per statutory requirement. Solvent will be kept at a separate specified area with all the safety measures.
• Hydrogen chloride gas will be scrubbed in efficient scrubbing system to get 30% HCl and which will be utilized for the manufacture of calcium chloride a valuable product.
• Details of solvent used, recovered & recycled as under;
Solvent Consumption MT/MONTH Recovered % Loss MT/MONTH Monochloro Benzene 1133.7 1098.56 3.1
Ethylene Dichloride 3070.51 2972.25 3.2
METHANOL 3079.56 2993.33 2.8
ORTHO DICHLORO BENZENE 1043.86 1013.59 2.9
TOLUENE 1566.53 1520.32 2.95
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Mixed Xylene 300.00 291.00 3
DMF 492.07 476.82 3.1
Tetra hydro Furan 420 405.72 3.4
XYLENE 683.33 659.41 3.5
MTBE 372.92 360.61 3.3
ACETONE 134.72 131.09 2.7
DMSO 90.00 87.75 2.5
ETHANOL 80.85 78.59 2.8
Hexane 580.28 562.87 3
(viii) Availability of water its source, Energy/power requirement and source should be given : Availability of water its source, Energy/power required and its source is below. Water withdrawal permission is attached as Annexure‐4. WATER CONSUMPTION (M3/DAY)
Sr. Particulars WATER CONSUMPTION, Effluent Generation, No. M3/DAY M3/day 1.0 Domestic 10.0 10.0
2.0 Processing & washing 383.0 170.0
3.0 Floor/container Washing 20.0 20.0
4.0 Cooling Tower 700.0 70.0
5.0 Boiler 120.0 7.0
6.0 Tail Scrubber 5.0 5.0
7.0 Gardening 20.0 0
8.0 Total 1258.0 281.0
9.0 Total Industrial 1228.0 271.0
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10.0 Treatment in RO Plant ‐ 102.0
11.0 Treatment in solvent ‐ 169.0 extraction followed by solvent stripper ,MEE
12.0 Condensate from MEE to ‐ 151.0 primary, secondary & tertiary treatment
13.0 Recycled to process from RO 91.0 ‐ permeate
14.0 Net Fresh water 1167.0 ‐
15.0 Net discharge to drainage ‐ 151.0 line
Note:
• Water consumption & effluent generation worked out on maximum water consumption & effluent generated group of product.
WATER BALANCE DIAGRAM
Total Water Consumption: 1258 M3/day (Fresh: 1167 + Recycle from RO: 91 M3/Day)
Domestic: 10 Processing: 383 Cooling: 700 Boiler: 120 Washing: 20 Scrubber: 5 Gardening: 20
170 70 7 20 5
Collection tank: 170
Caustic Soda: 102 RO Plant: 102 RO Permeate: 0.25 MT/Day Neutralization tank 91 Recycle
Extracted solvent: Recovered ODCB: RO Rejection: 11 M3/day to MEE Solvent Extraction 14.8 M3/Day 14.6 MT/Day
Recovered Solvent: Solvent Stripper: 170 M3/day Distillation Holding tank: 151 M3/Day 0.3 MT/Day
Loss: 5.7 m3 MEE: 169.7 M3/Day Primary, Secondary & + 11 M3 from Tertiary Treatment Plant RO rejection=175.0 Recovered ODCB: Residue: 0.2 MT/Day 14.6 MT/Day
Incineration Treated effluent GIDC pipe line
Salt: 24 MT Condensate: 151 M3/day Arabian Sea
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ENERGY REQUIREMENT AND ITS SOURCE Sr. Particulars Proposed Source No. 1 Steam 35000 kgs./hrs. Proposed 20 TPH x 2 Nos requirement steam boiler + 20 lacs kcals/hr thermic fluid heater capacity of coal fired steam boiler
POWER REQUIREMENT AND ITS SOURCE Sr. Particulars proposed Source No. 1 Power –Electricity 2500 KVA Will be sourced from Dakshin requirement Gujarat Vij Co. Ltd/Torrent Energy Limited.
(ix) Quantity of waste to be generated ( liquid and solid) and scheme for their Management/disposal : Quantity of waste to be generated (liquid and solid) and scheme for their Management/ disposal is enclosed as Anneuxure‐7. (x) Schematic representations of the feasibility drawing which give information of EIA purpose: A schematic representations of the feasibility drawing is attached as Annexure‐ 10.
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4. Site Analysis (i) Connectivity : The project is located in Plot. No. Z/111/B, SEZ: II, Dahej industrial estate, Ta: Vagra, di: Bharuch, Gujarat which is very well connected to National Highway no.8, Western Railways. And the nearest air port (Surat) and port are 50 KM away from the project site by road. (ii) Land Form, Land use and Land ownership : The land is in the form of industrial shed owned by Gujarat Industrial Development Corporation.
(iii) Topography (along with map) : Topography map showing the elevation of study area is below. The catchment area of the proposed project site altitude is 35 m (a.m.s.l) consists of the near site is flat topped, highly dissected plateaus and dyke ridges running in a west to east direction. The Main River (Narmada) in the catchment area flows in incised meanders forming steep geomorphologically ‘V’ shaped valleys with steep sides. The entire catchment has a rectangular and trellis pattern of drainage depicting the influence of the structures on the drainage development. The piedmonts at the base of the steep plateaus and dyke ridges are covered with thin soils, which support agriculture in very few areas. The river valley, wherever flat, has good quality soil and is mostly cultivated based on the availability of water. The river valley fills with thick alluvium provides the only area for cultivation.
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Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
The command area of the proposed project is surrounded by moderately dissected plateaus and piedmont slopes. The slope of the land along the piedmont and the nature of flow of the streams. The Narmada River with tributaries in the piedmont slope area show parallel pattern, which are partly controlled by the lineaments. Along the river valley the flood plain consists of good quality soil, suitable for cultivation. The largest portion of the command area is the alluvial plain, which has been formed by the river Man. The alluvial plain is studded with number of residual hills with degraded forests. The river man in the command area also flows in straight channels, which shows that the river is structurally controlled. Topography map showing the elevation of the study area below. The topographical map is enclosed as Annexure‐8. (iv) Existing land use pattern (agriculture, non‐agriculture, forest , water bodied ( including area under CRZ)), shortest distances from the periphery of the project to periphery of the forest, national park, wild life sanctuary , eco sensitive areas, water bodies (distance from the HFL of the river), CRZ . In case of notified industrial area, a copy of Gazette notification should be given : The proposed project to be located at SEZ:II, Dahej, Ta: Vagra, Di: Bharuch. Copy of plot allotment letter is enclosed herewith as Annexure‐9. The existing land use pattern are as under; Area Statistics of Land use / Land cover Map
Area (In Sr. No. Class Names Area (In Sq.Km.) Area % Hectares)
1 Water Body 1363.73 13.64 4.34
2 Open/Barren Land 5076.01 50.76 16.17
3 Agriculture Land 1159.56 11.60 3.69
4 Fallow Land 6291.40 62.91 20.04
5 Open/Degraded Vegetation 412.59 4.13 1.31
6 Vegetation Medium Density 397.40 3.97 1.27
7 River & Canal 23.25 0.23 0.07
8 Marshy Land 919.33 9.19 2.93
9 Salt Affected Land 128.45 1.28 0.41
10 Settlement & Habitation 324.50 3.25 1.03
11 Mud Flat 863.17 8.63 2.75
12 Jetty 32.91 0.33 0.10
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13 Salt Pans 2083.03 20.83 6.63
14 Mangrove(Sparse) 117.30 1.17 0.37
15 Mangrove(Dense) 223.00 2.23 0.71
16 Marshy Vegetation 46.55 0.47 0.15
17 Industrial Area 290.32 2.90 0.92
18 Sea 11589.46 115.89 36.91
19 Seasonal Water Body 59.04 0.59 0.19
Total 31400.99 314.01 100.00
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(v) Existing Infrastructure : The proposed project to be located in SEZ: II, Dahez notified industrial area of Dahej has the entire available infrastructure like water, electricity, roads, rail, transportation, availability of raw material and drainage system. (vi) Soil classification : Soil Characteristics under Project Area are as below Table;
CATEGORY AREA_SQ KM DESCRIPTION TAXONO TAXONO CLASS SUB_ MY1 MY2 CLASS
A 88.93 Very deep, Fine, Fine, Soils of Soils moderately montmori montmor west of well drained, llonitic illonitic coast alluvi calcareous, (calcareou (calcareo (soils of al fine soils on s), us) Gujarat plains very gently hyperther hyperthe plain) sloping mic Typic rmic Udic alluvial plain Chromust Chromus with slight erts ters erosion and moderate salinity; associated with very deep moderately well drained, calcareous, fine soils with moderate erosion.
C 108.64 Very deep, Fine‐ Fine, Soils of Soils poorly loamy, mixed west of drained, mixed (calcareo coast coast calcareous (calcareou us), (soils of al fine‐loamy s), hyperthe Gujarat plains soils on very hyperther rmic plain) gently sloping mic Aeric Typic coastal plain Haplaque Halaque with pts pts moderate erosion and strong salinity; associated with very
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Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
deep , imperfectly drained, calcareous, fine soils with severe erosion and strong salinity.
‐ 116.43 Sea ‐‐‐ ‐
(Courtesy: Environmental Information Centre, New Delhi)
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(vii) Climate data from secondary sources : Climatic data from secondary sources will be incorporated in EIA Study.
(viii) Social Infrastructure available : A) Natural Resource Management – The main focus of this program will be to maximize the yield returns of the farmers through efficient management of existing resources & extension of new agricultural practices.
1) Integrated Agricultural Growth Project – For improvement and use of the modern techniques and thereby would certainly contribute to prosperity in the agriculture sector and reduce the rural poverty by programs like Farmers Training, Nursery Growing Trainings, Modern agriculture equipment distribution programs etc. 2) Animal Husbandry Projects – Various programs like health checkups & treatment, vaccination program, Anti sterility camps, breed improvement etc. will be carried out. B) Income Generation Program ‐
1) Establishment of Self help groups. 2) Rural Entrepreneurship Development Program 3) Handcrafts Development Program 4) Vocational Training 5) Business process outsourcing C) Health, Education & Infrastructure
1) Aids Awareness Program 2) General Health Camps 3) Innovative Teaching Methods 4) Adult Education 5) Sanitation 6) Infrastructure Development Projects
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5. Planning Brief : (i) Planning Concept ( Type of industries, facilities, transportation etc) Town and Country Planning /Development authority Classification : Type of Industry: Proposed Agro Chemical & Organic Intermediates Unit There is a cluster of numerous large‐scale & medium‐scale industries, engaged in manufacture of variety of products, for example pharmaceuticals, dyes and chemicals, specialilty chemicals, pesticides and others in the Gujarat Industrial Development Corporation (GIDC) of Dahej.
(ii) Population Projection : Name Population Population Sex ratio (Persons) Density (No. of females per (Person / sq. 1000 males) km.)
Within 5 km Radius 13674 174 797 (1991)
Within 10 km Radius 21790 69 855 (1991)
68874 80 927 Taluka Vagra (1991)
82569 94 916 Taluka Vagra (2001)
District Bharuch (1991) 1546145 171 931
District Bharuch (2001) 1370104 210 920
(iii) Land use Planning (breakup along with green belt etc) : The proposed project to be located within the SEZ:II, GIDC Dahej Industrial Area by Government of Gujarat and due to the proposed project there will not be any change in the land use pattern of the region. Proposed Green belt planning in the project area is as below. For Green Belt Development as per the layout plan, the company proposes 18614 sq. meter (33%) green belt of the total land, i.e. 53449 sq. meters. The company shall develop green belt along the periphery of the proposed site and in common premises available outside the company premises.
While selecting the plants species to be grown in the green belt zone, following points will be taken into account:
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1. Climatic condition and soil characteristics of the region. 2. The air pollution emitted by the industry – gaseous and particulate matter. Plant interaction with both gaseous and particulate pollutants and to a great extent absorbs them and thus, removes them from the atmosphere. 3. Characteristics of plants including shapes of crowns considered necessary for effective absorption of pollutant gases and removal of dust particles. 4. Height of the plants should not be too high to be lethal. 5. For absorbance of gases, the duration of the foliage should be longer. 6. Vegetation controls soil erosion rates significantly. The decrease of water erosion rates with increasing vegetation cover is exponential. This review reveals that the decrease in water erosion rates with increasing root mass is also exponential. Plant species having good root system are selected, so that soil erosion can be checked.
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Site plan with Area table
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Area Table
Sr. No Particulars Area in m2
1 Total plot area 53449
2 Production plant 3105 3 Boiler & coal storage 1040 4 Other utilities 2370 5 Solid Raw material storage 440 6 Finished product storage 940 7 Gas storage 700 8 Solvent tank farm 1075 9 Liquid Raw material storage 980 10 ETP/MEE/Incineration & Solid waste 3230 storage 11 Plantation 18614 12 Common Plot 3480 13 Weigh bridge, Parking & Security area 5476 14 Office & Admn 800 15 Laboratory 480 16 Internal road 9714 17 Scrap Yard 1005 Total 53449
(iv) Assessment of Infrastructure demand ( Physical & Social) : • Employment would be as per prevailing norms of state government for skilled and unskilled people for the proposed project activity.
• Social Welfare
• Cordial relation with the industry shall be established and representation shall be made to villagers for help for creation of facilities related to health, education, etc.
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(v) Amenities/ Facilities : Details of amenities available in study area are as under;
Village Educatio Medica Drin Post & Commu Approach Nearest Power Taluka nal l king nication Wat Telegrap to Village Town Supply er h
Vagra Galenda P(2),Ac, RP,CH T,W, PO BS PR,KR Bharuch EA O W TK
Samatpo P(2),Ac RP,CH W,T ‐(‐5 Kms) BS PR,KR Bharuch EA r W K
Vav P(2),Ac RP,CH T,W, ‐(‐5 Kms) BS,RS PR,KR Bharuch EA W TK,H P
Jolva P(2),Ac, PHS,FP W,T ‐(‐5 Kms) BS,NW PR,KR Bharuch EA O C,RP,C K HW
Vadadla P(2),Ac CHW W,T PO BS PR,KR Bharuch EA K
Dahej P(4),H,A PHC,D, T,W, PTO, BS,RS,N PR,KR Bharuch EA c(4),O FPC,RP, TK W Phone CHW
Lakhiga P(2) PHS,RP W,T po BS,NW PR,KR Bharuch EA m ,CHW K
Luvara P(2),Ac RP,CH W,T ‐(‐5 Kms) BS,NW PR,KR,NR Bharuch EA W K
Jageshw P(2),Ac, RP,CH W,T PO BS,NW PR,KR,NR Bharuch EA ar H W K
Ambhet P(2),Ac CHW T,W, PO BS,NW KR,NR Bharuch EA a TK
Suva P(2),Ac ‐(5‐10 W,T ‐(‐5 Kms) BS,NW PR,KR,NR Bharuch EA Kms) K,R
Rahiad P(2),Ac(2 RP,CH W,T PO BS,NW PR,KR.NR Bharuch EA ),O W K
Harinaga Un r inha bite d
Padariya P(2),Ac RP,CH W,T PO BS PR,KR Amod EA W K
Kadodar P(2),Ac(2 PHS,FP W,T PO BS PR,KR Bharuch EA a ),H C, K RP,CH W
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Sambhet P(2),Ac ‐ W,T PO BS,RS PR,KR Bharuch EA i (10+Km K s)
ABBREVIATIONS
1. Education
P‐Primary Elementary School H‐Matriculation or Secondary
O‐Other Educational Institution
PUC‐Higher Secondary/Intermediate/pre‐University/junior Collage AC – Adult literacy class
TR – Training center
2. Medical Facilities
RP‐Registered Private Practitioner PHS‐Primary Health Centre
FPC‐Family Planning Centre
D‐ Dispensary
CHW ‐ Community Health Worker/Health Worker H ‐ Hospital
NH ‐ Nursing Home
MH ‐ Maternity Home
PHC ‐ Public Health Centre
CWC ‐ Child Welfare Centre
TB ‐ T.B Clinic
O ‐ Others 3. Drinking Water T‐Tap Water HP‐Hand Pump TK‐Tank Water W‐Well Water
R‐River Water
C‐Canal
N ‐ Nallah
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S ‐ Spring 4. Post & Telegraph PO‐Post Office PTO‐Post & Telegraph Phone‐Telephone Communication 5. Transportation
RS‐ Railway Station
BS‐Bus Station
NW‐Navigable Waterway
6. Approach to Village
PR‐Pucca Road
KR‐Kuccha Road
7. Power Supply
EA‐Electricity for all purposes
EAG ‐ Electricity for Agriculture ED ‐ Electricity for domestic EO ‐ Electricity for other purpose like Industrial, Commercial etc. 6. Proposed Infrastructure : (i) Industrial Area (Processing Area). The proposed infrastructure to manufacture products will be built with standard engineering design considering all the relevant parameters related to environment, health and safety. (ii) Residential Area (Non Processing Area) : No residential area is involved in the proposed project (iii) Green Belt : Green belt will be provided and maintained at the tune of 33 % of the total land area. (iv) Social Infrastructure : • Water Supply by GIDC • Power supply by TEL/DGVCL
(v) Connectivity (Traffic and Transportation Road/ Rail/ Metro/ Water ways etc) : The project site is very well connected by road through National Highway no. 8, railways. Major factors involved in the selection of site are listed below:
• Site is very well connected by road • Proximity to Raw Material suppliers • Availability of sufficient land free from cultivation and will have single crop
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pattern • Availability of power facilities • Availability of water for industrial use
(vi) Drinking Water management ( Source & Supply of water ) : Source of water is from GIDC water supply services. (vii) Sewerage System : GIDC has provided sewerage system to dispose the sewage effluent.
(viii) Industrial Waste Management :
• Industrial liquid effluent generation during the manufacturing of proposed products will be treated and discharge into treated effluent drainage line laid down by GIDC for ultimate disposal into Arabian Sea. • Generated domestic liquid waste is being disposed off through soak pit system to drainage.
(ix) Solid Waste Management : No Type of waste Category Qty. MT/ Treatment Disposal month
1 ETP waste (34.3) 34.3 27 Dried, packed Dispose off in bags into TSDF, BEIL, Ankleshwar & SEPPL, Dahej & Kutch 2 ETP waste & salt 34.3 598 Dried, packed Dispose off from MEE (34.3) in bags into TSDF, BEIL, Ankleshwar & SEPPL, Dahej & Kutch 3 Used Oil (5.1) 5.1 0.2 Packed in sell to carboys registered recycler 4 Discarded containers 33.3 2.0 De‐ Sell to (33.3) contaminate authorized d, stored recycler 5 Process waste 29.1 845 Packed in Dispose off (Inorganic) bags into TSDF, BEIL, Ankleshwar & SEPPL, Dahej & Kutch 6 Distillation residue 29.1 609 Packed in Sent for co‐ drums processing or New Project: Page 100 Manufacturing: Agro Chemicals & Organic Int.
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sent to SEPPL, Dahej & Kutch for incineration 7 Spent carbon 35.3 0.8 Packed in Sent for co‐ drums/bags processing or sent to SEPPL, Dahej & Kutch for incineration 8 Spent Catalyst 35.2 1.0 Packed in Sent for co‐ drum processing or TSDF BEIL, Ankleshwar & SEPPL, Dahej & Kutch 9 Used rubber hand X‐08 0.2 Packed in Sent for gloves/pipes etc drums/bags incineration to SEPPL, Dahej & Kutch 11 Iron sludge 26.1 231 Packed in Sent for co‐ drums/bags processing or TSDF BEIL, Ankleshwar & SEPPL, Dahej & Kutch 12 Date expired/off 29.3 1.0 Packed in Sent for specification drums/bags incineration pesticide 13 Fly ash ‐ 310 Packed in Sell to brick covered truck manufacturer
(x) Power Requirement & Supply / Source : Power requirement for proposed project will be taken from TEL/DGVCL.
7. Rehabilitation and Resettlement (R&R) Plan: (i) Policy to be adopted (Central/ State) in respect of the project affected persons including home oustees, land oustees and landless laborers (a brief outline to be given): There is no habitation on the proposed project activity area and it is barren land, so R & R policy is not applicable to this project.
There shall not be displacement of any population in project area. Any major activity that may lead to resettlement of the people is considered as permanent impact. Hence, there is no permanent impact on this account. The increasing industrial activity will boost the commercial and economical status of the locality up to some extent.
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8. Project Schedule & Cost Estimates : (i) Likely date of start of construction and likely date of completion ( Time schedule for the project to be given ) : After obtaining Environmental clearance and Consent to Establish from GPCB, the company shall start the proposed construction and commissioning of the proposed project.
(ii) Estimated project cost along with analysis in terms of economic viability of the project: Estimated project cost along with the analysis in terms of economic viability of the project is given as below;
Plant & Machinery, Pipeline & Fittings, Electrical Installation, Safety systems, etc. are the major heads considered in the Capital Cost Projection for the proposed project. Environment Protection has also been considered in planning the Cost Projection, which will include Green belt development, safety systems, etc.
CAPITAL COST PROJECTION
Sr. No. Particulars Cost in Rs.(Lacs) 1 Land app. 53000 Sq. meters 750 2 Building 800 3 Plant & Machinery 3.1 Equipment & machineries 1660 3.2 Pipes & fittings 1550 3.3 Utilities 600 4 Environmental Management 1065 System 5 Total Project Cost 6425 6 Utilities 6.1 Boiler, kgs/hr 20000 x 2 6.2 Thermic fluid heater 20 lacs kcals/hr 6.3 Cooling Tower, TR 4000 6.4 Chilling plant, TR 500 6.4 D.G. Set (Standby), KVA 2500 7 Power from TEL/DGVCL, KVA 2500 8 Fuel 8.1 Coal, kgs/hr 8600 8.2 HSD, kgs/hr 250 9 Water from GIDC KL/day 1258 Waste Water Generation 10 272 (Industrial) KL/day Waste Water Disposal 11 151 (Industrial) KL/day New Project: Page 102 Manufacturing: Agro Chemicals & Organic Int.
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PROJECT VIABILITY
Sr. No. PARTICULARS AMOUNT IN Cr./Year 1 Proposed Sale 153.96 2 Raw Material Cost 75 3 Power & Fuel 16 4 Labor Cost 8.4 5 Environmental Management System 17.37 6 Maintenance Cost 4 7 Selling, packing & Office Expenses 20 8 Proposed Profit 13.19
The company will provide budgetary provision for the recurring expenses for environmental issues while planning the allocation of funds during the annual budgetary planning.
Recurring Cost per annum Proposed (Rs. In Sr. No. Component Lacs/annum 1. Environment & Safety Management System 400 2. Greenbelt Maintenance 94
3. Solid waste Disposal 1243 Total 1737
9. Analysis of Proposal ( Final Recommendations): (i) Financial and social benefits with special emphasis on the befit to the local people including tribal population, if any, in the area: Proposed project activity will provide benefits to the local people in terms of financial and social welfare. • Local people will get direct financial benefit by way of employment. • Local people will get some contracts of supply and services to get indirect income. • Company will contribute in improving education and health facilities in nearby area.
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ANNEXURESANNEXURES
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ANNEXURE‐1 The map showing general location, specific location and project boundary and project site layout of M/s. Yashashvi Rasayan Pvt. Limited, located at Plot. No. Z/111/B, SEZ: II, Dahej industrial estate, Ta: Vagra, di: Bharuch, Gujarat. The location of the project site can be viewed in Figure 1.1
Fig. 1.1: Location map showing the Project site
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ANNEXURE: 2 Site Layout Plan
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Area Table
1 Total plot area 53449
2 Production plant 3105 3 Boiler & coal storage 1040 4 Other utilities 2370 5 Solid Raw material storage 440 6 Finished product storage 940 7 Gas storage 700 8 Solvent tank farm 1075 9 Liquid Raw material storage 980 10 ETP/MEE/Incineration & Solid waste 3230 storage 11 Plantation 18614 12 Common Plot 3480 13 Weigh bridge, Parking & Security area 5476 14 Office & Admn 800 15 Laboratory 480 16 Internal road 9714 17 Scrap Yard 1005 Total 53449
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ANNEXURE‐3
Detailed project description with process details ‐ MANUFACTURING PROCESS The company is using the latest available process technology for the production. This chapter includes the manufacturing process flow diagram of the product, chemical reactions, and material mass balance for the product.
(1.2) 1:2:4 & 1:2;3 TRI CHLORO BENZENE
Cl Cl Cl Cl + 3 Cl 2 + + 3 HCl Cl Benzene (78) Chlorine( 213) Cl 1:2:4 TCB (181.5) 1:2:4 TCB (181.5)
Benzene: 444 kgs Chlorine: 1174 kgs HCl (30‐33%): 2012 kgs Recovered DiChloro Benzene:250 kgs CHLORINATION Water for HCl: 1407 kgs Benzene loss: 10 kgs
Distillation Residue: 3 kgs DISTILLATION Recovery of Di Chloro Benzene: 250 kgs
1:2:4 TCB: 750 kgs 1:2:3 TCB: 250 kgs
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(2.1) CALCIUM CHLORIDE
CaCO + 2 HCl 3 CaCl2 + H2O + CO2
Calcium Carbonate Hydro Chloric Acid Calcium chloride Water Carbon dioxide (100) (73) (111) (18) (44)
Calcium Carbonate:950 kgs Carbon dioxide Liquid: 339 kgs Hydro Chloric acid: 2080 kgs REACTOR Carbon Dioxide gas: 37 kgs
Lime: 10 kgs Alkaline sludge: 135 kgs Water: 90 kgs NEUTRALIZER
FBG WaterEvaporation: 1619 kgs
Calcium Chloride: 1000 kgs
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(3.1) 3 CHLORO NITRO BENZENE
NO2 NO2
FeCl3 + HCl + Cl2 Cl
Nitro Benzene (123) Chlorine (71) 3-Chloro Nitro Hydro Chloric acid (36.5) benzene (157.5)
Nitro Benzene: 865 kgs Chlorine: 475 kgs Recovered nitro benzene: 835 kgs CHLORINATION HCl (30‐33%): 760 kgs Ferricchloride: 15 kgs Water for HCL: 520 kgs
Water: 500 kgs DUMPING Waste water: 515 kgs
Sodaash: 20 kgs WASHING Water for washing: 1000 kgs Waste water: 1020 kgs
RecoveredNitroBenzene: 835 kgs DISTILLATION Tarry waste: 100 kgs
3CHLORO NITRO BENZENE: 1000 kgs
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(4.1) N ‐ VALEROYL CHLORIDE
O O
EDC/Catalyst H C H C SO HCl 3 C + SOCl2 3 C + 2 + OH Cl Valeric acid (102) Thionyl Chloride (119) Valeroyl Chloride (120.5) (64) (36.5)
SO2 + 2 NaOH Na2SO3 + H2O (64) (80) (126) (18)
Valeric acid: 860 kgs Thionyl Chloride: 1025 kgs Ethylene Di Chloride: 2000 kgs Catalyst: 10 kgs HCl (30‐33%): 1010 kgs CHLORINATION Water for HCl: 708 kgs Sodium sulphite solution (20%): 4980 kgs 48% Caustic lye: 1390 kgs Water for 15% NaOH: 3060 kgs EDC Recovered: 1950 kgs DISTILLATION EDC loss: 50 kgs Tarry Waste: 63 kgs
N‐ VALEROYL CHLORIDE: 1000 kgs
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(5.2) 1:3:5 TRI CHLORO BENZENE
NH3HSO4 NH2 Cl Cl Cl Cl
+ H2SO4
Cl Cl 2:4:6 TCA (196.5) (98) 2:4:6 TCA sulphate( 294.5)
O NH3HSO4 N=N-HSO4 Cl Cl Cl Cl HO - S - NO + 2 + H2SO4 + H2O
Cl O Cl (2:4:6 TCA sulphate) (294.5) NSA (127) Diazo of TCA (305.5)
N=N-HSO4 Cl Cl Cl Cl HCHO H O + + 2 + H2SO4 + HCOOH + N2
Cl Cl Diazo of TCA (305.5) (30) (18) 1:3:5 TCA (181.5) (98) (46) (28)
(5.2) 1:3:5 TRI CHLORO BENZENE
2:4:6 TCA: 1270 kgs NitrosylSulphuricacid:2105 kgs DIAZOTIZATION
Water for decomposition: 1077 kgs HYDROLYSIS Spentacid (50‐55%): 7421 kgs Formaldehyde: 3745 kgs
Water for washing: 1793 kgs LAYER Waste water: 2102 kgs Sodaash: 24 kgs SEPARATION
DISTILLATION Tarrywaste: 124 kgs
1:3:5 TCB: 1000 kgs
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(6.1) ORTHO & PARA NITRO CUMENE
H2SO4 NO + 2 + H2O
Cumene (120) (63) NO2 O- Nitro Cumene P- Nitro Cumene (165) (165)
Cumene: 4800 kgs Spent sulphuric acid: 11200 kgs Nitric Acid (60%): 4600 kgs NITRATOR SulphuricAcid (98%): 8400 kgs Nitro Mass: 6600 kgs
Nitro Mass: 6600 kgs WASHING LAYER Effluent: 5000 kgs Tarry Waste: 300 kgs Water: 4900 kgs SEPARATION Soda ash: 100 kgs
O‐NITRO CUMENE: 1800 kgs P‐ NITRO CUMENE: 4500 kgs
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(7.23) 3: 5 DI AMINO BENZOIC ACID
COOH COOH
Catalyst 4H O + 6 H2 + 2
O2N NO2 H2N NH2
3:5 Di Nitro Benzoic acid (212) 3:5 Di Amino Benzoic acid (152)
3:5 Di Nitro Benzoic Acid: 2000 kgs Hydrogen loss: 11.32 kgs Hydrogen: 124.53 kgs HYDROGENATION Catalyst:23.8 kgs Catalyst recovered: 23.80 kgs
Nitro Mass: 6600 kgs Water: 4900 kgs DISTILLATION Effluent: 679.25 kgs Soda ash: 100 kgs Tarry Waste: 33.96 kgs
3,5 DI AMINO BENZOIC ACID: 1400 kgs
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(8.7) 2,3 DI CHLORO ANISOLE
OH OMe
Cl Cl 2 + (CH3)2SO4 + 2 NaOH 2 + Na SO + 2H O Cl Cl 2 4 2
2,3 DCP (326) DMS (126) (80) 2,3 DCA (354) (142) (18)
2,3 Di Chloro Phenol: 1020 kgs Di MethylSulphate: 410 kgs Sodiumhydroxide:260 kgs METHYLATION Sodium sulphate solution (20%): 2220 kgs Water: 1666 kgs Mono Chloro Benzene: 1800 kgs
Water: 500 kgs WASHING Effluent: 500 kgs
SOLVENT RECOVERY Recovered Mono Chloro Benzene: 1750 kgs Solventloss:50 kgs
DISTILLATION Tarrywaste: 134 kgs
2:3 DI CHLORO ANISOLE: 1000 KGS
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(9.1) 2:4 DI CHLORO ACETO PHENONE
Cl COCH3 AlCl3/EDC Cl CH Cl + HCl + 3 Cl Cl (36.5) m-di Chloro Benzene Acetyl Chloride 2,4 Di Chloro acetophenone (147) (78.5) (189)
M‐ Di Chloro Benzene: 900 kgs Aluminum Chloride: 1180 kgs Ethylene Di Chloride: 2000 kgs ACETYLATION HCl 930‐33%): 745 kgs Acetyl Chloride: 485 kgs Water for HCl: 522 kgs
Water: 4720 kgs DUMPING Aluminum chloride soln : 4720 kgs
Water: 450 kgs WASHING Sodaash:50 kgs Effluent: 500 kgs
Tarrywaste: 45 kgs DISTILLATION EDC recovered: 1950 kgs EDC loss: 50 kgs Impurity for incineration: 117 kgs
2,4 DI CHLORO ACETOPHENONE: 1000 KGS
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(10.8) PROTHIOCONAZOLE Cl Cl Cl -CH - CH - CH 2 3 + Cl + OH
2 hydroxy propanyl chloride 1 chloro 1,2 di chloro benzene (147) cyclo propane (94.5) (76.5)
Cl N Cl NH C CH2 + N OH O
1 chloro cyclopropyl 3 (2-chloro 1,2 Di hydroxy 3H- 1,2,4 Triazole 3 phenyl) 2 hydroxy chloro propane thione (101) (281.5)
Cl N Cl N CH C CH2 2 + HCl N O OH
Prothioconazole (381.5) (36.5)
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(10.8) PROTHIOCONAZOLE
1,2 Di Chloro Benzene: 455 kgs Chloro Cyclo propane:236 kgs 2 Hydroxy propanylchloride:295 kgs REACTOR HCl (30%): 720 kgs Xylene: 2000 kgs Catalyst:10 kgs
2,4 Di hydro 1,2,4 triazole 5 REACTOR Aluminumchloride soln: 4720 kgs thione:315 kga
Water: 1000 kgs WASHING Effluent: 1059 kgs
Tarry waste: 32 kgs DISTILLATION Xylene recovered: 1960 kgs Xylene loss: 40 kgs
PROTHIOCONAZOLE: 1000 KGS
(11.7) 1,3 BIS (3 AMINO PHENOXY BENZENE)
NO2 Cl OH O
+ 2 NaCl H O 2 + + 2 Cl O NO2
NO 3 Nitro Phenol m- Di Chloro Benzene 1,3 Bis (3 Nitro 2 (139) Phenoxyl) (58.5) (18) (289.5) Benzene (352)
NO2 NH2 O O
4 Fe + + 8 H2O + 2 Fe2O3 + 6 H2O O (224) (144) O (320) (108) NO 1,3 Bis (3 Nitro 2 NH2 Phenoxyl) 1,3 Bis (3 Amino Benzene (352) Phenoxyl) Benzene (292) New Project: Page 119 Manufacturing: Agro Chemicals & Organic Int.
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(11.7) 1,3 BIS (3 AMINO PHENOXY BENZENE)
3Nitrophenol:1070kgs MDC:566 kgs ETHERIFICATION Distilled water: 140 kgs recycle SodiumHydroxide:314 kgs
ODCB: 1800 kgs SOLVENT EXTRACTION
FILTERATION Sodium chloride: 460 kgs
Iron powder:1180 kgs Water: 1000 kgs REDUCTION Acetic acid: 30 kgs Sodaash:23 kgs FILTERATION Iron sludge:2310 kgs Water recycle: 245 kgs DISTILLATION ODCB recovered: 1750 kgs ODCB loss: 50 kgs
Methanol: 2200 kgs PURIFICATION
CRYSTALIZATION 1:3, BIS (3 AMINO PHENOXYL) BENZENE
DISTILLATION Tarry waste: 28 kgs Methanol recovered: 2130 kgs Methanol loss: 70 kgs
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(12.1) ORTHO CHLORO PARA NITRO ANILINE
NO2 NO2
+ NH4Cl + 2H O + 2 NH4Cl 2 Cl Cl NH Cl 2 (53.5) (36) ( 70) 3,4 Di Chloro Ortho Chloro Nitro benzene (192) Para Nitro Aniline (172.5)
3:4 Di Chloro Nitro Benzene: 1200 kgs Recovered Ammonia: 4500 kgs AMINATION Recovery of ammonia: 4500 kgs Anhydrous ammonia:300 kgs
Water: 4000 kgs WASHING/FILTER Waste water: 4500 kgs ATION
ORTHO CHLORO PARA NITRO ANILINE: 1000 KGS
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(13.9 ) TBSA
NH 2 N=NCl NaNO2 + HCl NaCl + + + H2O CF3 CF3
SO Cl N=NCl 2 N2 + NaCl + NaHSO3 + HCl + CF3 CF3
SO2Cl
2NH SO2NH2 + 3 + H2O CF 3 + NH4Cl CF 3
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(13.9 ) TBSA
NH 2 N=NCl NaNO2 + HCl + + NaCl + H 2 O CF3 CF3
SO Cl N=NCl 2 N 2 + NaCl + NaHSO3 + HCl + CF3 CF3
SO2 Cl
SO2 NH2 + 2NH3 + H 2 O CF 3 + NH4 Cl
CF3
TFMA: 400 kgs HCl: 830 kgs SodiumNitrite:450 kgs REACTOR Nitrogen: 65 kgs SulphurDioxide:195 kgs Water: 9910 kgs
SEPARATOR Waste water: 11600 kgs
Ammonia: 400 kgs REACTOR
TBSA: 500 kgs
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(14.1) 2:4 D ACID STAGE: 1 OH OH Cl
+ 2Cl2 + 2HCl
Cl Phenol Chlorine 2, 4 ‐ DCP 94 71 163 STAGE: 2 OH OCH2COONa Cl Cl
+ ClCH2COOH + 2NaOH +2NaCl+ 2H2O
Cl Cl 2, 4 ‐ DCP Chloro Acetic Acid Caustic 2, 4 –D Na Sodium Chloride water 163 94.5 80 243 58.5 18 STAGE: 3
OCH2COONa OCH2COOH Cl Cl + HCl +NaCl
Cl Cl 2, 4 –D Na Hydrogen Chloride 2, 4 – Dichloro Phenoxy Acetic Acid Sodium Chloride 243 36.5 221 58.5
(14.1) 2:4 D ACID
HCl (g) to scrubber: 4430.16 kg Cl (g) to scrubber: 447.44 kg Phenol: 6000 kg 2 REACTION Cl2 (g): 9065 kg
MCA: 7600 kg 2, 4 DCP recovered: 723.7 kg Phenol recovered Caustic: 14065 kg Effluent to phenol recovery: 35941.99 kg REACTION : 223.64 kg Water: 20000 kg Eff. To ETP: 35718.35 kg
Water: 40000 kg PURIFICATION Eff. To ETP: 61544.55 kg HCl: 18787.88 kg
2, 4 –D Acid: 12430 kg
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(15.2) ALPHAMETHRIN ALPHAMETHRIN Stage ‐ 1
O
CCl2 CH2 CH CH COCl OHC NaCN
C H3CCH3
227.5 19 8 4 9 Cypermethric Acid chloride M et a Phenoxy B enzaldehyde Sodium Cyanide
Catalyst
OCNO
CCl2 CH2 CH CH C O CH NaCl
C H3CCH3
416 58.5
Cypermethrin Sodium Chloride
Stage ‐ 2
OCNO
CCl2 CH2 CH CH C O CH
C
H3CCH3
416
Cypermethrin
Epimerisation
O
CCl2 CH2 CH CH C O CH CN
C
H3CCH3
416
A lphamet hrin O
Detoxification of Cyanide by Hypo
NaCN NaOCl NaOCN NaCl
49 74.5 65 58.5
Sodium Cyanide Sodium Hypo Chloride Sodium Cynate Sodium Chloride
2 NaOCN 3 NaOCl NaCl N2 NaHCO3
65 74.5 58.5 28 84
Sodium Cynate Sodium Hypo Chloride Sodium Chloride Nitrogen Sodium Bicarbonate
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(15.2) ALPHAMETHRIN Process Flow Chart of Alphamethrin All quantities are in Kgs Hypo Chloride Sodium Cyanide 230 1500 Water 1065 Catalyst 20 2943 Stage ‐ 1 Cyanide Layer Soda Ash 20 1443Treatment Waste Water Cyper Reaction CMAC 900 Cyanide Layer MPB 720 n‐Hexane 2780 5735 4292 Organic mass ( N‐Hexane + Cyper)
Water 1500 20 Evaporation Loss Stage ‐ 2 1512 Waste Water Washing
5792 4260 Organic mass ( N‐Hexane + Cyper)
Water 2000 Stage ‐ 3 20 Evaporation Loss Washing 2000 Waste Water
6260 4240 Organic mass ( N‐Hexane + Cyper)
71 Evaporation Loss Stage ‐ 4 2669 R . N‐Hexane n‐Hexaqne recovery
1500 Organic mass
644 Tri‐ethyl Amine Tri‐ethyl Amine 700 4992 n‐ Hexane n‐ Hexane 5200Stage ‐ 5 228 Evoperation Loss Water 2630Epimerisation 2766 Water 10030
1400 Organic mass
Stage ‐ 6 400 ML Cyper Filteration
Stage ‐ 7 Drying
1000 Kg Alphamethrin
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(16.1) SODIUM NAPHTHIOATE
AlphaNaphthylamine:610 kgs Sulphuricacid: 560 kgs ODCB loss: 80 kgs ODCB: 2280 kgs REACTOR ODCB Recovered: 2200 kgs SodaAsh:292 kgs Reaction mass: 4422 kgs Water:3060 kgs Evaporation loss: 100 kgs
CENTRIFUGE Waste water: 3100 kgs Tarry waste: 82 kgs
SODIUM NAPHTHIONATE: 920 kgs
(17.1) META TOLUIC ACID M‐ Xylene : 300Kgs Catalyst: 12 Kgs REACTOR Hydrogen: 6 kgs Oxygen :90 Kgs Bromine : 0.578 Kgs Chlorine : 0.245 Kgs M‐ Xylene: 179 kgs recycle DISTILLATION Residue: 82 kgs
m‐ Toluic acid: 135 kgs: 1.0 Kgs
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(18.1) M‐PHENOXY BENZALDEHYDE
m‐Phenoxy Benzaldehyde reaction chemistry
Stage‐1 preparation of m‐Bromo Benzaldehyde
CHO CHO
Br2/Cl2 EDC AlCl3 Br Benzaldehyde m-Bromo benzaldehyde m.wt.=106 m.wt.=185
Stage‐2 preparation of acetal of m‐bromo Benzaldehyde
O CH2 CHO CH O CH2 + CH2OH PTSA + H2O CH2OH Br Br m-Bromo benzaldehyde Mono ethylene acetal of m-Bromo m.wt.=185 glycol Benzaldehyde M.wt.=62 M.wt.=229
Stage‐3 preparation of acetal of m‐ phenoxy Benzaldehyde
O CH2 O CH2 OH CH CH O CH2 KOH O CH2 + + KBr H2O Toluene + Br O Phenol M.wt.=94 acetal of m-Bromo Benzaldehyde M.wt.=229 acetal of m-Phenoxy benzaldeyhe M.wt.= 242
O CH2 CH O CH2 CHO
CH2OH O + Hydrolysis O CH2OH
Mono ethylene acetal of m-Phenoxy m-Phenoxy glycol benzaldeyhe M.wt.=62 M.wt.= 242 benzaldeyhe M.wt.= 198
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(18.1) M‐PHENOXY BENZALDEHYDE Water : 0.904 Kgs Ethylene dichloride :2.778 Kgs Preparation of Anhydrous AlCl3: 1.155 Kgs HCl : 0.251 Kgs Benzaldelyde :0.7 Kgs Bromo Br2: 0.05 Kgs HCl Scrubber Bromine : 0.578 Kgs Benzaldelyde Chlorine : 0.245 Kgs Reaction Mass : 5.155 Kgs 25% HCl Solution : 1.205 Kgs Formic Acid : 0.025 Kgs HCl (30%) : 0.121 Kgs Dumping in Aqueous Mass : 5.703 Kgs Water : 4.402 Kgs chilled Water Washing Aqueous Mass : 1.11 Water for Washing : 1.10 Kgs Sodiumthio sulphate : 0.011 Kgs Organic Mass : 4.0 Kgs EDC recover & recycle : 2.631 Kgs Cut‐1 : 0.045 Kgs Solvent Remove Residue : 0.105 Kgs Loss : 0.148 Kgs m‐ bromo Benzaldelyde : 1.071 Kgs Preparation of Water : 0.104 Kgs Ethylene glycol : 0.78 Kgs Acetyl of m‐ bromo MEG recover & recycle : 0.415 Kgs Benzaldelyde Loss : 0.006 Kgs Phenol : 0.582 Kgs Reaction Mass : 1.326 Kgs KOH flakes : 0.384 Kgs Preparation of Water : 0.111 Kgs Toluene : 1.448 Kgs m ‐Phenoxy Loss : 0.02 Kgs CuCl: 0.0055 Kgs Benzaldelyde Aqueous Mass : 2.083 Kgs Water : 1.241 Kgs C.S Lye : 0.02 Kgs Reaction Mass : 2.793Kgs Water : 1.090 Kgs Hydrolysis MEG recover & recycle : 0.345 Kgs H2SO4 5% Solution : 1.09 Kgs Reaction Mass : 2.448 Kgs Aqueous Mass : 0.44 Kgs Water Washing : 0.451 Kgs LayerSeparation&WaterWashing Loss : 0.012 Kgs
Organic Mass : 2.447 Kgs Toluene recover & recycle : 1.375 Kgs Loss : 0.019 Kgs Distillation Cut‐1 recycle : 0.03 Kgs Residue : 0.023 Kgs m‐ Phenoxy Benzaldelyde : 1.0 Kgs
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ANNEXURE‐4 Permission for withdrawal of fresh water from SEZ (Industrial estate)
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ANNEXURE‐5 Quantity of waste to be generated (liquid and solid) and scheme for their Management/disposal.
Quantity of Waste Water (liquid waste) generation and its management :
Sr. Particulars Effluent Generation, M3/day No. 1.0 Domestic 10.0
2.0 Processing & washing 170.0
3.0 Floor/container Washing 20.0
4.0 Cooling Tower 70.0
5.0 Boiler 7.0
6.0 Tail Scrubber 5.0
7.0 Total 282.0
8.0 Total Industrial 272.0
9.0 Treatment in RO Plant 102.0
10.0 Treatment in solvent extraction followed by 169.0 solvent stripper ,MEE
11.0 Condensate from MEE to primary, secondary 151.0 & tertiary treatment
12.0 Recycled to process from RO permeate ‐
13.0 Net Fresh water ‐
14.0 Net discharge to drainage line 151.0
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Note: • Water consumption & effluent generation to be worked out on maximum water consumption & effluent generation group of product . • Total water requirement will be 1258 m3/day which is met through GIDC water supply, out of which 91 m3/day of RO permeate will be recycled hence total 1167 m3/day of fresh water will required.
• Total Industrial wastewater generation will be 272 m3/day. Out of which about 170 m3/day of effluent generated from the process will be collected separately, neutralized, extracted in solvent to remove organics, stripped in solvent stripper filtered & finally taken to MEE. Balance 102 m3/day of normal effluent from cooling tower, boiler blow down, scrubber & floor/container washing will be treated in Reverse Osmosis plant. 11 m3/day of RO rejection will be taken to MEE and 91 m3/day of permeate will be recycled. Total 151 m3/day of condensate from MEE will be treated in primary, secondary & tertiary treatment plant & discharge into under ground effluent drainage line of GIDC for ultimate disposal into Arabian Sea.
• Domestic Waste water (10 m3/day) will be disposed by septic tank & soak pit. • About 24 MT/day of Salt from MEE will be disposed off into TSDF. 91 m3/day of RO permeate will be reused in the process
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ANNEXURE: 6
DETAILS OF PROPOSED EFFLUENT TREATMENT PLANT
Design Criteria :
• Product : Agro Chemicals & Organic intermediates • Source of Effluent : Process & Utilities • Design Flow of Effluent : 164 KL/day Max. • Design Parameters : As under • Effluent Characteristics:
Sr. Parameters Untreated Input to Output Rejected Input to Condensat Outlet of No. process RO from RO from RO MEE e from P/S/T effluent (pure MEE water) 1 pH 2‐2.5 6‐8 6‐8 6‐8 6‐8 6‐8 6‐8 2 Color pt. co 600 < 100 < 100 < 100 600 150‐200 < 100 3 Suspended 600‐800 <100 < 10 <100 200‐300 < 25 < 25 solids, mg/l 4 Total 120000‐150000 1000 < 50 9000‐ 120000‐ 800‐1000 < 2100 dissolved 10000 150000 solids, mg/l 5 Oil and 3‐4 ND ND ND 2‐3 < 1 < 1 grease, mg/l 6 NH3‐N, mg/l 30‐40 0 0 0 20‐30 20‐30 <50 7 BOD, mg/l 11000‐12000 < 30 < 30 < 30 900‐ 800‐900 < 100 1000 8 COD, mg/l 40000‐50000 < 100 < 100 < 100 3500‐ 3000‐3500 < 250 4500 9 Heavy metal, 0.1 ND ND ND 0.1 ND ND mg/l 10 Phenolic 12‐15 ND ND ND 3‐4 1‐2 < 1 compounds, mg/l
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Based on the above criteria Effluent Treatment Plant having under mentioned specification is required to install.
Process of normal effluent stream:
Industrial effluent is generated from various sources like ‐ Process, Washings, Boiler blow‐down, Cooling blow‐down and Others (scrubbed liquor,etc). It is segregated as per its characteristics into two streams, namely,
1) Concentrated stream (high TDS & COD) &
2) Normal stream (low TDS, low COD)
Concentrated Effluent Stream: Concentrated Stream is mainly from process having very high COD & TDS. It is collected in Collection Tanks, equalized / neutralized in Equalization / Neutralization tanks. Neutral effluent is then filtered to remove suspended solids as ETP Sludge (to be subsequently dried, packed in bags, stored & finally dispatched to approve Land‐fill site for disposal). After this Primary Treatment, the effluent is taken for solvent extraction to remove organics. Then extracted effluent is taken into solvent stripper. Recovered solvent is recycled in the process. Then effluent is taken into MEE followed by ATFD. Condensate from MEE is taken inti primary, secondary and tertiary effluent treatment plant and finally discharge into under ground effluent drainage line for ultimate disposal into Arabian Sea. MEE salt is dispose off into TSDF.
Normal Effluent Stream: It is mainly generated from Washings, Boiler blow‐down, Cooling blow‐down and others (scrubbed liquor, etc). It has low COD and low TDS level. It is collected in Collection Tanks, equalized / neutralized in Equalization / Neutralization tanks. Neutral effluent is then filtered to remove suspended solids as ETP Sludge (to be subsequently dried, packed in bags, stored & finally dispatched to approve Land‐ fill site for disposal). After this Primary Treatment, the effluent is passes through RO system. RO permeate is recycle back to the process and RO rejected is collected and taken into MEE.
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DETAILS OF PROPOSED EFFLUENT TREATMENT PLANT, MEE, RO & PRIMARY, SECONDARY & TERTIARY TREATMENT PLANT
Sr. Name of the unit Size in meter Nos Capacity MOC
No
1 Oil/Grease trap 1 x 1 x 1 1 1 RCC/TL
2 Collection cum equalization tank with air 6 x 6 x 4.5 1 162 RCC/TL sparger
3 Neutralization tank with stirrer 2 m dia x 3 m ht 3 30 RCC/TL
4 Chemical dosing tank 1 x 1 x 1 1 3 HDPE
5 Filter press 36 x 36 2 20 MT PP
6 Holding tank 6 x 6 x 4.5 1 162 RCC/TL
Solvent Extraction plant ‐ 1 30 SS/GL
7 MEE with ATFD ‐ 1 170 SS
7.1 Calandria‐ 1 0.656 X 8.44 1 170 KLD Ti‐clad
7.2 Calandria‐ 2 0.573 X 8.36 1 170 KLD Ti‐clad
7.3 Calandria‐ 3 0.473 X 8.36 1 170 KLD Ti‐clad
7.4 ATFD 0.866X 6.7 1 30 MTD SS 316
8 Holding tank for MEE condensate & RO 6 x 6 x 4.5 1 162 RCC/TL rejection
9 Reverse Osmosis plant ‐ 1 110 ‐
10 Holding tank for RO permeate 3 x 3 x 4.5 2 80 RCC
11 Neutralization tank with air sparger 2 m dia x 3 m ht 3 30 RCC/TL
12 Filter press 36 x 36 2 20 MT PP
13 Effluent transfer pump 10 HP & 5 HP 6 ‐ CI/PP
14 Aeration tank with diffuser 6 x 6 x 5 m 1 180 m3 RCC
15 Air Blower 15 HP 2 Nos 20 HP CI
16 Secondary settling tank 4 x 4 x 5 2 Nos 160 RCC
17 Holding tank 3 x 3 x 4.5 2 80 RCC
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18 Sand bed filter 3 m dia x 5 m 1 35 m3 MSRL ht.
19 Activated carbon filter 3 m dia x 5 m 1 35 m3 MSRL ht.
20 Final treated water guard pond 6 x 6 x 4.5 1 162
Stream wise effluent, Treatment & expected characteristics of effluent
Sr. Parameters Untreated process effluent Combined untreated effluent from No. boiler, cooling, washing & scrubber 1 pH 2‐2.5 6‐8 2 Color pt. co 600 < 100 3 Suspended solids, mg/l 600‐800 <100 4 Total dissolved solids, 120000‐150000 1000 mg/l 5 Oil and grease, mg/l 3‐4 ND 6 NH3‐N, mg/l 30‐40 0 7 BOD, mg/l 11000‐12000 < 30 8 COD, mg/l 40000‐50000 < 100 9 Heavy metal, mg/l 0.1 ND 10 Phenolic compounds, 12‐15 ND mg/l
Sr. Parameters Results No. Input of Evaporator Condensate from Evaporator 1 pH 6‐8 6‐8 2 Color pt. co 600 150‐200 3 Suspended solids, mg/l 200‐300 < 25 4 Total dissolved solids, mg/l 120000‐150000 800‐1000 5 Oil and grease, mg/l 2‐3 < 1
6 NH3‐N, mg/l 20‐30 20‐30 7 BOD, mg/l 900‐1000 800‐900 8 COD, mg/l 3500‐4500 3000‐3500 9 Heavy metal, mg/l 0.1 ND 10 Phenolic compounds, mg/l 3‐4 1‐2
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Sr. Parameters Combined untreated No. normal effluent 1 pH 6‐8 2 Color pt. co < 100 3 Suspended solids, mg/l <100 4 Total dissolved solids, mg/l 1000 5 Oil and grease, mg/l ND 6 NH3‐N, mg/l 0 7 BOD, mg/l < 30 8 COD, mg/l < 100 9 Heavy metal, mg/l ND 10 Phenolic compounds, mg/l ND
Sr. Parameters Input to RO Permeate of Rejection from RO No. RO 1 pH 6‐8 6‐8 6‐8 2 Color pt. co < 100 < 100 < 100 3 Suspended solids, mg/l <100 < 10 <100 4 Total dissolved solids, 1000 < 50 9000‐10000 mg/l 5 Oil and grease, mg/l ND ND ND 6 NH3‐N, mg/l 0 0 0 7 BOD, mg/l < 30 < 30 < 30 8 COD, mg/l < 100 < 100 < 100 9 Heavy metal, mg/l ND ND ND 10 Phenolic compounds, ND ND ND mg/l
Sr. Parameters Combined effluent from RO rejection & No. Condensate from MEE
1 pH 6‐8 2 Color pt. co 150‐200 3 Suspended solids, mg/l < 100 4 Total dissolved solids, mg/l 2000‐3000 5 Oil and grease, mg/l < 1 6 NH3‐N, mg/l 20‐30 7 BOD, mg/l 1200‐1500 8 COD, mg/l 4000‐5000 9 Heavy metal, mg/l ND 10 Phenolic compounds, mg/l 1‐2
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Sr. Parameters Combined effluent from RO rejection Final treated No. & Condensate from MEE effluent 1 pH 6‐8 6‐8 2 Color pt. co 150‐200 < 100 3 Suspended solids, < 25 < 25 mg/l 4 Total dissolved 800‐1000 < 2100 solids, mg/l 5 Oil and grease, mg/l < 1 < 1 6 NH3‐N, mg/l 20‐30 <50 7 BOD, mg/l 800‐900 < 100 8 COD, mg/l 3000‐3500 < 250 9 Heavy metal, mg/l ND ND 10 Phenolic 1‐2 < 1 compounds, mg/l
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FLOW DIAGRAM OF EFFLUENT TREATMENT PLANT
FLOW DIAGRAM OF EFFLUENT TREATMENT SCHEME
Total EFFLUENT GENERATION: 281 M3/DAY
Domestic: 10 Concentrated effluent Normal from process: 170 Effluent: 102
Septic tank/soak pit Collection tank: 170 RO Plant: 102 RO Permeate: 91 Recycle Caustic Soda: 0.25 MT/Day Neutralization tank RO Rejection: 11 M3/day to MEE
Recovered ODCB: Solvent Extraction Extracted solvent: 14.6 MT/Day 14.8 M3/Day
Recovered Solvent: Solvent Stripper: 170 M3/day Holding tank: 151 M3/Day 0.3 MT/Day Distillation
Loss: 5.7 m3 MEE: 169.7 M3/Day + 11 M3 from Primary, Secondary & Tertiary Treatment Plant RO rejection=175.0 Recovered ODCB: Residue: 0.2 MT/Day 14.6 MT/Day
Incineration Treated effluent GIDC pipe line
Salt: 24 MT Condensate: 151 M3/day Arabian Sea
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ANNEXURE: 7
Quantity of Solid Waste generation and its management
No Type of waste Category Qty. MT/ Treatment Disposal month
1 ETP waste (34.3) 34.3 27 Dried, packed Dispose off in bags into TSDF, BEIL, Ankleshwar & SEPPL, Dahej & Kutch 2 ETP waste & salt 34.3 598 Dried, packed Dispose off from MEE (34.3) in bags into TSDF, BEIL, Ankleshwar & SEPPL, Dahej & Kutch 3 Used Oil (5.1) 5.1 0.2 Packed in sell to carboys registered recycler 4 Discarded containers 33.3 2.0 De‐ Sell to (33.3) contaminate authorized d, stored recycler 5 Process waste 29.1 845 Packed in Dispose off (Inorganic) bags into TSDF, BEIL, Ankleshwar & SEPPL, Dahej & Kutch 6 Distillation residue 29.1 609 Packed in Sent for co‐ drums processing or sent to SEPPL, Dahej & Kutch for incineration 7 Spent carbon 35.3 0.8 Packed in Sent for co‐ drums/bags processing or sent to SEPPL, Dahej & Kutch for incineration 8 Spent Catalyst 35.2 1.0 Packed in Sent for co‐ drum processing or TSDF BEIL, Ankleshwar & SEPPL, Dahej & Kutch 9 Used rubber hand X‐08 0.2 Packed in Sent for gloves/pipes etc drums/bags incineration to SEPPL, Dahej & Kutch 11 Iron sludge 26.1 231 Packed in Sent for co‐ drums/bags processing or TSDF BEIL,
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Ankleshwar & SEPPL, Dahej & Kutch 12 Date expired/off 29.3 1.0 Packed in Sent for specification drums/bags incineration pesticide 13 Fly ash ‐310 Packed in Sell to brick covered truck manufacturer
Note: We will apply for membership of SEPPL, Kutch and approved TSDF site of M/S BEIL, Ankleshwar.
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ANNEXURE‐8 The topographical map
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GOOGLE IMAGE OF THE PLOT
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Annexure‐9 PLOT ALLOTMENT LETTER ISSUED BY THE GIDC
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A Prefeasibility Report M/S YASHASHVI RASAYAN PVT. LIMITED
ANNEXURE‐10 A schematic representation of the feasibility drawing
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ANNEXURE‐11
Details of flue gas/process gas emission & its control measures
Sr. No. Particulars Details 1.0 Capacity of steam boiler & thermic fluid 20 TPH X 2 boiler 1.1 Fuel used Coal 1.2 Consumption 8000 kgs/hr 1.3 APC provided MDC & ESP 1.4 Height of chimney 55 meters x 2 2.0 Capacity of thermic fluid boiler 20 lacs kcals/hr 2.1 Fuel used Coal 2.2 Consumption 600 kgs/hr 2.3 APC provided MDC & ESP 2.4 Height of chimney 45 meters x 1 3.0 Capacity of D G set 2500 KVA 3.1 Fuel used HSD 3.2 Consumption 250 lits/hr 3.3 APC Exhaust 3.4 Height 11 meters 4.0 Stack attached to Reaction vessel
4.1 APC Two stage alkali scrubber x 3 nos 4.2 Height of vent 11 meters 4.3 Pollutants SO2< 40 mg/Nm3 NOx: < 25 mg/Nm3 4.0 Stack attached to Reaction vessel 4.1 APC Two stage water followed by alkali scrubber x 3 nos 4.2 Height of vent 11 meters 4.3 Pollutants NH3 < 175 mg/Nm3 SO2< 40 mg/Nm3 Br2: < 5 mg/Nm3 4.0 Stack attached to Reaction vessel 4.1 APC Two stage water followed by alkali scrubber 4.2 Height of vent 11 meters 4.3 Pollutants HCl: <20 mg/Nm3 Cl2: < 5 mg/Nm3
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