2020 Emergency Response Guidebook

Total Page:16

File Type:pdf, Size:1020Kb

2020 Emergency Response Guidebook 2020 A guidebook intended for use by first responders A guidebook intended for use by first responders during the initial phase of a transportation incident during the initial phase of a transportation incident involving hazardous materials/dangerous goods involving hazardous materials/dangerous goods EMERGENCY RESPONSE GUIDEBOOK THIS DOCUMENT SHOULD NOT BE USED TO DETERMINE COMPLIANCE WITH THE HAZARDOUS MATERIALS/ DANGEROUS GOODS REGULATIONS OR 2020 TO CREATE WORKER SAFETY DOCUMENTS EMERGENCY RESPONSE FOR SPECIFIC CHEMICALS GUIDEBOOK NOT FOR SALE This document is intended for distribution free of charge to Public Safety Organizations by the US Department of Transportation and Transport Canada. This copy may not be resold by commercial distributors. https://www.phmsa.dot.gov/hazmat https://www.tc.gc.ca/TDG http://www.sct.gob.mx SHIPPING PAPERS (DOCUMENTS) 24-HOUR EMERGENCY RESPONSE TELEPHONE NUMBERS For the purpose of this guidebook, shipping documents and shipping papers are synonymous. CANADA Shipping papers provide vital information regarding the hazardous materials/dangerous goods to 1. CANUTEC initiate protective actions. A consolidated version of the information found on shipping papers may 1-888-CANUTEC (226-8832) or 613-996-6666 * be found as follows: *666 (STAR 666) cellular (in Canada only) • Road – kept in the cab of a motor vehicle • Rail – kept in possession of a crew member UNITED STATES • Aviation – kept in possession of the pilot or aircraft employees • Marine – kept in a holder on the bridge of a vessel 1. CHEMTREC 1-800-424-9300 Information provided: (in the U.S., Canada and the U.S. Virgin Islands) • 4-digit identification number, UN or NA (go to yellow pages) For calls originating elsewhere: 703-527-3887 * • Proper shipping name (go to blue pages) • Hazard class or division number of material 2. CHEMTEL, INC. • Packing group 1-888-255-3924 • Emergency response telephone number (in the U.S., Canada, Puerto Rico and the U.S. Virgin Islands) • Information describing the hazards of the material (entered on or attached to the shipping For calls originating elsewhere: 813-248-0573 * paper)* 3. INFOTRAC EMERGENCY CONTACT EXAMPLE OF EMERGENCY 1-800-535-5053 1-000-000-0000 CONTACT TELEPHONE NUMBER (in the U.S., Canada and the U.S. Virgin Islands) For calls originating elsewhere: 352-323-3500 * CONTRACT #: XX-XXXX-X ** HAZARD CLASS OR DIVISION NO. NO. & TYPE QUANTITY 4. VERISK 3E OF PACKAGES 1-800-451-8346 UN1219 ISOPROPANOL 3 II 12 000 LITERS 1 TANKTRUCK (in the U.S., Canada and the U.S. Virgin Islands) For calls originating elsewhere: 760-602-8703 * ID NUMBER SHIPPING NAME PACKING GROUP The emergency response information services shown above maintain periodically updated lists of state and Federal radiation authorities who provide information and technical assistance on handling incidents involving radioactive materials. EXAMPLE OF PLACARD AND PANEL WITH ID NUMBER 5. MILITARY SHIPMENTS, for assistance at incidents involving materials being shipped by, for, The 4-digit ID Number may be shown on the diamond-shaped placard or on an adjacent orange or to the Department of Defense (DOD), call one of the following numbers: panel displayed on the ends and sides of a cargo tank, vehicle or rail car. 703-697-0218 * - Explosives/ammunition incidents (U.S. Army Operations Center) 1-800-851-8061 - All other hazardous materials/dangerous goods incidents A Numbered A Placard (Defense Logistics Agency) Placard OR and an Orange Panel 6. NATIONWIDE POISON CONTROL CENTER (United States only) 1-800-222-1222 * In the United States, this requirement may be satisfied by attaching a guide from the ERG2020 to the shipping paper, or by having the entire guidebook available for reference. ** In the United States, a registration or contract number may be required on a shipping paper. * Collect calls are accepted. HOWHOW TO TO USE THISTHIS GUIDEB GUIDEBOOKOOK RESIST RUSHING IN! APPROACH INCIDENT FROM UPWIND, AND UPHILL AND/OR UPSTREAM STAY CLEAR OF ALL SPILLS, VAPORS, FUMES, SMOKE, AND POTENTIAL HAZARDS WARNING: DO NOT USE THIS FLOWCHART if more than one hazardous material/dangerous good is involved. Immediately call the appropriate emergency response agency telephone number listed on the inside back cover of this guidebook. Do you see an explosive YES For Divisions 1.1, 1.2, 1.3, or 1.5 Use GUIDE 112 placard or For Divisions 1.4 or 1.6 Use GUIDE 114 label? NO Do you know NO Do you know NO Do you see NO Do you see NO Use the UN/NA the name of a placard or a railcar or GUIDE ID number? the material? label? road trailer? 111 YES YES YES YES Search for the Search for the ID number Refer to Refer to material in the in the Pages 8-9 Pages 10-14 Blue Pages Yellow Pages Determine the Guide Number If the Guide Number has a “P” Is the material NO Use the appropriate next to it, the material may suffer highlighted in Orange Guide a violent polymerization green? YES YES NO USE the appropriate USE TABLE 1 for Orange Guide for isolation and protective EVACUATION distances, THEN action distances, AND PROTECT in downwind CONSULT the appropriate direction according to TABLE 1 Orange Guide for residual material release If product includes the reference (when spilled in water), consult TABLE 2 for a list of the generated gases (for information purposes only), AND do not use water as extinguishing agent. BEFORE AN EMERGENCY - BECOME FAMILIAR WITH THIS GUIDEBOOK! First responders must be trained in the use of this guidebook. Page 1 LOCAL EMERGENCY TELEPHONE NUMBERS Please populate this page with emergency telephone numbers for local assistance: HAZMAT CONTRACTORS RAIL COMPANIES FEDERAL/STATE/PROVINCIAL AGENCIES OTHERS Page 2 TABLE OF CONTENTS Shipping Papers (Documents) . Inside front cover How to Use this Guidebook . .. 1 Local Emergency Telephone Numbers . 2 Safety Precautions . 4 Notification and Request for Technical Information . .. 5 Hazard Classification System . 6 Introduction to the Table of Markings, Labels And Placards . 7 Table of Markings, Labels, and Placards and Initial Response Guide to Use On-scene . 8 Rail Car Identification Chart . 10 Road Trailer Identification Chart . 12 Globally Harmonized System of Classification and Labeling of Chemicals (GHS) . 16 Hazard Identification Numbers Displayed On Some Intermodal Containers . .. 18 Pipeline Transportation . 22 ID Number Index (yellow pages) . 28 Name of Material Index (blue pages) . 92 Guides (orange pages) . 156 Introduction to Green Tables . 286 Protective Actions . 289 Protective Action Decision Factors to Consider . 291 Background on Table 1 – Initial Isolation and Protective Action Distances . .. 292 Table 1 – Initial Isolation and Protective Action Distances . 294 Table 2 – Water-Reactive Materials That Produce Toxic Gases . 344 Table 3 – Initial Isolation and Protective Action Distances for Large Spills for Different Quantities of Six Common TIH (PIH in the US) Gases . 350 ERG2020 User’s Guide . 354 Protective Clothing . 360 Decontamination . 362 Fire and Spill Control . 363 BLEVE and Heat Induced Tear . 365 BLEVE – Safety Precautions . 366 Criminal or Terrorist Use of Chemical, Biological and Radiological Agents . 368 Improvised Explosive Device (IED) Safe Stand-Off Distance . 373 Glossary . 375 Publication Data . 386 Canada and United States National Response Centers . 389 24-Hour Emergency Response Telephone Numbers . 392 Page 3 SAFETY PRECAUTIONS RESIST RUSHING IN! APPROACH CAUTIOUSLY FROM UPWIND, UPHILL AND/OR UPSTREAM: • Stay clear of Vapor, Fumes, Smoke and Spills. • Keep vehicle at a safe distance from the scene . SECURE THE SCENE: • Isolate the area and protect yourself and others . IDENTIFY THE HAZARDS USING ANY OF THE FOLLOWING: • Placards • Container labels • Shipping papers • Rail Car and Road Trailer Identification Chart • Safety Data Sheets (SDS) • Knowledge of persons on scene • Consult applicable guide page ASSESS THE SITUATION: • Is there a fire, a spill or a leak? • What are the weather conditions? • What is the terrain like? • Who/what is at risk: people, property or the environment? • What actions should be taken – evacuation, shelter-in-place or dike? • What resources (human and equipment) are required? • What can be done immediately? OBTAIN HELP: • Advise your headquarters to notify responsible agencies and call for assistance from qualified personnel . RESPOND: • Enter only when wearing appropriate protective gear . • Rescue attempts and protecting property must be weighed against you becoming part of the problem . • Establish a command post and lines of communication . • Continually reassess the situation and modify response accordingly . • Consider safety of people in the immediate area first, including your own safety . ABOVE ALL: Do not assume that gases or vapors are harmless because of lack of a smell – odorless gases or vapors may be harmful . Use CAUTION when handling empty containers because they may still present hazards until they are cleaned and purged of all residues . Page 4 NOTIFICATION AND REQUEST FOR TECHNICAL INFORMATION Follow the steps outlined in your organization’s standard operating procedures and/or local emergency response plan for obtaining qualified assistance . Generally, the notification sequence and requests for technical information beyond what is available in this guidebook should occur in the following order: 1. NOTIFY YOUR ORGANIZATION/AGENCY: • Based on information provided, this will set in motion a series of events . Actions may range from dispatching additional trained personnel to the scene, to activating the local emergency response plan . • Ensure that local fire and police departments have been notified . 2. CALL THE EMERGENCY RESPONSE TELEPHONE NUMBER ON THE SHIPPING PAPER • If shipping paper is not available, use guidance under next section “NATIONAL ASSISTANCE” . 3. NATIONAL ASSISTANCE • Contact the appropriate emergency response agency listed on the inside back cover of this guidebook . • Provide as much information about the hazardous material/dangerous good and the nature of the incident . • The agency will provide immediate advice on handling the early stages of the incident . • The agency will also contact the shipper or manufacturer of the material for more detailed information if necessary .
Recommended publications
  • Mechanistic Insights Into the Hydrocyanation Reaction
    Mechanistic insights into the hydrocyanation reaction Citation for published version (APA): Bini, L. (2009). Mechanistic insights into the hydrocyanation reaction. Technische Universiteit Eindhoven. https://doi.org/10.6100/IR644067 DOI: 10.6100/IR644067 Document status and date: Published: 01/01/2009 Document Version: Publisher’s PDF, also known as Version of Record (includes final page, issue and volume numbers) Please check the document version of this publication: • A submitted manuscript is the version of the article upon submission and before peer-review. There can be important differences between the submitted version and the official published version of record. People interested in the research are advised to contact the author for the final version of the publication, or visit the DOI to the publisher's website. • The final author version and the galley proof are versions of the publication after peer review. • The final published version features the final layout of the paper including the volume, issue and page numbers. Link to publication General rights Copyright and moral rights for the publications made accessible in the public portal are retained by the authors and/or other copyright owners and it is a condition of accessing publications that users recognise and abide by the legal requirements associated with these rights. • Users may download and print one copy of any publication from the public portal for the purpose of private study or research. • You may not further distribute the material or use it for any profit-making activity or commercial gain • You may freely distribute the URL identifying the publication in the public portal.
    [Show full text]
  • Numerical Simulation of a Two-Phase Flow for the Acrylonitrile Electrolytic Adiponitrile Process in a Vertical/Horizontal Electrolysis Cell
    energies Article Numerical Simulation of a Two-Phase Flow for the Acrylonitrile Electrolytic Adiponitrile Process in a Vertical/Horizontal Electrolysis Cell Jiin-Yuh Jang * and Yu-Feng Gan Department of Mechanical Engineering, National Cheng-Kung University, Tainan 70101, Taiwan; [email protected] * Correspondence: [email protected]; Tel.: +886-6-2088573 Received: 7 September 2018; Accepted: 6 October 2018; Published: 12 October 2018 Abstract: This paper investigated the effect of oxygen holdup on the current density distribution over the electrode of a vertical/horizontal electrolysis cell with a two-dimensional Eulerian–Eulerian two-phase flow model in the acrylonitrile (AN) electrolytic adiponitrile (ADN) process. The physical models consisted of a vertical/horizontal electrolysis cell 10 mm wide and 600 mm long. The electrical potential difference between the anode and cathode was fixed at 5 V, which corresponded to a uniform current density j = 0.4 A/cm2 without any bubbles released from the electrodes. The effects of different inlet electrolyte velocities (vin = 0.4, 0.6, 1.0 and 1.5 m/s) on the void fraction and the current density distributions were discussed in detail. It is shown that, for a given applied voltage, as the electrolyte velocity is increased, the gas diffusion layer thickness decreased and this resulted in the decrease of the gas void fraction and increase of the corresponding current density; for a given velocity, the current density for a vertical cell was higher than that for a horizontal cell. Furthermore, assuming the release of uniform mass flux for the oxygen results in overestimation of the total gas accumulation mass flow rate by 2.8% and 5.8% and it will also result in underestimation of the current density by 0.3% and 2.4% for a vertical cell and a horizontal cell, respectively.
    [Show full text]
  • Retention Indices for Frequently Reported Compounds of Plant Essential Oils
    Retention Indices for Frequently Reported Compounds of Plant Essential Oils V. I. Babushok,a) P. J. Linstrom, and I. G. Zenkevichb) National Institute of Standards and Technology, Gaithersburg, Maryland 20899, USA (Received 1 August 2011; accepted 27 September 2011; published online 29 November 2011) Gas chromatographic retention indices were evaluated for 505 frequently reported plant essential oil components using a large retention index database. Retention data are presented for three types of commonly used stationary phases: dimethyl silicone (nonpolar), dimethyl sili- cone with 5% phenyl groups (slightly polar), and polyethylene glycol (polar) stationary phases. The evaluations are based on the treatment of multiple measurements with the number of data records ranging from about 5 to 800 per compound. Data analysis was limited to temperature programmed conditions. The data reported include the average and median values of retention index with standard deviations and confidence intervals. VC 2011 by the U.S. Secretary of Commerce on behalf of the United States. All rights reserved. [doi:10.1063/1.3653552] Key words: essential oils; gas chromatography; Kova´ts indices; linear indices; retention indices; identification; flavor; olfaction. CONTENTS 1. Introduction The practical applications of plant essential oils are very 1. Introduction................................ 1 diverse. They are used for the production of food, drugs, per- fumes, aromatherapy, and many other applications.1–4 The 2. Retention Indices ........................... 2 need for identification of essential oil components ranges 3. Retention Data Presentation and Discussion . 2 from product quality control to basic research. The identifi- 4. Summary.................................. 45 cation of unknown compounds remains a complex problem, in spite of great progress made in analytical techniques over 5.
    [Show full text]
  • Transport of Dangerous Goods
    ST/SG/AC.10/1/Rev.16 (Vol.I) Recommendations on the TRANSPORT OF DANGEROUS GOODS Model Regulations Volume I Sixteenth revised edition UNITED NATIONS New York and Geneva, 2009 NOTE The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the Secretariat of the United Nations concerning the legal status of any country, territory, city or area, or of its authorities, or concerning the delimitation of its frontiers or boundaries. ST/SG/AC.10/1/Rev.16 (Vol.I) Copyright © United Nations, 2009 All rights reserved. No part of this publication may, for sales purposes, be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, electrostatic, magnetic tape, mechanical, photocopying or otherwise, without prior permission in writing from the United Nations. UNITED NATIONS Sales No. E.09.VIII.2 ISBN 978-92-1-139136-7 (complete set of two volumes) ISSN 1014-5753 Volumes I and II not to be sold separately FOREWORD The Recommendations on the Transport of Dangerous Goods are addressed to governments and to the international organizations concerned with safety in the transport of dangerous goods. The first version, prepared by the United Nations Economic and Social Council's Committee of Experts on the Transport of Dangerous Goods, was published in 1956 (ST/ECA/43-E/CN.2/170). In response to developments in technology and the changing needs of users, they have been regularly amended and updated at succeeding sessions of the Committee of Experts pursuant to Resolution 645 G (XXIII) of 26 April 1957 of the Economic and Social Council and subsequent resolutions.
    [Show full text]
  • Scientific Advisory Board
    OPCW Scientific Advisory Board SAB-III/1 27 April 2000 Original: ENGLISH REPORT OF THE THIRD SESSION OF THE SCIENTIFIC ADVISORY BOARD 1. Introduction 1.1 The Scientific Advisory Board (hereinafter referred to as the “Board”) held two meetings during its third session, which took place from 14 - 16 December 1999 and from 15 - 16 March 2000 in The Hague. 1.2 Dr Claude Eon of France, the Chairman of the Board, presided over its proceedings. 1.3 The Board considered the following issues: (a) adamsite; (b) analytical procedures; (c) equipment issues; (d) destruction technologies; (e) bio-medical samples; (f) future contributions of the Board to the preparation of the first Review Conference; and (g) any other business. 1.4 In preparation for its meeting the Board had received reports from its temporary working groups (TWGs) on adamsite and analytical procedures, and a report on a joint meeting of the temporary working groups on equipment issues and on chemical weapons destruction technologies. 1.5 During its meeting in December 1999, the Board received a briefing by the Deputy Director-General on the status of implementation of the Convention and on work priorities. The Board was also briefed by staff from the Verification and Inspectorate Divisions on experiences with the conduct of different types of inspection, as well as on analytical and equipment-related matters. It was further briefed on the results of an expert meeting on bio-medical samples conducted by the Secretariat in December 1999. CS-2000-1867 SAB-III/1 page 2 2. Work on substantive issues Adamsite 2.1 The Board received and discussed the draft report of the TWG on adamsite dated 7 October 1999, noted additional comments, and decided to include in its report the following considerations in relation to this matter: 2.2 Adamsite (10-chloro-5,10-dihydro-phenarsazine, code name DM, CAS registry number 578-94-9) is a yellow-green crystalline solid with a boiling point of 410ºC and a melting point of 195ºC.
    [Show full text]
  • 02/06/2019 12:05 PM Appendix 3745-21-09 Appendix A
    ACTION: Final EXISTING DATE: 02/06/2019 12:05 PM Appendix 3745-21-09 Appendix A List of Organic Chemicals for which Paragraphs (DD) and (EE) of Rule 3745-21-09 of the Administrative Code are Applicable Organic Chemical Organic Chemical Acetal Benzaldehyde Acetaldehyde Benzamide Acetaldol Benzene Acetamide Benzenedisulfonic acid Acetanilide Benzenesulfonic acid Acetic acid Benzil Acetic Anhydride Benzilic acid Acetone Benzoic acid Acetone cyanohydrin Benzoin Acetonitrile Benzonitrile Acetophenone Benzophenone Acetyl chloride Benzotrichloride Acetylene Benzoyl chloride Acrolein Benzyl alcohol Acrylamide Benzylamine Acrylic acid Benzyl benzoate Acrylonitrile Benzyl chloride Adipic acid Benzyl dichloride Adiponitrile Biphenyl Alkyl naphthalenes Bisphenol A Allyl alcohol Bromobenzene Allyl chloride Bromonaphthalene Aminobenzoic acid Butadiene Aminoethylethanolamine 1-butene p-aminophenol n-butyl acetate Amyl acetates n-butyl acrylate Amyl alcohols n-butyl alcohol Amyl amine s-butyl alcohol Amyl chloride t-butyl alcohol Amyl mercaptans n-butylamine Amyl phenol s-butylamine Aniline t-butylamine Aniline hydrochloride p-tertbutyl benzoic acid Anisidine 1,3-butylene glycol Anisole n-butyraldehyde Anthranilic acid Butyric acid Anthraquinone Butyric anhydride Butyronitrile Caprolactam APPENDIX p(183930) pa(324943) d: (715700) ra(553210) print date: 02/06/2019 12:05 PM 3745-21-09, Appendix A 2 Carbon disulfide Cyclohexene Carbon tetrabromide Cyclohexylamine Carbon tetrachloride Cyclooctadiene Cellulose acetate Decanol Chloroacetic acid Diacetone alcohol
    [Show full text]
  • Copyrighted Material
    1 Historical Milieu 1.1 Organophosphorus Nerve Agents 2 1.2 Blister Agents 5 1.3 Sternutator Agents 11 1.4 Chemical Weapons Convention (CWC) 13 1.4.1 Schedule of Chemicals 14 1.4.2 Destruction of Chemical Weapons 14 References 16 COPYRIGHTED MATERIAL Analysis of Chemical Warfare Degradation Products, First Edition. Karolin K. Kroening, Renee N. Easter, Douglas D. Richardson, Stuart A. Willison and Joseph A. Caruso. © 2011 John Wiley & Sons, Ltd. Published 2011 by John Wiley & Sons, Ltd. 2 ANALYSIS OF CHEMICAL WARFARE DEGRADATION PRODUCTS 1.1 ORGANOPHOSPHORUS NERVE AGENTS Organophosphorus (OP) type compounds, that is, deriva- tives containing the P=O moiety, were first discovered in the 1800s when researchers were investigating useful applica- tions for insecticides/rodenticides. There are many derivatives of organophosphorus compounds, however, the OP deriva- tives that are typically known as ‘nerve agents’ were discov- ered accidentally in Germany in 1936 by a research team led by Dr. Gerhard Schrader at IG Farben [1–4]. Schrader had noticed the effects and lethality of these organophosphorus compounds towards insects and began developing a new class of insecticides. While working towards the goal of an improved insecticide, Schrader experimented with numerous phosphorus-containing compounds, leading to the discovery of the first nerve agent, Tabun (or GA) (Figure 1.1). The potency of these insecticides towards humans was not realized until there was yet another accident, which involved a Tabun spill. Schrader and coworkers began experiencing symptoms, such as miosis (constriction of the pupils of the eyes), dizziness and severe shortness of breath, with numerous effects lasting several weeks [1, 4, 5].
    [Show full text]
  • Antimony Pentachloride Apc
    ANTIMONY PENTACHLORIDE APC CAUTIONARY RESPONSE INFORMATION 4. FIRE HAZARDS 7. SHIPPING INFORMATION 4.1 Flash Point: 7.1 Grades of Purity: 99+% Common Synonyms Liquid Colorless to brown Unpleasant odor Not flammable 7.2 Storage Temperature: Ambient Antimony (V) chloride 4.2 Flammable Limits in Air: Not flammable Antimony perchloride 7.3 Inert Atmosphere: No requirement 4.3 Fire Extinguishing Agents: Not pertinent Sinks in water. Irritating vapor is produced. Freezing point is 37°F. 7.4 Venting: Pressure-vacuum 4.4 Fire Extinguishing Agents Not to Be 7.5 IMO Pollution Category: Currently not available Avoid contact with liquid. Keep people away. Used: Do not use water or foam on Wear rubber overclothing (including gloves). adjacent fires. 7.6 Ship Type: Currently not available Stop discharge if possible. 4.5 Special Hazards of Combustion 7.7 Barge Hull Type: Currently not available Evacuate. Products: Not pertinent Isolate and remove discharged material. 4.6 Behavior in Fire: Irritating fumes of Notify local health and pollution control agencies. 8. HAZARD CLASSIFICATIONS hydrogen chloride given off when water Protect water intakes. or foam is used to extinguish adjacent 8.1 49 CFR Category: Corrosive material fire. 8.2 49 CFR Class: 8 Not flammable. 4.7 Auto Ignition Temperature: Not pertinent Fire POISONOUS GASES ARE PRODUCED WHEN HEATED. 8.3 49 CFR Package Group: II DO NOT USE WATER ON ADJACENT FIRES. 4.8 Electrical Hazards: Not pertinent 8.4 Marine Pollutant: No 4.9 Burning Rate: Not pertinent 8.5 NFPA Hazard Classification: Exposure Call for medical aid. 4.10 Adiabatic Flame Temperature: Not pertinent Category Classification VAPOR Health Hazard (Blue).........
    [Show full text]
  • Medicine with Deeper, More Biochemical Conception Of
    Edinburgh Medical Journal May 1951 APPLICATIONS of chemical defence research IN MEDICINET? By Professor R. A. PETERS to be invited It is a great responsibility, as well as a great honour, to Cameron lecturers give this lecture ; and I expect that with other I this ancient seat of share a sense of awe upon standing here in is learning. For me it is an awe tinged with much feeling (it possible that this is partly because some forebears of my mother came from near to recent of the this ; it is in part due the perusal city) perhaps " address here Froude in on the Times of John Knox, given by 1865 " " entitled Influence of the Reformation upon the Scottish Character ; this address drives home to the Sassenach the sterner stuff of which all of us in the the Scots are made ; but I really think it is more that as south, even if we come as I do from a Medical School as ancient the Hospital of St Bartholomew, know full well that Edinburgh stands high indeed in the world of Medical Schools as Scotland itself stands in the world of intellect. Elsewhere I have discussed fully the historical background of our for me back researches upon Chemical Defence substances, which go to World War I.23 Again in my Dixon lecture,24 I have indicated some of the interest for pharmacology. The outlook for medicine has not the been reviewed so far. Therefore I propose to-day to discuss of British influence upon the future of therapeutics of the discovery anti-lewisite and of some of the other researches upon war gas but substances ; and to consider not only the leads towards therapy, the possible newer trends given to medicine itself.
    [Show full text]
  • RIFM Fragrance Ingredient Safety Assessment, 2-Isopropyl-4- Methylanisole, CAS Registry Number 31574-44-4
    Food and Chemical Toxicology 110 (2017) S545eS551 Contents lists available at ScienceDirect Food and Chemical Toxicology journal homepage: www.elsevier.com/locate/foodchemtox Short review RIFM fragrance ingredient safety assessment, 2-isopropyl-4- methylanisole, CAS Registry Number 31574-44-4 * A.M. Api a, , D. Belsito b, D. Botelho a, D. Browne a, M. Bruze c, G.A. Burton Jr. d, J. Buschmann e, M.L. Dagli f, M. Date a, W. Dekant g, C. Deodhar a, M. Francis a, A.D. Fryer h, K. Joshi a,S.LaCavaa, A. Lapczynski a, D.C. Liebler i,D.O’Brien a, R. Parakhia a,A.Patela, T.M. Penning j, G. Ritacco a, J. Romine a, D. Salvito a, T.W. Schultz k, I.G. Sipes l, Y. Thakkar a, E.H. Theophilus a, A.K. Tiethof a, Y. Tokura m, S. Tsang a, J. Wahler a a Research Institute for Fragrance Materials, Inc., 50 Tice Boulevard, Woodcliff Lake, NJ 07677, USA b Columbia University Medical Center, Department of Dermatology, 161 Fort Washington Ave., New York, NY 10032, USA c Malmo University Hospital, Department of Occupational & Environmental Dermatology, Sodra Forstadsgatan 101, Entrance 47, Malmo SE-20502, Sweden d School of Natural Resources & Environment, University of Michigan, Dana Building G110, 440 Church St., Ann Arbor, MI 58109, USA e Fraunhofer Institute for Toxicology and Experimental Medicine, Nikolai-Fuchs-Strasse 1, 30625 Hannover, Germany f University of Sao Paulo, School of Veterinary Medicine and Animal Science, Department of Pathology, Av. Prof. dr. Orlando Marques de Paiva, 87, Sao Paulo CEP 05508-900, Brazil g University of Wuerzburg, Department of Toxicology, Versbacher Str.
    [Show full text]
  • 1,45%,562 UNITED SATES P All.‘ Bl If" Til?
    Patented May 1, 1923. 1,45%,562 UNITED SATES P All.‘ bl if" til? . ROBERT E. WILSON, LEON ‘JV. PARSONS, AND STANLEY 1E. OHXSHOLIYI, OF WASHINGTON, DISTRICT OF COLUMBIA. PROCESS THE PRODUCTION OE‘ All‘HALLEAETELMLETAL PERTJIANGANATES. N0 Drawing". Application ?led September 27, 1918. Serial No. 255,975. To (all to]: am it may concern. .' manganate by oxidation or acidification, Be it known that we, Romain‘ E. lllinsou, metatheses into calcium pern'iangamite by LEON “7. Parsons, and STANLEY L. Unis treatment With calcium sulphate or milk at HoLM, citizens of the United States. and sta lime. tioned at ViTashington, District of Columbia, O'li' these four possible methods, (1.) is not 60 in the o?icc of the Director the Chemical a possible large scale method. on account l/Varfare Service, Research Division, have in of its use ot silver; (2) and are elec vented a Process for the ll’roduction oif Al trolytic methods Without a. great deal out kali-Earth-l\letal Permanpjanates, of which promise, and are to be considered elsewhere; ll) the ‘following is a speci?cation. (ll) the principal subject of this applica G3 in The present invention relates to the pro tion. duction oi? alkah» earth metal permangam Three distinct methods for preparing: ba~ nates and especially the permanganates of rium (or strontium) manganate have been calcium and magnesium as these have beenv here investigated. The ?rst of? these meth found to be very ellicient oxidizing agents ods involves heating together barium perox 70 for certain purposes, more e?icient even. than ide, hydroxide, or a salt, such as the nitrate the permanganates of the allmliearth metals.
    [Show full text]
  • Report on Chemical Munitions Dumped in the Baltic Sea (HELCOM 1994)
    Baltic Sea Environment Proceedings No. 142 Baltic Marine Environment Protection Commission Chemical Munitions Dumped in the Baltic Sea Published by: HELCOM – Baltic Marine Environment Protection Commission Katajanokanlaituri 6 B FI-00160 Helsinki Finland www.helcom.fi Authors: Tobias Knobloch (Dr.), Jacek Bełdowski, Claus Böttcher, Martin Söderström, Niels-Peter Rühl, Jens Sternheim For bibliographic purposes this document should be cited as: HELCOM, 2013 Chemical Munitions Dumped in the Baltic Sea. Report of the ad hoc Expert Group to Update and Review the Existing Information on Dumped Chemical Munitions in the Baltic Sea (HELCOM MUNI) Baltic Sea Environment Proceeding (BSEP) No. 142 Number of pages: 128 Information included in this publication or extracts thereof are free for citation on the condition that the complete reference of the publication is given as stated above Copyright 2013 by the Baltic Marine Environment Protection Commission (HELCOM) ISSN 0357-2994 Language revision: Howard McKee Editing: Minna Pyhälä and Mikhail Durkin Design and layout: Leena Närhi, Bitdesign, Vantaa, Finland Chemical Munitions Dumped in the Baltic Sea Report of the ad hoc Expert Group to Update and Review the Existing Information on Dumped Chemical Munitions in the Baltic Sea (HELCOM MUNI) Table of Contents 1 Executive summary. .5 2 Introduction. .9 2.1 CHEMU report – subjects covered, recommendations & fulfilment. .10 2.2 MUNI report – scope & perspectives. 11 2.3 National and international activities since 1995. .14 2.3.1 Managerial initiatives. .14 2.3.2 Investigations in the Baltic Sea . .23 3 Chemical warfare materials dumped in the Baltic Sea. .28 3.1 Introduction. 29 3.1.1 Dumping activities .
    [Show full text]