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Prepared and Published with the Support of ATLAS SERIES THE CARLTON COUNTY BOARD OF COMMISSIONERS, ATLAS C-19, PART A GEOLOGICAL SURVEY THE MINNESOTA DEPARTMENT OF NATURAL RESOURCES, DIVISION OF WATERS, AND Plate 6—Mineral Endowment Harvey Thorleifson, Director the Fond du Lac Band of Chippewa

R. 19 W. MINERAL ENDOWMENT R. 18 W. St. Louis DESCRIPTION OF MAP UNITS T. 51 N. Brookston Plate 2, Bedrock Geology, contains a complete description of map units. By ¤ 2 Brook MESOPROTEROZOIC LOCATION DIAGRAM River Martin  Terrence J. Boerboom Joe mh Hinckley Sandstone. Martin Lake 92°30' mf Fond du Lac Formation. R. 17 W. 2009 T. 50 N. mc Basalt, Chengwatana Group. Twin Lakes  Interflow sandstone, Chengwatana Group. Lost Simian mi Lake Lake

Creek dc Cloquet dike. 93°00' 92°45' River ST. LOUIS COUNTY R. 21 W. R. 20 W. ST. LOUIS COUNTY R. 16 W. St. Louis  Esko oxide gabbro. Hardwood me Lake Esko Hasty Brook Simian )33 AITKIN COUNTY Dead (  46°45' Fish 46°45' mt Tamarack intrusion. Lake to  Cedar Creek River me Little Lake River PALEOPROTEROZOIC Tamarack )73 Brook Miller Cloquet River Cross Thomson Formation Lake INTRODUCTION demand for this light-colored sandstone as material for building restoration • Kalevala Township—Drill cores K-1 and KL-1 intersect beds within Lake Stoney Squaw T. 49 N. T. 49 N. projects. Although there are few known outcrops of the Hinckley Sandstone carbonaceous argillite, up to 2 centimeters thick and composed of 30 to 80 Old DeetzMidway  Slate and graywacke. Slate Quarry to The terms mineral or geologic endowment and mineral resource refer in Carlton County, the rock is likely close to the surface in many areas, and percent sulfides. The sulfide-rich layers are composed of very fine-grained Creek to geologic materials that have intrinsic economic value and thus potentially Rice Esko ¤61 it may be evaluated as a possible resource. pyrrhotite that locally contains delicately laminated sphalerite and chalcopyrite Portage ( ¦§35 th Hornfels of slate and graywacke protolith. Otter could be mined and marketed. Some examples of these materials are gold, Lake Part B of the Carlton County Geologic Atlas, which will be published by that may represent distal SEDEX-related deposits. There are also late brittle Big copper, nickel, iron, uranium, platinum-group elements, crushed rock aggregate, Lake  Variably graphitic slate and graywacke. the Minnesota Department of Natural Resources, will have a more thorough veins rich in sphalerite and/or chalcopyrite. Drill hole K-1 is reported to Woodbury Perch dc tt sand and gravel aggregate, and building stone. The geologic endowment of a Lake Cromwell Lake Creek Thomson overview of bedrock aggregate and decorative stone resources, as well as an have zinc values of up to 2.25 percent (possibly related to vein, rather than Tamarack Reservoir mineral commodity can be defined and quantified on observable physical and Wright LOUIS COUNTY ST.  Graphitic slate and graywacke. bedded, sphalerite). River Sawyer )210 tg assessment of the surficial sand and gravel resources. Otter compositional attributes of the deposit, such as deposit thickness and horizontal Island River • Kettle River area—Carbonaceous/graphitic rocks in this area contain Cole )210 Lake )210 tm Sulfidic-graphitic slate, metagraywacke, minor chert (includes units  dimensions, grade and tonnage, overburden thickness, measure of crushing Tamarack Torchlight Moose Creek pg Lake Lake Carlton URANIUM pyrite and pyrrhotite, with up to 30 percent total sulfides. Zinc analyses Lake St. Louis and  ). strength, and particle-size distribution. A mineral resource is a narrower Otter River pc were obtained from four drill holes in this area, and several anomalous zinc subset of a mineral endowment; it is an occurrence of geologic material of X Creek ) Carlton County was the focus of a brief but intense period of uranium Mattlia Eagle Little Otter 23 Mille Lacs Group values are reported from those holes, with reported values up to 4,717 ppm T. 48 N. Lake Lake economic interest in such form and quantity that reasonable prospects for exploration in the late 1970s to early 1980s. This exploration was spurred X Kettle River over a 10 foot interval in hole MG-7, and 3,300 ppm at 317 feet (97 meters) tt Chub  eventual economic extraction exist. If a part of the deposit does not have West 35 T. 48 N. gs Graphitic schist, silicate-facies iron-formation, chert, and metagabbro. by the similarity in geologic environments to areas such as the Athabasca Kettle ¦§ Lake Venoah depth and 7,400 ppm from 339 to 340 feet (103.3 to 103.6 meters) depth in ( Lake Lake reasonable prospects for eventual economic extraction, it cannot be included in basin in northern Saskatchewan and other similar deposits in Australia, where X ( tm Park hole MG-5. ( Wrenshall Tamarack Lake mg Dominantly mafic volcanic and hypabyssal intrusive rocks. a mineral resource (Resources and Reserves Committee, 1999). Factors that known economic uranium deposits are present. In those places, uranium (  Arrowhead • Split Rock area—Seven cores in this area were analyzed for zinc; out ( mt DOUGLAS COUNTY may remove some portion of an endowment from consideration as a resource is concentrated along Proterozoic stratigraphic intervals where quartz- ( Heikkila Mine ! ! ! Branch !! !! !! of 70 samples there were 2 intervals in drill core MG-3 with zinc anomalies: !! ! ! tg Hay  Carbonaceous argillite and iron-formation. are zoning restrictions, land ownership considerations, prohibitive taxation, rich sandstones unconformably overlie older graphite- or carbon-bearing (! Lake cs !  ! competing surface uses, and environmental considerations, in addition to the 2,151 ppm at 272 to 274 feet (83 to 84 meters) depth in an interval of rubbly

th ! tm bedrock. The uranium is concentrated mainly within brecciated fault zones

Creek ! basalt flow-top, and 1,100 ppm at 374 to 382 feet (114 to 116 meters) depth

(  ) supply–demand–price fluctuations of the commodity marketplace. Therefore ) in the underlying basement or in areas where the basement was covered by ( tt ! Clear vg Dominantly mafic volcanic and hypabyssal intrusive rocks, lesser

) Creek in graphitic-pyritic slate.

tm King a mineral resource must possess favorable geologic attributes and also be sandstone prior to erosion, and to a lesser extent in breccia zones and pod- West metasedimentary rocks.

Mahtowa)

X tm ! relatively unencumbered by socioeconomic factors that would remove it

River like concentrations in the overlying sandstone units. Occurrences of uranium

) !

 ( ) Deer from consideration as the basis of a business enterprise. The author of this IRON-FORMATION

tmKettle ) ) mineralization are also present in , related to the unconformity ) 73 Fork !  Carbonaceous argillite. X ( Mud ca tm Y ! ! Rock River ( Horn plate did not take into account these socioeconomic factors, and therefore the

tg Creek between the Mesoproterozoic Jacobsville sandstone and the underlying There are no known iron-formations of significance in Carlton County,

( Kalevala ( tg ! Blackhoof Creek T. 47 N.

T. 47 N. ) Y (Y( ( map portrays the mineral endowment, not the mineral resources of Carlton (

 ( Moose Paleoproterozoic Michigamme Formation. These units are generally equivalent

gs ) ! Creek  but there are known pyrite-pyrrhotite-rich metasedimentary rocks in many

Moose ) ( ! ! ga Mixed mafic rocks and sedimentary rocks.

) Dead ) Sandy County. to the Fond du Lac Formation and the Thomson Formation, respectively, in ) ) Creek areas. Although these deposits contain iron, they are unlikely to be economical

¤61 Lake !

! (

) This plate addresses the geologic endowment of only the bedrock beneath east-. Phosphatic horizons in the Michigamme slate are

mg ! Moose ag Graphitic schist and metagraywacke. because of the difficulty in separating iron from the sulfide. They may,

) River )

) Carlton County. It does not address surficial materials such as sand and also known to be uraniferous (Ojakangas, 1976).

( Creek however, be associated with zinc mineralization.

Horn

Silver) ! River

River River   gravel aggregate resources, nor does it fully address the bedrock materials The bedrock in Carlton County contains abundant carbonaceous and/ ) mf

 g Metagabbro.

cs ga Fork Nemadji that might be suitable for use as crushed stone or building stone. Part B of the ) ( or graphitic metasedimentary rocks of Paleoproterozoic age that are locally SULFUR ! Hunters ! Barnum South 46°30' Carlton County Geologic Atlas, to be produced by the Minnesota Department overlain by the Mesoproterozoic Fond du Lac Formation (sandstone), a setting 46°30' Creek  Bear Nemadji mm Dolomitic marble. ! k Kettle ! gg Lake Three diamond drill holes were drilled in 1950 and 1951 by the U.S.

River of Natural Resources, will provide maps that portray the size and quality of very similar to that described above. Radioactivity levels of 10 to 20 times

Kettle Brook !  ( Creek ca vg Kettle ! Creek Bureau of Mines in T. 46 N., R. 20 W., sec. 7 to look for iron sulfide ! River River ! River Little Falls Formation sand and gravel deposits, as well as more details on potential bedrock sources above normal background have been reported from brecciated graphitic slates !Y ! ! Brook !(! Creek River Creek deposits as a source of sulfur, as a follow-up to reports of earlier drilling by

( !! Clear for industrial minerals such as crushed stone. near the Arrowhead Mine west of Mahtowa (Ojakangas, 1976), and although

!  Metagraywacke. ( gg  Nemadji )23 unknown private interests that intersected sulfides (Pennington and Davis, ! mm Hanging Creek Silver mh The bedrock endowment map is a derivation of the bedrock geologic this area is some distance from the Fond du Lac Formation, it was probably ! Net ga ! River Horn Lake

Split g Gillespie Horn Fork T. 46 N. 1953). These holes intersected carbonaceous slates with local pyrrhotite

T. 46 N. ! Stony map (Plate 2, Bedrock Geology). On this plate, map units < , < , and < , covered by Fond du Lac Formation sandstone prior to erosion. Also, phosphatic

 Rock ( ! Moose ! to gs gg

ca ! Creek Line mineralization, similar to the Glen Township area in Aitkin County. No

( Lake

Y )27 !! Net composed of slate and graywacke (and their metamorphic equivalents), are not nodules with elevated levels of uranium have been described in slate from

Y ( ! ! ( !!!

( ! Moosehead

! !! ! )73 )27 Little significant sulfur or base metal mineralization was reported by the U.S. (

( ( Lake the Arrowhead Mine area (McSwiggen and others, 1986). Although there Rock  colored; these areas are least likely to be explored for mineral occurrences,

( ag

Anderson ( ! ¦§35 State Bureau of Mines in these holes. Subsequently, Hanna Mining drilled two ( given our current understanding of the bedrock geology and known types has been no known uranium exploration activity in Carlton County since the Split River mc

North holes in the general area of Kalevala Township, and three holes in Split ! ! Echo Moose  and models of mineral deposits. Likewise, map units < , < , < , and < 1980s, the seemingly favorable geologic setting could generate another cycle ! Lake mi MAP SYMBOLS mc mi mf mh Moose Sand Lake Rock Township, also for sulfur and possibly base metals. All of these holes Lake (Keweenawan sedimentary and volcanic rocks) are not colored for the same of exploration if future demand for nuclear power increases.

AITKIN COUNTY were situated over positive magnetic anomalies. Nearly all current domestic Geologic contact reason. In the future, more detailed information about the bedrock geology

PINE COUNTY R. 21 W. R. 20 W. R. 19 W. R. 18 W. R. 17 W. R. 16 W. PINE COUNTY DOUGLAS COUNTY sulfur production is as a by-product of oil and gas refining processes, and it

93°00' 92°45' 92°30' may be learned and new models of mineral exploration may be developed BASE METALS

Strike-slip fault—Speculative is unlikely that exploration for additional deposits of sulfur will take place )

Digital base modified from the Minnesota Department of GIS compilation by R.S. Lively ) that could lead to exploration in these areas as well. Also, many of the rocks

Base metals, such as zinc, lead, iron, and copper, are commonly associated in Carlton County.

Transportation BaseMap data; digital base annotation by Edited by Lori Robinson Thrust fault—Inferred in those units not colored on the map may prove to be suitable for use as ( the Minnesota Geological Survey. ( with volcanic and sedimentary rocks of many different ages, including Malmo structural discontinuity industrial minerals such as crushed stone or paving stone, but those commodities SCALE 1:200 000 Paleoproterozoic rocks similar to those in Carlton County. Many base Universal Transverse Mercator Projection, grid zone 15 are not the focus of this map. The colored map units shown on the bedrock TITANIUM AND RELATED ELEMENTS IN 1983 North American Datum 5 0 5 10 MILES Electromagnetic anomaly metal deposits are one of two types: sedimentary-exhalative (SEDEX) and endowment map are dominated by rock types such as pyrite and/or pyrrhotite- MESOPROTEROZOIC MAFIC INTRUSIONS volcanogenic-massive sulfide. The composition and geologic setting of the 5 0 5 10 15 KILOMETERS Bedrock outcrop rich sedimentary rocks, mafic intrusions, and mafic volcanic rocks, which are bedrock in Carlton County is compatible with either of these deposit types, Titanium is used in a wide variety of applications including paint pigment, Location of a drill hole targeting: most likely to host metallic mineral deposits based on analogy with known which has led to limited exploration activity and will likely lead to more an alloy in high-strength metals, plastics, paper, and many others. One source mineral deposits elsewhere. Several of these areas have already been explored of titanium is ilmenite (FeTiO ), which commonly coexists with magnetite X Scientific research activity in the future. The earliest exploration in Carlton County, by Hanna 3 to varying degrees, and will likely be the focus of future mineral exploration (Fe O ) in mafic intrusions. The Esko oxide gabbro in Carlton County Mining and the U.S. Bureau of Mines, was for iron sulfide mineralization, 3 4 ( Base and precious metals endeavors. Figure 1 shows the first-vertical derivative aeromagnetic data and was based largely on targeting geophysical anomalies similar to those creates a strong, reversely-polarized magnetic anomaly, an indication that it k superimposed on second-vertical derivative Bouguer gravity data, with the Methane in the Glen Township and Cuyuna Iron Range to the west of Carlton County. contains substantial quantities of magnetite. This intrusion has attracted past locations of drill holes, outcrops, and electromagnetic anomalies indicated. In ! Sporadic exploratory efforts from the 1990s were probably also based on exploration, and may be the focus of renewed exploration in the future, for Uranium areas such as Carlton County, which are covered by glacial sediments, these targeted geophysical anomalies, most likely for the SEDEX style of mineral titanium and possibly iron and/or other base metals. The Esko oxide gabbro Y Sulfur are the kinds of data likely to be used for minerals exploration. deposit. is not exposed at the surface, but is covered by only 20 to 50 feet (6 to 15 Compared to many areas of east-central Minnesota, the bedrock in parts meters) of glacial sediment. Exploration area discussed in the text SEDEX deposits are typically large, stratiform, massive sulfide bodies that ( of Carlton County is relatively well exposed, but nonetheless, only a tiny form by the exhalative discharge of hydrothermal fluids onto the seafloor, or The Esko oxide gabbro was reportedly drilled in 1966 by the W.S. Moore fraction of the bedrock is visible at the land surface. However, the bedrock into permeable beds close to the seafloor. SEDEX mineralization is typically Company after completion of detailed ground geophysical surveys. Later, exposures, when coupled with geophysical data such as aeromagnetic maps dominated by sphalerite (zinc sulfide) and galena (lead sulfide), along with in that same area, Laurentian Enterprises drilled several additional holes, and airborne and ground electromagnetic surveys, can provide clues to help pyrite and pyrrhotite (iron sulfides). These deposits are believed to typically but apparently did not encounter significant mineralization (Ikola, unpub. guide exploratory drilling efforts. form in relatively small, restricted oceanic basins that are filled with fine- data, 2009). The location and depth of the drill holes are unknown, as is This plate is intended to be used largely as a guide for county land grained, generally carbonaceous, clastic sedimentary rocks, within larger, the whereabouts of the drill core, and none of the information from those managers and land owners to understand which areas may be explored for rifted, continental basins. SEDEX deposits form by deeply circulating, hot programs is known to be publicly available (see explanation for unit

Every reasonable effort has been made to ensure the accuracy of the factual data on which this map interpretation is based; however, the Minnesota Geological Survey does not warrant or guarantee that there are no errors. Users may ©2009 by the State of Minnesota, Department of Natural wish to verify critical information; sources include both the references listed here and information on file at the offices of the Minnesota Geological Survey in St. Paul. In addition, effort has been made to ensure that the interpretation GEOLOGIC ATLAS OF CARLTON COUNTY and the Resources, and the Regents of the University of Minnesota conforms to sound geologic and cartographic principles. No claim is made that the interpretation shown is rigorously The University of Minnesota is an equal opportunity educator correct, however, and it should not be used to guide engineering-scale decisions without site-specific verification. and employer southern portion of St. Louis County, MINNESOTA