1FID: 00320557 C H E M I S T R I DATE: 06/27/02 VER DATE: 2001-04-27 MATERIAL SAFETY DATA SHEET TIME: 19:01:29 PAGE: 0001

------SECTION 01: CHEMICAL PRODUCT & COMPANY ID ------PRODUCT PRIMARY NAME: RHEOLUBE 362HB ALL SYNONYMS :NYE RHEOLUBE 362HB (FORMER) RHEOLUBE 362HB SAG 5482 SLIP JOINT LUBRICANT 26098237 362HB RHEOLUBE

SAFE USE CATEGORY AND DESCRIPTION: 04 -METAL WORKING FLUIDS AND LUBRICANTS

LAST UPDATED DATE: 2001-04-27

MANUFACTURER'S ID (MID): 000537160 MANUFACTURER'S NAME: NYE LUBRICANTS, INC MANUFACTURER'S EMERGENCY PHONE NUMBER/TEXT: US 508-996-6721 MANUFACTURER'S MAILING ADDRESS: 12 HOWLAND ROAD FAIRHAVEN MA 02719 US

SECTION 1 - OTHER INFORMATION: PRODUCT/CHEMICAL NAME: RHEOLUBE 362HB. GENERAL USE: LUBRICATING GREASE. EMERGENCY OVERVIEW: SUMMARY OF RISKS: MAY IRRITATE EYES. PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE IRRITATION. INHALATION OF OIL MIST OR VAPORS FROM MATERIAL AT HIGH TEMPERATURES MAY IRRITATE RESPIRATORY PASSAGES. POLYTETRAFLUOROETHYLENE (PTFE) (9002-84-0), WHEN THERMALLY DECOMPOSED (OVER 290 C), MAY CAUSE POLYMER FUME FEVER. THERMAL DECOMPOSITION OF PTFE (OVER 290 C) WILL GENERATE HYDROGEN FLUORIDE. PREPARED BY: WMM. ------SECTION 02: COMPOSITION & INGREDIENT INFO ------

CAS# FORMULATION W/V CHEMICAL NAME 007620771 R 6.0000/ 11.0000% W Octadecanoic acid, 12-hydroxy-, mo nolithium salt 009002840 = 10.0000/ 0.0000% W ETHYLENE, TETRAFLUORO-, POLYMER 068037014 R 80.0000/ 85.0000% W 1-Decene, homopolymer, hydrogenate d

SECTION 2 - OTHER INFORMATION: NO INGREDIENTS ARE KNOWN TO BE HAZARDOUS UNDER NORMAL USAGE. NOT A HAZARDOUS MATERIAL UNDER NORMAL USAGE, BUT PTFE (9002-84-0) CAN PRODUCE TOXIC FUMES IF PYROLIZED. ------SECTION 03: HAZARDS IDENTIFICATION ------PRIMARY ENTRY ROUTE INDICATORS: SKIN PRIMARY ENTRY ROUTE INDICATOR = Y EYE PRIMARY ENTRY ROUTE INDICATOR = Y INHALATION PRIMARY ENTRY ROUTE INDICATOR = Y INGESTION PRIMARY ENTRY ROUTE INDICATOR = Y PRIMARY ROUTES OF ENTRY TEXT: INHALATION AT HIGH TEMPERATURES, EYE CONTACT, SKIN CONTACT.

EFFECTS OF OVEREXPOSURE - SKIN: POTENTIAL HEALTH EFFECTS: REPEATED OR PROLONGED SKIN CONTACT MAY CAUSE IRRITATION. THERMAL DECOMPOSITION OF PTFE (9002-84-0) (OVER 290 C) WILL GENERATE HYDROGEN FLUORIDE, WHICH IS CORROSIVE, CAUSING BURNS ON CONTACT WITH SKIN AND OTHER TISSUE. EFFECTS OF OVEREXPOSURE - EYE: POTENTIAL HEALTH EFFECTS: MAY CAUSE IRRITATION. EFFECTS OF OVEREXPOSURE - INHALATION: POTENTIAL HEALTH EFFECTS: OIL MIST AND VAPORS AT HIGH TEMPERATURES MAY IRRITATE RESPIRATORY PASSAGES. INHALATION OF DECOMPOSITION PRODUCTS OF PTFE (OVER 290 C) MAY CAUSE POLYMER FUME FEVER, A TEMPORARY FLU-LIKE ILLNESS ACCOMPANIED BY FEVER, CHILLS, AND SOMETIMES COUGH, OF APPROXIMATELY 24 HOURS DURATION. REPEATED EPISODES OF POLYMER FUME FEVER MAY CAUSE LUNG DAMAGE. INHALATION OF FLUORINE COMPOUNDS AS DECOMPOSITION PRODUCTS OF PTFE (9002-84-0) (OVER 290 C) MAY CAUSE LUNG IRRITATION AND PULMONARY EDEMA. EFFECTS OF OVEREXPOSURE - INGESTION: POTENTIAL HEALTH EFFECTS: MAY CAUSE GASTROINTESTINAL IRRITATION. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: INDIVIDUALS WITH PRE-EXISTING DISEASE OF THE LUNGS MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES FROM THERMAL DECOMPOSITION PRODUCTS.

ADDITIONAL HEALTH HAZARD DATA: TARGET ORGANS: RESPIRATORY PASSAGES AT HIGH TEMPERATURES, EYES, SKIN.

------SECTION 04: FIRST AID MEASURES ------EMERGENCY FIRST AID PROCEDURES - SKIN: CONTACT: REMOVE CONTAMINATED CLOTHING. WASH EXPOSED AREA WITH SOAP AND WATER. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EMERGENCY FIRST AID PROCEDURES - EYES: CONTACT: FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. GET IMMEDIATE MEDICAL ATTENTION. EMERGENCY FIRST AID PROCEDURES - INHALATION: IF SYMPTOMS DEVELOP, REMOVE AFFECTED PERSON FROM SOURCE OF EXPOSURE TO FRESH AIR. GET IMMEDIATE MEDICAL ATTENTION. IF PERSON IS NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN IF AVAILABLE. EMERGENCY FIRST AID PROCEDURES - INGESTION: GET IMMEDIATE MEDICAL ATTENTION. DO NOT INDUCE VOMITING UNLESS INSTRUCTED TO DO SO BY A PHYSICIAN.

------SECTION 05: FIRE-FIGHTING MEASURES ------SPECIAL FIRE FIGHTING PROCEDURES: EXTINGUISHING MEDIA: CO2, FOAM, DRY CHEMICAL, WATER SPRAY. FIRE FIGHTING INSTRUCTIONS: WEAR A NIOSH APPROVED POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS WITH FULL PROTECTIVE CLOTHING. DO NOT RELEASE RUNOFF FROM FIRE CONTROL METHODS TO SEWERS OR WATERWAYS.

UNUSUAL FIRE AND EXPLOSION HAZARDS: UNUSUAL FIRE OR EXPLOSION HAZARDS: NONE. HMIS CODES: HMIS REACTIVITY CODE = 0 HMIS HEALTH CODE = 1 HMIS FLAMMABILITY CODE = 1 NFPA CODES: NFPA FLAMMABILITY CODE = 1 NFPA HEALTH CODE = 1 NFPA REACTIVITY CODE = 0

FLASH POINT TEMPS: > 204.00C/ 400.00F FLASH POINT METHOD: CC FLASH POINT METHOD TEXT: ASTM D93.

SECTION 5 - OTHER INFORMATION: NFPA NOT YET DETERMINED. NOT A HAZARDOUS MATERIAL UNDER NORMAL USAGE, BUT PTFE (9002-84-0) CAN PRODUCE TOXIC FUMES IF PYROLIZED. HMIS: PPE: SEE SECTION 8. LOWER FLAMMABLE LIMIT (LFL), UPPER FLAMMABLE LIMIT (UFL): N/A. HAZARDOUS COMBUSTION PRODUCTS: HYDROGEN FLUORIDE, CARBONYL FLUORIDE, CARBON MONOXIDE AND SMALL AMOUNT OF OTHER TOXIC FUMES.

------SECTION 06: ACCIDENTAL RELEASE MEASURES ------SPILL OR LEAK PROCEDURES: SPILL RESPONSE: OBSERVE PRECAUTIONS FROM OTHER SECTIONS. CONTAIN ANY SPILL WITH DIKES OR ABSORBENTS TO PREVENT MIGRATION AND ENTRY INTO DRAINS, SEWERS OR BODIES OF WATER. WIPE OR SCRAPE UP GREASE AND PLACE IT IN A PROPER CONTAINER FOR DISPOSAL. WASH WALKING SURFACES THOROUGHLY TO REDUCE SLIPPING HAZARD. FOLLOW APPLICABLE OSHA (29 CFR 1910.120), STATE AND LOCAL REGULATIONS.

------SECTION 07: HANDLING AND STORAGE ------PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: HANDLING PRECAUTIONS: EXERCISE ORDINARY CARE IN HANDLING INDUSTRIAL LUBRICANTS. AVOID CONTAMINATION OF CIGARETTES OR OTHER TOBACCO PRODUCTS. WASH HANDS THOROUGHLY BEFORE EATING OR SMOKING. REMOVE CONTAMINATED CLOTHING AND CLEAN BEFORE REUSE. USERS SHOULD BE ALERT TO THE POSSIBILITY THAT VERY SMALL PERCENTAGES OF THE POPULATION MAY DISPLAY UNEXPECTED ALLERGIC REACTIONS TO OTHERWISE INNOCUOUS INDUSTRIAL LUBRICANTS AND RAW MATERIALS. STORAGE REQUIREMENTS: DO NOT STORE IN OPEN OR UNLABELLED CONTAINERS. STORE AWAY FROM INCOMPATIBLES.

------SECTION 08: EXPOSURE CONTROLS - PROTECTION ------EYE PROTECTION: AVOID EYE CONTACT. WEAR SAFETY GLASSES OR CHEMICAL GOGGLES IN ACCORDANCE WITH OSHA 29 CFR 1910.133. DEPENDING ON CONDITIONS OF USE, ADDITIONAL PROTECTION MAY BE NECESSARY SUCH AS A FACESHIELD, ETC.

SKIN PROTECTION: AVOID SKIN CONTACT. DEPENDING ON CONDITIONS OF USE, ADDITIONAL PROTECTION MAY BE NECESSARY SUCH AS A APRON, ETC.

RESPIRATORY PROTECTION: AVOID BREATHING OIL MIST. RESPIRATORY PROTECTION IS GENERALLY NOT NECESSARY UNDER NORMAL CONDITIONS OF USE WITH ADEQUATE GENERAL VENTILATION.

ENGINEERING CONTROLS: VENTILATION: LOCAL VENTILATION IS GENERALLY NOT NECESSARY UNDER NORMAL CONDITIONS OF USE WITH ADEQUATE GENERAL VENTILATION. VENTILATION AND OTHER FORMS OF ENGINEERING CONTROLS ARE THE PREFERRED MEANS FOR CONTROLLING CHEMICAL EXPOSURES. SAFETY STATIONS: MAKE EMERGENCY EYEWASH STATIONS, SAFETY/QUICK-DRENCH SHOWERS, AND WASHING FACILITIES AVAILABLE IN WORK AREA.

WORKPLACE/HYGIENIC PRACTICES: OTHER PRECAUTIONARY INFORMATION: NEVER EAT, DRINK, OR SMOKE IN WORK AREAS. PRACTICE GOOD PERSONAL HYGIENE AFTER USING THIS MATERIAL, ESPECIALLY BEFORE EATING, DRINKING, SMOKING, USING THE TOILET, OR APPLYING COSMETICS.

PROTECTIVE GLOVES (SPECIFY TYPE): WEAR CHEMICAL PROTECTIVE GLOVES.

------SECTION 09: PHYSICAL & CHEMICAL PROPERTIES ------BOILING POINT TEXT: NOT VOLATILE.

SPECIFIC GRAVITY VALUES: = 0.8900 SPECIFIC GRAVITY TEXT: AT 25 C (H2O=1) AT 4 C.

VAPOR DENSITY TEXT: NOT DETERMINED.

VAPOR PRESSURE TEXT: NEGLIGIBLE.

PERCENT VOLATILE BY WEIGHT TEXT: NONE.

EVAPORATION RATE TEXT: NOT DETERMINED.

SOLUBILITY IN WATER TEXT: WATER SOLUBILITY: INSOLUBLE.

PH OF PRODUCT IN SOLUTION WITH WATER/TEXT: NOT DETERMINED.

APPEARANCE: SMOOTH, LIGHT TAN TO LIGHT YELLOW GREASE.

ODOR: SLIGHT ODOR.

PHYSICAL STATE: PAS

SECTION 9 - OTHER INFORMATION: DROPPING POINT: 202 C. FORMULA WEIGHT: NOT CALCULATED.

------SECTION 10: STABILITY & REACTIVITY ------STABILITY INDICATOR: Y STABILITY - TEXT: RHEOLUBE 362HB IS STABLE AT ROOM TEMPERATURE IN CLOSED CONTAINERS UNDER NORMAL STORAGE AND HANDLING CONDITIONS. CHEMICAL INCOMPATIBILITIES: STRONG OXIDIZING MATERIALS. CONDITIONS TO AVOID: PYROLYSIS.

HAZARDOUS DECOMPOSITION PRODUCTS: THERMAL OXIDATIVE DECOMPOSITION OF RHEOLUBE 362HB CAN PRODUCE HYDROGEN FLUORIDE, CABONYL FLUORIDE, CARBON MONOXIDE AS WELL AS SMALL AMOUNTS OF OTHER TOXIC FUMES.

HAZARDOUS POLYMERIZATION INDICATOR: N HAZARDOUS POLYMERIZATION TEXT: THIS PRODUCT WILL NOT UNDERGO HAZARDOUS POLYMERIZATION.

------SECTION 11: TOXICOLOGICAL INFORMATION ------TOXICOLOGICAL DATA UNLIMITED TEXT: TOXICITY DATA: NONE AVAILABLE.

CARCINOGENICITY: IARC, NTP, AND OSHA DO NOT LIST RHEOLUBE 362HB OR ITS INGREDIENTS AS CARCINOGENS.

------SECTION 12: ECOLOGICAL INFORMATION ------ECOLOGICAL INFORMATION: ENVIRONMENTAL FATE AND EFFECTS: NO DATA HAS BEEN ESTABLISHED FOR THIS PRODUCT.

------SECTION 13: DISPOSAL CONSIDERATIONS ------WASTE DISPOSAL METHOD: DISPOSAL: CONTACT A LICENSED WASTE-DISPOSAL CONTRACTOR FOR DETAILED RECOMMENDATIONS. DISPOSAL REGULATORY REQUIREMENTS: MANY STATES CLASSIFY WASTE LUBRICANTS AS HAZARDOUS, WHICH MEANS DISPOSAL ONLY BY A LICENSED FIRM. FOLLOW APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS.

------SECTION 14: TRANSPORT INFORMATION ------DOT INFORMATION: DOT TRANSPORTATION DATA (49 CFR 172.101): NOT REGULATED. ------SECTION 15: REGULATORY INFORMATION ------SARA 311/312 HAZARD INDICATORS: IMMEDIATE HEALTH INDICATOR = N DELAYED HEALTH INDICATOR = N FIRE INDICATOR = N SUDDEN PRESSURE RELEASE INDICATOR = N REACTIVITY INDICATOR = N

SECTION 15 - OTHER INFORMATION: TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY. SARA 313 TOXIC CHEMICALS (40 CFR 372): NO INGREDIENTS LISTED. SARA EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): NO INGREDIENTS LISTED. CERCLA HAZARDOUS SUBSTANCES (40 CFR 302): NO INGREDIENTS LISTED.

SAFE USE CATEGORY AND DESCRIPTION : ------04 METAL WORKING FLUIDS AND LUBRICANTS

REGULATORY IMPACTS(REG) AND ADDITIONAL HEALTH HAZARD STATEMENTS(HHS) : ------

CAS#: 007620771 Octadecanoic acid, 12-hydroxy-, monolithium salt REG: 0012 REG BY CATEGORY: 0034

CAS#: 009002840 ETHYLENE, TETRAFLUORO-, POLYMER REG: 0012,0061

CAS#: 068037014 1-Decene, homopolymer, hydrogenated REG: 0012

REGULATORY KEY LIST: 0001 OSHA-PEL 0003 ACGIH-TLV 0004 GM-SPEC CHEM 0005 SUSP CARCIN 0006 EPA HW261.33 0007 EPA HW-APP 8 0008 MCMR 0009 FWPC-SEC 311 0010 EPA PRIORPOL 0011 NY SUBS CONC 0012 TSCA INV 0014 MI AIR POLLU 0015 SUP TAX CHEM 0016 MI HW-ACT 64 0017 CA HAZ SUBST 0019 MA SUBST 0020 NJ ENV SUBST 0021 TOX ORGANICS 0022 MD CLASS I 0023 MD CLASS II 0026 EPA-CHEMCONC 0031 ALLGHNY CTY 0032 IL-RTK 0033 OSHA-HHCL 0034 FLT CRIT IND 0035 GM-AHC 0036 PRO EP TOX 0037 MO SPECIES 0038 MO-RTK 0039 ONT 654-86 0041 SARA312EXHAZ 0042 WI TABLE 1 0047 SARA 313 0048 CERCLASEC103 0049 P-65 CARCINO 0050 P-65 REP TOX 0051 MD CLSI .11 0053 MD CLSII .12 0055 CT 29-2 0056 CT 29-3 0058 EPA261.33(F) 0059 CA AIR TOX 1 0060 CA AIR TOX 2 0061 PA RTK 0063 PELS REVISED 0064 NPDES-TOXPOL 0065 NJ W&C RTK 0066 CAA HAZ POL 0067 NV HIGH HAZ. 0068 MI 307-CARC 0069 MI 307-NCARC 0070 MICH AIR 0074 B 0075 C 0076 D 0078 GREAT LAKES 0083 TSCA 8(D)) 0084 GM OEG 0087 TSCA 12(B) 0088 NAT. POLL. REL 0089 NY CHEM BULK 0090 GL PERSIST 0091 LAND DISP. - II 0093 TSCA - SPECIAL 0098 DSL - CANADA 0104 CERCLA-HAZWOPER 0105 GLPPP-SPECIFIC 0106 GLPPP-SPECIFIC 0107 PET. DISTILLATE 0109 APPENDIX IX 0112 RCRA PBT -DRAFT 0118 T.W. REPORT 0122 ACDM-REPORTING

GMBA/PLANT USING THIS FID: ------GMBA: 000550678 SPO - DISTRIBUTABLE MATERIALS CISCO: 17001; STATUS :ACTIVE GMBA: 000550957 CHEMICAL RISK MANAGEMENT CISCO: 89150; STATUS :ACTIVE GMBA: 000556705 ENVIRONMENTAL SYSTEMS HELPDESK CISCO: 99004; STATUS :ACTIVE