Table S1. GC-MS compounds generated at 5 °C/min.
0 wt.% 10 wt.% 30 wt.% 50 wt.%
GC GC GC GC Compounds Compounds Compounds Compounds Area (%) Area (%) Area (%) Area (%) Time (min.) (min.) Time Time (min.) (min.) Time (min.) Time (min.) Time
Propene Propene Propene Propene
7.42 1.26 5.47 1.20 7.38 1.200 1.200 1.200 1.214 1.214
1-Propene, 2- 1-Propene, 2- methyl- 1-Propene, 2-methyl- 1-Propene, 2-methyl-
7.34 7.34 2.41 methyl- 1.245 1.245 1.245 1.259 1.259 10.54 1.246 14.90
Pentane Pentane Pentane Pentane
3.79 1.375 1.375 1.395 1.395 11.81 1.381 13.17 1.375 12.83
1-Pentene, 2- 2-Butene, 2- 2-Butene, 2-methyl- 2-Butene, 2-methyl-
methyl- 7.25 0.93 methyl- 4.65 5.71 1.426 1.426 1.420 1.420 1.679 1.679
1H-Pyrazole, 4,5- Heptane, 4- 1H-Pyrazole, 4,5- 1-Pentene, 2-methyl- dihydro-5-
methyl- 1.92 1.57 2.25 dihydro-5-methyl- 2.44 1.659 1.659 1.562 1.569 3.762 3.762 methyl-
2,4-Dimethyl-1- 1-Pentene, 2- heptene 2-Butene, 2,3-dimethyl- 1-Pentene, 2-methyl-
1.27 1.27 methyl- 3.08 2.33 1.653 1.653 1.653 5.671 5.671 34.57 1.750 Cyclohexane, 1,3,5-trimethyl-, 2-Pentene, 3- 2,4-Dimethyl-1-heptene 2-Pentene, 2-methyl-
alpha.,3.alpha.,5.b 2.03 9.11 methyl-, €- 6.11 5.73 5.605 5.605 1.743 1.744 5.981 5.981 eta.)- 5-Aminoisoxazole 2-Pentene, 3- 2-Pentene, 3-methyl-, Spermine Ethanone, 1-cyclopentyl-
1.55 1.55 1.32 methyl-, (Z)- 1.59 €- 1.46 1.828 1.828 1.828 6.925 6.925 10.560
Ethanone, 1- 1R,2c,3t,4t-Tetramethyl- 1,3-Pentadiene, 1,4-Hexadiene, 5- cyclopentyl-
3.57 3.57 cyclohexan 0.97 2,3-dimethyl- 2.28 methyl- 2.31 2.584 2.584 2.585 10.613 10.613 10.638
N- Heptane, 2-methyl-3- Heptane, 4- Methylallylamine Toluene
2.49 2.49 methylene- 2.50 methyl- 2.97 4.31 3.697 3.697 3.697 14.047 14.047 10.684 10.684
2-Undecene, 4- Cyclopentane, (2- 2,4-Dimethyl-1- 2,4-Dimethyl-1- methyl-
7.81 7.81 methylbutyl)- 1.00 heptene heptene 5.605 5.605 22.29 22.29 5.605 12.95 14.086 14.086 14.163 Cyclohexane, Cyclohexane, 1,3,5- 2-Decene, 7- 1,3,5-trimethyl-, trimethyl- methyl-, (Z)- Hexane, 2,3,4-trimethyl- (1. 2.30 2.30 2.67 2.67 2.12 ,alpha.,3.alpha.,5.beta.) 1.56 5.922 5.922 5.922 5.922 14.203 14.203 14.280 Alpha.,3.alpha.,5. - beta.)- Dichloroacetic acid, 6-ethyl-3-oct Fumaric acid, nonyl 2,3,6- p-Xylene p-Xylene
yl ester 6.92 trichlorophenyl ester 7.42 1.59 3.82 6.297 6.297 6.285 14.326 14.326 21.628 Cyclododecaneme Cyclodecasiloxane, 1-Undecene, 7- Benzene, 1-ethyl-2- thanol 1.31 1.31 2.28 3.17 1.89
eicosamethyl- methyl- 8.374 methyl- 15.063 15.063 21.732 10.567 1.395 1.259 1.214 Time (min.) 16.920 1-Propene, 2-methyl- trifluoro-, 3,7- trifluoro-, dimethyloctyl Acetic acid, Compounds Compounds ester 0 wt.% 10 wt.% 30 wt.% 50 wt.% 50wt.% 30wt.% 10wt.% 0 wt.% Propene Pentane
GC GC
Table S2. 1.35
12.09 4.23 7.60 Area (%) 29.487 29.352 27.340 27.172 25.768 25.606 24.655 24.513 24.358 23.219 23.051 22.579
(Hexafluoroisopropylidene 3-(1-adamantyl)-1-phenyl- Fumaric acid, nonyl 2,3,6- nonyl acid, Fumaric 4-Thiazolemethanol, 2-(4- Pyrazole-4-carboxamide, chlorodiphenylsulfoxide chlorodiphenylsulfoxide
1.394 1.258 1.213 Time (min.) trichlorophenyl ester Cyclononasiloxane, Cyclononasiloxane, Cyclodecasiloxane, Cyclodecasiloxane, tetradecamethyl- tetradecamethyl- octadecamethyl- octadecamethyl- chlorophenyl)- dodecamethyl- GC-MS compounds generated at 30 °C/min. Pentasiloxane, Hexasiloxane, eicosamethyl- eicosamethyl- eicosamethyl- 4-Nitro-4’- 4-Nitro-4’- )diphenol 1-Propene, 2- Compounds Compounds 4,4’- Propene Pentane methyl-
GC GC
15.46 7.59 3.95 Area (%) 4.83 3.31 5.67 5.01 5.53 6.62 2.67 4.94 6.94 4.65 7.75 4.14
1.381 1.245 1.200 Time (min.) 16.498 14.286 14.163 14.047 10.638 11,11,13,13,15,15 -hexadecamethyl- Cyclopentane, (2- Acetylcyclopenta 1,1,3,3,5,5,7,7,9, methylbutyl)- methylbutyl)- Octasiloxane, Ethanone,1- cyclopentyl- Cyanamide, 1-Propene, 2- 1-Propene, Compounds Compounds dibutyl- Propene Pentane Pentane methyl- methyl- none 2- GC GC
1.92 5.61 2.34 6.28 2.39 12.49 12.88 6.46 Area (%) 20.257 16.499 14.280 14.163 14.047 13.982 13.646 10.638 10.560
1.388 1.258 1.213 Time (min.) bistrimethylsiloxy)tetra 2-Undecene, 4-methyl- 1-Undecene, 7-methyl- Cyclohexanone, 3,3,5- Cyclohexanone, Acetylcyclopentanone Acetylcyclopentanone Cyclohexane, 1,1’-(2- Cyclohexane, 1H-1,2,4-Triazole, 3- 1H-1,2,4-Triazole, (2-methylpropyl)- Heptamethyl-3,3- propanediyl)bis- propanediyl)bis- 1,1,1,5,7,7,7- Tetramethyl- 1R,2c,3t,4t- cyclohexan 1-Propene, 2- 1-Propene, Compounds Compounds trimethyl- trimethyl- ethyl-1,3- siloxane siloxane Propene Pentane methyl- methyl- 2- 2- GC
15.02 14.95 6.89 Area (%) 2.17 1.57 3.76 1.63 4.28 1.71 1.61 1.58 2.08 21.849 20.290 19.378 14.319 14.203 14.086 10.677 10.606 6.926 5.981 5.671 3.756 1.679 Cyclohexane, 1-ethyl-2- trimethylsiloxy)tetrasilo trimethylsiloxy)tetrasilo 2,4-Dimethyl-1-heptene 4-Decene, 3-methyl-, €- €- 3-methyl-, 4-Decene, alpha.,3.alpha.,5.alpha.) -3,4-dimethyl-, (.+-.)- (.+-.)- -3,4-dimethyl-, 2-Decene, 7-methyl-, 7-methyl-, 2-Decene, 7-methyl-, 2-Decene, 1-Pentene, 2-methyl- 2-methyl- 1-Pentene, Heptamethyl-3,3-bis Heptamethyl-3,3-bis Cyclohexane, 1,3,5- 4-Methyl-2-heptene 4-Methyl-2-heptene [(acetyloxy)methyl] [(acetyloxy)methyl] Heptane, 4-methyl- 2-Pentanone, 3- 1,1,1,5,7,7,7- 1,1,1,5,7,7,7- Ethanone, 1- cyclopentyl- trimethyl-, trimethyl-, propyl- xane xane (Z)- (Z)- 2- -
1.43 2.75 1.43 4.78 1.91 5.90 2.53 3.55 1.55 1.94 38.39 2.12 7.81
25.406 25.199 14.286 14.170 14.047 10.638 10.567 6.873 5.929 5.618 3.710 2.597 1.757 1.672 1.582 Alpha.,3.alpha.,5.be Cyclohexane, 1,3,5- 1,3-Pentadiene, 2,3- Acetylcyclopentano Acetylcyclopentano Cyclononasiloxane, Heptane, 4-methyl- 11,11,13,13,15,15- 1,1,3,3,5,5,7,7,9,9, cyclohexanedione hexadecamethyl- octadecamethyl- 4-Isopropyl-1,3- 2,4-Dimethyl-1- 2-Undecene, 4- 2-Undecene, 4- 1-Silacyclo-3- trimethyl-, (1. trimethyl-, Octasiloxane, 2-Pentene, 4- 2-Pentene, 3- 1-Pentene, 2- methyl-, (Z)- (Z)- methyl-, methyl-, (Z)- (Z)- methyl-, dimethyl- methyl- methyl- methyl- heptene pentene ta.)- ta.)- ne ne 2- 2-
2.40 2.42 4.45 1.83 5.65 2.68 3.85 1.52 2.06 30.38 2.34 2.14 3.21 6.07 1.99
14.280 14.047 10.638 10.560 6.867 6.284 5.922 5.612 5.463 3.703 2.591 2.067 1.834 1.750 1.659 1.569 1.426 1,3-Pentadiene, 2,3- Cyclohexane,1,3,5- ,alpha.,3.alpha.,5.be Acetylcyclopentano Heptane, 4-methyl- 4-methyl- Heptane, Cyclopropane,1,2- 2-Hepten-4-one, 2- dihydro-5-methyl- 1H-Pyrazole, 4,5- Cyclopentene, 1- Cyclopentene, 2,3-Dimethyl-3- 2,4-Dimethyl-1- 2-Undecene,4- dimethyl-, cis- cis- dimethyl-, 2-Butene, 2,3- 2-Butene, 1-Silacyclo-3- 2-Pentene, 3- 1-Pentene, 2- heptene, (Z)- (Z)- heptene, Ethanone, 1- cyclopentyl- methyl-, €- €- methyl-, trimethyl- dimethyl- dimethyl- p-Xylene heptene pentene methyl- methyl- methyl- methyl- methyl- methyl- methyl- methyl- ta.)- ta.)- ne 2-
2.92 3.69 1.77 2.71 1.44 1.55 1.67 17.61 1.60 2.30 2.81 1.43 1.75 5.58 3.22 2.21 5.75
13.982 13.646 10.638 10.567 6.873 6.291 5.929 5.612 5.463 3.710 2.597 2.074 1.841 1.757 1.666 1.582 1.433 Cyclohexane, 1,3,5- Cyclohexane, ,alpha.,3.alpha.,5.be cyclohexyl dodecyl Heptane, 4-methyl- 4-methyl- Heptane, Cyclopropane, 1,2- 2-Hepten-4-one, 2- 2-Hepten-4-one, ethyl-3-octyl ester ester ethyl-3-octyl 2,4-Hexadiene, 2- 2,4-Hexadiene, 1-Dodecanone, 1- Cyclopentene, 1- Cyclopentene, butenoic acid,6- 2,4-Dimethyl-1- 1,1,2-trimethyl- 3-Dodecene, €- €- 3-Dodecene, 4- 2-Undecene, Cyclopropane, dimethyl-, cis- cis- dimethyl-, Benzene, 1,3- Benzene, 2-Pentene, 3- 2-Pentene, 3- 2-Pentene, 2- 1-Pentene, methyl-, (Z)- (Z)- methyl-, cyclopropyl- cyclopropyl- 3-Methyl-2- Oxalic acid, trimethyl- dimethyl- methyl- methyl- methyl- heptene methyl- methyl- methyl- methyl- methyl- methyl- methyl- methyl- ester ta.)- ta.)-
1.56 1.60 1.80 2.74 1.78 2.46 1.57 14.71 1.79 3.03 2.86 1.67 1.56 5.33 2.42 3.17 5.68
24.358 23.058 21.796 21.641 20.108 methoxyquinolinate Cyclononasiloxane, Cyclodecasiloxane, 11,11,13,13,15,15- 1,1,3,3,5,5,7,7,9,9, Methylbutoxy)-7- hexadecamethyl- octadecamethyl- eicosamethyl- eicosamethyl- Octasiloxane, heptyl-2,2,4, Dimethyl 6- Dimethyl 1-(2-
1.24 1.60 1.35 1.53 2.41
14.286 14.047 Acetylcyclopentano Hexane, 3-ethyl- ne 2-
3.34 4.08