Table S1. GC-MS Compounds Generated at 5 °C/Min
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Table S1. GC-MS compounds generated at 5 °C/min. 0 wt.% 10 wt.% 30 wt.% 50 wt.% GC GC GC GC Compounds Compounds Compounds Compounds Area (%) Area (%) Area (%) Area (%) Time (min.) (min.) Time Time (min.) (min.) Time (min.) Time (min.) Time Propene Propene Propene Propene 7.42 7.42 1.26 5.47 1.20 7.38 1.200 1.200 1.200 1.214 1.214 1-Propene, 2- 1-Propene, 2- methyl- 1-Propene, 2-methyl- 1-Propene, 2-methyl- 7.34 7.34 2.41 methyl- 1.245 1.245 1.245 1.259 1.259 10.54 1.246 14.90 Pentane Pentane Pentane Pentane 3.79 3.79 1.375 1.375 1.395 1.395 11.81 1.381 13.17 1.375 12.83 1-Pentene, 2- 2-Butene, 2- 2-Butene, 2-methyl- 2-Butene, 2-methyl- methyl- 7.25 0.93 methyl- 4.65 5.71 1.426 1.426 1.420 1.420 1.679 1.679 1H-Pyrazole, 4,5- Heptane, 4- 1H-Pyrazole, 4,5- 1-Pentene, 2-methyl- dihydro-5- methyl- 1.92 1.57 2.25 dihydro-5-methyl- 2.44 1.659 1.659 1.562 1.569 3.762 3.762 methyl- 2,4-Dimethyl-1- 1-Pentene, 2- heptene 2-Butene, 2,3-dimethyl- 1-Pentene, 2-methyl- 1.27 1.27 methyl- 3.08 2.33 1.653 1.653 1.653 5.671 5.671 34.57 1.750 Cyclohexane, 1,3,5-trimethyl-, 2-Pentene, 3- 2,4-Dimethyl-1-heptene 2-Pentene, 2-methyl- alpha.,3.alpha.,5.b 2.03 9.11 methyl-, €- 6.11 5.73 5.605 5.605 1.743 1.744 5.981 5.981 eta.)- 5-Aminoisoxazole 2-Pentene, 3- 2-Pentene, 3-methyl-, Spermine Ethanone, 1-cyclopentyl- 1.55 1.55 1.32 methyl-, (Z)- 1.59 €- 1.46 1.828 1.828 1.828 6.925 6.925 10.560 Ethanone, 1- 1R,2c,3t,4t-Tetramethyl- 1,3-Pentadiene, 1,4-Hexadiene, 5- cyclopentyl- 3.57 3.57 cyclohexan 0.97 2,3-dimethyl- 2.28 methyl- 2.31 2.584 2.584 2.585 10.613 10.613 10.638 N- Heptane, 2-methyl-3- Heptane, 4- Methylallylamine Toluene 2.49 2.49 methylene- 2.50 methyl- 2.97 4.31 3.697 3.697 3.697 14.047 14.047 10.684 10.684 2-Undecene, 4- Cyclopentane, (2- 2,4-Dimethyl-1- 2,4-Dimethyl-1- methyl- 7.81 7.81 methylbutyl)- 1.00 heptene heptene 5.605 5.605 22.29 22.29 5.605 12.95 14.086 14.086 14.163 Cyclohexane, Cyclohexane, 1,3,5- 2-Decene, 7- 1,3,5-trimethyl-, trimethyl- methyl-, (Z)- Hexane, 2,3,4-trimethyl- (1. 2.30 2.30 2.67 2.67 2.12 ,alpha.,3.alpha.,5.beta.) 1.56 5.922 5.922 5.922 5.922 14.203 14.203 14.280 Alpha.,3.alpha.,5. - beta.)- Dichloroacetic acid, 6-ethyl-3-oct Fumaric acid, nonyl 2,3,6- p-Xylene p-Xylene yl ester 6.92 trichlorophenyl ester 7.42 1.59 3.82 6.297 6.297 6.285 14.326 14.326 21.628 Cyclododecaneme Cyclodecasiloxane, 1-Undecene, 7- Benzene, 1-ethyl-2- thanol 1.31 1.31 2.28 3.17 1.89 eicosamethyl- methyl- 8.374 methyl- 15.063 15.063 21.732 10.567 Acetic acid, 4,4’- trifluoro-, 3,7- Ethanone, 1- (Hexafluoroisopropylidene 1-Undecene, 7-methyl- dimethyloctyl 1.35 4.14 cyclopentyl- 2.39 2.08 22.579 22.579 10.638 10.560 16.920 16.920 )diphenol ester 2- 1R,2c,3t,4t- 4-Thiazolemethanol, 2-(4- Acetylcyclopenta Tetramethyl- chlorophenyl)- 7.75 6.28 1.58 14.047 14.047 10.638 23.051 23.051 none cyclohexan Cyclodecasiloxane, Cyclopentane, (2- 1H-1,2,4-Triazole, 3- eicosamethyl- 4.65 methylbutyl)- 2.34 (2-methylpropyl)- 1.61 23.219 23.219 14.163 14.163 13.646 Fumaric acid, nonyl 2,3,6- Cyanamide, Cyclohexanone, 3,3,5- trichlorophenyl ester 6.94 dibutyl- 5.61 trimethyl- 1.71 14.286 14.286 13.982 24.358 24.358 Octasiloxane, Cyclononasiloxane, 1,1,3,3,5,5,7,7,9, 2- octadecamethyl- 4.94 11,11,13,13,15,15 1.92 Acetylcyclopentanone 4.28 24.513 24.513 16.498 16.498 -hexadecamethyl- 14.047 Pyrazole-4-carboxamide, 2-Undecene, 4-methyl- 3-(1-adamantyl)-1-phenyl- 2.67 1.63 14.163 14.163 24.655 24.655 4-Nitro-4’- 2- chlorodiphenylsulfoxide 6.62 Acetylcyclopentanone 3.76 25.606 25.606 14.280 14.280 Cyclohexane, 1,1’-(2- Cyclononasiloxane, ethyl-1,3- octadecamethyl- 5.53 1.57 25.768 25.768 16.499 16.499 propanediyl)bis- 1,1,1,5,7,7,7- 4-Nitro-4’- Heptamethyl-3,3- chlorodiphenylsulfoxide 5.01 bistrimethylsiloxy)tetra 2.17 20.257 20.257 27.172 27.172 siloxane Cyclodecasiloxane, eicosamethyl- 5.67 27.340 27.340 Pentasiloxane, dodecamethyl- 3.31 29.352 29.352 Hexasiloxane, tetradecamethyl- 4.83 29.487 29.487 Table S2. GC-MS compounds generated at 30 °C/min. 0 wt.% 10 wt.% 30 wt.% 50 wt.% GC GC GC GC Compounds Compounds Compounds Compounds Area (%) Area (%) Area (%) Area (%) Time (min.) Time (min.) Time (min.) Time (min.) Propene Propene Propene Propene 7.60 7.60 3.95 6.46 6.89 1.214 1.214 1.213 1.213 1.200 1.213 1-Propene, 2-methyl- 1-Propene, 2- 1-Propene, 2- 1-Propene, 2- 4.23 4.23 7.59 methyl- methyl- methyl- 1.258 1.258 1.245 1.259 1.259 12.88 1.258 14.95 Pentane Pentane Pentane Pentane 1.395 1.395 12.09 1.394 15.46 1.381 12.49 1.388 15.02 1-Pentene, 2-methyl- 2-Pentene, 4- Cyclopropane, 1,2- Cyclopropane, 1,2- 7.81 7.81 1.99 5.75 5.68 methyl-, (Z)- dimethyl-, cis- dimethyl-, cis- 1.582 1.582 1.426 1.433 1.679 1.679 Heptane, 4-methyl- 1-Pentene, 2- 1H-Pyrazole, 4,5- Cyclopropane, 2.12 2.12 6.07 2.21 3.17 methyl- dihydro-5-methyl- 1,1,2-trimethyl- 1.672 1.672 1.569 1.582 3.756 3.756 2,4-Dimethyl-1-heptene 2-Pentene, 3- 1-Pentene, 2- 1-Pentene, 2- 3.21 3.21 3.22 2.42 methyl-, (Z)- methyl- methyl- 1.659 1.659 1.666 5.671 5.671 38.39 1.757 Cyclohexane, 1,3,5- trimethyl-, 1,3-Pentadiene, 2,3- 2-Butene, 2,3- 2-Pentene, 3- alpha.,3.alpha.,5.alpha.) 1.94 dimethyl- 2.14 dimethyl- 5.58 methyl-, (Z)- 5.33 2.597 2.597 1.750 1.757 5.981 5.981 - 2-Pentanone, 3- [(acetyloxy)methyl] 2-Pentene, 3- 2-Pentene, 3- Heptane, 4-methyl- -3,4-dimethyl-, (.+-.)- 1.55 2.34 methyl-, €- 1.75 methyl- 1.56 3.710 3.710 1.834 1.841 6.926 6.926 2- Ethanone, 1- 2,4-Dimethyl-1- Cyclopentene, 1- Cyclopentene, 1- cyclopentyl- 3.55 3.55 heptene methyl- 1.43 methyl- 1.67 5.618 5.618 2.074 30.38 30.38 2.067 10.606 10.606 Cyclohexane, 1,3,5- 4-Methyl-2-heptene trimethyl-, (1. 1,3-Pentadiene, 2,3- 2,4-Hexadiene, 2- 2.53 Alpha.,3.alpha.,5.be 2.06 dimethyl- 2.81 methyl- 2.86 5.929 5.929 2.591 2.597 10.677 10.677 ta.)- 2-Decene, 7-methyl-, 1-Silacyclo-3- (Z)- Heptane, 4-methyl- Heptane, 4-methyl- 5.90 5.90 pentene 1.52 2.30 3.03 6.873 6.873 3.703 3.710 14.086 14.086 2-Decene, 7-methyl-, 2-Undecene, 4- 2-Hepten-4-one, 2- 2-Hepten-4-one, 2- (Z)- 1.91 1.91 methyl- 3.85 methyl- 1.60 methyl- 1.79 5.463 5.463 5.463 10.567 10.567 14.203 14.203 4-Decene, 3-methyl-, €- 2-Undecene, 4- 2,4-Dimethyl-1- 2,4-Dimethyl-1- 4.78 4.78 2.68 methyl- heptene heptene 5.612 5.612 17.61 17.61 5.612 14.71 14.319 14.319 10.638 10.638 Cyclohexane, 1,3,5- Cyclohexane, 1,3,5- Cyclohexane, 1-ethyl-2- 2- trimethyl- trimethyl- propyl- Acetylcyclopentano 1.43 1.43 5.65 ,alpha.,3.alpha.,5.be 1.67 ,alpha.,3.alpha.,5.be 1.57 5.922 5.922 5.929 19.378 19.378 14.047 ne ta.)- ta.)- 1,1,1,5,7,7,7- 2- Heptamethyl-3,3-bis Benzene, 1,3- Acetylcyclopentano p-Xylene trimethylsiloxy)tetrasilo 2.75 1.83 1.55 dimethyl- 2.46 6.284 6.284 6.291 20.290 20.290 14.170 14.170 ne xane 1,1,1,5,7,7,7- Heptamethyl-3,3-bis 4-Isopropyl-1,3- 1-Silacyclo-3- 1-Dodecanone, 1- trimethylsiloxy)tetrasilo 1.43 cyclohexanedione 4.45 pentene 1.44 cyclopropyl- 1.78 6.867 6.867 6.873 14.286 14.286 21.849 21.849 xane Cyclononasiloxane, 2-Undecene, 4- 2-Undecene, 4- octadecamethyl- 2.42 methyl- 2.71 methyl- 2.74 25.199 25.199 10.560 10.560 10.567 Octasiloxane, 1,1,3,3,5,5,7,7,9,9, Ethanone, 1- 3-Dodecene, €- 11,11,13,13,15,15- 2.40 cyclopentyl- 1.77 1.80 25.406 25.406 10.638 10.638 10.638 hexadecamethyl- 2- Oxalic acid, Acetylcyclopentano cyclohexyl dodecyl 3.69 3.69 1.60 14.047 14.047 ne 13.646 ester 3-Methyl-2- 2,3-Dimethyl-3- butenoic acid, 6- heptene, (Z)- 2.92 1.56 14.280 14.280 13.982 13.982 ethyl-3-octyl ester 2- Cyclononasiloxane, Acetylcyclopentano octadecamethyl- 2.41 4.08 20.108 20.108 14.047 14.047 ne 1-(2- Methylbutoxy)-7- Hexane, 3-ethyl- 1.53 1.53 3.34 21.641 21.641 heptyl-2,2,4, 14.286 Cyclodecasiloxane, eicosamethyl- 1.35 21.796 21.796 Dimethyl 6- methoxyquinolinate 1.60 23.058 23.058 Octasiloxane, 1,1,3,3,5,5,7,7,9,9, 11,11,13,13,15,15- 1.24 24.358 24.358 hexadecamethyl- .