Table S1. GC-MS Compounds Generated at 5 °C/Min

Table S1. GC-MS Compounds Generated at 5 °C/Min

Table S1. GC-MS compounds generated at 5 °C/min. 0 wt.% 10 wt.% 30 wt.% 50 wt.% GC GC GC GC Compounds Compounds Compounds Compounds Area (%) Area (%) Area (%) Area (%) Time (min.) (min.) Time Time (min.) (min.) Time (min.) Time (min.) Time Propene Propene Propene Propene 7.42 7.42 1.26 5.47 1.20 7.38 1.200 1.200 1.200 1.214 1.214 1-Propene, 2- 1-Propene, 2- methyl- 1-Propene, 2-methyl- 1-Propene, 2-methyl- 7.34 7.34 2.41 methyl- 1.245 1.245 1.245 1.259 1.259 10.54 1.246 14.90 Pentane Pentane Pentane Pentane 3.79 3.79 1.375 1.375 1.395 1.395 11.81 1.381 13.17 1.375 12.83 1-Pentene, 2- 2-Butene, 2- 2-Butene, 2-methyl- 2-Butene, 2-methyl- methyl- 7.25 0.93 methyl- 4.65 5.71 1.426 1.426 1.420 1.420 1.679 1.679 1H-Pyrazole, 4,5- Heptane, 4- 1H-Pyrazole, 4,5- 1-Pentene, 2-methyl- dihydro-5- methyl- 1.92 1.57 2.25 dihydro-5-methyl- 2.44 1.659 1.659 1.562 1.569 3.762 3.762 methyl- 2,4-Dimethyl-1- 1-Pentene, 2- heptene 2-Butene, 2,3-dimethyl- 1-Pentene, 2-methyl- 1.27 1.27 methyl- 3.08 2.33 1.653 1.653 1.653 5.671 5.671 34.57 1.750 Cyclohexane, 1,3,5-trimethyl-, 2-Pentene, 3- 2,4-Dimethyl-1-heptene 2-Pentene, 2-methyl- alpha.,3.alpha.,5.b 2.03 9.11 methyl-, €- 6.11 5.73 5.605 5.605 1.743 1.744 5.981 5.981 eta.)- 5-Aminoisoxazole 2-Pentene, 3- 2-Pentene, 3-methyl-, Spermine Ethanone, 1-cyclopentyl- 1.55 1.55 1.32 methyl-, (Z)- 1.59 €- 1.46 1.828 1.828 1.828 6.925 6.925 10.560 Ethanone, 1- 1R,2c,3t,4t-Tetramethyl- 1,3-Pentadiene, 1,4-Hexadiene, 5- cyclopentyl- 3.57 3.57 cyclohexan 0.97 2,3-dimethyl- 2.28 methyl- 2.31 2.584 2.584 2.585 10.613 10.613 10.638 N- Heptane, 2-methyl-3- Heptane, 4- Methylallylamine Toluene 2.49 2.49 methylene- 2.50 methyl- 2.97 4.31 3.697 3.697 3.697 14.047 14.047 10.684 10.684 2-Undecene, 4- Cyclopentane, (2- 2,4-Dimethyl-1- 2,4-Dimethyl-1- methyl- 7.81 7.81 methylbutyl)- 1.00 heptene heptene 5.605 5.605 22.29 22.29 5.605 12.95 14.086 14.086 14.163 Cyclohexane, Cyclohexane, 1,3,5- 2-Decene, 7- 1,3,5-trimethyl-, trimethyl- methyl-, (Z)- Hexane, 2,3,4-trimethyl- (1. 2.30 2.30 2.67 2.67 2.12 ,alpha.,3.alpha.,5.beta.) 1.56 5.922 5.922 5.922 5.922 14.203 14.203 14.280 Alpha.,3.alpha.,5. - beta.)- Dichloroacetic acid, 6-ethyl-3-oct Fumaric acid, nonyl 2,3,6- p-Xylene p-Xylene yl ester 6.92 trichlorophenyl ester 7.42 1.59 3.82 6.297 6.297 6.285 14.326 14.326 21.628 Cyclododecaneme Cyclodecasiloxane, 1-Undecene, 7- Benzene, 1-ethyl-2- thanol 1.31 1.31 2.28 3.17 1.89 eicosamethyl- methyl- 8.374 methyl- 15.063 15.063 21.732 10.567 Acetic acid, 4,4’- trifluoro-, 3,7- Ethanone, 1- (Hexafluoroisopropylidene 1-Undecene, 7-methyl- dimethyloctyl 1.35 4.14 cyclopentyl- 2.39 2.08 22.579 22.579 10.638 10.560 16.920 16.920 )diphenol ester 2- 1R,2c,3t,4t- 4-Thiazolemethanol, 2-(4- Acetylcyclopenta Tetramethyl- chlorophenyl)- 7.75 6.28 1.58 14.047 14.047 10.638 23.051 23.051 none cyclohexan Cyclodecasiloxane, Cyclopentane, (2- 1H-1,2,4-Triazole, 3- eicosamethyl- 4.65 methylbutyl)- 2.34 (2-methylpropyl)- 1.61 23.219 23.219 14.163 14.163 13.646 Fumaric acid, nonyl 2,3,6- Cyanamide, Cyclohexanone, 3,3,5- trichlorophenyl ester 6.94 dibutyl- 5.61 trimethyl- 1.71 14.286 14.286 13.982 24.358 24.358 Octasiloxane, Cyclononasiloxane, 1,1,3,3,5,5,7,7,9, 2- octadecamethyl- 4.94 11,11,13,13,15,15 1.92 Acetylcyclopentanone 4.28 24.513 24.513 16.498 16.498 -hexadecamethyl- 14.047 Pyrazole-4-carboxamide, 2-Undecene, 4-methyl- 3-(1-adamantyl)-1-phenyl- 2.67 1.63 14.163 14.163 24.655 24.655 4-Nitro-4’- 2- chlorodiphenylsulfoxide 6.62 Acetylcyclopentanone 3.76 25.606 25.606 14.280 14.280 Cyclohexane, 1,1’-(2- Cyclononasiloxane, ethyl-1,3- octadecamethyl- 5.53 1.57 25.768 25.768 16.499 16.499 propanediyl)bis- 1,1,1,5,7,7,7- 4-Nitro-4’- Heptamethyl-3,3- chlorodiphenylsulfoxide 5.01 bistrimethylsiloxy)tetra 2.17 20.257 20.257 27.172 27.172 siloxane Cyclodecasiloxane, eicosamethyl- 5.67 27.340 27.340 Pentasiloxane, dodecamethyl- 3.31 29.352 29.352 Hexasiloxane, tetradecamethyl- 4.83 29.487 29.487 Table S2. GC-MS compounds generated at 30 °C/min. 0 wt.% 10 wt.% 30 wt.% 50 wt.% GC GC GC GC Compounds Compounds Compounds Compounds Area (%) Area (%) Area (%) Area (%) Time (min.) Time (min.) Time (min.) Time (min.) Propene Propene Propene Propene 7.60 7.60 3.95 6.46 6.89 1.214 1.214 1.213 1.213 1.200 1.213 1-Propene, 2-methyl- 1-Propene, 2- 1-Propene, 2- 1-Propene, 2- 4.23 4.23 7.59 methyl- methyl- methyl- 1.258 1.258 1.245 1.259 1.259 12.88 1.258 14.95 Pentane Pentane Pentane Pentane 1.395 1.395 12.09 1.394 15.46 1.381 12.49 1.388 15.02 1-Pentene, 2-methyl- 2-Pentene, 4- Cyclopropane, 1,2- Cyclopropane, 1,2- 7.81 7.81 1.99 5.75 5.68 methyl-, (Z)- dimethyl-, cis- dimethyl-, cis- 1.582 1.582 1.426 1.433 1.679 1.679 Heptane, 4-methyl- 1-Pentene, 2- 1H-Pyrazole, 4,5- Cyclopropane, 2.12 2.12 6.07 2.21 3.17 methyl- dihydro-5-methyl- 1,1,2-trimethyl- 1.672 1.672 1.569 1.582 3.756 3.756 2,4-Dimethyl-1-heptene 2-Pentene, 3- 1-Pentene, 2- 1-Pentene, 2- 3.21 3.21 3.22 2.42 methyl-, (Z)- methyl- methyl- 1.659 1.659 1.666 5.671 5.671 38.39 1.757 Cyclohexane, 1,3,5- trimethyl-, 1,3-Pentadiene, 2,3- 2-Butene, 2,3- 2-Pentene, 3- alpha.,3.alpha.,5.alpha.) 1.94 dimethyl- 2.14 dimethyl- 5.58 methyl-, (Z)- 5.33 2.597 2.597 1.750 1.757 5.981 5.981 - 2-Pentanone, 3- [(acetyloxy)methyl] 2-Pentene, 3- 2-Pentene, 3- Heptane, 4-methyl- -3,4-dimethyl-, (.+-.)- 1.55 2.34 methyl-, €- 1.75 methyl- 1.56 3.710 3.710 1.834 1.841 6.926 6.926 2- Ethanone, 1- 2,4-Dimethyl-1- Cyclopentene, 1- Cyclopentene, 1- cyclopentyl- 3.55 3.55 heptene methyl- 1.43 methyl- 1.67 5.618 5.618 2.074 30.38 30.38 2.067 10.606 10.606 Cyclohexane, 1,3,5- 4-Methyl-2-heptene trimethyl-, (1. 1,3-Pentadiene, 2,3- 2,4-Hexadiene, 2- 2.53 Alpha.,3.alpha.,5.be 2.06 dimethyl- 2.81 methyl- 2.86 5.929 5.929 2.591 2.597 10.677 10.677 ta.)- 2-Decene, 7-methyl-, 1-Silacyclo-3- (Z)- Heptane, 4-methyl- Heptane, 4-methyl- 5.90 5.90 pentene 1.52 2.30 3.03 6.873 6.873 3.703 3.710 14.086 14.086 2-Decene, 7-methyl-, 2-Undecene, 4- 2-Hepten-4-one, 2- 2-Hepten-4-one, 2- (Z)- 1.91 1.91 methyl- 3.85 methyl- 1.60 methyl- 1.79 5.463 5.463 5.463 10.567 10.567 14.203 14.203 4-Decene, 3-methyl-, €- 2-Undecene, 4- 2,4-Dimethyl-1- 2,4-Dimethyl-1- 4.78 4.78 2.68 methyl- heptene heptene 5.612 5.612 17.61 17.61 5.612 14.71 14.319 14.319 10.638 10.638 Cyclohexane, 1,3,5- Cyclohexane, 1,3,5- Cyclohexane, 1-ethyl-2- 2- trimethyl- trimethyl- propyl- Acetylcyclopentano 1.43 1.43 5.65 ,alpha.,3.alpha.,5.be 1.67 ,alpha.,3.alpha.,5.be 1.57 5.922 5.922 5.929 19.378 19.378 14.047 ne ta.)- ta.)- 1,1,1,5,7,7,7- 2- Heptamethyl-3,3-bis Benzene, 1,3- Acetylcyclopentano p-Xylene trimethylsiloxy)tetrasilo 2.75 1.83 1.55 dimethyl- 2.46 6.284 6.284 6.291 20.290 20.290 14.170 14.170 ne xane 1,1,1,5,7,7,7- Heptamethyl-3,3-bis 4-Isopropyl-1,3- 1-Silacyclo-3- 1-Dodecanone, 1- trimethylsiloxy)tetrasilo 1.43 cyclohexanedione 4.45 pentene 1.44 cyclopropyl- 1.78 6.867 6.867 6.873 14.286 14.286 21.849 21.849 xane Cyclononasiloxane, 2-Undecene, 4- 2-Undecene, 4- octadecamethyl- 2.42 methyl- 2.71 methyl- 2.74 25.199 25.199 10.560 10.560 10.567 Octasiloxane, 1,1,3,3,5,5,7,7,9,9, Ethanone, 1- 3-Dodecene, €- 11,11,13,13,15,15- 2.40 cyclopentyl- 1.77 1.80 25.406 25.406 10.638 10.638 10.638 hexadecamethyl- 2- Oxalic acid, Acetylcyclopentano cyclohexyl dodecyl 3.69 3.69 1.60 14.047 14.047 ne 13.646 ester 3-Methyl-2- 2,3-Dimethyl-3- butenoic acid, 6- heptene, (Z)- 2.92 1.56 14.280 14.280 13.982 13.982 ethyl-3-octyl ester 2- Cyclononasiloxane, Acetylcyclopentano octadecamethyl- 2.41 4.08 20.108 20.108 14.047 14.047 ne 1-(2- Methylbutoxy)-7- Hexane, 3-ethyl- 1.53 1.53 3.34 21.641 21.641 heptyl-2,2,4, 14.286 Cyclodecasiloxane, eicosamethyl- 1.35 21.796 21.796 Dimethyl 6- methoxyquinolinate 1.60 23.058 23.058 Octasiloxane, 1,1,3,3,5,5,7,7,9,9, 11,11,13,13,15,15- 1.24 24.358 24.358 hexadecamethyl- .

View Full Text

Details

  • File Type
    pdf
  • Upload Time
    -
  • Content Languages
    English
  • Upload User
    Anonymous/Not logged-in
  • File Pages
    4 Page
  • File Size
    -

Download

Channel Download Status
Express Download Enable

Copyright

We respect the copyrights and intellectual property rights of all users. All uploaded documents are either original works of the uploader or authorized works of the rightful owners.

  • Not to be reproduced or distributed without explicit permission.
  • Not used for commercial purposes outside of approved use cases.
  • Not used to infringe on the rights of the original creators.
  • If you believe any content infringes your copyright, please contact us immediately.

Support

For help with questions, suggestions, or problems, please contact us