Engineering Analysis Page: 1 of 6
Facility Name: The Anthony Galluzzo Corporation Engineer: chm Facility Location: Londonderry Date: 06/07/07 Facility ID No.: 3301590806 Application No.: FY05-0200
BOILER EMISSIONS
Data Inputs (Fuel Supply = 100% Wood): Heat Input : 3.9 MMBtu/hr Fuel Heating Value: 8,000 BTU/lb Potential Fuel Usage Rate: 0.24 ton/hr Potential Fuel Usage Rate: 2,102 ton/yr Permitted Fuel Usage Rate: 2,016 ton/yr
Analysis of Criteria Pollutants (Fuel Supply = 100% Wood): Emission Factor Emissions Pollutant Maximum Hourly Potential Annual Permitted Annual lb/MMBtu lb/ton lb/hr ton/yr ton/yr Permit TSP 0.30 a 4.80 1.15 5.05 4.84 Existing TSP 0.30 b,c 4.80 1.15 5.05 4.84
PM 10 0.287 b,d 4.59 1.10 4.83 4.63 3.19
SO 2 0.025 b 0.40 0.10 0.42 0.40 0.08 NOx 0.49 b 7.84 1.88 8.24 7.90 0.38 CO 0.60 b 9.60 2.30 10.09 9.68 6.65 VOC 0.017 b 0.27 0.07 0.29 0.27 0.04 a NH maximum allowable particulate emission rate as set forth in Env-A 2002.08 (c)(1). b USEPA, Compilation of Air Pollutant Emission Factors , AP-42, 5th Ed., Vol.1, Section 1.6 - Wood Residue Combustion in Boilers (9/03). c TSP is considered to be equal to filterable PM. d PM 10 is considered to be equal to the sum of filterable PM 10 and condensable PM.
Assumptions: Wood fuel is dry (<20% moisture per AP-42). Permitted fuel usage rates are as prescribed in the existing permit.
Sample calculations for NOx (fuel supply = 100% wood): Maximum Hourly: 0.49 lb/MMBtu x 0.008 MMBtu/lb x 0.24 ton/hr x 2000lb/ton = 1.88 lb/hr Potential Annual: 1.88 lb/hr x 8760 hr/yr ÷ 2000 lb/ton = 8.24 ton/yr Permitted Annual: 7.84 lb/ton x 2016 ton/yr ÷ 2000lb/ton = 7.90 ton/yr Engineering Analysis Page: 2 of 6
Facility Name: The Anthony Galluzzo Corporation Engineer: chm Facility Location: Londonderry Date: 06/07/07 Facility ID No.: 3301590806 Application No.: FY05-0200
SPRAY COAT EMISSIONS
Coating Usage Rates: Hourly a gal/hr 5.625 Daily b gal/day 45 Annual gal/yr 16,425
Potential Emissions: Maximum VOCs Maximum HAPs Maximum PM Category 10 Emitted c Emitted d Emitted e Hourly a lb/hr 46.1 40.3 0.0 Daily ton/day 0.18 0.16 0.009 Annual ton/yr 67.3 58.9 0.0 Permitted Annual f ton/yr <25 <10 / <25 <100 a Based on one 8-hour work shift per day. b Operating restriction imposed by existing permit. c Based on use of coating with highest VOC content (P98 Solvent Borne Adhesive) = 8.2 lb VOCs per gallon of coating. Sample calculation: 16,425 gal/yr x 8.2 lb VOCs/gal ÷ 2,000 lb/ton = 67.3 ton VOCs/yr d Based on use of coating with highest HAPs content (xylene) = 7.17 lb HAPs per gallon of coating. Sample calculation: 5.625 gal/hr x 7.17 lb HAPs/gal = 40.3 lb HAPs/hr e Based on use of pigmented coating with hypothetical 50% solids content, 8 lb/gal density, and 10% emissions rate: Sample calculation: 45 gal/day x 8 lb/gal x 0.50 x 0.10 ÷ 2000 lb/ton = 0.009 ton/day f Facility-wide emissions limitations under existing permit: 25 ton/yr VOCs limit is to exempt facility from VOC RACT provisions. 25 ton/yr HAPs limit is to exempt facility from Title V provisions. Engineering Analysis Page: 3 of 6
Facility Name: The Anthony Galluzzo Corporation Engineer: chm Facility Location: Londonderry Date: 06/07/07 Facility ID No.: 3301590806 Application No.: FY05-0200
TOTAL FACILITY EMISSIONS Annual Emissions from Wood-Fired Boiler and Spray Coating Process (all values in ton/yr)
Potential Annual Emissions: Wood-Fired Spray Coating Combined Pollutant Boiler Process Emissions
PM 10 4.83 0.00 4.83 SO 2 0.42 – 0.42 NOx 8.24 – 8.24 CO 10.09 – 10.09 VOCs 0.29 67.34 67.63 Total: 91.21 HAPs – 58.88 58.88
2006 Annual Emissions a: Wood-Fired Spray Coating Combined Pollutant Boiler Process Emissions
PM 10 0.11 – 0.11 SO 2 0.01 – 0.01 NOx 0.19 – 0.19 CO 0.23 – 0.23 VOCs 0.01 2.85 2.86 Total: 3.40 HAPs – 0.022 0.022 a Emissions as reported by applicant in 2006 Annual Report.
Note: Emissions from the burning of fuel oil are not included. Engineering Analysis Page: 4 of 6
Facility Name: The Anthony Galluzzo Corporation Engineer: chm Facility Location: Londonderry Date: 06/07/07 Facility ID No.: 3301590806 Application No.: FY05-0200
RTAPs ANALYSIS (see also Attachment A)
1. Compare Emissions against de Minimus Values: Spray Coating Usage RTAP Emissions c RTAP CAS Maximum RTAP % 24-Hour 24-Hour Annual Annual (Coating Product a ) Number lb/day b by Weight lb/day de Minimus lb/yr de Minimus lb/day lb/yr Formaldehyde 50-00-0 361.8 0.8 2.89 0.010 1,056 3.8 (V84 F 62 KEMVAR) Toluene 108-88-3 298.8 31 92.6 5.3 33,809 1,927 (Sol-Lac Thinner R7 K 119) a Product named is the one having highest RTAP concentration of all products listed for spray coating process. bMaximum allowed coating usage of 45 gal/day converted to lb/day based on product density. c De minimus values taken from Code of Administrative Rules Env-A 1450, Table 1450-1. Sample calculation for formaldehyde: Usage rate: 45 gal/day x 8.04 lb/gal = 361.8 lb/day Emission rate: 361.8 lb/day x 0.008 = 2.89 lb/day = 1,056 lb/yr Number in boldface denotes exceedence of de minimus emission value.
2. Compare In-Stack Concentrations against AALs: 24-Hour Emissions Annual Emissions RTAP CAS Emissions In-Stack Conc. AAL Emissions In-Stack Conc. AAL (Coating Product a ) Number lb/day ug/m 3 ug/m 3 lb/yr ug/m 3 ug/m 3 Formaldehyde 50-00-0 2.89 3.66 1.3 1,056 3.66 0.88 (V84 F 62 KEMVAR) Toluene 108-88-3 92.6 117 671 33,809 117 400 (Sol-Lac Thinner R7 K 119) Stack data for 2 spray booths (combined): A = 2 x 3.14 ft 2 Q = 22,000 acfm V = 58.4 ft/sec In-stack concentrations are adjusted values (divided by 400) to account for dispersion. Sample calculations for formaldehyde: 24-hour: 2.89 lb/day x 4.536 x 10 8 ug/lb ÷ 1,440 min/day ÷ 22,000 ft 3/min x 35.31 ft 3/m 3 ÷ 400 = 3.66 ug/m 3 Annual: 1,056 lb/yr x 4.536 x 10 8 ug/lb ÷ 525,600 min/yr ÷ 22,000 ft 3/min x 35.31 ft 3/m 3 ÷ 400 = 3.66 ug/m 3 Value in boldface italics denotes exceedence of AAL.
3. Compare Modeled Impacts against AALs: 24-Hour Emissions Annual Emissions RTAP CAS Emissions Mod. Impact AAL Emissions Mod. Impact AAL (Coating Product a ) Number lb/day ug/m 3 ug/m 3 lb/yr ug/m 3 ug/m 3 Formaldehyde 50-00-0 2.89 5.37 1.3 1,056 1.55 0.88 (V84 F 62 KEMVAR) Toluene 108-88-3 92.6 172 671 33,809 50 400 (Sol-Lac Thinner R7 K 119) Modeled impacts are calculated using site-specific unit impact factors: 353.3 ug/m 3 per g/sec and 102.2 ug/m 3 per g/sec for 24-hour and annual emissions, respectively. Sample calculations for formaldehyde: 24-hour: 2.89 lb/day ÷ 24 hr/day x 0.126 g/sec / lb/hr x 353.3 ug/m 3 / g/sec = 5.37 ug/m 3 Annual: 2.89 lb/day ÷ 24 hr/day x 0.126 g/sec / lb/hr x 102.2 ug/m 3 / g/sec = 1.55 ug/m 3 Value in boldface italics denotes exceedence of AAL. Attachment A – RTAPs Analysis Page: 5 of 6 Facility Name: The Anthony Galluzzo Corporation Engineer: chm Facility Location: Londonderry Date: 06/07/07 Facility ID No.: 3301590806 Application No.: FY05-0200
Maximum Emision Rate Modeled Impact de Minimis Value Ambient Air Limit CAS Number Chemical Name Hourly 24-Hour Annual 24-Hour Annual 24-Hour Annual 24-Hour Annual 3 3 3 3 lb/hr lb/day lb/yr µg/m µg/m lb/day lb/yr µg/m µg/m Method Compliance 50 - 0 - 0 Formaldehyde 0.12 2.89 1,056 5.37 1.55 0.010 3.8 1.3 0.88 R 64 - 17 - 5 Ethanol 11.31 271.44 99,076 503.47 145.64 74 27,147 9,457 6,304 M 67 - 56 - 1 Methanol 12.3 295.20 107,748 547.54 158.39 10 3,783 1,318 879 M 67 - 63 - 0 Isopropyl alcohol (2-Propanol) 4.33 103.92 37,931 192.75 55.76 14 5,044 1,757 1,171 M 67 - 64 - 1 Acetone (2-Propanone) 6.93 166.27 60,689 308.41 89.21 33 12,180 4,243 2,829 M 71 - 23 - 8 n- Propyl alcohol 0.00428 0.10 37 0.19 0.06 27 9,946 3,465 1,650 D 71 - 36 - 3 n- Butanol 2.24 53.76 19,622 99.72 28.84 2.4 875 305 203 M 71 - 55 - 6 1,1,1- Trichloroethane (Methyl chloroform) 15.27 366.48 133,765 679.76 196.63 54 19,582 6,821 4,548 M 78 - 83 - 1 2- Methyl-1-propanol (Isobutyl alcohol) 2.359 56.62 20,665 105.01 30.38 6.0 2,195 765 510 M 78 - 93 - 3 Methyl ethyl ketone (MEK) 7.1 170.40 62,196 316.06 91.43 39 14,353 5,000 5,000 M 84 - 74 - 2 Dibutyl phthalate 0.72 17.28 6,307 32.05 9.27 0.20 72 25 17 R 95 - 63 - 6 1,2,4- Trimethylbenzene (as Trimethylbenzene) 0.713 17.11 6,246 31.74 9.18 4.9 1,776 619 412 M 100 - 41 - 4 Ethyl benzene 1.676 40.22 14,682 74.61 21.58 7.9 2,871 1,000 1,000 M 101 - 68 - 8 Methylene bisphenyl isocyanate (MDI) 0.05 1.20 438 2.23 0.64 0.0014 0.33 0.18 0.020 R 107 - 21 - 1 Ethylene glycol 6.3 151.20 55,188 280.45 81.13 4.0 1,444 503 335 M 107 - 98 - 2 1- Methoxy-2-propanol (Propylene glycol monomethyl ether) 9.78 234.72 85,673 435.36 125.94 16 5,741 2,000 2,000 M 108 - 10 - 1 MIBK (Methyl isobutyl ketone, 4-Methyl-2-pentanone) 1.96 47.04 17,170 87.25 25.24 24 8,612 3,000 3,000 M 108 - 21 - 4 Isopropyl Acetate 0.905 21.72 7,928 40.29 11.65 68 24,998 8,708 4,147 D 108 - 88 - 3 Toluene 3.86 92.63 33,809 171.81 49.70 5.3 1,927 671 400 M 109 - 60 - 4 n- Propyl acetate 0.75 18.00 6,570 33.39 9.66 137 49,937 17,396 8,284 D 110 - 12 - 3 5- Methyl-2-hexanone (Methyl isoamyl ketone) 1.247 29.93 10,924 55.51 16.06 77 27,989 9,750 2,321 D 110 - 19 - 0 Isobutyl acetate 6.29 150.96 55,100 280.00 81.00 117 42,641 14,854 7,073 M 110 - 43 - 0 Methyl amyl ketone (2-Heptanone) 2.12 50.88 18,571 94.37 27.30 38 13,934 4,854 2,312 M 111 - 76 - 2 2- Butoxyethanol (Ethylene glycol butyl ether) 0.81 19.44 7,096 36.06 10.43 102 37,318 13,000 13,000 D 112 - 7 - 2 2- Butoxyethyl Acetate 0.12 2.88 1,051 5.34 1.55 5.2 1,892 659 439 D 123 - 42 - 2 Diacetone alcohol 1.38 33.12 12,089 61.43 17.77 9.4 3,436 1,197 798 M 123 - 86 - 4 n- Butyl acetate 4.14 99.36 36,266 184.30 53.31 28 10,296 3,587 2,391 M 141 - 78 - 6 Ethyl acetate 2.17 52.08 19,009 96.60 27.94 80 29,111 10,141 4,829 D 628 - 63 - 7 n- Amyl acetate (pentyl acetate) 0.603 14.47 5,282 26.84 7.76 87 31,852 11,096 2,642 D 822 - 6 - 0 Hexamethylene diisocyanate (1,6-Diisocyanatohexane) 0.00 0.00 0.00 0.00000 0.00000 0.00096 0.16 0.12 0.010 D 872 - 50 - 4 Methylpyrrolidone 0.487 11.69 4,266 21.68 6.27 11 4,102 1,429 952 M 1314 - 13 - 2 Zinc oxide dust 0.002 0.05 17.52 0.06 0.02 0.40 144 50 34 D 1330 - 20 - 7 Xylene (all isomers) 9.359 224.62 81,985 416.62 120.52 12 1,641 1,550 100 R 1332 - 58 - 7 Kaolin 0.01 0.24 88 0.38 0.13 0.079 29 10 6.7 M 1333 - 86 - 4 Carbon black 0.005 0.12 43.80 0.17 0.06 0.41 150 52 35 D 7440 - 47 - 3 Chromium III, Chromium VI (all forms) 0.0002 0.005 1.752 0.006 0.002 0.01568 5.71 2.016 1.344 D 7631 - 86 - 9 Silica, Amorphous, Fumed 0.001 0.02 9 0.03 0.01 0.079 29 10 6.7 D 7727 - 43 - 7 Barium sulfate 0.004 0.10 35.04 0.14 0.05 3.3 1,197 417 99 D 8008 - 20 - 6 Kerosene 2.55 61.20 22,338 113.52 32.84 7.9 2,888 1,006 671 M 8030 - 30 - 6 Rubber solvent (Naphtha) 0.00 0.00 0.00 0.00 0.00 63 22,959 7,998 5,332 D 8052 - 41 - 3 Stoddard solvent 6.413 153.91 56,178 285.48 82.58 21 7,581 2,641 1,761 M 12001 - 26 - 2 Mica 0.002 0.05 17.52 0.08 0.03 0.12 43 15 10 D 13463 - 67 - 7 Titanium dioxide 0.07 1.68 613 2.49 0.86 0.40 144 50 34 M 14464 - 46 - 1 Cristobalite 0.002 0.05 17.52 0.08 0.03 0.002 0.72 0.25 0.17 M 14807 - 96 - 6 Talc (containing no asbestos fibers) 0.02 0.48 175 0.74 0.25 0.079 29 10 6.7 M 14808 - 60 - 7 Quartz 0.013 0.31 114 0.50 0.17 0.0028 1.0 0.36 0.24 R 112926 - 0 - 8 Precipitated silica 0.003 0.07 26 0.14 0.04 0.40 144 50 34 D Modeled impacts are calculated using site-specific unit impact factors: Compliance Method Code: 353.3 ug/m 3 per g/sec and 102.2 ug/m 3 per g/sec for 24-hour and annual emissions, respectively. D = Max. emission rates are less than de minimus values. Sample calculations for formaldehyde: M = Modeled impact concentrations are less than AALs. 24-hour: 2.89 lb/day ¸ 24 hr/day x 0.126 g/sec / lb/hr x 353.3 ug/m 3 / g/sec = 5.37 ug/m 3 R = Emissions must be restricted to meet AALs. Annual: 2.89 lb/day ¸ 24 hr/day x 0.126 g/sec / lb/hr x 102.2 ug/m3 / g/sec = 1.55 ug/m3 Page: 5 of 6 (cont.)
Engineer: chm Date: 04/12/06
Ratio of Max. Ratio of Modeled Maximum Emission Rate to Impact to Allowable Usage* de Minimis Value Ambient Air Limit Higher lb/day Ratio 24-Hour Annual 24-Hour Annual Calculated Adjusted Guidance lb/day lb/yr µg/m 3 µg/m 3 Value Value** 289.44 278.01 4.13 1.76 4.13 0.70 – 0.7 3.67 3.65 0.05 0.02 0.05 5098.6 – NR 29.52 28.48 0.42 0.18 0.42 710.6 – NR 7.42 7.52 0.11 0.05 0.11 947.3 – NR 5.04 4.98 0.07 0.03 0.07 2287.5 – NR 0.00 0.00 0.00 0.00 0.00 1868.1 – NR 22.40 22.43 0.33 0.14 0.33 164.4 – 164.4 6.79 6.83 0.10 0.04 0.10 3677.4 – NR 9.44 9.41 0.14 0.06 0.14 412.4 – NR 4.37 4.33 0.06 0.02 0.06 2695.7 – NR 86.40 87.60 1.28 0.55 1.28 13.5 – 13.5 3.49 3.52 0.05 0.02 0.05 333.7 – NR 5.09 5.11 0.07 0.02 0.07 539.1 – NR 857.14 1327.27 12.37 32.19 32.19 0.04 – ER 37.80 38.22 0.56 0.24 0.56 271.2 – NR 14.67 14.92 0.22 0.06 0.22 1078.3 – NR 1.96 1.99 0.03 0.01 0.03 1617.4 – NR 0.32 0.32 0.00 0.00 0.00 4694.8 – NR 17.48 17.55 0.26 0.12 0.26 361.8 – NR 0.13 0.13 0.00 0.00 0.00 9378.8 – NR 0.39 0.39 0.01 0.01 0.01 4325.8 – NR 1.29 1.29 0.02 0.01 0.02 8008.3 – NR 1.34 1.33 0.02 0.01 0.02 2617.0 – NR 0.19 0.19 0.00 0.00 0.00 7008.7 – NR 0.55 0.56 0.01 0.00 0.01 355.3 – NR 3.52 3.52 0.05 0.02 0.05 645.3 – NR 3.55 3.52 0.05 0.02 0.05 1933.9 – NR 0.65 0.65 0.01 0.01 0.01 5467.4 – NR 0.17 0.17 0.00 0.00 0.00 4924.1 – NR 0.00 0.00 0.00 0.00 0.00 –– ER 1.06 1.04 0.02 0.01 0.02 770.4 – NR 0.12 0.12 0.00 0.00 0.00 40.0 400.0 NR 18.72 49.96 0.27 1.21 1.21 186.4 – 186.4 3.04 3.02 0.04 0.02 0.04 6.3 63.2 63.2 0.29 0.29 0.00 0.00 0.00 36.7 367.1 NR 0.31 0.31 0.00 0.00 0.00 1.6 16.1 16.1 0.30 0.30 0.00 0.00 0.00 8.0 80.0 80.0 0.03 0.03 0.00 0.00 0.00 190.1 1900.8 NR 7.75 7.73 0.11 0.05 0.11 542.4 – NR 0.00 0.00 0.00 0.00 0.00 –– NR 7.33 7.41 0.11 0.05 0.11 1423.9 – NR 0.40 0.41 0.01 0.00 0.01 9.0 90.0 90.0 4.20 4.26 0.05 0.03 0.05 33.7 337.3 NR 24.00 24.33 0.32 0.18 0.32 0.15 1.5 1.5 6.08 6.04 0.07 0.04 0.07 6.5 64.9 64.9 111.43 113.88 1.38 0.71 1.38 0.23 2.3 2.3 0.18 0.18 0.00 0.00 0.00 25.7 257.1 NR * To convert maximum allowable chemical usage, in lb/day, to maximum allowable product usage, in gal/day, use the following formula: gal/day = lb/day × 100 ÷ weight % of chemical constituent ÷ product density in lb/gal ** Adjusted for 90% reduction in emissions with filtration of overspray solids. NR = No further restriction required if product usage does not exceed 45 gal/day. ER = Evaluation required to determine maximum allowable usage. Chemical Usage Guide Page: 6 of 6 Facility Name: The Anthony Galluzzo Corporation Engineer: chm Facility Location: Londonderry Date: 06/07/07 Facility ID No.: 3301590806 Application No.: FY05-0200 Maximum Allowable Usage Maximum Product Maximum Weight CAS Number Chemical Name Chemical Usage1 ÷ × 100 ÷ Density ═ Product Usage2 % (lb/day) (lb/gal) (gal/day) 50 - 0 - 0 Formaldehyde 0.7 ÷ × 100 ÷ ═ 64 - 17 - 5 Ethanol NR 45 67 - 56 - 1 Methanol NR 45 67 - 63 - 0 Isopropyl alcohol (2-Propanol) NR 45 67 - 64 - 1 Acetone (2-Propanone) NR 45 71 - 23 - 8 n- Propyl alcohol NR 45 71 - 36 - 3 n- Butanol 164.4 ÷ × 100 ÷ ═ 71 - 55 - 6 1,1,1- Trichloroethane (Methyl chloroform) NR 45 78 - 83 - 1 2- Methyl-1-propanol (Isobutyl alcohol) NR 45 78 - 93 - 3 Methyl ethyl ketone (MEK) NR 45 84 - 74 - 2 Dibutyl phthalate 13.5 ÷ × 100 ÷ ═ 95 - 63 - 6 1,2,4- Trimethylbenzene (as Trimethylbenzene) NR 45 100 - 41 - 4 Ethyl benzene NR 45 101 - 68 - 8 Methylene bisphenyl isocyanate (MDI) ER ÷ × 100 ÷ ═ 107 - 21 - 1 Ethylene glycol NR 45 107 - 98 - 2 1- Methoxy-2-propanol (Propylene glycol monomethyl ether) NR 45 108 - 10 - 1 MIBK (Methyl isobutyl ketone, 4-Methyl-2-pentanone) NR 45 108 - 21 - 4 Isopropyl Acetate NR 45 108 - 88 - 3 Toluene NR 45 109 - 60 - 4 n- Propyl acetate NR 45 110 - 12 - 3 5- Methyl-2-hexanone (Methyl isoamyl ketone) NR 45 110 - 19 - 0 Isobutyl acetate NR 45 110 - 43 - 0 Methyl amyl ketone (2-Heptanone) NR 45 111 - 76 - 2 2- Butoxyethanol (Ethylene glycol butyl ether) NR 45 112 - 7 - 2 2- Butoxyethyl Acetate NR 45 123 - 42 - 2 Diacetone alcohol NR 45 123 - 86 - 4 n- Butyl acetate NR 45 141 - 78 - 6 Ethyl acetate NR 45 628 - 63 - 7 n- Amyl acetate (pentyl acetate) NR 45 822 - 6 - 0 Hexamethylene diisocyanate (1,6-Diisocyanatohexane) ER ÷ × 100 ÷ ═ 872 - 50 - 4 Methylpyrrolidone NR 45 1314 - 13 - 2 Zinc oxide dust NR 3 45 1330 - 20 - 7 Xylene (all isomers) 186.4 ÷ × 100 ÷ ═ 1332 - 58 - 7 Kaolin 63.2 3 ÷ × 100 ÷ ═ 1333 - 86 - 4 Carbon black NR 3 45 7440 - 47 - 3 Chromium III, Chromium VI (all forms) 16.1 3 ÷ × 100 ÷ ═ 7631 - 86 - 9 Silica, Amorphous, Fumed 80.0 3 ÷ × 100 ÷ ═ 7727 - 43 - 7 Barium sulfate NR 3 45 8008 - 20 - 6 Kerosene NR 45 8030 - 30 - 6 Rubber solvent (Naphtha) NR 45 8052 - 41 - 3 Stoddard solvent NR 45 12001 - 26 - 2 Mica 90.0 3 ÷ × 100 ÷ ═ 13463 - 67 - 7 Titanium dioxide NR 3 45 14464 - 46 - 1 Cristobalite 1.5 3 ÷ × 100 ÷ ═ 14807 - 96 - 6 Talc (containing no asbestos fibers) 64.9 3 ÷ × 100 ÷ ═ 14808 - 60 - 7 Quartz 2.3 3 ÷ × 100 ÷ ═ 112926 - 0 - 8 Precipitated silica NR 3 45 1Maximum chemical usage, in lb/day , that meets AALs. Convert to maximum allowable product usage, in gal/day , using this formula: 100 gal/day = lb/day × ÷÷÷ product density, in lb/gal weight % of chemical constituent 2Total usage of all coating products shall not exceed 45 gal/day. 3Allowable usage adjusted for 90% reduction in emissions with filtration of overspray solids. NR = No further restriction necessary if product usage does not exceed 45 gal/day. ER = Evaluation required to determine maximum allowable usage. Chemical Usage Guide Page: 6 of 6 Facility Name: The Anthony Galluzzo Corporation Engineer: chm Facility Location: Londonderry Date: 06/07/07 Facility ID No.: 3301590806 Application No.: FY05-0200 Maximum Allowable Usage Maximum Product Maximum Weight CAS Number Chemical Name Chemical Usage1 ÷ × 100 ÷ Density ═ Product Usage2 % (lb/day) (lb/gal) (gal/day) 50 - 0 - 0 Formaldehyde 0.7 ÷ 0.2 × 100 ÷ 8.5 ═ 41 64 - 17 - 5 Ethanol NR 45 67 - 56 - 1 Methanol NR 45 67 - 63 - 0 Isopropyl alcohol (2-Propanol) NR 45 67 - 64 - 1 Acetone (2-Propanone) NR 45 71 - 23 - 8 n- Propyl alcohol NR 45 71 - 36 - 3 n- Butanol 164.4 ÷ 46 × 100 ÷ 8.5 ═ 42 71 - 55 - 6 1,1,1- Trichloroethane (Methyl chloroform) NR 45 78 - 83 - 1 2- Methyl-1-propanol (Isobutyl alcohol) NR 45 78 - 93 - 3 Methyl ethyl ketone (MEK) NR 45 84 - 74 - 2 Dibutyl phthalate 13.5 ÷ 4 × 100 ÷ 8.5 ═ 40 95 - 63 - 6 1,2,4- Trimethylbenzene (as Trimethylbenzene) NR 45 100 - 41 - 4 Ethyl benzene NR 45 101 - 68 - 8 Methylene bisphenyl isocyanate (MDI) ER ÷ × 100 ÷ ═ 107 - 21 - 1 Ethylene glycol NR 45 107 - 98 - 2 1- Methoxy-2-propanol (Propylene glycol monomethyl ether) NR 45 108 - 10 - 1 MIBK (Methyl isobutyl ketone, 4-Methyl-2-pentanone) NR 45 108 - 21 - 4 Isopropyl Acetate NR 45 108 - 88 - 3 Toluene NR 45 109 - 60 - 4 n- Propyl acetate NR 45 110 - 12 - 3 5- Methyl-2-hexanone (Methyl isoamyl ketone) NR Example 45 110 - 19 - 0 Isobutyl acetate NR 45 110 - 43 - 0 Methyl amyl ketone (2-Heptanone) NR 45 111 - 76 - 2 2- Butoxyethanol (Ethylene glycol butyl ether) NR 45 112 - 7 - 2 2- Butoxyethyl Acetate NR 45 123 - 42 - 2 Diacetone alcohol NR 45 123 - 86 - 4 n- Butyl acetate NR 45 141 - 78 - 6 Ethyl acetate NR 45 628 - 63 - 7 n- Amyl acetate (pentyl acetate) NR 45 822 - 6 - 0 Hexamethylene diisocyanate (1,6-Diisocyanatohexane) ER ÷ × 100 ÷ ═ 872 - 50 - 4 Methylpyrrolidone NR 45 1314 - 13 - 2 Zinc oxide dust NR 3 45 1330 - 20 - 7 Xylene (all isomers) 186.4 ÷ 50 × 100 ÷ 8.5 ═ 44 1332 - 58 - 7 Kaolin 63.2 3 ÷ 18 × 100 ÷ 8.5 ═ 41 1333 - 86 - 4 Carbon black NR 3 45 7440 - 47 - 3 Chromium III, Chromium VI (all forms) 16.1 3 ÷ 4.5 × 100 ÷ 8.5 ═ 42 7631 - 86 - 9 Silica, Amorphous, Fumed 80.0 3 ÷ 25 × 100 ÷ 8.5 ═ 38 7727 - 43 - 7 Barium sulfate NR 3 45 8008 - 20 - 6 Kerosene NR 45 8030 - 30 - 6 Rubber solvent (Naphtha) NR 45 8052 - 41 - 3 Stoddard solvent NR 45 12001 - 26 - 2 Mica 90.0 3 ÷ 25 × 100 ÷ 8.5 ═ 42 13463 - 67 - 7 Titanium dioxide NR 3 45 14464 - 46 - 1 Cristobalite 1.5 3 ÷ 0.45 × 100 ÷ 8.5 ═ 39 14807 - 96 - 6 Talc (containing no asbestos fibers) 64.9 3 ÷ 19 × 100 ÷ 8.5 ═ 40 14808 - 60 - 7 Quartz 2.3 3 ÷ 0.7 × 100 ÷ 8.5 ═ 39 112926 - 0 - 8 Precipitated silica NR 3 45 1Maximum chemical usage, in lb/day , that meets AALs. Convert to maximum allowable product usage, in gal/day , using this formula: 100 gal/day = lb/day × ÷÷÷ product density, in lb/gal weight % of chemical constituent 2Total usage of all coating products shall not exceed 45 gal/day. 3Allowable usage adjusted for 90% reduction in emissions with filtration of overspray solids. NR = No further restriction necessary if product usage does not exceed 45 gal/day. ER = Evaluation required to determine maximum allowable usage.