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FOREWORD ...... iii ABSTRACT ...... iv ACKNOWLEDGMENTS ...... v METHOD FINDER ...... MF-1
I. INTRODUCTION A. Purpose and Scope ...... 1 B. How to Use NMAM ...... 2 C. Quality Assurance by D. L. Smith, CIH, M. L. Bolyard, CIH, and P. M. Eller, Ph.D., CIH ...... 7 D. General Considerations for Sampling Airborne Substances by Charles S. McCammon, Ph.D., CIH, and Mary Lynn Woebkenberg, Ph.D...... 17 E. Development and Evaluation of Methods by Eugene R. Kennedy, Ph.D, Thomas J. Fishbach, Ruiguang Song, Ph.D, Peter M. Eller, Ph.D, Stanley A.Schulman, Ph.D, and R. DeLon Hull, Ph.D...... 36 F. Application of Biological Monitoring Methods by Alexander W. Teass, Ph.D, Raymond E. Biagini, Ph.D, D. Gayle DeBord, Ph.D, and R. DeLon Hull, Ph.D...... 52 G. Aerosol Photometers for Respirable Dust Measurements by Paul A. Baron, Ph.D...... 63 H. Portable Electrochemical Sensor Methods by W. J. Woodfin ...... 70 I. Portable Gas Chromatography by Judd C. Posner, Ph.D...... 75 J. Sampling and Characterization of Bioaerosols by Paul A. Jensen, Ph.D. and Millie P. Schafer, Ph.D...... 82 K. Determination of Airborne Isocyanate Exposure by Robert P. Streicher, Ph.D., Christopher M. Reh, Ph.D., Rosa Key-Schwartz, Ph.D., Paul C. Schlecht, and Mary Ellen Cassinelli ...... 115 L. Measurement of Fibers by Paul A. Baron, Ph.D...... 143 M. Sampling and Analysis of Soluble Metal Compounds by Kevin Ashley, Ph.D., and Richard Fairfax, CIH ...... 167 N. Aerosol Sampling: Minimizing Particle Loss From Cassette Bypass Leakage by Paul A. Baron, Ph.D. .... 179 O. Factors Affecting Aerosol Sampling by Paul A. Baron, Ph.D...... 184 P. Measurement Uncertainty and NIOSH Method Accuracy Range by David L. Bartley, Ph.D., Stanley A. Shulman, and Paul C. Schl echt ...... 208 Q. Monitoring of Diesel Particulate Exhaust in the Workplace by M. Eileen Birch ...... 229 R. Determination of Airborne Crystalline Silica by Rosa J. Key-Schwartz, Ph.D., Paul A. Baron, Ph.D., David L. Bartley, Ph.D., Faye L. Rice, and Paul C. Schlecht ...... 260
II. METHODS METHOD METHOD NAME NUMBER
A CETALDEHYDE ...... 2018 ACETALDEHYDE by GC ...... 2538 ACETALDEHYDE by HPLC ...... 3507 ACETIC ACID ...... 1603 ACETI C ANHYDRIDE ...... 3506 ACETOI N ...... 2558 ACETONE ...... 2555 ACETONE CYANOHYDRIN ...... 2506 ACETONITRILE ...... 1606 ACI DS, INORGANIC ...... 7903 Hydrobromic acid Hydrofluoric acid Phosphoric acid Hydrochloric acid Nitric acid Sulfuric acid ACROLEIN ...... 2501 ACRYLONITRILE ...... 1604 AEROBIC BACTERI A by GC-FAME ...... 0801 ALACHLOR in AIR ...... 5603
3/15/2003 NIOSH Manual of Analytical Methods vi ALCOHOLS I (desorption in 99:1 CS2 :2-butanol) ...... 1400 tert-Butyl alcohol Isopropyl alcohol Ethanol
ALCOHOLS II (desorption in 99:1 CS2 :2-propanol) ...... 1401 n-Butyl alcohol Isobutyl alcohol sec-Butyl alcohol n-Propyl alcohol
ALCOHOLS III (desorption in 95:5 CS2 :2-propanol) ...... 1402 All yl alcohol Isoamyl alcohol Methyl isobutyl carbinol Cyclohexanol Diacetone alcohol
ALCOHOLS IV (desorption in 95:5 CH2 Cl 2 :methanol) ...... 1403 2-Butoxyethanol 2-Ethoxyethanol 2-Methoxyethanol
ALCOHOLS COMBINED ...... 1405 n-Butyl alcohol sec-Butyl alcohol Isobutyl alcohol All yl alcohol Diacetone alcohol Cyclohexanol Isoamyl alcohol Methyl isobutyl carbinol n -Propyl alcohol ALDEHYDES, SCREENING ...... 2539 ALDRIN and LINDANE ...... 5502 ALIPHATIC ALDEHYDES ...... 2018 ALKALINE DUSTS ...... 7401 ALLYL CHLORI DE ...... 1000 ALLYL GLYCIDYL ETHER ...... 2545 ALUMINUM ...... 7013 AMINES, ALIPHATIC ...... 2010 Diethylamine Dimethylamine AMINES, AROMATIC ...... 2002 Aniline N,N-Dimethyl-p-toluidine 2,4-Xylidine N,N-Dimethylaniline o-Toluidine AMINOETHANOL COMPOUNDS I ...... 2007 2-Aminoethanol 2-Diethylaminoethanol 2-Dibutylaminoethanol AMINOETHANOL COMPOUNDS II ...... 3509 Monoethanolamine (MEA) Diethanolamine (DEA) Triet hanolamine (TEA) AMMONIA ...... 6015 AMMONIA by IC ...... 6016 N-AMYL ACETATE ...... 1450 ISO-AMYL ACETATE ...... 1450 ANILINE, o -TOLUIDINE, and NITROBENZENE ...... 2017 ANILINE ...... 8317 ANISI DINE ...... 2514 ARSENIC (hydride AAS) ...... 7900 ARSENIC, ORGANO- ...... 5022 p -Aminophenylarsonic acid Methylarsonic acid Dimethylarsenic acid ARSENIC TRIOXIDE (GFAAS) ...... 7901 ARSI NE ...... 6001 ASBESTOS (bulk) by PLM ...... 9002 ASBESTOS, CHRYSOTILE by XRD ...... 9000 ASBESTOS and other FIBERS by PCM ...... 7400 ASBESTOS FIBERS by TEM ...... 7402 ASPARTAME ...... 5031 AZELAIC ACID ...... 5019
B ARIUM, sol uble compounds ...... 7056 BENZENE by portabl e GC ...... 3700 BENZENE-SOLUBLE FRACTION and TOTAL PARTICULATE (ASPHALT FUME) ...... 5042 BENZIDINE and 3, 3' -DICHLOROBENZIDINE ...... 5509
3/15/2003 NIOSH Manual of Analytical Methods vii BENZIDINE in urine (GC) ...... 8306 BENZOTHIAZOLE in Asphalt Fume ...... 2550 BENZOYL PEROXIDE ...... 5009 BERYLLIUM ...... 7102 BIOAEROSOL SAMPLING ...... 0800 BORON CARBI DE ...... 7506 BROMOFORM ...... 1003 1-BROMOPROPANE and 2-BROMOPROPANE ...... 1025 BROMOXYNIL and BROMOXYNIL OCTANOATE ...... 5010 1, 3-BUTADI ENE ...... 1024 BUTOXYACETIC ACID in URINE ...... 8316 n- BUTYLAMINE ...... 2012 1-BUTYLACETATE ...... 1450 ISO-BUTYLACETATE ...... 1450 n-BUTYL GLYCIDYL ETHER ...... 1616 n-BUTYL MERCAPTAN ...... 2525
C ADMIUM by FAAS ...... 7048 CALCI UM ...... 7020 CAPSAICIN and DIHYDROCAPSAICIN ...... 5041 CAPTAN ...... 9202 CAPTAN ...... 9205 CARBARYL ...... 5006 CARBON BLACK ...... 5000 CARBON DI OXI DE ...... 6603 CARBON DI SULFIDE ...... 1600 CARBON MONOXI DE ...... 6604 CELLULOSE INSULATI ON ...... 7404 CHLORDANE ...... 5510 CHLORINATED CAMPHENE ...... 5039 CHLORI NATED DIPHENYL OXI DE ...... 5025 CHLORINATED and ORGANONI TROGEN HERBICI DES (AIR SAMPLING) ...... 5602 Alachl or 2,4-D acid Metolachlor Atrazine 2,4-D,2-butoxyethyl ester Simazine Cyanazine 2,4-D,2-ethylhexyl ester CHLORINATED and ORGANONITROGEN HERBICIDES ( HAND WASH) ...... 9200 CHLORINATED and ORGANONITROGEN HERBICIDES ( DERMAL PATCH) ...... 9201 CHLORINATED TERPHENYL ...... 5014 CHLORINE AND BROMINE ...... 6011 CHLOROACETALDEHYDE ...... 2015 CHLOROACETIC ACID ...... 2008 D -CHLOROBENZOTRI FLUORI DE ...... 1026 CHLOROBROMOMETHANE ...... 1003 p -CHLOROPHENOL ...... 2014 $ -CHLOROPRENE ...... 1002 CHROMIUM by FAAS ...... 7024 CHROMIUM, HEXAVALENT, by VIS ...... 7600 CHROMIUM, HEXAVALENT, by IC ...... 7604 CHROMIUM, HEXAVALENT by I ON CHROMATOGRAPHY ...... 7605 CHROMIUM, HEXAVALENT, in settled dust samples ...... 9101 CHROMIUM, HEXAVALENT by FI ELD-PORTABLE SPECTROPHOTOMETRY ...... 7703 COBALT ...... 7027 COPPER (dust and fume) ...... 7029 CRESOLS and PHENOL ...... 2546 CROTONALDEHYDE ...... 3516 CYANIDES (aerosol and gas) by ISE ...... 7904 CYANURIC ACID ...... 5030
3/15/2003 NIOSH Manual of Analytical Methods viii CYCLOHEXANONE ...... 2555 1, 3-CYCLOPENTADI ENE ...... 2523
2,4-D and 2,4,5-T ...... 5001 DECABROMODIPHENYL OXI DE ...... 2559 DEMETON ...... 5514 DIACETYL ...... 2557 DIAZOMETHANE ...... 2515 DIBORANE ...... 6006 DIBUTYL PHOSPHATE ...... 5017 DIBUTYL PHTHALATE and DI(2-ETHYLHEXYL) PHTHALATE ...... 5020 @ -DICHLOROBENZENE ...... 1003 D -DICHLOROBENZENE ...... 1003 DICHLORODIFLUOROMETHANE, 1,2-DICHLOROTETRAFLUOROETHANE, and CHLORODIFLUOROMETHANE ...... 1018 DICHLOROETHYL ETHER ...... 1004 DICHLOROFLUOROMETHANE ...... 2516 1, 1-DICHLORO-1-NITROETHANE ...... 1601 DIFLUORODIBROMOMETHANE ...... 1012 DIISOBYTYL KETONE ...... 2555 DIMETHYLACETAMIDE and DIMETHYLFORMAMIDE ...... 2004 2-(DIMETHYLAMINO)ETHANOL and 1-DIMETHYLAMINO-2-PROPANOL ...... 2561 1, 1-DIMETHYLHYDRAZINE ...... 3515 DIMETHYL SULFATE ...... 2524 DIOXANE ...... 1602 DIPHENYL ...... 2530 DYES, BENZIDINE, o -DIANISIDINE, and o -TOLIDINE ...... 5013
E LEMENTAL CARBON (DIESEL PARTICULATE) ...... 5040 ELEMENTS in blood or tissue ...... 8005 Antimony Lanthanum Silver Cadmium Lead Strontium Chromium Manganese Tin Cobalt Molybdenum Titanium Copper Nickel Zinc Iron Platinum ELEMENTS on WIPES ...... 9102 Arsenic Barium Beryllium Cadmium Cobalt Chromium Copper Iron Lanthanum Manganese Molybdenum Nickel Phosphorus Lead Selenium Silver Strontium Tellurium Thallium Vanadium Yttrium Zinc Zirconium ELEMENTS by ICP ...... 7300 Aluminum Iron Platinum Tungsten Arsenic Lead Selenium Vanadium Beryllium Lithium Sodium Yttrium Calcium Magnesium Silver Zinc Cadmium Manganese Tellurium Zirconium Chromium Molybdenum Tin Cobalt Nickel Titanium Copper Phosphorus Thallium
3/15/2003 NIOSH Manual of Analytical Methods ix ELEMENTS by ICP (AQUA REGIA ASHING) ...... 7301 Aluminum Antimony Arsenic Barium Beryllium Bismuth Boron Cadmium Calcium Chromium Cobalt Copper Gallium Gold Indium Iron Lead Manganese Magnesium Molybdenum Neodymium Nickel Palladium Phosphorus Platinum Potassium Selenium Sodium Strontium Tellurium Thallium Tin Titanium Vanadium Yttrium Zinc ELEMENTS by ICP ...... 7303 Aluminum Chromium Manganese Sodium Antimony Cobalt Molybdenum Strontium Arsenic Copper Neodymium Tellurium Barium Gallium Nickel Thallium Beryllium Gold Palladium Tin Bismuth Indium Phosphorus Titanium Boron Iron Platinum Vanadium Cadmium Lead Potassium Yttrium Calcium Magnesium Selenium Zinc ENDRIN ...... 5519 EPI CHLOROHYDRIN ...... 1010 EPN ...... 5012 ESTERS I ...... 1450 n-Amyl acetate Ethyl acrylate n-Butyl acetate Isoamyl acetate sec-Butyl acetate Isobutyl acetate t-Butyl acetate Methyl isoamyl acetate 2-Ethoxyethyl acetate n-Propyl acetate ESTROGENI C COMPOUNDS ...... 5044 $ -Estradiol Estrone Progesterone $ -Estrodiol-3-Benzoate ETHYL ACETATE ...... 1457 ETHYL BROMIDE ...... 1011 ETHYL CHLORI DE ...... 2519 ETHYL ETHER ...... 1610 ETHYL FORMATE ...... 1452 ETHYL METHACRYLATE ...... 2537 ETHYLENE CHLOROHYDRIN ...... 2513 ETHYLENEDIAMINE, DIETHYLENETRI AMINE, & TRI ETHYLENETETRAMINE ...... 2540 ETHYLENE DIBROMIDE ...... 1008 ETHYLENE OXI DE ...... 1614 ETHYLENE OXIDE (portabl e GC) ...... 3702 ETHYLENE THIOUREA ...... 5011 ETHYLENI MINE ...... 3514
F LUORIDE in urine ...... 8308 FLUORIDES by IC ...... 7906 FLUORIDES by ISE ...... 7902 FLUOROTRI CHLOROMETHANE ...... 1006 FORMALDEHYDE (DNPH Cartridge) ...... 2016 FORMALDEHYDE [2-(hydroxymethyl)piperidine] by GC ...... 2541 FORMALDEHYDE (chromotropic acid) by VIS ...... 3500 FORMALDEHYDE ON DUST ...... 5700 FORMIC ACID by IC ...... 2011 FURFURAL ...... 2529 FURFURYL ALCOHOL ...... 2505
3/15/2003 NIOSH Manual of Analytical Methods x G LUTARALDEHYDE by HPLC/ UV ...... 2532 GLYCI DOL ...... 1608 GLYCOLS ...... 5523 Ethyl ene glycol 1,3-butylene glycol Triethylene glycol Propylene glycol Diethylene glycol Tetraethylene glycol GLYCOL ETHERS ...... 2554 Propylene glycol monomethyl ether Dipropylene glycol monomethyl ether Propylene glycol monomethyl ether acetate
HEXACHLOROBUTADI ENE ...... 2543 HEXACHLORO-1, 3-CYCLOPENTADI ENE ...... 2518 2-HEXANONE ...... 2555 HIPPURIC ACID in urine (VIS) ...... 8300 HIPPURIC and METHYL HIPPURIC ACIDS in urine (HPLC) ...... 8301 HYDRAZINE ...... 3503 HYDROCARBONS, BP 36 - 216 N C ...... 1500 Cyclohexane n-Heptane n-Octane Cyclohexene n-Hexane n-Pentane n-Decane Methylcyclohexane n-Undecane n-Dodecane n-Nonane HYDROCARBONS, AROMATIC ...... 1501 Benzene " -Methylstyrene o,m,p-Xyl ene p -tert-Butyltoluene $ -Methylstyrene Cumene Styrene Ethylbenzene Toluene HYDROCARBONS, HALOGENATED ...... 1003 Benzyl chloride o -Dichl orobenzene Hexachloroethane Bromoform p-Dichlorobenzene 1,1,1-Trichloroethane Carbon tetrachl oride 1,1-Dichloroethane 1,1,2-Trichloroethane Chloroform 1,2-Dichloroethylene 1,2,3-Trichloropropane Chlorobenzene Ethylene dichloride Tetrachloroethylene Chlorobromomethane Trichloroethylene HYDROGEN CYANI DE ...... 6010 HYDROGEN CYANI DE ...... 6017 HYDROQUI NONE ...... 5004
I ODINE ...... 6005 ISOCYANATES, MONOMERIC ...... 5521 2, 4- TDI 2, 6- TDI MDI HDI ISOCYANATES (Fluorescence Detection) ...... 5522 2, 4- TDI 2, 6- TDI MDI HDI ISOCYANATES, TOTAL ( MAP) ...... 5525 Toluene 2,6-diisocyanate (2,6-TDI) Toluene 2,4-diisocyanate (2,4-TDI) 4,4'-Methylene-bis(phenyl isocyanate) (MDI) 1,6-Hexamethylene diisocyanate (HDI) Isophorone diisocyanate (IPDI) 4,4'-Methylene-bis (cyclohexyl isocyanate) (HMDI) 1,5-Napthalene diisocyanate (NDI) Naphthalene ISOPHORONE ...... 2508 ISOPHORONE ...... 2556 ISOPROPYL ACETATE ...... 1454 ISOPROPYL ACETATE ...... 1460 ISOPROPYL ETHER ...... 1618 ISOPROPYL GLYCIDYL ETHER ...... 1620
3/15/2003 NIOSH Manual of Analytical Methods xi ISOVALERALDEHYDE ...... 2018
K EPONE ...... 5508
KETONES I (desorption in CS2 ) ...... 1300 Acetone Diisobutyl ketone Methyl isobutyl ketone Cyclohexanone 2-Hexanone 2-Pentanone KETONES I ...... 2555 Acetone Methyl isobutyl ketone Diisobutyl ketone Methyl ethyl ketone 2-Hexanone Cyclohexanone 2-Pentanone
KETONES II (desorption in 99:1 CS2 :methanol) ...... 1301 Camphor 5-Methyl-3-heptanone Mesi tyl oxide Ethyl butyl ketone Methyl-(n-amyl)-ketone KETONES II ...... 2553 2-Heptanone 5-Methyl-3-heptanone 3-Heptanone Camphor Mesi tyl oxide
L EAD in air by chemical spot test ...... 7700 LEAD in blood and urine ...... 8003 LEAD in dust wipes ...... 9105 LEAD in surface wipe samples ...... 9100 LEAD by FIELD PORTABLE XRF ...... 7702 LEAD by ULTRASOUND/ASV ...... 7701 LEAD by FAAS ...... 7082 LEAD by GFAAS ...... 7105 LEAD SULFIDE ...... 7505
M ALEI C ANHYDRIDE ...... 3512 MANEB ...... 3600 MANEB ...... 3601 MBOCA in urine ...... 8302 MERCAPTANS, Methyl-, Ethyl-, n-Butyl- ...... 2542 MERCURY ...... 6009 METALS in urine (ICP) ...... 8310 Aluminum Copper Molybdenum Strontium Barium Iron Nickel Tin Cadmium Lead Platinum Titanium Chromium Manganese Silver Zinc METALWORKING FLUIDS ...... 5524 METHANOL ...... 2000 METHYL ACETATE ...... 1458 METHYL ACRYLATE ...... 1459 METHYL ACRYLATE ...... 2552 METHYL and ETHYL METHACRYLATE ...... 2537 Methyl methacrylate Ethyl methacrytate METHYL BROMIDE ...... 2520 METHYLAL ...... 1611 METHYL tert-BUTYL ETHER (MTBE) ...... 1615 METHYL CELLOSOLVE ACETATE ...... 1451 METHYL CHLORI DE ...... 1001 METHYLCYCLOHEXANOL ...... 1404 METHYLCYCLOHEXANONE ...... 2521 METHYLENE CHLORI DE ...... 1005 4,4' -METHYLENEDIANILI NE (MDA) ...... 5029 METHYL ETHYL KETONE ...... 2500
3/15/2003 NIOSH Manual of Analytical Methods xii METHYL ETHYL KETONE ...... 2555 METHYL ETHYL KETONE, ETHANOL and TOLUENE in blood ...... 8002 METHYL ETHYL KETONE PEROXIDE ...... 3508 METHYL IODIDE ...... 1014 METHYL ISOBUTYL KETONE ...... 2555 METHYL METHACRYLATE ...... 2537 N -METHYL-2-PYRROLIDINONE ...... 1302 METHYLTIN CHLORIDES ...... 5526 Methyltin chloride Dimethyltin dichloride Trimethyltin chloride MONOMETHYLANILINE ...... 3511 MONOMETHYLHYDRAZINE ...... 3510 MYCOBACTERI UM TUBERCULOSI S, AIRBORNE ...... 0900
N APHTHAS ...... 1550 Coal tar naphtha Mineral spirits Petroleum naphtha Stoddard solvent Kerosene Petroleum ether Rubber sol vent NAPHTHYLAMINES ...... 5518 NICKEL CARBONYL ...... 6007 NICOTI NE ...... 2551 NICOTI NE ...... 2544 NITRI C OXIDE and NITROGEN DI OXI DE ...... 6014 p -NITROANI LINE ...... 5033 NITROAROMATI C COMPOUNDS ...... 2005 4-Chloronitrobenzene Nitrobenzene o-,m-,p-Nitrotoluene NITROETHANE ...... 2526 NITROGEN DIOXIDE (diffusive sampler) ...... 6700 NITROGLYCERIN/ EGDN ...... 2507 NITROMETHANE ...... 2527 2-NITROPROPANE ...... 2528 1-NITROPYRENE ...... 2560 NITROSAMINES ...... 2522 N -nitrosodimethylamine N-nitrosodibutylamine N-nitrosopyrrolidine N-nitrosodiethylamine N-nitrosomorpholine N-nitrosodipropylamine N-nitrosopiperidine NITROUS OXIDE (field-readable) ...... 6600
1-O CTANETHIOL ...... 2510 OIL MIST, MINERAL ...... 5026 ORGANIC and INORGANIC GASES by EXTRACTI VE FTIR SPECTROMETRY ...... 3800 Benzene n-Hexane Trichloroethylene o-Xylene Acetone Tetrafluoroethylene m-Xylene 2-Butanone Formaldehyde p-Xyl ene Methanol Ethylene oxide Styrene Methylene chloride Tetrahydrofuran Toluene Vinylidene fluoride Nitrous oxide ORGANONITROGEN PESTICIDES ...... 5601 Aldicarb Carbaryl Carbendazim Methiocarb Propham Benomyl Carbofuran Diuron Methomyl Proxpur Captan Chlorprophan Formetanate Oxamyl Thiobencarb
3/15/2003 NIOSH Manual of Analytical Methods xiii ORGANOPHOSPHORUS PESTICIDES ...... 5600 Azinphos methyl Chlorpyrifos Diazinon Dicrotophos Disulfoton Ethion Ethoprop Fenamiphos Fonofos Malathion Methamidophos Methyl parathion Mevinphos (E) Mevinphos (E&Z) Monocrotophos (E) Monocrotophos (Z) Parathion Phorate Ronnel Sulprophos Terbufos ORGANOTIN COMPOUNDS ...... 5504 Dibutyltin bis(isooctyl mercaptoacetate) Tetrabutyltin Tributyltin chloride Tricyclohexyltin hydroxide OXYGEN (field-readable) ...... 6601
P ARAQUAT ...... 5003 PARTICULATES NOT OTHERWISE REGULATED, RESPIRABLE ...... 0600 PARTI CULATES NOT OTHERWISE REGULATED, TOTAL ...... 0500 PENTACHLOROETHANE ...... 2517 PENTACHLOROPHENOL ...... 5512 PENTACHLOROPHENOL in blood ...... 8001 PENTACHLOROPHENOL in urine ...... 8303 PENTAMIDINE ISETHIONATE ...... 5032 2-PENTANONE ...... 2555 PERCHLOROETHYLENE (Portable GC) in Exhaled Breath and Air ...... 3704 PHENOL and p -CRESOL in urine ...... 8305 PHENYL ETHER ...... 1617 PHENYL ETHER-DIPHENYL MIX ...... 2013 PHENYL GLYCIDYL ETHER ...... 1619 PHENYLHYDRAZINE ...... 3518 PHOSPHI NE ...... 6002 PHOSPHORUS ...... 7905 PHOSPHORUS TRI CHLORI DE ...... 6402 POLYCHLOROBENZENES ...... 5517 1,2,4-Trichlorobenzene 1,2,4,5-Tetrachlorobenzene Pentachlorobenzene POLYCHLOROBIPHENYLS ...... 5503 POLYCHLOROBIPHENYLS in serum ...... 8004 POLYCYCLIC AROMATIC HYDROCARBONS, TOTAL (PACs) ...... 5800 POLYNUCLEAR AROMATIC HYDROCARBONS (HPLC) ...... 5506 Acenaphthene Benzo[ghi]perylene Fluorene Acenaphthylene Benzo[a]pyrene Indeno[1,2,3-cd]pyrene Anthracene Benzo[e]pyrene Naphthalene Benz[a]anthracene Chrysene Phenanthrene Benzo[b]fluoranthene Dibenz[a,h]anthracene Pyrene Benzo[k]fluoranthene Fluoranthene POLYNUCLEAR AROMATIC HYDROCARBONS (GC) ...... 5515 Acenaphthene Benzo[ghi]perylene Fluorene Acenaphthylene Benzo[a]pyrene Indeno[1,2,3-cd]pyrene Anthracene Benzo[e]pyrene Naphthalene Benz[a]anthracene Chrysene Phenanthrene Benzo[b]fluoranthene Dibenz[a,h]anthracene Pyrene Benzo[k]fluoranthene Fluoranthene PROPI ONALDEHYDE ...... 2018 PROPYLENE DICHLORI DE ...... 1013 PROPYLENE OXI DE ...... 1612 PYRETHRUM ...... 5008 PYRIDINE ...... 1613
3/15/2003 NIOSH Manual of Analytical Methods xiv R ESORCI NOL ...... 5701 RIBAVIRIN ...... 5027 ROTENONE ...... 5007
S ILICA, AMORPHOUS ...... 7501 SILICA in coal mine dust by IR ...... 7603 SILICA, CRYSTALLINE, Respirable, by XRD ...... 7500 SILICA, CRYSTALLINE by VIS ...... 7601 SILICA, CRYSTALLINE by IR ...... 7602 STIBINE ...... 6008 STRYCHNINE ...... 5016 SULFUR DI OXI DE ...... 6004 SULFUR HEXAFLUORIDE by portable GC ...... 6602 SULFURYL FLUORI DE ...... 6012 SUPER ABSORBENT POLYMER ...... 5035
T ERPENES ...... 1552 Limonene, d-, l- "-pinene $ -pinene 3-carene o -TERPHENYL ...... 5021 1, 1, 2, 2-TETRABROMOETHANE ...... 2003 1,1,1,2-TETRACHLORO-2,2-DIFLUOROETHANE and 1,1,2,2-TETRACHLORO-1,2-DIFLUOROETHANE ...... 1016 1, 1, 2, 2-TETRACHLOROETHANE ...... 1019 1, 1, 2, 2-TETRACHLOROETHANE ...... 2562 TETRACHLOROETHYLENE ...... 1003 TETRAETHYL LEAD ...... 2533 TETRAETHYL PYROPHOSPHATE (TEPP) ...... 2504 TETRAHYDROFURAN ...... 1609 TETRAKIS (HYDROXYMETHYL) PHOSPHONIUM CHLORIDE ...... 5046 TETRAMETHYL LEAD ...... 2534 TETRAMETHYL THIOUREA ...... 3505 TETRANI TROMETHANE ...... 3513 THIOPHENATE-METHYL in air ...... 5606 THIOPHENATE-METHYL, hand rinse ...... 9202 THIOPHENATE-METHYL on dermal patch ...... 9205 THIRAM ...... 5005 TOLUENE (diffusive sampler) ...... 4000 2,4- & 2,6-TOLUENEDIAMINE (TDA) ...... 5516 TOLUENE-2,4-DIISOCYANATE (TDI) ...... 2535 p -TOLUENESULFONIC ACID ...... 5043 @ -TOLUIDINE ...... 8317 TRIAZINE HERBICIDES and their METABOLITES ...... 8315 Atrazine Cyanazine Simazine Desethylatrazine Propazine Desisopropylatrazine TRIBUTYL PHOSPHATE ...... 5034 TRI CHLOROETHYLENE ...... 1003 TRI CHLOROETHYLENE ...... 1022 TRICHLOROETHYLENE (portabl e GC) ...... 3701 1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE ...... 1020 TRI FLUOROBROMOMETHANE ...... 1017 TRI MELLITI C ANHYDRIDE ...... 5036 2, 4, 7-TRI NITROFLUOREN- 9-ONE ...... 5018 TRIORTHOCRESYL PHOSPHATE ...... 5037
3/15/2003 NIOSH Manual of Analytical Methods xv TRIPHENYL PHOSPHATE ...... 5038 TRI PHENYL TI N CHLORI DE ...... 5527 TUNGSTEN (soluble and insoluble) ...... 7074 TURPENTINE ...... 1551
V ALERALDEHYDE ...... 2018 VALERALDEHYDE ...... 2536 VANADIUM OXIDES ...... 7504 VINYL ACETATE ...... 1453 VI NYL BROMIDE ...... 1009 VI NYL CHLORI DE ...... 1007 VI NYLIDENE CHLORI DE ...... 1015 VOLATI LE ORGANI C COMPOUNDS ( SCREENING) ...... 2549
W ARFARIN ...... 5002
Z INC ...... 7030 ZI NC OXIDE ...... 7502
III. APPENDIXES
A. Unit Equivalents ...... A-1 B. Air Concentration Calculations for Comparison to OSHA Standards ...... A-2
IV. Glossary of Abbreviations, Definitions and Symbols ...... A-3
V. Indexes A. Third and Fourth Edition Method Numbers ...... A-11 B. First and Second Edition Method Numbers ...... A-18 C. Names and Synonyms ...... A-32
3/15/2003 NIOSH Manual of Analytical Methods xvi