Lecture 11. Surface Evaporation and Soil Moisture (Garratt 5.3) in This
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Energy Analysis and Carbon Saving Potential of a Complex Heating
European Journal of Sustainable Development Research 2019, 3(1), em0067 ISSN: 2542-4742 Energy Analysis and Carbon Saving Potential of a Complex Heating System with Solar Assisted Heat Pump and Phase Change Material (PCM) Thermal Storage in Different Climatic Conditions Uroš Stritih 1*, Eva Zavrl 1, Halime Omur Paksoy 2 1 University of Ljubljana, SLOVENIA 2 Çukurova Üniversitesi, TURKEY *Corresponding Author: [email protected] Citation: Stritih, U., Zavrl, E. and Paksoy, H. O. (2019). Energy Analysis and Carbon Saving Potential of a Complex Heating System with Solar Assisted Heat Pump and Phase Change Material (PCM) Thermal Storage in Different Climatic Conditions. European Journal of Sustainable Development Research, 3(1), em0067. https://doi.org/10.20897/ejosdr/3930 Published: February 6, 2019 ABSTRACT Building sector still consumes 40% of total energy consumption. Therefore, an improved heating system with Solar Assisted Heat Pump (SAHP) was introduced in order to minimse the energy consumption of the fossil fuels and to lower the carbon dioxide emissions occurring from combustion. An energy analysis of the complex heating system for heating of buildings, consisting of solar collectors (SC), latent heat storage tank (LHS) and heat pump (HP) was performed. The analysis was made for the heating season within the time from October to March for different climatic conditions. These climatic conditions were defined using test reference years (TRY) for cities: Adana, Ljubljana, Rome and Stockholm. The energy analysis was performed using a mathematical model which allowed hourly dynamics calculation of losses and gains for a given system. In Adana, Rome and Ljubljana, it was found that the system could cover 80% of energy from the sun and the heat pump coefficient of performance (COP) reached 5.7. -
Chapter 8 and 9 – Energy Balances
CBE2124, Levicky Chapter 8 and 9 – Energy Balances Reference States . Recall that enthalpy and internal energy are always defined relative to a reference state (Chapter 7). When solving energy balance problems, it is therefore necessary to define a reference state for each chemical species in the energy balance (the reference state may be predefined if a tabulated set of data is used such as the steam tables). Example . Suppose water vapor at 300 oC and 5 bar is chosen as a reference state at which Hˆ is defined to be zero. Relative to this state, what is the specific enthalpy of liquid water at 75 oC and 1 bar? What is the specific internal energy of liquid water at 75 oC and 1 bar? (Use Table B. 7). Calculating changes in enthalpy and internal energy. Hˆ and Uˆ are state functions , meaning that their values only depend on the state of the system, and not on the path taken to arrive at that state. IMPORTANT : Given a state A (as characterized by a set of variables such as pressure, temperature, composition) and a state B, the change in enthalpy of the system as it passes from A to B can be calculated along any path that leads from A to B, whether or not the path is the one actually followed. Example . 18 g of liquid water freezes to 18 g of ice while the temperature is held constant at 0 oC and the pressure is held constant at 1 atm. The enthalpy change for the process is measured to be ∆ Hˆ = - 6.01 kJ. -
A Comprehensive Review of Thermal Energy Storage
sustainability Review A Comprehensive Review of Thermal Energy Storage Ioan Sarbu * ID and Calin Sebarchievici Department of Building Services Engineering, Polytechnic University of Timisoara, Piata Victoriei, No. 2A, 300006 Timisoara, Romania; [email protected] * Correspondence: [email protected]; Tel.: +40-256-403-991; Fax: +40-256-403-987 Received: 7 December 2017; Accepted: 10 January 2018; Published: 14 January 2018 Abstract: Thermal energy storage (TES) is a technology that stocks thermal energy by heating or cooling a storage medium so that the stored energy can be used at a later time for heating and cooling applications and power generation. TES systems are used particularly in buildings and in industrial processes. This paper is focused on TES technologies that provide a way of valorizing solar heat and reducing the energy demand of buildings. The principles of several energy storage methods and calculation of storage capacities are described. Sensible heat storage technologies, including water tank, underground, and packed-bed storage methods, are briefly reviewed. Additionally, latent-heat storage systems associated with phase-change materials for use in solar heating/cooling of buildings, solar water heating, heat-pump systems, and concentrating solar power plants as well as thermo-chemical storage are discussed. Finally, cool thermal energy storage is also briefly reviewed and outstanding information on the performance and costs of TES systems are included. Keywords: storage system; phase-change materials; chemical storage; cold storage; performance 1. Introduction Recent projections predict that the primary energy consumption will rise by 48% in 2040 [1]. On the other hand, the depletion of fossil resources in addition to their negative impact on the environment has accelerated the shift toward sustainable energy sources. -
Psychrometrics Outline
Psychrometrics Outline • What is psychrometrics? • Psychrometrics in daily life and food industry • Psychrometric chart – Dry bulb temperature, wet bulb temperature, absolute humidity, relative humidity, specific volume, enthalpy – Dew point temperature • Mixing two streams of air • Heating of air and using it to dry a product 2 Psychrometrics • Psychrometrics is the study of properties of mixtures of air and water vapor • Water vapor – Superheated steam (unsaturated steam) at low pressure – Superheated steam tables are on page 817 of textbook – Properties of dry air are on page 818 of textbook – Psychrometric charts are on page 819 & 820 of textbook • What are these properties of interest and why do we need to know these properties? 3 Psychrometrics in Daily Life • Sea breeze and land breeze – When and why do we get them? • How do thunderstorms, hurricanes, and tornadoes form? • What are dew, fog, mist, and frost and when do they form? • When and why does the windshield of a car fog up? – How do you de-fog it? Is it better to blow hot air or cold air? Why? • Why do you feel dry in a heated room? – Is the moisture content of hot air lower than that of cold air? • How does a fan provide relief from sweating? • How does an air conditioner provide relief from sweating? • When does a soda can “sweat”? • When and why do we “see” our breath? • Do sailboats perform better at high or low relative humidity? Key factors: Temperature, Pressure, and Moisture Content of Air 4 Do Sailboats Perform Better at low or High RH? • Does dry air or moist air provide more thrust against the sail? • Which is denser – humid air or dry air? – Avogadro’s law: At the same temperature and pressure, the no. -
Cryogenicscryogenics Forfor Particleparticle Acceleratorsaccelerators Ph
CryogenicsCryogenics forfor particleparticle acceleratorsaccelerators Ph. Lebrun CAS Course in General Accelerator Physics Divonne-les-Bains, 23-27 February 2009 Contents • Low temperatures and liquefied gases • Cryogenics in accelerators • Properties of fluids • Heat transfer & thermal insulation • Cryogenic distribution & cooling schemes • Refrigeration & liquefaction Contents • Low temperatures and liquefied gases ••• CryogenicsCryogenicsCryogenics ininin acceleratorsacceleratorsaccelerators ••• PropertiesPropertiesProperties ofofof fluidsfluidsfluids ••• HeatHeatHeat transfertransfertransfer &&& thermalthermalthermal insulationinsulationinsulation ••• CryogenicCryogenicCryogenic distributiondistributiondistribution &&& coolingcoolingcooling schemesschemesschemes ••• RefrigerationRefrigerationRefrigeration &&& liquefactionliquefactionliquefaction • cryogenics, that branch of physics which deals with the production of very low temperatures and their effects on matter Oxford English Dictionary 2nd edition, Oxford University Press (1989) • cryogenics, the science and technology of temperatures below 120 K New International Dictionary of Refrigeration 3rd edition, IIF-IIR Paris (1975) Characteristic temperatures of cryogens Triple point Normal boiling Critical Cryogen [K] point [K] point [K] Methane 90.7 111.6 190.5 Oxygen 54.4 90.2 154.6 Argon 83.8 87.3 150.9 Nitrogen 63.1 77.3 126.2 Neon 24.6 27.1 44.4 Hydrogen 13.8 20.4 33.2 Helium 2.2 (*) 4.2 5.2 (*): λ Point Densification, liquefaction & separation of gases LNG Rocket fuels LIN & LOX 130 000 m3 LNG carrier with double hull Ariane 5 25 t LHY, 130 t LOX Air separation by cryogenic distillation Up to 4500 t/day LOX What is a low temperature? • The entropy of a thermodynamical system in a macrostate corresponding to a multiplicity W of microstates is S = kB ln W • Adding reversibly heat dQ to the system results in a change of its entropy dS with a proportionality factor T T = dQ/dS ⇒ high temperature: heating produces small entropy change ⇒ low temperature: heating produces large entropy change L. -
Pressure Vs Temperature (Boiling Point)
Boiling Points and Vapor Pressure Background Boiling Points and Vapor Pressure Background: Definitions Vapor Pressure: The equilibrium pressure of a vapor above its liquid; the pressure of the vapor resulting from the evaporation of a liquid above a sample of the liquid in a closed container. Boiling Point: The temperature at which the vapor pressure of a liquid is equal to the atmospheric (or applied) pressure. As the temperature of the liquid increases, the vapor pressure will increase, as seen below: https://www.chem.purdue.edu/gchelp/liquids/vpress.html Vapor pressure is interpreted in terms of molecules of liquid converting to the gaseous phase and escaping into the empty space above the liquid. In order for the molecules to escape, the intermolecular forces (Van der Waals, dipole- dipole, and hydrogen bonding) have to be overcome, which requires energy. This energy can come in the form of heat, aka increase in temperature. Due to this relationship between vapor pressure and temperature, the boiling point of a liquid decreases as the atmospheric pressure decreases since there is more room above the liquid for molecules to escape into at lower pressure. The graph below illustrates this relationship using common solvents and some terpenes: Pressure vs Temperature (boiling point) Ethanol Heptane Isopropyl Alcohol B-myrcene 290.0 B-caryophyllene d-Limonene Linalool Pulegone 270.0 250.0 1,8-cineole (eucalyptol) a-pinene a-terpineol terpineol-4-ol 230.0 p-cymene 210.0 190.0 170.0 150.0 130.0 110.0 90.0 Temperature (˚C) Temperature 70.0 50.0 30.0 10 20 30 40 50 60 70 80 90 100 200 300 400 500 600 760 10.0 -10.0 -30.0 Pressure (torr) 1 Boiling Points and Vapor Pressure Background As a very general rule of thumb, the boiling point of many liquids will drop about 0.5˚C for a 10mmHg decrease in pressure when operating in the region of 760 mmHg (atmospheric pressure). -
It's Just a Phase!
BASIS Lesson Plan Lesson Name: It’s Just a Phase! Grade Level Connection(s) NGSS Standards: Grade 2, Physical Science FOSS CA Edition: Grade 3 Physical Science: Matter and Energy Module *Note to teachers: Detailed standards connections can be found at the end of this lesson plan. Teaser/Overview Properties of matter are illustrated through a series of demonstrations and hands-on explorations. Students will learn to identify solids, liquids, and gases. Water will be used to demonstrate the three phases. Students will learn about sublimation through a fun experiment with dry ice (solid CO2). Next, they will compare the propensity of several liquids to evaporate. Finally, they will learn about freezing and melting while making ice cream. Lesson Objectives ● Students will be able to identify the three states of matter (solid, liquid, gas) based on the relative properties of those states. ● Students will understand how to describe the transition from one phase to another (melting, freezing, evaporation, condensation, sublimation) ● Students will learn that matter can change phase when heat/energy is added or removed Vocabulary Words ● Solid: A phase of matter that is characterized by a resistance to change in shape and volume. ● Liquid: A phase of matter that is characterized by a resistance to change in volume; a liquid takes the shape of its container ● Gas: A phase of matter that can change shape and volume ● Phase change: Transformation from one phase of matter to another ● Melting: Transformation from a solid to a liquid ● Freezing: Transformation -
A Critical Review on Thermal Energy Storage Materials and Systems for Solar Applications
AIMS Energy, 7(4): 507–526. DOI: 10.3934/energy.2019.4.507 Received: 05 July 2019 Accepted: 14 August 2019 Published: 23 August 2019 http://www.aimspress.com/journal/energy Review A critical review on thermal energy storage materials and systems for solar applications D.M. Reddy Prasad1,*, R. Senthilkumar2, Govindarajan Lakshmanarao2, Saravanakumar Krishnan2 and B.S. Naveen Prasad3 1 Petroleum and Chemical Engineering Programme area, Faculty of Engineering, Universiti Teknologi Brunei, Gadong, Brunei Darussalam 2 Department of Engineering, College of Applied Sciences, Sohar, Sultanate of Oman 3 Sathyabama Institute of Science and Technology, Chennai, India * Correspondence: Email: [email protected]; [email protected]. Abstract: Due to advances in its effectiveness and efficiency, solar thermal energy is becoming increasingly attractive as a renewal energy source. Efficient energy storage, however, is a key limiting factor on its further development and adoption. Storage is essential to smooth out energy fluctuations throughout the day and has a major influence on the cost-effectiveness of solar energy systems. This review paper will present the most recent advances in these storage systems. The manuscript aims to review and discuss the various types of storage that have been developed, specifically thermochemical storage (TCS), latent heat storage (LHS), and sensible heat storage (SHS). Among these storage types, SHS is the most developed and commercialized, whereas TCS is still in development stages. The merits and demerits of each storage types are discussed in this review. Some of the important organic and inorganic phase change materials focused in recent years have been summarized. The key contributions of this review article include summarizing the inherent benefits and weaknesses, properties, and design criteria of materials used for storing solar thermal energy, as well as discussion of recent investigations into the dynamic performance of solar energy storage systems. -
Matching the Sensible Heat Ratio of Air Conditioning Equipment with the Building Load SHR
Matching the Sensible Heat Ratio of Air Conditioning Equipment with the Building Load SHR Final Report to: Airxchange November 12, 2003 Report prepared by: TIAX LLC Reference D5186 Notice: This report was commissioned by Airxchange on terms specifically limiting TIAX’s liability. Our conclusions are the results of the exercise of our best professional judgement, based in part upon materials and information provided to us by Airxchange and others. Use of this report by any third party for whatever purpose should not, and does not, absolve such third party from using due diligence in verifying the report’s contents. Any use which a third party makes of this document, or any reliance on it, or decisions to be made based on it, are the responsibility of such third party. TIAX accepts no duty of care or liability of any kind whatsoever to any such third party, and no responsibility for damages, if any, suffered by any third party as a result of decisions made, or not made, or actions taken, or not taken, based on this document. TIAX LLC Acorn Park • Cambridge, MA • 02140-2390 USA • +1 617 498 5000 www.tiax.biz Table of Contents TABLE OF CONTENTS............................................................................................................................ I LIST OF TABLES .....................................................................................................................................II LIST OF FIGURES .................................................................................................................................III -
Heat and Thermodynamics Course
Heat and Thermodynamics Introduction Definitions ! Internal energy ! Kinetic and potential energy ! Joules ! Enthalpy and specific enthalpy ! H= U + p x V ! Reference to the triple point ! Engineering unit ! ∆H is the work done in a process ! J, J/kg More Definitions ! Work ! Standard definition W = f x d ! In a gas W = p x ∆V ! Heat ! At one time considered a unique form of energy ! Changes in heat are the same as changes in enthalpy Yet more definitions ! Temperature ! Measure of the heat in a body ! Heat flows from high to low temperature ! SI unit Kelvin ! Entropy and Specific Entropy ! Perhaps the strangest physics concept ! Notes define it as energy loss ! Symbol S ! Units kJ/K, kJ/(kg•k) ! Entropy increases mean less work can be done by the system Sensible and Latent Heat ! Heat transfers change kinetic or potential energy or both ! Temperature is a measure of kinetic energy ! Sensible heat changes kinetic (and maybe potential energy) ! Latent heat changes only the potential energy. Sensible Heat Q = m⋅c ⋅(t f − ti ) ! Q is positive for transfers in ! c is the specific heat capacity ! c has units kJ/(kg•C) Latent Heat Q = m⋅lv Q = m⋅lm ! Heat to cause a change of state (melting or vaporization) ! Temperature is constant Enthalpy Changes Q = m⋅∆h ! Enthalpy changes take into account both latent and sensible heat changes Thermodynamic Properties of H2O Temperature °C Sensible heat Latent heat Saturation temp 100°C Saturated Saturated liquid steam Superheated Steam Wet steam Subcooled liquid Specific enthalpy Pressure Effects Laws of Thermodynamics ! First Law ! Energy is conserved ! Second Law ! It is impossible to convert all of the heat supplied to a heat engine into work ! Heat will not naturally flow from cold to hot ! Disorder increases Heat Transfer Radiation Conduction • • A 4 Q = k ⋅ ⋅∆T QαA⋅T l A T2 T1 l More Heat Transfer Convection Condensation Latent heat transfer Mass Flow • from vapor Q = h⋅ A⋅∆T Dalton’s Law If we have more than one gas in a container the pressure is the sum of the pressures associated with an individual gas. -
Module P7.4 Specific Heat, Latent Heat and Entropy
FLEXIBLE LEARNING APPROACH TO PHYSICS Module P7.4 Specific heat, latent heat and entropy 1 Opening items 4 PVT-surfaces and changes of phase 1.1 Module introduction 4.1 The critical point 1.2 Fast track questions 4.2 The triple point 1.3 Ready to study? 4.3 The Clausius–Clapeyron equation 2 Heating solids and liquids 5 Entropy and the second law of thermodynamics 2.1 Heat, work and internal energy 5.1 The second law of thermodynamics 2.2 Changes of temperature: specific heat 5.2 Entropy: a function of state 2.3 Changes of phase: latent heat 5.3 The principle of entropy increase 2.4 Measuring specific heats and latent heats 5.4 The irreversibility of nature 3 Heating gases 6 Closing items 3.1 Ideal gases 6.1 Module summary 3.2 Principal specific heats: monatomic ideal gases 6.2 Achievements 3.3 Principal specific heats: other gases 6.3 Exit test 3.4 Isothermal and adiabatic processes Exit module FLAP P7.4 Specific heat, latent heat and entropy COPYRIGHT © 1998 THE OPEN UNIVERSITY S570 V1.1 1 Opening items 1.1 Module introduction What happens when a substance is heated? Its temperature may rise; it may melt or evaporate; it may expand and do work1—1the net effect of the heating depends on the conditions under which the heating takes place. In this module we discuss the heating of solids, liquids and gases under a variety of conditions. We also look more generally at the problem of converting heat into useful work, and the related issue of the irreversibility of many natural processes. -
Appendix B: Petroski
““TheThe wordword sciencescience waswas prominentprominent inin PresidentPresident--electelect BarackBarack ObamaObama’’ss announcementannouncement ofof hishis choiceschoices toto taketake onon leadingleading rolesroles inin thethe areasareas ofof energyenergy andand thethe environment.environment. Unfortunately,Unfortunately, thethe wordword engineeringengineering waswas absentabsent fromfrom hishis remarks.remarks.”” first draft, December 10, 2008 ““.. .. .. WeWe willwill buildbuild thethe roadsroads andand bridges,bridges, thethe electricelectric gridsgrids andand thethe digitaldigital lineslines thatthat feedfeed ourour commercecommerce andand bindbind usus together.together. ““WeWe willwill restorerestore sciencescience toto itsits rightfulrightful place,place, andand wieldwield technologytechnology’’ss wonderswonders toto raiseraise healthhealth carecare’’ss qualityquality andand lowerlower itsits cost.cost. WeWe willwill harnessharness thethe sunsun andand thethe windswinds andand thethe soilsoil toto fuelfuel ourour carscars andand runrun ourour factories.factories.”” ——InauguralInaugural AddressAddress JanuaryJanuary 20,20, 20200909 “‘“‘WeWe willwill restorerestore sciencescience toto itsits rightfulrightful place,place,’’ PresidentPresident ObamaObama declareddeclared inin hishis inauguralinaugural address.address. ThatThat certainlycertainly soundssounds likelike aa worthyworthy goal.goal. ButBut frankly,frankly, itit hashas meme worried.worried. IfIf wewe wantwant toto ‘‘harnessharness thethe sunsun andand thethe windswinds