DOCSLIB.ORG

LOS ALAMOS SCIENTIFIC LABORATORY of the University of California LOS ALAMOS ● NEW MEXICO

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
LOS ALAMOS SCIENTIFIC LABORATORY of the University of California LOS ALAMOS ● NEW MEXICO LA-3871-MS LOS ALAMOS SCIENTIFIC LABORATORY of the University of California LOS ALAMOS ● NEW MEXICO A Bibliography on Nuclear Magnetic Resonance of Inorganic Fluorides 1.. .— t“ l-- — r! UNITED STATES ATOMIC ENERGY COMMISSION CONTRACT W-7405 -ENG. 36 LEGAL NOTICE This reportwas preparedas an accountof Governmentsponsoredwork. Neitherthe United States,nor theCommission,nor any personactingon behalfoftheCommission: A. Makes any warrantyorrepresentation,expressedor implied,withrespecttoiheaccu- racy,completeness,or usefulnessoftheinformationcontainedinthisreport,or thattheuse of any information,apparatus,meihcd,or processdisclosedin thisreportmay not infringe privatelyowned rights;or B. Assumes any liabilitieswithrespecttotheuse of,or fordamages resultingfrom the use ofany information,apparatus,method,or processdisclosedinthisreport. AE used in theabove,“personactingon behalfof the Commission” includesany em- ployeeor contractorof theCommission,or employeeof such contractor,tothe extentthat such empioyeeor contractorof theCommission,or employeeof such contractorprepares, disseminates,or providesaccessto,any informationpursuanitohisemploymentor contract withtheCommission,or hiaemploymentwithsuchcontractor. This report expresses the opinions of the author or authors and does not necessarily reflect the opinions or views of the Los Alamos Scientific Laboratory. Printed in the United States of America. Available from Clearinghouse for Federal Scientific and Technical Information * National Bureau of Standards, U. S. Department of Commerce Springfield, Virginia 22151 Price: Printed Copy $ 3.00; Microfiche $0.65 , LA-3871-MS UC-4, CHEMISTRY TID-4500 LOS ALAMOS SCIENTIFIC LABORATORY of the University of California LOS AI.AMOS c NEW MEXICO Report written: December 1967 Report distributed: February 19, 1968 A Bibliography on Nuclear Magnetic Resonance of Inorganic Fluorides Compiled by ..——— Jean Furnish . -1 . ● A BIBLIOGRAPHYON ● NUCLEAR MAGNETIC RESONANCE OF INORGANIC FLUORIDES INTRODUCTION For this bibliography only volumes 51 (1957) through NUCLSAR NAGNETIC RESONANCE IN COF2 AND FeF2 65 (1966) of Chemical Abstracts were consulted. In- J. M. Baker and W. Hayea organic fluorides alone, in solvents of any sort, Phys. Rev. ~, 603-4 (1~~) and in complexes with organic and inorganicmole- 51:17432d cules have been included. All referenceswere in- dexed under “nuclear magnetic resonance” in Chemi- FLUORINE-19 NUCLEAR-MAGNSTIC-RESONANCELINS SHAPES ical Abstracts. IN CALCIUM FLUORIDE C. R. Bruce Most of the references included in this bibliography Phys;5~+5& 43-5 (1957) were published in the period 197-1966. However, : since the search was confined to specific volumes of Chemical Abstracts, and all references therefrom NUCLEAR MGNETIC RESONANCE STUDIES OF THE ALUMINUM were included, it will be noted that there are some FLUORIDE COMPLEKES citations earlier than 1957. It may also be pointed Robert E. Cormick and Richard E. Poulson out that in order to obtain a somewhat more complete J. h52ChlnndSOCO ~, 5153-’7(1957) list of references for 1966 it would be necessary : to go beyond the cut-off point of volume 65 of Chemical Abstracts. It was not possible to do this NUCLEAR NAGNETIC RESONANCE STUDIES OF BF3 CCMPLEX in the present case. FORMATION P. Diehl and R. A. Ogg Entries in this bibliography are arranged by year Nat.r~2@&114 (1957) with the earliest given first, then alphabetically : by author’a name. For each item the location of the Chemical Abstracts entry is given following the bib- NucLsAR WGNETIC RESONANCE IN PARAMAGN5TIC IRON liographic citation. ‘l%is includes volume and COl- GROUP FLUORIDES umn location number only, i.e., 63:7866f indicates V. Jaccarino, R. G. Shulman, and J. W. Stout the item is from volume 63 of Chemical Abstracts, phys.5~+4* 602-3 (1957) and the location is at 7866f within that volume. : NUCLEAR MAGNETIC RESONANCE (n.m.r.) IN ANTIFERRO- MAGNETIc NnF49 NUCLEAR RESONANCE SPECTRA AND THE STRUCTURESOF THE V. Jaccarino and R. G. Schulman MONO- AND DIHYDRATE OF EJ3RONTRIFLUORIDE Phys.5fij4v 1196-7 (1957) P. T. Ford and R. E. Richarda : J. Chem. Sot. 387o-4 (1956) 51:1669d NUCLEAR MAGNETIC RESONANCE IN SINGLE-CRYSTALLITHI- UM FLUORIDE EOWN TO 1.5°K NITRYL FLUORIDE: A NEW METHOD OF PREPARATION, Frank J. Law and C. F. Squire NUCLEAR MAGNETIC SPECTRUM, AND STRUCTURE Bull. Am. Phya. Sot. (2); g, 103 (1957) Richard A. Ogg, Jr., and James D. Ray 52:12546d J. Chq.T~&;. Q, 797-8 (1956) : FREE-INDucTIoNDEcAw IN SOLIDS I. J. Lowe and R. E. Norberg NUCLBAR MAGNETIC RESONANCE STUDIES OF SOME INOR- Phys.5~;5~ 46-61 (1957) GANIC ~LECULES AND IONS : . Richard Edwin Poulson UCRL-~~6:h:~PP. (1956) LEwIs CHARACTER oF TELLURIUM HEKAFLuoRIDE : E. L. Muetterties and W. D. Phillips J. &lh1ch~WlU40Co ~, 2075 (1957) . NUCLEAR RELAXATION IN ANTIFERROMAGNETICCRYSTALS : J. van Kranendonk and M. Bloom Physica 22, 545-6o (1956) 52:9775e 1 STRUCTURE OF CIF AND EXCHANGE STUDIES ON SOME hfAGN5TIcwsowcE LINE SHAPES AT THE ONSET OF HALOGEN FLUORIDE2 BY NUCLEAR MAGNETIC RESONANCE SATURATION (n.m.r.) D. F. Holcomb E. L. Muetterties and W. D. Phillips Phys. Rev. ~ 1599-1603 (l@) J. Am;2chh6dsoc. Q 322-6 (197) 53:19572i : NUCLEAR RESONANCE SIGNALS OBTAINED BY DYNAMIC NUCLEAR MAGNETIC RESONANCE SPLITTINGS IN VERY WBAK POLARIZATION FIELDS (35-15 GAUSSES) Andre Landesman Dominique P. Roux and George J. Bene timPtj2r&&~ 1538-4o (1958) J. Chem. Phys. ~, 968-9 (1957) : 51:12646i PROTON RESONANCE SPECTRA OF SOKS CRYSTALS CONTAIN- NUCLEAR MAGNETIC KESONANCE IN PARAMAGNETICMANGA- ING NITROGEN AND FLUORINE NOUS FLUORIDE J. B. Leane and R. E. Richards R. G. Shulman and V. Jaccarino Spectrochim.Acta~, 154-60 (IY8) Phys.5~k* 1219-31 (1957) 52:$1755d ELECTKDN-NUCLZARDOUBLE RESONANCE OF F CENTERS ME!! IN LITHIUM FLUORIDE Norman W. I.ard CHEMICAL SHIFT AND THE FINE STRUCTURE OF THE SIG- Phys. Rev. Lettera ~, 170-1 (1958) NALS OF NUCLEAR NAGNETIC RESONANCE. I. EXPERI- 52:17g64h MENTAL METHOD AND THE INVESTIGATIONOF THE SYSTEM HF-H20 NUCLEAR MAGNETIC RESONANCE IN LITHIUM FLWRIDE P. M. Borodin and F. I. Skripor F. J. Low and C. F. Squire Izvest. Vysshikh Ucheb. Zavedneii, Radiofiz, No. 3, Phys.5mi&rn. Solids ~, 85-8 (1958) 37-49 (1958) : 53:12000b CHEMISTRY OF SOME SULFUR OXYFLUORIDES EFFECT OF ENVIRONMENT ON THE FLUORINE MAGNETIC E. L. Muetterties and D. D. Coffman RESONANCE IN SOLUTIONS OF POTASSIUM FLUORIDE J. Am;3Che;gSOC. ~ 5914-18 (1958) Alan Barrington and Theodore Hines J. Chem. Phys. 28, 727-8 (1958) 52:12561a INDIRECT COUPLING OF NUCLEAR SPINS IN AN ANTI- FERkOMAGNETWITH PARTICULAR REFERENCE TO MnF2 AT TETRAFLUOROHYDRAZINE VERY LOW TEMPERATURES Charlea B. tilburn and Al Kennedy Tautao Nakamura J. Am#emiSOC. &J, 5004 (1958) progr. Theoret. Phys. (Kyoto)~, 5@-52 (1958) : 53:10970b ELECTROLYTE EFFECTS ON NUCLSAR MAGNETIC RESONANCE NUCLEAR MAGNETIC RESONANCE (N.M.R.) STUDIES OF GO- FREQUENCIES OF FLUORINE IN AQUEOUS SOLUTIONS ORDINATE COMPLEX FORMATION BY BORON TRIFLUORIDE Robert E. Connick and Richard E. Poulson Richard A. Ogg, Jr., and Peter Diehl J. Phys. Chem. ~, 1oo2-4 (1958) Chem. Co-Oral.Compds., Symp., Rome 1957, 468-75 53:865i (Pub. 1958) 58 :2041c NUCLEAR RSEONANCE SPECTRUM AND STRUCTURE OF SULFUR TETKAFLUORIDE NUCLEAR MAGNETIC RESONANCE STUDIES OF COORDINATE F. A. Cotton, J. W. George, and J. S. Waugh COMPLEX FORNATION BY BORON TRIFLUORIDE J. Chem. Phys. 28, 994-5 (1958) Richard A. Ogg, Jr., and Peter Diehl ~2:15252c J. Inc.~j9~~ Nuclear Chem. ~, 468-75 (1958) NUCLEAR MAGNETIC RESONANCE STUDIES OF BORON TRI- FLUORIDE COMPLEX FORMATION LITHIUM-7 AND FLUORINE-19 NUCLEAR MAGNETIC RESO- P. Diehl NANCES IN NEUTRON-IRRADIATEDLITHIUM FLUORIDE Helv. Phys. Actajil, 685-712 (1958) P. J. Ring. J. G. O!Keefe. and P. J. Brav 53:17673b F’hys.5ev~$etters~, 453:4 (l$@3) “ : STUDY OF BORON TRIFLUORIDE COMPLEXES BY NUCLEAR MAGNETIC RESONANCE DOUBLE NUCLEAR RESONANCE IN CRYSTALS OF LITHIUM P. Diehl and J. Gr~nacher FLUORIDE Helv~-Phya.Acta~ 43-4 (1958) E. E. Schneider and K. ThomDson 52:19656b J. Phya. Radium~, 834-6 (ig’j8) (in French) . 53:8814e THE STRUCTURE OF LIQUID ANTIMONY PENTAFLUORIDE Charlea J. Hoffman, Bert E. Holder, and William L. NUCLEAR MAGNETIC RESONANCE OF FLUORINS IN FLUORO- SILANES . Erhard Schnell and Eugene G. Rochow J. InOrg. Nucl. Chem.-~, 303-7 (1958) 52:17g63d 2 ORIGIN OF NUCLEAR MAGNETIC RESONANCE SHIFTS IN PARA- EFFECTS OF THE COBALT-59 HYPERFINE STRUCTURE ON MAGNETIC MANGANESE ‘TRIFLUORIDE THE FLUORINE-19 HIGH-FREQUENCYNUCLEAR MAGNETIC R. G. Schulman and V. Jaccarino RESONANCE IN ANTIFERROMAGNETICCOF2 Phys. Rev. l= 1084-5 (1958) V. Jaccarino >2:ll>78a J. Chem. Phys. ~, 1627-8 (1959) >3:19>7jd NUCLEAR MAGNETIC RESONANCE IN ANTIFERROMAGNETIC THE FORM OF RESONANCE LINES IN RIGID SYSTEMS M*19 Anatole Abragam and Jacques Michel Winter V. $accarfno and L. R. Walker timPtj4r:n&j8~ 1633-4 (1959) J. Phys, Radium2Q, 341-3 (1959) : 53:21181h PRINCIPLES OF PHOSPHORUS CHEMISTRY. IV. THE sYs- DIFLUOROAMINE TEM OF FLUOROPHOSPHORICACIDS Al Kennedy and Charles B. Colburn Donald P. Ames, Shf.geruOhashi, Clayton F. Callis, J. Am. Chem. Sot. 81, 2906-7 (1959) and John R. Van Wazer 53:l>844b J. Am. Chem. Sot. & 635o-7 (1959) >k:l1792d FREE INDUCTION DECAY OF ROTATING SOLIDS I. J. Lowe NUCLEAR MAGNETIC RESONANCE STUDY OF FLUORINE IN Phys.5fiG1~ters~ 285-7 (1959) SILVER FLUORIDE AND SILVER SUBFLUORIDE : Q. Won Choi Univ. Microfilms (Ann Arbor, Mich.), L.C. Card No. NUCLEAR MAGNETIC RESONANCE FREQUENCY SHIFT OF C059 Mic 59-1611, 97 pp.; DissertationAbstr. 20, 111 IN COF2 (1959) Toru Noriya 53:18632a Phys.5hm.oolidsll, 175-6 (1959) F19 NUCLEAR MAGNETIC RESONANCE OF VARIOUS METAL- FLUORIDE COMPLEXES IN AQUEOUS SOLUTION STRUCTURE OF EXCHANGE PROCESSES IN SOME INORGANIC Robert E. Connick and Richard E. Poulson FLUORIDES BY NUCLEAR MAGNETIC RESONANCE J. Phys. Chem. ~, 568-9 (1959) E. L. Muetterties and W. D. Phillips 53:l>772e J. Am. Chem. Sot. 81, 1084-8 (1959) 53:10974b STRUCTURE SENSITIVI’lYOF THE HIGH-FREQUENCYNUCLEAR MAGNETIC RESONANCE IN POWDERED ANTIFERROMAGNETIC CRYSTALLINEFIELD SPLITTING IN FERROUS FLUOSILICATE W2 Taiichiro Ohtsuka J, L. Davis, G. E. Devlin, V. Jaccarino, and A. L. J. Ph~;.9~2i Japan~, 1245 (1959) Schawlow Phys.5~;o~~.
Load more

Recommended publications
  • Ni33nh3+3Nhi
    Pure & Appi. Chem., Vol. 49, pp.67—73. Pergamon Press, 1977. Printed in Great Britain. NON-AQJEOUS SOLVENTS FOR PREPARATION AND REACTIONS OF NITROGEN HALOGEN COMPOUNDS Jochen Jander Department of Chemistry, University of Heidelberg, D 69 Heidelberg, Germany Abstract -Theimportance of non—aqueous solvents for the chemistry of haloamines is shown in more recent reaction examples. The solvents must be low-melting because of the general temperature sensitivity of the haloamines. They may take part in the reaction (formation of CH NI •CH NH (CH )2NI, NI-,.5 NH-, and NH0I.NH-)ormay e ner (ormation of I .quinuiilidin, 2 NI •1 trithylenediamine, [I(qunuclidine),] salts pure NBr, and compounds of the type R1R2NC103 with R1 and R2 =orgnicgroup or hydrogen). INTRODUCTION Non-aqueous solvents play an important role in preparation and reactions of nitrogen halogen compounds. Due to the fact, that all haloamines are derivatives of ammonia or amines, liquid ammonia or liquid organic amines are used as solvents very often. Liquid ammonia and the lower organic amines reveal, in addition, the advantage of low melting points (liquid ammonia -78, liquid monomethylamine -93.5, liquid dimethylamine -92, liquid tn-. methylamine -12k°C); these meet the general temperature sensitivity of the nitrogen halogen compounds, especially of the pure .lorganic ones. Ammonia and amines are very seldom inert solvents; they mostly take part in the reaction planned for synthesis or conversion of the haloamine. In case a reaction of the solvent is to be avoided, one has to look for a low melting inert solvent, for example methylene chloride (m.p.
    [Show full text]
  • (VI) and Chromium (V) Oxide Fluorides
    Portland State University PDXScholar Dissertations and Theses Dissertations and Theses 1976 The chemistry of chromium (VI) and chromium (V) oxide fluorides Patrick Jay Green Portland State University Follow this and additional works at: https://pdxscholar.library.pdx.edu/open_access_etds Part of the Chemistry Commons Let us know how access to this document benefits ou.y Recommended Citation Green, Patrick Jay, "The chemistry of chromium (VI) and chromium (V) oxide fluorides" (1976). Dissertations and Theses. Paper 4039. https://doi.org/10.15760/etd.5923 This Thesis is brought to you for free and open access. It has been accepted for inclusion in Dissertations and Theses by an authorized administrator of PDXScholar. Please contact us if we can make this document more accessible: [email protected]. All ABSTRACT OF THE TllESIS OF Patrick Jay Green for the Master of Science in Chemistry presented April 16, 1976. Title: Chemistry of Chromium(VI) and Chromium(V) Oxide Fluorides. APPROVEO BY MEMBERS OF THE THESIS CO'"o\l TIEE: y . • Ii . ' I : • • • • • New preparative routes to chromyl fluoride were sought. It was found that chlorine ironofluoride reacts with chromium trioxide and chromyl chlo­ ride to produce chromyl fluoride. Attempts were ~ade to define a mechan­ ism for the reaction of ClF and Cr0 in light of by-products observed 3 and previous investigations. Carbonyl fluoride and chromium trioxide react to fom chro·yl fluoride and carbo:i dioxide. A mechanism was also proposed for this react10n. Chromium trioxide 11itl\ l~F6 or WF5 reacts to produce chromyl fluoride and the respective oxide tetrafluoride. 2 Sulfur hexafluoride did not react with Cr03.
    [Show full text]
  • Safety Data Sheet
    SAFETY DATA SHEET Preparation Date: 05/19/2015 Revision Date: 05/08/2017 Revision Number: G2 1. IDENTIFICATION Product identifier Product code: B1100 Product Name: BISMUTH METAL, GRANULAR, REAGENT Other means of identification Synonyms: Bismuth-209 Bismuth, elemental CAS #: 7440-69-9 RTECS # EB2600000 CI#: Not available Recommended use of the chemical and restrictions on use Recommended use: In safety devices in fire detection and extinguishing systems; Catalyst for making acrylic fibers; In production of malleable irons; carrier for radioactive uranium fuel in atomic reactor; In printing industry; alloying agent; chemical intermediate for pharmaceuticals and other chemicals; In cosmetics. Uses advised against No information available Supplier: Spectrum Chemical Mfg. Corp 14422 South San Pedro St. Gardena, CA 90248 (310) 516-8000. Order Online At: https://www.spectrumchemical.com Emergency telephone number Chemtrec 1-800-424-9300 Contact Person: Martin LaBenz (West Coast) Contact Person: Ibad Tirmiz (East Coast) 2. HAZARDS IDENTIFICATION Classification This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Not a dangerous substance or mixture according to the Globally Harmonized System (GHS) Label elements Not classified Hazards not otherwise classified (HNOC) Not Applicable Other hazards May be harmful if swallowed Product code: B1100 Product name: BISMUTH METAL, 1 / 11 GRANULAR, REAGENT 3. COMPOSITION/INFORMATION ON INGREDIENTS Components CAS-No. Weight % Bismuth Metal 7440-69-9 100 4. FIRST AID MEASURES First aid measures General Advice: National Capital Poison Center in the United States can provide assistance if you have a poison emergency and need to talk to a poison specialist.
    [Show full text]
  • United States Patent Office Patented Dec
    3,629,301 United States Patent Office Patented Dec. 21, 1971 3,629,301 3,3-DIFLUORO-2-SUBSTITUTED STEROIDS AND THER PREPARATION William C. Ripka, Wilmington, Del, assignor to E. I. du Pont de Nemours and Company, Wilmington, Del. 5 where R is hydrogen, methyl, or ethynyl, and R2 is hydro No Drawing. Filed Oct. 24, 1969, Ser. No. 869,352 gen or an alkanoyl having no more than 8 carbon atoms, Int, C. C07c 169/20 Such as formyl, acetyl, propionyl, butyryl, valleryl and U.S. C. 260-397.3 10 Claims caproyl. These compounds are prepared from 3-fluoro-A2-steroids 10 by a reaction with nitrosyl fluoride and subsequent conver ABSTRACT OF THE DISCLOSURE sion of the 3,3-difluoro-2-nitrimino steroid products to the New steroids of the formula corresponding 3,3-difluoro-2-keto steroids with alumina CE containing Water, as shown in the reaction scheme below X involving the steroid A-ring: R NO R R ? NOF N= A. AlO3.H2O Os R - A. l -3 F2 Fs! N Z-F 20 The 2-keto group can be converted to the 2-hydroxy F= group by conventional techniques, including, for example, wherein Z is oxygen or reduction with sodium borohydrides. DETALED DESCRIPTION OF THE INVENTION The first step of the reaction sequence, the reaction of a .O 3-fluoro-Asteroid with nitrosyl fluoride is carried out in R is hydrogen or methyl; and X is oxygen or an inert Solvent such as methylene chloride, chloroform, OR2 carbon tetrachloride, fluorodichloromethane, and ethylene 30 dichloride.
    [Show full text]
  • Chemical Chemical Hazard and Compatibility Information
    Chemical Chemical Hazard and Compatibility Information Acetic Acid HAZARDS & STORAGE: Corrosive and combustible liquid. Serious health hazard. Reacts with oxidizing and alkali materials. Keep above freezing point (62 degrees F) to avoid rupture of carboys and glass containers.. INCOMPATIBILITIES: 2-amino-ethanol, Acetaldehyde, Acetic anhydride, Acids, Alcohol, Amines, 2-Amino-ethanol, Ammonia, Ammonium nitrate, 5-Azidotetrazole, Bases, Bromine pentafluoride, Caustics (strong), Chlorosulfonic acid, Chromic Acid, Chromium trioxide, Chlorine trifluoride, Ethylene imine, Ethylene glycol, Ethylene diamine, Hydrogen cyanide, Hydrogen peroxide, Hydrogen sulfide, Hydroxyl compounds, Ketones, Nitric Acid, Oleum, Oxidizers (strong), P(OCN)3, Perchloric acid, Permanganates, Peroxides, Phenols, Phosphorus isocyanate, Phosphorus trichloride, Potassium hydroxide, Potassium permanganate, Potassium-tert-butoxide, Sodium hydroxide, Sodium peroxide, Sulfuric acid, n-Xylene. Acetone HAZARDS & STORAGE: Store in a cool, dry, well ventilated place. INCOMPATIBILITIES: Acids, Bromine trifluoride, Bromine, Bromoform, Carbon, Chloroform, Chromium oxide, Chromium trioxide, Chromyl chloride, Dioxygen difluoride, Fluorine oxide, Hydrogen peroxide, 2-Methyl-1,2-butadiene, NaOBr, Nitric acid, Nitrosyl chloride, Nitrosyl perchlorate, Nitryl perchlorate, NOCl, Oxidizing materials, Permonosulfuric acid, Peroxomonosulfuric acid, Potassium-tert-butoxide, Sulfur dichloride, Sulfuric acid, thio-Diglycol, Thiotrithiazyl perchlorate, Trichloromelamine, 2,4,6-Trichloro-1,3,5-triazine
    [Show full text]
  • Information to Users
    INFORMATION TO USERS This manuscript has been reproduced from the microfilm master. UMI films the text directly from the original or copy submitted. Thus, some thesis and dissertation copies are in typewriter face, while others may be from any type of computer printer. The quality of this reproduction is dependent upon the quality of the copy submitted. Broken or indistinct print, colored or poor quality illustrations and photographs, print bleedthrough, substandard margins, and improper alignment can adversely affect reproduction. In the unlikely event that the author did not send UMI a complete manuscript and there are missing pages, these will be noted. Also, if unauthorized copyright material had to be removed, a note will indicate the deletion. Oversize materials (e.g., maps, drawings, charts) are reproduced by sectioning the original, beginning at the upper left-hand corner and continuing from left to right in equal sections with small overlaps. Each original is also photographed in one exposure and is included in reduced form at the back of the book. Photographs included in the original manuscript have been reproduced xerographically in this copy. Higher quality 6" x 9" black and white photographic prints are available for any photographs or illustrations appearing in this copy for an additional charge. Contact UMI directly to order. University Microfilms International A Bell & Howell Information Company 300 North Zeeb Road. Ann Arbor. Ml 48106-1346 USA 313/761-4700 800/521-0600 Order Number 9505198 T h e 1 /1 1 band of cyanuric fluoride and the A *11 - X *E+ transition of aluminum monobromide Fleming, Patrick E., Ph.D.
    [Show full text]
  • 2019 Sodium Iodide
    VETPAK SAFETY DATA SHEET Section 1: Identification of the Substance or Mixture and of the Supplier Product Name: Sodium Iodide. Other Names: Sodium monoiodide. Recommended Use: Reagent in analytical chemistry, Photographic emulsions (precipitating silver), Feed additive, Spectroscopy, Infrared transmission, dietary supplement (up to 0.01% in table salt). Company Details: Vetpak Ltd. Address: 249 Bruce Berquist Dr, Te Awamutu 3800. Telephone Number: (07) 870 2024 Emergency Telephone Number: (0800) 764-766 24 hours. National Poisons Centre, Department of Preventative and Social Medicine, University of Otago, P O Box 913, Dunedin, New Zealand. (07) 870 2024 Vetpak. 8.00am to 5.00pm Monday to Friday except public holidays. Date of Preparation: 31st July 2019 Section 2: Hazards Identification STATEMENT OF HAZARDOUS NATURE This product is HAZARDOUS IN THIS FORM AND AT THIS STRENGTH. Handle correctly and as directed by this SDS. EPA New Zealand approval code: HSR003606 HAZARD LABELLING WARNING HAZARD CLASSIFICATION AND STATEMENTS HSNO HSNO GHS Signal Word GHS Hazard Statement 6.1E Acute Toxicity (All) Category 5 Warning H303 H313 H333 May be harmful if swallowed, in contact with the skin, inhaled 6.5B Contact sensitiser Category 1 Warning H317 May cause an allergic skin reaction 6.9A Harmful to human target Category 1 Danger H370 H372 Causes damage organs or systems to organs 9.1A Aquatic toxicity Category 1 Warning H400 Very toxic to aquatic life Prevention Statements: P102: Keep out of reach of children. P103: Read label before use. P260: Do not breathe mist/vapours/spray P261: Avoid breathing dust P264: Wash hands thoroughly after use. P270: Do not eat, drink or smoke when handling this product.
    [Show full text]
  • Naming Molecular Compounds General Instructions: Please Do the Activities for Each Day As Indicated
    Teacher Name: Dwight Lillie Student Name: ________________________ Class: ELL Chemistry Period: Per 4 Assignment: Assignment week 2 Due: Friday, 5/8 Naming Molecular Compounds General Instructions: Please do the activities for each day as indicated. Any additional paper needed please attach. Submitted Work: 1) Completed packet. Questions: Please send email to your instructor and/or attend published virtual office hours. Schedule: Date Activity Monday (4/27) Read Sections 9.3, 9.5 in your textbook. Tuesday (4/28) Read and work through questions 1-9 Wednesday (4/29) Read and work through questions 10-14 Thursday (4/30) Read and work through questions 14-18 Friday (5/31) Read and work through questions 19-21 How are the chemical formula and name of a molecular compound related? Why? When you began chemistry class this year, you probably already knew that the chemical formula for carbon dioxide was CO2. Today you will find out why CO2 is named that way. Naming chemical compounds correctly is of paramount importance. The slight difference between the names carbon monoxide (CO, a poisonous, deadly gas) and carbon dioxide (CO2, a greenhouse gas that we exhale when we breathe out) can be the difference between life and death! In this activity you will learn the naming system for molecular compounds. Model 1 – Molecular Compounds Molecular Number of Atoms Number of Atoms in Name of Compound Formula of First Element Second Element ClF Chlorine monofluoride ClF5 1 5 Chlorine pentafluoride CO Carbon monoxide CO2 Carbon dioxide Cl2O Dichlorine monoxide PCl5 Phosphorus pentachloride N2O5 Dinitrogen pentoxide 1. Fill in the table to indicate the number of atoms of each type in the molecular formula.
    [Show full text]
  • Megalomania's Controversial Chem Lab
    Megalomania's Controversial Chem Lab Navigation Welcome to the Controversial Chem Lab. Here at the Chem Lab you » Home can find information on a large number of chemicals that have a » Explosives certain stigma attached to them. Chemicals such as explosives, drugs, and pesticides are vitally important for the survival of our civilization. » Chemical Unfortunately, the scientific elite jealously hoards the knowledge on Weapons using and preparing these chemicals. Adding to the confusion is the » Pharmaceuticals scientific ignorant who fear chemistry and think these chemicals are » Pesticides dangerous. As my chemistry professor used to say about what they think, “chemistry equals bad.” » Precursors The Controversial Chem Lab was created to be a free reference on » Lab Skills how to synthesize chemicals. It is also a virtual laboratory skills » Lab Equipment manual, complete with descriptions on how to conduct laboratories, » Safety and a visual database on many different kinds of laboratory apparatus. While the Chem Lab is written for the non-chemist audience, it does » Rogue Science require a basic understanding of laboratory skills. Of course, all of the » Links information needed to acquire a basic understanding of lab skills is » What’s New included within the site. The Chem Lab even goes the extra mile in providing information on » Contact Me how to synthesize many of the chemicals used in making explosives, » Disclaimer etc. It also provides information on where to acquire certain chemicals » Search this site and apparatus. While all of this information is perfectly legal, it may be against the law in certain areas to prepare some of these chemicals without the proper license.
    [Show full text]
  • WO 2016/074683 Al 19 May 2016 (19.05.2016) W P O P C T
    (12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (10) International Publication Number (43) International Publication Date WO 2016/074683 Al 19 May 2016 (19.05.2016) W P O P C T (51) International Patent Classification: (81) Designated States (unless otherwise indicated, for every C12N 15/10 (2006.01) kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, (21) International Application Number: BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, PCT/DK20 15/050343 DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, (22) International Filing Date: HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KN, KP, KR, 11 November 2015 ( 11. 1 1.2015) KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, (25) Filing Language: English PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, (26) Publication Language: English SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (30) Priority Data: PA 2014 00655 11 November 2014 ( 11. 1 1.2014) DK (84) Designated States (unless otherwise indicated, for every 62/077,933 11 November 2014 ( 11. 11.2014) US kind of regional protection available): ARIPO (BW, GH, 62/202,3 18 7 August 2015 (07.08.2015) US GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, (71) Applicant: LUNDORF PEDERSEN MATERIALS APS TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, [DK/DK]; Nordvej 16 B, Himmelev, DK-4000 Roskilde DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, (DK).
    [Show full text]
  • Crystal Structure Transformations in Binary Halides
    1 A UNITED STATES DEPARTMENT OF A111D3 074^50 IMMERCE JBLICAT10N NSRDS—NBS 41 HT°r /V\t Co^ NSRDS r #C£ DM* ' Crystal Structure Transformations in Binary Halides u.s. ARTMENT OF COMMERCE National Bureau of -QC*-| 100 US73 ho . 4 1^ 72. NATIONAL BUREAU OF STANDARDS 1 The National Bureau of Standards was established by an act of Congress March 3, 1901. The Bureau's overall goal is to strengthen and advance the Nation’s science and technology and facilitate their effective application for public benefit. To this end, the Bureau conducts research and provides: (1) a basis for the Nation’s physical measure- ment system, (2) scientific and technological services for industry and government, (3) a technical basis for equity in trade, and (4) technical services to promote public safety. The Bureau consists of the Institute for Basic Standards, the Institute for Materials Research, the Institute for Applied Technology, the Center for Computer Sciences and Technology, and the Office for Information Programs. THE INSTITUTE FOR BASIC STANDARDS provides the central basis within the United States of a complete and consistent system of physical measurement; coordinates that system with measurement systems of other nations; and furnishes essential services leading to accurate and uniform physical measurements throughout the Nation’s scien- tific community, industry, and commerce. The Institute consists of a Center for Radia- tion Research, an Office of Measurement Services and the following divisions: Applied Mathematics—Electricity—Heat—Mechanics—Optical Physics—Linac Radiation 2—Nuclear Radiation 2—Applied Radiation 2—Quantum Electronics 3— Electromagnetics 3—Time and Frequency 3—Laboratory Astrophysics 3—Cryo- 3 genics .
    [Show full text]
  • Report | CAMEO Chemicals | NOAA
    Report | CAMEO Chemicals | NOAA http://cameochemicals.noaa.gov/report?key=CH2013 Print Chemical Datasheet 0 HYDROFLUORIC ACID 4 1 Chemical Identifiers UN/NA Number CAS Number CHRIS Code DOT Hazard Label 1790 7664-39-3 HFA CORROSIVE POISON NFPA 704: Red 0 -- Flammability: Will not burn Blue 4 -- Health Hazard: Too dangerous to enter - vapor or liquid Yellow 1 -- Reactivity: Unstable if heated - use normal precautions General Description A colorless fuming mobile aqueous solution with a pungent odor. Density 9.6 lb / gal. Corrosive to metals and tissue. Highly toxic by ingestion and inhalation. Exposure to fumes or very short contact with liquid may cause severe painful burns; penetrates skin to cause deep-seated ulceration that may lead to gangrene. Hazards Reactivity Alerts 1 of 8 7/15/09 12:07 AM Report | CAMEO Chemicals | NOAA http://cameochemicals.noaa.gov/report?key=CH2013 Water-Reactive Air-Reactive Air & Water Reactions Fumes in air. Fumes are highly irritating, corrosive, and poisonous. Generates much heat on dissolution [Merck, 11th ed., 1989]. Heat can cause spattering, fuming, etc. Fire Hazard Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water. (ERG, 2008) Health Hazard TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death.
    [Show full text]