Naming Molecular Compounds General Instructions: Please Do the Activities for Each Day As Indicated
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Transport of Dangerous Goods
ST/SG/AC.10/1/Rev.16 (Vol.I) Recommendations on the TRANSPORT OF DANGEROUS GOODS Model Regulations Volume I Sixteenth revised edition UNITED NATIONS New York and Geneva, 2009 NOTE The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the Secretariat of the United Nations concerning the legal status of any country, territory, city or area, or of its authorities, or concerning the delimitation of its frontiers or boundaries. ST/SG/AC.10/1/Rev.16 (Vol.I) Copyright © United Nations, 2009 All rights reserved. No part of this publication may, for sales purposes, be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, electrostatic, magnetic tape, mechanical, photocopying or otherwise, without prior permission in writing from the United Nations. UNITED NATIONS Sales No. E.09.VIII.2 ISBN 978-92-1-139136-7 (complete set of two volumes) ISSN 1014-5753 Volumes I and II not to be sold separately FOREWORD The Recommendations on the Transport of Dangerous Goods are addressed to governments and to the international organizations concerned with safety in the transport of dangerous goods. The first version, prepared by the United Nations Economic and Social Council's Committee of Experts on the Transport of Dangerous Goods, was published in 1956 (ST/ECA/43-E/CN.2/170). In response to developments in technology and the changing needs of users, they have been regularly amended and updated at succeeding sessions of the Committee of Experts pursuant to Resolution 645 G (XXIII) of 26 April 1957 of the Economic and Social Council and subsequent resolutions. -
Immediately Dangerous to Life Or Health (Idlh) Value Profile for Chlorine Pentafluoride [Cas No. 13637-63-3] and Bromine Pentafl
External Review Draft March 2015 1 2 3 4 5 6 7 IMMEDIATELY DANGEROUS TO LIFE OR HEALTH (IDLH) VALUE PROFILE 8 9 10 11 FOR 12 13 14 15 CHLORINE PENTAFLUORIDE [CAS NO. 13637-63-3] 16 17 AND 18 19 BROMINE PENTAFLUORIDE [CAS NO. 7789-30-2] 20 21 22 23 24 25 26 Department of Health and Human Services 27 Centers for Disease Control and Prevention 28 National Institute for Occupational Safety and Health This information is distributed solely for the purpose of pre-dissemination peer review under applicable information quality guidelines. It has not been formally disseminated by the National Institute for Occupational Safety and Health. It does not represent and should not be construed to represent any agency determination or policy. i External Review Draft March 2015 1 DISCLAIMER 2 Mention of any company or product does not constitute endorsement by the National Institute for Occupational 3 Safety and Health (NIOSH). In addition, citations of Web sites external to NIOSH do not constitute NIOSH 4 endorsement of the sponsoring organizations or their programs or products. Furthermore, NIOSH is not 5 responsible for the content of these Web sites. 6 7 ORDERING INFORMATION 8 This document is in the public domain and may be freely copied or reprinted. To receive NIOSH documents or 9 other information about occupational safety and health topics, contact NIOSH at 10 Telephone: 1-800-CDC-INFO (1-800-232-4636) 11 TTY: 1-888-232-6348 12 E-mail: [email protected] 13 14 or visit the NIOSH Web site at www.cdc.gov/niosh. -
(VI) and Chromium (V) Oxide Fluorides
Portland State University PDXScholar Dissertations and Theses Dissertations and Theses 1976 The chemistry of chromium (VI) and chromium (V) oxide fluorides Patrick Jay Green Portland State University Follow this and additional works at: https://pdxscholar.library.pdx.edu/open_access_etds Part of the Chemistry Commons Let us know how access to this document benefits ou.y Recommended Citation Green, Patrick Jay, "The chemistry of chromium (VI) and chromium (V) oxide fluorides" (1976). Dissertations and Theses. Paper 4039. https://doi.org/10.15760/etd.5923 This Thesis is brought to you for free and open access. It has been accepted for inclusion in Dissertations and Theses by an authorized administrator of PDXScholar. Please contact us if we can make this document more accessible: [email protected]. All ABSTRACT OF THE TllESIS OF Patrick Jay Green for the Master of Science in Chemistry presented April 16, 1976. Title: Chemistry of Chromium(VI) and Chromium(V) Oxide Fluorides. APPROVEO BY MEMBERS OF THE THESIS CO'"o\l TIEE: y . • Ii . ' I : • • • • • New preparative routes to chromyl fluoride were sought. It was found that chlorine ironofluoride reacts with chromium trioxide and chromyl chlo ride to produce chromyl fluoride. Attempts were ~ade to define a mechan ism for the reaction of ClF and Cr0 in light of by-products observed 3 and previous investigations. Carbonyl fluoride and chromium trioxide react to fom chro·yl fluoride and carbo:i dioxide. A mechanism was also proposed for this react10n. Chromium trioxide 11itl\ l~F6 or WF5 reacts to produce chromyl fluoride and the respective oxide tetrafluoride. 2 Sulfur hexafluoride did not react with Cr03. -
Assessment of Portable HAZMAT Sensors for First Responders
The author(s) shown below used Federal funds provided by the U.S. Department of Justice and prepared the following final report: Document Title: Assessment of Portable HAZMAT Sensors for First Responders Author(s): Chad Huffman, Ph.D., Lars Ericson, Ph.D. Document No.: 246708 Date Received: May 2014 Award Number: 2010-IJ-CX-K024 This report has not been published by the U.S. Department of Justice. To provide better customer service, NCJRS has made this Federally- funded grant report available electronically. Opinions or points of view expressed are those of the author(s) and do not necessarily reflect the official position or policies of the U.S. Department of Justice. Assessment of Portable HAZMAT Sensors for First Responders DOJ Office of Justice Programs National Institute of Justice Sensor, Surveillance, and Biometric Technologies (SSBT) Center of Excellence (CoE) March 1, 2012 Submitted by ManTech Advanced Systems International 1000 Technology Drive, Suite 3310 Fairmont, West Virginia 26554 Telephone: (304) 368-4120 Fax: (304) 366-8096 Dr. Chad Huffman, Senior Scientist Dr. Lars Ericson, Director UNCLASSIFIED This project was supported by Award No. 2010-IJ-CX-K024, awarded by the National Institute of Justice, Office of Justice Programs, U.S. Department of Justice. The opinions, findings, and conclusions or recommendations expressed in this publication are those of the author(s) and do not necessarily reflect those of the Department of Justice. This document is a research report submitted to the U.S. Department of Justice. This report has not been published by the Department. Opinions or points of view expressed are those of the author(s) and do not necessarily reflect the official position or policies of the U.S. -
Polymorphism, Halogen Bonding, and Chalcogen Bonding in the Diiodine Adducts of 1,3- and 1,4-Dithiane
molecules Article Polymorphism, Halogen Bonding, and Chalcogen Bonding in the Diiodine Adducts of 1,3- and 1,4-Dithiane Andrew J. Peloquin 1, Srikar Alapati 2, Colin D. McMillen 1, Timothy W. Hanks 2 and William T. Pennington 1,* 1 Department of Chemistry, Clemson University, Clemson, SC 29634, USA; [email protected] (A.J.P.); [email protected] (C.D.M.) 2 Department of Chemistry, Furman University, Greenville, SC 29613, USA; [email protected] (S.A.); [email protected] (T.W.H.) * Correspondence: [email protected] Abstract: Through variations in reaction solvent and stoichiometry, a series of S-diiodine adducts of 1,3- and 1,4-dithiane were isolated by direct reaction of the dithianes with molecular diiodine in solution. In the case of 1,3-dithiane, variations in reaction solvent yielded both the equatorial and the axial isomers of S-diiodo-1,3-dithiane, and their solution thermodynamics were further studied via DFT. Additionally, S,S’-bis(diiodo)-1,3-dithiane was also isolated. The 1:1 cocrystal, (1,4-dithiane)·(I2) was further isolated, as well as a new polymorph of S,S’-bis(diiodo)-1,4-dithiane. Each structure showed significant S···I halogen and chalcogen bonding interactions. Further, the product of the diiodine-promoted oxidative addition of acetone to 1,4-dithiane, as well as two new cocrystals of 1,4-dithiane-1,4-dioxide involving hydronium, bromide, and tribromide ions, was isolated. Keywords: crystal engineering; chalcogen bonding; halogen bonding; polymorphism; X-ray diffraction Citation: Peloquin, A.J.; Alapati, S.; McMillen, C.D.; Hanks, T.W.; Pennington, W.T. -
Chemical Name Federal P Code CAS Registry Number Acutely
Acutely / Extremely Hazardous Waste List Federal P CAS Registry Acutely / Extremely Chemical Name Code Number Hazardous 4,7-Methano-1H-indene, 1,4,5,6,7,8,8-heptachloro-3a,4,7,7a-tetrahydro- P059 76-44-8 Acutely Hazardous 6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10- hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide P050 115-29-7 Acutely Hazardous Methanimidamide, N,N-dimethyl-N'-[2-methyl-4-[[(methylamino)carbonyl]oxy]phenyl]- P197 17702-57-7 Acutely Hazardous 1-(o-Chlorophenyl)thiourea P026 5344-82-1 Acutely Hazardous 1-(o-Chlorophenyl)thiourea 5344-82-1 Extremely Hazardous 1,1,1-Trichloro-2, -bis(p-methoxyphenyl)ethane Extremely Hazardous 1,1a,2,2,3,3a,4,5,5,5a,5b,6-Dodecachlorooctahydro-1,3,4-metheno-1H-cyclobuta (cd) pentalene, Dechlorane Extremely Hazardous 1,1a,3,3a,4,5,5,5a,5b,6-Decachloro--octahydro-1,2,4-metheno-2H-cyclobuta (cd) pentalen-2- one, chlorecone Extremely Hazardous 1,1-Dimethylhydrazine 57-14-7 Extremely Hazardous 1,2,3,4,10,10-Hexachloro-6,7-epoxy-1,4,4,4a,5,6,7,8,8a-octahydro-1,4-endo-endo-5,8- dimethanonaph-thalene Extremely Hazardous 1,2,3-Propanetriol, trinitrate P081 55-63-0 Acutely Hazardous 1,2,3-Propanetriol, trinitrate 55-63-0 Extremely Hazardous 1,2,4,5,6,7,8,8-Octachloro-4,7-methano-3a,4,7,7a-tetra- hydro- indane Extremely Hazardous 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]- 51-43-4 Extremely Hazardous 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]-, P042 51-43-4 Acutely Hazardous 1,2-Dibromo-3-chloropropane 96-12-8 Extremely Hazardous 1,2-Propylenimine P067 75-55-8 Acutely Hazardous 1,2-Propylenimine 75-55-8 Extremely Hazardous 1,3,4,5,6,7,8,8-Octachloro-1,3,3a,4,7,7a-hexahydro-4,7-methanoisobenzofuran Extremely Hazardous 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime 26419-73-8 Extremely Hazardous 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime. -
WO 2016/074683 Al 19 May 2016 (19.05.2016) W P O P C T
(12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (10) International Publication Number (43) International Publication Date WO 2016/074683 Al 19 May 2016 (19.05.2016) W P O P C T (51) International Patent Classification: (81) Designated States (unless otherwise indicated, for every C12N 15/10 (2006.01) kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, (21) International Application Number: BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, PCT/DK20 15/050343 DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, (22) International Filing Date: HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KN, KP, KR, 11 November 2015 ( 11. 1 1.2015) KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, (25) Filing Language: English PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, (26) Publication Language: English SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (30) Priority Data: PA 2014 00655 11 November 2014 ( 11. 1 1.2014) DK (84) Designated States (unless otherwise indicated, for every 62/077,933 11 November 2014 ( 11. 11.2014) US kind of regional protection available): ARIPO (BW, GH, 62/202,3 18 7 August 2015 (07.08.2015) US GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, (71) Applicant: LUNDORF PEDERSEN MATERIALS APS TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, [DK/DK]; Nordvej 16 B, Himmelev, DK-4000 Roskilde DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, (DK). -
Health-Based Reassessment of Administrative Occupational Exposure Limits
Gezondheidsraad Voorzitter Health Council of the Netherlands Aan de Staatssecretaris van Sociale Zaken en Werkgelegenheid Onderwerp : Aanbieding adviezen herevaluatie bestuurlijke MAC-waarden Uw kenmerk : ARBO/AMIL/97/00648 Ons kenmerk : U 2204/CB/mj/563-B5 Bijlagen : 1 Datum : 13 november 2001 Mijnheer de staatssecretaris, Op verzoek van uw ambtsvoorganger bied ik u hierbij 12 adviezen aan van een reeks over de gezondheidskundige basis van uit het buitenland overgenomen grenswaarden voor beroepsmatige blootstelling aan stoffen. Het verzoek om deze adviezen is in algemene zin vervat in brief nr ARBO/AMIL/97/00648 en in latere stadia door uw departement toegespitst op afzonderlijke stoffen. De adviezen zijn opgesteld door een daartoe door mij geformeerde internationale commissie van de Gezondheidsraad en beoordeeld door de Beraadsgroep Gezondheid en Omgeving. De beoogde reeks van in het Engels gestelde adviezen zal losbladig worden gepubliceerd onder ons publicatienummer 2000/15OSH en, conform de aan de Gezondheidsraad voorgelegde toespitsingen van de adviesaanvraag, betrekking hebben op 168 stoffen. Het u thans aangeboden tweede pakket bestaat uit de adviezen genummerd 2000/15OSH/018 tot en met 2000/15OSH/029, respectievelijk betrekking hebbend op: bornanon-2 (kamfer, synthetisch), chloortrifluoride, o-chloorstyreen, cyclohexylamine, dizwaveldecafluoride, hexafluoroaceton, keteen, pentachloornaftaleen, perchlorylfluoride, m-ftalodinitril, thionylchloride en trichloornaftaleen. Bij afronding van de werkzaamheden van de hierboven bedoelde -
Pp-03-25-New Dots.Qxd 10/23/02 2:16 PM Page 136
pp-03-25-new dots.qxd 10/23/02 2:16 PM Page 136 136 BROMIC ACID / BROMINE BROMIC ACID [7789–31–3] Formula: HBrO3; MW 128.91 Uses Bromic acid is used as an oxidizing agent; and also as intermediate in the preparation of dyes and pharmaceuticals . Physical Properties Unstable compound; stable only in dilute aqueous solutions; solution turns yellow on standing; decomposes when heated to 100°C. Preparation Bromic acid is prepared by adding sulfuric acid to barium bromate. Ba(BrO3)2 + H2SO4 → 2HBrO3 + BaSO4 The product is distilled and absorbed in water. A 50% solution may be obtained by slow evaporation of the dilute solution in vacuum at –12°C. Toxicity Contact with skin and eyes can cause severe irritation. BROMINE [7726–95–6] Symbol Br; atomic number 35; atomic weight 79.904; a halogen group ele- ment; electron affinity 3.36359 eV; electronegativity 2.8; electron configura- tion [Ar] 3d104s24p5; most stable valence states –1 and +5, less stable valence states +1 and +3; a diatomic molecule (Br2) in liquid and vapor states over a wide range of temperature; two stable isotopes, Br–79 (50.57%) and Br–81 (49.43%). Occurrence and Uses Bromine occurs in nature as bromide in many natural brine wells and salt deposits. It also is found in seawater at a concentration of 85 mg/L. The ele- ment was discovered by A. J. Balard and C. Lowig, independently in 1826. Bromine is used in bleaching fibers and as a disinfectant for water purifica- tion. Other applications are in organic synthesis as an oxidizing or brominat- ing agent; in the manufacture of ethylene dibromide, methyl bromide and other bromo compounds for dyes and pharmaceutical uses; as a fire retardant for plastics; and in chemical analysis. -
The Synthesis and Characterization of Novel Pentafluorosulfanyl-Containing Heterocycles and Pentafluorosulfanyldifluoromethane
Clemson University TigerPrints All Dissertations Dissertations May 2019 The yS nthesis and Characterization of Novel Pentafluorosulfanyl-Containing Heterocycles and Pentafluorosulfanyldifluoromethane Steven Paul Belina Clemson University, [email protected] Follow this and additional works at: https://tigerprints.clemson.edu/all_dissertations Recommended Citation Belina, Steven Paul, "The yS nthesis and Characterization of Novel Pentafluorosulfanyl-Containing Heterocycles and Pentafluorosulfanyldifluoromethane" (2019). All Dissertations. 2373. https://tigerprints.clemson.edu/all_dissertations/2373 This Dissertation is brought to you for free and open access by the Dissertations at TigerPrints. It has been accepted for inclusion in All Dissertations by an authorized administrator of TigerPrints. For more information, please contact [email protected]. THE SYNTHESIS AND CHARACTERIZATION OF NOVEL PENTAFLUOROSULFANYL-CONTAINING HETEROCYCLES AND PENTAFLUOROSULFANYLDIFLUOROMETHANE A Dissertation Presented to the Graduate School of Clemson University In Partial Fulfillment of the Requirements for the Degree Doctor of Philosophy Chemistry by Steven Paul Belina May 2019 Accepted by Joseph S. Thrasher, Ph.D., Committee Chair Julia L. Brumaghim, Ph.D. R. Karl Dieter, Ph.D. Joseph W. Kolis, Ph.D. Title Page ABSTRACT Beginning in the early 1960s, scientists began to experiment with the pentafluorosulfanyl moiety. The unique properties of the functional group has attracted interest among fluorine chemists and more recently even organic chemists. These properties include high group electronegativity, high steric bulk, high lipophilicity, a highly electron withdrawing nature, and a square pyramidal geometry. However, the development and deployment of the pentafluorosulfanyl functional group has been significantly slowed. The main cause for the slow development is a lack of easily available reagents to synthesize pentafluorosulfanyl-containing compounds. Historically, the primary reagents used for synthesizing pentafluorosulfanyl-containing compounds were SF5Cl and SF5Br. -
Unit 8: CHEMICAL NAMES and FORMULAS
Unit 8: CHEMICAL NAMES AND FORMULAS Name _________________________________________________________________ Date __________________________ Mod ____________ Exam __________________________ Across 28. These have various oxidation numbers 1. These have a 1+ oxidation number 29. The name for the compound of calcium and oxygen 3. Every compound always contains the same elements in the same proportions. Down 6. The type of compound containing only two elements 2. The number that tells how many atoms of an element are in a 7. Compounds form so that atoms can satisfy what rule? unit of the compound 8. ammonium chloride 4. A compound containing more than 2 different elements 10. The formula for chromium (III) and oxygen 5. A covalent bond wherein the electrons are shared equally 18. Name P4O10 among elements 19. silver oxide 6. The name for a compound of barium and hydroxide 20. A covalent bond wherein the electrons are not shared equally 9. These have a 1- oxidation number 21. The formula for beryllium and iodine 11. Nickel (I) carbonate 22. NH4OH 12. Name As2O5 23. A chemical combination of two or more elements having 13. The group which does not have oxidation numbers. different properties than the individual elements 14. Nona is the prefix for ___ in a covalent bond 24. Name Na2S 15. The prefix for 7 in a covalent bond 25. A single atom with a charge 16. The formula for calcium and oxygen 26. The prefix for 4 in a covalent bond 17. The ion ClO3- 27. The positive/negative number assigned to an element that shows its ability to combine in a compound Also for the exam: Be able to draw electron dot diagrams for various ionic bonds (brackets) and covalent bonds (dots). -
The WMS Model
Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is © the Owner Societies 2018 S-1 ELECTRONIC SUPPLEMENTARY INFORMATION OCT. 8, 2018 Extrapolation of High-Order Correlation Energies: The WMS Model Yan Zhao,a Lixue Xia,a Xiaobin Liao,a Qiu He,a Maria X. Zhao,b and Donald G. Truhlarc aState Key Laboratory of Silicate Materials for Architectures,International School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, People’s Republic of China. bLynbrook High School, 1280 Johnson Avenue, San Jose, California 95129 cDepartment of Chemistry and Supercomputing Institute, University of Minnesota, 207 Pleasant Street S.E., Minneapolis, MN 55455-0431 TABLE OF CONTENTS Table S1: Calculated classical barrier heights (kcal/mol) for the DBH24-W4 database S-2 Table S2: RMSE of the scalar relativistic contribution in WMS (kcal/mol) S-3 Table S3: RMSE of the composite methods for the W4-17 database (kcal/mol) S-4 Table S4: Calculated Born-Oppenheimer atomization energy (kcal/mol) for the W4-17 database S-5 Table S5: Example input file for a WMS calculation: the H2O molecule S-11 Table S6: Example input file for a WMS calculation: the CH3 radical S-12 Table S7. perl scripts for performing WMS calculations S-13 S-2 Table S1: Calculated classical barrier heights (kcal/mol) for the DBH24-W4 database (The ZPE contributions are excluded.) Reactions Best Est. WMS Hydrogen Atom Transfers ! ∆E! 6.35 6.25 OH + CH4 → CH3 + H2O ! ∆E! 19.26 19.28 ! ∆E! 10.77 10.88 H + OH → O + H2 ! ∆E! 13.17