Pulp Mill Optimization No Longer Pulp Fiction
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Making! the E-Magazine for the Fibrous Forest Products Sector
PAPERmaking! The e-magazine for the Fibrous Forest Products Sector Produced by: The Paper Industry Technical Association Volume 5 / Number 1 / 2019 PAPERmaking! FROM THE PUBLISHERS OF PAPER TECHNOLOGY Volume 5, Number 1, 2019 CONTENTS: FEATURE ARTICLES: 1. Wastewater: Modelling control of an anaerobic reactor 2. Biobleaching: Enzyme bleaching of wood pulp 3. Novel Coatings: Using solutions of cellulose for coating purposes 4. Warehouse Design: Optimising design by using Augmented Reality technology 5. Analysis: Flow cytometry for analysis of polyelectrolyte complexes 6. Wood Panel: Explosion severity caused by wood dust 7. Agriwaste: Soda-AQ pulping of agriwaste in Sudan 8. New Ideas: 5 tips to help nurture new ideas 9. Driving: Driving in wet weather - problems caused by Spring showers 10. Women and Leadership: Importance of mentoring and sponsoring to leaders 11. Networking: 8 networking skills required by professionals 12. Time Management: 101 tips to boost everyday productivity 13. Report Writing: An introduction to report writing skills SUPPLIERS NEWS SECTION: Products & Services: Section 1 – PITA Corporate Members: ABB / ARCHROMA / JARSHIRE / VALMET Section 2 – Other Suppliers Materials Handling / Safety / Testing & Analysis / Miscellaneous DATA COMPILATION: Installations: Overview of equipment orders and installations since November 2018 Research Articles: Recent peer-reviewed articles from the technical paper press Technical Abstracts: Recent peer-reviewed articles from the general scientific press Events: Information on forthcoming national and international events and courses The Paper Industry Technical Association (PITA) is an independent organisation which operates for the general benefit of its members – both individual and corporate – dedicated to promoting and improving the technical and scientific knowledge of those working in the UK pulp and paper industry. -
Extended Impregnation Kraft Cooking of Softwood: Effects on Reject, Yield, Pulping Uniformity, and Physical Properties
Extended Impregnation Kraft Cooking of Softwood: Effects on reject, yield, pulping uniformity, and physical properties Katarina Karlström Licentiate thesis Royal Institute of Technology (KTH) Department of Fibre and Polymer Technology Division of Wood Chemistry and Pulp Technology Stockholm 2009 TRITA-CHE-Report 2009:59 ISSN 1654-1081 ISBN 978-91-7415-496-2 Extended impregnation kraft cooking of softwood: Effects on reject, yield, pulping uniformity, and physical properties Katarina Karlström AKADEMISK AVHANDLING Som med tillstånd av Kungliga Tekniska Högskolan i Stockholm framlägges till offentlig granskning för avläggande av teknologie licentiatexamen fredagen den 18:e december 2009, kl. 10.00 i STFI-salen, Innventia AB, Drottning Kristinas väg 61, Stockholm. Avhandlingen försvaras på svenska. © Katarina Karlström Stockholm 2009 Department of Fibre and Polymer Technology Teknikringen 56-58 SE-100 44 Stockholm Sweden Abstract Converting wood into paper is a complex process involving many different stages, one of which is pulping. Pulping involves liberating the wood fibres from each other, which can be done either chemically or mechanically. This thesis focuses on the most common chemical pulping method, the kraft cooking process, and especially on a recently developed improvement of the impregnation phase, which is the first part of a kraft cook. Extended impregnation kraft cooking (EIC) technique is demonstrated to be an improvement of the kraft pulping process and provides a way to utilize softwood to a higher degree, at higher pulp yield. We demonstrate that it is possible to produce softwood ( Picea abies ) kraft pulp using a new cooking technique, resulting in a pulp that can be defibrated without inline refining at as high lignin content as 8% on wood, measured as kappa numbers above 90. -
Basics of Kraft Pulping
Lignin Wood is composed of many chemical components, primarily extractives, carbohydrates, and lignin, which are distributed nonuniformly as the result of anatomical structure. Lignin is derived from the Latin term lignum, which means wood.1 Anselme Payen (1838) was the first to recognize the composite nature of wood and referred to a carbon- rich substance as the “encrusting material” which embedded cellulose in the wood. Schulze (1865) later defined this encrusting material as lignin. Lignin has been described as a random, three-dimensional network polymer comprised of variously linked phenylpropane units.2 Lignin is the second most abundant biological material on the planet, exceeded only by cellulose and hemicellulose, and comprises 15-25% of the dry weight of woody plants. This macromolecule plays a vital role in providing mechanical support to bind plant fibers together. Lignin also decreases the permeation of water through the cell walls of the xylem, thereby playing an intricate role in the transport of water and nutrients. Finally, lignin plays an important function in a plant’s natural defense against degradation by impeding penetration of destructive enzymes through the cell wall. Although lignin is necessary to trees, it is undesirable in most chemical papermaking fibers and is removed by pulping and bleaching processes. 1.1.1 Biosynthesis Plant lignins can be broadly divided into three classes: softwood (gymnosperm), hardwood (angiosperm) and grass or annual plant (graminaceous) lignin.3 Three different phenylpropane units, or monolignols, are responsible for lignin biosynthesis.4 Guaiacyl lignin is composed principally of coniferyl alcohol units, while guaiacyl-syringyl lignin contains monomeric units from coniferyl and sinapyl alcohol. -
A Review on the Modeling, Control and Diagnostics of Continuous Pulp Digesters
processes Review A Review on the Modeling, Control and Diagnostics of Continuous Pulp Digesters Moksadur Rahman * , Anders Avelin and Konstantinos Kyprianidis School of Business, Society and Engineering, Mälardalen University, Box 883, 72123 Västerås, Sweden; [email protected] (A.V.); [email protected] (K.K.) * Correspondence: [email protected]; Tel.: +46-(0)21-10-1594 Received: 12 August 2020; Accepted: 23 September 2020; Published: 1 October 2020 Abstract: Being at the heart of modern pulp mills, continuous pulp digesters have attracted much attention from the research community. In this article, a comprehensive review in the area of modeling, control and diagnostics of continuous pulp digesters is conducted. The evolution of research focus within these areas is followed and discussed. Particular effort has been devoted to identifying the state-of-the-art and the research gap in a summarized way. Finally, the current and future research directions in the areas have been analyzed and discussed. To date, digester modeling following the Purdue approach, Kappa number control using model predictive controllers and health index-based diagnostic approaches by utilizing different statistical methods have dominated the field. While the rising research interest within the field is evident, we anticipate further developments in advanced sensors and integration of these sensors for improving model prediction and controller performance; and the exploration of different AI-based approaches will be at the core of future research. Keywords: Kraft pulping; pulp digester; modeling; control; diagnostics 1. Introduction With the widespread expansion of the Internet, electronic media and paperless communication, the demand for the graphic paper (i.e., newsprint and higher-value printing and writing paper) has been declining since 2000 [1]. -
Importance of Unbleached Pulp Lignin Content
ENVIRONMENTAL FOOTPRINT COMPARISON TOOL A tool for understanding environmental decisions related to the pulp and paper industry EFFECTS OF DECREASED RELEASE OF CHLORINATED COMPOUNDS ON ENERGY USE Importance of Unbleached Pulp Lignin Content Kappa number is a measure of the amount of lignin remaining in pulp. The higher the kappa number value, the higher the use of bleaching chemicals required to brighten the pulp. The kappa numbers of pulps leaving the digester are typically about 30 for softwoods and 20 for hardwoods in bleached kraft mills that employ conventional cooking methods. Several modifications to conventional cooking, known collectively as extended cooking (EC), have enabled kappa numbers to be further reduced in the digester in ways that minimize yield and strength losses. Kappa numbers associated with EC are about 20 for softwoods and about 14 for hardwoods. Oxygen delignification (OD) is another technology that is used extensively to lower the residual lignin content prior to the bleach plant. The technology is more selective than most extended cooking processes. Lignin reductions of approximately 50% are achievable with OD, resulting in softwood kappa number in the 14-18 range. Some mills use both extended cooking and oxygen delignification to achieve very low kappa number pulps prior to bleaching, producing pulps with kappa number values in the range of 10-12, perhaps even lower. Deterioration of pulp strength properties is the limiting obstacle for kappa number reduction prior to the bleach plant. More recent strategies have been focused away from obtaining the most delignification possible in the digester and toward optimizing the fiberline as a whole based on economic, quality, and environmental factors. -
American Ft Forest & Paper 2QE5
A 1 , i American Ft Forest & Paper 2QE5; Association , - May 6, 2015 Via Hand Delivery and by Email to iones.iim(a^epa.gov Administrator Gina McCarthy (1101A) Office of the Administrator Environmental Protection Agency 1200 Pennsylvania Avenue, N.W. Washington, DC 20460 Re: Reguest for Full Exemption of Four Pulping Chemicals from the TSCA Chemical Data Reporting Rule Reguirements Dear Administrator McCarthy: The American Forest & Paper Association (AF&PA) hereby petitions EPA to amend the Chemical Data Reporting rule (CDR), 40 C.F.R. Part 711, to exempt from all CDR requirements four pulping chemicals involved in the manufacture of paper and other pulp-based products. The four pulping chemicals are complex mixtures used in the kraft pulping process: • Sulfite Liquors and Cooking Liquors, white (CAS No. 68131-33-9) (white liquor) • Sulfite Liquors and Cooking Liquors, spent (CAS No. 66071-92-9) (black liquor) • Sulfite Liquors and Cooking Liquors, spent, oxidized (CAS No. 68514-09-0) (black liquor, oxidized) • Sulfite Liquors and Cooking Liquors, green (CAS No. 68131-30-6) (green liquor) Each of these substances is manufactured and recycled onsite in a continuous closed loop. EPA has an enormous amount of information about these pulping chemicals and little current interest in them, as their potential risks are well understood and adequately managed. 1101 K Street, N.W., Suite 700 • Was hington, D.C.20005 • (202) 463•2700 •afandpa.org May 6, 2015 Page 2 This petition first identifies the four pulping chemicals in greater detail and explains why the kraft chemical regeneration process has led to inflated production volumes for these pulping chemicals in CDR data. -
A Dynamic Na/S Balance of a Kraft Pulp Mill
A dynamic Na/S balance of a kraft pulp mill Modeling and simulation of a kraft pulp mill using WinGEMS En dynamisk Na/S balans av ett sulfatbruk Modellering och simulering av ett sulfatbruk i WinGEMS Per Andersson Faculty of Health, Science and Technology Department of Engineering and Chemical Science, Chemical Engineering, Karlstad University Master theisis, 30 credits Supervisors: Niklas Kvarnström (KAU), Maria Björk (Stora Enso), Rickard Wadsborn (Stora Enso) Examinat or: Lars Järnström (KAU) 2014 -01-08 Version : 2.0 Abstract The main scope of this thesis was to create a simulation model of a kraft pulp mill and produce a dynamic Na/S balance. The model was made in WinGEMS 5.3 and the method consisted of implementing a static Na/S balance from the mill and created a model that described this chemical balance. Input data from the mill was collected and implemented in the model. A number of different cases were simulated to predict the effects of different process changes over time, dynamic balances. The result from the static balance showed that the model can describes the mill case. The result from the dynamic simulation showed that the model can be used to predict the effect of process changes over shorter periods of time. Executive Summary In the kraft mill the chemical balance is of interest to minimize the production cost. Normally there is an excess of sulfur and low levels of sodium, compared to what the process requires. In the future, the pulp mill will most likely produce other products than just pulp. These new production processes will also most likely affect the sodium and sulfur balance and there is a need to be able to predict this change. -
Paper Recycling Technology Detailed Part 1A
Paper Recycling Technology and Science Dr. Richard A. Venditti Paper Science and Engineering Forest Biomaterials Department North Carolina State University Lecture: Paper recycling and technology course introduction and objectives Dr. Richard Venditti Faculty member in the Paper Science and Engineering Program in the Forest Biomaterials Department at North Carolina State University PhD in Chemical Engineering, BS in Pulp and Paper Science and Chemical Engineering Research areas: � Paper recycling � Utilization of forest/agricultural materials for new applications � Life cycle analysis Named a TAPPI Fellow in 2012 Relevant research projects: – The detection of adhesive contaminants – The changes in fibers upon recycling – Automatic sorting of recovered papers – Flotation deinking surfactants – Agglomeration deinking – Screening phenomena and pressure sensitive adhesives – Deposition of adhesive contaminants – Neural networks to control deinking operations – Sludge conversion to bio-ethanol and to bio- materials Course Outline The US Paper Recycling Industry Recovered Paper Grades and Contaminants Effect of Recycling on Fibers/Paper Unit Operations � Pulping, Cleaning, Screening, Washing, Flotation, Dispersion, Bleaching, ….. Image Analysis, Deinking Chemicals System Design Advanced/Additional Topics Course Activities Viewing of the Videos of Lectures � Base lectures by Venditti � Guest lectures from industry leaders Homework assignments Final Exam Critical Issues in Recycling: Going deeper into the recovered paper stream -
Odorless Pulp Mill in Operation
Published May 26, 2017 Odorless Pulp Mill Odorless pulp mill in successful operation Executive Summary The sulphur in the cooking process can result in bad odor in the surroundings of a Kraft pulp mill. Together with the odor, sulphur compounds can also be an environmental problem since they are released to the atmosphere. Although emissions are becoming lower as mills are upgraded, odors have continued to be a problem for people living close to the mills, because of the very low odor threshold of sulphur compounds. Valmet has delivered a unique, practically odorless mill to CMPC Riograndese Ltda in Guaíba, Brazil. The design guidelines were to not vent odorous gases and to aim for zero smells. The gas handling system collects and controls odors from more than 100 sources and all process areas are included. Incineration of non-condensable gases is ensured through multiple, simultaneously available incineration locations. According to CMPC it can be said that the system availability is practically 100% and there is always a system ready to handle NCG and prevent gases from being emitted to the atmosphere. This paper describes the emphasis CMPC placed in the concept of the odorless mill in Guaíba and its surroundings and outlines the chosen technical solutions to achieve this target. The paper emphasizes the necessity of ensuring that odorous gases are treated also in shutdown and emergency situations, and explains how this has been achieved at the mill. © Valmet Page | 1 Published May 26, 2017 Odorless Pulp Mill Background No venting of odorous gases and a "zero smell" pulp mill. -
Alkaline Pulping: Deadload Reduction Studies in Chemical Recovery System
ALKALINE PULPING: DEADLOAD REDUCTION STUDIES IN CHEMICAL RECOVERY SYSTEM A Thesis Presented To The Academic Faculty By Yusup Chandra In Partial Fulfillments Of the Requirements for the Degree Master of Science in Paper Science Engineering School of Chemical & Biomolecular Engineering Georgia Institute of Technology November 8th, 2004 ALKALINE PULPING: DEADLOAD REDUCTION STUDIES IN CHEMICAL RECOVERY SYSTEM Approved by: Dr. Howard (Jeff) Empie, Advisor Dr. Yulin Deng Dr. Sujit Banerjee Date Approved: November 8th, 2004 ACKNOWLEDGMENT I would like to dedicate this thesis first and foremost to my parents, Azis and Rienni, who have given me all the love and support the years. I would like to thank IPST for this great opportunity to attend this Georgia Tech and to meet all of the wonderful people here. Dr. Empie thanks for introducing me to this new thesis topic and doing a great job. I know it has been difficult through this period of time, but we got through it. Dr. Banerjee and Dr. Deng thank you for taking the time out of your busy schedules. I appreciate all the assistance and advice I have received from everyone on the committee. Lastly, I would like to thank the people that made my stay here in Atlanta an exciting and memorable experience. Special thanks to Luis, Sheila, Daniel, Jacobo, Josh, and Trevor who made getting through the toughest times so much easier. iii TABLE OF CONTENTS Acknowledgment iii Table of Contents iv List of Tables vi List of Figures vii Summary viii Chapter 1 Introduction 1 1.1. Terms and Definitions 2 1.2. -
Construction Health and Safety Manual: Pulp and Paper Mills
PULP AND PAPER MILLS 33 PULP AND PAPER MILLS The two common forms of chemical pulping are 1) the dominant “alkaline” or “kraft” process, and Processes 2) the “acid pulping” or “sulphite” process. Acid pulping has generally declined but is still in use. The A number of processes, grouped by type as mechanical, digester liquor is a solution of sulphurous acid, H SO , chemical, and semi-chemical (or hybrid), are used in 2 3 mixed with lime (CaO) or other base (magnesium, the preparation of wood pulp. In 1990 (according to sodium, or ammonium) to form bisulphites. Lockwood’s Directory) the distribution of pulp mills in Ontario and Quebec was as follows: Mechanical processes produce the highest yield from the wood, but have high energy demands. Mechanical pulping Process Type generally incorporates thermal or chemical pre-softening Chemical Processes Semi-chemical Mechanical Total of the wood chips, resulting in lower energy requirements. Kraft Sulphite Some chemical processes include mechanical features. Ontario 94 2 15 30 The division is not distinct and is generally based on Quebec 10 8241 61 efficiency of production from dry wood. Figure 22.1: Number of pulp mills by type in Ontario and Quebec Figure 22.2 provides a flow diagram for a semi-chemical pulp mill. In chemical pulping, the wood chips are cooked, using heat and a chemical solution that depends on the type of Of the chemical processes , alkaline pulping – the kraft process being used. The lignin binder, a natural glue that or sulphite process – is the most common and is shown in holds the wood cells (fibres) together, is dissolved. -
Fibre to Board
Fibre to board Fibre to board Today’s processes of separating fibre and making paper- compost and road-building material. Using the entire tree board take place in facilities characterised by capital is an important part of our ambition to carry out sustain- intensity, high production volumes and the application of able production. the latest techniques of materials handling, continuous production and process control. From timber to fibre – the pulping process In many cases, including the mills of Iggesund Paper- The timber logs which are delivered to the pulp mill are first board, the production of pulp and the manufacture of debarked, since bark does not contain fibre suitable for paperboard are carried out on the same site in a continu- pulp manufacture. Bark is removed by friction, as logs are ous integrated process, giving benefits in quality, efficiency tumbled together in a rotating drum. The bark is then used and economy. as a fuel within the mill or composted to create garden soil. Managed forests provide the primary source of cellulose The next process depends on the type of separation or fibre from wood varieties such as spruce, pine and birch. defibration process used. The fibre is separated by mechanical or chemical pulp- ing and the whiteness and purity may subsequently be Pulp manufacture improved by bleaching. Basically the choice is between long fibres (spruce and Processing on the paperboard machine starts with the pine) and short fibres (birch). The boardmaker optimises formation of a layer of entangled fibres on a moving wire sheet forming, appearance and performance properties or plastic mesh from which water is removed by drainage.