United States Patent [1,] [11] 3,998,848 > Stapp [45] Dec. 21, 1976

[54] CYCLODIMERIZATION OF ETHYLENE [56] References Cited OXIDE ' UNITED STATES PATENTS

’ Inventor: Paul R. Stapp, Bartlesvine, 3,480,632 11/1969 SchebenMCCIUI'B et...... al...... 260/340.6 .. X [731 Assigneer Phillips Petroleum Company, FOREIGN PATENTS OR APPLICATIONS Bartlesville, Okla. 2,134,016 l/1973 Germany ...... 260/340.6 [22] Fi‘adZ Oct_ 3’ 1975 Primary Examiner-Ethel G. Love - [57] ABSTRACT [21 1, APPI' No-l 619,322 The cyclodimerization of ethylene oxide is carried out ‘ . using elemental iodine as catalyst and a sulfolane as the UsS- CI- ...... diluent to form L4,-dioxane and z-methyl-l,3_dioxo _ 260/601 R lane. . , [51] Int. Cl.2 ...... C07D 319/10 1581 Field of Search ...... 260/340.6, 340.9 5 Claims, No Drawings 3,998,848 l. , 2 The process is carried out for a‘time suf?cient to CYCLODlMERlZATI-ON ETHYLENE OXIDE e?ect the desired degreeof conversion of the ethylene oxide. The reaction time will depend upon the temper This invention relates to a processifor cyclodimeriz ature of reaction and the concentration, of the catalyst ing ethylene oxide. ' in the reaction mixture to effect the desiredv conversion. The cyclodimerizaton of ethylene oxide is well The process of this invention is carried out at any known in the art. For example, ethylene'oxide canm be convenient pressure. Autogenous pressure is usually cyclodimerized to 1,4-dioxane using acidic catalysts. employed. The reaction can also be effected using platinum group Following completion of the reaction period, the metal catalysts such as the platinum-palladium triad 10 reaction mixture can be separated by any convenient catalysts. However, such systems are relatively expen method, vsuch as by fractional distillation. In a batch sive and/or produce relatively low yields of the desired process, the catalyst system, i.e., iodine in sulfolane cyclodimers. The present invention provides a rela remains in the distillation kettle residue and can be tively inexpensive catalyst system for cyclodirnerizing used again for the cyclodimerization of a fresh charge ethylene oxide in good yield. of ethylene oxide. It is an object of this invention1to provide a novel The process of this invention can also be carried out process for cyclodimerizing ethylene oxide. in a continuous manner by passing a mixture of ethyl¢ Other objects, aspects and advantages of this inven ene oxide, iodine and a sulfolane through a suitable tion will be readily apparent to those skilled in the art reaction zone under suitable conditions of temperature from the reading of the following disclosure. 20 and residence time to provide the desired cyclodimeri In accordance with the present invention I have dis zation. The effluent from such a reaction zone can be covered that ethylene oxide can be cyclodimerized in fractionally distilled and the catalyst system recycled to

the presence of elemental iodine and a sulfolane. the reaction zone. . _ . The process of the present inventon generally com ' The cyclodimerization products of the process of this prises reacting ethylene oxide in the presence of a cata 25 invention are l,4-dioxane and 2-methyl-pl,3-dioxolane. lytic amount of elemental iodine in a sulfolane, as here The relative proportions of these dimers can be varied inafter described. The sulfolane is employed as diluent by proper selection of reaction conditions to give a. in an amount ranging from about 5 to about 500 ml per preponderance of one isomer over the other or sub 100 grams of ethylene oxide, preferably from about 25 stantially equal amounts of each dimer, if desired. to about 200 ml per 100 grams of ethylene oxide. The 30 The cyclodimers produced in accordance with the iodine is employed in approximate amounts ranging present invention are well known in the art. They are from 0.1 to 10 grams per liter of diluent, preferably useful as solvents in a variety of applications. They can about 0.5 to 5 grams of iodine per liter of diluent. also be used as monomers in the formation of high The diluent is a sulfolane having from 4 to 7 carbon molecular weight polymers. 1 > atoms per molecule corresponding‘ to the formula 35 The following examples illustrate the invention.‘ . ‘ ‘EXAMPLE 1 A one liter autoclave ‘equipped with stirrertwas‘ charged with 200ml of distilled tetrahydrothiophene» 40 l,l-dioxide, 0.5 grams of iodine crystals, and 159 grams (3.614 moles) of ethylene oxide. ‘The mixture was heated for 6 hours at 225° C while the. pressure decreased from 650 to 200 psig. The autoclave reactor was vented and the reaction mixture transferred,- using O ether to wash the reactor, to a distilling ?ask. The reac tion mixture was then fractionally distilled at atmo spheric pressure to recover three fractions as shown wherein each R is individually selected from the group consisting of hydrogen and alkyl having from 1 to 3 below: carbon atoms. 50 Examples of the diluents which can be employed in Fraction No. Boiling Range, ‘’ C Weight, Grams , the practice of the present invention include: tetrahy 1 ‘ 25-83 ‘ 57.9 ‘ , drothiophene-Ll-dioxide, also known as sulfolane, and 2 . 83-98 92.8 the substituted sulfolanes such as 2-methyl sulfolane, 3 98—l02 10.6 3-methyl sulfolane, 2-ethyl sulfolane, 3-ethyl sulfolane, 55 _2'-propyl sulfolane, 3-propyl sulfolane, 2-isopropyl sul folane, 3-isopropyl sulfolane, 2,2-dimethyl sulfolane, The above described fractions were analyzed by gas ~ 2,3-diniethyl sulfolane, 2,4-dimethyl sulfolane, 2,5 liquid chromatography with the results shown in the ‘ -dimethyl sulfolane, 3,3-dim'ethyl sulfolane, 3,4 following table. ‘dimethyl ‘sulfolane, 2,3,4-trimethyl sulfolane, 2,3,5 60 =trimethyl sulfolane, Z-methyl-S-ethyl sulfolane, and the like and mixtures thereof. Presently preferred diluents Fraction Acetaldehyde, Z-Methyl-l ,S-dioxolane, 1,4-Dioxane ' include ‘unsubstituted sulfolane, 2-methyl sulfolane and No. Grams ' ‘ Gram! Grants 3emethyl sulfolane. The more presently preferred dilu 1 15.07 6.55 2.77 2 2.37 25.60 63.70 ent is unsubstituted sulfolane. 3 1.17 1.34 7.51 The process of this‘invention is carried out at a tem- ‘ Total 18.61 43.49 73.98 perature in the approximate range of 75° to 300° C, preferably in the approximate range of 150° to 250° C. 3,998,848 3 4 The above results show that the percent yield of of l48"—l 52° C at 10 millimeters l-lg pressure. No cy 2methyl-l,3-dioxolane was 27.4 and l,4-dioxane was clodimers of ethylene oxide were observed in the reac 46.5 basedon the starting ethylene oxide. The above tion mixture obtained according to the conditions de results show that good yields of the cyclodimers of the scribed above. The results of this run indicate that ethylene oxide were obtained according to the process tetrahydrothiophene-l,l-dioxide alone was not a suit of the instant invention. able catalyst for the cyclodimerization of ethylene oxide under the conditions employed. EXAMPLE ll Reasonable variations and modi?cations, which will For comparison, a run was conducted using benzene be apparent to those skilled in the art, can be made in in place of the tetrahydrothiophene-l,l-dioxide em this invention without departing from the spirit and ployed in Example I. scope thereof. ' > The one liter autoclave utilized in Example l was What is claimed is: charged with 200 ml of benzene, 0.5 grams of iodine l. A process for the.cyclodimerizaton of ethylene crystals, and 161 grams (3.659 moles) of ethylene oxide which comprises reacting ethylene oxide in the oxide and was heated for six hours at 225° C while the presence of a catalytic amount of a catalyst system pressure decreased from 825 to 800 psig. The reactor consisting of elemental iodine in a sulfolane ‘having was then vented and‘ the product transferred to a sam from 4 to 7 carbon atoms per molecule corresponding ple bottle. The recovered reaction mixture weighed to the formula 358.7 grams. The reaction mixture was analyzed by gas-liquid chromatograhy and showed by the analysis 20 the presence of only ethylene oxide and benzene al though a trace 'of acetaldehyde may have been present. No 1,4-dioxane or 2-methyl‘l,3-dioxolane was de tected in the mixture. The results of this run demon strate that iodine in benzene under the conditions em ployed was'not effective for the cyclodimerization .of ethylene oxide. ‘ I a ' .

‘ EXAMPLE lll _. vFor further ‘comparison ‘a run‘ was conducted follow 30 wherein each R isvindividually selected from the group ing the general procedure of Example l,‘but without the consisting of ‘hydrogen. and alkyl having from 1 to 3, carbon atoms. ‘ r p . iodine' The onecatalyst. liter‘autoclave reactor utilizedv w in‘the‘I above 2.‘Th'e process of claim’ 1 wherein said reaction is described runs was charged with‘ 200' ml‘ of distilled carried out at a temperature in the approximate range tetrahydrothiophene- l , l ‘-dioxide and ‘l 603 grams ’( 3.636 of75‘fto 300°C . ‘ >‘ ' moles) of ethylene oxide. The reaction mixture was 3. The process of claim] wherein the amount of said heated for 6 ‘hours at 225°C while ‘the pressure de sulfolane is in the approximate range of 5 to 500 ml per creased from 700 to 525 psig. The reactor was vented 100g. of said ethylene oxide. ‘ . and the reaction-mixture transferred‘ to ‘a distillation .4. The processof claim 1 wherein the amount of said ?ask andthel ethylene oxide removed by distillation at iodine is in the ‘approximate rangeof 0.1 to 10 grams atmosphericjpressure'.Dnlyethylehe oxide was found per liter of said sulfolane.‘ ‘ ‘ in the distillatehbtained at room temperature.‘ The 5. The process of‘ claim 1 wherein said sulfolane is residue was then ‘distilled further to give 196 ml of tetrahydrothiophene- l , l -dioxide. tetrahydrothiophene-l,l-dioxide with ‘a boiling range ***'

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