DOCSLIB.ORG

Contents 11/29 Molecular Constants

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text

Load more

Contents 11/29 Molecular Constants Subvolume D3 1 General Introduction 1 1.1 General remarks 1 1.2 Review articles and tables 1 1.3 Arrangement of tables, substances and parameters 1 1.4 Error notation 2 1.5 Selection of data 3 1.6 Abbreviations used for experimental methods 3 1.7 Selected fundamental constants and conversion factors 3 1.8 References for 1 5 2 Asymmetric Top Molecules: Introduction 6 2.1 Rotational parameters 6 2.1.1 Defining equations 6 2.1.2 List of tabulated rotational parameters 10 2.1.3 References for 2.1 12 2.2. Hyperfine coupling constants 13 2.2.1 Quadrupole coupling constants, defining equations 13 2.2.2 Magnetic-interaction constants, defining equations 15 2.2.3 List of tabulated asymmetric-top hfs parameters 20 2.2.4 References for 2.2 21 2.3 Internal rotation 23 2.3.1 Defining equations 23 2.3.2 List of tabulated internal-rotation parameters 26 2.3.3 Conversion factors 28 2.3.4 References for 2.3 28 2.4 Symmetric top electric dipole moments 29 2.4.1 References for 2.4 29 2.5 External field magnetic interaction parameters 30 2.5.1 Defining equations 30 2.5.2 List of tabulated asymmetric-top external-magnetic-field parameters 30 2.5.3 References for 2.5 30 3 Data (J. DEMAISON, J. VOGT) 31 581 C6HN 2-(Cyanoethynyl)-2-cyclopropen-l-ylidene 31 582 C6H2 l,2,3-Hexatrien-5-yn-l-ylidene 32 583 C6H2 1,2,3,4,5-Hexapentaenylidene 33 584 C6H2S 1,2,3,4,5-Hexapentaene-l-thione 34 585 C6H3ArF3 1,2,3-Trifluorobenzene-argon (1/1) 35 586 C6H4 (3Z)-3-Hexene-l,5-diyne 36 587 C6H4 l-Hexene-3,5-diyne 38 588 C6H4 l,3-Cydohexadien-5-yne 39 589 C6H4C1F l-Chloro-4-fluorobenzene 41 590 C6H4F2O 2,4-Difluorophenol 42 2 591 C6H4FeO4 Tetracarbonyl(^ -ethene)iron 43 Bibliografische Informationen digitalisiert durch http://d-nb.info/1002961882 VIII Contents 592 C6H4N2 l-Cyclobutene-l,2-dicarbonitrile 45 593 C6H5ArCl Chlorobenzene - argon (1/1) 48 594 C6H5ArF Fluorobenzene - argon (1/1) 49 595 C6H5Br Bromobenzene 50 3 596 C6H5BrFe03 Bromotricarbonyl(// -2-propenyl)iron 53 597 C6H5ClNe Chlorobenzene-neon (1/1) 56 598 C6H5C1O Chlorophenol 57 599 C6H5F Fluorobenzene 58 600 C6H5FNe Fluorobenzene-neon (1/1) 60 601 C6H6BC1 l-Chloro-l//-borepin 61 602 C6H6C1F Fluorobenzene-hydrogen chloride (1/1) 62 603 C6H6FN 4-Fluorobenzenamine 64 604 C6H6O2 1,3-Benzenediol 66 605 C6H7ArN 2-Methylpyridine - argon (1/1) 67 606 C6H7ArN Benzeneamine - argon (1/1) 68 607 C6H7F3O4 Cyclopropylcarboxylic acid - 2,2,2-trifluoroacetic acid (1/1) 69 608 C6H7N 5-Hexynenitrile 70 609 C6H7N Benzenamine 71 610 C6H7N 2-Methylpyridine 72 611 C6H7NNe Benzeneamine-neon (1/1) 75 612 C6H8O 2,5-Dihydrofuran-ethyne(l/l) 77 613 C6H8O Benzene-water (1/1) 79 614 C6H9NO (l£)-2-Cyclohexen-l-oneoxime 81 615 C6H9NO Benzenamine-water (1/1) 82 616 C6H10 1-Hexyne 83 617 C6H,0 3-Hexyne 86 618 C6H10 4-Methyl-l-pentyne 87 619 C6H10F2 frans-1,2-Difluorocyclohexane 88 620 C6H10O 7-Oxabicyclo[4.1.0]heptane 89 621 C6HnClO 7-Oxabicyclo[4.1.0]heptane- hydrogen chloride (1/1) 91 622 C6HUC1O 7-Oxabicyclo[2.2.1]heptane-hydrogen chloride (1/1) 92 623 C6H„FO 7-Oxabicyclo[2.2.1]heptane-hydrogen fluoride (1/1) 94 624 C6HnNO 1-Piperidinecarboxaldehyde 96 625 C6H,,NO Cyclohexanone oxime 97 626 C6HHNO3 N-Acetylalanine methyl ester 99 627 C6HnNO3 N-Acetylglycine ethyl ester 101 628 C6H12 1-Hexene 103 L 629 C6H]2N2O2 2-(Acetylamino)-A methylpropanamide 105 630 C6H12O2 2-Methyloxirane dimer 107 631 C6H12S3 1,4,7-Trithionane 109 632 C6H13NO2 I-Isoleucine 110 633 C6H,4Si 1-Methylsilacyclohexane 111 634 C6H)5O3P Ethylphosphonic acid diethyl ester 113 635 C7F5N 2,3,4,5,6-Pentafluorobenzonitrile 114 636 C7H2 1,2,3,4,5,6-Heptahexaenylidene 115 637 C7H2 2-(l,3-Butadiynyl)-2-cyclopropen-l-ylidene 116 638 C7H2S 1,2,3,4,5,6-Heptahexaene-l-thione 117 639 C7H3F2N 2,3-Difluorobenzonitrile 118 640 C7H3N 6-Heptene-2,4-diynenitrile 119 641 C7H4C1N 3-Chlorobenzonitrile 120 642 C7H4FN 2-Fluorobenzonitrile 122 643 C7H4FNS l-Fluoro-2-isothiocyanatobenzene 123 644 C7H5FO Fluorobenzene-carbon monoxide (1/1) 124 Contents IX 645 C7H5F3O (Trifluoromethoxy)benzene 127 5 646 C7H5O2Rh Dicarbonyl(v -2,4-cyclopentadien-l-yl)rhodium 128 647 C7H6Ar02 2-Hydroxy-2,4,6-cycloheptatrien-l-one-argon (1/1) 129 648 C7H6O Benzaldehyde 130 649 C7H6O2 Benzoic acid 133 650 C7H6O2 2-Hydroxy-2,4,6-cycloheptatrien-l-one 134 651 C7H6O2 1,3-Benzodioxole 138 652 C7H7ArF l-Fluoro-4-methylbenzene - argon (1/1) 139 653 C7H7C1 l-Chloro-2-methylbenzene 140 654 C7H7F l-Fluoro-2-methylbenzene 142 655 C7H7F l-Fluoro-4-methylbenzene 144 656 C7H7F (Fluoromethyl)benzene 146 657 C7H7NO JV-Phenylformamide 147 658 C7H7NO Benzonitrile - water (1/1) 149 659 C7H7NO (£)-Benzaldehyde oxime 152 660 C7H8 Methylbenzene 153 661 C7H8 Bicyclo[2.2.1]hepta-2,5-diene 154 662 C7H8 1,6-Heptadiyne 155 663 C7H8O 2-Methylphenol 156 664 C7H8O 3-Methylphenol 158 665 C7H8O 4-Methylphenol 160 666 C7H8O Benzenemethanol 161 667 C7H8O Methoxybenzene 162 668 C7H9N JV-Methylbenzenamine 165 669 C7H9N Benzenemethanamine 166 670 C7HioO 2-Cyclopropylidenecyclopropanemethanol 168 671 C7H10O2 Methoxybenzene-water (1/1) 169 672 C7H(iN a-Cyclopropylcyclopropanemethanimine 172 673 C7HUNO Benzenamine -methanol (1/1) 173 674 C7H,2 3-Heptyne 174 675 C7Hi2O a-Cyclopropylcyclopropanemethanol 175 676 C7Hi2O 2-Methylcyclohexanone 176 677 C7Hi2O 4-Methylcyclohexanone 177 678 C7H14FO2P Methylphosphonofluoridic acid cyclohexyl ester 178 679 C7HI4O Heptanal 180 680 C7H16FO2P Methylphosphonofluoridic acid 1,2,2-trimethylpropyl ester 183 681 C7H16O2 Heptanal-water(1/1) 184 682 C7H17O3P Methylphosphonic acid bis(l-methylethyl) ester 185 683 CgH2 1,2,3,4,5,6,7-Octaheptaenylidene 186 684 C8H4 l-Octene-3,5,7-triyne 187 685 C8H6 Ethynylbenzene 188 686 C8H6Ar Ethynylbenzene-argon (1/1) 195 5 687 C8H6MoO3 Tricarbonyl(// -2,4-cyclopentadien-l-yl) hydromolybdenum 199 688 C8H6O Benzofuran 201 689 C8H6O2 1,2-Benzenedicarboxaldehyde 204 5 690 C8H6O3W Tricarbonyl(^ -2,4-cyclopentadien-l-yl)hydrotungsten 205 691 C8H6S Benzo[6]thiophene 207 692 C8H7N 2-Methylbenzonitrile 209 693 C8H7N 3-Methylbenzonitrile 210 694 CgH8Fe03 Tricarbonyl[(l,2,3,4->7)-(3£)-l,3-pentadiene]iron 211 695 CgH8Fe03 Tricarbonyl[(l,2,3,4-^)-2-methyl-l,3-butadiene]iron 212 696 C8H8O 1-Phenylethanone 213 697 C8H8O 2,3-Dihydrobenzofiiran 214 X Contents 698 C8H8O2 4-Methoxybenzaldehyde 215 699 CgH8O3 2-Hydroxybenzoic acid methyl ester 217 700 C8H9N 6,7-Dihydro-5#-cyclopenta[Z>]pyridine 218 701 C8H9NO JV-Phenylacetamide 219 702 C8H9NO 1/f-Indole-water (1/1) 220 703 C8H9NO2 a-Aminobenzeneacetic acid 221 704 C8H,0 1,3-Dimethylbenzene 222 705 C8H10 Ethylbenzene 223 706 C8H10O Benzeneethanol 225 707 C8H,,N Benzeneethanamine 227 708 C8H„NO 4-(2-Aminoethyl)phenol 229 709 C8H16 1-Octene 231 710 C8H20O2 2-Butanol dimer 234 711 C9H2 1,2,3,4,5,6,7,8-Nonaoctaenylidene 235 712 C9H2 2-(l,3,5-Hexatriynyl)-2-cyclopropen-l-ylidene 236 713 C9H7Mn03 Tricarbonyl[(l,2,3,4,5-//)-l-methyl-2,4-cyclopentadien-l-yl]manganese . 237 714 C9H7N Quinoline 238 715 C9H7N Isoquinoline 239 716 C9H8 2-Propyn-l-yl-benzene 240 717 C9H8O l,3-Dihydro-27/-inden-2-one 242 718 C9H10 Cyclopropylbenzene 243 719 C9H10FeO3 Tricarbonyl[(2,3,4,5-v)-(2£',4£)-2,4-hexadiene]iron 245 720 C9H,0O a-Methylbenzeneacetaldehyde 246 721 C9HI0O l-Phenyl-2-propanone 247 722 C9H10O 2,3-Dihydro-m-inden-l-ol 248 723 C9H10O 2,3-Dihydro-l#-inden-2-ol 249 724 C9H12 Propylbenzene 250 725 C9H12O a-Methylbenzeneethanol 251 726 C9H12O a-Ethylbenzenemethanol 252 727 C9H,3N (aS)-a-Methylbenzeneethanamine 254 728 C!0H2 1,2,3,4,5,6,7,8,9-Decanonaenylidene 256 729 CioHg Azulene 257 730 C10H8N2 2,4'-Bipyridine 260 731 CioHgO 1-Naphthalenol 261 732 Ci0H9BrFe Bromoferrocene 262 733 Ci0H9ClFe Chloroferrocene 263 734 C10HnNO l//-Indole-3-ethanol 266 735 CioH12N2 l//-Indole-3-ethanamine 267 736 C,oH120 4-Propylbenzaldehyde 268 737 Ci0H,4 Butylbenzene 269 738 CioH15N JV,a-Dimethylbenzeneethanamine 271 739 Ci0H16O l,7,7-Trimethylbicyclo[2.2.1]heptan-2-one 272 740 CnH8Fe03 Tricarbonyl[(l,2,3,4-?/)-l,3,5,7-cyclooctatetraene]iron 275 741 C,iH,0FeO Formylferrocene . 276 742 CMH12Fe Methylferrocene 278 743 Ci2H8 Acenaphthylen 280 744 Ci2H8F4 1,2-Difluorobenzene dimer 281 745 C,2H10 1,2-Dihydroacenaphthylene 282 746 C,2Hi0Fe Ethynylferrocene 283 747 C,2H,0N2 (£)-2-[2-(4-Pyridinyl)ethenyl]pyridine 285 748 Ci2H10O2 [l,l'-Biphenyl]-2,2'-diol 286 749 Ci2H!3N a-Methyl-1-naphthalenemethanamine 287 750 C]2Hl4Fe l,l'-Dimethylferrocene 289 Contents XI 751 C13H9N Phenanthridine 291 752 C13Hl0 9//-Fluorene 292 753 Ci5H9N 9-Anthracenecarbonitrile 293 754 C1FH2O Chlorine fluoride-water (1/1) 294 755 C1FO Chlorosyl fluoride 296 756 C1FO2 Chloryl fluoride 299 757 C1FS Sulfur chloride fluoride 303 758 ClFSi Chlorofluorosilylene 305 759 C1F3 Chlorine trifluoride 306 760 ClGeH Chlorogermylene 308 761 C1HN2O Dinitrogen monoxide -hydrogenchloride (1/1) 310 762 C1HO Hypochlorous acid 314 763 C1HO4 Perchloric acid 318 764 CIHSi Chlorosilylene 319 + 765 C1H2 Chloronium 320 766 C1H2IO Iodine Chloride-water (1/1) 322 767 C1H2IS Iodine chloride-hydrogen sulfide (1/1) 324 768 ClH2NaO Sodium chloride-water (1/1) 326 769 C1H3O Hydrogen chloride-water (1/1) 328 770 ClH4NaO2 Sodium chloride-water (1/2) 331 771 C1H5O2 Hydrogen chloride-water (1/2) 333 772 C1NO3 Chlorine nitrate 337 773 C1OP Phosphenous Chloride 341 774 C1O2P Phosphenic chloride 343 775 C12H2O Dichlorine-water (1/1) 345 776 C12O2 Chloryl chloride 348 777 C12S Sulfur dichloride 352 778 CuHS Copper hydrogen sulfide 355 779 FHN2O Dinitrogen monoxide-hydrogen fluoride (1/1) 356 780 FH3O Hydrogen fluoride-water (1/1) 358 781 FOP Phosphenous fluoride 359 782 FPS Phosphenothious fluoride 362 783 F2H2O Difluorine-water
Recommended publications
  • (VI) and Chromium (V) Oxide Fluorides

    (VI) and Chromium (V) Oxide Fluorides

    Portland State University PDXScholar Dissertations and Theses Dissertations and Theses 1976 The chemistry of chromium (VI) and chromium (V) oxide fluorides Patrick Jay Green Portland State University Follow this and additional works at: https://pdxscholar.library.pdx.edu/open_access_etds Part of the Chemistry Commons Let us know how access to this document benefits ou.y Recommended Citation Green, Patrick Jay, "The chemistry of chromium (VI) and chromium (V) oxide fluorides" (1976). Dissertations and Theses. Paper 4039. https://doi.org/10.15760/etd.5923 This Thesis is brought to you for free and open access. It has been accepted for inclusion in Dissertations and Theses by an authorized administrator of PDXScholar. Please contact us if we can make this document more accessible: [email protected]. All ABSTRACT OF THE TllESIS OF Patrick Jay Green for the Master of Science in Chemistry presented April 16, 1976. Title: Chemistry of Chromium(VI) and Chromium(V) Oxide Fluorides. APPROVEO BY MEMBERS OF THE THESIS CO'"o\l TIEE: y . • Ii . ' I : • • • • • New preparative routes to chromyl fluoride were sought. It was found that chlorine ironofluoride reacts with chromium trioxide and chromyl chlo­ ride to produce chromyl fluoride. Attempts were ~ade to define a mechan­ ism for the reaction of ClF and Cr0 in light of by-products observed 3 and previous investigations. Carbonyl fluoride and chromium trioxide react to fom chro·yl fluoride and carbo:i dioxide. A mechanism was also proposed for this react10n. Chromium trioxide 11itl\ l~F6 or WF5 reacts to produce chromyl fluoride and the respective oxide tetrafluoride. 2 Sulfur hexafluoride did not react with Cr03.
  • Acute Exposure Guideline Levels for Selected Airborne Chemicals: Volume 11

    Acute Exposure Guideline Levels for Selected Airborne Chemicals: Volume 11

    This PDF is available from The National Academies Press at http://www.nap.edu/catalog.php?record_id=13374 Acute Exposure Guideline Levels for Selected Airborne Chemicals: Volume 11 ISBN Committee on Acute Exposure Guideline Levels; Committee on 978-0-309-25481-6 Toxicology; National Research Council 356 pages 6 x 9 PAPERBACK (2012) Visit the National Academies Press online and register for... Instant access to free PDF downloads of titles from the NATIONAL ACADEMY OF SCIENCES NATIONAL ACADEMY OF ENGINEERING INSTITUTE OF MEDICINE NATIONAL RESEARCH COUNCIL 10% off print titles Custom notification of new releases in your field of interest Special offers and discounts Distribution, posting, or copying of this PDF is strictly prohibited without written permission of the National Academies Press. Unless otherwise indicated, all materials in this PDF are copyrighted by the National Academy of Sciences. Request reprint permission for this book Copyright © National Academy of Sciences. All rights reserved. Acute Exposure Guideline Levels for Selected Airborne Chemicals: Volume 11 Committee on Acute Exposure Guideline Levels Committee on Toxicology Board on Environmental Studies and Toxicology Division on Earth and Life Studies Copyright © National Academy of Sciences. All rights reserved. Acute Exposure Guideline Levels for Selected Airborne Chemicals: Volume 11 THE NATIONAL ACADEMIES PRESS 500 FIFTH STREET, NW WASHINGTON, DC 20001 NOTICE: The project that is the subject of this report was approved by the Governing Board of the National Research Council, whose members are drawn from the councils of the National Academy of Sciences, the National Academy of Engineering, and the Insti- tute of Medicine. The members of the committee responsible for the report were chosen for their special competences and with regard for appropriate balance.
  • Chlorine Trifluoride

    Chlorine Trifluoride

    MATERIAL SAFETY DATA SHEET Prepared to U.S. OSHA, CMA, ANSI and Canadian WHMIS Standards 1. PRODUCT IDENTIFICATION CHEMICAL NAME; CLASS: CHLORINE TRIFLUORIDE SYNONYMS: Chlorine Fluoride CHEMICAL FAMILY NAME: Halogen Fluoride FORMULA: ClF3 Document Number: 20026 PRODUCT USE: Use as a fluorinator; for cutting oil-well tubes; reprocessing reactor fuels, as an oxidizer in propellants. SUPPLIER/MANUFACTURER'S NAME: AIR LIQUIDE AMERICA CORPORATION ADDRESS: 2700 Post Oak Drive Houston, TX 77056-8229 EMERGENCY PHONE: CHEMTREC: 1-800-424-9300 BUSINESS PHONE: General MSDS Information 1-713/896-2896 Fax on Demand: 1-800/231-1366 2. COMPOSITION and INFORMATION ON INGREDIENTS CHEMICAL NAME CAS # mole % EXPOSURE LIMITS IN AIR ACGIH OSHA TLV STEL PEL STEL IDLH OTHER ppm ppm ppm ppm ppm Chlorine Trifluoride 7790-91-2 > 99% NE 0.1, C NE 0.1, C 20 NIOSH REL: 0.1 C ppm DFG MAK: 0.1 ppm, C Maximum Impurities < 1% None of the trace impurities in this product contribute significantly to the hazards associated with the product. All hazard information pertinent to this product has been provided in this Material Safety Data Sheet, per the requirements of the OSHA Hazard Communication Standard (29 CFR 1910.1200) and State equivalents standards. NE = Not Established C = Ceiling Limit See Section 16 for Definitions of Terms Used. NOTE: all WHMIS required information is included. It is located in appropriate sections based on the ANSI Z400.1-1993 format. CHLORINE TRIFLUORIDE - ClF3 MSDS EFFECTIVE DATE: JUNE 1, 1998 PAGE 1 OF 9 3. HAZARD IDENTIFICATION EMERGENCY OVERVIEW: Chlorine Trifluoride is an extremely toxic, corrosive, water-reactive, oxidizing, colorless, liquefied gas, with a suffocating, sweet odor.
  • Chemical Chemical Hazard and Compatibility Information

    Chemical Chemical Hazard and Compatibility Information

    Chemical Chemical Hazard and Compatibility Information Acetic Acid HAZARDS & STORAGE: Corrosive and combustible liquid. Serious health hazard. Reacts with oxidizing and alkali materials. Keep above freezing point (62 degrees F) to avoid rupture of carboys and glass containers.. INCOMPATIBILITIES: 2-amino-ethanol, Acetaldehyde, Acetic anhydride, Acids, Alcohol, Amines, 2-Amino-ethanol, Ammonia, Ammonium nitrate, 5-Azidotetrazole, Bases, Bromine pentafluoride, Caustics (strong), Chlorosulfonic acid, Chromic Acid, Chromium trioxide, Chlorine trifluoride, Ethylene imine, Ethylene glycol, Ethylene diamine, Hydrogen cyanide, Hydrogen peroxide, Hydrogen sulfide, Hydroxyl compounds, Ketones, Nitric Acid, Oleum, Oxidizers (strong), P(OCN)3, Perchloric acid, Permanganates, Peroxides, Phenols, Phosphorus isocyanate, Phosphorus trichloride, Potassium hydroxide, Potassium permanganate, Potassium-tert-butoxide, Sodium hydroxide, Sodium peroxide, Sulfuric acid, n-Xylene. Acetone HAZARDS & STORAGE: Store in a cool, dry, well ventilated place. INCOMPATIBILITIES: Acids, Bromine trifluoride, Bromine, Bromoform, Carbon, Chloroform, Chromium oxide, Chromium trioxide, Chromyl chloride, Dioxygen difluoride, Fluorine oxide, Hydrogen peroxide, 2-Methyl-1,2-butadiene, NaOBr, Nitric acid, Nitrosyl chloride, Nitrosyl perchlorate, Nitryl perchlorate, NOCl, Oxidizing materials, Permonosulfuric acid, Peroxomonosulfuric acid, Potassium-tert-butoxide, Sulfur dichloride, Sulfuric acid, thio-Diglycol, Thiotrithiazyl perchlorate, Trichloromelamine, 2,4,6-Trichloro-1,3,5-triazine
  • Chemical Names and CAS Numbers Final

    Chemical Names and CAS Numbers Final

    Chemical Abstract Chemical Formula Chemical Name Service (CAS) Number C3H8O 1‐propanol C4H7BrO2 2‐bromobutyric acid 80‐58‐0 GeH3COOH 2‐germaacetic acid C4H10 2‐methylpropane 75‐28‐5 C3H8O 2‐propanol 67‐63‐0 C6H10O3 4‐acetylbutyric acid 448671 C4H7BrO2 4‐bromobutyric acid 2623‐87‐2 CH3CHO acetaldehyde CH3CONH2 acetamide C8H9NO2 acetaminophen 103‐90‐2 − C2H3O2 acetate ion − CH3COO acetate ion C2H4O2 acetic acid 64‐19‐7 CH3COOH acetic acid (CH3)2CO acetone CH3COCl acetyl chloride C2H2 acetylene 74‐86‐2 HCCH acetylene C9H8O4 acetylsalicylic acid 50‐78‐2 H2C(CH)CN acrylonitrile C3H7NO2 Ala C3H7NO2 alanine 56‐41‐7 NaAlSi3O3 albite AlSb aluminium antimonide 25152‐52‐7 AlAs aluminium arsenide 22831‐42‐1 AlBO2 aluminium borate 61279‐70‐7 AlBO aluminium boron oxide 12041‐48‐4 AlBr3 aluminium bromide 7727‐15‐3 AlBr3•6H2O aluminium bromide hexahydrate 2149397 AlCl4Cs aluminium caesium tetrachloride 17992‐03‐9 AlCl3 aluminium chloride (anhydrous) 7446‐70‐0 AlCl3•6H2O aluminium chloride hexahydrate 7784‐13‐6 AlClO aluminium chloride oxide 13596‐11‐7 AlB2 aluminium diboride 12041‐50‐8 AlF2 aluminium difluoride 13569‐23‐8 AlF2O aluminium difluoride oxide 38344‐66‐0 AlB12 aluminium dodecaboride 12041‐54‐2 Al2F6 aluminium fluoride 17949‐86‐9 AlF3 aluminium fluoride 7784‐18‐1 Al(CHO2)3 aluminium formate 7360‐53‐4 1 of 75 Chemical Abstract Chemical Formula Chemical Name Service (CAS) Number Al(OH)3 aluminium hydroxide 21645‐51‐2 Al2I6 aluminium iodide 18898‐35‐6 AlI3 aluminium iodide 7784‐23‐8 AlBr aluminium monobromide 22359‐97‐3 AlCl aluminium monochloride
  • Tables of Rate Constants for Gas Phase Chemical Reactions of Sulfur Compounds (1971-1980)

    Tables of Rate Constants for Gas Phase Chemical Reactions of Sulfur Compounds (1971-1980)

    A 11 ID 2 1 M t> 3 5 7 All 1021 46357 Weslley, Francis/Tables of rate constant QC100 .U573 V72;1982 C.2 NBS-PUB-C 1982 NSRDS-NBS 72 U.S. DEPARTMENT OF COMMERCE / National Bureau of Standards NATIONAL BUREAU OF STANDARDS The National Bureau of Standards' was established by an act of Congress on March 3, 1901. The Bureau’s overall goal is to strengthen and advance the Nation’s science and technology and facilitate their effective application for public benefit. To this end, the Bureau conducts research and provides: (1) a basis for the Nation’s physical measurement system, (2) scientific and technological services for industry and government, (3) a technical basis for equity in trade, and (4) technical services to promote public safety. The Bureau’s technical work is per- formed by the National Measurement Laboratory, the National Engineering Laboratory, and the Institute for Computer Sciences and Technology. THE NATIONAL MEASUREMENT LABORATORY provides the national system of physical and chemical and materials measurement; coordinates the system with measurement systems of other nations and furnishes essential services leading to accurate and uniform physical and chemical measurement throughout the Nation’s scientific community, industry, and commerce; conducts materials research leading to improved methods of measurement, standards, and data on the properties of materials needed by industry, commerce, educational institutions, and Government; provides advisory and research services to other Government agencies; develops, produces, and
  • Perchloryl Fluoride Final AEGL

    Perchloryl Fluoride Final AEGL

    This PDF is available from The National Academies Press at http://www.nap.edu/catalog.php?record_id=15852 Acute Exposure Guideline Levels for Selected Airborne Chemicals: Volume 13 ISBN Committee on Acute Exposure Guideline Levels; Committee on 978-0-309-29025-8 Toxicology; Board on Environmental Studies and Toxicology; Division on Earth and Life Studies; National Research Council 292 pages 6 x 9 PAPERBACK (2013) Visit the National Academies Press online and register for... Instant access to free PDF downloads of titles from the NATIONAL ACADEMY OF SCIENCES NATIONAL ACADEMY OF ENGINEERING INSTITUTE OF MEDICINE NATIONAL RESEARCH COUNCIL 10% off print titles Custom notification of new releases in your field of interest Special offers and discounts Distribution, posting, or copying of this PDF is strictly prohibited without written permission of the National Academies Press. Unless otherwise indicated, all materials in this PDF are copyrighted by the National Academy of Sciences. Request reprint permission for this book Copyright © National Academy of Sciences. All rights reserved. Acute Exposure Guideline Levels for Selected Airborne Chemicals: Volume 13 Committee on Acute Exposure Guideline Levels Committee on Toxicology Board on Environmental Studies and Toxicology Division on Earth and Life Studies Copyright © National Academy of Sciences. All rights reserved. Acute Exposure Guideline Levels for Selected Airborne Chemicals: Volume 13 THE NATIONAL ACADEMIES PRESS 500 FIFTH STREET, NW WASHINGTON, DC 20001 NOTICE: The project that is the subject of this report was approved by the Governing Board of the National Research Council, whose members are drawn from the councils of the National Academy of Sciences, the National Academy of Engineering, and the Insti- tute of Medicine.
  • An Anthracene-Based Precursor for Sulfur

    An Anthracene-Based Precursor for Sulfur

    An Anthracene-based Precursor for Sulfur Monoxide Delivery: Thermal Release, Spectroscopic Identification and Transfer Reactivity Maximilian Joost, Matthew Nava, Wesley J. Transue, M. A. Martin-Drumel, Michael Mccarthy, David Patterson, Christopher C Cummins To cite this version: Maximilian Joost, Matthew Nava, Wesley J. Transue, M. A. Martin-Drumel, Michael Mccarthy, et al.. An Anthracene-based Precursor for Sulfur Monoxide Delivery: Thermal Release, Spectroscopic Identi- fication and Transfer Reactivity. Proceedings of the National Academy of Sciences of the United States of America , National Academy of Sciences, 2018, 115 (23), pp.5866-5871. 10.1073/pnas.1804035115. hal-02305406 HAL Id: hal-02305406 https://hal.archives-ouvertes.fr/hal-02305406 Submitted on 4 Oct 2019 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. An Anthracene-based Precursor for Sulfur Monoxide Delivery: Thermal Release, Spectroscopic Identification and Transfer Reactivity Maximilian Joosta, Matthew Navaa, Wesley J. Transuea, Marie-Aline Martin-Drumelb, Michael C. McCarthyc,
  • Nitrogen Oxides (Nox), Why and How They Are Controlled

    Nitrogen Oxides (Nox), Why and How They Are Controlled

    United States Office of Air Quality EPA 456/F-99-006R Environmental Protection Planning and Standards November 1999 Agency Research Triangle Park, NC 27711 Air EPA-456/F-99-006R November 1999 Nitrogen Oxides (NOx), Why and How They Are Controlled Prepared by Clean Air Technology Center (MD-12) Information Transfer and Program Integration Division Office of Air Quality Planning and Standards U.S. Environmental Protection Agency Research Triangle Park, North Carolina 27711 DISCLAIMER This report has been reviewed by the Information Transfer and Program Integration Division of the Office of Air Quality Planning and Standards, U.S. Environmental Protection Agency and approved for publication. Approval does not signify that the contents of this report reflect the views and policies of the U.S. Environmental Protection Agency. Mention of trade names or commercial products is not intended to constitute endorsement or recommendation for use. Copies of this report are available form the National Technical Information Service, U.S. Department of Commerce, 5285 Port Royal Road, Springfield, Virginia 22161, telephone number (800) 553-6847. CORRECTION NOTICE This document, EPA-456/F-99-006a, corrects errors found in the original document, EPA-456/F-99-006. These corrections are: Page 8, fourth paragraph: “Destruction or Recovery Efficiency” has been changed to “Destruction or Removal Efficiency;” Page 10, Method 2. Reducing Residence Time: This section has been rewritten to correct for an ambiguity in the original text. Page 20, Table 4. Added Selective Non-Catalytic Reduction (SNCR) to the table and added acronyms for other technologies. Page 29, last paragraph: This paragraph has been rewritten to correct an error in stating the configuration of a typical cogeneration facility.
  • Identification of OSSO As a Near-UV Absorber in The

    Identification of OSSO As a Near-UV Absorber in The

    Geophysical Research Letters RESEARCH LETTER Identification of OSSO as a near-UV absorber 10.1002/2016GL070916 in the Venusian atmosphere Key Points: 1 2 1 • Identification of new sulfur oxides in Benjamin N. Frandsen , Paul O. Wennberg , and Henrik G. Kjaergaard the Venusian atmosphere • Near-UV absorption of OSSO matches 1Department of Chemistry, University of Copenhagen, Copenhagen, Denmark, 2Division of Engineering and Applied missing absorber on Venus Science and Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California, USA • Important sulfur oxide reservoir found below 70 km altitude Abstract The planet Venus exhibits atmospheric absorption in the 320–400 nm wavelength range Supporting Information: produced by unknown chemistry. We investigate electronic transitions in molecules that may exist in the • Supporting Information S1 atmosphere of Venus. We identify two different S O isomers, cis-OSSO and trans-OSSO, which are formed • Table S1 2 2 • Table S2 in significant amounts and are removed predominantly by near-UV photolysis. We estimate the rate of photolysis of cis- and trans-OSSO in the Venusian atmosphere and find that they are good candidates to explain the enigmatic 320–400 nm near-UV absorption. Between 58 and 70 km, the calculated OSSO Correspondence to: H. G. Kjaergaard, concentrations are similar to those of sulfur monoxide (SO), generally thought to be the second most [email protected] abundant sulfur oxide on Venus. Citation: Frandsen, B. N., P. O. Wennberg, and 1. Introduction H. G. Kjaergaard (2016), Identifica- tion of OSSO as a near-UV absorber In 1974, the first spacecraft passed by Venus and took high-resolution spectra of the planet [Dunne, 1974; in the Venusian atmosphere, Geo- Murray et al., 1974].
  • The Chemistry of Solvated Nitric Oxide

    The Chemistry of Solvated Nitric Oxide

    The Chemistry of Solvated Nitric Oxide: As the Free Radical and as Super-saturated Dinitrogen Trioxide Solutions By Kristopher A. Rosadiuk March, 2015 A thesis submitted to McGill University in partial fulfillment of the requirements in the degree of: DOCTORATE OF PHILOSOPHY Department of Chemistry, Faculty of Science McGill University Montreal, Quebec, Canada © Kristopher Rosadiuk, 2015. Abstract The unusual behaviour of the mid-oxidation state nitrogen oxides, nitric oxide (NO) and dinitrogen trioxide (N2O3), are explored in solution. Nitric oxide is shown to catalyze the cis-trans isomerizations of diazo species in aqueous and organic solutions, and a model is presented by which this proceeds by spin catalysis, making use of the unpaired electron of NO to permit access to triplet patways. Five diazo compounds are tested and compared to stilbene, which is not found to isomerize under these conditions. Dinitrogen trioxide is found to form easily in organic solvents, which stabilize the molecule even above room temperature. Solutions can be formed at chemically useful concentrations and levels of purity, and this result is compared with the sparse literature concerning this phenomenon. The chemistry of these solutions at 0˚C is surveyed extensively, with 23 distinct organic reactions and 15 inorganic reactions being described. The first reported room temperature adduct of dinitrogen trioxide is presented, as well as novel syntheses for nitrosyl chloride and nitrosylsulfuric acid. X-ray structures are also given for a previously reported benzoquinone-phenol adduct, as well as a new mixed valent-mercury nitride salt of the form Hg4N4O9. Résumé Le comportement inhabituel des oxydes d'azote aux états d’oxydations moyens, comme l’oxyde nitrique (NO) et le trioxyde dinitrique (N2O3), est exploré en solution.
  • Proposed Adipic Acid Production Protocol

    Proposed Adipic Acid Production Protocol

    ADIPIC ACID PRODUCTION PROJECT PROTOCOL Proposed Protocol October 26, 2019 ClimeCo Corporation One E Philadelphia Ave Boyertown, Pennsylvania 19512 (484) 415-0501 climeco.com Adipic Acid Production Project Protocol Prepared by: Bill Flederbach & James Winch, ClimeCo Corporation Version: 2.0 (Proposed Public Protocol) Version Date: 10/26/2019 This proposed protocol, initially developed by ClimeCo Corporation, is for use by the Climate Action Reserve in the development and evaluation process for a standardized offset project protocol reducing N2O emissions from adipic acid production. Contact Information: Bill Flederbach, Jr. ClimeCo Corporation One E Philadelphia Ave, Boyertown, Pennsylvania 19512 (484) 415-0501 [email protected] Tip Stama ClimeCo Corporation One E Philadelphia Ave, Boyertown, Pennsylvania 19512 (484) 415-0501 [email protected] i Adipic Acid Production Project Protocol Table of Contents 1. Introduction .......................................................................................................................................... 2 2. The GHG Reduction Project .................................................................................................................. 3 2.1. Background ............................................................................................................................... 3 2.2. Project Definition ...................................................................................................................... 4 2.3. The Project Developer .............................................................................................................