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Advances in Organometallic Chemistry EDITED BY ROBERT WEST ANTHONY F. HILL DEPARTMENT OF CHEMISTRY DEPARTMENT OF CHEMISTRY UNIVERSITY OF WISCONSIN IMPERIAL COLLEGE OF SCIENCE, MADISON, WISCONSIN TECHNOLOGY, AND MEDICINE LONDON, ENGLAND FOUNDING EDITOR F. GORDON A. STONE VOLUME 45 Cumulative Subject and Contributor Indexes and Tables of Contents for Volumes 1-44 ACADEMIC PRESS San Diego London Boston New York Sydney Tokyo Toronto This book is printed on acid-Cree paper. @ Copyright 'C 2000 hy ACADEMIC PRESS All Rights Reserved. No part ufthis publication may bc reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopy. recording, or any information storage and retrieval system, without permission in writing from thc Publisher. The appearaiicc ofthe code at the bottom ofthe lirst page of a chaptcr in this book indicates the Publisher's consent that copies of the chapter may he made for personal or internal use of specific clients. This consent is given on the condition, however, that the copier pay the stated per copy fee through the Copyright Clearance Center, Inc. (222 Rosewood Drive, Danvers, Massachusetts 01 923). for copying beyond that permitted by Sections 107 or 108 of the 1J.S. Copyright Law. This consent does not extend to other kinds of copying, such as copying for general distribution, for advertising or promotional purposes, for creating new collective works. or for resale. Copy fees for pre-2000 chapters are as shown on the title pages. Ifno fee code appears on the title page, the copy fee is the same as for current chaptcrs. no~1s-30~5/oo$30.00 Explicit permission from Academic Press is not required to reproduce a maximum of two figures or tables from an Academic Press chapter in another scientific or research publication provided that the material has not been credited to another source and that full credit to the Academic Press chapter is given. Acadcinic Press A Hlirrottrr Science nnd Technology Conrpnny 525 B Street. Suite 1900, San Diego, California 92 I01 -4495. USA littp://www.apiiet.com Academic Press 24-28 Oval Road, London NWI 7DX, UK http://www.hbuk.co.uk/ap/ International Standard Book Number: 0- 12-03 I 145-3 PRINTED IN THE UNITED STATES OF AMERICA 99 0001 02 03 04 MM 9 X 7 6 5 4 3 2 I Subject Index Boldface numerals indicate volume number A Acetylacetonates, redistribution, 6260 Acetylbis( ~5-cyclopentadieny1)hydndomo- Ab initio calculations Iybdenum, 26337 nonlinear optics, 42311 Acetylcarbonyl-~4-cyclopentadiene-~5- silylenium ion intermediate, 30245-246 cyclopen tadienylmolybdenum Ab iniiio studies reactions acyclic A5Si-silicates,44:227 with carbon monoxide, 26:344 spirocyclic zwitterionic A%-silicates with conjugated dienes, 26:345-346 with bidentate Iigands thermal rearrangement, 26:342-344 ethene-1,2-diolato(2-), M237-238 with trimethylphosphite, 26:344-345 naphthalene-2,3-diolato(2-), synthesis, 26337 M232-233 A~etylcarbonyl-~~-cyclopentadienyl-~~- with bidentate ligands benzene-1,2-dio- lato(2-), 44:232-233 dienetungsten complexes diene rotation, 26341-342 Absolute bond energies, definition, 2:108 synthesis, 26:341 Absolute configuration, of chiral metal com- plexes, 18193-195 Acetylcyclopentadienylsodium, tetrahydro- Absolute integrated intensities, v(C0) furan adduct, -224 bands, see Intensities of v(C0) bands Absorption spectroscopy, substituent effects insertion reactions Of, 28:46 in metallocenes, 40933-135 organic synthesis with nickel carbonyl, Abstraction, hydrogen 841-45 intramolecular, by alkyl radical, M81 q’-Acetylene, formation of titanocene mo- reactivity trends, M79 nocarbonyl complexes, 25358-361 Acetaldehyde Acetylene cobalt carbonyls, inhibition of po- from ethylene, 5321-352 lymerization, 6165 from synthesis gas, 37:202 Acetylene complexes, 1455-57 AcetaIs, formation in 0x0 reaction, 6138 catalytic reactions, 14261-265 Acetate complexes, palladium, nonlability activation of acetylene on coordina- of bridging acetates, 13366-367 tion, 14261-262 Acetates, ally], 28120-121 cocyclization with isocyanides, Acetic acid 14263-265 via carbonylation with organonickel com- cyclo-oligomerization, 14262 pounds, 17:233 linear oligomerization, 14:262-263 commercial production, 1R25.5-256 electron-deficient species, 14258-259 Acetohydroximato(2-) bidentate ligand, in Group v metals, lo:% spirocyclic A%-silicates in homogeneous catalysis, 14245-265 NMR studies, M255-256 via insertion reactions, 14251-261 synthesis, a255 geometry of transition state, 14255 Acetonitrile ligand, deprutonation, 18:41 mechanism, 14:253-255 Acetophenone, 26:153 NMR studies, 14251 coupling with Ti-gr, a127 stereochemistry of product, 14251-253 reduction of, 2&102-103 mass spectra, 6291, 301-302 1 Acetylene complexes 2 metalococyclization reactions, 14260-261 metathesis, 16:297 with carbon monoxide, 14260 oxidation to benzils or acyloins, 11:193 with isocyanides, 1k260 oxidative-addition reactions, 265-66 metalocyclization reactions, 14256-260 reactions with formation of metalocycloheptatrienes, organotin hydrides, k62-63, 65 14259-260 thiallium(II1) salts, 1k191-194 formation of metalocyclopentadicnes, transition metal carbynes, 2289-94 14:256-257 Acetylene trimerization, catalysis by alkyli- palladium(O), 13375 dynetricobaltnonacarbonyls, 14137 palladium(II), 13374 Acetylenic alcohol, 3248-49 structure and bonding, 14246-2.51 Acetylferrocene, manganesepentacarbonyl effect of metal oxidation statc, 1521 alkyl reaction, 32205 Huckel calculations, 1520-21 Acetylide dianions, 3249 MO scheme, 14246 Acetylide-metal complexes, third-order, nature of interacting orbitals. nonlinear optics, 43377, 379-382, 14246-247 385-387 twisting of C=C bond, 14.56 Acetylide osmium(I1) complexes, variation of CzC bond length. 1456, 29200-201 247 Acetylides, 37:72 variation of CZC-Cn bond angle, bridging, 3266 14247 Acetylmethylenetriphenylphosphorane de- variation of CEC-H bond angle, rivatives, synthesis of, 28234-235 1520-21 3-Acetyl-l-phosphaferrocene, 39345 substitution reactions, 10:352-355 ~3'-r'.4~s-endo-Acetyl-2,2',3-trihydrobis( 1,I ' - cobalt, 10354 cyclopentadieny1)carbonyl-7'- platinum, 10353 cyclopenta-dienylmolybdenum, 26546 thermal stability and extent of back-bond- Acetyltriphenylgermane, structure, 2117 ing, 14248 Acid-base equilibria, organocobalt com- variation in stretching frequencies of pounds, 1k396-397 metal-acetylene unit, 14248-251 Acid halides, reactions with anionic transi- effect of other ligands, 14250 tion metal hydrides, 2241-43 Acetylcnedicobalt hexacarbonyl, Acidic reactions, acyclic hsSi-silicates, 14138-140 44:227-228 analogy with alkyhdynctricobaltnonacar- Acids, hard and soft, activation of C-H bonyls, 14139-140 bonds by transition metal complexes, Acetylenediolate, disodium salt, 185 15148-149 Acetylene-Fe carbonyl complexes, k37-38, Acids, reactions with transition metal car- 41-42 bynes, 2278-81 Acetylenc hydride. 32122 Acoustic frequency, effect on sonochemis- Acetylene oligomerization, catalysis by sup- try, 25237-88 ported nickel complexes, 15224-226 Acoustic intensity, effect on sonochemistry, Acetylene polymerization, cylopentadienylti- 2588 tanium catalysts, 1944 Acrylonitrile, reaction with digermenes, Acetylenes MI38 cocyclization with butadiene, 12142 Acrylonitrile complexes, 10143-146 formation of metallocycles, 266 Actinides hydrogenation catalyzed by nickel isocya- cyclooctatetraene compounds, 9385-386, nide cluster, 12235. 370 388, 390 hydroplumbation reactions, 228 1 cyclopentadienyls, 9382-39 1 hydrosilation, 12443-445 general chemistry, 9380-382 3 Acyclic pentadienylmetal complexes organic derivatives, 9382-391 in pentadienyllithium and -potassium Activation of C-H bonds by transition complexes, 26128 metal complexes in ~3-pentadienylmetalcomplexes, in alkanes, 15147-185 26141-142 of alkyl groups in polypyrazolylborate cyclization, 26130 compounds, 15157-158 molecular orbitals, 26156-157 in alkyls, 15156-158 orientation by hard and soft acids, 15148-149 in bis(pentadieny1)metal complexes, in ligands, 19149-158 26139 H-D exchange in phosphines, 15149, in cyclopentadienyl(pentadieny1)rho- 154 dium, 26153 orfho-metallation of phosphines, reactions 15149-154 with alkali metals, 26127 Activation parameters with bases, 26127 for carbonyl scrambling with butyllithium, 26127 in ~~-dienechromiumtetracarbonyls, with phenylsodium, 26:127 26304 with potassium amide, 26127 in substituted tricarbonyl(g4-didrene) proton exchange, 26130 chromium complexes, 26307 rearrangements, 26130 in substituted tricarbonyl(v4-diene) structure, 26127-130 tungsten complexes, 26307 bond lengths, 26139 for diene ligand rotation, 26308 bond rotation, 26129-130 for ligand movement, 26320 molecular orbital calculations, 26:129 95 q3 Acyclic (ammonioorgany1)tetrafluorosili- to slippage, 26150 stereoisomerism, 26129 cates, synthesis, M223 Acyclic pentadienylmetal complexes, Acyclic (ammonioorganyl)trifluoro(organyl) 26125-164 silicates, synthesis, 44:223 alkali metal derivatives, preparation, Acyclic diene Fe(C0)3 complexes 26:126-127 cationic configuration, k33 bonding modes, 26125-126 NMR, k12 cross-conjugated dienyltricarbonyliron cat- preparation, k18 ions, 26:148 Acyclic hydrocarbon ligands, a-bonded, of Group I1 and Group I11 elements, Group 4B carbonyl complexes con- 26130-131 taining, 25372-374 reactions with electrophiles, 26:131-134 Acyclic A’Si-silicates structure, 26131 ab inifio studies, M227 synthesis, 26130-131 acidic reaction, 44:227-228 of Group IV elements, reactions with geometry optimizations, a226 electrophiles, 26134-135 NMR studies, M226-227
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    Synthesis, Characterization and Metal Carbonyl Complex Formation of Polycyclic Phosphorus Ligands Arthur Cyril Vandenbroucke Jr

    Iowa State University Capstones, Theses and Retrospective Theses and Dissertations Dissertations 1967 Synthesis, characterization and metal carbonyl complex formation of polycyclic phosphorus ligands Arthur Cyril Vandenbroucke Jr. Iowa State University Follow this and additional works at: https://lib.dr.iastate.edu/rtd Part of the Inorganic Chemistry Commons Recommended Citation Vandenbroucke, Arthur Cyril Jr., "Synthesis, characterization and metal carbonyl complex formation of polycyclic phosphorus ligands " (1967). Retrospective Theses and Dissertations. 3219. https://lib.dr.iastate.edu/rtd/3219 This Dissertation is brought to you for free and open access by the Iowa State University Capstones, Theses and Dissertations at Iowa State University Digital Repository. It has been accepted for inclusion in Retrospective Theses and Dissertations by an authorized administrator of Iowa State University Digital Repository. For more information, please contact [email protected]. This dissertation has been microfihned exactly as received 68-5990 VANDENBROUCKE, Jr., Arthur Cyril, 1941- SYNTHESIS, CHARACTERIZATION AND METAL CARBONYL COMPLEX FORMATION OF POLYCYCLIC PHOSPHORUS LIGANDS. Iowa State University, Ph.D,, 1967 Chemistry, inorganic University Microfilms, Inc., Ann Arbor, Michigan . .SYNTHESISJ CHARACTERIZATION AND METAL CARBONYL COMPLEX FORMATION OF POLYCYCLIC PHOSPHORUS LIGANDS by Arthur Cyril Vandenbroucke, Jr. A -Dissertation Submitted to the Graduate Faculty in Partial Fulfillment of The Requirements for the Degree of DOCTOR OF PHILOSOPHY Major Subject: Inorganic Chemistry • Approved: Signature was redacted for privacy. argë of Major Work Signature was redacted for privacy. Head of Major DepartmentDepart Signature was redacted for privacy. Iowa State University •Of Science and Technology Ames J Iowa 1967 il TABLE OF CONTENTS Pagé I. INTRODUCTION 1 II. A STUDY OF THE SYNTHESIS OF 1-PHOSPHAADAMANTANE 2 A.