Summaries of FY 1997 Research in the Chemical Sciences

Total Page:16

File Type:pdf, Size:1020Kb

Summaries of FY 1997 Research in the Chemical Sciences DOE/NBM-1098 Rev.-1 September 1997 T O EN FE TM N R E A R P G E Y D U • • A N C I I T R E D E M ST A ATES OF Summaries of FY 1997 Research in the Chemical Sciences U.S. Department of Energy Office of Energy Research Division of Chemical Sciences A searchable version of this summary book is available at the following web address: http://websrv.er.doe.gov/asp/search.asp This search tool is also accessible from the Chemical Sciences web page at: http://www.er.doe.gov/production/bes/chm/chmhome.html Available to DOE and DOE contractors from the Office of Scientific and Technical Information, P.O. Box 62, Oak Ridge, TN 37831; prices available from (423) 576-8401 Available to the public from the U.S. Department of Commerce, Technology Administration, National Technical Information Service, Springfield, VA 22161 This document was produced under contract number DE-AC05-76OR00033 between the U.S. Department of Energy and Oak Ridge Associated Universities. ORISE 97-1555 CONTENTS CONTENTS PREFACE ........................................................................ vii Oak Ridge National Laboratory.............................. 42 DIVISION OF CHEMICAL SCIENCES ..................... viii Pacific Northwest National Laboratory .................. 44 PROGRAM DESCRIPTIONS ........................................ ix Heavy Element Chemistry ....................................... 45 LABORATORY ADMINISTRATION ......................... xiii Argonne National Laboratory ................................. 45 Lawrence Berkeley National Laboratory................ 46 NATIONAL LABORATORIES ..................................... 15 Los Alamos National Laboratory............................ 46 Photochemical and Radiation Sciences .................. 15 Oak Ridge National Laboratory.............................. 47 Ames Laboratory .................................................... 15 Stanford Linear Accelerator Center ........................ 48 Argonne National Laboratory ................................. 16 Chemical Engineering Sciences............................... 48 Brookhaven National Laboratory ........................... 17 Ames Laboratory .................................................... 48 Lawrence Berkeley National Laboratory................ 18 Argonne National Laboratory ................................. 49 National Renewable Energy Laboratory ................ 18 Brookhaven National Laboratory ........................... 50 University of Notre Dame ...................................... 20 Lawrence Berkeley National Laboratory................ 50 Chemical Physics ...................................................... 22 Los Alamos National Laboratory............................ 52 Ames Laboratory .................................................... 22 National Renewable Energy Laboratory ................ 53 Argonne National Laboratory ................................. 22 Oak Ridge National Laboratory.............................. 53 Brookhaven National Laboratory ........................... 23 Sandia National Laboratories, California ............... 54 Lawrence Berkeley National Laboratory................ 24 Lawrence Livermore National Laboratory ............. 25 OFFSITE INSTITUTIONS ............................................ 55 Pacific Northwest National Laboratory .................. 25 Photochemical and Radiation Sciences .................. 55 Sandia National Laboratories California ................ 26 The University of Akron ......................................... 55 Atomic, Molecular, and Optical Physics ................ 28 The University of Alabama ..................................... 55 Argonne National Laboratory ................................. 28 Arizona State University......................................... 55 Lawrence Berkeley National Laboratory................ 29 Boston University ................................................... 56 Lawrence Livermore National Laboratory ............. 30 Brandeis University ................................................ 56 Oak Ridge National Laboratory.............................. 30 California Institute of Technology .......................... 56 Chemical Energy ...................................................... 31 University of California, Berkeley ......................... 57 Ames Laboratory .................................................... 31 University of California, San Diego ....................... 57 Argonne National Laboratory ................................. 32 University of Chicago ............................................. 57 Brookhaven National Laboratory ........................... 34 Colorado State University....................................... 58 Lawrence Berkeley National Laboratory................ 34 University of Colorado ........................................... 59 Lawrence Livermore National Laboratory ............. 36 Columbia University ............................................... 59 Los Alamos National Laboratory............................ 36 Dartmouth College.................................................. 60 National Renewable Energy Laboratory ................ 36 Georgia Institute of Technology ............................. 61 Oak Ridge National Laboratory.............................. 37 University of Houston............................................. 61 Pacific Northwest National Laboratory .................. 38 Johns Hopkins University ....................................... 61 Separations and Analysis ......................................... 39 Marquette University .............................................. 62 Ames Laboratory .................................................... 39 University of Massachusetts at Boston ................... 62 Argonne National Laboratory ................................. 40 University of Minnesota ......................................... 62 Brookhaven National Laboratory ........................... 40 National Institute of Standards and Technology, Idaho National Engineering and Environmental ........ Gaithersburg ........................................................ 63 Laboratory ........................................................... 41 North Carolina State University ............................. 63 Lawrence Berkeley National Laboratory................ 41 Research in Chemical Sciences iii CONTENTS University of North Carolina at Chapel Hill........... 64 University of North Carolina at Chapel Hill........... 82 Northwestern University ......................................... 64 North Dakota State University................................ 82 Ohio State University ............................................. 65 University of Oregon .............................................. 83 University of Oklahoma ......................................... 65 The Pennsylvania State University ......................... 83 University of Oregon .............................................. 65 University of Pennsylvania ..................................... 83 The Pennsylvania State University, University of Pittsburgh .......................................... 84 University Park ................................................... 66 Princeton University ............................................... 84 University of Pennsylvania ..................................... 66 Purdue University ................................................... 85 University of Pittsburgh .......................................... 67 Rice University ....................................................... 85 University of Rochester .......................................... 67 University of Rochester .......................................... 86 Rutgers, The State University of New Jersey ......... 68 University of Southern California .......................... 86 Stanford University ................................................. 68 Stanford University................................................. 87 University of Tennessee at Knoxville ..................... 68 State University of New York at Stony Brook........ 87 University of Texas at Arlington ............................. 69 University of Utah .................................................. 87 University of Texas at Austin.................................. 69 University of Virginia ............................................. 88 Tulane University ................................................... 69 University of Wisconsin at Madison....................... 88 Washington State University .................................. 70 Atomic, Molecular, and Optical Physics ................ 89 University of Washington ....................................... 71 California Institute of Technology .......................... 89 Wayne State University .......................................... 71 California State University, Fullerton ..................... 89 Wichita State University ......................................... 71 Clark Atlanta University ......................................... 90 Chemical Physics ...................................................... 72 Colorado State University....................................... 90 University of Akron ................................................ 72 University of Colorado ........................................... 90 Arizona State University......................................... 72 University of Connecticut ....................................... 91 University of Arizona ............................................. 73 Cornell University .................................................. 91 University
Recommended publications
  • Polycyclic Aromatic Hydrocarbon Structure Index
    NIST Special Publication 922 Polycyclic Aromatic Hydrocarbon Structure Index Lane C. Sander and Stephen A. Wise Chemical Science and Technology Laboratory National Institute of Standards and Technology Gaithersburg, MD 20899-0001 December 1997 revised August 2020 U.S. Department of Commerce William M. Daley, Secretary Technology Administration Gary R. Bachula, Acting Under Secretary for Technology National Institute of Standards and Technology Raymond G. Kammer, Director Polycyclic Aromatic Hydrocarbon Structure Index Lane C. Sander and Stephen A. Wise Chemical Science and Technology Laboratory National Institute of Standards and Technology Gaithersburg, MD 20899 This tabulation is presented as an aid in the identification of the chemical structures of polycyclic aromatic hydrocarbons (PAHs). The Structure Index consists of two parts: (1) a cross index of named PAHs listed in alphabetical order, and (2) chemical structures including ring numbering, name(s), Chemical Abstract Service (CAS) Registry numbers, chemical formulas, molecular weights, and length-to-breadth ratios (L/B) and shape descriptors of PAHs listed in order of increasing molecular weight. Where possible, synonyms (including those employing alternate and/or obsolete naming conventions) have been included. Synonyms used in the Structure Index were compiled from a variety of sources including “Polynuclear Aromatic Hydrocarbons Nomenclature Guide,” by Loening, et al. [1], “Analytical Chemistry of Polycyclic Aromatic Compounds,” by Lee et al. [2], “Calculated Molecular Properties of Polycyclic Aromatic Hydrocarbons,” by Hites and Simonsick [3], “Handbook of Polycyclic Hydrocarbons,” by J. R. Dias [4], “The Ring Index,” by Patterson and Capell [5], “CAS 12th Collective Index,” [6] and “Aldrich Structure Index” [7]. In this publication the IUPAC preferred name is shown in large or bold type.
    [Show full text]
  • 1 Vita Peter J. Stang Personal Data
    VITA PETER J. STANG PERSONAL DATA: BORN: November 17, 1941, Nurnberg, Germany CITIZENSHIP: U.S.A. (Naturalized, June, 1962) MARRIED: 1969, Christine M.E. Schirmer CHILDREN: Antonia (b. 1973); B.S. Brown Univ. 1995; M.D. and MBA McGill Univ. 2001 Alexandra (b. 1977); Honors B.S. Univ. of Utah 2000 ADDRESS: 1406 S Chancellor Way, Salt Lake City, Utah 84108 Chemistry Department, 315 S 1400 E, Rm. 2020, University of Utah, Salt Lake City, Utah 84112 PHONE: Office – (801) 581-8329; Home – (801) 581-9749; FAX: Office – (801) 581-8433 EDUCATION B.S. Chemistry, 1963, DePaul University, Chicago, Illinois (Magna Cum Laude) Ph.D., Chemistry, 1966, University of California, Berkeley (NIH Fellow, with A. Streitwieser) Postdoctoral, 1966-68, Princeton University (NIH Fellow, with P.v.R. Schleyer) ACADEMIC EXPERIENCE David P. Gardner Chair of Chemistry, 2014-present Distinguished Professor of Chemistry, University of Utah, 1992-present Dean, College of Science, University of Utah, 1997-2007 Chairperson, Department of Chemistry, University of Utah, 1989-1995 Professor, University of Utah, 1979-1992 Honorary Professor of Chemistry, CAS Institute of Chemistry, Beijing, China Honorary Professor, Zhejiang Univ., East China Normal Univ. and East China Univ. of Science and Technology, Soochow University, Nanjing Normal University, University of Science & Technology of China Senior Fellow, Loker Hydrocarbon Research Inst., U. of Southern Calif. 1991-Present Visiting Scientist, MIT, Cambridge, Mass., 1978 Associate Professor, University of Utah, 1975-79 Assistant Professor, University of Utah, 1969-75 Instructor, Princeton University, 1968-69 RESEARCH INTERESTS Molecular Architecture via Coordination: Formation of discrete supramolecular species with well defined geometries and shapes via self-assembly (molecular triangles, squares, rectangles, pentagons, hexagons, 3D assemblies).
    [Show full text]
  • Catalytic Organic Transformations Mediated by Actinide Complexes
    Inorganics 2015, 3, 392-428; doi:10.3390/inorganics3040392 OPEN ACCESS inorganics ISSN 2304-6740 www.mdpi.com/journal/inorganics Review Catalytic Organic Transformations Mediated by Actinide Complexes Isabell S. R. Karmel, Rami J. Batrice and Moris S. Eisen * Schulich Faculty of Chemistry, Technion—Israel Institute of Technology, Technion City, Haifa 32000, Israel; E-Mails: [email protected] (I.S.R.K.); [email protected] (R.J.B.) * Author to whom correspondence should be addressed; E-Mail: [email protected]; Tel./Fax: +972-4-829-2680. Academic Editors: Stephen Mansell and Steve Liddle Received: 16 September 2015 / Accepted: 9 October 2015 / Published: 30 October 2015 Abstract: This review article presents the development of organoactinides and actinide coordination complexes as catalysts for homogeneous organic transformations. This chapter introduces the basic principles of actinide catalysis and deals with the historic development of actinide complexes in catalytic processes. The application of organoactinides in homogeneous catalysis is exemplified in the hydroelementation reactions, such as the hydroamination, hydrosilylation, hydroalkoxylation and hydrothiolation of alkynes. Additionally, the use of actinide coordination complexes for the catalytic polymerization of α-olefins and the ring opening polymerization of cyclic esters is presented. The last part of this review article highlights novel catalytic transformations mediated by actinide compounds and gives an outlook to the further potential of this field. Keywords: organoactinides; actinide coordination complexes; homogeneous catalysis; hydroelementations; polymerization of olefins; ROP; activation of heterocumulenes 1. Introduction The beginning of modern organoactinide chemistry is often attributed to the synthesis of 8 uranocene, [(η -C8H8)2U] in 1968, as the analogous compound to ferrocene and other transition metal metallocenes [1,2].
    [Show full text]
  • Recent Studies on the Aromaticity and Antiaromaticity of Planar Cyclooctatetraene
    Symmetry 2010 , 2, 76-97; doi:10.3390/sym2010076 OPEN ACCESS symmetry ISSN 2073-8994 www.mdpi.com/journal/symmetry Review Recent Studies on the Aromaticity and Antiaromaticity of Planar Cyclooctatetraene Tohru Nishinaga *, Takeshi Ohmae and Masahiko Iyoda Department of Chemistry, Graduate School of Science and Engineering, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan; E-Mails: [email protected] (T.O.); [email protected] (M.I.) * Author to whom correspondence should be addressed; E-Mail: [email protected]. Received: 29 December 2009; in revised form: 23 January 2010 / Accepted: 4 February 2010 / Published: 5 February 2010 Abstract: Cyclooctatetraene (COT), the first 4n π-electron system to be studied, adopts an inherently nonplanar tub-shaped geometry of D2d symmetry with alternating single and double bonds, and hence behaves as a nonaromatic polyene rather than an antiaromatic compound. Recently, however, considerable 8 π-antiaromatic paratropicity has been shown to be generated in planar COT rings even with the bond alternated D4h structure. In this review, we highlight recent theoretical and experimental studies on the antiaromaticity of hypothetical and actual planar COT. In addition, theoretically predicted triplet aromaticity and stacked aromaticity of planar COT are also briefly described. Keywords: antiaromaticity; cyclooctatetraene; NMR chemical shifts; quantum chemical calculations; ring current 1. Introduction Cyclooctatetraene (COT) was first prepared by Willstätter in 1911 [1,2]. At that time, the special stability of benzene was elusive and it was of interest to learn the reactivity of COT as the next higher vinylogue of benzene. However, unlike benzene, COT was found to be highly reactive to electrophiles just like other alkenes.
    [Show full text]
  • WO 2016/074683 Al 19 May 2016 (19.05.2016) W P O P C T
    (12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (10) International Publication Number (43) International Publication Date WO 2016/074683 Al 19 May 2016 (19.05.2016) W P O P C T (51) International Patent Classification: (81) Designated States (unless otherwise indicated, for every C12N 15/10 (2006.01) kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, (21) International Application Number: BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, PCT/DK20 15/050343 DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, (22) International Filing Date: HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KN, KP, KR, 11 November 2015 ( 11. 1 1.2015) KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, (25) Filing Language: English PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, (26) Publication Language: English SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (30) Priority Data: PA 2014 00655 11 November 2014 ( 11. 1 1.2014) DK (84) Designated States (unless otherwise indicated, for every 62/077,933 11 November 2014 ( 11. 11.2014) US kind of regional protection available): ARIPO (BW, GH, 62/202,3 18 7 August 2015 (07.08.2015) US GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, (71) Applicant: LUNDORF PEDERSEN MATERIALS APS TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, [DK/DK]; Nordvej 16 B, Himmelev, DK-4000 Roskilde DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, (DK).
    [Show full text]
  • Diphosphazide-Supported Trialkyl Thorium(IV) Complex Tara K
    pubs.acs.org/Organometallics Communication Diphosphazide-Supported Trialkyl Thorium(IV) Complex Tara K. K. Dickie, Ashraf A. Aborawi, and Paul G. Hayes* Cite This: Organometallics 2020, 39, 2047−2052 Read Online ACCESS Metrics & More Article Recommendations *sı Supporting Information ABSTRACT: The potassium salt of a new ligand, KLP=N3 (2, κ5 i i − LP=N3 = -2,5-[(4- PrC6H4)N3 P Pr2]2N(C4H2) ), that features two units of the rare phosphazide (RN3 PR3) functionality was synthesized via an incomplete Staudinger reaction between K[2,5- i i ( Pr2P)2N(C4H2)] (1)and4-PrC6H4N3. The diphosphazide ligand was transferred to a thorium(IV) metal center using salt metathesis strategies, yielding LP=N3ThCl3 (3), which contains two intact and coordinated phosphazides. Reaction of complex 3 with 3 equiv of LiCH2SiMe3 resulted in formation of the trialkyl thorium species LP=N3Th(CH2SiMe3)3 (4). In contrast, attempts to synthesize an organothorium complex supported by the previously κ3 reported bisphosphinimine ligand LP=N (LP=N = -2,5- i i − ff [(4- PrC6H4)N P Pr2]2N(C4H2) )aorded the cyclometalated * * κ4 i i i i 2− dialkyl complex L P=NTh(CH2SiMe3)2 (6,L PN = -2-[(4- PrC6H3)N P Pr2]-5-[(4- PrC6H4)N P Pr2]N(C4H2) ) and 1 equiv of free tetramethylsilane. 1 he Staudinger reaction, discovered in 1919, introduced the facile loss of N2, and, accordingly, were overlooked as ′ ’ T the formation of a phosphinimine group (R3P NR ) via viable functional groups in ligand design. Since Staudinger s the reaction of a tertiary phosphine (R3P) with an organic original work, multiple methods have been developed to ′ azide (N3R ), resulting in concomitant loss of N2.
    [Show full text]
  • (12) Patent Application Publication (10) Pub. No.: US 2007/0087223 A1 Sakamoto Et Al
    US 20070087223A1. (19) United States (12) Patent Application Publication (10) Pub. No.: US 2007/0087223 A1 Sakamoto et al. (43) Pub. Date: Apr. 19, 2007 (54) DIBENZOANTHRACENE DERIVATIVES, 14-position of a dibenzoa,canthracene skeleton and repre ORGANIC ELECTROLUMNESCENT sented by the following formula (1) or (2): DEVICES, AND DISPLAY APPARATUS Formula (1) (75) Inventors: Yukinari Sakamoto, Tokyo (JP); Yoshihisa Miyabayashi, Kanagawa (JP); Tadahiko Yoshinaga, Kanagawa (JP) Correspondence Address: ROBERT. DEPKE LEWIS T. STEADMAN ROCKEY, DEPKE, LYONS AND KITZINGER, LLC SUTE 5450 SEARS TOWER CHICAGO, IL 60606-6306 (US) Formula (2) (73) Assignee: SONY CORPORATION (21) Appl. No.: 11/583,645 (22) Filed: Oct. 17, 2006 (30) Foreign Application Priority Data Oct. 19, 2005 (JP).................................... P2005-304.047 Publication Classification (51) Int. Cl. wherein X', X and X each independently represents a HOIL 5/54 (2006.01) substituted or unsubstituted arylene or divalent heterocyclic C09K II/06 (2006.01) group; A, B, C and D each independently represents a CD7C 2 II/6 (2006.01) Substituted or unsubstituted alkyl, aryl or heterocyclic group, (52) U.S. Cl. ......................... 428/690; 428/917; 313/504; and between the adjacent groups, may be fused together to 313/506; 257/E51; 257/E51; form rings; and Y' to Y''' and R' each independently rep 564/426; 564/434 resents a hydrogen or halogen atom, an alkoxy group, or a Substituted or unsubstituted alkyl, aryl or heterocyclic group, (57) ABSTRACT and, when Y to U' and R' are other than a hydrogen or Dibenzoanthracene derivatives are each substituted by an halogen atom, Y' to Y' and R' may be fused together amino compound group at at least one of 9-position and between the adjacent groups to form rings.
    [Show full text]
  • Alkyl and Fluoroalkyl Manganese Pentacarbonyl Complexes As
    En vue de l'obtention du DOCTORAT DE L'UNIVERSITÉ DE TOULOUSE Délivré par : Institut National Polytechnique de Toulouse (Toulouse INP) Discipline ou spécialité : Chimie Organométallique et de Coordination Présentée et soutenue par : M. ROBERTO MORALES CERRADA le jeudi 15 novembre 2018 Titre : Complexes de manganèse pentacarbonyle alkyle et fluoroalkyle comme modèles d'espèces dormantes de l'OMRP Ecole doctorale : Sciences de la Matière (SDM) Unité de recherche : Laboratoire de Chimie de Coordination (L.C.C.) Directeur(s) de Thèse : MME FLORENCE GAYET M. BRUNO AMEDURI Rapporteurs : M. GERARD JAOUEN, UNIVERSITE PARIS 6 Mme SOPHIE GUILLAUME, CNRS Membre(s) du jury : M. MATHIAS DESTARAC, UNIVERSITE TOULOUSE 3, Président M. BRUNO AMEDURI, CNRS, Membre M. HENRI CRAMAIL, INP BORDEAUX, Membre Mme FLORENCE GAYET, INP TOULOUSE, Membre A mi abuelo Antonio ‐ i ‐ ‐ ii ‐ Remerciements Ce travail a été réalisé dans deux unités de recherche du CNRS : le laboratoire de Chimie de Coordination (LCC) à Toulouse, au sein de l’équipe LAC2, et l’Institut Charles Gerhardt de Montpellier (ICGM), au sein de l’équipe IAM. Il a été codirigé par Dr. Florence Gayet et Dr. Bruno Améduri. Je tiens tout d’abord à remercier Dr. Azzedine Bousseksou, directeur du LCC, et Dr. Patrick Lacroix‐Desmazes, directeur de l’équipe IAM à l’ICGM, pour avoir accepté de m’accueillir au sein de ses laboratoires. Je remercie tout particulièrement mes directeurs de thèse, Dr. Florence Gayet et Dr. Bruno Améduri, pour m’avoir encadré durant ces trois années de doctorat. Un immense merci à tous les deux pour tous leurs conseils, leur patience et leurs connaissances qui m’ont apporté et qui m’ont permis de mener à bien ce travail.
    [Show full text]
  • Organometallic and Catalysis
    ORGANOMETALLIC AND CATALYSIS Dr. Malay Dolai, Assistant Professor, Department of Chemistry, Prabhat Kumar College, Contai, Purba Medinipur-721404, WB, India. 1.Introduction Organometallic chemistry is the study of organometallic compounds, chemical compounds containing at least one chemical bond between a carbon atom of an organic molecule and a metal, including alkaline, alkaline earth, and transition metals, and sometimes broadened to include metalloids like boron, silicon, and tin, as well. Aside from bonds to organyl fragments or molecules, bonds to 'inorganic' carbon, like carbon monoxide (metal carbonyls), cyanide, or carbide, are generally considered to be organometallic as well. Some related compounds such as transition metal hydrides and metal phosphine complexes are often included in discussions of organometallic compounds, though strictly speaking, they are not necessarily organometallic. The related but distinct term "metalorganic compound" refers to metal-containing compounds lacking direct metal-carbon bonds but which contain organic ligands. In 1827, Zeise's salt is the first platinum- olefin complex: K[PtCl3(C2H4)].H2O, the first invented organometallic compound. Organometallic compounds find wide use in commercial reactions, both as homogeneous catalysis and as stoichiometric reagents For instance, organolithium, organomagnesium, and organoaluminium compounds, examples of which are highly basic and highly reducing, are useful stoichiometrically, but also catalyze many polymerization reactions. Almost all processes involving carbon monoxide rely on catalysts, notable examples being described as carbonylations. The production of acetic acid from methanol and carbon monoxide is catalyzed via metal carbonyl complexes in the Monsanto process and Cativa process. Most synthetic aldehydes are produced via hydroformylation. The bulk of the synthetic alcohols, at least those larger than ethanol, are produced by hydrogenation of hydroformylation- derived aldehydes.
    [Show full text]
  • Alkaline-Earth Metal Compounds Oddities and Applications 45 Topics in Organometallic Chemistry
    Topics in Organometallic Chemistry 45 Sjoerd Harder Editor Alkaline-Earth Metal Compounds Oddities and Applications 45 Topics in Organometallic Chemistry Editorial Board: M. Beller l J. M. Brown l P. H. Dixneuf A. Fu¨rstner l L. J. Gooßen P. Hofmann l T. Ikariya l S. Nolan L. A. Oro l Q.-L. Zhou Topics in Organometallic Chemistry Recently Published Volumes Inventing Reactions Iridium Catalysis Volume Editor: Lukas J. Gooßen Volume Editor: P. G. Andersson Vol. 44, 2013 Vol. 34, 2011 Hydrofunctionalization Iron Catalysis – Fundamentals and Volume Editors: Valentine P. Ananikov, Applications Masato Tanaka Volume Editor: B. Plietker Vol. 43, 2013 Vol. 33, 2011 Organometallics as Catalysts Medicinal Organometallic Chemistry in the Fine Chemical Industry Volume Editors: G. Jaouen, N. Metzler-Nolte Volume Editors: Matthias Beller, Vol. 32, 2010 Hans-Ulrich Blaser C-X Bond Formation Vol. 42, 2012 Volume Editor: A. Vigalok Modern Organoaluminum Reagents: Vol. 31, 2010 Preparation, Structure, Reactivity and Use Transition Metal Complexes of Neutral Volume Editors: Simon Woodward, h1-Carbon Ligands Samuel Dagorne Volume Editors: R. Chauvin, Y. Canac Vol. 41, 2012 Vol. 30, 2010 Organometallic Pincer Chemistry Photophysics of Organometallics Volume Editors: Gerard van Koten, Volume Editor: A. J. Lees David Milstein Vol. 29, 2010 Vol. 40, 2012 Molecular Organometallic Materials Organometallics and Renewables for Optics Volume Editors: Michael A. R. Meier, Volume Editors: H. Le Bozec, V. Guerchais Bert M. Weckhuysen, Pieter C. A. Bruijnincx Vol. 28, 2010 Vol. 39, 2012 Conducting and Magnetic Organometallic Transition Metal Catalyzed Enantioselective Molecular Materials Allylic Substitution in Organic Synthesis Volume Editors: M. Fourmigue´, L. Ouahab Volume Editor: Uli Kazmaier Vol.
    [Show full text]
  • Metal Carbonyls
    MODULE 1: METAL CARBONYLS Key words: Carbon monoxide; transition metal complexes; ligand substitution reactions; mononuclear carbonyls; dinuclear carbonyls; polynuclear carbonyls; catalytic activity; Monsanto process; Collman’s reagent; effective atomic number; 18-electron rule V. D. Bhatt / Selected topics in coordination chemistry / 2 MODULE 1: METAL CARBONYLS LECTURE #1 1. INTRODUCTION: Justus von Liebig attempted initial experiments on reaction of carbon monoxide with metals in 1834. However, it was demonstrated later that the compound he claimed to be potassium carbonyl was not a metal carbonyl at all. After the synthesis of [PtCl2(CO)2] and [PtCl2(CO)]2 reported by Schutzenberger (1868) followed by [Ni(CO)4] reported by Mond et al (1890), Hieber prepared numerous compounds containing metal and carbon monoxide. Compounds having at least one bond between carbon and metal are known as organometallic compounds. Metal carbonyls are the transition metal complexes of carbon monoxide containing metal-carbon bond. Lone pair of electrons are available on both carbon and oxygen atoms of carbon monoxide ligand. However, as the carbon atoms donate electrons to the metal, these complexes are named as carbonyls. A variety of such complexes such as mono nuclear, poly nuclear, homoleptic and mixed ligand are known. These compounds are widely studied due to industrial importance, catalytic properties and structural interest. V. D. Bhatt / Selected topics in coordination chemistry / 3 Carbon monoxide is one of the most important π- acceptor ligand. Because of its π- acidity, carbon monoxide can stabilize zero formal oxidation state of metals in carbonyl complexes. 2. SYNTHESIS OF METAL CARBONYLS Following are some of the general methods of preparation of metal carbonyls.
    [Show full text]
  • That the Tout Untuk U Roma W Atu to Ni Kali Hinthi
    THATTHE TOUT UNTUK USU 20180134954A1ROMAW ATU TO NIKALI HINTHI ( 19) United States (12 ) Patent Application Publication ( 10) Pub . No. : US 2018 /0134954 A1 TSAI et al. (43 ) Pub . Date : May 17 , 2018 ( 54 ) ORGANIC ELECTROLUMINESCENT Related U . S . Application Data MATERIALS AND DEVICES (63 ) Continuation - in -part of application No . 15 /407 ,337 , (71 ) Applicant : Universal Display Corporation , filed on Jan . 17 , 2017 . Ewing , NJ (US ) (60 ) Provisional application No .62 / 293 ,100 , filed on Feb . 9 , 2016 , provisional application No. 62 / 338 ,616 , filed (72 ) Inventors : Jui- Yi TSAI, Newtown, PA (US ) ; on May 19 , 2016 . Chuanjun XIA , Lawrenceville , NJ (US ) ; Chun LIN , Yardley, PA (US ) ; Publication Classification Adrian U . PALACIOS , Zaragoza (ES ) ; (51 ) Int. CI. Enrique OÑATE , Zaragoza (ES ) ; CO9K 11 /06 (2006 .01 ) Miguel A . Esteruelas , Zaragoza (ES ) ; CO7F 15 / 00 ( 2006 . 01 ) Pierre -Luc T . BOUDREAULT , HOIL 51/ 00 (2006 .01 ) Pennington , NJ (US ); Sonia BAJO , 2 ) U . S . CI. Zaragoza (ES ) ; Montserrat OLIVÁN , CPC . C09K 11 /06 ( 2013 . 01 ) ; HOIL 51 /5016 Zaragoza (ES ) (2013 . 01 ) ; HOIL 51/ 0085 ( 2013 .01 ) ; CO7F ( 73 ) Assignee : Universal Display Corporation , 15/ 0033 (2013 . 01 ) Ewing , NJ (US ) (57 ) ABSTRACT Novel Iridium complexes having three different bidentate ( 21 ) Appl. No .: 15 / 866 , 561 ligands useful for phosphorescent emitters in OLEDs are disclosed . At least one of the three different bidentate ligands (22 ) Filed : Jan . 10 , 2018 is a carbene ligand . ) www Patent Application Publication May 17, 2018 Sheet lof7 US 2018 / 0134954 A1 ** “ ? ,,, MMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMM M MMMM * * * mmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmm &s??????8 … … … … … * * . ) Ht - ? FIG ? 1 Patent Application Publication May 17 , 2018 Sheet 2 of 7 US 2018 / 0134954 A1 ????? ????? ????? ????? ??? ?????? ???????? ????? ????? ???????? ????? ????? ?????? ??? ?? ????? ????? ????? ????? ???? ????? ???? ?? ? FIG .
    [Show full text]