Impact of Nitrogen Profile in Gate Nitrided-Oxide on Deep-Submicron CMOS Performance and Reliability

v Kanetake Takasaki v Kiyoshi Irino v Takayuki Aoyama v Youichi Momiyama v Toshiro Nakanishi v Yasuyuki Tamura v Takashi Ito (Manuscript received December 25, 2002)

Silicon dioxide has been used for the gate insulator in CMOS with gate lengths down to 0.25 µm. However, when we enter the sub-0.18 µm era, nitrogen atoms must be incorporated into the dioxide to prevent an undesirable penetration of boron atoms from the gate electrode to the Si substrate. In this paper, we describe the ef- fects of the nitrogen atom profile on CMOS performance and reliability and clarify the mechanisms underlying these effects. We show that high-performance, high-reliability CMOSFETs can be achieved by using a newly developed nitrided-oxide process that features a 900°C gate nitrided-oxide and establishes different nitrogen concentrations between the gate and extension area. When we enter the sub-100 nm-gate-length era of CMOS, we will need to replace thermal nitridation for the gate oxide with an alterna- tive nitridation process, for example, plasma nitridation.

1. Introduction current drivability due to depletion of the poly- Without an exquisite combination of silicon- crystalline-silicon electrode.5) dioxide (SiO2) and Si, we could not have enjoyed Fujitsu has a long history of comprehensive- the benefits of IT (Information Technology) tech- ly studying nitrided-oxide gate , 6),7) and nologies based on state-of-the-art CMOS to address these issues caused by boron diffusion,

(Complementary Metal-Oxide-Semiconductor) we have tried to replace gate SiO2 with nitrided- technology. oxide. Nitrided-oxide gate dielectrics (Gate-NO) As long as CMOS gate lengths stay around have been used for dual-gate CMOSFETs with 0.25 µm, we do not need to worry about using deep submicron channel lengths because of their as a gate-insulator. However, when high boron blocking ability8),9) (Figure 1) and hot we enter the sub-0.18 µm-gate-length era of carrier immunity.10),11) However, the most serious CMOS, for the first time we face the need to re- problem with Gate-NO is that it deteriorates p- 12) place SiO2 with another gate insulator. To achieve MOSFET drivability. Preventing extension a high-performance, 0.18 µm-gate-length surface- dopants, especially boron, from diffusing outward channel p-MOSFET, we need to use into the sidewall and increasing the parasitic se- p+-poly-crystalline-silicon for the gate material.1) ries resistance (Rext) is expected to be another However, boron penetration from the p+-poly- important issue. To address these issues, we in- crystalline-silicon gate into the underlying silicon serted a nitrided-oxide (Ex-NO) between the substrate degrades device operation. This degra- extension area and sidewall as a blocking layer dation includes instability in the threshold voltage (Figure 2). We devised a novel way to indepen-

(Vth), an increase in the charge-trapping rate, a dently optimize the nitrogen profile and content decrease in low-field mobility,2)-4) and a reduced for the Gate-NO and Ex-NO to suppress the deg-

40 FUJITSU Sci. Tech. J., 39,1,p.40-51(June 2003) K. Takasaki et al.: Impact of Nitrogen Profile in Gate Nitrided-Oxide on Deep-Submicron CMOS Performance and Reliability

Annealing temperature (°C) 1200 1100 1000 900 800 Gate Gate -15 B Gate-NO 10 B B /s) -2 B B 2 + B Ex-NO BF2 : 5E15 cm B B B -16 Oxynitride B B 10 B B B B B B B B B B B B Nitrogen -17 Extension 10 B layer

0% Rext(PO) Rchannel Rext(NO) Rchannel 10-18 > Rext(PO) Rext(NO) 10-19 4% 25% 18% 9%

Boron diffusion coefficient (cm Figure 2 10-20 0.65 0.7 0.75 0.8 0.85 0.9 0.95 Schematic cross section of p-MOSFET described in this paper. 1000/T (K-1)

Figure 1 Boron diffusion coefficient in oxynitride.

Furnace Process

Quartz Temperature Nitridation O , N NO, N 2 2 2 tube 900°C

Oxidation 750°C

H2, N2

300°C Purge

(Steam) (N2 gas) (NO gas)

Pyrogenic Exhaust reactor NO O N

SiO2 Si3N4 Si Si

Figure 3 Gate nitrided-oxide process. radation of p-MOSFET drivability and the out- same furnace after gate electrode formation and ward diffusion of extension dopant. residual gate oxide removal. The process flow of the MOSFET is shown in Figure 4. After isola- 2. Experiments tion, a thin (3.5 to 5.5 nm) gate was The gate insulator formation furnace and grown. The thickness was deter- process are shown in Figure 3. As a control, gate mined by C-V measurement. Dual gate doping oxide was thermally grown in the furnace at 750 was carried out by B + and P + implantation after to 800°C. Gate-NO was grown by annealing ther- poly-Si deposition (180 nm). Shallow extension ° mal oxide in NO or N2O gas ambient at 800 C or was performed by low-energy implantation after ° 900 C. Ex-NO was also formed with NO in the Ex-NO formation. Sidewall formation (CVD-SiO2)

FUJITSU Sci. Tech. J., 39,1,(June 2003) 41 K. Takasaki et al.: Impact of Nitrogen Profile in Gate Nitrided-Oxide on Deep-Submicron CMOS Performance and Reliability

was followed by deep S/D implantation and RTA 3. Results (Rapid Thermal Annealing) at 1000°C. 3.1 Nitrided-oxide film properties We examined the nitrogen depth profile us- We examined the nitrogen depth profile by ing SIMS (Secondary Ion Mass Spectroscopy), the SIMS for three kinds of nitrided-oxide: 900°C-NO, nitrogen chemical bonding state using XPS (X-ray 800°C-NO, and 900°C-N2O (Figure 5). We also Photo-emission Spectroscopy), and the interface studied the nitrogen chemical bonding state us- property using charge pumping current measure- ing XPS. Figure 6 shows N1s spectra at various ment. We evaluated the characteristics of 0.2 µm take-off angles for the 900°C-NO and 800°C-NO. CMOSFETs and extracted the mobility and series The 900°C-NO has a sharp peak at about 398 eV, 13) ≡ resistance using the shift and ratio method. We which corresponds to the Si3 N bond in 14) ° also evaluated the hot carrier immunity for n- CVD-Si3N4. On the other hand, the 800 C-NO . has two peaks: one at about 398 eV and another at about 399 eV. The intensity of the 398 eV peaks increases with the take-off angle, and the intensity of the 399 eV peak decreases with the take-off angle. Gate-NO This indicates that the 398 and 399 eV peaks cor- After gate-NO respond, respectively, to a nitrogen-related bond STI near the interface and a nitrogen-related bond in the bulk nitrided-oxide.15) As the thickness of the Poly Si Ex-NO 800°C-NO is increased, the binding energy (BE) After extension-NO formation around 399 eV increases, but the BE around 398 eV remains almost constant (Figure 7). This CVD-SiO CoSi2 2 energy shift might be caused by the X-ray induced 16) After source drain charge-up effect, implying that the 399 eV peak formation ≡ also corresponds to Si3 N bonds and some nitro- gen atoms exist away from the interface. These Figure 4 results suggest that nitrogen atoms exist both at Process flow of MOSFET. the interface and in the bulk in the 800°C-NO

3 900°C-N O 2 Si ≡ N: 398 eV 800°C-NO 3 2.5 Gate 900°C-NO 900°C-NO 800°C-NO insulator 2 Si-substrate 1.5 Si profile ° ° 1 (arb. unit) 90 90 Nitrogen (at. %) Nitrogen (at. Intensity (a.u.) Intensity 0.5 ° (a.u.) Intensity 45 45° 20° 0 20° -4 -20 2 4 Depth (nm) 404 402 400 398 396 394 404 402 400 398 396 394 Binding energy (eV) Binding energy (eV) Figure 5 Nitrogen depth profile for 900°C-NO, 800°C-NO, and Figure 6 ° 900 C-N2O measured by secondary ion mass spectros- N1s photoelectron spectra for various take-off angles of copy. 900°C-NO and 800°C-NO by XPS.

42 FUJITSU Sci. Tech. J., 39,1,(June 2003) K. Takasaki et al.: Impact of Nitrogen Profile in Gate Nitrided-Oxide on Deep-Submicron CMOS Performance and Reliability

400 400 ° ° ° 900 C-N2O 800 C-NO 900 C-NO 900°C-NO 800°C-NO

SiO2 SiO2 SiO2 Nitrogen 399 399 Interface

Charge-up effect

398 398 Si Si Si binding energy (eV) binding energy (eV) s 1s 1 N N Mainly in Mainly at At interface bulk interface 397 397 2 2.5 3 3.5 4 4.5 5 2 2.5 3 3.5 4 4.5 5 Figure 8 Thickness (nm) Thickness (nm) Schematic cross section of nitrided oxide showing the lo- cation of nitrogen. Figure 7

Dependence of N1s binding energy on oxynitride ° ° thickness for 900 C-NO and 800 C-NO by XPS. ≡ ≡ ≡ (a) N Si3 (a’) N Si2O (b) N Si3 samples, but only at the interface in the 900°C-NO) samples.17) The XPS spectra for the ° 900 C-N2O mainly consisted of a 399 eV peak, showing that nitrogen atoms are located in the bulk (Figure 8).18) ≡ ≡ (c) N Si3 (d) N O3 NO A theoretical analysis based on first- Si principle calculation also confirms that the Relative energy ≡ Si3 N bonds at the interface are the most stable a 0.0 (eV) a' 2.4 and higher temperature thermal treatments in- b 0.7 duce nitrogen atoms to pile up at the SiO2/Si c 1.8 d 7.7 interface (Figure 9).19)

3.2 Nitrided-oxide interface properties Figure 9 ≡ Three-coordinated-N-configurations. (a) Si3 N at the in- Figure 10 shows the charge pumping cur- ≡ ≡ terface, (a’) Si2O N at the interface, (b) Si3 N at the 20) ≡ rent of n-MOSFETs and p-MOSFETs with second layer in the substrate, (c) Si3 N at the third layer in the substrate, and (d) O ≡ N in the SiO region. various gate insulators. The peak nitrogen con- 3 2 centration of nitride-oxide was confirmed to be 0.8 atomic %. The charge pumping currents of caused by boron penetration. Figure 11 shows ° the 900 C-NO n- and p-MOSFETs are less than the dependence of Nit on Npeak in the n- and p- those for the other samples. This implies that the MOSFETs. Among the n-MOSFETs, in this range ° ° Nit for 900 C-NO is the smallest. Furthermore, of Npeak the Nit of the 900 C-NO sample was lower compared with the n-MOSFETs, there is a remark- than that of the other samples, even the pure ox- able Vth shift in the p-MOSFETs. This Vth shift ide sample. Also, the Nit of all three nitrided-oxide was not caused by a fixed charge in the gate di- samples increased as Npeak increased. Among the electric, because the same shift was not observed p-MOSFETs, the 900°C-NO sample with a in the n-MOSFETs. Moreover, the Vth of the gate 0.8 atomic % Npeak had the smallest Nit , indicat- oxide is shifted positively from the Vth of the gate ing that it had better interface characteristics than nitrided-oxide. Therefore, we consider that the the other samples.

Vth shift was caused by boron penetration. Thus, According to the theoretical analysis men- 19) ≡ the gate nitrided-oxide suppressed the Vth shift tioned above, the interface Si3 N configuration

FUJITSU Sci. Tech. J., 39,1,(June 2003) 43 K. Takasaki et al.: Impact of Nitrogen Profile in Gate Nitrided-Oxide on Deep-Submicron CMOS Performance and Reliability

3.5 × 10-8 -10 × 10-7

900°C-N O 900°C-N O 2 3 × 10-8 2 -8 × 10-8 2.5 × 10-8 800°C-NO ° 800 C-NO Control Control -6 × 10-8 2 × 10-8

1.5 × 10-8 -4 × 10-8

1 × 10-8 Charge pumping current (A) current pumping Charge Charge pumping current (A) current pumping Charge 900°C-NO 900°C-NO -2 × 10-8 0.5 × 10-9

0 × 10 0 0 × 10 0 -0.8 -0.6 -0.4 -0.2 0 0.2 0.4 0.6 -0.8 -0.6 -0.4 -0.2 0 0.2 0.4 0.6 Pulse base voltage (V) Pulse base voltage (V) (a) n-MOSFET (b) p-MOSFET

Figure 10 Charge pumping current of n-MOSFETs and p-MOSFETs with various gate insulators.

2.2 × 1010 6.5 × 1010 ° 900 C-N2O ° 900 C-N2O 2 × 1010 6 × 1010

1.8 × 1010 5.5 × 1010 800°C-NO ) ) × 10 × 10 2 2 1.6 10 5 10 - - (cm (cm

it it Control 10 ° 10 N 1.4 × 10 800 C-NO N 4.5 × 10

1.2 × 1010 4 × 1010 900°C-NO ° 1 × 1010 Control 3.5 × 1010 900 C-NO

8 × 10 9 3 × 1010 0 0.5 1 1.5 2 2.5 0 0.5 1 1.5 2 2.5 Peak nitrogen concentration (%) Peak nitrogen concentration (%) (a) n-MOSFET (b) p-MOSFET Figure 11 Dependence of interface state density obtained by charge pumping measurement on peak nitrogen con- centration in n- and p-MOSFETs. of (a) has no gap states. Substituted N atoms in atom content above 0.8%, nitrogen atoms can no configurations (b) and (c) generate dangling bonds longer be accommodated at the SiO2/Si interface, at the Si atoms near the N atoms, and the dan- which might create gap states, especially in p- gling bonds create gap states and work as hole MOSFETs. trapping sites. When we increase the nitrogen

44 FUJITSU Sci. Tech. J., 39,1,(June 2003) K. Takasaki et al.: Impact of Nitrogen Profile in Gate Nitrided-Oxide on Deep-Submicron CMOS Performance and Reliability

3.3 Characteristics of CMOSFETs with the mobility characteristics. However, 5.3% NO the same NO concentrations in the deteriorates the mobility. The parasitic resistanc- gate and extension es (Rext) of this p-MOSFET with various Figure 12 shows the Ion vs. Ioff character- dielectrics are shown in Figure 14. The decrease istics for a 0.2 µm p-MOSFET. A significant 50% of Rext for 1.5% NO compared with pure oxide reduction in Ioff has been achieved using 1.5% NO implies that Ex-NO can effectively suppress the compared with pure oxide. This remarkable re- outward diffusion of dopant. This effect is more duction in Ioff might be due to the suppression of prominent when the nitrogen concentration is in- dopant (boron) diffusion in the lateral direction, creased to 5.3%. owing to the Ex-NO. Figure 13 shows the mobil- Figure 15 shows the dependence of device ities of this p-MOSFET with various gate lifetime on the substrate current for n-MOSFETs dielectrics. Surprisingly enough, the nitrogen con- tent can be increased to 1.5% without degrading 1000 Pure oxide 10-9 800

(Pure oxide) 600 (1.5% NO) p-MOSFET 1.5% NO ( Ω / µ m) W = 10 µm ext 400 R 10-10 5.3% NO /W (A/ µ m) 200 off I

p-MOSFET 0 W = 10 µm 1 0 -1 -2 -3 -4 Vg (V) 10-11 0 100 200 300 Figure 14 I /w (µA/µm) on Rext of 0.2 µm p-MOSFET with various gate dielectrics obtained by shift and ratio method. Dopant concentration Figure 12 near the surface of extension area is about Ion vs Ioff characteristics of p-MOSFET (W = 10 µm). 1019 atoms/cm3.

105 120 900°C-NO

Lg = 0.2 µm 100 104 800°C-NO

S) 80 - Control 3

/V 10

2 Pure oxide 60

1.5% NO (s) Lifetime

2 40 10 5.3% NO Nitrogen peak °

Mobility (cm 900 C-N2O concentration: 0.8% 20 101 10-6 10-5 10-4

0 Isub/W (A/mm) 0 0.5 1 1.5 2 2.5 3 Vg-Vth (V) Figure 15 Dependence of device lifetime of n-MOSFET on substrate Figure 13 current under drain avalanche hot carrier stress. Lifetime Mobilities of 0.2 µm p-MOSFET with various gate dielec- is defined as the time to reach a 10% degradation in satu- trics obtained by shift and ratio method. ration current.

FUJITSU Sci. Tech. J., 39,1,(June 2003) 45 K. Takasaki et al.: Impact of Nitrogen Profile in Gate Nitrided-Oxide on Deep-Submicron CMOS Performance and Reliability

with gate oxide and gate nitrided-oxide under the combination of gate and extension pure oxide DAHC (Drain Avalanche Hot Carrier) stress. The (Table 1).22) As the channel length is reduced, the

Npeak of the nitrided-oxide is 0.8 atomic %. The contribution of Rext becomes larger. For lifetime is defined as the time to reach a 10% deg- p-MOSFETs with gate lengths below 0.1 µm, a radation in the saturation current measured at further increase in Ids could be expected by sup-

Vd = Vg = 2.5 V, where Vd and Vg are the drain and pressing unfavorable boron diffusion from the gate voltages, respectively. The nitrided-oxide, extension area. Enveloping the boron extension especially 900°C-NO, yielded better hot carrier area with implanted nitrogen (N-tub) (Figure 17) immunity than the pure oxide. Figure 16 shows is also effective for suppressing the unfavorable the dependence of Nit on Npeak for n-MOSFETs af- boron diffusion and clearly verifies the validity of 4 23) ter application of hot carrier stress for 10 s. Nit this idea (Figure 18). of the nitrided-oxide is less than that of pure ox- ide and decreases as Npeak increases. This implies 4. Gate insulator in sub-100 nm that the use of nitrided-oxide suppressed the gen- node eration of Nit during DAHC stress. Moreover, a When we fabricate devices with gate lengths superior suppression of hot carrier degradation of less than 100 nm, we have to reduce the gate 24)-26) with 900°C-NO was observed, even when Npeak was oxide thickness to less than 1.2 nm, which the same.21) results in a serious increase in gate cur- rent. Increasing the dielectric constant of the gate 3.4 Characteristics of CMOSFETs with different NO concentrations in the gate and extension Table 1 The trade-off problem between mobility and Ion and Ioff of p-MOSFET with various Gate-NO and Extension-NO. Rext inevitably arises for the same Gate-NO and Npeak concentration (%) Relative ratio (pure oxide = 1) Ex-NO concentration. The combination of 1.5% Gate-NO Ex-NO Ion Ioff Gate-NO and 5.3% Ex-NO successfully increases 0 0 1 1 Ids by 12% in a 0.2 µm p-MOSFET compared to 1.5 1.5 1.07 0.52 1.5 5.3 1.12 0.50

4.5 × 1011 After 104 s Nitrogen implantation 11 4 × 10 DAHC stress (V = 3.5 V) 11 d 3.5 × 10 Control ° 11 900 C-N2O ) ×

2 3 10 -

× 11 (cm 2.5 10 it N ° 11 800 C-NO 2 × 10 High tilt-angle ° 900 C-NO Sb-pocket 1.5 × 1011

1 × 1011 0 0.5 1 1.5 2 2.5 Peak nitrogen concentration (%) Shallow Xj Figure 16 Low-energy B implantation Dependence of interface state density of n-MOSFET ob- High ramp-up/down rate spike-RTA tained by charge pumping measurement on peak nitro- gen concentration after application of drain avalanche hot Figure 17 carrier stress for 104 s. Schematic of N-tub design concept.

46 FUJITSU Sci. Tech. J., 39,1,(June 2003) K. Takasaki et al.: Impact of Nitrogen Profile in Gate Nitrided-Oxide on Deep-Submicron CMOS Performance and Reliability

-0.8 Table 2 N-tub, Ext., Lg Change of gate oxide process. × 14 5 10 High 43 nm Device w.o. Med. 45 nm Lg>250 nm 180 nm>Lg>130 nm Lg<100 nm -0.6 generation Vg = -1.2 V µ Gate oxide Ioff = -100 nA/ m Tox>5.5 nm 4.0 nm>Tox>1.8 nm Tox<1.2 nm thickness

-0.4 O2 O2, NO O2, NO plasma N2 Id (mA/ µ m) Structure -0.2 step V 0.2

Si substrate Si substrate Si substrate

0.0 Near Si substrate 0.0 -0.2 -1.0 -1.5 N distribution None Near Si substrate +SiO2 surface Vd (V) Oxidation Oxidation Process Oxidation +NO nitridation +NO nitridation Figure 18 +Plasma nitridation Id-Vd characteristics of N-tub MOSFET.

insulator is an effective way to avoid the leakage 5. Conclusions current increase.27) Reducing the gate oxide thick- We showed that a nitrided-oxide gate dielec- ness requires a further ability of gate tric grown at 900°C in NO has a nitrogen peak at nitrided-oxide to suppress boron penetration. In the SiO2/Si interface, which has the effect of de- general, this further ability might be achieved by creasing the interface state density and increasing the nitrogen content of the nitrided- suppressing the outward diffusion of extension oxide. However, further increases of the nitrogen dopant. We have fabricated a high-performance, content around the gate-oxide/Si-substrate inter- high-reliability CMOSFET using a newly devel- face enhances Negative Bias Temperature oped nitrided-oxide process. The process features Instability (NBTI).28)-30) 900°C Gate-NO and establishes different nitro- Plasma nitridation of the nitrided-oxide has gen concentrations between the gate and been developed as a promising solution to reduce extension area. In p-MOSFETs, the new process the gate leakage current and gate-to-substrate can increase Ids by 12% and decrease Ioff by 50% boron penetration without enhancing the NBTI, compared with the case when pure oxide is used. because this process can confine the nitrogen at- In n-MOSFETs, the new process can significantly oms around the top of the gate nitrided-oxide31) improve hot carrier reliability. (Table 2). When we enter the sub-100 nm-gate-length In addition to an aggressive development of era of CMOS, we will need to replace thermal ni- new technologies that enable us to fabricate thin- tridation for the gate oxide with an alternative ner gate nitrided-oxides, a comprehensive nitridation process, for example, plasma nitrida- understanding of the NBTI mechanism as well as tion. the development of a highly nitrogen-doped gate oxide that is free of fixed charges are strongly References anticipated. A theoretical analysis that is tightly 1) G. J. Hu and R. H. Bruce: Design Tradeoffs linked with precise material research, of course between Surface and Buried-channel FET’s. guided by device performance evaluation, might IEEE Trans. Electron Devices, ED-32, p.584- be a solid solution to this keen need to further 588 (1985). reduce gate oxide thickness. 2) J. R. Pfiester, F. K. Baker, T. C. Mele, H.-H,

FUJITSU Sci. Tech. J., 39,1,(June 2003) 47 K. Takasaki et al.: Impact of Nitrogen Profile in Gate Nitrided-Oxide on Deep-Submicron CMOS Performance and Reliability

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50 FUJITSU Sci. Tech. J., 39,1,(June 2003) K. Takasaki et al.: Impact of Nitrogen Profile in Gate Nitrided-Oxide on Deep-Submicron CMOS Performance and Reliability

Kanetake Takasaki received the B.S. Toshiro Nakanishi received the B.E. degree in Physics from Osaka Univer- and M.E. degrees in Electronics Engi- sity, Japan in 1973 and the M.S. and neering from Kobe University, Kobe, Ph.D. degrees in Applied Physics from Japan in 1981 and 1983, respectively, the University of Tokyo, Tokyo, Japan in and the D.Eng. degree from Tohoku Uni- 1975 and 1978, respectively. He joined versity, Sendai, Japan in 1998. In 1983, Fujitsu Ltd., Kawasaki, Japan in 1978, he joined Fujitsu Laboratories Ltd., where he has been engaged in research Kawasaki, Japan, where he was en- and development of IC processing. gaged in research of Si and SiO2. He From 1993 to 2003 he was transferred was responsible for development of hot to Fujitsu Laboratories Ltd., Atsugi, processes at the Fujitsu/Toshiba DRAM Japan. He is an Executive Director of the Japan Society of Ap- joint development project from 1999 to 2001. He is currently plied Physics. In 2000, he received the Ohkouchi Memorial Award engaged in memory device development. for the work described in this paper.

Kiyoshi Irino received the B.S. and Yasuyuki Tamura received the B.S. M.S. degrees in Electronics Engineer- degree in Physics from Yokohama City ing from Toyama University, Toyama, University, Yokohama, Japan in 1993. Japan in 1982 and 1984, respectively. He joined Fujitsu Laboratories Ltd., He joined Fujitsu Ltd., Kawasaki, Japan Atsugi, Japan in 1993, where he has in 1984, where he has been engaged been researching process and device in research and development of IC pro- technologies for the gate dielectrics of cessing. From 1998 to 2002, he was MOS devices. His current interest is transferred to Fujitsu Laboratories Ltd., high-k materials as candidates for gate Atsugi, Japan. He is a member of the dielectrics. He is a member of the Japan Society of Applied Physics. Japan Society of Applied Physics.

Takayuki Aoyama received the B.E. Dr. Takashi Ito received the B.S., M.S., and M.E. degrees in Electronics Engi- and Ph.D. degrees in Electronics Engi- neering from Tohoku University, Sendai, neering from Tokyo Institute of Technol- Japan in 1985 and 1987, respectively. ogy, Tokyo, Japan in 1969, 1971, and He joined Fujitsu Laboratories Ltd., 1974, respectively. He joined Fujitsu Atsugi, Japan in 1987, where he has Laboratories Ltd., Kawasaki, Japan in been engaged in surface cleaning for 1974, where he has been engaged in silicon epitaxy and impurity diffusion in research and development of semicon-

SiO2. He is now developing IC process- ductor technologies for high-speed LSIs. ing at the Akiruno Technology Center. Dr. Ito is a member of the Institute of Electronics, Information and Communi- cation Engineers (IEICE) of Japan and the Electrochemical So- ciety. He received the Ohm Technology Award and Ohkouchi Memorial Award in 1999 and 2000, respectively.

Youichi Momiyama received the B.S. and M.S. degrees in Electronics Engi- neering from Niigata University, Niigata, Japan in 1990 and 1992, re- spectively. He joined Fujitsu Laborato- ries Ltd., Atsugi, Japan in 1992, where he has been engaged in research and development of low-power and high- speed CMOS devices. He is a member of the IEEE.

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