1
Droplet Formation
How do spherical cloud droplets form? What are the necessary physical conditions?
To start with, we need to intro duce the concept of surface tension. Weintro duce the
Gibbs Free Energy of a droplet as
G = U TS + pV
Where U is the total internal energy,Sisentropy.
Recall that U can also b e expressed as
U = TS p V
which is the rst law of thermo dynamics. So wenowhave
G = U TS + ST +p V + VP
and some of the terms obviously vanish leaving
G = ST + VP
Consider nowa water droplet immersed in water vap or which has partial pressure e.
The droplet and vap or are not in equilibrium meaning
e 6= e
s
We let the Gibbs free energy p er unit mass of the vap or b e G and of the droplet G .
V d
Next we make use of a standard 'trick' in lots of areas of physics and we makea very
small p ertubation to a quantity. In this case we will vary the partial pressure by an amount
e in sucha way so as the temp erature remains constant. Hence
G = V e ; G = V e
v v d d
Now clearly
2
V >> V
v d
so that
G G =V V e V e
v d v d v
We assume that the vap or satis es the ideal gas law
RT
V =
v
e
so that
e
G = V e = RT
v v
e
Integrating at constant T then gives
G G = RT l ne+constant
v d
Implicit throughout this is the understanding that G is a function of temp erature and
pressure and therefore the constantwould change with Temp erature.
At equilibrium on the vap or pressure phase diagram, e = e and G = G Therfore,
s v d
our constantmust equal