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Ep 3111763 A1 (19) TZZ¥___¥_T (11) EP 3 111 763 A1 (12) EUROPEAN PATENT APPLICATION (43) Date of publication: (51) Int Cl.: 04.01.2017 Bulletin 2017/01 A01N 43/58 (2006.01) A01N 43/653 (2006.01) A01P 7/00 (2006.01) (21) Application number: 15175092.4 (22) Date of filing: 02.07.2015 (84) Designated Contracting States: (71) Applicant: BASF Agro B.V. AL AT BE BG CH CY CZ DE DK EE ES FI FR GB 6835 EA Arnhem (NL) GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR (72) Inventor: Mazuir, Florent Designated Extension States: 68165 Mannheim (DE) BA ME Designated Validation States: (74) Representative: BASF IP Association MA BASF SE ZRX-C6 67056 Ludwigshafen (DE) (54) PESTICIDAL COMPOSITIONS COMPRISING A TRIAZOLE COMPOUND (57) The present invention relates to pesticidal compositions and uses and methods for combatting harmful pests using the inventive compositions, such as phythopathogenic fungi and/or for the control of insects, acarids or nematodes. Furthermore, the present invention provides methods for improving the health of a plant using the inventive compositions. EP 3 111 763 A1 Printed by Jouve, 75001 PARIS (FR) EP 3 111 763 A1 Description [0001] The present invention relates to pesticidal compositions and uses and methods for combatting harmful pests using the inventive compositions, such as phythopathogenic fungi and/or for the control of insects, acarids or nematodes. 5 Furthermore, the present invention provides methods for improving the health of a plant using the inventive compositions. [0002] The invention furthermore relates to the use of the inventive compositions for controlling phytopathogenic fungi as detailled herein and preparations or compositions comprising them. The invention furthermore also relates to seed comprising the compositions. The invention furthermore also relates to methods for controlling phytopathogenic fungi as detailled herein, wherein the fungi or the materials, plants, the soil or seed to be protected from fungal attack are 10 treated with an effective amount of a compositions according to the invention. The invention furthermore also relates to processes for preparing the compositions according to the invention. [0003] Practical agricultural experience has shown that the repeated and exclusive application of an individual active compound in the control of harmful fungi leads in many cases to a rapid selection of those fungus strains which have developed natural or adapted resistance against the active compound in question. Effective control of these fungi with 15 the active compound in question is then no longer possible. [0004] To reduce the risk of the selection of resistant fungus strains, compositions of different active compounds are nowadays conventionally employed for controlling harmful fungi. By combining active compounds having different mech- anisms of action, it is possible to ensure successful control over a relatively long period of time. [0005] Furthermore, there is a desire for pesticide compounds or combination of compounds, which when applied 20 improve plants, which may result in "plant health", "vitality of plant propagation material" or "increased plant yield". [0006] It is therefore an object of the present invention to provide agricultural combinations which solves one or more than one of the discussed problems. It has been found that this object is in part or in whole achieved by the combination of active compounds defined below. [0007] We have accordingly found that this object is achieved by the compositions, defined herein, comprising a 25 compound I, a compound II and a compound III. Moreover, we have found that simultaneous, that is joint or separate, application of a compound I and a compound II or successive application of a compound I, a compound II and of compound III allows better control of harmful fungi than is possible with the individual compounds alone (synergistic compositions). [0008] The present invention relates, to compositions comprising, 30 1) as component I a compound selected from the group consisting of the compounds I-1, I-2, I-3, I-4, I-5, I-6, I-7, I- 8, I-9, I-10, I-11, I-12, I-13, I-14, I-15, I-16, I-17, I-18, I-19, I-20, I-21, I-22, I-23, I-24, I-25, I-26, I-27, I-28, I-29, I-30 and I-31, or the N-oxides or the agriculturally acceptable salts of each of the compounds; 35 2) as component II a compound of formula II: 40 wherein 45 1 R is H, C1-C2-alkyl, or C1-C2-alkoxy-C1-C2-alkyl; 2 R is CH3, or halomethyl; 50 3 R is CN, C1-C6-alkyl, C1-C6-haloalkyl, C1-C2-alkoxy-C1-C2-alkyl, C2-C6-alkenyl and C2-C6-alkynyl, C3-C6-cy- cloalkyl, C 5-C6-cycloalkenyl, C1-C6-alkoxy, wherein the C-atoms are unsubstituted, or partially or fully substituted by Ra; a R is halogen, CN, C1-C2-alkyl, C1-C2-haloalkyl, C1-C4-alkoxy, C1-C2-haloalkoxy; 55 4 3 R is C1-C4-alkyl, or a group mentioned for R ; or 3 4 a R and R may together form C5-C6-cycloalkyl, which is unsubstituted, or partially or fully substituted by R ; 2 EP 3 111 763 A1 R5 is H, or a group mentioned for R4; and the stereoisomers, salts, tautomers and N-oxides thereof; and 5 3) as component III a compound selected from the group consisting of the compounds L1) Microbial pesticides with fungicidal, bactericidal, viricidal and/or plant defense activator activity: Ampelomy- ces quisqualis, Aspergillus flavus, Aureobasidium pullulans, Bacillus altitudinis, B. amyloliquefaciens, B. meg- aterium, B. mojavensis, B. mycoides, B. pumilus, B. simplex, B. solisalsi, B. subtilis, B. subtilis var. amylolique- 10 faciens, Candida oleophila, C. saitoana, Clavibacter michiganensis (bacteriophages), Coniothyrium minitans, Cryphonectria parasitica, Cryptococcus albidus, Dilophosphora alopecuri, Fusarium oxysporum , Clonostachys rosea f. catenulate (also named Gliocladium catenulatum), Gliocladium roseum, Lysobacter antibioticus, L. enzymogenes, Metschnikowia fructicola, Microdochium dimerum, Microsphaeropsis ochracea, Muscodor albus, Paenibacillus alvei, Paenibacillus polymyxa, Pantoea vagans, Penicillium bilaiae, Phlebiopsis gigantea, Pseu- 15 domonas sp., Pseudomonas chloraphis , Pseudozymaflocculosa , Pichia anomala, Pythium oligandrum, Sphaer- odes mycoparasitica, Streptomyces griseoviridis, S. lydicus, S. violaceusniger, Talaromyces flavus, Trichode- rma asperellum, T. atroviride, T. fertile, T. gamsii, T. harmatum, T. harzianum, T. polysporum, T. stromaticum, T. virens, T. viride, Typhula phacorrhiza, Ulocladium oudemansii, Verticillium dahlia, zucchini yellow mosaic virus (avirulent strain); 20 L2) Biochemical pesticides with fungicidal, bactericidal, viricidal and/or plant defense activator activity: chitosan (hydrolysate), harpin protein, laminarin, Menhaden fish oil, natamycin, Plum pox virus coat protein, potassium or sodium bicarbonate, Reynoutria sachalinensis extract, salicylic acid, tea tree oil; L3) Microbial pesticides with insecticidal, acaricidal, molluscidal and/or nematicidal activity: Agrobacterium ra- diobacter, Bacillus cereus, B. firmus, B. thuringiensis, B. thuringiensis ssp. aizawai, B. t. ssp. israelensis, B. t. 25 ssp. galleriae, B. t. ssp. kurstaki, B. t. ssp. tenebrionis, Beauveria bassiana, B. brongniartii, Burkholderia spp., Chromobacterium subtsugae, Cydia pomonella granulovirus (CpGV), Cryptophlebia leucotreta granulovirus (CrIeGV), Flavobacterium spp., Helicoverpa armigera nucleopolyhedrovirus (HearNPV), Heterorhabditis bac- teriophora, Isaria fumosorosea, Lecanicillium longisporum, L. muscarium, Metarhizium anisopliae, Metarhizium anisopliae var. anisopliae, M. anisopliae var. acridum, Nomuraea rileyi, Paecilomyces lilacinus, Paenibacillus 30 popilliae, Pasteuria spp., P. nishizawae, P. penetrans, P. ramosa, P. thornea, P. usgae, Pseudomonas fluores- cens, Spodoptera littoralis nucleopolyhedrovirus (SpIiNPV), Steinernema carpocapsae, S. feltiae, S. kraussei, Streptomyces galbus, S. microflavus; L4) Biochemical pesticides with insecticidal, acaricidal, molluscidal, pheromone and/or nematicidal activity: L- carvone, citral, (E,Z)-7,9-dodecadien-1-yl acetate, ethyl formate, (E,Z)-2,4-ethyl decadienoate (pear ester), 35 (Z,Z,E)-7,11,13-hexadecatrienal, heptyl butyrate, isopropyl myristate, lavanulyl senecioate, cis-jasmone, 2-me- thyl 1-butanol, methyl eugenol, methyl jasmonate, (E,Z)-2,13-octadecadien-1-ol, (E,Z)-2,13-octadecadien-1-ol acetate, (E,Z)-3,13-octadecadien-1-ol, R-1-octen-3-ol, pentatermanone, potassium silicate, sorbitol actanoate, (E,Z,Z)-3,8,11-tetradecatrienyl acetate, (Z,E)-9,12-tetradecadien-1-yl acetate, Z-7-tetradecen-2-one, Z-9-tetra- decen-1-yl acetate, Z-11-tetradecenal, Z-11-tetradecen-1-ol, Acacia negra extract, extract of grapefruit seeds 40 and pulp, extract of Chenopodium ambrosiodes, Catnip oil, Neem oil, Quillay extract, Tagetes oil; L5) Microbial pesticides with plant stress reducing, plant growth regulator, plant growth promoting and/or yield enhancing activity: Azospirillum amazonense, A. brasilense, A. lipoferum, A. irakense, A. halopraeferens, Bradyrhizobium spp., B. elkanii, B. japonicum, B. liaoningense, B. lupini, Delftia acidovorans, Glomus intrarad- ices, Mesorhizobium spp., Rhizobium leguminosarum bv. phaseoli, R. I. bv. trifolii, R. I. bv. viciae, R. tropici, 45 Sinorhizobium meliloti; L6) Biochemical pesticides with plant stress reducing, plant growth regulator and/or plant yield enhancing activity: abscisic acid, aluminium silicate (kaolin), 3-decen-2-one, formononetin, genistein, hesperetin, homobrassino- lide, humates, jasmonic acid and its salts or derivatives thereof, lysophosphatidyl ethanolamine, naringenin, polymeric polyhydroxy
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