nanomaterials Article The Mechanism of Low-Temperature Oxidation of Carbon Monoxide by Oxygen over the PdCl2–CuCl2/γ-Al2O3 Nanocatalyst Lev Bruk 1, Denis Titov 1, Alexander Ustyugov 1, Yan Zubavichus 2 ID , Valeriya Chernikova 3, Olga Tkachenko 4, Leonid Kustov 4,*, Vadim Murzin 5, Irina Oshanina 1 and Oleg Temkin 1 1 Moscow Technological University, Institute of Fine Chemical Technology, Department of General Chemical Technology, Moscow 119571, Russia;
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[email protected] (O.T.) 2 National Research Centre “Kurchatov Institute”, Moscow 123182, Russia;
[email protected] 3 Functional Materials Design, Discovery and Development Research Group (FMD3), Advanced Membranes and Porous Materials Center (AMPMC), Division of Physical Sciences and Engineering (PSE), King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Kingdom of Saudi Arabia;
[email protected] 4 N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow 119991, Russia;
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[email protected]; Tel.: +7-499-137-2935 Received: 19 February 2018; Accepted: 30 March 2018; Published: 3 April 2018 Abstract: The state of palladium and copper on the surface of the PdCl2–CuCl2/γ-Al2O3 nanocatalyst for the low-temperature oxidation of CO by molecular oxygen was studied by various spectroscopic techniques. Using X-ray absorption spectroscopy (XAS), powder X-ray diffraction (XRD), and diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), freshly prepared samples of the catalyst were studied.