4 Organic Compounds
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The Evolutionary Story Ahead of Biochemistry
Downloaded from http://cshperspectives.cshlp.org/ on September 24, 2021 - Published by Cold Spring Harbor Laboratory Press The Organic Composition of Carbonaceous Meteorites: The Evolutionary Story Ahead of Biochemistry Sandra Pizzarello1 and Everett Shock1,2 1Department of Chemistry and Biochemistry, Arizona State University, Tempe, Arizona 85287-1604 2School of Earth and Space Exploration, Arizona State University, Tempe, Arizona 85287-1404 Correspondence: [email protected] Carbon-containing meteorites provide a natural sample of the extraterrestrial organic chemistry that occurred in the solar system ahead of life’s origin on the Earth. Analyses of 40 years have shown the organic content of these meteorites to be materials as diverse as kerogen-like macromolecules and simpler soluble compounds such as amino acids and polyols. Many meteoritic molecules have identical counterpart in the biosphere and, in a primitive group of meteorites, represent the majority of their carbon. Most of the compounds in meteorites have isotopic compositions that date their formation to presolar environments and reveal a long and active cosmochemical evolution of the biogenic elements. Whether this evolution resumed on the Earth to foster biogenesis after exogenous deliveryof meteoritic and cometary materials is not known, yet, the selective abundance of biomolecule precur- sors evident in some cosmic environments and the unique L-asymmetry of some meteoritic amino acids are suggestive of their possible contribution to terrestrial molecular evolution. INTRODUCTION that fostered biogenesis. These conditions are entirely unknown because geological and Why Meteorites are Part of the Discourse biological processes of over four billion years about the Origin of Life have long eradicated any traces of early Earth’s he studies of meteorites have long been part chemistry. -
The Chemical Origin of Behavior Is Rooted in Abiogenesis
Life 2012, 2, 313-322; doi:10.3390/life2040313 OPEN ACCESS life ISSN 2075-1729 www.mdpi.com/journal/life Article The Chemical Origin of Behavior is Rooted in Abiogenesis Brian C. Larson, R. Paul Jensen and Niles Lehman * Department of Chemistry, Portland State University, P.O. Box 751, Portland, OR 97207, USA; E-Mails: [email protected] (B.C.L.); [email protected] (R.P.J.) * Author to whom correspondence should be addressed; E-Mail: [email protected]; Tel.: +1-503-725-8769. Received: 6 August 2012; in revised form: 29 September 2012 / Accepted: 2 November 2012 / Published: 7 November 2012 Abstract: We describe the initial realization of behavior in the biosphere, which we term behavioral chemistry. If molecules are complex enough to attain a stochastic element to their structural conformation in such as a way as to radically affect their function in a biological (evolvable) setting, then they have the capacity to behave. This circumstance is described here as behavioral chemistry, unique in its definition from the colloquial chemical behavior. This transition between chemical behavior and behavioral chemistry need be explicit when discussing the root cause of behavior, which itself lies squarely at the origins of life and is the foundation of choice. RNA polymers of sufficient length meet the criteria for behavioral chemistry and therefore are capable of making a choice. Keywords: behavior; chemistry; free will; RNA; origins of life 1. Introduction Behavior is an integral feature of life. Behavior is manifest when a choice is possible, and a living entity responds to its environment in one of multiple possible ways. -
Volatile Organic Compounds, Polycyclic Aromatic Hydrocarbons and Elements in the Air of Ten Urban Homes
AIVC #13,657 J11<loor Air 2001; 11: 49-64 Copyrigfil © Mi111ksg11nl'd 2001 /itlp;//jo11mnls.1111111ksgnard.dlr/i11doornir L'IDOOR AIR Pd1lied in De1111111rk. All rights reserved ISSN 0905-6947 Volatile Organic Compounds, Polycyclic Aromatic Hydrocarbons and Elements in the Air of Ten Urban Homes MICHAEL R. VAN WINKLE1 AND PETER A. SCHEFF2* istics or occupant activities. The data indicate that several pre Abstract Ten homes were monitored at regular intervals from dietor variables, including mothball storage, air freshener use, June 1994 through April 1995 as part of a Public Health Assess and cooking activities, are reasonable predictors for emission ment in Southeast Chicago for exposure to volatile organic com rates of specific pollutants in the homes. pounds (VOCs), polycyclic aromatic hydrocarbons (PAHs), and elements. Simultaneous 24-h indoor and outdoor samples were Received for review 24 March 1999. Accepted for publication 11 March 2000. collected. VOCs were and analyzed using USEPA Method T0-14 © Indoor Air (2001) with Selected Ion Monitoring Mass Spectrometry (GC/MS). PAHs were analyzed using USEPA Method T0-13 with GC/MS. Elements were collected on quartz fiber filters and analyzed by Inductively Coupled Argon Plasma (ICP) spectroscopy or Graph ite Furnace Atomic Absorption (GFA A). Continuous measure Introduction ments of C02 and temperature were recorded for each indoor Exposure to indoor airborne pollutants is a function of sample. Twenty-four h total C02 emissions were determined from occupancy and estimated gas stove usage and were moder many variables, including pollutant infiltration, exfil 2 ately correlated (R =0.19) with 24 h average indoor C02 concen tration, deposition, resuspension, filtration, and gener trations. -
Phosphorus and Sulfur Cosmochemistry: Implications for the Origins of Life
Phosphorus and Sulfur Cosmochemistry: Implications for the Origins of Life Item Type text; Electronic Dissertation Authors Pasek, Matthew Adam Publisher The University of Arizona. Rights Copyright © is held by the author. Digital access to this material is made possible by the University Libraries, University of Arizona. Further transmission, reproduction or presentation (such as public display or performance) of protected items is prohibited except with permission of the author. Download date 07/10/2021 06:16:37 Link to Item http://hdl.handle.net/10150/194288 PHOSPHORUS AND SULFUR COSMOCHEMISTRY: IMPLICATIONS FOR THE ORIGINS OF LIFE by Matthew Adam Pasek ________________________ A Dissertation Submitted to the Faculty of the DEPARTMENT OF PLANETARY SCIENCE In Partial Fulfillment of the Requirements For the Degree of DOCTOR OF PHILOSOPHY In the Graduate College UNIVERSITY OF ARIZONA 2 0 0 6 2 THE UNIVERSITY OF ARIZONA GRADUATE COLLEGE As members of the Dissertation Committee, we certify that we have read the dissertation prepared by Matthew Adam Pasek entitled Phosphorus and Sulfur Cosmochemistry: Implications for the Origins of Life and recommend that it be accepted as fulfilling the dissertation requirement for the Degree of Doctor of Philosophy _______________________________________________________________________ Date: 04/11/2006 Dante Lauretta _______________________________________________________________________ Date: 04/11/2006 Timothy Swindle _______________________________________________________________________ Date: 04/11/2006 -
PATENT OFFICE 2,632,026 OXDATION OFAROMATIC HYDROCARBONS Joshua C
Patented Mar. 17, 1953 2,632,026 UNITED STATES PATENT OFFICE 2,632,026 OXDATION OFAROMATIC HYDROCARBONS Joshua C. Conner, Jr., Wilmington, Dei, assignor to Hercules Powder Company, Wilmington, Dei, a corporation of Delaware No Drawing. Application February 18, 1950, Serial No. 145,091 9 Cairms. (C. 260-610) 1. 2 This invention relates to a process for oxidizing of cumene at a temperature in excess of 20° C. an alkyl-substituted aromatic organic compound while simultaneously passing a stream of an having the structural formula, Oxygen-containing gas containing gaseous am Rt H monia, in catalytic amounts through the reac N / tion mixture. The reaction is continued until standard analytical data, such as refractive in R / Air dex, indicate the conversion of from about 10% to about 70% of the original cumene to oxygen in which R1 and R2 represent alkyl groups and ated products. The reaction mixture may then Ar represents either an aryl group or an alkaryl 0. be treated in accordance with known techniques group. More particularly, the invention relates to obtain a product containing preponderant to a process for the oxidation of compounds Such amounts of a,c-dimethylbenzyl hydroperoxide. as cumene in the liquid phase by naeans of no Having thus described the invention, the foll lecular. Oxygen. lowing examples are specific embodiments there It is known that cunene, for example, may be 5 of. All parts are parts by weight unless otherwise oxidized in the liquid phase by means of molec indicated. ular oxygen, but none of the processes hereto EXAMPLE 1. fore disclosed for the oxidation of cumene have resulted in substantial yields of a,c-dimethyl A glass reaction vessel equipped with a reflux benzyl hydroperoxide. -