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Lecture 4 2018/2019 • Hydrostatic Hydrostatic pressure – p = ρgh 1 atm=760 mmHg (torr) SI 1 atm= 101 325 Pa

푝푉 = 푛푅푇

1 푚표푙 8,314퐽푚표푙−1퐾−1273,15퐾 푝 = 0,02241푚3

푝 = 101 325 푃푎 • Archimedes’ principle – buoyant force

Any object, wholly or partially immersed in a fluid, is buoyed up by a force equal to the weight of the fluid displaced by the object. Archimedes of Syracuse FB=h2ρgA-h1ρgA=(h2-h1)A ρg=V ρg=mg Density, pycnometry ρ = m/V [ρ] = 1 kg/m3

Vp – known or measured with a known liquid

solid 1. weight of solid material 2. volume of solid material (weight of empty pycnometer, pycnometer+ solid, pycnometer+ water-pycnometer+water+ solid)

Mohr-Westphal balances Bouyancy • Pascals law

When additional pressure exerted to an confined liquid, the pressure is transmitted equally to all parts of the liquid.

- reason incompressibility of liquids - consequence hydraulic press (hydraulic jack) 푝1 = 푝2

퐹1 퐹2 = 푆1 푆2

푆2 퐹2 = 퐹1 푆1 hydraulic ratio

m1=90 kg m2=5000 kg S1=? 2 S2=π r2 F= mg r1=0.134 m d1=0.268 m • Hydrodynamics Ideal liquid – incompressible, no , real liquids – little compressible, viscous

Ideal liquids 3 -1 -1 Volume-, mass- rate of flow – QV [m s ], Qm [kgs ]

incompressibility => Sv = constant ρSv=mv = constant V = Svt m=ρSvt Kinetic energy

Potential energy

Pressure energy Steady state – non-viscous, incompressible dE = 0 => E=constant Bernoulli’s equation 1 휌푣2푑푉 + 휌𝑔ℎ푑푉 + 푝푑푉 = 푐표푛푠푡푎푛푡 2

1 2 휌푣 + 휌𝑔ℎ + 푝 = 푐표푛푠푡푎푛푡 Daniel Bernoulli 2 (1700-1782) consequencies • Torricelli’s theorem

Evangelista Torricelli (1608-1647)

h1

v2 Viscosity-  resistance to flow  material constant, decreases with increasing temperature [ η] =1 Pa s dynamic viscosity

푑푣푥 퐹 = 푆휂 = 푆휏 푑푦 τ – shear stress kinematic viscosity 휂 휐 = [ν]=1 m2s-1 휚 Fluidity 1 휑 = [ϕ]= 1Pa-1s-1 휂 Real liquids - Stokes’ law (falling-sphere viscosimeter) Laminar flow, uniform spherical, smooth particles

drag force gravity bouyancy in equilibrium • Settling velocity in gravitational force

sedimentation of emulsions – stability of emulsions

2 2 2 • Settling velocity in centrifuge af=ω R=4π f R • Laminar and turbulent flow

Reynold´s number – ratio of inertial and viscous forces laminar flow Re<2000 휚푣푙 푣푙 푅푒 = = turbulent flow Re>2000 휂 휐 (fully RE> 4000) Korotkoff sounds Real liquid – little -compressible fluid with viscous stress forces, laminar flow flow volume rate resistance to flow

Poiseuille’s law

Qv

Qv A 16 % decrease in radius will halve the volume flow rate! • 16% occlusion –> r2=0.84r1

Δp1=Δp2=120 mmHg 3 Qv1=100 cm /min

Qv2=? Thermal physics Temperature – T (t) – Intrinsic property – independent on the amount of the material

temperarure = average kinetic energy of molecules

[T] = 1 K = 1oC T = t + 273.15 oC Measurement of temperature properties of materials varying with temperature • volume

• electrical properties

• pressure (gauges thermometers)

• IR radiation…. • Temperature scales – [T] = 1 K – [t] = 1 oC

0 oC = 273.15 K 100 oC = 373.15 K water freezing-boiling

o T1 K = (t1 + 273.15 ) C o T2 K = (t2 + 273.15 ) C o (T1 - T2) K = (t2 - t2 ) C

T=0K => p=0, V=0 impossible to reach • Thermal expansion of materials α – linear (area, volume ) thermal expanson coefficient [α]=K-1

• Density variation with temperature

Density decreases with increasing temperature! • Anomaly of water density 0 3.98oC β>0, density decreases with t “normal” behaviour Summary

Hydrostatic pressure 푝ℎ푦푑푟 = ℎ휚𝑔

Archimedes’ principle 퐹 = 푉푆(휚푠 − 휚푙 )𝑔 퐹 퐹 ’s law- hydraulic press 1 = 2 푆1 푆2 푑푣 휂 Viscosity 퐹 = 휂 푆 푥 휐 = 푑푦 휚

Hydrodynamics 푄푣 = 푆푣 푄푚 = 푆푣휚 1 2 Bernoulli’s equation 2 휌푣 + 휌𝑔ℎ + 푝 = 푐표푛푠푡푎푛푡 Torricelli’s theorem 푣 = 2𝑔ℎ

Stokes law 퐹푑 = 6휋휂푟푣 2 푟2 휚 −휚 𝑔 2 푟2 휚 −휚 휔 2푥 Sedimentation 푣 = 푠 푙 푣 = 푠 푙 9 휂 9 휂 푣휚푙 Reynold’s number 푅푒 = 휂 휋푟4Δ푝 Poiseuille’s law 푉 = 푡 8휂푙