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Modern Problems of Molecular Physics Selected Reviews from the 7th International Conference “Physics of Liquid Matter: Modern Problems”, Kyiv, Ukraine, May 27–31, 2016

123 Editors Leonid A. Bulavin Alexander V. Chalyi Department of Molecular Department of Medical Physics and Biological Physics Taras Shevchenko National Bogomolets National University of Kyiv Medical University Kyiv Kyiv Ukraine Ukraine

ISSN 0930-8989 ISSN 1867-4941 (electronic) Springer Proceedings in Physics ISBN 978-3-319-61108-2 ISBN 978-3-319-61109-9 (eBook) https://doi.org/10.1007/978-3-319-61109-9

Library of Congress Control Number: 2017958837

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This Springer imprint is published by Springer Nature The registered company is Springer International Publishing AG The registered company address is: Gewerbestrasse 11, 6330 Cham, Switzerland Preface

Once upon a time, about 30 years ago, at the summer school on theoretical physics, lying on the beach of a gentle Black Sea in the sport camp of the Odessa University together with the well-known throughout the physical world scientists Valentin Pokrovsky and Alexander Patashinskii, who wrote a famous book “Fluctuation Theory of Phase Transitions” (Pergamon Press, Oxford, 1979), one of the editors (A.Ch.) of the Springer book “Modern Problems of Molecular Physics: Selected Reviews” heard from them such words: “Our great teacher Dau told us that there is nothing to consider the density of a liquid is different from the unit!”. Should we explain the meaning of this sacramental phrase for respected readers, which seems to be an “error” by the Nobel Prize Laureate Lev Landau? In fact, a genius physicist L. D. Landau did not make mistakes in his physical works. Indeed, the density of the most common in nature, simultaneously so unique and myste- rious, liquid water is equal to 1 in grams per cubic centimeter under normal con- ditions at room temperature and at atmospheric pressure. Then, what is a reason to use the word “error” even in quotes? As is known, Landau did not consider the physics of the liquid state of matter was equally interesting and promising area for building a successful physical theory, as, say, the solid-state physics or the physics of elementary particles. There is a well-known statement: “Theoretical physics is the physics of limiting cases”. In this sense, it is difficult to introduce small parameters for liquids, and the water density is not such a small parameter. It is interesting to note that Landau made many of his outstanding work in Ukraine, being a Head of the Theoretical Physics Department at the Kharkov Institute of Physics and Technology. Here, in 1934 at the age of 26, he became a Doctor of Physical and Mathematical Sciences, and a year later received the title of Professor. Thus, the theoretical physics in Ukraine (and not only in Ukraine, and not only the theoretical physics) has received a tremendous impact for its further development, thanks to the Kharkov period of Landau scientific activities. Unfortunately, the great physicist died very early-at the age of 60, in April 1968. One may say, paraphrasing one of our bards of that time: “60 is the time of achievements! 60 is the age of the tops!…60 seems like a lot, 60 is still not enough!”.

v vi Preface

We are sure that L. D. Landau, who received the Nobel Prize on physics in November 1962 for his outstanding work on superfluidity of quantum liquids, or more precisely, “for his pioneering theories for condensed matter, especially liquid helium”, could make much more enlightening discoveries, including the field of classical liquids, did not be that fatal car accident on January 7, 1962. In more than half a century since that time, the physics of liquids has leaped forward. It is sufficient to list the main directions of development of these advanced knowledge areas: nanophysics of liquid systems, medical applications of liquids; water and aqueous solutions in normal and metastable state; ionic and ionic-electronic liquids; magnetic liquid systems; phase transitions and critical phenomena; surface phenomena and liquids in confined geometry; quantum liquids; radiation physics of liquids; etc. All these areas were presented at the 7th International Conference “Physics of Liquid Matter: Modern Problems” (PLMMP-2016) which was held during May 27–31, 2016, in Kyiv, Ukraine. The PLMMP-2016 International Conference was organized by the Taras Shevchenko National University of Kyiv and Bogolyubov Institute for Theoretical Physics of the National Academy of Sciences of Ukraine. The scientific program of the conference comprised invited lectures, oral presen- tations, and posters contributed by hundreds of scientists from many countries all over the world (Austria, Brazil, France, Germany, Great Britain, Hungary, Italy, Poland, Portugal, Romania, Russia, Slovakia, Turkey, Ukraine, and United States of America). Of course, the realization of the PLMMP-2016 International Conference is an important event in the scientific life of Ukraine, whose role cannot be overesti- mated. After all, the state of science and education largely determines the economic independence of any country and its ability to provide adequate answers to the challenges of modern civilization processes. The book “Modern Problems of Molecular Physics: Selected Reviews” repre- sents the collection of selected plenary and invited lectures of the PLMMP-2016 Conference and is aimed at elucidation the most important and modern aspects of the molecular physics, condensed and soft matter physics. The unification of experimental, theoretical, and computational methods allow to receive significant results in such four directions: (a) Liquid Systems with Nanoparticles, (b) Ionic and Ionic-Electronic Liquids, (c) Magnetic Liquid Systems, and (d) Phase Transitions and Critical Phenomena. This book is written for the scientific researchers as well as for teachers, engineers, students, and all those readers interested in modern problems of the physical sciences. On behalf of the Organizing Committee of the PLMMP-2016 Conference and editors of the book “Modern Problems of Molecular Physics: Selected Reviews”, we would like to thank all the plenary and invited speakers as well as all the participants for their valuable contributions and brainstorming discussions, the International Advisory Board and Local Organizing Committee for assistance in Preface vii organizing and realization the scientific program of the PLMMP-2016 Conference, and the Springer International Publishing AG Switzerland for helping to organize the publication of the book “Modern Problems of Molecular Physics: Selected Reviews” in Springer Proceedings in Physics.

Kyiv, Ukraine Leonid A. Bulavin Alexander V. Chalyi Contents

Part I Liquid Systems with Nanoparticles

1 Self-Organization of Pristine C60 Fullerene and its Complexes with Chemotherapy Drugs in Aqueous Solution as Promising Anticancer Agents ...... 3 Leonid A. Bulavin, Yuriy Prylutskyy, Olena Kyzyma, Maxim Evstigneev, Uwe Ritter and Peter Scharff 2 Colloid Nanoparticles and Carbon Nanotubes. What Can We Learn About Their Biomedical Application From Molecular Dynamics Simulations? ...... 23 Tomasz Panczyk, Lukasz Konczak and Pawel Wolski 3 Phase Behavior of Liquids Embedded with Graphene Genealogic Tree Nanoparticles ...... 39 Sergey Artemenko, Victoria Karnaukh and Victor Mazur

Part II Ionic and Ionic-Electronic Liquids 4 Peculiarities of NMR Relaxation in Ionic Liquids: Difficulties in Interpretation and Novel Possibilities ...... 51 Vladimir V. Matveev and Konstantin V. Tyutyukin 5 Transport Properties and Ion Aggregation in Mixtures of Room Temperature Ionic Liquids with Aprotic Dipolar Solvents ...... 67 Oleg N. Kalugin, Anastasiia V. Riabchunova, Iuliia V. Voroshylova, Vitaly V. Chaban, Bogdan A. Marekha, Volodymyr A. Koverga and Abdenacer Idrissi 6 Microsegregation in Ion-Electron Liquids: Molten Metals and Alloys ...... 111 Yuriy Plevachuk, Vasyl Sklyarchuk and Andriy Yakymovych

ix x Contents

7Influence of the Nature of Counterions and Solvent on the Structure of PSS Solutions ...... 133 Georgiy Smolyakov, Jean-Marie Catala, Nataliya Kutsevol and Michel Rawiso

Part III Magnetic Liquid Systems 8 Magnetic Fluids and Their Complex Systems ...... 151 Peter Kopcansky, Milan Timko, Martina Koneracka, Vlasta Zavisova, Martina Kubovcikova, Matus Molcan, Lucia Balejcikova, Natalia Tomasovicova, Michal Rajnak and Veronika Gdovinova 9 Structure, Dynamics, and Thermodynamics of Ferrofluids ...... 185 Philip J. Camp 10 Magnetic Fluids: Structural Aspects by Scattering Techniques .... 205 V. I. Petrenko, A. V. Nagornyi, I. V. Gapon, L. Vekas, V. M. Garamus, L. Almasy, A. V. Feoktystov and M. V. Avdeev

Part IV Phase Transitions and Critical Phenomena 11 Phase Transitions in a Continuum Curie-Weiss System: A Quantitative Analysis ...... 229 Yuri Kozitsky, Mykhailo Kozlovskii and Oksana Dobush 12 Dynamic Anomalies in Confined Supercooled Water and Bulk Fluids ...... 253 Alexander V. Chalyi 13 The Polycluster Theory for the Structure of Glasses: Evidence from Low Temperature Physics ...... 291 Giancarlo Jug 14 Relaxation and Vitrification Processes of Disordered Iron Based Systems ...... 331 Leonid A. Bulavin, Volodymyr Karbivskyy, Viktor Artemyuk and Love Karbivska Index ...... 373 Contributors

L. Almasy Neutron Spectroscopy Department, Wigner Research Centre for Phy- sics, Budapest, Hungary; State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials, South-West University of Science and Technology, Mianyang, China Sergey Artemenko Institute of Refrigeration, Cryotechnologies, and Eco-Power Engineering, Odessa National Academy of Food Technologies, Odessa, Ukraine Viktor Artemyuk G.V. Kurdymov Institute for Metal Physics of the NAS of Ukraine, Kiev, Ukraine M. V. Avdeev Frank Laboratory of Neutron Physics, Joint Institute for Nuclear Research, Dubna, Moscow Reg., Russia Lucia Balejcikova Institute of Experimental Physics SAS, Košice, Slovakia Leonid A. Bulavin Faculty of Physics, Taras Shevchenko National University of Kyiv, Kiev, Ukraine Philip J. Camp School of Chemistry, University of Edinburgh, David Brewster Road, Edinburgh, Scotland; Institute of Natural Sciences and Mathematics, Ural Federal University, Ekaterinburg, Russia Jean-Marie Catala Institut Charles Sadron (CNRS-UdS), Strasbourg, France Vitaly V. Chaban Instituto de Ciência e Tecnologia, Universidade Federal de São Paulo, São José dos Campos, SP, Brazil Alexander V. Chalyi Department of Medical and Biological Physics, Bogomolets National Medical University, Kiev, Ukraine Oksana Dobush Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, Lviv, Ukraine Maxim Evstigneev Belgorod State University, Belgorod, Russia

xi xii Contributors

A. V. Feoktystov Jülich Centre for Neutron Science (JCNS), Heinz Maier-Leibnitz Zentrum (MLZ), Garching, Germany I. V. Gapon Frank Laboratory of Neutron Physics, Joint Institute for Nuclear Research, Dubna, Moscow Reg., Russia; Faculty of Physics, Taras Shevchenko National University of Kyiv, Kiev, Ukraine V. M. Garamus Helmholtz-Zentrum Geesthacht: Centre for Materials and Coastal Research, Geesthacht, Germany Veronika Gdovinova Institute of Experimental Physics SAS, Košice, Slovakia Abdenacer Idrissi University of Lille, Science and Technology, LASIR (UMR CNRS A8516), Villeneuve d’Ascq Cedex, France Giancarlo Jug Dipartimento di Scienza ed Alta Tecnologia and To.Sca.Lab, Università dell’Insubria, Como, Italy; INFN – Sezione di Pavia, Pavia, Italy Oleg N. Kalugin Department of Inorganic Chemistry, V. N. Karazin Kharkiv National University, Kharkiv, Ukraine Love Karbivska G.V. Kurdymov Institute for Metal Physics of the NAS of Ukraine, Kiev, Ukraine Volodymyr Karbivskyy G.V. Kurdymov Institute for Metal Physics of the NAS of Ukraine, Kiev, Ukraine Victoria Karnaukh Faculty of Engineering, Department of Food Engineering, Akdeniz University, Antalya, Turkey Lukasz Konczak Jerzy Haber Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, Krakow, Poland Martina Koneracka Institute of Experimental Physics SAS, Košice, Slovakia Peter Kopcansky Institute of Experimental Physics SAS, Košice, Slovakia Volodymyr A. Koverga University of Lille, Science and Technology, LASIR (UMR CNRS A8516), Villeneuve d’Ascq Cedex, France Yuri Kozitsky Maria Curie-Skłodowska University, Lublin, Poland Mykhailo Kozlovskii Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, Lviv, Ukraine Martina Kubovcikova Institute of Experimental Physics SAS, Košice, Slovakia Nataliya Kutsevol National Taras Shevchenko University of Kyiv, Kiev, Ukraine Olena Kyzyma Faculty of Physics, Taras Shevchenko National University of Kyiv, Kyiv, Ukraine; Joint Institute for Nuclear Research, Dubna, Moscow reg., Russia Bogdan A. Marekha Normandie University, Caen, France Contributors xiii

Vladimir V. Matveev St. Petersburg State University, Saint Petersburg, Russia Victor Mazur Institute of Refrigeration, Cryotechnologies, and Eco-Power Engineering, Odessa National Academy of Food Technologies, Odessa, Ukraine Matus Molcan Institute of Experimental Physics SAS, Košice, Slovakia A. V. Nagornyi Frank Laboratory of Neutron Physics, Joint Institute for Nuclear Research, Joliot-Curie 6, 141980 Dubna, Moscow Reg., Russia; Faculty of Physics, Taras Shevchenko National University of Kyiv, Kiev, Ukraine Tomasz Panczyk Jerzy Haber Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, Krakow, Poland V. I. Petrenko Frank Laboratory of Neutron Physics, Joint Institute for Nuclear Research, Dubna, Moscow Reg., Russia; Faculty of Physics, Taras Shevchenko National University of Kyiv, Kiev, Ukraine Yuriy Plevachuk Department of Metal Physics, Ivan Franko National University of Lviv, Lviv, Ukraine Yuriy Prylutskyy ESC “Institute of Biology and Medicine”, Department of Biophysics and Medical Informatics, Taras Shevchenko National University of Kyiv, Kyiv, Ukraine Michal Rajnak Institute of Experimental Physics SAS, Košice, Slovakia; Faculty of Electrical Engineering and Informatics, Technical University of Košice, Košice, Slovakia Michel Rawiso Institut Charles Sadron (CNRS-UdS), Strasbourg, France Anastasiia V. Riabchunova Department of Inorganic Chemistry, V. N. Karazin Kharkiv National University, Kharkiv, Ukraine Uwe Ritter Institute of Chemistry and Biotechnology, Technical University of Ilmenau, Ilmenau, Germany Peter Scharff Institute of Chemistry and Biotechnology, Technical University of Ilmenau, Ilmenau, Germany Vasyl Sklyarchuk Department of Metal Physics, Ivan Franko National University of Lviv, Lviv, Ukraine Georgiy Smolyakov Institut Charles Sadron (CNRS-UdS), Strasbourg, France Milan Timko Institute of Experimental Physics SAS, Košice, Slovakia Natalia Tomasovicova Institute of Experimental Physics SAS, Košice, Slovakia Konstantin V. Tyutyukin St. Petersburg State University, Saint Petersburg, Russia L. Vekas Center for Fundamental and Advanced Technical Research, Romanian Academy-Timisoara Branch, Timisoara, Romania xiv Contributors

Iuliia V. Voroshylova CIQ(UP)/REQUIMTE@LAQV, Departamento de Quí- mica e Bioquímica, Faculdade de Ciências, Universidade do Porto, Porto, Portugal Pawel Wolski Jerzy Haber Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, Krakow, Poland Andriy Yakymovych Department of Metal Physics, Ivan Franko National University of Lviv, Lviv, Ukraine; Department of Inorganic Chemistry—Functional Materials, Faculty of Chemistry, University of Vienna, Vienna, Austria Vlasta Zavisova Institute of Experimental Physics SAS, Košice, Slovakia