ABSTRACT CROSBY, LYNN MARIE. Studies on Mechanisms Of
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NACE Bromine Chemistry Review Paper
25 YEARS OF BROMINE CHEMISTRY IN INDUSTRIAL WATER SYSTEMS: A REVIEW Christopher J. Nalepa Albemarle Corporation P.O. Box 14799 Baton Rouge, LA 70898 ABSTRACT Bromine chemistry is used to great advantage in nature for fouling control by a number of sessile marine organisms such as sponges, seaweeds, and bryozoans. Such organisms produce small quantities of brominated organic compounds that effectively help keep their surfaces clean of problem bacteria, fungi, and algae. For over two decades, bromine chemistry has been used to similar advantage in the treatment of industrial water systems. The past several years in particular has seen the development of several diverse bromine product forms – one-drum stabilized bromine liquids, all-bromine hydantoin solids, and pumpable gels. The purpose of this paper is to review the development of bromine chemistry in industrial water treatment, discuss characteristics of the new product forms, and speculate on future developments. Keywords: Oxidizing biocide, bleach, bromine, bromine chemistry, sodium hypobromite, activated sodium bromide, Bromochlorodimethylhydantoin, Bromochloromethyethylhydantoin, Dibromodi- methylhydantoin,, BCDMH, BCMEH, DBDMH, stabilized bromine chloride, stabilized hypobromite INTRODUCTION Sessile marine organisms generate metabolites to ward off predators and deter attachment of potential micro- and macrofoulants. Sponges, algae, and bryozoans for example, produce a rich variety of bromine-containing compounds that exhibit antifoulant properties (Fig. 1).1,2,3 Scientists are actively studying these organisms to understand how they maintain surfaces that are relatively clean and slime- free.4 Brominated furanones isolated from the red algae Delisea pulchra, for example, have been found to interfere with the chemical signals (acylated homoserine lactones) that bacteria use to communicate with one another to produce biofilms.5,6 This work may eventually lead to more effective control of microorganisms in a number of industries such as industrial water treatment, oil and gas production, health care, etc. -
THE MONATOMIC IONS! 1. What Is the Formula for Silver? Ag 2. What Is
Name: ______________________________ THE MONATOMIC IONS! 1. What is the formula for silver? Ag+ 22. What is the formula for cobalt (II)? Co2+ 2. What is the formula for cadmium? Cd2+ 23. What is the formula for chromium (II)? Cr2+ 3. What is the formula for manganese (II)? Mn2+ 24. What is the formula for copper (II)? Cu2+ 4. What is the formula for nickel (II)? Ni2+ 25. What is the formula for tin (IV)? Sn4+ 5. What is the formula for chromous? Cr2+ 26. What is the formula for lead (IV)? Pb4+ 6. What is the formula for zinc? Zn2+ 27. What is the formula for iron (III)? Fe3+ 2+ 2+ 7. What is the formula for cobaltous? Co 28. What is the formula for mercury (I)? Hg2 8. What is the formula for cuprous? Cu+ 29. What is the formula for lead (II)? Pb2+ 9. What is the formula for ferrous? Fe2+ 30. What is the formula for mercury (II)? Hg2+ 2+ 2+ 10. What is the formula for mercurous? Hg2 31. What is the formula for iron (II)? Fe 11. What is the formula for stannous? Sn2+ 32. What is the formula for copper (I)? Cu+ 12. What is the formula for plumbous? Pb2+ 33. What is the formula for tin (II)? Sn2+ 13. What is the formula for chromic? Cr3+ 34. What is the formula for fluoride? F- 14. What is the formula for cobaltic? Co3+ 35. What is the formula for chloride? Cl- 15. What is the formula for cupric? Cu2+ 36. What is the formula for hydride? H- 16. -
Safety Data Sheet
SAFETY DATA SHEET Issue Date 13-Apr-2017 Revision Date 13-Apr-2017 Version 2.1 Page 1 / 17 1. IDENTIFICATION Product identifier Product Name Chromium 1 Reagent Other means of identification Product Code(s) 204399 Safety data sheet number M00033 UN/ID no UN3262 Recommended use of the chemical and restrictions on use Recommended Use Laboratory reagent. Determination of chromium. Uses advised against None. Restrictions on use None. Details of the supplier of the safety data sheet Manufacturer Address Hach Company P.O.Box 389 Loveland, CO 80539 USA (970) 669-3050 Emergency telephone number (303) 623-5716 - 24 Hour Service (515)232-2533 - 8am - 4pm CST 2. HAZARDS IDENTIFICATION Classification Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Oral Category 4 Acute toxicity - Inhalation (Dusts/Mists) Category 4 Skin corrosion/irritation Category 1 Sub-category A Serious eye damage/eye irritation Category 1 Hazards not otherwise classified (HNOC) Not applicable Label elements Signal word - Danger Obtained by Global Safety Management, www.globalsafetynet.com, (877) 683-7460 Product Code(s) 204399 Product Name Chromium 1 Reagent Issue Date 13-Apr-2017 Revision Date 13-Apr-2017 Version 2.1 Page 2 / 17 Hazard statements H302 - Harmful if swallowed H314 - Causes severe skin burns and eye damage H332 - Harmful if inhaled Precautionary statements P264 - Wash face, hands and any exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P260 - Do not breathe dust/fume/gas/mist/vapors/spray P280 - Wear protective gloves/protective clothing/eye protection/face protection P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P312 - Call a POISON CENTER or doctor/physician if you feel unwell P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. -
Nomenclature of Inorganic Chemistry (IUPAC Recommendations 2005)
NOMENCLATURE OF INORGANIC CHEMISTRY IUPAC Recommendations 2005 IUPAC Periodic Table of the Elements 118 1 2 21314151617 H He 3 4 5 6 7 8 9 10 Li Be B C N O F Ne 11 12 13 14 15 16 17 18 3456 78910 11 12 Na Mg Al Si P S Cl Ar 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe 55 56 * 57− 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 Cs Ba lanthanoids Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn 87 88 ‡ 89− 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 Fr Ra actinoids Rf Db Sg Bh Hs Mt Ds Rg Uub Uut Uuq Uup Uuh Uus Uuo * 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu ‡ 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr International Union of Pure and Applied Chemistry Nomenclature of Inorganic Chemistry IUPAC RECOMMENDATIONS 2005 Issued by the Division of Chemical Nomenclature and Structure Representation in collaboration with the Division of Inorganic Chemistry Prepared for publication by Neil G. -
Benefit & Cost Analysis for Proposed Revisions to Effluent Guidelines For
United States Office of Water EPA-821-R-19-011 Environmental Protection Washington, DC 20460 November 1, 2019 Agency Benefit and Cost Analysis for Proposed Revisions to the Effluent Limitations Guidelines and Standards for the Steam Electric Power Generating Point Source Category Benefit and Cost Analysis for Proposed Revisions to the Effluent Limitations Guidelines and Standards for the Steam Electric Power Generating Point Source Category EPA-821-R-19-011 November 2019 U.S. Environmental Protection Agency Office of Water (4303T) Engineering and Analysis Division 1200 Pennsylvania Avenue, NW Washington, DC 20460 BCA for Proposed Revisions to the Steam Electric Power Generating ELGs Acknowledgements and Disclaimer This report was prepared by the U.S. Environmental Protection Agency. Neither the United States Government nor any of its employees, contractors, subcontractors, or their employees make any warrant, expressed or implied, or assume any legal liability or responsibility for any third party’s use of or the results of such use of any information, apparatus, product, or process discussed in this report, or represents that its use by such party would not infringe on privately owned rights. BCA for Proposed Revisions to the Steam Electric Power Generating ELGs Table of Contents Table of Contents Table of Contents ................................................................................................................................................ i List of Figures ................................................................................................................................................... -
Preparation for AP Chemistry Period Date IONSLISTBYNAME
MHS • AP Chemistry Name Preparation for AP Chemistry Period Date IONSLISTBYNAME − − 2− Acetate C2H3O2 or Hydrogen sulfate, HSO4 Oxide O − CH3COO bisulfate 3+ + − Aluminum Al Hydronium H3O Perbromate BrO4 + − − Ammonium NH4 Hydroxide OH Perchlorate ClO4 2+ − − − Barium Ba Hypobromite BrO or OBr Periodate IO4 − − − − Bromate BrO3 Hypochlorite ClO or OCl Permanganate MnO4 − − − 2− Bromide Br Hypoiodite IO or OI Peroxide O2 − − 3− Bromite BrO2 Iodate IO3 Phosphate PO4 2+ − 3− Calcium Ca Iodide I Phosphite PO3 2− − + Carbonate CO3 Iodite IO2 Potassium K − 2+ + Chlorate ClO3 Iron (II), ferrous Fe Silver Ag Chloride Cl− Iron (III), ferric Fe3+ Sodium Na+ − 2+ 2+ Chlorite ClO2 Lead (II), plumbous Pb Strontium Sr 2− 4+ 2− Chromate CrO4 Lead (IV), plumbic Pb Sulfate SO4 Copper (I), cuprous Cu+ Lithium Li+ Sulfide S2− 2+ 2+ 2− Copper (II), cupric Cu Magnesium Mg Sulfite SO3 − 2+ − Cyanide CN Mercury (I), mercurous Hg2 Thiocyanate SCN 2− 2+ 2− Dichromate Cr2O7 Mercury (II), mercuric Hg Thiosulfate S2O3 Fluoride F− Nickel Ni2+ Tin (II), stannous Sn2+ + − 4+ Hydrogen H Nitrate NO3 Tin (IV), stannic Sn − − 2+ Hydrogen carbonate, HCO3 Nitrite NO2 Zinc Zn bicarbonate, MHS• AP Chemistry Name Preparation for AP Chemistry Period Date IONSLISTBYSET Set 1 Aluminum Al3+ Fluoride F− Oxide O2− Barium Ba2+ Hydrogen H+ Potassium K+ Bromide Br− Iodide I− Sodium Na+ Calcium Ca2+ Lithium Li+ Strontium Sr2+ Chloride Cl− Magnesium Mg2+ Sulfide S2− Set 2 + 3+ 2+ Ammonium NH4 Iron (III), ferric Fe Nickel Ni Copper (I), cuprous Cu+ Lead (II), plumbous Pb2+ Silver Ag+ Copper -
TOXICOLOGICAL REVIEW of BROMATE (CAS No
EPA/635/R-01/002 TOXICOLOGICAL REVIEW OF BROMATE (CAS No. 15541-45-4) In Support of Summary Information on the Integrated Risk Information System (IRIS) March 2001 U.S. Environmental Protection Agency Washington, DC DISCLAIMER This document has been reviewed in accordance with U.S. Environmental Protection Agency policy. Mention of trade names or commercial products does not constitute endorsement or recommendation for use. Note: This document may undergo revisions in the future. The most up-to-date version will be made available electronically via the IRIS Home Page at http://www.epa.gov/iris. ii CONTENTS—TOXICOLOGICAL REVIEW OF BROMATE (CAS No. 15541-45-4) FOREWORD .................................................................v AUTHORS, CONTRIBUTORS, AND REVIEWERS ................................ vi 1. INTRODUCTION ..........................................................1 2. CHEMICAL AND PHYSICAL PROPERTIES RELEVANT TO ASSESSMENTS ....... 2 3. TOXICOKINETICS RELEVANT TO ASSESSMENTS ............................4 3.1. ABSORPTION .......................................................4 3.2. DISTRIBUTION ......................................................4 3.3. METABOLISM .......................................................5 3.4. EXCRETION ........................................................5 3.5. BIOACCUMULATION AND RETENTION ................................6 3.6. SUMMARY .........................................................6 4. HAZARD IDENTIFICATION ................................................6 4.1. STUDIES IN HUMANS—EPIDEMIOLOGY, -
Common Polyatomic Ions
Common Polyatomic Ions (Alphabetical order by ion name) NOTE: -ite ending means one less oxygen than the -ate form. Ion Ion Ion Ion Ion Name Ion Name Ion Name Ion Name Symbol Symbol Symbol Symbol - CH3CO2 2- - - Acetate or Dichromate Cr2O7 Hypobromite BrO Perrhenate ReO4 - CH3COO + Dihydrogen - - 3- Ammonium NH4 H2PO4 Hypochlorite ClO Phosphate PO4 Phosphate 3- Dihydrogen - - 3- Arsenate AsO4 H2PO3 Hypoiodite IO Phosphite PO3 Phosphite 3- 2- - 2- Arsenite AsO3 Dithionate S2O6 Iodate IO3 Plumbate PbO3 - 2- - 2- Azide N3 Dithionite S2O4 Iodite IO2 Plumbite PbO2 2- 3- - 2- Borate BO3 Ferricyanide Fe(CN)6 Isocyanate NCO Rhenate ReO4 - 4- 2- 2- Bromate BrO3 Ferrocyanide Fe(CN)6 Manganate MnO4 Selenate SeO4 - - - 2- Bromite BrO2 Fulminate CNO Nitrate NO3 Selenite SeO3 2- - - 2- Carbonate CO3 Hydrazide N2H3 Nitrite NO2 Silicate SiO3 - Hydrogen 2- 2- 2- Chlorate ClO3 HAsO4 Oxalate C2O4 Stannate SnO3 arsenate - Hydrogen - - 2- Chlorite ClO2 HCO3 Ozonide O3 Stannite SnO2 carbonate 2- Hydrogen 2- - 2- Chromate CrO4 HPO4 Perbromate BrO4 Sulfate SO4 Phosphate - Hydrogen 2- - 2- Chromite CrO2 HPO3 Perchlorate ClO4 Sulfite SO3 Phosphite 3- Hydrogen - - - Citrate C6H5O7 HSO4 Periodate IO4 Superoxide O2 Sulfate - Hydrogen - - - Cyanate OCN HSO3 Permanganate MnO4 Thiocyanate SCN Sulfite - - 2- 2- Cyanide CN Hydroxide OH Peroxide O2 Thiosulfate S2O3 2- Tungstate WO4 PREFIXES: per- = one more oxygen than -ate hypo- = one less oxygen than –ite Common Polyatomic Ions (Alphabetical order by formula) Ion Ion Ion Ion Ion Ion Name Ion Name Ion Name Symbol Name -
2. Chemistry of Disinfectants and Disinfectant By-Products
2. CHEMISTRY OF DISINFECTANTS AND DISINFECTANT BY-PRODUCTS 2.1 Background The use of chlorine (Cl2) as a water disinfectant has come under scrutiny because of its potential to react with natural organic matter (NOM) and form chlorinated disinfectant by-products (DBPs). Within this context, NOM serves as the organic DBP precursor, whereas bro- mide ion (Br–) serves as the inorganic precursor. Treatment strategies generally available to water systems exceeding drinking-water standards include removing DBP precursors and using alternative disinfectants for primary and/or secondary (distribution system) disinfection. Alternative disinfectant options that show promise are chloramines (NH2Cl, monochloramine), chlorine dioxide (ClO2) and ozone (O3). While ozone can serve as a primary disinfectant only and chloramines as a secondary disinfectant only, both chlorine and chlorine dioxide can serve as either primary or secondary disinfectants. Chloramine presents the significant advantage of virtually elimi- nating the formation of chlorination by-products and, unlike chlorine, does not react with phenols to create taste- and odour-causing com- pounds. However, the required contact time for inactivation of viruses and Giardia cysts is rarely obtainable by chloramine post-disinfection at existing water treatment facilities (monochloramine is significantly less biocidal than free chlorine). More recently, the presence of – – nitrifying bacteria and nitrite (NO2 ) and nitrate (NO3 ) production in chloraminated distribution systems as well as the formation of organic chloramines have raised concern. The use of chlorine dioxide, like chloramine, can reduce the formation of chlorinated by-products during primary disinfection. However, production of chlorine dioxide, its decomposition and reaction with NOM lead to the formation of by-products such as – chlorite (ClO2 ), a compound that is of health concern. -
Bromine As a Drinking-Water Disinfectant
Bromine as a drinking-water disinfectant Bromine as a drinking-water disinfectant Alternative drinking-water disinfectants: bromine ISBN 978-92-4-151369-2 © World Health Organization 2018 Some rights reserved. This work is available under the Creative Commons Attribution- NonCommercial-ShareAlike 3.0 IGO licence (CC BY-NC-SA 3.0 IGO; https://creativecommons.org/licenses/by-nc-sa/3.0/igo). Under the terms of this licence, you may copy, redistribute and adapt the work for non-commercial purposes, provided the work is appropriately cited, as indicated below. In any use of this work, there should be no suggestion that WHO endorses any specific organization, products or services. The use of the WHO logo is not permitted. If you adapt the work, then you must license your work under the same or equivalent Creative Commons licence. If you create a translation of this work, you should add the following disclaimer along with the suggested citation: “This translation was not created by the World Health Organization (WHO). WHO is not responsible for the content or accuracy of this translation. The original English edition shall be the binding and authentic edition”. Any mediation relating to disputes arising under the licence shall be conducted in accordance with the mediation rules of the World Intellectual Property Organization. Suggested citation. Alternative drinking-water disinfectants: bromine, iodine and silver. Geneva: World Health Organization; 2018. Licence: CC BY-NC-SA 3.0 IGO. Cataloguing-in-Publication (CIP) data. CIP data are available at http://apps.who.int/iris. Sales, rights and licensing. To purchase WHO publications, see http://apps.who.int/bookorders. -
Download Author Version (PDF)
Analytical Methods Applications of 1,3,5-trimethoxybenzene as a derivatizing agent for quantifying free chlorine, free bromine, bromamines, and bromide in aqueous systems Journal: Analytical Methods Manuscript ID AY-ART-07-2019-001443.R1 Article Type: Paper Date Submitted by the 10-Sep-2019 Author: Complete List of Authors: Dias, Ryan; Towson University, Chemistry Schammel, Marella; Towson University, Chemistry Reber, Keith; Towson University, Chemistry Sivey, John; Towson University, Chemistry Page 1 of 32 Analytical Methods 1 2 3 4 Applications of 1,3,5-trimethoxybenzene as a 5 6 derivatizing agent for quantifying free chlorine, free 7 8 bromine, bromamines, and bromide in aqueous 9 10 systems 11 12 13 Ryan P. Dias,a‡ Marella H. Schammel,a Keith P. Reber,a and John D. Sivey*ab 14 15 16 a Department of Chemistry, Towson University, 8000 York Road, Towson, Maryland 21252, 17 18 United States 19 b 20 Urban Environmental Biogeochemistry Laboratory, Towson University, 8000 York Road, 21 Towson, Maryland 21252, United States 22 23 24 * Corresponding author contact information: phone: 1-410-704-6087; e-mail: [email protected] 25 26 ‡ Current affiliation : Department of Chemistry, University of Alberta, 11227 Saskatchewan Drive, 27 Edmonton, Alberta, Canada T6G 2G2 28 29 30 31 Submitted exclusively to Analytical Methods 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 Analytical Methods Page 2 of 32 1 2 3 4 Abstract 5 6 Free chlorine and free bromine (e.g., HOCl and HOBr) are employed as disinfectants in a 7 8 9 variety of aqueous systems, including drinking water, wastewater, ballast water, recreational 10 11 waters, and cleaning products. -
Bromate in Drinking-Water
WHO/SDE/WSH/05.08/78 English only Bromate in Drinking-water Background document for development of WHO Guidelines for Drinking-water Quality © World Health Organization 2005 This document may be freely reviewed, abstracted, reproduced and translated in part or in whole but not for sale or for use in conjunction with commercial purposes. Inquiries should be addressed to: [email protected]. The designations employed and the presentation of the material in this document do not imply the expression of any opinion whatsoever on the part of the World Health Organization concerning the legal status of any country, territory, city or area or of its authorities, or concerning the delimitation of its frontiers or boundaries. The mention of specific companies or of certain manufacturers’ products does not imply that they are endorsed or recommended by the World Health Organization in preference to others of a similar nature that are not mentioned. Errors and omissions excepted, the names of proprietary products are distinguished by initial capital letters. The World Health Organization does not warrant that the information contained in this publication is complete and correct and shall not be liable for any damages incurred as a result of its use. Preface One of the primary goals of WHO and its member states is that “all people, whatever their stage of development and their social and economic conditions, have the right to have access to an adequate supply of safe drinking water.” A major WHO function to achieve such goals is the responsibility “to propose ... regulations, and to make recommendations with respect to international health matters ....” The first WHO document dealing specifically with public drinking-water quality was published in 1958 as International Standards for Drinking-water.