PIANO Calibration Standards

Paraffinic Liquid Boiling Peak Retention Linear Peak Weight MOLE Volume Specific MOLE Point Components Number Time Index Type %%%Gravity Weight °F

n-Pentane 1 8.40 500.0 P5 1.671 2.629 2.007 0.6310 72.15 96.92 n-Hexane 2 12.93 600.0 P6 1.694 2.231 1.933 0.6640 86.18 155.72 n-Heptane 3 23.56 700.0 P7 1.742 1.962 1.918 0.6882 100.75 209.17 n-Octane 4 39.74 800.0 P8 1.701 1.690 1.823 0.7068 114.22 258.20 n-Nonane 5 63.61 900.0 P9 1.611 1.426 1.692 0.7217 128.25 303.44 n-Decane 6 82.14 1000.0 P10 1.647 1.314 1.700 0.7341 142.28 345.42 n-Undecane 7 94.26 1100.0 P11 1.659 1.205 1.689 0.7443 156.30 384.62 n-Dodecane 8 103.84 1200.0 P12 1.676 1.116 1.696 0.7487 170.34 421.30 n-Tridecane 9 112.09 1300.0 P13 1.587 0.977 1.590 0.7564 184.37 455.72 n-Tetradecane 10 119.54 1400.0 P14 1.567 0.896 1.556 0.7628 198.40 488.66 n-Pentadecane 11 126.45 1500.0 P15 1.263 0.675 1.245 0.7685 212.42 514.71

Totals 17.819 16.119 18.850

Note: Retention times valid for specified conditions only.

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Isoparaffinic Liquid Boiling Peak Retention Linear Peak Weight MOLE Volume Specific MOLE Point Components Number Time Index Type %%%Gravity Weight °F

Isopentane 1 7.65 483.4 I5 0.432 0.680 0.524 0.6247 72.15 82.10 2,3-Dimethylbutane 2 10.65 549.7 I6 0.089 0.117 0.101 0.6664 86.18 136.36 2-Methylpentane 3 10.85 554.1 I6 0.645 0.849 0.743 0.6579 86.18 140.47 3-Methylpentane 4 11.62 571.1 I6 1.060 1.396 1.201 0.6690 86.18 145.89 2,2-Dimethylpentane 5 14.55 615.2 I7 0.352 0.397 0.393 0.6782 100.75 174.54 2,4-Dimethylpentane 6 15.09 620.3 I7 0.728 0.820 0.815 0.6772 100.75 176.89 2,2,3-Trimethylbutane 7 15.56 624.7 I7 0.775 0.873 0.845 0.6946 100.75 177.58 3,3-Dimethylpentane 8 17.53 643.3 I7 0.368 0.415 0.400 0.6976 100.75 186.91 2-Methylhexane 9 18.98 656.9 I7 0.467 0.526 0.518 0.6830 100.75 194.09 2,3-Dimethylpentane 10 19.15 658.5 I7 0.353 0.397 0.382 0.6996 100.75 196.36 3-Methylhexane 11 20.01 666.6 I7 0.317 0.357 0.348 0.6917 100.75 197.32 3-Ethylpentane 12 21.26 678.4 I7 0.104 0.117 0.112 0.7028 100.75 200.25 2,2-Dimethylhexane 13 26.31 717.0 I8 0.260 0.258 0.281 0.6996 114.22 224.31 2,5-Dimethylhexane 14 27.91 726.9 I8 0.734 0.729 0.797 0.6979 114.22 228.39 2,2,3-Trimethylpentane 15 27.91 726.9 I8 0.341 0.339 0.358 0.7203 114.22 229.71 2,4-Dimethylhexane 16 28.15 728.4 I8 0.326 0.324 0.350 0.7047 114.22 228.97 2,3-Dimethylhexane 17 32.31 754.1 I8 0.320 0.317 0.338 0.7165 114.22 240.09 2-Methylheptane 18 33.44 761.1 I8 0.865 0.859 0.933 0.7021 114.22 243.16 4-Methylheptane 19 33.67 762.5 I8 0.633 0.629 0.677 0.7090 114.22 243.88 3-Methylheptane 20 34.68 768.7 I8 1.078 1.071 1.150 0.7101 114.22 244.40 3-Ethylhexane 21 34.84 769.7 I8 0.141 0.140 0.149 0.7178 114.22 245.36 2,5-Dimethylheptane 22 46.28 827.4 I9 1.113 0.984 1.169 0.7210 128.25 276.80 3,5-Dimethylheptane (D)* 23 46.28 827.4 I9 0.000 0.000 0.000 0.7265 128.25 276.80 3,3-Dimethylheptane 24 46.57 828.6 I9 0.332 0.294 0.345 0.7299 128.25 278.62 3,5-Dimethylheptane (L) 25 46.57 828.6 I9 0.150 0.133 0.156 0.7265 128.25 276.80 2,3-Dimethylheptane 26 50.85 846.5 I9 0.293 0.260 0.304 0.7302 128.25 284.90 3,4-Dimethylheptane (D)* 27 51.28 848.3 I9 0.338 0.299 0.348 0.7356 128.25 285.10 3,4-Dimethylheptane (L) 28 51.49 849.2 I9 0.389 0.344 0.401 0.7356 128.25 285.10 2-Methyloctane 29 53.18 856.3 I9 0.742 0.657 0.784 0.7175 128.25 289.87 3-Methyloctane 30 54.87 863.4 I9 1.108 0.981 1.159 0.7245 128.25 290.30 3,3-Diethylpentane 31 55.08 864.3 I9 0.311 0.275 0.311 0.7575 128.25 296.91 2,2-Dimethyloctane 32 67.38 920.3 I10 0.644 0.514 0.670 0.7285 142.28 314.40 3,3-Dimethyloctane 33 70.89 939.3 I10 0.628 0.501 0.641 0.7432 142.28 322.20 2,3-Dimethyloctane 34 74.51 958.8 I10 0.760 0.606 0.776 0.7420 142.28 327.76 2-Methylnonane 35 76.33 968.6 I10 0.734 0.586 0.761 0.7306 142.28 332.60 3-Ethyloctane 36 76.82 971.3 I10 0.730 0.582 0.743 0.7442 142.28 334.00 3-Methylnonane 37 77.36 974.2 I10 1.140 0.909 1.171 0.7375 142.28 334.40

Totals 19.800 19.534 21.156

* Component not available – for peak reference only. Note: Retention times valid for specified conditions only.

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Aromatic Liquid Boiling Peak Retention Linear Peak Weight MOLE Volume Specific MOLE Point Components Number Time Index Type %%%Gravity Weight °F

Benzene 1 17.03 638.6 A6 1.697 2.465 1.454 0.8844 78.11 176.17 Toluene 2 31.18 747.1 A7 1.088 1.340 0.945 0.8719 92.13 231.12 Ethylbenzene 3 48.35 836.1 A8 1.607 1.718 1.397 0.8718 106.16 277.14 m-Xylene 4 50.39 844.6 A8 0.539 0.576 0.470 0.8688 106.16 282.38 p-Xylene 5 50.65 845.7 A8 1.144 1.222 1.001 0.8658 106.16 281.03 o-Xylene 6 55.94 867.9 A8 0.537 0.574 0.460 0.8848 106.16 291.95 Isopropylbenzene 7 65.08 907.9 A9 0.528 0.499 0.462 0.8666 120.19 306.31 n-Propylbenzene 8 71.42 942.1 A9 1.083 1.023 0.947 0.8666 120.19 318.59 1-Methyl-3-Ethylbenzene 9 72.94 950.4 A9 0.523 0.494 0.456 0.8690 120.19 322.34 1-Methyl-4-Ethylbenzene 10 73.29 952.2 A9 0.515 0.487 0.451 0.8657 120.19 323.57 1,3,5-Trimethylbenzene 11 75.48 964.1 A9 0.268 0.253 0.233 0.8696 120.19 328.48 1-Methyl-2-Ethylbenzene 12 75.91 966.4 A9 0.535 0.505 0.458 0.8852 120.19 329.27 1,2,4-Trimethylbenzene 13 78.41 979.9 A9 0.603 0.569 0.519 0.8802 120.19 336.82 tert-Butylbenzene 14 78.41 979.9 A10 1.092 0.924 0.950 0.8710 134.12 336.40 Isobutylbenzene 15 80.78 992.7 A10 1.049 0.888 0.927 0.8577 134.12 342.96 sec-Butylbenzene 16 81.15 994.7 A10 0.535 0.453 0.468 0.8665 134.12 343.94 1-Methyl-3-Isopropylbenzene 17 82.86 1005.9 A10 0.263 0.223 0.231 0.8655 134.12 348.40 1-Methyl-4-Isopropylbenzene 18 83.18 1008.6 A10 0.255 0.215 0.224 0.8618 134.12 350.78 1-Methyl-2-Isopropylbenzene 19 84.89 1022.7 A10 0.268 0.227 0.230 0.8811 134.12 352.67 1-Methyl-3-n-Propylbenzene 20 86.68 1037.5 A10 0.502 0.425 0.440 0.8653 134.12 359.62 1-Methyl-4-n-Propylbenzene 21 87.15 1041.3 A10 0.529 0.447 0.464 0.8628 134.12 362.16 n-Butylbenzene 22 87.27 1042.3 A10 0.525 0.444 0.460 0.8646 134.12 361.89 1,3-Dimethyl-5-Ethylbenzene 23 88.00 1048.3 A10 0.523 0.442 0.450 0.8807 134.12 362.76 1,2-Diethylbenzene 24 88.12 1049.3 A10 0.260 0.220 0.223 0.8843 134.12 362.16 1-Methyl-2-n-Propylbenzene 25 88.50 1052.5 A10 0.533 0.451 0.460 0.8779 134.12 364.95 1,4-Dimethyl-2-Ethylbenzene 26 89.77 1063.0 A10 0.543 0.459 0.467 0.8816 134.12 368.29 1,2-Dimethyl-4-Ethylbenzene 27 90.66 1070.3 A10 0.536 0.454 0.462 0.8788 134.12 373.06 1,3-Dimethyl-2-Ethylbenzene 28 91.31 1075.7 A10 0.272 0.230 0.230 0.8948 134.12 374.02 1,2-Dimethyl-3-Ethylbenzene 29 92.86 1088.4 A10 0.520 0.440 0.440 0.8965 134.12 381.04 1,2,4,5-Tetramethylbenzene 30 94.41 1101.2 A10 0.057 0.048 0.048 0.8918 134.12 386.24 2-Methylbutylbenzene 31 94.46 1102.1 A11 0.272 0.208 0.238 0.8650 148.24 386.00 tert-1-Butyl-2-Methylbenzene 32 95.91 1117.2 A11 0.183 0.140 0.160 0.8650 148.24 390.00 n-Pentylbenzene 33 98.39 1143.1 A11 1.062 0.813 0.933 0.8628 148.24 401.72 t-1-Butyl-3,5-Dimethylbenzene 34 100.39 1164.0 A12 0.514 0.359 0.449 0.8671 162.16 400.00 t-1-Butyl-4-Ethylbenzene 35 100.91 1169.4 A12 0.532 0.372 0.468 0.8610 162.26 403.00 1,3,5-Triethylbenzene 36 104.31 1205.7 A12 1.082 0.757 0.932 0.8791 162.26 420.80 1,2,4-Triethylbenzene 37 105.92 1225.2 A12 0.265 0.185 0.228 0.8791 162.26 423.86 n-Hexylbenzene 38 107.73 1247.2 A12 1.067 0.746 0.938 0.8617 162.26 439.00

Totals 23.904 22.295 20.773

Note: Retention times valid for specified conditions only.

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Naphthenic Liquid Boiling Peak Retention Linear Peak Weight MOLE Volume Specific MOLE Point Components Number Time Index Type %%%Gravity Weight °F

Cyclopentane 1 10.62 549.0 N5 1.053 1.703 1.063 0.7505 70.13 120.67 Methylcyclopentane 2 14.81 317.7 N6 0.693 0.934 0.696 0.7536 84.16 161.25 Cyclohexane 3 17.96 647.3 N7 1.144 1.542 1.106 0.7834 84.16 177.29 1,1-Dimethylcyclopentane 4 19.49 661.7 N7 0.738 0.853 0.736 0.7593 98.18 190.12 cis-1,3-Dimethylcyclopentane 5 20.78 673.8 N7 0.128 0.148 0.129 0.7496 98.18 195.39 trans-1,3-Dimethylcyclopentane 6 21.13 677.1 N7 0.582 0.673 0.585 0.7537 98.18 197.10 trans-1,2-Dimethylcyclopentane 7 21.47 680.3 N7 0.311 0.359 0.312 0.7562 98.18 197.36 Methylcyclohexane 8 25.89 714.4 N7 1.210 1.398 1.184 0.7740 98.18 204.82 Ethylcyclopentane 9 27.62 725.1 N7 0.757 0.875 0.744 0.7710 98.18 218.24 ctc-1,2,4-Trimethylcyclopentane 10 28.29 729.2 N8 0.354 0.358 0.357 0.7518 112.21 228.72 ctc-1,2,3-Trimethylcyclopentane 11 30.14 740.7 N8 0.336 0.340 0.336 0.7580 112.21 230.40 ctt-1,2,4-Trimethylcyclopentane 12 34.29 766.3 N8 0.797 0.805 0.786 0.7680 112.21 242.12 trans-1,4-Dimethylcyclohexane 13 35.12 771.4 N8 0.753 0.762 0.744 0.7670 112.21 246.93 1-Ethyl-1-Methylcyclopentane 14 37.58 786.7 N8 0.228 0.230 0.220 0.7854 112.21 250.74 trans-1,2-Dimethylcyclohexane 15 38.05 789.6 N8 0.354 0.358 0.343 0.7803 112.21 254.15 ccc-1,2,3-Trimethylcyclopentane 16 39.01 795.5 N8 0.171 0.173 0.165 0.7836 112.21 253.40 Isopropylcyclopentane 17 40.48 803.1 N8 0.744 0.752 0.722 0.7808 112.21 259.52 cis-1,2-Dimethylcyclohexane 18 43.48 815.7 N8 0.789 0.798 0.747 0.8006 112.21 265.51 n-Propylcyclopentane 19 44.55 820.2 N8 0.779 0.788 0.756 0.7808 112.21 267.71 ccc-1,3,5-Trimethylcyclohexane 20 44.55 820.2 N9 0.754 0.678 0.738 0.7737 126.23 281.14 1,1,4-Trimethylcyclohexane 21 46.13 826.8 N9 0.780 0.701 0.761 0.7760 126.23 275.00 ctt-1,2,4-Trimethylcyclohexane 22 48.88 838.3 N9 0.770 0.692 0.731 0.7980 126.23 286.23 ctc-1,2,4-Trimethylcyclohexane 23 54.78 863.0 N9 0.750 0.674 0.718 0.7920 126.23 298.00 1,1,2-Trimethylcyclohexane 24 55.92 867.8 N9 0.714 0.642 0.674 0.8030 126.23 294.80 Isobutylcyclopentane 25 59.95 884.7 N9 0.790 0.710 0.762 0.7850 126.23 298.40 Isopropylcyclohexane 26 66.18 913.9 N9 1.222 1.099 1.149 0.8060 126.23 310.23 n-Butylcyclopentane 27 69.65 932.6 N9 0.789 0.709 0.758 0.7888 126.23 313.81 Isobutylcyclohexane 28 79.05 983.3 N10 1.195 0.966 1.133 0.7990 140.26 340.32 t-l-Methyl-2-Propylcyclohexane 29 80.61 991.7 N10 0.697 0.564 0.648 0.8150 140.26 350.00 t-l-Methyl-2-(4MP)cyclopentane 30 98.75 1146.9 N12 0.804 0.542 0.743 0.8200 168.33 400.00

Totals 21.182 21.826 20.546

Note: Retention times valid for specified conditions only.

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Olefinic Liquid Boiling Peak Retention Linear Peak Weight MOLE Volume Specific MOLE Point Components Number Time Index Type %%%Gravity Weight °F

Isobutene * 6.47 457.4 O4 0.000 0.000 0.000 0.6004 56.11 19.59 1-Butene * 6.47 457.4 O4 0.000 0.000 0.000 0.6013 56.11 20.75 cis-2-Butene * 6.84 465.6 O4 0.000 0.000 0.000 0.6271 56.11 38.69 3-Methyl-1-Butene 1 7.33 476.4 O5 0.349 0.564 0.418 0.6325 70.13 68.11 1-Pentene 2 7.99 490.9 O5 0.729 1.179 0.855 0.6457 70.13 85.94 2-Methyl-1-Butene 3 8.15 494.5 O5 0.254 0.410 0.293 0.6557 70.13 88.09 2-Methyl-1,3-Butadiene 4 8.39 499.8 O5 0.427 0.691 0.494 0.6549 70.13 93.20 trans-2-Pentene 5 8.47 501.5 O5 0.320 0.517 0.371 0.6533 70.13 97.44 cis-2-Pentene 6 8.71 506.8 O5 0.350 0.566 0.401 0.6608 70.13 98.50 4-Methylpentene-1 7 10.25 540.8 O6 0.601 0.811 0.682 0.6686 84.16 128.96 1-Hexene 8 11.99 579.2 O6 1.341 1.808 1.498 0.6780 84.16 146.27 trans-2-Hexene 9 13.05 601.1 O6 0.307 0.414 0.341 0.6827 84.16 154.19 2-Methylpentene-2 10 13.21 602.6 O6 0.588 0.793 0.645 0.6912 84.16 153.15 cis-2-Hexene 11 13.74 607.6 O6 0.685 0.924 0.750 0.6920 84.16 155.99 1-Heptene 12 21.68 682.3 O7 1.332 1.539 1.439 0.7015 98.19 200.55 trans-3-Heptene 13 22.96 694.4 O7 0.644 0.745 0.695 0.7026 98.19 204.21 cis-3-Heptene 14 23.67 700.7 O7 1.023 1.183 1.096 0.7073 98.19 204.35 trans-2-Heptene 15 23.88 702.0 O7 0.652 0.754 0.700 0.7057 98.19 208.31 cis-2-Heptene 16 25.01 709.0 O7 1.007 1.163 1.072 0.7116 98.19 209.14 1-Octene 17 37.29 784.9 O8 1.350 1.365 1.422 0.7193 112.22 250.29 trans-2-Octene 18 39.95 800.9 O8 0.346 0.350 0.362 0.7243 112.22 257.00 cis-2-Octene 19 41.38 806.9 O8 0.689 0.696 0.716 0.7287 112.22 258.10 1-Nonene 20 59.66 883.5 O9 1.345 1.209 1.390 0.7334 126.24 296.40 trans-3-Nonene 21 61.69 892.0 O9 0.325 0.292 0.338 0.7294 126.24 297.86 cis-3-Nonene 22 62.03 893.4 O9 0.705 0.633 0.732 0.7294 126.24 297.86 trans-2-Nonene 23 63.71 900.5 O9 0.175 0.157 0.180 0.7380 126.24 299.30 cis-2-Nonene 24 65.58 910.6 O9 0.480 0.432 0.493 0.7380 126.24 299.30 1-Decene 25 80.04 988.7 O10 1.271 1.028 1.293 0.7450 140.25 339.08

Totals 17.295 20.225 18.675

* N/A: Component not in blend. Note: Retention times valid for specified conditions only.

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