Quick Check - Covalent Compounds Naming Covalent Compounds (That Are Not Organic) (Pogil) - Questions? - Turn It In

Total Page:16

File Type:pdf, Size:1020Kb

Quick Check - Covalent Compounds Naming Covalent Compounds (That Are Not Organic) (Pogil) - Questions? - Turn It In Agenda Dec 3, 2018 Quick Check - covalent compounds Naming Covalent compounds (that are not organic) (Pogil) - questions? - Turn it in. Crystal growing lab set up Quick Check - covalent compounds 1. Write the structural formula for methane, CH4(g) 2. What does the (g) stands for in the formula above? 3. What would the molecular formula be for the following structural formula: 4. What do the : represent here? 5. Name the compound. 1. The structural formula for methane, CH4(g) is 2. In the formula above (g) means that the molecule is in the gaseous state (or gas phase). 3. What would the molecular formula be for the following structural formula: P2O5 You are not expected to know the physical state. 4. The 2 dots represent lone pairs of electrons sometimes called non-bonding pairs (valence electrons that are not involved in a covalent bond). 3. What would the molecular formula be for the following structural formula: P2O5 2 Ps 5 O. 5) Name: Diphosphorus pentoxide Organic molecules What patterns did you notice as you drew the structures, made the models and wrote the molecular formulas? Organic molecules Alkanes - all C-C, C-H single bonds Saturated hydrocarbons, main reactions are combustion CH4 + O2 → Organic molecules Alkanes - all C-C, C-H single bonds Saturated hydrocarbons, main reactions are combustion CH4 + O2 → CO2(g) + H2O skeleton equation Organic molecules Alkanes - all C-C, C-H single bonds Saturated hydrocarbons, main reactions are combustion CH4 + 2 O2 → CO2(g) + 2 H2O balanced equation Organic molecules Alkenes - all at least 1 C=C, rest C-C, C-H single bonds unsaturated hydrocarbons, main reactions are combustion And addition - across the double bond Organic molecules Alkynes - all at least 1 C to C triple bond, rest C-C, C-H single bonds unsaturated hydrocarbons, main reactions are combustion And addition - across the triple bond Organic molecules - there is a separate naming system Alcohols -OH Amines -NH2 Aldehydes, ketones, carboxylic acids, ethers, esters, amides Cyclic, aromatic = you get the picture, there is a lot to learn and do with organic molecules. Naming Molecular Compounds (that are not organic) How are the chemical formula and name of a molecular compound related? Model 1 - Molecular Compounds Molecular formula Number of Number of atoms Name of compound atoms of first of second element element ClF 1 1 Chlorine monofluoride ClF5 1 5 Chlorine pentafluoride CO 1 1 Carbon monoxide CO2 1 2 Carbon dioxide Cl2O 2 1 Dichlorine monoxide PCl5 1 5 Phosphorus pentachloride N2O5 2 5 Dinitrogen pentoxide 2. Examine the molecular formulas given in Model 1 for various molecular compounds. a) How many different elements are present in each compound shown? Two b) Do the compounds combine metals with metals, metals with nonmetals, or nonmetals with nonmetals? Nonmetals are combined with nonmetals in molecular compounds. c) Based on answer in b) the bonding in molecular compounds must be covalent. 3. Find all the compounds in Model 1 that have chlorine and fluorine in them. Explain why the name “chlorine fluoride” is not sufficient to identify a specific compound. There are two compounds with chlorine and fluorine. The name “chlorine fluoride” does not make it clear which compound it refers to. It could be the one with one fluorine atom, or the one with five fluorine atoms. 4. Assuming that the name of the compound gives a clue to its molecular formula, predict how many atoms each of these prefixes indicates, and provide two examples. Mono- one carbon monoxide, or chlorine monofluoride Di- two carbon dioxide or dinitrogen pentoxide Penta- five chlorine pentafluoride or phosphorus pentafluoride Model 2 - Prefixes and Suffixes Prefix Numerical value mono 1 di 2 tri 3 tetra 4 penta 5 hexa 6 hepta 7 octa 8 nona 9 deca 10 Prefix Numerical value mono 1 di 2 tri 3 tetra 4 penta 5 hexa 6 hepta 7 octa 8 nona 9 deca 10 Molecular Formula Name of compound BCl3 Boron trifluoride SF6 Sulfur hexafluoride IF7 Iodine heptafluoride NI3 Nitrogen triiodide N2O4 Dinitrogen tetroxide Molecular Formula Name of compound Cl2O Dichlorine monoxide P4O10 Tetraphosphorus decoxide B5H9 Pentaboron nonahydride Br3O8 Tribromine octoxide ClF Chlorine monofluoride 6. What suffix (ending) do all the compound names in Model 2 have in common? All the names end in the suffix -ide. 7. Carefully examine the names of the compounds in Model 2. When is a prefix NOT used in front of the name of an element? The prefix mono- is not used when there is only one atom of the element that appears first in the formula. 8. Consider the compound NO. a) Which element, nitrogen or oxygen, would require a prefix in the molecule name? Explain your answer. The element oxygen would require a prefix (mono-). The element N would not require a prefix since it is the element that appears first in the formula and the prefix mono- is not used in this case. 8. Consider the compound NO. b) Name the molecule NO. Its name would be nitrogen monoxide. 9. Find two compounds in Model 2 that contain a subscript of “4” in their molecular formula. a) List the formulas and names for the two compounds. N2O4 dinitrogen tetroxide P4O10 tetraphosphorus pentoxide b) What is different about the spelling of the prefix meaning “four” in these two names? One of the names cuts off the “a” in tetra-, while the other one uses the whole prefix. 10. Find two compounds in Model 2 that contain the prefix “mono-” in their names. a) List the formulas and names for the two compounds. ClF chlorine monofluoride Cl2O dichlorine monoxide b) What is different about the spelling of the prefix meaning “one” in these two names? One of the names cuts off the last “o” in mono, while the other one uses the whole prefix. 11. Identify any remaining names of compounds in Model 2 where the prefixes do not exactly match the spelling shown in the prefix table. Tetraphosphorus decoxide (instead of decaoxide) Tribromine octoxide (instead of octooxide) 12. If a prefix ends in vowel and the element begins with a vowel, the vowel on the prefix is removed. Vowels are generally not repeated. 13. Nitrogen tri-iodide is easy to say even though there is a repeated vowel. If a prefix ends in vowel (a or o) and the element begins with a vowel (o), the vowel on the prefix is removed. 14. Binary molecular compounds contain 2 non-metallic elements only. 15. Rules for recognizing and naming binary molecular compounds from their chemical formulas. 1) Binary molecular compounds can be recognized because they contain only 2 elements and both elements will be nonmetals ( or a metalloid with a nonmetal). 2) Write a prefix in front of the name of the first element that corresponds with the subscript for that element, unless there is only one atom of the first element. In that case just write the name of the first element. 15. 3) Write the prefix corresponding to the subscript for the second element in front of the name of that element. 4) If a prefix ends in either an “a” or an “o” and the name of the element begins with an “o”, drop the final vowel from the prefix. 5) Remove the ending from the name of the second element and replace it with the suffix -ide. 16. FeI3 ICl5 HBrO4 Fe is a metal Yes, rules Not binary Not a molecular apply rules do not Compound apply 17. Use the rules to name the molecular compounds. Molecular formula Molecule name PBr3 Phosphorus tribromide SCl4 Sulfur tetrachloride N2F2 Dinitrogen difluoride SO3 Sulfur trioxide BrF Bromine monofluoride 18. Use the rules to write the molecular formulas. Molecular formula Molecule name S2F10 Disulfur decafluoride CCl4 Carbon tetrachloride OF2 Oxygen difluoride N2O3 Dinitrogen trioxide P4S7 Tetraphosphorus heptasulfide 18. Use the rules to write the molecular formulas. Molecular formula Molecule name Some of these are not S F Disulfur decafluoride followin 2 10 g the “Octet CCl Carbon tetrachloride Rule” - 4 but all these OF Oxygen difluoride compou 2 nds do exist N2O3 Dinitrogen trioxide P4S7 Tetraphosphorus heptasulfide Refer to reactions sheet 2 AgNO3(aq) + Cu Ag(s) + 2 Cu(NO3)2 (aq) Single Displacement Reaction (show left behind in test tube now) Refer to reactions sheet Pb(NO3)2(aq)+ 2 KI(aq) PbI2(s) + 2 KNO3(aq) Double Displacement Reaction Ions changing partners - one of the new combinations is not soluble so we see it. “Quick reaction = small crystal size.” Dissolving view video cliphttps://drive.google.com/drive/folders/1mep 8mSrnR0egN-mEX-JK3nTZVduJf4E0 Dissolving Dissolving Can we reverse dissolving? Reverse of dissolving? Reverse of dissolving? After all the water has evaporated we would have our original solid substance back. Reverse of dissolving? Dissolving - solid mixes with water to form a homogeneous mixture called a solution. When the solvent evaporates we get our original solid back. Reverse of dissolving? Dissolving is a physical process - no new chemical substances are ever really formed. We can easily reverse the process. Dissolving in reverse in nature: Making crystals - like these in Mexico? http://www.tourismontheedge.com/places/largest-crystals-in-the-world-giant-crystal-cave-mexico.html A sulfur crystal that grew naturally: Previous students were able to grow crystals on an ornamental shape Last year's results Crystal size - longest axis you can find. Eg. 3.45 cm Growing our own crystals: Who will grow the biggest crystals on a pipe cleaner support? Beginning Questions Read from sheet. Safety: Growing our own crystals: Who will grow the biggest crystals on a pipe cleaner support? Beginning Questions Read from sheet.
Recommended publications
  • Transport of Dangerous Goods
    ST/SG/AC.10/1/Rev.16 (Vol.I) Recommendations on the TRANSPORT OF DANGEROUS GOODS Model Regulations Volume I Sixteenth revised edition UNITED NATIONS New York and Geneva, 2009 NOTE The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the Secretariat of the United Nations concerning the legal status of any country, territory, city or area, or of its authorities, or concerning the delimitation of its frontiers or boundaries. ST/SG/AC.10/1/Rev.16 (Vol.I) Copyright © United Nations, 2009 All rights reserved. No part of this publication may, for sales purposes, be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, electrostatic, magnetic tape, mechanical, photocopying or otherwise, without prior permission in writing from the United Nations. UNITED NATIONS Sales No. E.09.VIII.2 ISBN 978-92-1-139136-7 (complete set of two volumes) ISSN 1014-5753 Volumes I and II not to be sold separately FOREWORD The Recommendations on the Transport of Dangerous Goods are addressed to governments and to the international organizations concerned with safety in the transport of dangerous goods. The first version, prepared by the United Nations Economic and Social Council's Committee of Experts on the Transport of Dangerous Goods, was published in 1956 (ST/ECA/43-E/CN.2/170). In response to developments in technology and the changing needs of users, they have been regularly amended and updated at succeeding sessions of the Committee of Experts pursuant to Resolution 645 G (XXIII) of 26 April 1957 of the Economic and Social Council and subsequent resolutions.
    [Show full text]
  • Immediately Dangerous to Life Or Health (Idlh) Value Profile for Chlorine Pentafluoride [Cas No. 13637-63-3] and Bromine Pentafl
    External Review Draft March 2015 1 2 3 4 5 6 7 IMMEDIATELY DANGEROUS TO LIFE OR HEALTH (IDLH) VALUE PROFILE 8 9 10 11 FOR 12 13 14 15 CHLORINE PENTAFLUORIDE [CAS NO. 13637-63-3] 16 17 AND 18 19 BROMINE PENTAFLUORIDE [CAS NO. 7789-30-2] 20 21 22 23 24 25 26 Department of Health and Human Services 27 Centers for Disease Control and Prevention 28 National Institute for Occupational Safety and Health This information is distributed solely for the purpose of pre-dissemination peer review under applicable information quality guidelines. It has not been formally disseminated by the National Institute for Occupational Safety and Health. It does not represent and should not be construed to represent any agency determination or policy. i External Review Draft March 2015 1 DISCLAIMER 2 Mention of any company or product does not constitute endorsement by the National Institute for Occupational 3 Safety and Health (NIOSH). In addition, citations of Web sites external to NIOSH do not constitute NIOSH 4 endorsement of the sponsoring organizations or their programs or products. Furthermore, NIOSH is not 5 responsible for the content of these Web sites. 6 7 ORDERING INFORMATION 8 This document is in the public domain and may be freely copied or reprinted. To receive NIOSH documents or 9 other information about occupational safety and health topics, contact NIOSH at 10 Telephone: 1-800-CDC-INFO (1-800-232-4636) 11 TTY: 1-888-232-6348 12 E-mail: [email protected] 13 14 or visit the NIOSH Web site at www.cdc.gov/niosh.
    [Show full text]
  • (VI) and Chromium (V) Oxide Fluorides
    Portland State University PDXScholar Dissertations and Theses Dissertations and Theses 1976 The chemistry of chromium (VI) and chromium (V) oxide fluorides Patrick Jay Green Portland State University Follow this and additional works at: https://pdxscholar.library.pdx.edu/open_access_etds Part of the Chemistry Commons Let us know how access to this document benefits ou.y Recommended Citation Green, Patrick Jay, "The chemistry of chromium (VI) and chromium (V) oxide fluorides" (1976). Dissertations and Theses. Paper 4039. https://doi.org/10.15760/etd.5923 This Thesis is brought to you for free and open access. It has been accepted for inclusion in Dissertations and Theses by an authorized administrator of PDXScholar. Please contact us if we can make this document more accessible: [email protected]. All ABSTRACT OF THE TllESIS OF Patrick Jay Green for the Master of Science in Chemistry presented April 16, 1976. Title: Chemistry of Chromium(VI) and Chromium(V) Oxide Fluorides. APPROVEO BY MEMBERS OF THE THESIS CO'"o\l TIEE: y . • Ii . ' I : • • • • • New preparative routes to chromyl fluoride were sought. It was found that chlorine ironofluoride reacts with chromium trioxide and chromyl chlo­ ride to produce chromyl fluoride. Attempts were ~ade to define a mechan­ ism for the reaction of ClF and Cr0 in light of by-products observed 3 and previous investigations. Carbonyl fluoride and chromium trioxide react to fom chro·yl fluoride and carbo:i dioxide. A mechanism was also proposed for this react10n. Chromium trioxide 11itl\ l~F6 or WF5 reacts to produce chromyl fluoride and the respective oxide tetrafluoride. 2 Sulfur hexafluoride did not react with Cr03.
    [Show full text]
  • Assessment of Portable HAZMAT Sensors for First Responders
    The author(s) shown below used Federal funds provided by the U.S. Department of Justice and prepared the following final report: Document Title: Assessment of Portable HAZMAT Sensors for First Responders Author(s): Chad Huffman, Ph.D., Lars Ericson, Ph.D. Document No.: 246708 Date Received: May 2014 Award Number: 2010-IJ-CX-K024 This report has not been published by the U.S. Department of Justice. To provide better customer service, NCJRS has made this Federally- funded grant report available electronically. Opinions or points of view expressed are those of the author(s) and do not necessarily reflect the official position or policies of the U.S. Department of Justice. Assessment of Portable HAZMAT Sensors for First Responders DOJ Office of Justice Programs National Institute of Justice Sensor, Surveillance, and Biometric Technologies (SSBT) Center of Excellence (CoE) March 1, 2012 Submitted by ManTech Advanced Systems International 1000 Technology Drive, Suite 3310 Fairmont, West Virginia 26554 Telephone: (304) 368-4120 Fax: (304) 366-8096 Dr. Chad Huffman, Senior Scientist Dr. Lars Ericson, Director UNCLASSIFIED This project was supported by Award No. 2010-IJ-CX-K024, awarded by the National Institute of Justice, Office of Justice Programs, U.S. Department of Justice. The opinions, findings, and conclusions or recommendations expressed in this publication are those of the author(s) and do not necessarily reflect those of the Department of Justice. This document is a research report submitted to the U.S. Department of Justice. This report has not been published by the Department. Opinions or points of view expressed are those of the author(s) and do not necessarily reflect the official position or policies of the U.S.
    [Show full text]
  • Nitrogen Oxide - Wikipedia, the Free Encyclopedia Page 1 of 3
    Nitrogen oxide - Wikipedia, the free encyclopedia Page 1 of 3 Nitrogen oxide From Wikipedia, the free encyclopedia Nitrogen oxide can refer to a binary compound of oxygen and nitrogen, or a mixture of such compounds: Contents ■ Nitric oxide (NO), nitrogen(II) oxide ■ Nitrogen dioxide (NO2), nitrogen(IV) oxide ■ 1 NOx ■ Nitrous oxide (N2O), nitrogen(I) oxide ■ 2 Derivatives ■ Nitrate radical (NO3), nitrogen(VI) oxide ■ 3 See also ■ Dinitrogen trioxide (N2O3), nitrogen(II,IV) oxide ■ 4 References ■ Dinitrogen tetroxide (N2O4), nitrogen(IV) oxide ■ Dinitrogen pentoxide (N2O5), nitrogen(V) oxide In atmospheric chemistry and air pollution and related fields, nitrogen oxides refers specifically to NOx [1][2] (NO and NO2). Only the first three of these compounds can be isolated at room temperature. N2O3, N2O4, and N2O5 all decompose rapidly at room temperature. Nitrate radical is very reactive. N2O is stable and rather unreactive at room temperature, while NO and NO2 are quite reactive but nevertheless quite stable when isolated. Dinitrogen trioxide, Nitric oxide, NO Nitrogen dioxide, NO2 Nitrous oxide, N2O N2O3 Dinitrogen tetroxide, Dinitrogen pentoxide, N2O4 N2O5 http://en.wikipedia.org/wiki/Nitrogen_oxide 11/2/2010 Nitrogen oxide - Wikipedia, the free encyclopedia Page 2 of 3 NOx Main article: NOx NOx (often written NOx) refers to NO and NO2. They are produced during combustion, especially at high temperature. These two chemicals are important trace species in Earth's atmosphere. In the troposphere, during daylight, NO reacts with partly oxidized organic species (or the peroxy radical) to form NO2, which is then photolyzed by sunlight to reform NO: NO + CH3O2 → NO2 + CH3O NO2 + sunlight → NO + O The oxygen atom formed in the second reaction then goes on to form ozone; this series of reactions is the main source of tropospheric ozone.
    [Show full text]
  • Chemical Name Federal P Code CAS Registry Number Acutely
    Acutely / Extremely Hazardous Waste List Federal P CAS Registry Acutely / Extremely Chemical Name Code Number Hazardous 4,7-Methano-1H-indene, 1,4,5,6,7,8,8-heptachloro-3a,4,7,7a-tetrahydro- P059 76-44-8 Acutely Hazardous 6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10- hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide P050 115-29-7 Acutely Hazardous Methanimidamide, N,N-dimethyl-N'-[2-methyl-4-[[(methylamino)carbonyl]oxy]phenyl]- P197 17702-57-7 Acutely Hazardous 1-(o-Chlorophenyl)thiourea P026 5344-82-1 Acutely Hazardous 1-(o-Chlorophenyl)thiourea 5344-82-1 Extremely Hazardous 1,1,1-Trichloro-2, -bis(p-methoxyphenyl)ethane Extremely Hazardous 1,1a,2,2,3,3a,4,5,5,5a,5b,6-Dodecachlorooctahydro-1,3,4-metheno-1H-cyclobuta (cd) pentalene, Dechlorane Extremely Hazardous 1,1a,3,3a,4,5,5,5a,5b,6-Decachloro--octahydro-1,2,4-metheno-2H-cyclobuta (cd) pentalen-2- one, chlorecone Extremely Hazardous 1,1-Dimethylhydrazine 57-14-7 Extremely Hazardous 1,2,3,4,10,10-Hexachloro-6,7-epoxy-1,4,4,4a,5,6,7,8,8a-octahydro-1,4-endo-endo-5,8- dimethanonaph-thalene Extremely Hazardous 1,2,3-Propanetriol, trinitrate P081 55-63-0 Acutely Hazardous 1,2,3-Propanetriol, trinitrate 55-63-0 Extremely Hazardous 1,2,4,5,6,7,8,8-Octachloro-4,7-methano-3a,4,7,7a-tetra- hydro- indane Extremely Hazardous 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]- 51-43-4 Extremely Hazardous 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]-, P042 51-43-4 Acutely Hazardous 1,2-Dibromo-3-chloropropane 96-12-8 Extremely Hazardous 1,2-Propylenimine P067 75-55-8 Acutely Hazardous 1,2-Propylenimine 75-55-8 Extremely Hazardous 1,3,4,5,6,7,8,8-Octachloro-1,3,3a,4,7,7a-hexahydro-4,7-methanoisobenzofuran Extremely Hazardous 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime 26419-73-8 Extremely Hazardous 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime.
    [Show full text]
  • Naming Molecular Compounds General Instructions: Please Do the Activities for Each Day As Indicated
    Teacher Name: Dwight Lillie Student Name: ________________________ Class: ELL Chemistry Period: Per 4 Assignment: Assignment week 2 Due: Friday, 5/8 Naming Molecular Compounds General Instructions: Please do the activities for each day as indicated. Any additional paper needed please attach. Submitted Work: 1) Completed packet. Questions: Please send email to your instructor and/or attend published virtual office hours. Schedule: Date Activity Monday (4/27) Read Sections 9.3, 9.5 in your textbook. Tuesday (4/28) Read and work through questions 1-9 Wednesday (4/29) Read and work through questions 10-14 Thursday (4/30) Read and work through questions 14-18 Friday (5/31) Read and work through questions 19-21 How are the chemical formula and name of a molecular compound related? Why? When you began chemistry class this year, you probably already knew that the chemical formula for carbon dioxide was CO2. Today you will find out why CO2 is named that way. Naming chemical compounds correctly is of paramount importance. The slight difference between the names carbon monoxide (CO, a poisonous, deadly gas) and carbon dioxide (CO2, a greenhouse gas that we exhale when we breathe out) can be the difference between life and death! In this activity you will learn the naming system for molecular compounds. Model 1 – Molecular Compounds Molecular Number of Atoms Number of Atoms in Name of Compound Formula of First Element Second Element ClF Chlorine monofluoride ClF5 1 5 Chlorine pentafluoride CO Carbon monoxide CO2 Carbon dioxide Cl2O Dichlorine monoxide PCl5 Phosphorus pentachloride N2O5 Dinitrogen pentoxide 1. Fill in the table to indicate the number of atoms of each type in the molecular formula.
    [Show full text]
  • COVALENT COMPOUNDS Unit 2 COVALENT BOND
    COVALENT COMPOUNDS Unit 2 COVALENT BOND Forms between two non-metals! Electrons are shared! Co= share Valent = electrons Since electrons are shared, no need to balance charges Covalent bonds form molecules. Molecule - group of neutral atoms held together with a covalent bond Diatomic molecules – molecule consisting of 2 atoms MOLECULES H2O2Br2F2I2N2Cl2 Compound composed of molecules is a molecular compound. MOLECULAR COMPOUNDS Molecular Compounds Properties Gases or liquids Low melting/boiling points Usually made from 2 nonmetals bonded covalently Do not conduct electricity (solid or dissolved) Molecular chemical formula shows how many atoms of each element a molecule contains. H2O – Molecular formula of water 2 Hydrogen atoms, 1 Oxygen atom CO2 – Molecular formula for Carbon Dioxide MOLECULAR 1 Carbon atom, 2 Oxygen atoms FORMULAS H:H - Lewis Dot H-H – Structural Formula H2 – Molecular chemical formula LEWIS STRUCTURES COVALENT BONDING To draw a Lewis Structure, one must know the types of atoms in the molecule, the number of atoms in the molecule and the number of valence electrons for each atom in the molecule. DOUBLE & TRIPLE COVALENT BONDS Sharing a pair of electrons creates a single covalent bond Sharing more than one pair of electrons creates double and triple covalent bonds. 2 shared pairs – Double covalent bond 3 shared pairs – Triple covalent bond Carbon, Nitrogen, Oxygen 1. First element is named first, using the full name of the element 2. The second element is named by dropping ending and adding RULES FOR “–ide” NAMING 3. Prefixes are used to denote # COVALENT of each atom present COMPOUNDS 4. Prefix mono- is never used on the first element 5.
    [Show full text]
  • Binary Covalent Common Names
    Binary Covalent Common Names – H2O, water – NH3, ammonia – CH4, methane – C2H6, ethane – C3H8, propane – C4H10, butane – C5H12, pentane – C6H14, hexane Naming Binary Covalent CompounDs • If the subscript for the first element is greater than one, inDicate the subscript with a prefix. – We Do not write mono- on the first name. – Leave the "a" off the enD of the prefixes that enD in "a" anD the “o” off of mono- if they are placeD in front of an element that begins with a vowel (oxygen or ioDine). Prefixes mon(o) hex(a) di hept(a) tri oct(a) tetr(a) non(a) pent(a) dec(a) Nitrogen OxiDe Names • N2O3 – name starts with di • N2O5 – name starts with di • NO2 – no initial prefix • NO – no initial prefix Naming Binary Covalent CompounDs • Follow the prefix with the name of the first element in the formula. – N2O3 – dinitrogen – N2O3 – dinitrogen – NO2 – nitrogen – NO – nitrogen Naming Binary Covalent CompounDs • Write a prefix to inDicate the subscript for the seconD element. (Remember to leave the “o” off of mono- anD the “a” off of the prefixes that enD in “a” when they are placeD in front of a name that begins with a vowel.) – N2O3 – dinitrogen tri – N2O5 – dinitrogen pent – NO2 – nitrogen di – NO – nitrogen mon Naming Binary Covalent CompounDs • Write the root of the name of the seconD symbol in the formula. (See the next sliDe.) – N2O3 – dinitrogen triox – N2O5 – dinitrogen pentox – NO2 – nitrogen diox – NO – nitrogen monox Roots of Nonmetals H hydr- F fluor- C carb- Cl chlor- N nitr- Br brom- P phosph- I iod- O ox- S sulf- Se selen- Naming Binary Covalent CompounDs • AdD -ide to the enD of the name.
    [Show full text]
  • The Synthesis and Characterization of Novel Pentafluorosulfanyl-Containing Heterocycles and Pentafluorosulfanyldifluoromethane
    Clemson University TigerPrints All Dissertations Dissertations May 2019 The yS nthesis and Characterization of Novel Pentafluorosulfanyl-Containing Heterocycles and Pentafluorosulfanyldifluoromethane Steven Paul Belina Clemson University, [email protected] Follow this and additional works at: https://tigerprints.clemson.edu/all_dissertations Recommended Citation Belina, Steven Paul, "The yS nthesis and Characterization of Novel Pentafluorosulfanyl-Containing Heterocycles and Pentafluorosulfanyldifluoromethane" (2019). All Dissertations. 2373. https://tigerprints.clemson.edu/all_dissertations/2373 This Dissertation is brought to you for free and open access by the Dissertations at TigerPrints. It has been accepted for inclusion in All Dissertations by an authorized administrator of TigerPrints. For more information, please contact [email protected]. THE SYNTHESIS AND CHARACTERIZATION OF NOVEL PENTAFLUOROSULFANYL-CONTAINING HETEROCYCLES AND PENTAFLUOROSULFANYLDIFLUOROMETHANE A Dissertation Presented to the Graduate School of Clemson University In Partial Fulfillment of the Requirements for the Degree Doctor of Philosophy Chemistry by Steven Paul Belina May 2019 Accepted by Joseph S. Thrasher, Ph.D., Committee Chair Julia L. Brumaghim, Ph.D. R. Karl Dieter, Ph.D. Joseph W. Kolis, Ph.D. Title Page ABSTRACT Beginning in the early 1960s, scientists began to experiment with the pentafluorosulfanyl moiety. The unique properties of the functional group has attracted interest among fluorine chemists and more recently even organic chemists. These properties include high group electronegativity, high steric bulk, high lipophilicity, a highly electron withdrawing nature, and a square pyramidal geometry. However, the development and deployment of the pentafluorosulfanyl functional group has been significantly slowed. The main cause for the slow development is a lack of easily available reagents to synthesize pentafluorosulfanyl-containing compounds. Historically, the primary reagents used for synthesizing pentafluorosulfanyl-containing compounds were SF5Cl and SF5Br.
    [Show full text]
  • The WMS Model
    Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is © the Owner Societies 2018 S-1 ELECTRONIC SUPPLEMENTARY INFORMATION OCT. 8, 2018 Extrapolation of High-Order Correlation Energies: The WMS Model Yan Zhao,a Lixue Xia,a Xiaobin Liao,a Qiu He,a Maria X. Zhao,b and Donald G. Truhlarc aState Key Laboratory of Silicate Materials for Architectures,International School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, People’s Republic of China. bLynbrook High School, 1280 Johnson Avenue, San Jose, California 95129 cDepartment of Chemistry and Supercomputing Institute, University of Minnesota, 207 Pleasant Street S.E., Minneapolis, MN 55455-0431 TABLE OF CONTENTS Table S1: Calculated classical barrier heights (kcal/mol) for the DBH24-W4 database S-2 Table S2: RMSE of the scalar relativistic contribution in WMS (kcal/mol) S-3 Table S3: RMSE of the composite methods for the W4-17 database (kcal/mol) S-4 Table S4: Calculated Born-Oppenheimer atomization energy (kcal/mol) for the W4-17 database S-5 Table S5: Example input file for a WMS calculation: the H2O molecule S-11 Table S6: Example input file for a WMS calculation: the CH3 radical S-12 Table S7. perl scripts for performing WMS calculations S-13 S-2 Table S1: Calculated classical barrier heights (kcal/mol) for the DBH24-W4 database (The ZPE contributions are excluded.) Reactions Best Est. WMS Hydrogen Atom Transfers ! ∆E! 6.35 6.25 OH + CH4 → CH3 + H2O ! ∆E! 19.26 19.28 ! ∆E! 10.77 10.88 H + OH → O + H2 ! ∆E! 13.17
    [Show full text]
  • United States Patent Office Patented Mar
    3,373,000 United States Patent Office Patented Mar. 2, 1968 2 3,373,000 monofluoride is also an economical reactant, since it is PROCESS FOR PREPARING TETRAFLUORDES conveniently prepared by the disproportionation of ele AND HEXAFLUOR DES mental chlorine in liquid hydrogen fluoride, thereby avoid James J. Pitts, West Haven, and Albert W. Jache, North ing the use of expensive elemental fluorine. The selective Haven, Conn., assignors to Olin Mathieson Chemical fluorination process of this invention is particularly Sur Corporation, a corporation of Virginia prising and unexpected in view of the prior art which No Drawing. Filed Nov. 1, 1966, Ser. No. 591,079 teaches that chlorine monofluoride adds to a wide variety 9 Claims. (Cl. 23-352) of compounds, thereby acting as a chloro-fluorinating agent. For instance, U.S. Patent 3,035,893 discloses the 10 preparation of sulfur chloride pentafluoride from Sulfur ABSTRACT OF THE DISCLOSURE tetrafluoride and chlorine monofluoride. The tetrafluorides and hexafluorides of sulfur, selenium According to the process of this invention, the tetra and tellurium are provided by reacting chlorine mono fluorides and hexafluorides of sulfur, selenium and tel fluoride with sulfur, selenium, tellurium, metal sulfides, lurium are provided by reacting chlorine monofluoride metal selenides or metal tellurides. The hexafluorides of 15 with a material selected from the group consisting of Sul tungsten, molybdenum and uranium are provided by the fur, selenium, tellurium, metal sulfides, metal selenides reaction of chlorine monofluoride with the metals, their and metal tellurides. The hexafluorides of tungsten, oxides, sulfides and salts containing the metallate anion. molybdenum and uranium are provided by reacting These tetrafluorides and hexafluorides are well-known chlorine monofluoride with a material selected from the compounds, useful as fluorinating agents, gaseous di 20 group consisting of tungsten; molybdenum, uranium; the electrics, sources of high purity metallic powders, etc.
    [Show full text]