Pond Champs Aqua Blue Safety Data Sheet According to Federal Register / Vol

Pond Champs Aqua Blue Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 08/17/2015 Version: 1.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier Product form : Mixture Product name : Pond Champs Aqua Blue

1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Pond dye

1.3. Details of the supplier of the safety data sheet Sanco Industries, Inc. 1819 S. Calhoun Street Fort Wayne, IN 46802 Phone: 260-426-6281 Toll Free: 888-697-2626

1.4. Emergency telephone number Emergency number : 24 Hour Contact - CHEMTREC 1-800-424-9300

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture Classification (GHS-US) Skin Sens. 1 H317

2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) :

GHS07 Signal word (GHS-US) : Warning Hazard statements (GHS-US) : H317 - May cause an allergic skin reaction Precautionary statements (GHS-US) : P261 - Avoid breathing vapors P272 - Contaminated work clothing must not be allowed out of the workplace P280 - Wear protective equipment P302 + P352 - If on skin: Wash with plenty of water P333+P313 - If skin irritation or rash occurs: Get medical advice/attention P362+P364 - Take off contaminated clothing and wash it before reuse

2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) None of the ingredients are of unknown toxicity SECTION 3: Composition/information on ingredients

3.1. Substance Not applicable – product is a mixture 3.2. Mixture

Name Product identifier % Classification (GHS-US) Benzenesulfonic acid, 3-((4-(phenylamino)phenyl)azo)-, (CAS No) 587-98-4 0.715 Skin Sens. 1, H317 monosodium salt

SECTION 4: First aid measures

4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the product label where possible). First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest.

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Pond Champs Aqua Blue Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.

4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use.

4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures

5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixture No additional information available

5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Contain all water used for fire-fighting to the greatest extent possible. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area.

6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if significant quantities of solution enters sewers or public waters.

6.3. Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.

6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage

7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor.

7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep only in the original container in a cool, well ventilated place. Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight.

7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection

8.1. Control parameters

No additional information available 8.2. Exposure controls Appropriate engineering controls : Ensure that proper ventilation is provided.

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Pond Champs Aqua Blue Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Respiratory protection : Not typically required. Other information : Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties Physical state : Liquid

Color : Blue-Green

Odor : None

Odor threshold : No data available

pH : No data available

Melting point : No data available

Freezing point : No data available

Boiling point : No data available

Flash point : No data available

Relative evaporation rate (butyl acetate=1) : No data available

Flammability (solid, gas) : No data available

Explosion limits : No data available

Explosive properties : No data available

Oxidizing properties : No data available

Vapor pressure : No data available

Relative density : No data available

Relative vapor density at 20 °C : No data available

Solubility : Soluble in water

Log Pow : No data available

Log Kow : No data available

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Viscosity : No data available

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

9.2. Other information No additional information available SECTION 10: Stability and reactivity

10.1. Reactivity No additional information available 10.2. Chemical stability Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information

11.1. Information on toxicological effects Likely routes of exposure : Skin and eye contact

Acute toxicity : Not classified

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Pond Champs Aqua Blue Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Benzenesulfonic acid, 3-((4-(phenylamino)phenyl)azo)-, monosodium salt (587-98-4) LD50 oral rat 5000 mg/kg ATE US (oral) 5000.000 mg/kg body weight

Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitization : May cause an allergic skin reaction. Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated : Not classified exposure) Aspiration hazard : Not classified Potential Adverse human health effects and : No additional information available symptoms

SECTION 12: Ecological information

12.1. Toxicity No additional information available

12.2. Persistence and degradability Pond Champs Aqua Blue Persistence and degradability Not established.

12.3. Bioaccumulative potential Pond Champs Aqua Blue Bioaccumulative potential Not established.

12.4. Mobility in soil No additional information available

12.5. Other adverse effects Other information : Avoid release to the environment.

SECTION 13: Disposal considerations

13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local, state, and federal regulations. Ecology - waste materials : Avoid release to the environment.

SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Not regulated for transport Additional information ADR No additional information available Transport by sea No additional information available Air transport No additional information available SECTION 15: Regulatory information

15.1. US Federal regulations Pond Champs Aqua Blue SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Delayed (chronic) health hazard

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Pond Champs Aqua Blue Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Benzenesulfonic acid, 3-((4-(phenylamino)phenyl)azo)-, monosodium salt (587-98-4) Listed on the United States TSCA (Toxic Substances Control Act) inventory

15.2. International regulations CANADA

Benzenesulfonic acid, 3-((4-(phenylamino)phenyl)azo)-, monosodium salt (587-98-4) Listed on the Canadian DSL (Domestic Sustances List)

EU-Regulations

Benzenesulfonic acid, 3-((4-(phenylamino)phenyl)azo)-, monosodium salt (587-98-4) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)

Classification according to Regulation (EC) No. 1272/2008 [CLP] No additional information available

Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] No additional information available

National regulations

Benzenesulfonic acid, 3-((4-(phenylamino)phenyl)azo)-, monosodium salt (587-98-4) Listed on the AICS (Australian Inventory of Chemical Substances) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)

15.3. US State regulations No additional information available

SECTION 16: Other information

Other information : None.

Full text of H-phrases: ------Skin Sens. 1 Skin sensitization Category 1 ------H317 May cause an allergic skin reaction

SDS US (GHS HazCom 2012)

While Sanco Industries, Inc. believes the data set forth is accurate to the best of our knowledge, Sanco Industries, Inc. makes no warranties and expressly disclaims all liability for reliance thereon. Such data is offered solely for your consideration and verification.

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