150 Jahre The Lumina® Royal Family Marketing Pigments for Automotive Coatings 150 Jahre
The Lumina® Royal Family at a glance
Mica-based interference pigments with best chromaticity of all competitive products Improved particle size distribution
Lumina® Royal Blue: Lumina® Royal Aqua: Lumina® Royal Indigo: Lumina® Royal Copper: Lumina® Royal Most chromatic, Most chromatic, Shade between Highest chroma in Magenta: Shade reddish-blue greenish-blue Pyrisma® Indigo and semi-transparent effect between Pyrisma® with high lightness Violet pigments Magenta and Violet
2009 2012 2013 2014
2 150 Jahre
Lumina® Royal Blue
Most chromatic blue interference pigment based on mica Flat, uniform surfaces for high brilliancy Prevailed already into Automotive shades
3 150 Jahre
Coloristic properties
® Lumina Royal Exterior Blue 6803H
70 Lumina® Royal Exterior Blue 6803H
Lumina® Exterior Red Blue 6303D 60 Best competitive, blue interference pigment
50
40 Test system C* 90:10 black reduction in a solvent-borne binder 30 (polyester/CAB, medium solid)
20 15° angle h C* L* DH* DC* DL* DE*
® 10 Lumina Royal Exterior Blue 6803H 285.6 60.1 36.9 Lumina® Exterior Red Blue 6303D 271.6 42.8 38.7 -12.4 -17.3 1.8 21.3
0 Best competitive, blue interference pigment 278.7 52.7 36.9 -6.8 -7.4 0.0 10.1 260 265 270 275 280 285 290 h
4 150 Jahre
Coloristic properties
Lumina® Royal Blue 9680H
70 Lumina® Royal Blue 9680H Lumina® Red Blue 9B30D 60
50
40 Test system C* 90:10 black reduction in a solvent-borne binder 30 (polyester/CAB, medium solid)
20 15° angle h C* L* DH* DC* DL* DE*
® 10 Lumina Royal Blue 9680H 284.8 60.7 38.6 Lumina® Red Blue 9B30D 273.4 46.9 42.9 -10.6 -13.9 4.3 18.0
0 265 270 275 280 285 290 h
5 150 Jahre
Coloristic properties
Lumina® Royal Exterior Blue 6803H
In combination with blue organic pigments
100 Royal Blue 6803H / P.B.60 / FW 200 Red Blue 6303D / P.B.60 / FW 200 90 Best competitive, blue interference pigment / P.B.60 / FW 200 80 Royal Blue 6803H / L 6950 / FW 200 Red Blue 6303D / L 6950 / FW 200 70 Best competitive interference pigment / L 6950 / FW 200 L
60 Test system C* 50 50 parts P.B.60 / Heliogen 45 parts blue interference pigment 40 5 parts black pigment FW 200
In a solvent-borne CAB/polyester 30
20
10 250 260 270 280 290 300 310 h
6 150 Jahre
Coloristic properties
Lumina® Royal Exterior Blue 6803H
Impact on a mid-blue metallic styling
65 Styling with Lumina® Royal Exterior Blue Styling with Exterior Mearlin® Super Blue 6303Z 60 Styling with best competitive, blue interference pigment
55
50
45 Mid-blue metallic styling C* ® 40 40 parts blue mica (6803H or 6303Z or Pyrisma Blue)
10 parts a luminum 35 37.2 parts P.B.60
9.9 parts Heliogen® Blue L 6950 30 1.2 parts Cinquasia ® L 4540
25 1.7 parts Cromophtal® D 5800
20 260 265 270 275 280 285 290 295 h
7 150 Jahre
Coloristic properties
Lumina® Royal Exterior Blue 6803H
Impact on a deep reddish -blue styling 70 Styling with Lumina® Royal Exterior Blue
Styling with Exterior Mearlin® Super Blue 6303Z
60 Styling with best competitive, blue interference pigment
50
Reddish-blue styling C* 40 20 parts blue mica (6803H or 6303Z or Pyrisma® Blue) ® 20 parts Mearlin Super Violet 5303Z 30 50 parts P.B.60
8 parts Heliogen® Blue L 7081D
20 2 parts Carbon Black FW 200
10 292 294 296 298 300 302 h
8 150 Jahre
Summary
Lumina® Royal Exterior Blue 6803H and Lumina® Royal Blue 9680H Lumina® Royal Blue is a highly chromatic reddish-blue (Note: The greenish-blue side is covered by Lumina® Royal Aqua) Lumina® Royal Blue shows extreme chroma in combination with P.B.60, alpha-CuPc (15:1, 15:2) and epsilon-CuPc (P.B., 15:6) For combination with greenish-blues (beta-Blue, 15:3, 15:4), Lumina® Royal Aqua is the best choice Brilliant and smooth appearance thanks to optimized particle size distribution
9 150 Jahre Particle size distribution H vs. D-fraction
Lumina® Royal Blue 6803H and 9680H
10 ® Lumina Royal Blue 9 Lumina ® D-fraction
8 L 7 dLumina ® Royal H dd ~ 10 µm 6 10
dd50 ~ 19 µm 5 d90 ~ 34 µm
4 Volume (%) LLumina ® D 3 dd10 ~ 10 µm
2 dd50 ~ 21 µm
dd90 ~ 39 µm 1
0 0,1 1 10 100 1000 Masterizer 2000 Version 5.12G Particle size ( μm) S/N: MAL101491 The H fraction has an optimized d90 value
10 150 Jahre
Technical data
Lumina® Royal Exterior Blue 6803H
Chemical composition mica 53,7 % by weight
TiO2 (Rutile) 27,4 % by weight
SnO2 1,6 % by weight
SiO (amorphous) 14,8 % bei weight 2 Surface treatment Polymer 2,5 % bei weight
Physical form white powder
Physical data* pH 7.7 (10 % aq. suspension)
Conductivity 31.6 µS/cm (10 % aq. suspension) Bulk volume 1.8 l/kg 3 Density 2.84 g/cm Total solids > 99.5 % by weight
Particle size distribution** d10 10 µm
d50 19 µm
d90 34 µm
Fastness to solvents practically insoluble in all solvents Chemical resistance HCl (2%) no change
(in coatings) NaOH (2%) no change
Heat stability > 200 °C Weathering data*** 2 years Florida ongoing accelerated 4000 h ok Humdity resistance**** 24 h, 70°C no whitening gloss and DOI after 24 h 100 % cross hatch after 1 h 0 10 d, 40°C no whitening gloss and DOI after 24 h 100 % cross hatch after 1 h 0
* Physical data determined at lot 207553
** Particle size distribution (Vol %) determined with Mastersizer 2000 Ver 5.12G (Malvern Instruments) *** test in a black reduction (pigmentation 90 pts. EH 402 + 10 pts. FW 200) acc. DIN EN ISO 4892-2 **** test in a black reduction (pigmentation 90 pts. EH 402 + 10 pts. FW 200, solventborne basecoat/clearcoat)
11 150 Jahre
Technical data
Lumina® Royal Blue 9680H
Chemical composition mica 55,1 % % by weight
TiO2 (Rutile) 28,1% by weight
SnO2 1,6 % by weight
SiO2 (amorphous) 15,2 % by weight Physical form white powder Physical data* pH 9.2 (10 % aq. suspension) Conductivity 29 µS/cm (10 % aq. suspension) Bulk volume 2.95 l/kg 3 Density 2.88 g/cm Total solids > 99.5 % by weight
Particle size distribution** d10 10 µm
d50 19 µm
d90 34 µm
Fastness to solvents practically insoluble in all solvents
Chemical resistance HCl (2%) no change
(in coatings) NaOH (2%) no change
Heat stability > 200 °C FDA-approval yes
* Physical data determined at lot 207468 ** Particle size distribution (Vol %) determined with Mastersizer 2000 Ver 5.12G (Malvern Instruments)
12 150 Jahre
Lumina® Royal Aqua
Most chromatic effect pigment Greenish-blue with high lightness
13 150 Jahre
Coloristic properties
Lumina® Royal Exterior Aqua 7803H Higher lightness and higher chroma
60,00 Lumina® Royal Exterior Aqua 7803H 15° Lumina® Exterior Aqua 7303D 50,00 -15°
-15° 40,00 15°
25°
Test system L** 30,00 Solvent-borne base coat / solvent-borne clear coat 25° 90 parts blue interference pigment 20,00 10 parts Pigment Black 7
10,00
110° 0,00 0,00 10,00 20,00 30,00 40,00 50,00 60,00 C*
14 150 Jahre
Coloristic properties
Lumina® Royal Aqua 9780H Higher lightness and higher chroma
60,00 Lumina® Royal Aqua 9780H 15° ® -15° Lumina Aqua 9A30D 50,00
-15° 15° 40,00 25°
Test system L* 30,00 Solvent-borne base coat / solvent-borne clear coat 25° 90 parts blue interference pigment 20,00 10 parts Pigment Black 7
10,00
110° 0,00 0,00 10,00 20,00 30,00 40,00 50,00 60,00 C*
15 150 Jahre
Coloristic data
-15° h C* L* a* b* ΔH* ΔC* ΔL* Δa* Δb* ΔE* -15° h C* L* a* b* ΔH* ΔC* ΔL* Δa* Δb* ΔE* 7803H 265,0 51,7 49,9 -4,5 -51,5 9780H 262,8 52,3 52,5 -6,6 -51,9 7303D 263,3 42,9 44,1 -5,0 -42,6 -1,4 -8,8 -5,8 -0,5 8,9 10,6 9A30D 264,4 45,3 45,8 -4,4 -45,1 1,4 -7,0 -6,7 2,1 6,8 9,8
15° h C* L* a* b* ΔH* ΔC* ΔL* Δa* Δb* ΔE* 15° h C* L* a* b* ΔH* ΔC* ΔL* Δa* Δb* ΔE* 7803H 256,5 45,3 51,5 -10,6 -44,0 9780H 254,1 45,6 54,1 -12,5 -43,9 7303D 252,0 38,3 43,3 -11,9 -36,4 -3,3 -7 -8,2 -1,2 7,6 11,3 9A30D 252,9 39,7 44,5 -11,7 -38,0 -0,9 -5,9 -9,6 0,8 5,9 11,3
25° h C* L* a* b* ΔH* ΔC* ΔL* Δa* Δb* ΔE* 25° h C* L* a* b* ΔH* ΔC* ΔL* Δa* Δb* ΔE* 7803H 253,0 31,7 36,3 -9,2 -30,3 9780H 251,0 31,8 38,0 -10,4 -30,1 7303D 249,0 26,2 28,8 -9,4 -24,4 -2 -5,5 -7,5 -0,1 5,8 9,5 9A30D 249,9 25,9 28,5 -8,9 -24,3 -0,5 -6,0 -9,5 1,5 5,8 11,2
45° h C* L* a* b* ΔH* ΔC* ΔL* Δa* Δb* ΔE* 45° h C* L* a* b* ΔH* ΔC* ΔL* Δa* Δb* ΔE* 7803H 251,8 17,1 17,1 -5,4 -16,2 9780H 249,7 17,0 17,8 -5,9 -15,9 7303D 250,6 13,3 12,6 -4,4 -12,5 -0,3 -3,8 -4,6 1 3,7 6 9A30D 252,8 12,8 12,5 -3,8 -12,2 0,8 -4,2 -5,3 2,1 3,7 6,8
75° h C* L* a* b* ΔH* ΔC* ΔL* Δa* Δb* ΔE* 75° h C* L* a* b* ΔH* ΔC* ΔL* Δa* Δb* ΔE* 7803H 254,7 9,7 7,9 -2,6 -9,3 9780H 252,8 9,7 8,3 -2,9 -9,2 7303D 261,0 6,6 6,6 -1,0 -6,5 0,9 -3,1 -1,3 1,5 2,8 3,4 9A30D 263,1 6,6 6,9 -0,8 -6,5 1,4 -3,1 -1,4 2,1 2,7 3,7
110° h C* L* a* b* ΔH* ΔC* ΔL* Δa* Δb* ΔE* 110° h C* L* a* b* ΔH* ΔC* ΔL* Δa* Δb* ΔE* 7803H 263,4 5,2 4,2 -0,6 -5,2 9780H 262,4 5,4 4,4 -0,7 -5,4 7303D 271,0 3,4 4,7 0,1 -3,4 0,6 -1,8 0,4 0,7 1,8 2 9A30D 272,3 3,4 4,9 0,1 -3,4 0,7 -2,0 0,5 0,9 2,0 2,2
Test system 90:10 black reduction in a solvent-borne binder (polyester/CAB, medium solid)
16 150 Jahre Lumina® Royal vs. best competitive interference pigments
Lumina® Royal Exterior Blue 6803H Best competitive interference blue Lumina® Royal Exterior Aqua 7803H Lumina® Royal Exterior Indigo 5803H Best competitive indigo Best competitive violet
Test system C* 90:10 black reduction in a solvent-borne, medium-solid system (polyester/CAB)
h
17 150 Jahre
Particle size distribution
® ® Lumina Exterior Aqua 7303H vs. Lumina Royal Exterior Aqua 7803H
9 Lumina® Exterior Aqua 7303D
8 Lumina® Royal Exterior Aqua 7803H
7 7303D 6 d10 ~ 12 µm
5 d50 ~ 22 µm
d90 ~ 44 µm 4 d100 ~ 73 µm
Volume (%) 3 7803H d ~ 9 µm 2 10
d50 ~ 18 µm 1 d90 ~ 33 µm d ~ 60 µm 0 100 Measured with Masterizer 2000 Version 5.12G 1 10 100 1000 S/N:MAL101491 Malvern Instruments Ltd. -1
Particle size (μm)
18 150 Jahre
Particle size distribution
Lumina® Aqua 9A30D vs. Lumina® Royal Aqua 9780H
9 Lumina® Aqua 9A30D
8 Lumina® Royal Aqua 9780H
7 9A30D 6 d10 ~ 12 µm
5 d50 ~ 22 µm
d90 ~ 44 µm 4 d100 ~ 73 µm
Volume (%) 3 9780H d ~ 9 µm 2 10 d50 ~ 18 µm 1 d90 ~ 33 µm
d100 ~ 60 µm Measured with 0 Masterizer 2000 Version 5.12G 1 10 100 1000 S/N:MAL101491
Malvern Instruments Ltd. -1
Particle size (μm)
19 150 Jahre
Summary
Lumina® Royal Exterior Aqua 7803H and Lumina® Royal Aqua 9780H Greenish-blue interference pigments with highest chroma and lightness Improved particle size distribution Both are standardized Production process under control with high-quality consistency
20 150 Jahre
Lumina® Royal Indigo
High chroma pigment Shade between Pyrisma Indigo and Violet
21 150 Jahre
Majestic effects with Lumina® Royal
Lumina® Royal Exterior Violet 5803H vs. the state of the art in a 90:10 black reduction (PE/CAB-MS)
Mearlin® Super Violet 539Z 15° ® 15° Lumina Royal Exterior Violet 5803H Best competitive violet 15°
C*
110° Lumina® Royal Exterior Indigo is designed for extremely chromatic shades in combination with transparent organic pigments such as Paliogen Blue or Cinquasia Violet.
h
22 150 Jahre
Particle size distribution
Particle size distribution of Lumina® Royal Exterior Indigo 5803H vs. Mearlin® Exterior Super Violet 5303Z
Lumina® Royal Exterior Indigo 5803H Mearlin® Super Violet 5303Z
5803H
d10 ~ 9 µm
d50 ~ 18 µm
d90 ~ 33 µm
Volume (%) d100 ~ 60 µm 5303Z
d10 ~ 9 µm
d50 ~ 19 µm
d90 ~ 37 µm
Particle size (μm) d100 ~ 73 µm
Measured with Mastersizer 2000 Version 5.12G S/N: MAL 101491 Malvern Instruments Ltd.
23 150 Jahre
Lumina® Royal Copper
Highest chroma in semi-transparent effect pigments Extraordinary sparkle behavior
24 150 Jahre
Lumina® Royal Copper
Lumina® Royal effect pigments benefits Better color purity, strength, and brilliancy and sparkle compared to pigments of the same class New, extremely high chroma shades can now be created Extension of color space for new styling options and greater formulation flexibility The option to use reduced levels in standard effect shade formulations
Areas of application Exterior grades: e.g. aerospace, automotive OEM and refinish coatings, consumer electronics, building and construction Standard grades: e.g. consumer electronics, kitchen and major appliances, household goods, sporting goods, cosmetic and personal care packaging, print packaging, powder and coil coatings, wall coverings, and specialty applications
25 150 Jahre Lumina® Royal Copper Benefits
Primary Properties Customer properties in application benefits
Higher chroma Extension of color space New modern styling Pronounced sparkle . Highest chroma options to differentiate . from competitors Narrower particle size Strong sparkle distribution Higher impact on Greater formulation resulting shade through flexibility to optimize . d less than 35 µm 90 higher color intensity formulations Luxurious browns and Reduction of pigment warm metal tones load to gain flexibility Benefit in printing and packaging applications
26 150 Jahre
Coloristic properties
Lumina® Royal Copper vs. state of the art
45 parts Lumina® Royal Copper 50 parts Paliogen® Red L 3885 5 parts FW 200
45 parts Lumina® Copper 50 parts Paliogen® Red L 3885 5 parts FW 200
C* 90 parts Lumina® Royal Copper 10 parts FW 200
90 parts Lumina® Copper 10 parts FW 200
h
27 150 Jahre Lumina® Royal Copper Sparkle characteristics
Total sparkle grade of Lumina® Royal Copper vs. state of the art
45 parts Lumina® Royal Copper 50 parts Paliogen® Red L 3885 5 parts FW 200
45 parts Lumina® Copper 50 parts Paliogen® Red L 3885 S_G 5 parts FW 200
90 parts Lumina® Royal Copper 10 parts FW 200
90 parts Lumina® Copper 10 parts FW 200
Illumination angle
Lumina® Royal Copper has about 60% stronger sparkle effect than Lumina® Copper
28 150 Jahre
Lumina® Royal Magenta
Shade between Pyrisma Magenta and Violet
29 150 Jahre Lumina® Royal Magenta Benefits
Primary Properties Customer properties in application benefits
Magenta interference Extension of color space New modern styling effect pigment Tinting in blue and red options to differentiate Extreme chroma shades from competitors Narrower particle size . Blues go red Greater formulation distribution . Reds go blue flexibility to optimize formulations . d90 less than 35 µm Higher impact on resulting shade through Reduction of pigment higher color intensity load to gain flexibility and achieve more economical solutions
30 150 Jahre
Competitive landscape
Lumina® Royal range vs. best competitive interference pigments
Lumina® Exterior Royal Aqua 7803H Blue Indigo Lumina® Royal Exterior Blue 6803H ® Magenta Lumina Royal Exterior Indigo 5803H Aqua Lumina® Royal Exterior Magenta EH 5000 (4803H) State-of-the-art blue State-of-the-art indigo C* State-of-the-art violet State-of-the-art magenta
Test system 90 parts effect pigment 10 parts FW 200
h
Lumina® Royal is superior in chroma in all shade areas Lumina® Royal Magenta completes the series of “Blue Royals” at the reddish end
31 150 Jahre
Coloristic properties
Lumina® Royal Exterior Magenta EH 5000 (4803H) vs. best competitive pigments
Lumina® Royal Exterior Magenta EH 5000 (4803H) : FW 200 90 : 10 State-of-the-art violet : state-of-the-art magenta : FW 200 35 : 35 : 20
Test system 90 parts effect pigment C* 10 parts FW 200
h Lumina® Royal Magenta exhibits the highest chroma in black reduction
32 150 Jahre
Coloristic properties
Lumina® Royal Exterior Magenta EH 5000 (4803H) In a magenta styling
Lumina® Royal Exterior Magenta EH 5000 (4803H) : L 4540 : FW 200 = 45 : 50 : 5 State-of-the-art violet : state-of-the-art magenta : L 4540 : FW 200 = 17.5 : 27.5 : 50 : 5
Test styling 45 parts effect pigment C* 50 parts Cinquasia® Magenta L 4540 5 parts FW 200
h Lumina® Royal Magenta exhibits the highest chroma in pigment combinations
33 150 Jahre
Coloristic properties
Lumina® Royal Exterior Magenta EH 5000 (4803H) More chromatic than the state of the art
EH 5000 : L 4540 : FW 200 = 45 : 50 : 5 5803H : L 4540 : FW 200 = 45 : 50 : 5 4303D : L 4540 : FW 200 = 45 : 50 : 5 5803H : 4303D : L 4540 : FW 200 = 22.5 : 22.5 : 50 : 5 5803H : 4303D : L 4540 : FW 200 = 27.5 : 17.5 : 50 : 5 State-of-the-art violet : state-of-the-art magenta : L 4540 : FW 200 = 17.5 : 27.5 : 50 : 5 C* Test styling 45 parts Lumina® Royal Exterior Magenta EH 5000 50 parts Cinquasia® Magenta L 4540 5 parts FW 200
Hue matches based on combinations of Lumina® Royal Indigo with Lumina® Red have lower chroma Hue matches based on combinations of state-of-the-art violet and magenta have lower chroma h Lumina® Royal Magenta unmatched by state-of-the-art effect pigments
34 150 Jahre
Styling options
Lumina® Red 4303D Lumina® Royal Exterior Magenta EH 5000 (4803H)
50 pts Paliogen® Red L 3885 P.R. 179 50 pts Paliogen® Red L 3885 45 pts Lumina® Red 4303D 45 pts Lumina® Royal Ext. Magenta 5 pts Carbon Black FW 200 EH 5000 (4803H) 5 pts Carbon Black FW 200
50 pts Irgazin® Rubine L 4025 (TR) P.R. 264 50 pts Irgazin® Rubine L 4025 (TR) 45 pts Lumina® Red 4303D 45 pts Lumina® Royal Ext. Magenta 5 pts Carbon Black FW 200 EH 5000 (4803H) 5 pts Carbon Black FW 200
50 pts Cinquasia® Magenta L 4540 (RT-355-D) C.I. n.a. 50 pts Cinquasia® Magenta L 4540 (RT-355-D) 45 pts Lumina® Red 4303D 45 pts Lumina® Royal Ext. Magenta 5 pts Carbon Black FW 200 EH 5000 (4803H) 5 pts Carbon Black FW 200
50 pts Paliogen® Blue L 6480 P.B. 60 50 pts Paliogen® Blue L 6480 45 pts Lumina® Red 4303D 45 pts Lumina® Royal Ext. Magenta 5 pts Carbon Black FW 200 EH 5000 (4803H) 5 pts Carbon Black FW 200
Lumina® Royal Magenta in combination with organic pigments leads to brilliant effect shades between Lumina® Red and Royal Indigo
35 150 Jahre Please get in touch with your local account manager Marketing Pigments for Automotive Coatings 150 Jahre