, . VJU|FCI J U « ENVIRONMENTAL LABORATORIES, INC. ^Jf' I^ S flnaivtieaianalytica l testintestinag ananddenvironmentaenvironmentallsciencesciencess liKfcAK 142 Twipto SSMt Nmv Haven CT 06510 (203) 789-1260 OTHER: J^jg}{^ EPA«C7-02t Com. Cen. #PH.04SC /' ' NAME/ADDRESS: Mr. Robert F. Moody
Raymark Industries, Inc. SDMS DocID 464969 . 75 East Main Street Stratford, CT 06497
E U PROJECT NUMBER: 91-545-18
EU SAMPLE NUMBER(S): 93-0090 93-0092
COIXECTED BY: EU/JP
DATE COU£CTED: 1-24-94 DATE RECEIVED: 1-25-94
COMPLETION DATE: 1-31-94
Reviewed and Approved by: Date: yj^/y y^oben Schock, Laboratory Division Manager
Tltis icpon b 'PROPRIETARY AND CONFIDENTIAL* and delivered to, and intended for the exclusive uie of tbe above named clieol only. Environmenul Labotaioriea, Inc. aiaimea no ieq>ooiibility or liability for the reliance hereon or uae hereof by anyone other than the above named client.
94FEBWK1J
A SUBSIDIARY OF ENVIRONMENTAL AND INFRASTRUCTURE CONSULTANTS. INC. (EICON) BRIDGEPORT . NEW HAVEN • HARTFORD RESULTS OF ANALYSIS;
SAMPLE DESCRIPnON: SB-68 02-04 SB-7 04-06 SB-68 06-08
EU SAMPLE NUMBER: 93-0090 93-0091 93-0092 FARAMETER UNITS
TotalLead: Wet Weight 2,593 mg/Kg 1.56 % W/W 1.44 % W/W Diy Weight 2,998. mg/Kg 2.44 * W/W 2.01 % W/W
Total PCB's: Wet Weight 45.9^ 177.» 76.8' mg/Kg Dry Weight 53.1' 277.' 107.' mg/Kg
Percent Solid 86.5 63.9 71.7 %
' Matrix spike sample for lead analysis out of laboratory control limits (of 75 - 125 %) for this batch. Probably due to a dilution of the sample because elevated analyte levels. All other QA/QC are within laboratory control limits.
' Aroclor 1268
ND • Nooe Detected BDL - Below Dctrctioa Limit ENVIh /lENTAL LABORATORIES. INC. Chain Custody 142 Tompio Street /V». Haiieh, Cl' Oi anal/ticai tatting and environmerttsl sciences Conn. C««t. #PM-0450 EPA IC
Project Name: Raymark Phase UB ANALYSIS REQUIRED Project Location: Stratford, Conaectictit ITIM NUr^lBER: 10 III I U U 14 Project Number: 91-545-11 Tn
LABORATORY: EU AQUATEC EEG TLI
B««tlc Siic/Code: LAB No. »r B«ttl(s: ID
pTBerre:
ANALVnCAL TESTING D c C METHODS A o a STA. T M M A SAMnt iDooincATiot* FVMC lOltl No. C C r NUMSU
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SAMPLER'S SIGNATURE AfTILIATION Time TRNSF ITEM .TRANSFERS NO. NO. CINQI ACCEPTED BV DATE TIME ± ^^l^^-j^j^ fgj^^ /loO^ RCMAIU'ftM^-U . / J I ll
ArlUikL fy^' ill-/ (fille^rtl S^f/«:)«.^.1 ' n ENVIRONMENTAL LABORATORIES, INC. i^ B 5 analytical testing ani d environmental sciences
142 Tample SsMt Naw Haven CT 06510 (203) 789-1260 EPA «CT-0. Conn. Can #PH.04
NAME/ADDRESS: Mr. Robert F. Moody Raymark Industries, Inc. 75 East Main Street Stratford, CT 06497
FTI PROJECT NUMBER: 91-545-17
FT ,1 SAMPLE NUMBER(S): 94-0050
COLLECTED BY: EU/JP
DATE COLLECTED: 1-18-94 DATE RECEIVED: 1-18-94
COMPLETION DATE: 1-24-94
Reviewed and yy/yi- ^ y^^ / n / ^^/^/ Anprovcd bv: .^'P^^ J^^^^JY Date: / ' X / " / 7 " Robert'Schock, I iiboratory Division Manager
TUi fcpon U 'PROPRIETARY AND CONI-IDENTIAL' UKI deiivet«d to, and mteoded for the exclutive ueeofthe above named clieiu only. Eaviromneaial Labofatoriea, Inc. anumea no reqmnnbUity or liability for tbe reliance bereao or uae beieof by anyone other than tbe above named ciieal.
94iANWK4.24 I
A SUBSIDiARV o r ENVIRONMENTAL AND INFRASTTtUCTunE CONSULTANTS. INC. (EICON) BRIDGEPORT • NEW HAVEN . HARTFORD }fY^}^Jfi OF ANALYSIS: SAMPLE TOTAL TCLP SLP DESCRIPTION LEAD LEAD LEAD EU SAMPLE mg/Kg mg/L mg/L NUMBER:
94^50 SBIO 18-48" 37. 0.34 ND < 0.20
Percent SoUds = 95.7
ND- None Detected BDL > Below Detectioo Limit RK5UT.TS OF ANALYSE! METOOD 8080 PC35
SAMPLE DESCRIPTION: SBIO 18-48" KI J SAMPLE NUMBER: 94-0050
TOTAL TCLP SIJ» (ms/Kg) (mg/L) (mg/L)
PCB-1016 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1221 ND < 2.0 ND < 0.020 ND < 0.020 PCB-1232 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1242 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1248 ND < 0.2 ND < 0.002 ND < o.m PCB-1254 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1260 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1262 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1268 7.1 ND < 0.001 ND < 0.001
ND - None Delected BDL - Below Detection Liniit i-ivviH i tvlAL LABORATUmES. INC . Chain "ustody 142 r«rti,»(cj Street /V«» ven. cr 06 ''""'vJical I ,j find environmental ,scJencas Conn. Cert. #PH O450 CPAdCT
^V.^ject Name: Rayiii-rk Phase IIH f*rojecl Locafioii: Siirtirord, Conjietiii ui • VViijt;; Ntimber; 91 .'^45-17
SuuacECopf.^; w := wiji. o otHFAij. r 'IHK SO Smxit <; SOIL PHI-AljivAnVtCOPei: A = A'» OK BIC ACID N NiTKU: ALIO (HNOJ S S'HillAt L LAOOON TR I«I:>IT-U X OTMM • pimsc llM)Ri)>.l|lF. (NAOH ) H " IbliKiKTHIORICACID fHCl.) I IcCD F " Fll1t«>X) E AMRIJI EPA VIAL BomjStZ^: I . 40.f . ^ |2JoC J 2VI.. 4 . SOO CC S l bAMPLER'^ SVjfiA niHI; A»Mi I ^ | u REMABU: Oc/'^Cy NAME/ADDRESS: Mr. Robert F. Moody Raymaik Industries, Inc. 75 East Main Street Stratford, CT 06497 FT .1 PROJECT NUMBER: 91-545-17 E U SAMPLE NUMBERCS): 94-0050 COLLECTED BY: EU/JP DATE COLLECTED: 1-18-94 DATE RECEIVED: 1-18-94 COMPLETION DATE: 1-24-94 Reviewed and /^yP\- ^ / ^ / yi>/ ^^/^Z Aooroved bv: ^ ^ Jy<^^j7^ Date: /'P/r-/y Robert'Schock, 1.ahoratory Division Manager Thu fcpoft it 'PROPRIETARY AND CONFIDENTIAL' and deliverad lo, end intended for the excluiive the relience beraoo or lue hereof by anyone other than tbe above named cbent. 94JANWK4J4 1 A SUBSIDIARV (3F ENVIRONMENTAI. AND INFRASTRUCTURE CONSULTANTS. INC. (EICON) BRIDGEPORT . NEW HAVEN . HARTFORD SAMPLE TOTAL TCLP SLP DESCRIPTION LEAD LEAD LEAD F U SAMPLE mg/Kg mg/L mg/L NUMBER: 94-0050 SBIO 18-48" 37. 0.34 ND < 0.: Percent Solids = 95.7 ND - None Detected BDL - Below Detection Limit FRSTTT.T? Of ANAl-YSJS: MKTHQP g08Q ECBs SAMPLE DESCRIPTION: SBIO 18-48' E U SAMPLE NUMBER: 94-0050 TOTAL TCLP SLP (mg/Kg) (mg/L) (mg/L) PCB-1016 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1221 ND < 2.0 ND < 0.020 ND < 0.020 PCB-1232 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1242 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1248 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1254 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1260 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1262 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1268 7.1 ND < 0.001 ND < 0.001 ND - None Detected BDL • Below Detection Limit i-WviHL fcMAL LABORAIUMIES, INC. Cham Custody 142 refrr.,^16 Street fit /avan. CT Oi inniytlcal ^ttni hnd environmental science! Conn. Cert. *PM O4S0 EPA fC yr»]tti Nttnit: Rayin-rk Phase IIB ANALYSIS REQlrtRI'n Projec* LocalHiiv: Siiatfoid, Coimctii>ui l*riije.} Ntimber: 91 .'45-17 •rrrst si -.frcR: II U I; 13 14 LAM)h>.":.)KV: • Ell '-Ul.ATEC EEC Tl.l V-M S:..> ud«: OL LAD Ne. of B- ti fx^terte: s ANAl.^":^<:M, • I TEST INC D c c ^u:TMllll^ A o a nd d ('•.«t«.iiti T A I ?» S o ( ti! ^ l^^l--iIilki\cy*.'L • X fn-fi tf'Hf^ t / TYCO.!. V ± StiiiBCECopf4| w •= wijj o - OuTFAij r • '»NK so siiixit ^ suit |'»ni>VAnv|-Copet: A = AN.-iSBic ACIO N - Nir«ii: ACID (HNOJ S •S'iiiiu»4 L - LAUOON TR - lRi>iH) X - Omi^ji • MiiivE llMXiiMiiF. (NAOH) 11 « ihincK.-HiflwcAaDfllCi.) I - IccD F - Fiin»u) E - AMDia EPA VIAL BuULtlEt 1-40.1 . - iJJcc 3 - jvi.. 4 J ^oooc 5 - i'l"! •; r - SiiiiKiM TXlOSUIjAtl-. V "^ SdltllKIC Aai> )N ^^••p^\i^^ 7?I7l ft X REI4ABK*: W ENVIRONMENTAL LABORATORIES. INC. I- " analytical testing and environmental sciences M2 TenwM SiiMl Nr» Havwi CT 06510 (203) 789-1260 EPA «CTO Com Cen «PH.Od NAME/ADDRESS: Mr. Robert F. Moody Raymaik Industries, Inc. 75 East Main Street Stratford, CT 06497 E U PROJECT NUMBER: 91-545-17 FU SAMPLE NUMBER(S): 94-0050 COLLECTED BY: EU/JP DATE COLLECTED: 1-18-94 DATE RECEIVED: 1-18-94 COMPLETION DATE: 1-24-94 Reviewed and /yfy)- ^ ^y* / yi// ^ y / ADDTOvedbv: y^<> J^.^£y/r Date: /'P/X'/ z - ' Robert Schock, Laboratory Division Manager Tliii repon b -PROPRIETARY AND CONFIDENTLa* and deliverad lo. and intended for the excluove lueoflfaetbawc named client only. EoviroaoKaul Labontonea. Inc. anumea no toponability or liability for the reliance beraon or lue hereof by anyone iMfaer than tbe above named client. 94JANWK4.34 1 A SUBSIDIARY OF ENVmONMENTAL ANO INFRASTRUCTURE C0I4SULTANTS. ItC. (ECON) BRtOGEPORT • NEW HAVEN • HARTFORD SAMPLE TOTAL TCLP SLP DESCRIPTION LEAD LEAD LEAD E U SAMPLE mg/Kg mg/L mg/L NUMBER: 94-0050 SBIO 18-48" 37. 0.34 ND < 0.: Percent Solids = 95.7 ND •• None Detected BDL V Below Dmiiction Limit pP5!Tn.TS OF ANALYSIS: MFTHOD 8080 PCBs SAMPLE DESCRIPTION: SBIO 18-48" FU SAMPLE NUMBER: 94-0050 TOTAL TCLP SLP (mg/Kg) (mg/L) (mg/L) PCB-1016 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1221 ND < 2.0 ND < 0.020 ND < 0.020 PCB-1232 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1242 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1248 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1254 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1260 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1262 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1268 7.1 ND < 0.001 ND < 0.001 ND - None Detected BDL - Below DatMtioa Linut LivviH fcMAL LABORATUMIES , INC. Chain 7ustody 142 rem,1,0 Street Ne even. CT Ot "intiyiical ini t'^d environmental sciences Conn. Carl. «PM O450 EPA fC ^V..jen Ntimt: Kaytn-rt Phase IIH ^fi'ltd LOOIIHIII: SliMifoid. CoDi)c<.ii< ul • J'Tiije:: Ni;inb«r. 91 .'45-17 S«)ti>CECopfa; W -. Wij, . U OUTfAll. f UNK SO Sllixi t S SOIL I'U yMM V A n vt Copo: A " A-x OR BIC AOO N Niiitu: ACID (HNOJ S • S-MHUM L •• LAOOON TR " iBt>M>-u X OTMI-JI • iit>iNE HMIROMICCNAOH ) H llvi>i«K:HIX)lllcAaD(HCl I I > !c:CO F Fll tl»ii) C AMHijt EPA VIAL BL'm£ Sg^j I 4U REMAaU: > H ENVIRONMENTAL LABORATORIES, INC. =.i^ m S analytical testing and environmental sciences ^• H V V 142 Tempw Street Nw* Havener 06510 (203) 789-1260 EPA »CT-02t Conn. Cen *PH^VI5C NAME/ADDRESS: Mr. Robert F. Moody Raymark Industries, Inc. 75 East Main Street Stratford, CT 06497 E U PROJECT NUMBER: 91-545-17 E U SAMPLE NUMBER(S): 94-0050 COLLECTED BY: EU/JP DATE COLLECTED: 1-18-94 DATE RECEIVED: 1-18-94 COMPLETION DATE: 1-24-94 RevieweKeviewed anda yyfy^i- /^ '^^ y yi / ^'yy Approved by: A<^^ M^J^j ^ Date: y-JP/'/y Robert Schock, Laboratory Division Manager Thii report ii 'PROPRIETARY AND CONFIDENTIAL* and delivered to, and intended for the excluiive uae of tbe above named client only. Eovironmenlal Laboratoriea, Inc. aifumet no reaponsibility or liability for the reliance bereon or uae bereof by anyone other than Ihe above named client. 94JANWK4.24 A SUBSIDIARY OF ENVIRONMENTAL AND INFRASTRUCTURE CONSULTANTS. INC. (EICON) BRIDGEPORT . NEW HAVEN • HARTFORD SAMPLE TOTAL TCLP SLP DESCRIPTION LEAD LEAD • LEAD E U SAMPLE mg/Kg mg/L mg/L NUMBER: 94-0050 SBIO 18-48" 37. 0.34 ND < 0.: Percent Solids = 95.7 ND •> None Detected BDL •• Below Detection Limit RESULTS OF ANALY.ST.S METHOD 8080 ECBs SAMPLE DESCRIPTION: SBIO 18-48" EU SAMPLE NUMBER: 94-0050 TOTAL TCLP SLP (mg/Kg) (mg/L) (mg/L) PCB-1016 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1221 ND < 2.0 ND < 0.020 ND < 0.020 PCB-1232 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1242 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1248 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1254 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1260 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1262 ND < 0.2 ND < 0.002 ND < 0.002 PCB-1268 7.1 ND < 0.001 ND < 0.001 ND - None Detected BDL • Below Detection Limit LKviH^^-'l-M/^L LABORATUMIES, INC. Chairr 'Custody 142 Tnrr.,iie Street Ne. iven, CT 061 in>iivticai m rttid environmental sciencsi Conn. Cert. »PH O450 EPA #CT ^V.»jert Nunit: Hayrn-rk Phase IIB ANALYSIS REQlJTRI-n Project Localioii: Sii^troid. Coiuitxii. ui 14 l*rnje:J Ntimber: 91 .':45-17 •ITCSI N' -.flCR; II U t; 13 T LAf.Ok>.":'iKV: ELI ».giATBC ESC TII P-3« Si:».i'ud*: J^ LAD I No.'ifB- -..Irs: ID fxeatrtt: 1. ANAI.^TICAL •» TESTINC a.^ D c MtTM.iii:.iMiM>.s^ nvr11>' -J A o hi T A SAMTUE IncND.i' ' MON ndd 7—m M C • Nl'l-IBLV r ?3. CCI i/i^/^i \CA-^C>_ y ^B-iQ l3^H^'' v/ ?'/CC\'j(^ I- I ! = StiUWCE CopF^ W -^ Wijj. O - OmFAIJ. r ^ ^;^slC SO - Sl I isib l>VAnvt COOO: A = AvimBicAaD N - Niruii: AClD(HNOJ S -S-MHUM- BomijC'iota: t " LAOOON TR - TRi>t>v X • OmM - i>msE IIM>RII>.I|)R(NAO|{) M - ll>l)H<>CMl/OMCAaD (HCl.i I - ICED F - Fllll»»]) E - AMHiJi EPA VIAL B<»ni£ SIZE: I « 40.t . - I25CC 3 - 25i). . 4 - ^00 OC 5 => I'Xifi .; r ' Sii|it(IMTHIOSUt>AII: V - Slili-1)«ICAaiMH,S(),) Z - ZIMC ACtTATF. A - AMDMI C - CUEAII REMAUU: \ INTEROFFICE MEMORANDUM TO: Richard Desrosiers P FROM: Robert Schock SUBJECT: Raymark Treatability Analysis; TCLP vs. SLP EU #91-545-32 DATE: January 12, 1994 Attached are two reports and the associated QA/(^ for the comparison of the TCLP (EPA Method 1311) and SLP (EPA Method 1312) extraction procedures. In addition, the laboratory was able to obtain water from Well A-1 which was also used as an extraction medium for one of the tests. Please note that the well water was filtered prior to use in the laboratory. Report number one, dated 01-04-94, compares the TCTLP/SLP metal results from, three separate soil samples (SB21 01-02, SB20 06-08 and SB30 05-07). Prior to analysis, the soil samples were thoroughly mixed by laboratoiy personnel in an effort to achieve the greatest degree of homogeneity possible. The most striking result of the study is the apparent contrast in the aggressiveness of the TCLP fluid relative to the SLP fluid when various metals are present in the sample matrix with lead, copper and zinc showing the most pronounced differences. A compilation of these results follows with the respective variations in results: SAMPLE SB21 01-02 SL£ TCLP Difference Cu 1.04 314 301.9 x Pb 0.56 740 1321 x Zn 0.39 108 276.9 X SAMPLE SB20 06-08 SLP TCLP Difference Cu 0.32 376 1175 X Pb <0.2 462 Zn <0.04 14 .ENVIRONMENTALLABORATORIES, INC. Raymark Treatability Analysis; TCLP vs. SLP EU #91-545-32 January 12, 1994 Page2 .<;AVrPT.FSB30 05-07 SLE TCLP PiffCTCTgg Cu 0.112 0.424 3.78 X Pb 5.26 286 54.4 x Zn 30 64 2.1 x Variations in the analytical results may be attributable to the form of the metal in the sample matrix. Metals can exist both in a wide variety of chemical complexes and crystalline forms with varying solubilities which may explain some of the variations encountered. There also exists the added fact that soils are notorious for being nonhomogeneous. Report number two provides several interesting pieces of information about the sample collected from the "Waste Pile" and the extraction media that were used. These are: • Again, the TCLP fluid appears to be a more aggressive extraction medium towards Cu, Pb and Zn. Analytical levels were considerably lower than samples in the first report, however. • Analytical precision between the duplicate samples is fairly good, with the worst results being for Cu using the SLP extraction fluid. Further studies need to be performed to determine if this is a result of the extraction efficiency of the fluid or a homogeneity effect. • Water from Well A-1 was also used as an extraction fluid and a blank (after it had been filtered). Again, precision was pretty good and appeared to be within acceptable limits considering that the samples were only performed in duplicate. The interesting point to note is that Cu and Zn were extracted by the groundwater sample while Pb was not. In conclusion, further studies using a single homogeneous sample should provide more precise data and prove the applicability of the SLP procedure to use on "real-world" samples. RJS/jd 053RM Enclosure .ENVIRONMENTALLABORATORIES, INC. ENVIRONMENTAL LABORATORIES. INC. analytical testing and environmental sciences 142 Temple Street Nw» •«««> CT 065101203) 7B9-1260 EPA = CT-c; Coim Cer. *»H NAME/ADDRESS: Mr. Robert F. Moody Raymark Industries, Inc. 75 East Main Street Stratford, CT 06497 E U PROJECT NUMBER: 91-545-32 EU SAMPLE NUMBER(S): 93-3019 - 93-3021 COLLECTED BY: EU/RD DATE COLLECTED: Various DATE RECEIVED: 12-13-93 COMPLETION DATE: 12-22-93 Reviewed and Approved by: _ D^:_AJ±J:^ R(4)ert Schock, Laboratory Division Manager Thb lepoil it 'PROPRIETARY AND CONFIDE?aiAL* and deliverMi to, and iaieaded (br the exehiiive uae of tbe abonre named clieat only. Eaviroameiial Laboniotie*. Inc. aininifi no re^Mnnbility or liability for tbe reliance betcon or uae bereof by anjroae other than tbe above named cliem. 94)ANWK1J A SUBSIDIARV OF ENVIRONMENTAL AND INFRASTRUCTURE CONSULTANTS. INC. (ECONl BfllOGEOORT . NEW HAVEN • HARTFORD RESULTS OF ANALYSIS: EXTRACnON DATE: 12-16^3ANALYSr: JF CONCENTRATION (ppm) SAMPLE IDENnnER: SB21 01-02 EU SAMPLE NUMBER: 93-3019 ANALYSIS TCLP SLP DATE ANALYST UN] Antimony' 0.007 ND < 0.005 12-22-93 PA PP' Aneaic ND < O.OIO ND < 0.010 12-17-93 PA ppi Barium 1.02 0.28 12-17-93 JM PP' Berylliiun BDL < 0.010 BDL < 0.010 12-17-93 JM ppi rarimiiim 0.040 ND < 0.010 12-17-93 JM PP' ND < 2* 0.02 12-17-93 JM W" Cobalt ND < 0.10 ND < 0.10 12-17-93 JM ppi Copper 314.^ 1.04 12-17-93 JM ppi Lead 740.* 0.56 12-17-93 JM PP' Mercuiy ND < 0.0005 ND < 0.0005 12-22-93 PA PP' Nickel 0.82 ND < 0.08 12-17-93 JM PP' Seleaium ND < 0.10 ND < 0.010 12-17-93 PA ppi Silver ND < 0.02 ND < 0.02 12-17-93 JM ppi Thallium ND < O.IO' ND < 0.010 12-21-93 PA ppr Tin' BDL < 0.50 ND < 0.50 12-22-93 JM ppi Vanadium ND < 0.10 ND < 0.10 12-17-93 JM ppi Zinc 108.* 0.39 12-17-93 JM ppi ' Extraction Date: 12-21-93 Analyst: GB * Analysis Date: 12-20-93 ' Quomium detection limit (TCLP only) raised to a dilutioo caused by matrix interference. * Matrix ^ike recovery is low. ND - None Detected BDL-Below j>rtflfiifm LJDBt 30 RESULTS OF ANALYSIS: ECTRACnON DATE: 12-16-93 ANALYST: JF CONCENTRATION (ppm) SAMPLE IDENTIFIER: SB20 06-08 EU SAMPLE NUMBER: 93-3020 ANALYSIS TCLP SLP DATE ANALYST UNT Antimony' 0.009 ND < 0.005 12-22-93 PA ppn Arsenic ND < 0.010 ND < 0.010 12-17-93 PA ppn Barium 3.58 BDL < 0.20 12-17-93 JM ppn Beryllium BDL < 0.010 BDL < 0.010 12-17-93 JM ppn PaHmiiim 0.056 BDL < 0.010 12-17-93 JM ppu Chromiimi BDL < 0.02 0.02* 12-17-93 JM ppn Cobalt ND < 0.10 ND < 0.10 12-17-93 JM ppn Copper 376,* 0.320 12-17-93 JM ppn Lead 462.* BDL < 0.20 12-17-93 JM ppn Mercury ND < 0.0005 ND < 0.0005 12-22-93 PA ppa Nickel 0.46 ND < 0.08 12-17-93 JM ppir Selenium ND < 0.10 ND < 0.010 12-17-93 PA pps SUver ND < 0.02 0.04* 12-17-93 JM ppm Thallium ND < O.IO* ND < 0.010 12-21-93 PA ppm Tin' ND < 0.50 ND < 0.50 12-22-93 JM ppa Vanadium ND < 0.10 ND < 0.10 12-17-93 JM ppm Zinc 14.* BDL < 0.04 12-17-93 JM ppn: ' Extraction Date: 12-21-93 Analyst: GB * Analysis Date: 12-20-93 ' Matrix spike recovery is low. * Chromium and silver result fbr SLP is greaier than TCLP. ND - None Detected BDL - Bekw Deiactioo Loi t 31 RESULTS OF ANALYSIS: EXTRACTION DATE: 12-16-93 ANALYST: JF CONCENTRATION (ppm) SAMPLE IDENTiraER: SB30 05-07 E U SAMPLE NUMBER: 93-3021 ANALYSIS TCLP SLP DATE ANALYST UN n Antimony' ND < 0.005 ND < 0.25* 12-22-93 PA ppm Axwoic ND < 0.010 ND < 0.010 12-17-93 PA ppm Barium ND < 0.2 ND < 0.20 12-17-93 JM ppm Beryllium BDL < 0.010 BDL < 0.010 12-17-93 JM ppm 0.018 BDL < O.OIO 12-17-93 JM ppm Chromium* ND < 2. ND < 2. 12-17-93 JM ppm Cobalt 0.48 0.28 12-17-93 JM ppm Copper 0.424 0.112 12-17-93 JM ppm 286,* 5.26 12-17-93 JM ppm Mercury ND < 0.0005 ND < 0.0005 12-22-93 PA ppm Nickel 7.90 3.28 12-17-93 JM ppm Selemiimi ND < 0.10 ND < 0.010 12-17-93 PA ppm Silver ND < 0.02 ND < 0.02 12-17-93 JM ppm Thallium ND < 0.10* ND < 0.010* 12-21-93 PA ppm Tin' ND < 0.50 ND < 0.50 12-22-93 JM ppm Vanadiiui ND < 0.10 ND < 0.10 12-17-93 JM ppm Zinc 64. 30. 12-17-93 JM ppm ' Extnction Date: 12-21-93 Analjrst: GB * Chromiiun detection limit raised to a dilutioa by matru mierference. ' Matrix spike recovery is low. * Analytical spike recovery on full atreoftfa saaple adiftwl a negative interfereooe. The sample was diluted and respiked until; acceptable ^ike recovery was obtained. (Final fador 1:50) ' Analysis Date: 12-20-93 * Analysis Date: 12-22-93 ND - None Detected BDL - Below r>*"*»t~ti Limit 32 rn-w^ew crA am-iHH rojecl Niunc: Raymark Phase IIB ANALYSIS REQUIRED rojcci Location: Slralford, Coonecticul reject Number: 91-54547*72. ITfM NUMBER! IB I II U I 13 14 LABORATORVi ELI AQUATEC EEG TU BlU«Sh«/C«4« j® ^ ( ^ LAB Na. at Boal«i ! 1 ID rnMrvti fi^ «h 5P ANALYTICAL TESTING D T c G i METHODS A I o R ITA. T M M A SAMTLK iDKNnnCATKM rWUCaMiaaM 40. B K r B NUMBER JiSE P! y H Lbji^ j / 6B^/ fl/-o^> UAJ ' H^gPt^ •/^ joii ;«o 1/ .ST^TA tf^-6^ 'A?if(ir y \Q2C\ f& fsi^3£.. tivr- ^g^ft fsf<=>^ •?<»,f'^y^r- ./ J^L ^^/^^CB CODES: W - Wai. O • OinrAU. T •• TANK SO • SLUOOB 9 - SOIL pBEieavATiVE ^poeij A - Aicotatc ACU> N - Nrrmic AOD (HNOJ S - SOOHJM • • LAOOON TK - TREAno X •• omoi •-oinNB HYDRonoe (NAOH) H - HvoaocHijaBic Aao (HCg I - Icco F - FH.TEta> E - AMRER EPA VIAL irngfne! I - 4O0C 2 - USoc 3 -ZSOoc 4 -SOOoc S - lOOOoc T - SOUUM THIOSULFATC P - SULfUMC AaiXtl,SOJ Z - ZINC ACRTATB A - AMRER C •• CLEAR BMARKS: lH SBa^r-- ^MdJ^l y^^ ^/a rtitt,\^ 9r^ ftrttAii^ • a .niM •••*iiw>a>ii«ll| IVoJecl Name: RRymark Phase IIB ANALYSIS REQUIRED iVoJeci Location: Slraiford, Cooneclicul IVoJert Number: 91 -545-17 ITEMNUMBEIU 3 4 IB I 11 U I 13 14 LABORATORYt ELI .JIQUATB<^^^ J -cee Bowh Sit/Cadw fi % I KI ^ Na.WBo«tlMt ID s ANALYTICAL o TESTING D c G u METHODS a A o B B 4 i 4 STA. T M M A C SAMPLE lociaincA'noN ntUCwua a VT v/> No. B B P B NUMRER ^fO /3^ y •gfl-<3 <^3-g'h iti^^ J y J i?/Sl CALY> y i U cai£i2. i L ^ y JL y y b2<:> M l y tffl-W Oiz^^ • ' ^ Z / :2L 11^ / rtn-iVl £!k:£^ z v / j5;i /?1< t / IfCRCOPEl: W •• WELL O - OUIFALL T - TANK SO - SLUDOE S - SOIL PREltRVATlVE CODEl: A * AlCOMIC AOD N - NlTRIC AQD (HNOJ S •• SOMUM • BftTTUCPPHi « LAOOON TV •• TREATED X •-OTHER *-OEnNE HvDaoxioe (NAOH) H •• HVDIOCHLOMC AOU (HCL) I - ICED F •• FILTERED E •• AMBER EPA VIAL BTHJlSm: I - 40cc a •• IISCC 3 -UOoc 4 -SOOCC S - lOOOoc T > SODIUM TXiosuLr^TE P •• SuLfvajc Aao(H,SO,) Z •> ZINC ACETATB . A - AMBER C •• CLEAK tMn.M'SaCWATUBE AfnUATlON Hsu TRNSF ITEM TRANSFERS NO. NO. iyELINQUISIiqaiNQUISIIU> BY ACCEPTED BY DATE 1630 h3 M /v>^/f3 MARIS: w^ ' f ^ / j >ttn«- t*^<^r^ ^'^^ I^C lMl£@[r®LrifD©© IMilJlfD© LglAg^Lf^ T^: "^k I Cr^Ue^ Datm: 12^/1^/13 g^BWi '^.>cJL~T^fl^roSHP#;r Pro). No: fl^SHS-s2. Subject: "TCJj^ /f^tiP /^yttsJi,*)^ Tasr^ ^ -f^i^u /^?^ -^'^'^ - ^ .yyT^JSi^yj y^y*^ ^yol ^ .A^ ^^je> ^ ^t^ioZe^ ^li Zl Of-DL (X2P ' ^Cl^ff^ - r,ey Amkt^ S^t g'B ao or-o? rARp > ^ci.K^ ffm 10U) - Field iheit^ gt^fe -72UMJU ^Jou^/j/i JAy^tnJsl .y/y^ ytjC^^^t.^ .jLy> Tg^l^/* y C^IL/^ ^^^^ ^^ \—^^X y Signatur* ENVIRONMENTAL LABORATORIES. INC. analytical testing and environmentai sciences U2 TefivM SirMi **»» ^Mven CT 06510 (203i 7B9-126C Conn Cer •o«.0 NAME/ADDRESS: Mr. Robert F. Moody Raymaik Industries, Inc. 75 East Main Street Stratford, CT 06497 E U PROJECT NUMBER: 91-545-33 E U SAMPLE NUMBERCS): 93-3081 COLLECTED BY: EU/JP DATE COLLECTED: 12-22-93 DATE RECEIVED: 12-23-93 COMPLETION DATE: 1-06-94 Reviewed Rnd jy^PC''// j^ / /- y Approved by: /^lyPp^/^J^ Date: /^r3^- TUi npon ii fVOPRIETAKY AND CONFIDENTIAL* aod ddiveied to. aad naoded for tbe exehuive me of ttaa above nuDod ebcai ooly. EaviwwiuBWil LibocMoriei, Inc. innium no icgpofaibility or b»bUity for tbe nliaace iMiwa or Me bereof by aoyooe olber tbea tbe above oeaed clieA. I MIANWKI.7 © * S'.'BSQiARV 0= cMVtRONMcNTAL AO iNFRASTTtUCTjRE CONSULTANTS. INC. (EICON) anOGsPOn ' • NEW HAVEN • HARTFORD RESULTS OF ANALYSIS: EXTRACTION DATE: 12-3093 ANALYST: JM CONCENTRATION (ppm) SAMPLE IDENTIFIER: Waste Pile EU SAMPLE NUMBER: 93-3081 TCLP TCLP SLP SLP ANALYSIS ANALYST DUP. DUP DATE Antimony' ND < 0.0Q5 ND < 0.005 ND <0.25» ND<0.25» 1-06-94 PA Aisenic ND < 0.010 ND < 0.010 ND < 0.010 ND < 0.010 1-03-94 PA Barium 0.78 0.72 BDL < 0.20 ND < 0.20 1-04-94 JM Beryllium BDL < 0.010 BDL < 0.010 BDL < 0.010 BDL < 0.010 1-04-94 JM Cadmium BDL < 0.010 ND < 0.010 BDL < 0.010 ND < 0.010 1-04-94 JM Chromium BDL < 0.02 ND < 0.02 BDL < 0.02 ND < 0.02 1-04-94 JM Cobalt ND < 0.10 ND < 0.10 ND < 0.10 N D < 0.10 1-04-94 JM Copper 3.86 2.56 0.358 0.174 1-04-94 JM Lead 1.48 1.18 BDL < 0.20 ND < 0.20 1-04-94 JM Mercury BDL < 0.0005 ND < 0.0005 ND < 0.0005 ND < O.OOQS 1-03-94 JM Nickel BDL < 0.08 ND < 0.08 ND < 0.08 ND < 0.08 1-04-94 JM Selenium ND < 0.010 ND < 0.010 ND < 0.010 ND < 0.010 1-03-94 PA Silver ND < 0.02 ND < 0.02 ND < 0.02 ND < 0.02 1-04-94 JM Tballiiun ND < 0.010 ND < 0.010 ND < 0.010 ND < 0.010 1-04-94 PA Tin' ND < 0.50 ND < 0.50 ND < 0.50 ND < 0.50 1-05-94 JM Vanadium ND < 0.10 ND < 0.10 ND < 0.10 ND < 0.10 1-04-94 JM Zinc 1.10 0.94 0.28 0.22 1-04-94 JM ' Extraction Date: 1-04-94 Analyst: GB/PA ^ Analytical spike recoveries indiratr a matrix interference associated with these samples. Respiking diluted samples at factors 1:5, 1:10, and 1:50 showed ix> improvement in recoveries. . ^ Duplicate sample was not diluted. The detection limit was raised for comparison purposes. ND - NooeDcteeiad BDL - Below Dnrction LioMt RESULTS OF. ANALYSIS: ETTRACnON DATE: 12-30-93 ANALYST: JM CONCENTRATION (ppm) SAMPLE IDENTIFIER: Waste Pile Q J SAMPLE NUMBER: 93-3081 WeOA-1 WeU A-1 WeU A-1 ANALYSIS ANALYSl DUP. Blank DATE Antimony' ND < 0.25» ND < 0.25* ND < 0.25» 1-06-94 PA Aiseoic ND < 0.010 ND < 0.010 ND < 0.010 1-03^94 PA Barium ND < 0.20 ND < 0.20 ND < 0.20 1-04-94 JM Beryllium BDL < 0.010 BDL < 0.010 BDL < 0.010 1-04-94 JM Parfpiiittii ND < 0.010 ND < 0.010 BDL < 0.010 1-04-94 JM Chromiimi ND < 0.02 ND < 0.02 ND < 0.02 1-04-94 JM Cobalt ND < 0.10 ND < 0.10 ND < 0.10 1-04-94 JM Copper 0.110 0.090 ND < 0.050 1-04-94 JM Lead ND < 0.20 BDL < 0.20 ND < 0.20 1-04-94 JM Mercury ND < 0.0005 ND < 0.0005 ND < O.OOQS 1-03-94 JM Nickel BDL < 0.08 ND < 0.08 ND < 0.08 1-04-94 JM Selenium ND < O.OIO ND < 0.010 ND < 0.010 1-03-94 PA Silver ND < 0.02 ND < 0.02 ND < 0.02 1-04-94 JM Thallium ND < 0.010 ND < 0.010 ND < 0.010 1-04-94 PA Tin' ND < 0.50 ND < 0.50 ND < 0.50 1-05-94 JM Vanadium ND < 0.10 ND < 0.10 ND < 0.10 1-04-94 JM Zinc 0.36 0.28 ND < 0.04 1-04-94 JM ' Extraction Date: 1-04-94 Analyst: GB/PA 2 Analjrtical spike recoveries indirate a matrix interference associated wdth these samples. Req>iking diluted samples at fmcton 1:5, 1:10, Rnd 1:50 showed no improvement in recoveries. ' Di^licate sample was not diluted. Tbe detection limit was raised for comparison purposes. ND BDL' ENVIROl iNTAL LABORATORIES, INC. Chain o, .^ustody 142 Temple Street New noven, CT 065 analytical testing and environmental sciences Conn. Cart. #PH-04B0 EPA «CT-i Project Name: Raymark (RCRA) ANALYSIS REQUIRED Project Location: Stratfoid, Cooneclicut ITEM NUMBERt 11 Project Number: 9\-5A5-t^3S LABORATORYt EEC TLI Bottle Skc/Cedc: LAB No. af Bottltt! ID PrtMrrc: ANALYTICAL TESTING D T C G METHODS A I o R STA. T M M A SAMTtC iDCminCATION No. t t r fl NtMSCR 14)L Mu isi5 y r^i/wg- f'/v 30SI t±i H SouRcB CODES; w • WELL O - OUTTALL T • TANK SO - SLUDOE S - SOIL FRESERVATIVp CODEl! A - ASCORSIC AOD N « NrtRIC ACID (HNO,) S - SOOIUM • BsnuLCscBa! L - LAOOOH TR • TREATED X • OTKER • - DEFINE HYDRonoe (NAOH) H - HVDROCHLORJC ACID (HCL) I - ICED F •• FILTERED B - AMBER BPA VIAL BOTTLE SIZE: 1-40CC 2-125CC 3-230CC 4-JOOCC 5- 1000 cc T - SoDitm THIOSULFATE P - SULFURIC AaD(H,S04) z > ZINC ACETATE A - AMBER C - CUV •SAMPLER'S SlGNATintE AmUATiQN Pan TIBH TRNSF ITEM NO. NO. ACCEPTED BY DATE TIM pa: i'7l< ) iu^VCLv^ t3cn/^&a.v y^y?.'. iu REMARKS! dt. /^ES/' /ff~ *7»«e- ^"Hr^ s ENVIRONMENTAL LABORATORIES, INC. I. S analytical testing and environmental sciences -142 Temple Street New Haven CT 06510 (203) 789-1260 EPA »CT-025 Conn. Cen *PH^)450 NAME/ADDRESS: Mr. Robert F. Moody Raymark Industries, Inc. 75 East Main Street Stratford, CT 06497 E U PROJECT NUMBER: 91-545-33 EU SAMPLE NUMBER(S): 93-3081 COLLECTED BY: EU/JP DATE COLLECTED: 12-22-93 DATE RECEIVED: 12-23-93 COMPLETION DATE: 1-06-94 A^'roved b^: y^^1^^>^ Date: //^^^Ay/ Robot Schock, Laboratory Division Manager TU* icpoit il 'PROPRIETARY AND CONFIDOmAL* and delivered lo. and tmended for the exclunve UM of the above vmaaui ebcal ooty. Eawiiomueaul Labocmlohes, Inc. aaaimes oo reqxmiibility or babUily for the leUance hcnoa or aaa bcraof b)r tajoaa other ihaa the above named client. I 94JANWK1.7 2B — ? A S'.-ES'OiAP'' O- ESvmONViSTA;. »K0 iN^BASTauCTuRE CONSULTANTS. INC. (EICON) BRiOGEOOflT • NEW HAVEN • HARTPOflD RESULTS OF ANALYSIS: EXTRACTION DATE: 12-30-93 ANALYST: JM CONCENTRATION (ppm) SAMPLE IDENTIFIER: Waste Pile KT .1 SAMPLE NUMBER: 93-3081 Tap TCLP SLP SLP ANALYSIS ANALYST DUP. DUP DATE Antimony' ND < 0.005 ND < 0.005 ND < 0.25^ ND < 0.25* 1-06-94 PA Arsenic ND < 0.010 ND < 0.010 ND < 0.010 ND < 0.010 1-03-94 PA Barium 0.78 0.72 BDL < 0.20 ND < 0.20 1-04-94 JM Beryllium BDL < 0.010 BDL < 0.010 BDL < 0.010 BDL < 0.010 1-04-94 JM Cadmium BDL < 0.010 ND < 0.010 BDL < 0.010 ND < 0.010 1-04-94 JM Chromium BDL < 0.02 ND < 0.02 BDL < 0.02 ND < 0.02 1-04-94 JM Cobalt ND < 0.10 ND < 0.10 ND < 0.10 ND < 0.10 1-04-94 JM Copper 3.86 2.56 0.358 0.174 1-04-94 JM Lra ' Extraction Date: 1-04-94 Analyst: GB/PA ^ Analytical spike recoveries indicate a matrix interference associated with these sanq>les. Respiking diluted samples at fiactors of 1:5, 1:10, and 1:50 showed no improvement in recoveries. ^Duplicate sample was not diluted. The detection limit was raised for comparison purposes. ND > Nooel BDL > Below Detcctioe Linil RESULTS OF ANALYSIS: EXTRACTION DATE: 12-30-93 ANALYST: JM CONCENTRATION (ppm) SAMPLE IDENTD1ER: Waste Pile E U SAMPLE NUMBER:; 93-3081 Well A-1 Well A-1 Wen A-1 ANALYSIS ANALYST DUP. Blank DATE Antimony' ND < 0.25» ND < 0.25» ND <0.25» 1-06-94 PA Arsenic ND < O.OIO ND < 0.010 ND < 0.010 1-03-94 PA Barium ND < 0.20 ND< 0.20 ND < 0.20 1-04-94 JM Beryllium BDL < 0.010 BDL < 0.010 BDL < 0.010 1-04-94 JM ND < 0.010 ND < 0.010 BDL < 0.010 1-04-94 JM Chromium ND < 0.02 ND < 0.02 ND < 0.02 1-04-94 JM Cohalt ND < 0.10 ND < 0.10 ND < 0.10 1-04-94 JM Cof^wr 0.110 0.090 ND < 0.0S0 1-04-94 JM Lead ND < 0.20 BDL < 0.20 ND < 0.20 1-04-94 JM Mercury ND < 0.0005 ND < 0.0005 ND < 0.0005 1-03-94 JM Nickel BDL < 0.08 ND < 0.08 ND < 0.08 1-04-94 JM Seleniimi ND < 0.010 ND < 0.010 ND < 0.010 1-03-94 PA Silver ND < 0.02 ND < 0.02 ND < 0.02 1-04-94 JM Thallium ND < 0.010 ND < 0.010 ND < 0.010 1-04-94 PA Tin' ND < 0.50 ND < 0.50 ND < 0.50 1-05-94 JM Vanadium ND < 0.10 ND < 0.10 ND < 0.10 1-04-94 JM Zinc 0.36 0.28 ND < 0.04 1-04-94 JM ' Extraction Date: 1-04-94 Analyst* GB/PA ^ Analytical ^ike recoveries indiratr. a matrix interference associated with these samples. Reqiiking diluted samples at factors of 1:5, 1:10, and 1:50 showed no improvement in recovenes. ^ Duplicate sample was not diluted. Tbe detecticn limit was raised for conqnrison purposes. ND-Noi BDL - Below Drtoctioii Limit ENVIROh NTAL LABORATORIES, INC. Chain o. jstody 142 Temple Street New •en. CT 065] analytical testing and environmentai sciences Conn. Cart, f PH-0450 EPA f CT-0 Project Name: Raymark (RCRA) ANALYSIS REQUIRED Project Location: Stratford, Coimecticut ITEM NUMBER: D I 10 Project Niunber: 91-545^^5 LABORATORY: ELI AQUATEC EEG TU Bottle Skc/Codc: LAB No. of Bottlcf: I ID Prtscrrt: ff ANALYTICAL TESTING ^ D T c METHODS A i o STA. T M M SAMTLC IDENTinCATION No. E e r NUMBER i ^ ^Hv isiS y Ut/fi^ P./fc^ 30SI SowcB CoOEi; w " WELL O «• OUTFAU. T TANK SO SLUDOE S SOIL PRESERVATIVE CODES; A ASCORBIC Aao N Nmuc Aao (HNO,) S •• SODIUM • BomtBCoPBS; L •» LAOOON TR TREATED X OTHER • - DEFINE HYDROXIDE (NAOH) H >• HYDROCHLORIC Aao (HCL) I kxo F > FILTERED B AMBER EPA VIAL BOTUBSIZE; I -40cc 2 - 1250C 3-2J0cc 4 = S00cc 5 - 1000cc T SODIUM THIOSULFATE P > SULFURIC AaD(tl,S04) Z ZINC ACETATE A AMBER C •• CLEAI SAMPLER'S SIGNATURE AmLIATION fills Time TRNSF ITEM PRINTI NO. NO. ACCEPTED BY DATE TIME POL SIGN"ir/: / iPiP ) iu^vpL-v ihcftj^^^ 'j/o^ yjL REMARKS: dt. /fes / /fT^ 5?K mailln ENVIRONMENTAL LABORATORIES, INC. 142 TEMPLE STREET NEW HAVEN. CT0B510 (203)789-1200 FAX (203) 78M261 December 22, 1993 Mr. Michael Hill U.S. Environmental Protection Agency JFK Federal Building Mail Code HEE-CAN6 Boston, Massachusetts 02203-2211 RE: Raymark Industries, Inc. SoU Sampling Location Contaminant Hot Spots E U No. 91-545-32 Dear Mr. Hill: Environmental Laboratories, Inc. has received your fax dated December 16, 1993 concerning the sampling parameter for the treatabilityAeachability study. We understand that the primary goal of this sampling program is to collect three representative soil samples with a low, medium and high concentration of metals (^.tzA), total PCB and asbestos. These samples will be collected based upon the following criteria: Sample Location % Ad>estos Total PCB's (ppm) Lead (ppm) { 1 5-85% 2-10 500-> 10,000 1 2 5-85% 50-70 500-> 10,000 1 3 5-85% 200-300 500-> 10,000 1 These soils samples will be used in conjunction with a treatability study and leachability study on-site. In addition, EPA will be collecting off-site soils based on this same criteria. <© A SUaaOIMV OF BlvmONMENTAL ANO MFMSTRUCTUnE 00NSULTANT8. MC. (ECON) BRDQEPORT • HPM HAVEN • HARTFORD Mr. Michael Hm -2 - December 22, 1993 U.S. Envixtnunental Protection Agency EU No. 91-545-32 OD December 20, 1993, Environmental Laboratories, Inc. met with yourself, Mr. Michael Jasinski of EPA Region I and Mr. Stephen Parker of NUS to discuss the sampling location. Prior to identifying the location, we leviewed the laboratory PCB related to isolated hotspots. This review was fte basis for the fidd sampling location. It was agreed that asbestos and metals are present wiAin tiie fill and tbe PCB data is tiie dependent variable for your treatability study. Thus, fbe following locations meet tiie criteria given: Sample Location %Asbest06 Total PCB's (ppm)> Lead (ppm)^ LOW B-68* 2-4 ft 10-15% @ 1-2 ft 36 3,134 5-10% ® 4-6 ft B-42 0-2 ft (alt) 10-15%® 4-6 ft 45 1,443 MED B-7* 4-6 ft 2-5% 73 20,106 B-30A 0.7-3 (alt) 0% 62 8,257 HlfiH 1 B-10* 1-4 fl (composite) 2-5% 26,700 294 B-68 6-8 ft (alt-1) 5-10% @ 4-6 ft 300 3,134 B-30A 5-7 ft (alt-2) 2-5% 590 20,106 ' Data based on actual laboratory analyses. Data has not been validated. This data is assumed approximate. ^ Data based on field XRF screening. Data is considered zppToxima.te values. * Primary sampling locations. Note: EU will collect an additional sample at B-68 six to eight feet for leachability studies. These locations will be sampled on January 5, 1994. All sampling locations wiU be prqjared on January 4, 1994 in advance of the sampling by Raymark Industries, Inc. The sampling protocol and required gkssware will be prqnred by NUS on behalf of the EPA Region I. The intent is to collect tiie samples in a one day event (weatiier dq)endent). Raymark will provide a backhoe and all equ^ment will be steam cleaned between sampling locations. E U strongly recommends tiiat a soil sample be collected from B-68 six to eight feet This sample rqnesents the typical high levels on-site. B-10 is an isolated hot spot which may require a unique treatment alternative. The concentration of PCB at B-68 is only exceeded at only one other location on-site besides B-10 and B-7 (represents hot spot). Thus, if B-68 can be evaluated for treatability and found to be accq>table, then the majority of the site can be treated if treatment if required. Mr. KGdiad HiU December 22, 1993 U.S. Environmental Protection Agency EU No. 91-545-32 The goal is to collectively ooUect tiiese samples. An E U representative will be present to split these samples witii your subcontractor. If you have any questions regarding tiiese locations, please do not hesitate to contact us. Very truly yours. Richard J. Project Manager/Senior Hydrogeologist RJD/jd 050RL/3 cc: Mr. Robert F. Moody - Raymark Industries, Inc. Mr. Michael Jasinski - EPA R^on I Mr. Mark Zimmerman, Esq. - Updike, Kelly and Spellacy, P.C. Mr. Robert G. Wasp, P.E. - Environmental Laboratories, Inc. mUi # ENVIRONMENTAL LABORATORIES, INC. U 2 TE^APLE STHEET NEW HAVEN. CT 06S10 (203) 789-1260 FAX (203) 789-8261 July 21, 1992 Mr. Robert Moody Raymark Industries, Inc. 75 East Main Street Stratford, Connecticut 06497 RE: Soil Spoils Wells D and £ E U #92-613-10 Dear Mr. Moody: On February 27* and 28*, 1991, EU reinstalled Monitoring Wells Dl-1 and El-1 located adjacent to Lagoon No. 1 in the westerly portion of the facility site. During the drilling the soils were contained in 55 gallon drums for analysis prior to their disposal. EU , in accordance with our contract, conducted a full TCLP analysis on the drums to determine proper disposal of the soils. A TCLP analysis is required by most landfills prior to the disposal of the soils. The results of the TCLP analysis indicate that the soils in the four (4) drums for the D and E series wells are not listed as hazardous waste. The constituents identified on the attached referenced report indicate the following parameters: CONCENTRATIONS (PPM) CHEMICAL CONSTITUENTS ACTION LEVEL D-1 E-1-1 1 Barium 0.140 0.135 100.0 1 Cadmium BDL 0.003 1.0 1 Chromium 0.014 0.013 5.0 1 1 I^ad 0.035 1.33 2.0 (CD 1 5.0 (EPA) 1 1 Selenium 0.92 0.84 1-0 1 Silver 0.001 0.002 5.0 1 *t A SUBS:OiABV 0= ENVIRONMENTAL ANO INPRASTHUCTUHE CONSULTANTS. INC. (EICON) BHiOGEPOflT • NEW HAVEN • MAaTror,C. Mr. Robert Moody June 3, 1992 Raymark Industries, Inc. EU #92-613-10 These results indicated that only lead at a concentration 1.33 ppm was present within the soil above Connecticut State Drinking Water Action Levels. The Drinking Water Standard for lead within the State of Connecticut is 0.02 and 0.05 for Federal EPA. To be declared a hazardous waste in the State of Connecticut, lead would have to be 100 times the State Action Level of .02 or 2 ppm. Since the concentrations identified on-site are 1.33 ppm, these soils would not be considered hazardous waste for lead constituents. Since the Federal EPA Guidelines are less strict than Connecticut, EPA would not considered the soils located within these drums as hazardous waste. However, since the level of lead within these drums is greater than the State Action Level, these would be considered contaminated soils requiring proper manifest and disposal to a landfill within the State of Connecticut ELI has marked these drums in Uie field located adjacent to Wells D and E, adjacent to Lagoon No. 1. We assume that Raymark Industries will dispose of these soil samples properly in accordance with the attached chemical analysis. We thank you for the opportunity to work with you on installing Wells D and E and the results of the TCLP analysis indicated that the soils are non-hazardous. Should you have any questions regarding the analysis, please do not hesitate to contact us. Very truly yours, Richard J. Desrosiers Hydrogeologist RJD/jd 007RL/4 Enclosures cc: Mark Zimmerman, Esq. ENVIRONMENTAL LABORATORIES, INC. It analytical testing and environmental sciences 142 Temoie Street New Haven CT 06510 (203) 789-1260 Conn Cen »PH NAME/ADDRESS: Mr. Robert F. Moody Raymark Industries, Inc. 75 East Main Street Stratford, CT 06497 EU PROJECT NUMBER: 92-613-10 E U SAMPLE NUMBER(S): 92-1311 - 92-1312 COLLECTED BY: EU/PH DATE RECEIVED: 04/28/92 COMPLETION DATE: 05/26/92 REPORT CERTIFIED BY: ELAINE A. CARINO LABORATORY DIRECTOR C:\WP\DAILY\92MAYWK4J6 . i=v c- ;•.'.':)S\'.'?'."A. A';D ACatS-^RLlCU^; nONSj.TANTS 'KZ :E;C0N1 B3;DGE=0S" • NEW MAVcN • "ASTCoaC |^]?SULTS OF /ANALYSIS; DtitClION CONCENTRATION LIMIT (ppm) (ppm) SAMPLE IDENTIFIER: D-1 E-1-1 E U SAMPLE NUMBER: 92-1311 92-1312 PARAMLTER TCLP: Anenic ND ND 0.005 Barium 0.140 0.135 O.OQS ND ND 0.005 ^o/4iniiiTii BDL 0.003 0.001 Caibon tetncfaloride ND ND 0.005 Chloidone ND ND 0.005 CUorobeozeae ND ND 0.005 Chloiofonn ND ND 0.1 Qiromiuiii 0.014 0.013 0.005 Crasol ND ND 0.1 2.4-D ND ND 0.01 1,4-DicUorobenzeDe ND ND 0.005 1,2-DicUoroetbiiie ND ND 0.005 1,1 -Dichloroethylene ND ND 0.005 2,4-DinitTDtoIueiie ND ND 0.01 Endrin ND ND 0.001 Hq>tachlor ND ND 0.0005 Hqitachlor qwxide ND ND 0.0005 ND ND 0.01 Hexachlorobutadieoe ND ND 0.005 Hexachloroethane ND ND 0.005 Lead 0.035 1J3 0.005 Lindane ND ND 0.001 Mercury ND ND 0.0005 Methoxychlor ND ND 0.01 Methyl ethyl ketone ND ND 0.1 Nitrobenzene ND ND 0.1 ND ND 1. Pyridine ND ND 0.5 Selenium 0.92 0.84 0.005 Silver 0.001 0.002 0.001 Tetrachloroethylene ND ND 0.005 Toxaphene ND ND 0.05 Trichloroethylene ND ND 0.005 2.4,5-TrichloropheiK>l ND ND 0.1 2,4,6-Tridiloropheool ND ND 0.1 2,4,5-TP(SUvex) ND ND 0.002 Vinyl chloride ND ND 0.005 ND > None Detected BDL •> Below Dctcctioo Limit Uw Cook Indu^ _ . 26-28 WavwSbMl ENVIRONMENTAL LABORATORIES. INC. Aneonla.CT 09401 (203) 735-ieoa analytical testing and environmental sciences FAX (203) 735^500 142 Tenv** Sireel New Havw* CT 06510 (203) 789-1200 ell cHa 11 -or-c0sTODf IKCORD Com. C«1. #PH-04S0 PROJECT LOCHTION: PROJECT mmBER: 9!l'-^yi-/y> SOtfflCE (XIOES: W = Hell 0 = Outfall HO = Waste Oil RO = Run Off B = BottcB Sedivnt SH - Semm SO = Sludge S = Soil R = Ri«ar/Slr«« LT = Lattdf ill MH » Haatemter L = Laka/Ocean I = Other; Specifi (XmRINER TMSni miDEI ITEM SMVLC SOURa MkLTSIS RCQUIRCD UMIE1R& hRD CHECK RO. I.D. COOC NO. TWE SIZE PRESERVE 1 2 3 / S ^ a 7(^Lyf^ / Container Codesi 9 = Plastic E = EPR VIM. 6 = Glass > - Mwr Glass B = Bacteria Bottle Preservative Codes: I = Iced P = Filtered N = Ritric Itcld (HNO,) H - Hidrodiloric Icid (HCl) S= Sodiiai Hfdnniide (NaOH) T - Sodlua nilosulCata P > Sulfuric Id 0 = Other; Speciff_ Bi^YI^APK TREATABfLnr The E U laboratoiy received three soil samples for treatability testing on January 25, 1994. Sample « EL .SfllTlpII g f SB 68 02-04 94-0090 SB 7 04-06 94-0091 SB 68 06-08 94-0092 These samples were collected by ELI's technical personnel in accordance with USEPA guidelines and transported under strict Qiain-of-Custody to tat laboratoiy where they were accepted by ELI's laboratoiy personnel for analysis. Each soil sample was to be subjected to a battery of analytical tests in an effoit to determine the variation in analytical results obtained between: • Total analysis for a variety of analytical parameters • TCLP analyst:: for the same list of analytical parameters using EPA method 1311 to leach the soils • Modified TCLP analysis for the same list of analytical parameters using EPA Method 1312 to leach the soils • Samples were also agitated for seven days using distilled water according to the procedures specified in the Equilibrium Leach Test (ELT) It must be noted that samples were not milled to the required size of < 150 p.m as specified in the ELT prcx:edure because of the nature of the samples. An initial attempt was made using samples SB 68 02-04 to grind the sample sufficiently to pass a ^100 sieve using a mortar and pestle. This was discontinued when it was detennined that the effort being expended relative to the types of samples involved would yield minimal increase in overall sample homogeneity and require an exoibitant amount of staff time. A. Sample SB 68 02-04 was predominantly of a sandy-loam nature with some larger rocks. Roughly 90-95% of this material passed through a ^10 sieve with only mechanical agitation. Less than 1 % of the material passed through a #40 sieve and less than 0.2% of the material actually passed through the #1(X) sieve (this was the material we were actually able to grind fine enough to pass the sieve). B. Sample SB 68 06-08 was a much more moist sample and had the appearance of a 'black loam' type of soil with some fme sand-like grains. This sample had to be physically forced through the f 10 sieve with virtually no material passing through the #40 sieve. C. Sample SB 7 04-06 appeared to have a higher content of clay than either of the first two samples and had an extremely high water content. This sample had to be physically forced through the #10 sieve and a slight amount of liquid from the sample was the only material that passed through the #40 sieve. - 1 Review of tiie data reveals tiiat tiie only significant On my qpinion) contaminants appear in tiie PCB and metals fractions for tiie total analysis of all tiiree samples. Leachate extraction did not remove PCB from any of tiie samples where as, many of tiie metals were extracted to varying extents, when subjected to the three leaching procedures. In all cases, the SLP and ELP extraction procedures are much less aggressive towards the various metals than TCXP which is as we had cxpeaed. Of considerable interest though, is the fact that the ELP procedure ^ipears to be a more aggressive leaching solvent for calcium, magnesium, manganese, nickd, potassium, sodium and zinc than the SLP procedure. The most logical explanation for this, is the fact that the ELP method calls for a seven day tumble where as SLP only requires tumbling the samples for 18±2 hours. RJS/jd 060RM VOLATILES RESULTS SAMPLE IDENTIFIER: SB-68 02-04 E U SAMPLE NUMBER: 94-0090 TOTAL TCLP SLP ELP (mg/Kc) (mg/L) (mg/L) (ng/L) 0.100 Acetone ND< 0.500 ND ND BDL fffny*^ ND < 0.025 ND ND ND 0.005 BromodichlofDmetbaiie ND < 0.025 ND ND ND 0.005 Bromofonn ND < 0.025 ND ND ND 0.005 2-ButaDone ND< 0.025 ND ND ND 0.050 Carbon disulfide ND < 0.025 ND ND ND 0.005 Cjobaa tetnchloride ND <0.02S ND ND ND 0.005 Ghlorodibromomrthanf. ND < 0.02S ND ND ND 0.005 2-Chloroethylvinyl ether ND < 0.050 ND ND ND 0.010 Chlorobenzeoe ND < 0.025 ND ND ND 0.005 nhloroethaoe ND < 0.050 ND ND ND 0.010 Chloroform ND < 0.025 ND ND ND 0.005 Chloromethane/Methyl chloride ND < 0.050 ND ND ND 0.010 1,1-Dichloroethane ND < 0.025 ND ND ND 0.005 1,2-Dichloroethane ND < 0.025 ND ND ND 0.005 1.1-Diehloroethene ND < 0.025 ND ND ND 0.005 trans-1.2-DichloroetheDe ND < 0.025 ND ND ND 0.005 cis-1,3-Dichloropropeoe ND < 0.025 ND ND ND 0.005 trans-1,3-Dichloropropeoe ND < 0.025 ND ND ND 0.005 Ethylbenzene ND < 0.025 ND ND ND 0.005 Methylene chloride ND < 0.025 ND ND BDL 0.005 4-M ethy I-2-pentanone ND < 0.025 ND ND ND 0.050 Styrene ND < 0.025 ND ND ND 0.005 1,1.2,2-Tetrachloroethane ND < 0.025 ND ND ND 0.005 Tetrachloroethene ND < 0.025 ND ND ND 0.005 Toluene ND < 0.025 BDL BDL BDL 0.005 1,1.1 -Trichloroethane ND < 0.025 ND ND ND 0.005 1.1.2-Trichloror4hane ND < 0.025 ND ND ND 0.005 Trichloroethene ND < 0.025 ND ND ND 0.005 Trichlorofluoromethane ND < 0.050 ND ND ND 0.010 Vinyl acetate ND < 0.025 ND ND ND 0.005 Vinyl chloride ND < 0.050 ND ND ND 0.010 Total Xylenes ND < 0.025 BDL BDL BDL 0.005 BASE NEUTRAL, ACID *Aiiuii-i ABi ^ ar SAMPLE mENTDlER: SB ^ 02-04 EU SAMPLE NUMBER: 94-0090 TOTAL TCLP SLP ELP (mg/Kg) (wglL) (mg/L) (mg/L) Af'wiaphthcoe ND < 3.3 ND ND ND 0.1 AceoaphAyleoe ND < 3.3 ND ND ND 0.1 Anthracene ND < 3.3 ND ND ND 0.1 Benzo(a)aDthracene BDL < 3.3 ND ND ND 0.1 Benzo(b)fluoTantheDe BDL < 3.3 ND ND ND 0.1 Benzo(k)fluoranthene BDL < 3.3 ND ND ND 0.1 Beh2o(g,h,i)perylM>e BDL < 3.3 ND ND ND 0.1 Benzo(a)pyreoe BDL < 3.3 ND ND ND 0.1 Benzoic acid ND < 16.7 ND ND ND OS Benzyl alcohol ND < 6.7 ND ND ND 0.2 Bis(2-chloroethoxy)methane ND < 3.3 ND ND ND 0.1 Bis(2-chloroethyl)ether ND < 3.3 ND ND ND 0.1 BiE(2-chloroisopfopyl ether) ND < 3.3 ND ND ND 0.1 Bis(2-ethylhexyl)phthalate ND < 3.3 ND ND ND 0.1 4-Bromopheoyl phenyl ether ND < 3.3 ND ND ND 0.1 Butyl benzyl phthalate ND < 3.3 ND ND ND 0.1 p-Chloroaniline ND < 6.7 ND ND ND 0.2 f>-Chloro-n»-cresol ND < 6.7 ND ND ND 0.2 2-Chloronaphthaleoe ND < 3.3 ND ND ND 0.1 2-Chloropbeool ND < 3.3 ND ND ND 0.1 4-Chloropbenyl phenyl ether ND < 3.3 ND ND ND 0.1 Chrysene BDL < 3.3 ND ND ND 0.1 o-Cresol C2-M ethy Iphenol) ND < 3.3 ND ND ND 0.1 p-Cresol (4-MethylpheooI) ND < 3.3 ND ND ND 0.1 Di-n-butylphthalate ND < 3.3 ND ND ND 0.1 Diben2o(a.h)anthr«cene ND < 3.3 ND ND ND 0.1 o-Dichlorobenzene ND < 3.3 ND ND ND 0.1 m-Dichlorobenzene ND < 3.3 ND ND ND 0.1 p-Dichl orobenzene ND < 3.3 ND ND ND 0.1 3.3 •-Dichlorobenzidine ND < 6.7 ND ND ND 0.1 2.4-Dichloropheool ND < 3.3 ND ND ND 0.1 Diethyl phthalate ND < 3.3 BDL ND ND 0.1 2.4-Dimethylpheool ND < 3.3 ND ND ND 0.1 1,2-Diphenylhydrazine ND < 3.3 ND ND ND 0.1 4.6-Dinitro-o-cresol ND < 16.7 ND ND ND 0.5 BASE NEUTRAL, ACID 1^1 KAUi AVUb SBJUTUbAi (Cont) RESULTS SAMPLE IDENTIFIER: SB-68 02-04 EU SAMPLE NUMBER: 944IU90 TOTAL TCLP SLP ELP (ng/Kg) (mg/L) (mg/L) (mg/L) 2,4-DinitiD|riienol ND < 16.7 ND ND ND 0.5 2,4-Dinitiotoluene ND < 3J ND ND ND 0.1 2,6-Dinitrotoluene ND < 3.3 ND ND ND 0.1 Di-o-octyl phthalate ND < 3J ND ND ND 0.1 Fluoranthene ND < 3.3 ND ND ND 0.1 Fluorene BDL < 23 ND ND ND 0.1 Hexachlorobenzene ND < 3.3 ND ND ND 0.1 Hexachlorocyclopentadiene ND< 3.3 ND ND ND 0.1 Hexachloroethane ND < 3.3 ND ND ND 0.1 Hexachlorobutadiene ND < 3.3 ND ND ND 0.1 ladeno( 1.2.3-cd)pyTeoe ND < 3J ND ND ND 0.1 Isophorone ND < 3.3 ND ND ND 0.1 2«metfayinapbthaleoe ND < 3.3 ND ND ND 0.1 Naphthalene ND < 3.3 ND ND ND 0.1 o-Nitroaniline ND < 16.7 ND ND ND 0.5 nt-Nitroaniline ND < 16.7 ND ND ND OJ p-Nitroaniline ND < 16.7 ND ND ND 0.5 Nitrobenzene ND < 3.3 ND ND ND 0.1 o~Ni trophenol ND < 3.3 ND ND ND 0.1 p-Nitropbenol ND < 16.7 ND ND ND 0.5 D'Nitrosodimethylamine ND < 3.3 ND ND ND 0.1 O'Nitrosodipbenylaauoe ND < 3.3 ND ND ND O.I n-Nltrosodi-n-propylamine ND < 3.3 ND ND ND 0.1 Pentachlorophenol ND < 16.7 ND ND ND 0.5 Phenanthrene BDL < 3.3 ND ND ND 0.1 Phenol ND < 3.3 ND ND ND 0.1 Pyrene BDL < 3.3 ND ND ND 0.1 1,2,4-Trichlorobenzcne ND < 3.3 ND ND ND 0.1 2,4.5-TrichlorophenoI ND < 3.3 ND ND ND 0.1 PCB DETECnc RESULTS UMTT tmtlL) SAMPLE IDENTinER: SB-68 02-04 EU SAMPLE NUMBER: 94-0090 TOTAL TCLP SLP ELP (mg/Kg) (mg/L) (mg/L) (iqg/L) PCB-1242 ND < 50.0 ND ND ND 0.003 PCB-1254 ND <50.0 ND ND ND 0.003 PCB-1221 ND < SOO. ND ND ND 0.030 PCB-1232 ND < 50.0 ND ND ND 0.003 PCB-1248 ND <50.0 ND ND ND 0.003 PCB-1260 ND < 50.0 ND ND ND 0.003 PCB-1016 ND <50.0 ND ND ND 0.003 PCB-1262 ND <50.0 ND ND ND 0.003 PCB-1268 45.9 ND ND ND 0.001 HERBICIDES 2.4-D ND < 0.25 ND ND ND 0.005 2.4.5-TP (silvex) ND < 0.05 ND ND ND 0.001 INORGANICS ISTECnC RESULTS UMTT (ng/L) SAMPLE IDENTIFIER: SB-68 02-04 E U SAMPLE NUMBER: 94-0090 TOTAL TCLP SLP ELP (mg/Kg) (ngA.) (ng/L) (mg/L) 7341 . 1J4 BDL .24 0.2 Antimony' ND < 10. ND H D ND 0.0002 Anenic' 7.6 ND ND ND 0.010 Barium' 3.468. .86 BDL .34 0.20 Boyllium ND < 0.6 BDL BDL BDL 0.010 Cudini^'in ND < 0.6 BDL ND ND 0.010 Calcium 1.040. 7.52 5.42 17.40 0.20 Chromium 67. ND ND ND 0.020 Cobalt 9. ND ND ND 0.10 Copper 1.549. 24.50 .976 .604 0.50 Iron 15.873. .16 BDL ND 0.10 Lead 6,300. 135.0 5.90 1.92 0.20 Magnesiiun 29,676. 1.36 .82 5.96 0.40 Manganese 185. .34 .10 .52 0.020 Mercury BDL < 0.29 ND ND ND 0.0005 Nickel' 111. .14 BDL .16 0.080 Potassium 908. 5.88 BDL 5.22 2.000 Selenium' ND < 25. ND ND ND 0.010 Silver^ ND < 1. ND ND ND 0.020. Sodium' BDL < 578. N/A 3.34 2.62 Thallium' ND < 10. ND ND ND 0.010 Vanadium 13. ND ND ND 0.100 Zmc' 240. 1.68 0.62 1.11 0.040 ' Recoveries for zinc, nickel, lilver. and banua an aoi wiihu normal laboraotry control limits (of 75 - 125 %) for the matrix spike sample of this batch. All other QA/QC «vaB wtthm acoepuble laboratory control limits except fbr silver. Recoveries for silver were out of normal laboratory oootrol lima (of 10 • 120 %) and the manuAu:turers advisory range fbr the LCS of this sample batch. ^ N/A-TCLP extraction fluid mntaini aodiam hydroxide, can not run for sodium. ' See comment page'. All results reported on a dry wei ^ baas VOLATILES RESULTS SAMPLE IDENTIFIER: SB-7 04-06 EU SAMPLE NUMBER: 94-0091 TOTAL TCLP SLP ELP (mg/Kg) (mg/L) (mg/L) (mg/L) Acetone ND < 0.500 ND ND BDL 0.100 ND < 0.025 ND ND BDL 0.005 Bromodichloromethane ND < 0.025 ND ND ND 0.005 Bromoform ND < 0.025 ND ND ND 0.005 2-Butanone ND < 0.025 BDL ND BDL 0.050 Caibon disulfide BDL < 0.025 BDL ND ND 0.005 Carbon tetrachloride ND < 0.025 ND ND ND 0.005 Chlorodibromomethane ND < 0.025 ND ND ND 0.005 2-Chloroethylviayl ether ND < 0.050 ND ND ND 0.010 Chlorobenzene BDL < 0.025 BDL ND BDL 0.005 Chloroethane ND < 0.050 ND ND ND 0.010 Chloroform ND < O.OZS ND ND ND 0.005 Chloromethane/Methyl chloride ND < 0.050 ND ND ND 0.010 1,1-Dichloroethane ND < 0.025 ND ND ND 0.005 1,2-Dichloroethane ND < 0.025 ND ND ND 0.005 1,1-Diehloroethene ND < 0.025 ND ND ND 0.005 trans-1,2-Dichloroetheae ND < 0.025 ND ND ND 0.005 cis-1,3-Dichloropropene ND < 0.025 ND ND ND 0.005 trans-1,3-Dichloropropeoe ND < 0.025 ND ND ND 0.005 Ethylbenzene ND < 0.025 BDL BDL BDL 0.005 Methylene chloride ND < 0.025 ND ND BDL 0.005 4-Methyl-2-pentanone ND < 0.025 ND ND BDL 0.050 Styrene ND < 0.025 ND ND ND 0.005 1.1.2.2-Tetrachloroethane ND < 0.025 ND ND ND 0.005 Tetrachloroethene ND < 0.025 ND ND ND 0.005 Toluene ND < 0.025 0.013 0.005 0.009 0.005 1.1.1 -Trichloroethane ND < 0.025 ND ND ND 0.005 1,1.2-Trichloroethane ND < 0.025 ND ND ND 0.005 Trichloroethene ND < 0.025 BDL BDL BDL 0.005 Trichlorofluoromethane ND < 0.050 ND ND ND 0 010 Vinyl acetate ND < 0.025 ND ND ND 0.005 Vinyl chloride ND < O.QSO ND ND ND 0.010 Total Xylenes BDL < 0.025 0.011 0.013 0.024 0.005 BASE NEUTRAL, ACID 1£AIKAU1AJI1.£ MuniTULAAiLco DETECnO RESULTS LIMIT (mg/L) SAMPLE IDENTIFIER: SB-7 04-06 EU SAMPLE NUMBER: 94-0091 TOTAL TCLP SLP EL P (mg/Kg) (mg/L) (ng/L) (ng/L) Acen^Mitnene BDL < 3.3 ND ND ND 0.1 Acenaphthylene BDL < 3.3 ND ND ND 0.1 Anthracene BDL < 3.3 ND ND ND 0.1 Benzo(a)anthracene 3.4 ND ND ND 0.1 Benzo(b)fluoranthene BDL < 3.3 ND ND ND 0.1 Benzo(k)fluonmthene 3.4 ND ND ND 0.1 Benzo(g,h,i)perylene ND< 3.3 ND ND ND 0.1 Benzo(a)pyrene 3.6 ND ND ND 0.1 Benzoic acid ND < 16.7 ND ND ND OJ Benzyl alccdiol ND < 6.7 ND ND ND 0.2 Bis(2-chloroethoxy)methane ND < 3.3 ND ND ND 0.1 Bis(2-chloroethyl)ether ND < 3.3 ND ND ND 0.1 Bis<2-chloroisopropyl ether) ND < 3.3 ND ND ND 0.1 Bis(2-ethylhexyl)phthalale ND < 3.3 ND ND BDL 0.1 4-Bromophenyl phenyl ether ND < 3.3 ND ND ND 0.1 Butyl benzyl phthalate ND < 3.3 ND ND ND 0.1 p-Chloroaniline ND < 6.7 ND ND ND 0.2 p-Chloro-m-cresol ND < 6.7 ND ND ND 0.2 2-Chloronaphthalene ND < 3.3 ND ND ND 0.1 2-ChlorDpbenol ND < 3.3 ND ND ND 0.1 4-Chloropbenyl phenyl ether ND < 3.3 ND ND ND 0.1 Chrysene 4.0 ND ND ND 0.1 o-Cresol (2-Methylpbenol) ND < 3.3 ND ND ND 0.1 p-Cresol (4-Methylpheool) BDL < 3.3 ND ND ND 0.1 Di-n-butylphthalate ND < 3.3 ND ND ND 0.1 Dibenzo(a,h>anthracene ND < 3.3 ND ND ND 0.1 o-Dichlorobeozene ND < 3.3 ND ND ND 0.1 m-Dichlorobenzene ND < 3.3 ND ND ND 0.1 p-Dichlorobenzene ND < 3.3 ND ND ND 0.1 3.3'-Dichlorobenzidine ND < 6.7 ND ND ND O.I 2,4-Dichlorophenol ND < 3.3 ND ND ND 0.1 Diethylphthalate ND < 3.3 ND ND ND 0.1 2,4-Dimethylpbenol 12.1 ND ND ND 0.1 1,2-Diphenylhydrazine ND < 3.3 ND ND ND 0.1 4,6-Dini tro-o-cresol ND < 16.7 ND ND ND 0.5 BASE NEOTRAL, AOD EXTRACTABI-E SEJWivuLAiiua DETECnc (Coot.) RESULTS UMir imgiL) SAMPLE IDENTIFIER: SB-7 04-06 ELI SAMPLE NUMBER: 94-0091 TOTAL TCLP SLP ELP (ng/Kg) (ng/L) (ng/L) (mg/L) 2,4-Dinitio|riienol ND < 16.7 ND ND ND OJ 2,4-Diiutrotoliiene ND < 3.3 ND ND ND 0.1 2,6-Dinitrotoluene ND<3.3 ND ND ND 0.1 Di-n-octyl phthalate ND < 3.3 ND ND ND 0.1 7.9 ND ND ND 0.1 Fluorene BDL < 3.3 ND ND ND 0.1 Hexachlorobenzene ND < 3.3 ND ND ND 0.1 Hexachlorocyclopentadiene ND < 3.3 ND ND ND 0.1 ND < 3.3 ND ND ND 0.1 Hexachlorobutadiene ND < 3.3 ND ND ND 0.1 Indeno( 1,2.3-cd)pyrene BDL < 3.3 ND ND ND 0.1 Isophorone ND < 3.3 ND ND ND 0.1 2-methyloaphthalene BDL < 3.3 ND ND ND 0.1 Naphthalene BDL < 3.3 ND ND ND 0.1 o-Nitroaniline ND < 16.7 ND ND ND OJ m-Nitroamline ND < 16.7 ND ND ND OJ p-Nitroaniline ND < 16.7 ND ND ND OJ Nitrobenzene ND < 3.3 ND ND ND 0.1 o-Ni trophenol ND < 3.3 ND ND ND 0.1 p-Nitropbenol ND < 16.7 ND ND ND 0.5 D-Nitrosodimetfaylamine ND < 3.3 ND ND ND 0.1 D-Nitrosodipbenylamme ND < 3.3 ND ND ND 0.1 n-Nitrosodi-n-propylamme ND < 3.3 ND ND ND 0.1 Pentachlorophenol ND < 16.7 ND ND ND 0.5 Phenanthrene 6.1 ND ND ND 0.1 Phenol ND < 3.3 ND ND ND 0.1 Pyrene 7.2 ND ND ND 0.1 1.2.4-Trichlorobenzene ND < 3.3 ND ND ND 0.1 2.4.5-Trichloropbenol ND < 3.3 ND ND ND 0.1 rcB DETECnC RESULTS LIMIT (nglL) SAMPLE IDEKTIFIRR: SB-7 04-06 EU SAMPLE NUMBER: 94-0091 TOTAL TCLP SLP ELP (ng/Kg) (mg/L) (mg/L) (mg/L) PCB-1242 ND <250. ND ND ND 0.003 PCB-1254 ND<250. ND ND ND 0.003 PCB-1221 ND < 2J00. ND ND ND 0.030 PCB-1232 ND <250. ND ND ND 0.003 PCB-1248 ND < 250. ND ND ND 0.003 PCB-1260 ND < 250. ND ND ND 0.003 PCB-1016 ND<250. ND ND ND 0.003 PCB-1262 ND < 250. ND ND ND 0.003 PCB-1268 177. ND ND ND 0.001 HF.RRICIDES 2,4-D ND < 0.25 ND ND ND . 0.005 2.4.5-TP (silvex) ND < 0.05 ND ND ND 0.001 INORGANICS IXETECTK RESULTS LIMIT (mg/L) SAMPLE IDENTIFIQl: SB-7 04-06 EU SAMPLE NUMBER: 94-0091 TOTAL TCLP SLP ELP (mg/Kg) (mgo.) (mg/L) (mg/L) Aliuunum 8.028. 1J 2 ND ND 0.200 Antimcay^ ND < 10. ND ND ND 0.2 Arsenic' 6.6 ND ND ND 0.010 Barium 2,861. 1.22 0.240 BDL 0.200 Beryllium' ND < 0.6 BDL BDL BDL 0.010 Cw^miiim 2.0 0.026 ND ND 0.010 Calcium 3,459. 65.4 11.94 32.2 0.200 Chromiimi 105. BDL ND BDL 0.020 Cobalt 17. ND ND ND 0.100 Copper 14,710. 133. 0.224 0.064 0.500 Iron 20,829. 0.400 ND ND 0.100 Lead 15,039. 326. 0.260 0.460 0.200 Magnesium 40,923. 8.30 5.08 24.2 0.400 Manganese 313. 0.84 0.140 0.500 0.020 Mercury BDL < 0.39 ND ND ND 0.0005 Nickel' 263. 0.400 ND 0.100 0.080 Potassium 815. 2.900 BDL 4.34 2.000 Selenium' ND < 25. ND ND ND 0.010 Silver" ND < 1. ND ND ND 0.020 Sodium BDL < 782. N/A 1.88 6.04 Thallium' ND < 10. ND ND ND 0.010 Vanadium 30. ND ND ND 0.100 Zmc' 3.818. 16.70 0.480 2.94 0.040 ' Recoveries for zinc, nickel, silver, and barium are oot within normal laboraotry control limits (of 75 - 125 %) for the matri: spike sample of this batch. All other QA/QC was within acceptable laboratory control limits except for silver. Recoveries fbr silver were out of normal laboratory control limits (of 80 - 120 %) and the manufacturers advisory rmnge for the LCS of this sample batch. ' See comment page. All results reported on a dry weight basis VOLATILES DETECnC RESULTS UMTT (mg/L) SAMPLE IDENTIFIER: SB-68 06-08 EU SAMPLE NUMBER: 94-0092 TOTAL TCLP SLP ELP (mg/Kg) (tagIL) (ng/L) (mg/L) Acetone ND < 0 JOO ND ND BDL Benzene ND < 0.025 ND ND ND Bromodichloromethane ND < 0.025 ND ND ND Bromoform ND < 0.025 ND ND ND 2-Butanone ND < 0.025 ND ND ND Carbon disulfide 0.051 BDL ND BDL Carbon tetrachloride ND < 0.025 ND ND ND Chlorodibromomethane ND < 0.025 ND ND ND 2-Chloroethylvinyl ether ND < 0.050 ND ND ND Chlorobenzene ND < 0.025 ND ND ND Chloroethane ND < 0.050 ND ND ND Chloroform ND < 0.025 ND ND ND 0||r>rr>|iw.»kanr/M''^tiv I ehlr>ri(l<>. ND < 0.050 ND ND ND 1,1 -Dichloroethane ND < 0.025 ND ND ND 1,2-Dichloroethane ND < 0.025 ND ND ND 1,1-Diehloroethene ND < 0.025 ND ND ND trans-1,2-Dichloroetfaene ND < 0.025 ND ND ND cis-1.3-Dichloropropene ND < 0.025 ND ND ND trans-1.3-Dtchloropropene ND < 0.025 ND ND ND Ethylbenzene BDL < 0.025 ND ND ND Methylene chloride ND < 0.025 ND ND ND 4-M ethy 1 •2-pentanone ND < 0.025 ND ND ND Styrene ND < 0.025 ND ND ND 1.1.2,2-Tetrachloroethane ND < 0.025 ND ND ND Tetrachloroethene ND < 0.025 ND BDL ND Toluene BDL < 0.025 ND BDL BDL 1,1,1 -Trichloroethane ND < 0.025 ND ND ND 1,1.2-Trichl oroethane ND < 0.025 ND ND ND Trichloroethene ND < 0.025 ND ND ND ND < 0.050 ND ND ND Vinyl acetate ND < 0.025 ND ND ND Vinyl chloride ND < 0.050 ND ND ND Total Xylenes BDL < 0.025 ND BDL BDL jfAab r*r.vAMu%M^ Acja/ «>/»' DETECnO RESULTS UMTT (mg/L) SAMPLE IDENTIFIER: SB-68 06-08 EU SAMPLE NUMBER: 94-0092 TOTAL TCLP SLP ELP (mg/Kg) (ng/L) (ng/L) (mg/L) Acwiaphtbfnc ND < 3.3 ND ND ND 0.1 Acenaphtfayleoe ND<3.3 ND ND ND 0.1 Anthracene ND < 3.3 ND ND ND 0.1 Benzo(a)anduscene ND< 3 J ND ND ND 0.1 Benzo(b)fIuoranthene ND < 3.3 ND ND ND 0.1 Benzo(k)fluoianthene ND<3.3 ND ND ND 0.1 Benzo(g,h,i)peiylene ND < 3.3 ND ND ND 0.1 Benzo(a)pyTcne ND < 3.3 ND ND ND 0.1 Benzoic acid ND < 16.7 ND ND ND OJ Benzyl alcohol ND < 6.7 ND ND ND 0.2 ND < 3.3 ND ND ND 0.1 Bis(2-chloroethyl)ether ND < 3.3 ND ND ND 0.1 Bis(2-chloroisopropyl ether) ND < 3.3 ND ND ND 0.1 Bis(2-ethylhexyl)phthalate ND < 3.3 ND ND 0.1 0.1 4-Bromophenyl phenyl ether ND < 3.3 ND ND ND 0.1 Butyl benzyl phthalate ND < 3.3 ND ND ND 0.1 p-Chloroaniline ND < 6.7 ND ND ND 0.2 p-Chloro-m-cresol ND < 6.7 ND ND ND 0.2 2-rhloronapbthalene ND < 3.3 ND ND ND 0.1 2-rhlorophenoI ND < 3.3 ND ND ND 0.1 4-Chlorophenyl phenyl ether ND < 3.3 ND ND ND 0.1 Chrysene ND < 3.3 ND ND ND O.I o-Cresol (2-Methylphenol) ND < 3.3 ND ND ND 0.1 p-Cresol (4-Methylphenol) ND < 3.3 ND ND ND 0.1 Di-n-butylphthalate ND < 3.3 ND ND ND 0.1 Dibm7jr>(a,h)anthracene ND < 3.3 ND ND ND 0.1 o-Dichlorobeozene ND < 3.3 ND ND ND 0.1 m-Dichlorobenzeoe ND < 3.3 m> ND ND 0.1 p-Dichlorobenzene ND < 3.3 ND ND ND 0.1 3,3 '-Dichlorobenzidine ND < 6.7 ND ND ND 0.1 2.4-Dichloropbenol ND < 3.3 ND ND ND 0.1 Diethyl phthalate ND < 3.3 ND ND ND 0.1 2,4-DimethylpheooI ND < 3.3 ND ND ND 0.1 1,2-Diphenylhydrazine ND < 3.3 ND ND ND 0.1 4,6-Dinitro-o-cresoI ND < 16.7 ND ND ND 0.5 BASE NEUTRAL, ACID EXTRACTABLE SEMIVUUkTlUb (ConL) DETECTK RESULTS UMTT (mg/L) SAMPLE IDENTIFIER: SB-68 06-08 EU SAMPLE NUMBER: 94-0092 TOTAL TCLP SLP ELP (mg/Kg) (mg/L) (mg/L) (mg/L) 2,4-DinitropheDoI ND < 16.7 ND ND ND OJ 2,4-Dinitrotoluene ND<3.3 ND ND ND 0.1 2,6-Dinitrt>toluene ND < 3.3 ND ND ND 0.1 Di-n-octyl i^thalate ND < 3.3 ND ND ND 0.1 Fluoranthene BDL < 3.3 ND ND ND 0.1 Fluorene ND < 3.3 ND ND ND 0.1 ND < 3.3 ND ND ND 0.1 Hexachlorocyclc^ieotadiene ND < 3.3 ND ND ND 0.1 Hexachloroethane ND< 3.3 ND ND ND 0.1 Hexachlorobutadiene ND < 3.3 ND ND ND 0.1 lndeno( 1,2.3-cd)pyrene ND < 3.3 ND ND ND 0.1 Isophorone ND < 3.3 ND ND ND 0.1 2-methyinaphthalene BDL < 3.3 ND ND ND 0.1 Naphthalene BDL < 3.3 ND ND ND 0.1 o-Nitro«niline ND < 16.7 ND ND ND O J m-Nitroaniline ND < 16.7 ND ND ND OJ p-Nitroaniline ND < 16.7 ND ND ND 0.5 Nitrobenzene ND < 3.3 ND ND . ND 0.1 o-Nitropbenol ND < 3.3 ND ND ND 0.1 p-Nitrophenol ND < 16.7 ND ND ND 0.5 n-Nitrosodimethylamine ND < 3.3 ND ND ND 0.1 n-Nitrosodiphenylamine ND < 3.3 ND ND ND 0.1 n-Nitrosodi-n-propylamine ND < 3.3 ND ND ND 0.1 Pentachlorophenol ND < 16.7 ND ND ND 0.5 Phenanthrene BDL < 3.3 ND ND ND 0.1 Phenol ND < 3.3 ND ND ND 0.1 Pyrene ND < 3.3 ND ND ND . 0.1 1,2,4-Trichlorobeazeoe ND < 3.3 ND ND ND 0.1 2,4.5-Trichloropheool ND < 3.3 ND ND ND 0.1 PCB DETECnC RESULTS LIMIT (mg/L) SAMPLE IDENTIFIER: SB-68 06-08 EU SAMPLE NUMBER: 94-0092 • TOTAL TCLP SI-P ELP (mg/Kg) (ng/L) (mg/L) (mg/L) ND 0.003 PCB-1242 ND<250. ND ND PCB-1254 ND<250. ND ND ND 0.003 PCB-1221 ND < 2J00. ND ND ND 0.030 PCB-1232 ND <250. ND ND ND 0.003 PCB-1248 ND < 250. ND ND ND 0.003 PCB-1260 ND < 250. ND ND ND 0.003 PCB-1016 ND < 250. ND ND ND 0.003 PCB-1262 ND < 250. ND ND ND 0.003 PCB-1268 76.8 ND ND ND 0.001 HERBICIDES 2.4-D ND < 0.25 ND ND ND 0.005 2,4.5-TP (silvex) ND < 0.05 ND ND ND 0.001 INORGANICS DETECT! RESULTS UM n (mg/L} SAMPLE IDENTIFIER: SB^8 06-08 E U SAMn £ NUMBQt: 94-0092 TOTAL TCLP SLP ELP (ng/Kg) (ng/L) (mg/L) (mg/L) Aliminum 5,621. 1.68 BDL 0.480 0.200 Antimonjr' ND < 10. ND ND ND 0.000? Arsenic' 6.4 ND ND ND 0.010 Bariimi' 1,756. 0.440 BDL ND 0.200 Beryllium ND < 0.6 BDL BDL BDL 0.010 Cadmiimi ND < 0.6 0.014 0.010 0.020 0.010 Calcium 2,385. 32-0 28.6 87.6 0.200 Chromium 112. BDL BDL 0.060 0.020 Cobalt 20. 0.120 BDL 0.200 0.100 Copper 5,969. 193. 0.802 1.57 0.500 Iron 16,165. 0.460 ND ND . 0.100 Lead 21J06. 186. 4.68 6.90 0.200 Magnesiiun 56,946. 10.1 8.10 28.8 0.400 Manganese 572. 4.28 3.22 10.20 0.020 Mercury ND < 0.39 ND ND ND 0.UUU5 Nickel' 303. 1.84 0.960 2.36 0.080 Potassium 453. 2.98 ND 7.20 2.000 Selenium' ND < 25. ND ND ND 0.010 Silver' ND < 1. ND ND ND 0.020 Sodium' BDL < 697. N/A ND 1.32 Thallium' ND < 10. ND ND ND 0.010 Vanadium 10. ND ND ND 0.100 Zmc' 890. 12.1 5.62 16.20 0.040 ' Recoveries for zinc, nickel, silver, and banum an not withm normal laboraotry control limits (of 75 - 125 %) for the matr spike sample of this batch. All other QA/QC was within acceptable laboratory control Umits except for silver. Recoveries fc silver were out of normal laboratory control luniu (of 80 • 120 %) and the manufacturers advisory range fpr the LCS of this sample batch. ' N/A-TCLP extraction fluid contains sodium bydroaide. can not nm for sodium. ' See comment page^ All results reported on a dry weight basis comments to accompany results for sample numbers 94-0090 - 94-0092. * The analytical sfoke recovery nssff^"*^ with this sample was outside of normal laboratoiy control limits, which is indicative of a severe matrix interference. All other QA/QC associated with tiiis sample was within accq>table limits, therefore, the data was considered to be acceptable. ^ Analytical and matrix spike recoveries as-sociated with this sample were outside of normal laboratoiy control limits which is indicative of a severe matrix interference. All other QA/QC associated with this sample was considered to be accqitable. ' The matrix spike recovery associated with this sample was outside of normal laboratory control limits which is indicative of a severe matrix interference. All other QA/QC associated with this sample was within acceptable limits, therefore, the data was considered to be acceptable. ORGANIC EXTRACTIONS ELI INTTIAL FINAL ANALYST METHOD NUMBER SOLVENT VOLUME VOLUME SURROGATES REMARKS jihML ,f?ar? •v-\^ ri gq^Q MLL ISU^ \%A, P03 V-> • oo'^^ i^^ ^<\A if^ AITICY I^^ ^ >n^e\. Ppq Y li oO^di MD^t i: )i/. l^'? %A'i ^•* 00'^^ g^J-6i4T^3'> QH QOK 2±:Ii2M. q>/oo^j \-^-> ig.a/ >.-3t*-r^ ;?r ^pK .Ji. JJ Jl i-^-jj^ a tO^^ I iL _jVV_Ui_ L222. Li^ttJii 'tty-oov? CLT nrC\a ^Sl^JUL dxxL fj^i. aact ^^^ JikL t n«-P qvonqi Ctr .^iJL «• i>i ftt>fK f>iP ^r]j •rit..>ur Una e > ^ / ^/ \ ^ ORGANIC EXTRACTIONS ELI INITUL FINAL DATE ANALYST METHOD NUMBER SOLVENT VOLUME VOLUME SURROGATES REMARKS ^^^ H iv»i>o £.Tl-)0 t-i^ri.Js 9*/ ob<»o ei-r Ihe/.ia. O.l L 1 -^1. iQVI.ll nf S ?*, *• 17 { 1 j <.LP 1 \ >)/ -r/.P ' 4fo0*«l CLT SLP \ M3yl "tiO ^-c»aa-7^«!*t>oo^-, (ti Si-P 1 ,-.-> .1 ti/ri £ - O'V'/ b'CT loMj ,,.^ - hift 6LP ' 1 ^1^ s ^T^uP f < \ • ^ TCLP / V \ ftw1V»ii 6l4«k ^ •1/ \/ V tf-' 50 1.4- IH lV\tAJ «a7o- r/iH ^H-OA;^"1 ^(1. i ml. ;.on.i/ fli S 3/. 1 ' \ ^^ oa«iri -' 1 f ^)H(iO-'\\ i 1 1 1 oiH oa<\^ 44 oa-ts t hHn^^^) Hf 03^5" qM - oOH' 1 V / A /• \/_ \ I'^/H -ttP'Jt »»?' ^ V "o..! .-r^-^^k ?op.o^^, ^^ MMMi^ i ,•.y ORGANIC EXTRACTIONS ELI INITUL FINAL ANALYST METHOD NUMBER SOLVENT VOLUME VOLUME SURROGATES REMARKS f^i/muL Hfih ftl'.rig Ei7 iidLiM$^ gTtyj&fA7^« jjiA P X^ ,'-' Mi. i M- iLUasL ^^Vf^c^^^i^ aorJP il n..b. Ai:cio£)!\ 6T0 /P^.„^< lO^Lo^ 3.H.vTlc»|fl(n f'h^ mv: 'i'l 0090 ^ •^1 )^L 17 pf>?r? n^ '•HDJ . t i tfO^Q ff-il) 3±J2SilL li oo^:k f^'-K ^P'< }k rudUflJi gi ^ ^ 4/ jGOisl fterij»/^.; ELI INITIAL FINAL )ATE ANALYST METHOD NUMBER SOLVENT VOLUME VOLUME SURROGATES REMARKS g't^qn JAJ ^ I^Tn 1^^ ^ 'N o^ Y7- Q')Uit Method Sections To Run On A Barcode Mismatch ( ) Full Method (X) Inject Anyway (X) Reprocessing Only ( ) Don't Inject Line Type Vial DataFile Method Sample Name 1) Sample 1 MAR02001 8270 8270 mix #1, 50.0 ppm 2) Sample 2 MAR02002 8270 8270 mix #2, 50.0 ppm 3) Sample 3 MAR02003 8270 Blcink 4) Sample 4 MAR02004 8270 Method blank, 0.1 L/l mL 5) Sample 5 MAR02005 8270 94-0090 SLP, 0.1 L/l mL 6) Sample 6 MAR02006 8270 94-0091 SLP, 0.1 L/l mL 7) Sample 7 MAR02007 8270 94-0092 SLP, 0.1 L/l mL 8) Sample 8 MAR02008 8270 94-0091 MS SLP, 0.1 L/l mL, IC 9) Sample 9 MAR02009 8270 94-0091 MSD SLP, 0.1 L/l mL, 1 10) Sample 10 MAR02010 8270 94-0090 ELT, 0.1 L/l mL 11) Sample 11 MAR02011 8270 94-0091 ELT, 0.1 L/l mL 12) Sample 12 MAR02012 8270 94-0092 ELT, 0.1 L/l mL 13) Sample 13 MAR02013 8270 DFTPP +, 50.0 ppm Last Modified: Wed Apr 06 11:28:59 1994 Page Data File C: \HPC:HEM\1\DA,TA\MAR02\DFTPP-2 . D Acq Time 2 Meu: 94 5:23 pm Operator: mw/jp Sample dftpp, 50.0 ppm, Inst : Semivolat Misc em voltage lowered by 50 Multiplr: 1.00 Method C:\HPCHEM\1\METH0DS\DFTPP-2.M Title Scan Number 294 Target Rel. to Lower Upper Rel. Raw Result Mass Mass Limit% Limit% Abn% Abn Pass/Fail 51 198 30 60 42.5 72224 PASS 68 69 0 2 0.0 0 PASS 69 198 0 100 61.4 104320 PASS 70 69 0 2 0.0 0 PASS 127 198 40 60 49.7 84352 PASS 197 198 0 1 0.0 0 PASS 198 196 100 100 100.0 169792 PASS 199 198 5 9 6.6 11255 PASS 275 198 10 30 22.2 37656 PASS 365 198 1 100 2.8 4704 PASS 441 443 0 100 95.9 22848 PASS 442 198 40 100 74.0 125648 PASS 443 442 17 23 19.0 23816 PASS DFTPP-2.D DFTPP-2.M Wed Mar 02 17:34:21 1994 Data File C:\HPCHEM\l\nATA\MAR02\MAR02009.D Acq Time 2 Mar 94 5:45 pm Operator: jp Sample 8270 mix #i, 50.0 ppm Inst : Semivo Misc Multiplr: 1.00 Quant Time Mar 4 8:45 1994 Method C:\HPC3ffiM\l\METHODS\8270.M Title Method 8270 Last Update Thu Mar 03 17:12:32 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev(M 1) 1,4-dichloroben2ene-d4 8.36 152 409882 40.00 ug/mL -0. 19) naphthalene-d8 11.14 136 1628801 40.00 ug/mL -0. 34) acenaphthene-dlO 15.35 164 769439 40.00 ug/mL -0. 53) phenanthrene-dl0 19.29 188 1172475 40.00 ug/mL -0. 67) chrysene-dl2 27.03 240 1029875 40.00 ug/mL -O.i 75) perylene-dl2 31.41 264 1245395 40.00 ug/mL -O.i Syst em Monitoring Compounds %Recove: 4) 2-fluorophenol (surr) 6.00 112 696927 47.13 ug/mL 23-T-: 5) phenol-d5 (surr) 7.83 99 802123 44.69 ug/mL 2* ^ 20) nitrobenzene-d5 (surr) 9.62 82 738845 45.60 ug/mL 45T^ 38) 2-fluorobiphenyl (surr) 13.75 172 117B296 52.23 ug/mL -5S-r-: 58) 2,4,6-tribromophenol (surr 17.46 330 200177 89.07 ug/mL -44rtJ 69) terphenyl-dl4 (surr) 24.06 244 1198012 49.05 ug/mL -«-H Targ st Compounds Qvali 3) N-nitrosodimethylamin e 3.90 42 286250 38.94 ug/mL 1 6) phenol 7.86 94 860663 44.43 ug/mL ( *7 \ 7-t 8) bis(2-chloroethyl)ethe r 7.97 93 741022 42.28 ug/mL# { 9) 2-chlorophenol B.OO 128 702473 48.07 ug/mL ( 15) bis(2-chloroisopropyl)ethe 9.09 45 712426 31.68 ug/mL ( 17) N-nitrosodi-n-propylamine 9.42 70 533155 40.90 ug/mL ( 23) 2-nitrophenol 10.37 139 484697 52.50 ug/mL ( 24) 2,4-dimethylphenol 10.55 122 506331 4 9.24 ug/mL ( 25) bis(2-chloroethoxy)methane 10.78 93 877063 44.92 ug/mL ( 26) 2,4-dichlorophenol 10.91 162 470723 47.97 ug/mL ( 29) naphthalene 11.19 128 1750010 45.94 ug/mL 11 32) 4-chloro-3-methyiphenoi 12.61 107 547236 42.13 ug/mL 1 •o-s-t— Iz . ul 4^0J 33 le.-do ugAmijfl 36) 2,4,6-trichlorophenol 13.54 196 278892 54 .46' ug/mL I •37) A ^ n n .. .— 1 ..T t noX JtrJ n 1. UO—ug/mij— dimethylphthalate ( 41) 14.94 163 1212246 45.25 ug/mL# 42) acenaphthylene 14.94 152 1544528 44.55 ug/mL ( 4 34 3 , 6-dinitrotoluene -^4r^3 -i66 - 12969 1.8 9 ug/mL# 45) acenaphthene 15.44 154 974853 47.86 ug/mL c 46) 2,4-dinitrophenol 15.63 184 104962 29.07 ug/mL ( 47) 4-nitrophenol 15.97 139 302299 42.75 ug/mL i 50) diethylphthalate 16.82 149 1337842 50.44 ug/mL ( 51) fluorene 16.75 166 1153458 54.29 ug/mL < 52) 4-chlorophenyl phenyl ethe 16.85 204 484145 4 9.91 ug/mL ( 55) 4,6-dinitro-2-methylphenol 17.13 198 191343 3 9.99 ug/mL# ( 56) N-nitrosodiphenylamine 17.21 169 827847 55.38 ug/mL ( 57) -azobenzene- • • 17.21 77 104359 3.21 ug/mL#- -- (#) = qualifier out of range (m) « manual integration MAR02009.D 8270.M Fri Mar 04 08:54:03 1994 Page : Data File C:\HPCHEM\l\nATA\MAR02\MAR02009.D Acq Time 2 Mar 94 5:45 pm Operator: jp Sample 8270 mix #1, 50.0 ppm Inst ; Semivc Misc Multiplr: 1.00 Qusmt Time Mar 4 8:45 1994 Method C:\HPCHEM\1\METHODS\B270.M Title Method 8270 Last Update Thu Mar 03 17:12:32 1994 Response via Multiple Level Calibration Confound R.T. Qlon Response Cone Unit Qval 59 4-bromophenyl phenyl ether 18.15 248 310907 60.41 ug/mL 61 pentachlorophenol 19.02 266 231029 62.06 ug/mL 62 phenanthrene 19.37 178 1591696 49.16 ug/mL 63 anthracene 19.48 178 1574597 48.41 ug/mL 64 di-n-butylphthalate 21.43 149 2464182 48.53 ug/mL 65 fluoranthene 22.77 202 1524636 47.96 ug/mL 68 pyrene 23.38 202 1568667 42.59 ug/mL 70 butyl benzyl phthalate 25.77 149 1103083 42.70 ug/mL 71 benzo (a) anthracene 26.96 228 1414183 47.50 ug/mL 73 chrysene 27.11 228 1205656 46.09 ug/mL 74 bis (2-ethylhexyl) phthala 27.74 149 1561964 41.24 ug/mL 76 di-n-octylphthalate 29.69 149 2834722 38.63 ug/mL 77 benzo(b)fluoranthene 30.29 252 1533330 43.96 ug/mL 78 benzo(k)fluoranthene 30.38 252 1423950 53.81 ug/mL 79 benzo(a)pyrene 31.22 252 1442917 47.81 ug/mL 80 benzo(g,h,i)perylene 34.41 276 1406643 48.91 ug/mL# 81 dibenzo(a,h)anthracene 34.53 278 1415196 52.33 ug/mL# 82 indeno(1,2,3-c,d)pyrene 35.15 276 1386228 49.58 ug/mL# (#) = qualifier out of range (m) <» manual integration MAR02009.D 8270.M Fri Mar 04 08:54:06 1994 Page Data File C: \HPCHEM\ 1 \nA.TA\MARO 2 \MARO 2 0 0 9 . D Acq Time 2 Mar 94 5:45 pm Operator: jp Sample 8270 mix #1, 50.0 ppm Inst : Semiv Misc Multiplr: 1.00 Quant Time Mar 4 8:45 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Thu M£Ur 03 17:12:32 1994 Response via Multiple Level Calibration lAbundance TIC: MAR02009.D 3200000 3000000 42T 2800000- 23C 20S 2600000 17M29T 45M 74T I II I 2400000 9M 38S 57T 2200000 §§f 15T 56C 2000000 8T 191 341 76C ^ 51T 52T 64M 1800000 - 26:: 68M 73": 78T 1600000 5S si-es 7(pX7] 4S I 53ll 5 ^ 37rr 1400000 321II 159? 9S •'•^?5I i;p 65 af^T 1200000 -• 36C lii SET J79C 1000000 -i 61 1 800000 -'T 8CT 1 600000 - 7N 400000 200000 0 - ^ . .J ml tUL 1 i , fl Time--> 5.00 10.00 15.00 20.00 25.00 30.00 35.00 MAR02009.D 8270.M Fri Mar 04 08:54:17 1994 Page Data File C:\HPCHEM\1\DATA\MAR02\MAR02010.D Acq Time 2 Mar 94 6:35 pm Operator: jp Sample 8270 mix #2, 50.0 ppm Inst : Semi\ Misc Multiplr: 1.00 Quant Time Mar 4 8:57 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Thu MeLr 03 17:12:32 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev( 1) l,4-dichloroben2ene-d4 8.36 152 399382 40.00 ug/mL -C 19) naphthalene-d8 11.15 136 1598143 40.00 ug/mL -C 34) acenaphthene-dl0 15.35 164 781958 40.00 ug/mL -c 53) phenanthrene-dl0 19.29 188 1174436 4 0.00 ug/mL -c 67) chrysene-dl2 27.00 240 1077845 40.00 ug/mL -0 75) perylene-dl2 31.38 264 1251289 40.00 ug/mL -0 System Monitoring Compounds %Recov 4) 2-fluorophenol (surr) 0.00 112 0 0.00 ug/mL 0 5) phenol-d5 (surr) 0.00 99 0 0.00 ug/mL 0 20) nitrobenzene-d5 (surr) 9.41 82 63439 3.99 ug/mL 3 38) 2-fluorobiphenyl (surr) 13.63 172 1075 0.05 ug/mL 0 58) 2,4,6-tribromophenol (surr 0.00 330 0 0.00 ug/mL c 69) terphenyl-dl4 (surr) 24.02 244 478 0.02 ug/mL c Target Compounds Qva 2) pyridine 3.83 79 754683 4 6.47 ug/mL c^ - -7.83-- 94-- 77618 7) aniline 7.82 93 1065173 43.75 ug/mL R ) 7 Rl 1 n r '^ 1 71 OJ T-1 xu \j .1X 1 ^ 10) 1,3-dichlorobenzene 8.28 146 737862 50.08 ug/mL 11) 1,4-dichlorobenzene B.40 146 708016 48.91 ug/mL 12) benzyl alcohol 8.77 108 415772 39.27 ug/mL 13) 1,2-dichlorobenzene 8.78 146 661058 47.01 ug/mL 14) o-cresol 9.07 108 638090 44.55 ug/mL 16) p-cresol 9.39 108 629923 41.55 ug/mL 18) hexachloroethane 9.41 117 273775 4 5.75 ug/mL 21) nitrobenzene 9.66 77 717378 46.85 ug/mL 22) isophorone 10.20 82 1388881 44.98 ug/mL 23 ) ->fl r-^n in ''^ ITX J OJ 27) benzoic acid i.. t £. ug/mjj?f 11.05 122 390600 45..84 ug/mL 28) 1,2,4-trichlorobenzene 11.07 180 522838 51.33 ug/mL 29) .naphr hal *»n^ 11 4"' 128 70738 1 flO n o 'iTiT a 30) 4-chloroaniline 11.43 127 815186 47.61 ug/mL 31) hexachlorobutadiene 11.65 225 249342 52.79 ug/mL 33) 2-methylnaphthalene 12.79 142 1105472 4 8.12 ug/mL 35) hexachlorocyclopentadiene 13.33 237 169666 32.95 ug/mL# 36)- T or 37) 2,4,5-trichlorophenol 13.63 196 342022 50.54 ug/mL 39) 2-chloronaphthalene 13.92 162 1106618 49.85 ug/mL 40) 2-nitroaniline 14.33 65 399953 44.33 ug/mL 43) 2,6-dinitrotoluene 15.09 165 349208 50.08 ug/mL 44) 3-nitroaniline 15.41 138 417433 50.43 ug/mL# Tin 4-7^ ' )f - r- /- T .\ r\ r X J J - —7B.1J ug/mLff— (#) = qualifier out of range (m) « manual integration MAR02010.D 8270.M Fri Mar 04 09:05:02 1994 Pag€ Data File C:\HPCHEM\l\nATA\MAR02\MAR02010.D Acq Time 2 Mar 94 6:35 pm Operator: jp Sanple 8270 mix #2, 50.0 ppm Inst : Serai Vf Misc Multiplr: 1.00 Quant Time Mar 4 8:57 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last l^date Thu Mar 03 17:12:32 1994 Response via Multiple Level Calibration Compound R.T. Qlon Response Cone Unit Qval 4 8) dibenzofuran 15.85 168 1487780 48.41 ug/mL 49) 2,4-dinitrotoluene 16.06 165 474965 49.30 ug/mL 54) 4-nitroooiiline 17.05 138 434870 52.13 ug/mL 57) azobenzene 17.26 77 1468371 45.16 ug/mL 6 0) hexachlorobenzene 18.46 284 380932 70.38 ug/mL# 66) benzidine 23.31 184 725246 36.85 ug/mL 72) 3,3'-dichlorobenzidine 27.09 252 583134 55.98 ug/mL# (#) = qualifier out of range (m) - manual integration MAR02010.D 8270.M Fri Mar 04 09:05:06 1994 Page Data File : C:\HPCHEM\1\DATA\MAR02\MAR02010.D Acq Time : 2 Mar 94 6:35 pm Operator: jp Sanple : 8270 mix #2, 50.0 ppm Inst : Semivc Misc : Multiplr: 1.00 Quant Time: Mar 4 8:57 1994 Method C:\HPCHEMVl\METHODS\8270.M Title Method 8270 Last Update Thu Mar 03 17:12:32 1994 Response via Multiple Level Calibration Abundance TIC: MAR02010.D 13T 2200000 191 39T 2000000 #2§? 47M gip JOS 341 57T 1800000 7T^' ^ ,!,•,'" 6M 2BM 1600000 531 OT iBT 2|LT i:. 1400000 37rr 40T 1200000 :.(;T 60T ??? ] P6C44T 1000000 -;. 5[' PM 751 4311 800000 66T 600000 54T 400000 200000 i l oi »Ja 1V CUiL- L u JLx. I I t I I rrime--> 5.00 10.00 isioo 20^00 25^00 30.00 35.00 MAR02010.D 8270.M Fri Mar 04 09:05:16 1994 Page Data File C:\HPCHEM\1\DATA\MAR02\MAR02011.D Acq Time 2 Mar 94 7:27 pm Operator: jp Sanple blank Inst : Semivc Misc Multiplr: 1.00 Quant Time Mar 4 9:25 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Thu Mar 03 17:12:32 1994 Response via Multiple Level Calibration internal Standards R.T. Qlon Response Cone Units Dev(r 1) l,4-dichlorobenzene-d4 8.36 152 378404 40.00 ug/mL -0. 19) naphthalene-dB 11.13 136 1428161 40.00 ug/raL -0. 34) acenaphthene-dlO 15.35 164 698827 40.0 0 ug/mL -0. 53) phenanthrene-dlO 19.28 188 985676 40.0 0 ug/mL -0. 67) chrysene-dl2 26.99 240 1000227 40.00 ug/mL -0. 75) perylene-dl2 31.37 264 1106589 40.00 ug/mL -0. System Monitoring Compounds % Re cove 4) 2-fluorophenol (surr) 6.00 112 655699 48.03 ug/mL .34 5) phenol-d5 (surr) 7.82 99 770174 46.48 ug/mL 29-: 20) nitrobenzene-d5 (surr) 9.62 82 710334 50.00 ug/mL Se-. 38) 2-fluorobiphenyl (surr) 13.76 172 1120459 54 . 68 ug/mL -54-: 58) 2,4,6-tribromophenol (surr 17.45 330 198830 105.2 4 ug/mL -5*r 69) terphenyl-dl4 (surr) 24.07 244 1166099 49.16 ug/mL -*&-. Target Compounds QvaJ 17) N-nitrosodi-n-propylamine 9.62 70 99702 8.28 ug/mL# 4 3) -2-,-&-difli&i--©feol-«e«€ 15. 35 3r&5 9076-8 14.57 ug/mL# (#) = qualifier out of range (m) - manual integration ^4AR02011.D 8270.M Fri Mar 04 09:30:36 1994 Page Data File C:\HPCHEM\1\DATA\MAR02\MAR02011.D Acq Time 2 Mar 94 7:27 pm Operator: jp Sample blank Inst : Semivc Misc ' Multiplr: 1.00 Quant Time Mar 4 9:25 1994 Method : C:\HPCHEMV1\METHODS\8270.M Title : Method 8270 Last Update : Thu Mar 03 17:12:32 1994 Response via Multiple Level Calibration Abundance TIC: MAR02011.D 2000000 1800000 38S 1600000 20S19I r '"17M 1400000 33T 69S 5S 531 1200000 4S J ] 671 1000000 -, 1 751 j 800000 - 58S 600000 400000 -, 200000 0 -^ JL L "^ I " ' I r 1 1 1 r rrime--> 5.00 10.00 15.00 20.00 25.00 30.00 35.00 MAR02011.D 8270.M Fri Mar 04 09:30:43 1994 Page Data File C:\HPCHEM\1\DATA\MAR02\MAR02012 .D Acq Time 2 Mar 94 B:18 pm Operator: jp Sample Method blank, 0.1 L/l mL Inst : Semiv Misc Multiplr: 1.00 Quant Time Mar 4 9:33 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Thu Mar 03 17:12:32 1994 Response via Multiple Level Calibration Internal Stzmdards R.T. Qlon Response Cone Units Dev|] 1) l,4-dichloroben2ene-d4 8.36 152 393695 40.0 0 ug/mL -0 19) naphthalene-dB 11.14 136 1475688 40.00 ug/mL -0 34) acenaphthene-dlO 15.35 164 727268 40.0 0 ug/mL -0 53) phenanthrene-dlO 19.28 188 1034490 40.00 ug/mL -0 67) chrysene-dl2 27.01 240 1038253 40.00 ug/mL -0 75) perylene-dl2 31.39 264 1210077 40.00 ug/mL -0 System Monitoring Compounds %Recov 4) 2-fluorophenol (surr) 6.01 112 1199478 84.45 ug/mL 42 5) phenol-dS (surr) 7.83 99 1233 968 71.58 ug/mL 35 20) nitrobenzene-d5 (surr) 9.63 82 926692 63.1 3 ug/mL 63 38) 2-fluorobiphenyl (surr) 13.76 172 1577746 73.99 ug/mL 73 58) 2,4,6-tribromophenol (surr 17.48 330 566924 285.9 1 ug/mL 142 69) terphenyl-dl4 (surr) 24.09 244 2061601 83.73 ug/mL 83 Target Compounds Qva 1-7)- tj-nitreaodi n-propylamine -9^-66 ?« 13335C 10.05 ug/iiiLti 434- C dinitrotoluene •i-5-.-35—i-65— —93^36 ±4T4-2 ug/mLti 564--K—nit-rosodipheny 1 amine 17.48 169 19799 -l-.-50-ug/mL# 74) bis (2-ethylhexyl) phthala 27.72 149 46113 1.21 ug/mL (#) = qualifier out of range (m) « manual integration MAR02012.D 8270.M Fri Mar 04 09:35:25 1994 Page Data Pile : C:\HPCHEM\1\DATA\MAR02\MAR02012.D Acq Time 2 Mar 94 8:18 pm Operator: jp Sample : Method blank, 0.1 L/l mL Inst : Semiv( Misc • : Multiplr: 1.00 Quant Time: Mar 4 9:33 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Thu Mar 03 17:12:32 1994 Response via Multiple Level Calibration Abundance TIC: MAR02012.D 2800000 ( 2600000 2400000 191 38S 2200000 20S 2000000 17M 4S 58S 69S 1800000 5S II 1600000 56C SST 1400000 531 1200000 671 1000000 ] 751 800000 600000 ! 400000 74T 200000 Ju- ll *i—1—i"^"la^ llll l rrime--> 5.00 10.00 15.00 20.00 25.00 30.00 35.00 MAR02012.D 8270.M Fri Mar 04 09:35:32 1994 Page Data File C:\HPCHEM\l\nATA\MAR02\MAR02013.D Acq Time 2 Mar 94 9:10 pm Operator: jp Sanple 94-0090 SLP, 0.1 L/l mL Inst : Semivc Misc Multiplr: 1.00 Quant Time Mar 4 9:36 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Thu Mar 03 17:12:32 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev(f 1) l,4-dichlorobenzene-d4 8.36 152 374083 40.00 ug/mL -0. 19) naphthalene-dB 11.15 136 1403276 40.00 ug/mL -0. 34) acenaphthene-dlO 15.35 164 695697 40.00 ug/mL -0. 5 3) phenemthrene-dl0 19.29 188 972516 40.00. ug/mL -0. 67) chrysene-dl2 27.01 240 986926 40.00 ug/mL -0. 75) perylene-dl2 31.39 264 1135883 40.00 ug/mL -0. System Monitoring Compounds %Recov€ 4) 2-fluorophenol (surr) 6.01 112 1185267 87.82 ug/mL 43. 5) phenol-d5 (surr) 7.83 99 1138101 69.48 ug/mL 34. 20) nitroben2ene-d5 (surr) 9.63 82 958776 68.68. ug/mL 68. 38) 2-fluorobiphenyl (surr) 13.76 172 1599831 78.43 ug/mL 78. 58) 2,4,6-tribromophenol (surr 17.48 330 576471 309.25 ug/mL 154. 69) terphenyl-dl4 (surr) 24.09 244 2078430 88.80 ug/mL 88. Target Compounds Qva3 17-)—N-fHrt-Toeodi -propyl amitve- 0.C3. ^7« 3^7270 11-54 -Mg^mm 43) 2,6-dinitrot-^uene- --15. 35—1-6-5 ~ - 90175-—14 -r-54-nig/mL# 56)—M-ni trn<=;nHiphenylamine 17.48 169 20431- - -1.-65 ug/mL# (#) = cjualifier out of range (m) « manual integration MAR02013.D 8270.M Fri Mar 04 09:36:37 1994 Page Data File : C:\HPCHEM\l\DATA\MAR02\MAR02013.D Acq Time 2 Mar 94 9:10 pm Operator: jp Sample : 94-0090 SLP, 0.1 L/l mL Inst : Semivo Misc : Multiplr: 1.00 Quant Time: Mar 4 9:36 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last I^date Thu Mar 03 17:12:32 1994 Response via Multiple Level Calibration Abundouace TIC: MAR02013.D 2600000 2400000 38S 191 2200000 20S 2000000 17M 58S 4S 1800000 69S 5S 56C 1600000 J II SST ; 1400000 j 531 j ( 1200000 ; I 1 671 1 i 1000000 i 751 800000 600000 400000 200000 L JL^ k"r" I " • ' — I — ' - ITime--> 5.00 10.00 15.00 20.00 25.00 3o!oo 35.00 MAR02013.D 8270.M Fri Mar 04 09:36:44 1994 Page Data File C:\HPCHEM\1\DATA\MAR02\MAR02014.D Acq Time 2 Mar 94 10:02 pm Operator: DP Sample 94-0091 SLP, 0.1 L/l mL Inst Semiv Misc : Multiplr: 1.00 Quant Time: Mar 4 9:37 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Upciate Thu Mar 03 17:12:32 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev( 1) i,4-dichlorobenzene-d4 8 .37 152 371682 40 .00 ug/raL -0 19) naphthalene-dB 11 .14 136 1383623 40 .00 ug/mL -0 3 4) acenaphthene-dl0 15 .35 164 689081 40 .00 ug/mL -0 5 3) phenanthrene-dl0 19 .29 188 970748 40 .00 ug/mL -0 67) chrysene-dl2 27 .00 240 979458 40 .00 ug/mL -0 75) perylene-dl2 31 .38 264 1143148 40 00 ug/mL -0 System Monitoring Compounds %Recov 4) 2-fluorophenol (surr) 6 02 112 1040751 77 61 ug/mL 38 5) phenol-d5 (surr) 7 83 99 978631 60. 13 ug/mL 30 20) nitrobenzene-d5 (surr) 9 64 82 885525 64. 34 ug/mL 64 38) 2-fluorobiphenyl (surr) 13. 77 172 1525315 75. 50 ug/mL 75 58) 2,4,6-tribromophenol (surr 17. 49 330 558445 300. 13 ug/mL 150 69) terphenyl-dl4 (surr) 24. 09 244 2028167 87. 31 ug/mL 87 Target Compounds Qva 17-)—N nitrooodi n propylamine— 9.64 ?•« 136486 10.70 ug/mLtt 43-)—2,6 dinitrotoluono' 15.3D 3r&5— 00304 14.71 ug/mL# 56-)—N-ni-t-rosodiphenylamine 17.49 169 19413 i.57 ug/mL# 74) bis (2-ethylhexyl) phthala 27.73 149 77240 2.14 ug/mL (it) = cjualifier out of range (m) « manual integration MAR02014.D 8270.M Fri Mar 04 09:37:39 1994 Page Data File C:\HPCHEM\1\DATA\MAR02\MAR02014.D Acq Time 2 Mar 94 10:02 pm Operator: jp Sample 94-0091 SLP, 0.1 L/l mL Inst : Semivc Misc Multiplr: 1.00 Quant Time Mar 4 9:37 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Thu Mar 03 17:12:32 1994 Response via Multiple Level Calibration abundance TIC: MAR02014.D 2600000 2400000 191 38S 2200000 2000000 20S 17M 1800000 58S 69S 1 4S II 1600000 ] ^ 5S 5iC 1 «3T 1400000 531 1200000 671 1000000 751 800000 600000 74T 400000 200000 0 -^^ L \^ A \j-^j^ I ^-^ ^ Time--> 5.00 10.00 15.00 20.00 25.00 30.00 35.00 MAR02014.D 8270.M Fri Mar 04 09:37:46 1994 Page Data File C:\HPCHEM\1\DATA\MAR02\MAR02015.D Acq Time 2 Mar 94 10:54 pm Operator: DP Sanple 94-0092 SLP, 0.1 L/l mL Inst Semiv Misc ' Multiplr: 1.00 Quant Time; Mar 4 9:38 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Thu Mar 03 17:12:32 1994 Response via Multiple Level Calibration Internal Stauidards R.T. Qlon Response Cone Units DevO 1) l,4-dichloroben2ene-d4 8.37 152 372230 40.0 0 ug/mL -0 19) naphthalene-dB 11.14 136 1376912 40.00 ug/mL -0 34) acenaphthene-dlO 15.36 164 679982 40.0 0 ug/mL -0 5 3) phenanthrene-dl0 19.29 188 961386 40.0 0 ug/mL -0 67) chrysene-dl2 27.01 240 968445 40.0 0 ug/mL -0 75) perylene-dl2 31.39 264 1129857 40.00 ug/mL -0 System Monitoring Compounds %Recov 4) 2-fluorophenol (surr) 6.02 112 1050208 78.20 ug/mL 39 5) phenol-d5 (surr) 7.83 99 1012238 62.11 ug/mL 31 20) nitrobenzene-d5 (surr) 9.64 82 870120 63.52 ug/mL 63 38) 2-fluorobiphenyl (surr) 13.77 172 1463163 73.3 9 ug/mL 73 58) 2,4,6-tribromophenol (surr 17.48 330 447194 242.68 ug/mL 121 69) terphenyl-dl4 (surr) 24.10 244 2050828 89.29 ug/mL 89 Target Compounds Qva 17)—N-.-.niirosodi -n-propylamine 9.64 - 70 135130 1-0-^57 ug/mLtt 43)-2,6-dinitrotoluene 15.36 165 8796B l-4-.53^ug/mL# .56) N-nitrosodiphenylamine 17.48 169 14999 1.-22 ug/mL« 74) bis (2-ethylhexyl) phthala 27.72 149 81167 2.28 ug/mL {#) = qualifier out of range (m) = manual integration MAR02015.D 8270.M Fri Mar 04 09:38:55 1994 Page Data File : C;\HPCHEM\1\DATA\MAR02\MAR02015.D Acq Time : 2 Mar 94 10:54 pm Operator: jp Sanple : 94-0092 SLP, 0.1 L/l mL Inst : Semiv Misc : Multiplr: 1.00 Quant Time: Mar 4 9:38 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Thu Mar 03 17:12:32 1994 Response via Multiple Level Calibration Abundance TIC: MAR02015.D 2600000-1 2400000 2200000 I 2000000 1800000 1600000 1400000 ; ^ I 1200000 ^ 1000000 751 800000 H 600000 74T 400000 200000 Time--> 5.00 10.00 15.00 20.00 25.00 30.00 35.00 MAR02015.D 8270.M Fri Mar 04 09:39:02 1994 Page Data File : C:\HPCHEM\1\DATA\MAR02\MAR02016.D Acq Time 2 Mar 94 11:46 pm Operator: DP Sanple 94-0091 MS SLP, 0.1 L/l mL, 100 Inst Seiv. '/I Misc Multiplr: 1.0 Quant Time; Mar 4 9:40 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Thu Mar 03 17:12:32 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev 1) i,4-dichloroben2ene-d4 8.38 152 375333 40,00 ug/mL -0 19) naphthalene-dB 11.16 136 1421007 40.00 ug/mL -0 34) acenaphthene-dlO 15.36 164 72901 3 40.00 ug/mL -0. 53) phenanthrene-dlO 19.31 188 100472 4 40.00 ug/mL -0. 67) chrysene-dl2 27.02 240 996988 40.00 ug/mL -0. 75) perylene-dl2 31.40 264 1178712 40.00 ug/mL -0. System Monitoring Compounds %Recove 4) 2-fluorophenol (surr) 6.02 112 113916 4 84.12 ug/mL 42. 5) phenol-d5 (surr) 7.85 99 118615 5 72.17 ug/mL 36.. 20) nitrobenzene-d5 (surr) 9.65 82 899673 63.64 . ug/mL 63. 38) 2-fluorobiphenyl (surr) 13.77 172 1543728 72.22 ug/mL 72. 58) 2,4,6-tribromophenol (surr 17.50 330 564838 293.3 0 ug/mL 146. 69) terphenyl-dl4 (surr) 24.10 244 204403 1 86.45 ug/mL 86. Target Compounds Qval 6) phenol 7.88 94 659819 37.20 ug/mL 6) bic (3-chloroGthyl)othor -8 . 03 —9 3 1€-7-91 —l-.-05-ug/mL#~ 9) 2-chlorophenol 8.03 128 766073 57.24 ug/mL 10-)—1; S-dichlorobenaono 8-r-4-3r -^4-6 -=?^6-i^ri^J. —57-r53-ug-/mt— 11) 1,4-dichlorobenzene 8.41 146 796559 58.55 ug/mL 17) N-nitrosodi-n-propylamine 9.45 70 722687 60.54 ug/mL 28) 1,2,4-trichlorobenzene 11.08 180 627211 69.25 ug/mL 32) 4-chloro-3-methylphenol 12.63 107 791509 69.84 ug/mL 33) 2-methylnaphthalene 12.63 142 621738 3 0.44 ug/mL# 4-3-)—2T-6—dini trotoluene 15.3C 1« P5381 14 .67 ug/mL# 45) acenaphthene 15.46 154 1385037 71.77 ug/mL 47) 4-nitrophenol 15.98 139 336875 50.29 ug/mL# 49) 2,4-dinitrotoluene 16.10 165 748646 83.34 ug/mL 5^-)—5^ N nitrooodiphenylomine 17.DO 3r69 IDQOO I.D5 ug/iiiLti 61) pentachlorophenol 19.03 266 395103 123.85 - ug/mL 68) pyrene 23.41 202 2766374 77.59 ug/mL 74) bis (2-ethylhexyl) phthala 27.73 149 84947 2.32 ug/mL (#) = qualifier out of range (m) « manual integration MAR02016.D 8270.M Fri Mar 04 09:40:14 1994 Page Data File C:\HPCHEM\l\nATA\MAR02\MAR02016.D Acq Time 2 Mar 94 11:46 pm Operator: 2' Sanple 94-0091 MS SLP, 0.1 L/l mL, 100 Inst : S i'^ Misc Multiplr: 1. 0 Quant Time Mar 4 9:40 1994 Method : C:\HPCHEM\1\METHODS\8270.M Title : Method 8270 Last Update : Thu Mar 03 17:12:32 1994 Response via Multiple Level Calibration Abundance TIC: MAR02016.D 2800000 45M 2600000 2400000 9M 38S 2200000 4S ^L. xxM 69S 2000000 6M 68M 5S .9l33T 58S 1800000 lOT i9M 32M 56C • 1600000 28M 531 20S 1400000 17M «IT 61M 1200000 671 ] ; 1000000 .M I 751 I : , 800000 600000 74T 400000 I 200000 - rJ* I. I II.I ,1 t LL Time- 5.00 10.00 15.00 20.00 25.00 30.00 35.00 MAR02016.D 8270.M Fri Mar 04 09:40:23 1994 Page Data File C:\HPCHEM\1\DATA\MAR02\MAR02017.D Acq Time 3 Mar 94 12:38 am Operator D¥- Sanple 94-0091 MSD SLP, 0.1 L/l mL, 100 Inst Se Misc Multiplr 1.: Quant Time Mar 4 9:41 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Thu Mar 03 17:12:32 1994 Response via Multiple Level Calibration Internal Stamdards R.T. Qlon Response Cone Units Dev 1) 1,4-dichlorcbenzene-d4 8.38 152 374656 40.00 ug/raL -( 19) naphthalene-dB 11.17 136 1416098 40.00 ug/mL -t 34) acenaphthene-dlO 15.37 164 724491 40,00 ug/mL -0 53) phenanthrene-dlO 19.31 188 1000175 40.00 ug/mL -0 67) chrysene-dl2 27.02 240 992430 40.00 ug/mL -0 75) perylene-dl2 31.41 264 1158154 40.00 ug/mL -0 System Monitoring Compounds %Recov< 4) 2-fluorophenol (surr) 6.02 112 1138911 84.26 ug/mL 42 5) phenol-d5 (surr) 7.85 99 1179362 71.89 ug/mL 35. 20) nitrobenzene-d5 (surr) 9.65 82 905314 64.27 ug/mL 64 38) 2-fluorobiphenyl (surr) 13.78 172 1528331 71.95 ug/mL 71 58) 2,4,6-tribromophenol (surr 17.51 330 564206 294.30 ug/mL 147 69) terphenyl-dl4 (surr) 24.11 244 2015067 85.61 ug/mL 85 Target Compounds Qva. 6) phenol 7.87 94 619137 34.97 ug/mL# -8-)—bio (3-chloroethyl) ether -&-r*3- -9^ - ~1^^4 9 2-chlorophenol 8.03 128 762048 57.05 ug/mL 1-6-r 1, 3—dichi-orobenzene- • 8.4 2 146 799471 57. es ug^/mL 11) 1,4-dichlorobenzene 8.42 146 799471 se. 87 ug/mL 17) N-nitrosodi-n-propylamine 9.46 70 717773 60.24 ug/mL 28) 1,2,4-trichlorobenzene 11.09 180 625976 69.36 ug/mL 32) 4-chloro-3-methyiphenoi 12.64 107 800815 70.91 ug/mL -S-met-hylnaphthalene——> 12 ^ .&/"6'i, i4-45^ 634001 3 0.66 ug/mLft 404 2 r-6—dini;; rot oluene 15.36 3r^-5- P3500 14 . 47 ug/mLtt 45) acenaphthene 15.47 154 1375940 71.75 ug/mL 47) 4-nitrophenol 15.98 139 331117 4 9,74 ug/mL# 49) 2,4-dinitrotoluene 16.10 165 754621 84.53 ug/mL 56)-N•nitrooodiphenylawtne 17.51 3r&-9- 19790 1.5 5 ug/mLti 61) pentachlorophenol 19.04 266 374627 117.97 ug/mL 68) pyrene 23.42 202 2758834 77.74 ug/mL 74) bis (2-ethylhexyl) phthala 27.74 149 84785 2.32 ug/mL (#) = cjualifier out of range (m) - manual integration MAR02017.D 8270.M Fri Mar 04 09:41:22 1994 Page Data File C:\HPCHEM\1\DATA\MAR02\MAR02017.D Acq Time 3 Mar 94 12:38 am Operator: jj, Sanple 94-0091 MSD SLP, 0.1 L/l mL, 100 Inst : Se; v Misc Multiplr: I.L Quant Time Mar 4 9:41 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last I^date Thu Mar 03 17:12:32 1994 Response via Multiple Level Calibration Abundcuice TIC: MAR02017.D 1 lOT ^5M 2600000 20S 17M 2400000 . 38S 1 2200000 9M 68 M 2000000 ;9S 1 IIM 19^ 1800000 5S 3: 1600000 m 1 1 =f^53I J 2JI M 3 ' I 14 00000 -! 4: T 61M 1200000 -j ll1 1 "M 671 1000000 7^1 800000 600000 400000 - 74T • 200000 n - .. ^^_i ^ .L. . .1 ,K-. I. tj k rime--> 5 00 10.00 15.00 20.00 25.00 30. 00 35.00 MAR02017.D 8270.M Fri Mar 04 09:41:30 1994 Page Method C:\HPCHEM\1\METHODS\B270.M Title Method 8270 Last Update Fri Mar 04 09:52:25 1994 Response via Initial Calibration Non-Spiked Sanple: MAR02014.D Spike Spike Sanple Duplicate Sample File ID MAR02016.D MAR02017.D Sample 94-0091 MS SLP, 0.1 L/l mL, 100 I 94-0091 MSD SLl Acq Time 2 Mar 94 11:46 pm 3 Mar 94 12:38 am Compound Sanple Spike Spike Dup Spike Dup RPD QC Limitt Cone Added Res Res %Ree %Rec RPD % Rec phenol 1 0.1 1 100 37 1 35 1 37 1 35 1 ^ 1 ^^ 12 - 8; 2-chlorophenol 0.0 100 57 57 57 57 0 40 27-12; 1,4-dichlorobenzene 0.0 100 59 59 59 59 1 28 36- 9' N-nitrosodi-n-propyl 10.7 100 61 60 50 50 1 38 41-lK 1,2,4-trichlorobenze 0.0 100 69 69 69 69 0 28 39- 9{ 4 -chloro-3-methylphe 0.0 100 70 71 70 71 2 42 23- 9' acenaphthene 0.1 100 72 72 72 72 0 31 46-111 4-nitrophenol 0.0 100 50 50 50 50 1 50 10- 8( 2,4-dinitrotoluene 0.0 100 83 85 83 85 1 38 24- 9( pent a chlorophenol 0.0 100 124 118 124# 118# 5 i 50 1 9-10: ^ di-n-butylphthalate— 0.2 100 - 0- 0— -nit nn 1 r ii-i: pyrene -tt«r - Xv 0.0 100 78 78 78 78 0 31 1 26-12' 8270.M Fri Mar 04 09:52:55 1994 'A .-X' ,-v»tAr\r\>. "iPi lt>- yv.. n Data File C:\HPCHEM\1\DATA\MAR02\MAR0201B.D Acq Time 3 Mar 94 1:31 am Operator: j Sanple 94-0090 ELT, 0.1 L/l mL .Inst : s ,^ Misc" : Multiplr: 1 Quant Time: Mar 4 9:42 1994 Method C:\HPCHEM\1\METHODS\82 70.M Title Method 8270 Last Update Thu Mar 03 17:12:32 1994 Response via Multiple Level Calibration Internal Standcurds R.T. Qlon Response Cone Units De"\ 1) 1,4-dichlorobenzene-d4 8.38 152 367616 40.00 ug/mL 19) naphthalene-dB 11.15 136 1390961 40,00 ug/mL -( 34) acenaphthene-dlO 15.37 164 688005 40.00 ug/mL -C 53) phenanthrene-dlO 19.31 188 969341 40.00 ug/mL -0 67) ehrysene-dl2 27.03 240 978135 40.00 ug/mL -0 75) perylene-dl2 31.40 264 1131950 40.00 ug/mL -0 System Monitoring Compounds VRecov( 4) 2-fluorophenol (surr) 6.03 112 1287608 97.08 ug/mL 48 5) phenol-dS (surr) 7.85 99 1236382 76.81 ug/mL 38 20) nitrobenzene-ds (surr) 9.65 82 976972 70.61 ug/mL 70 38) 2-fluorobiphenyl (surr) 13.78 172 1604517 79,54 ug/mL 79 58) 2,4,6-tribromophenol (surr 17.51 330 588196 316.5 8 ug/mL 158 69) terphenyl-dl4 (surr) 24.11 244 2007515 86.54 ug/mL 86 Target Compounds Qva. 1-7J—N-nitrosodi-n-propylamine 9 . 65 ?-& 1361CC 11.02 ug/mLtt 43J 7 , f;-r}-in-irT-r>rn1iig»np .15-37.-165 19480 -14.5^9 -ug/raL# 56) N-nitrosodiphenylamine 17.50 169 20826 1.68 ug/mL# 74) bis {2-ethylhexyl) phthala 27.75 149 2776'20 7.72 ug/mL (#) = qualifier out of range (m) « manual integration MAR02018.D 8270.M Fri Mar 04 09:42:28 1994 Page Data File C:\HPCHEM\1\DATA\MAR02\MAR02018.D Acq Time 3 Mar 94 1:31 am Operator: j Sanple 94-0090 ELT, 0.1 L/l mL Inst : Si. .\ Misc Multiplr: 1. QueUit Time Mar 4 9:42 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last l^date Thu Mar 03 17:12:32 1994 Response via Multiple Level Calibration Sundance TIC: MAR02018.D 2B00000H 2600000 2400000 38S 191 2200000 20S 2000000 45 17M 1800000 SS 69S 1600000 -I igg II 1400000 asT 531 1200000 671 1000000 751 800000 74T 600000 400000 200000 jJ i». IWVjJL —ill ,-.. k t-l M-^ ' — ' —I— '~ rime--> 5.00 10.00 15.00 20.00 25.00 30.00 35.00 MAR02018.D 8270.M Fri Mar 04 09:42:35 1994 Page Data File C:\HPCHEM\1\DATA\MAR02\MAR02019.D Acq Time 3 Mar 94 2:24 am Operator: jj Sanple 94-0091 ELT, 0.1 L/l mL Inst : Sfc V Misc Multiplr: 1. Quant Time; Mar 4 9:43 1994 Method : C:\HPCHEM\1\METHODS\8270.M Title : Method 8270 Last Update : Thu Mar 03 17:12:32 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units De^ 1) 1,4-dichlorobenzene-d4 8.39 152 369331 40.0 0 ug/mL -^ 19) naphthalene-dB 11.16 136 1402978 40.00 ug/mL -t 34) acenaphthene-dlO 15.37 164 694979 40.0 0 ug/mL -0 53) phenanthrene-dlO 19.31 188 969353 40.0 0 ug/mL -0. 67) chrysene-dl2 27.04 240 989413 4 0.00 ug/mL -0. 75) perylene-dl2 31.42 264 1170925 40.00 ug/mL -0. System Monitoring Compounds %Recovc 4) 2-fluorophenol (surr) 6.03 112 1063289 79.80 ug/mL 39. 5) phenol-d5 (surr) 7.85 99 1133198 70.07 ug/mL 35. 20) nitrobenzene-dS (surr) 9.66 82 886281 63.5 0 ug/mL 63. 38) 2-fluorobiphenyl (surr) 13.79 172 1509543 74.08 ug/mL 74. 58) 2,4,6-tribromophenol (surr 17.51 330 519971 279.8 5 ug/mL 139. 69) terphenyl-dl4 (surr) 24.12 244 1968923 83.91 ug/mL 83, Target Compounds QvaJ I'U—N-ni4:rosodi-D-. propylamine 9-66 ^ 128276 10.02 ug/mL# 24) 2,4-dimethylphenol 10.5.0.58 121222 14438 1.63 ug/mL -«4- -3/-6-dini-tret-oluefle 15-. 37—tfr5 -9^3574 i4.50 ug/mLtt -5-64—^ nitrogodiphenylamirte 2-7 r5i 3r6-9 —±6252 i-.^-B-ug/mL# 74) bis (2-ethylhexyl) phthala 27.75 149 223653 6.15 ug/mL (#) = qualifier out of range (m) « manual integration MAR02019.D 8270.M Fri Mar 04 09:43:34 1994 Page Data File C:\HPCHEM\1\DATA\MAR02\MAR02019.D Acq Time 3 Mar 94 2:24 am Operator: *. Sanple 94-0091 ELT, 0.1 L/l mL Inst : Si i- Misc Multiplr: 1. ) Qusmt Time Mar 4 9:43 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Thu Mar 03 17:12:32 1994 Response via Multiple Level Calibration ?Vbundanee TIC: MAR02019.D 2600000 191 2400000 38S 2200000 •{ 2000000 20S 17M 1800000 58S 69S 4S 1600000 :¥ I 56C i 1400000 -J )I IIT 1 531 ; 1200000 671 J ! 1000000 751 24 800000 600000 74T 400000 200000 ALL ui • f - • |-.iiirf>F'*,>^ r^r , -' ! y n , , r- Time--> 5.00 10.00 15.00 20.00 25.00 30.00 35.00 MAR02019.D 8270.M Fri Mar 04 09:43:41 1994 Pag€ Data File C:\HPCHEM\1\DATA\MAR02\MAR02020.D Acq Time 3 Mar 94 3:17 am Operator: j; Sanple 94-0092 ELT, 0.1 L/l mL Inst : Se V Misc Multiplr: 1.. Quamt Time Mar 4 9:45 1994 Method : C:\HPCHEM\1\METHODS\8270.M Title : Method 8270 Last Update : Thu Mar 03 17:12:32 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev 1) 1,4 -dichlorobenzene-d4 8.39 152 383007 40 .00 ug/mL -V. 19) naphthalene-dB 11.17 136 1440779 40 .00 ug/mL -I 34) acenaphthene-dlO 15.38 164 713032 40 .00 ug/mL -c 5 3) phenanthrene-dl0 19.32 188 1000302 40 .00 ug/mL -0. 67) chrysene-dl2 27.04 240 1023148 40 .00 ug/raL -0. 75) perylene-dl2 31.43 264 1195077 40 .00 ug/mL 0. System Monitoring Compounds *Recov€ 4) 2-f1uorophenol (surr) 6.04 112 1172843 84 .87 ug/mL 42. 5) phenol-d5 (surr) 7.85 99 1108952 66 .12 ug/mL 33. 20) nitrobenzene-dS (surr) 9.66 82 1015441 70 .85 ug/mL 70. 3 8) 2-f1uorobiphenyl (surr) 13.79 172 1676709 80 .20 ug/mL 80. 58) 2,4,6-tribromophenol (surr 17.52 330 550241 286 98 ug/mL 143. 69) terphenyl-dl4 (surr) 24.12 244 2096589 86 40 ug/roL 86. Target Compounds aval 1^-^—N-nit-rosodi—n-propylamine - -9-.-6-6- 7n 43) -2-r6-dinitrotolue»e- - -1-5--.^^?--^5 qn-i 07 1 A ^LH 56) N-nitrnsodiphenylamine 17.52 16 9 18 775 1 • . 47 ^ig/iTaj# 61) pentachlorophenol — 18.96 266- - - -6913- 2-.-l-8-«gyfltL# 74) bis (2-ethylhexyl) phthala 27.76 149 448388 11. 92 ug/mL (#) = cjualifier out of range (m) - manual integration MAR02020.D 8270.M Fri Mar 04 09:45:56 1994 Page Data File C:\HPCHEM\1\DATA\MAR02\MAR02020.D Acq Time 3 Mar 94 3:17 am Operator: j; Sanple 94-0092 ELT, 0.1 L/l mL Inst : sk .1"^ Misc Multiplr: 1. > Qucuit Time Mar 4 9:45 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Thu Mar 03 17:12:32 1994 Response via Multiple Level Calibration Abundance 2800000 2600000 2400000 2200000 2000000 1800000 1600000 -I 1400000 1200000 J 1000000 800000 600000 400000 200000 frime--> 5.00 10.00 15.00 20.00 25.00 30.00 35.00 MAR02020.D 8270.M Fri Mar 04 09:46:03 1994 Page Data File C:\HPCHEM\1\DATA\MAR02\MAR02021.D Acq Time 3 Kax 94 4:08 am Operator: 3 Sanple DFTPP +, 50-0 ppm. Inst : St. i-t Misc Multiplr: 1., Quant Time Mar 4 9:46 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Thu Mar 03 17:12:32 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dex 1) i,4-dichloroben2ene-d4 8.40 152 460914 40.00 ug/mL 19) naphthalene-dB 11.18 136 1700010 40,00 ug/mL - K 3 4) acenaphthene-dl0 15.38 164 842977 40.00 ug/mL -C 5 3) phenanthrene-dl0 19.33 188 1200630 40.00 ug/mL 0 67) ehrysene-dl2 27.05 240 1207624 40.00 ug/mL 0 75) perylene-dl2 31.42 264 1119580 40.00 ug/mL -0 System Monitoring Compounds %Recov( 4) 2-fluorophenol (surr) 0.00 112 0 0.00 ug/mL 0 5) phenol-dS (surr) 0.00 99 0 0.00 ug/mL 0 20) nitrobenzene-dS (surr) 0.00 82 0 0.00 ug/mL 0. 38) 2-fluorobiphenyl (surr) 0.00 172 0 0.00 ug/mL 0 58) 2,4,6-tribromophenol (surr 0.00 330 0 0.00 ug/mL 0 69) terphenyl-dl4 (surr) 24.07 244 516 0.02 ug/mL 0 Target Compounds Qva." 43) 2 g-dinitrotoluono 15.30 -3rfr5 10DC70 14.DD ug/u^L# 61) pentachlorophenol 19.05 266 284543 74.64 ug/mL 66) benzidine 23.37 184 1218948 60.58 ug/mL (#) = cjualifier out of range (m) « manual integration MAR02021.D 8270.M Fri Mar 04 09:46:53 1994 Page Data File C:\HPCHEM\1\DATA\MAR02\MAR02021.D Acq Time 3 Mar 94 4:08 am Operator: j|: Sanple DFTPP +, 50.0 ppm. Inst : Se' V Misc Multiplr: l.C Quant Time Mar 4 9:46 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Thu Mar 03 17:12:32 1994 Response via Multiple Level Calibration Abundance TIC: MAR02021.D 2200000 191 2000000 341 1800000 531 1600000 43T II 1400000 1200000 -i 671 1 66T t 61^1 I 1 J 1000000 I j 751 800000 " 600000 400000 ] 200000 .^ 0 -^ L ll il L I I I rrime--> 5.00 10.00 15.00 20.00 25.00 30.00 35.00 MAR02021.D 8270.M Fri Mar 04 09:46:59 1994 Page Comment: Operator; Data Path: C:\HPCHEM\1\DATA\ Pre-Seq Cmd: Post-Seq C^md: Method Sections To Run On A Barcode Mismatch ( ) Full Method (X) Inject Anyway (X) Reprocessing Only ( ) Don't Inject Line Type Vial DataFile Method Sanple Name 1) Sample 1 MAR03001 8270 8270 mix #1, 50.0 ppm 2) Sample 2 MAR03002 8270 8270 mix #2, 50.0 ppm 3) Sample 3 MAR03003 8270 Blank 4) Sample 4 MAR03004 8270 94-0090 TCLP, 0.1 L/l mL 5) Sample 5 MAR03005 8270 94-0091 TCLP, 0.1 L/l mL 6) Sample 6 MAR03006 8270 94-0092 TCLP, 0.1 L/l mL 7) Sample 7 MAR03007 8270 94-0090 soil, 3.0 g/1 mL 8) Sample 8 MAR0300e 8270 94-0092 soil, 3.0 g/1 mL 9) Sample 9 MAR03009 8270 94-0092 MS soil, 3.0 g/1 mL, i 10) Sample 10 MAR03010 8270 94-0091 soil, 3.0 g/1 mL, l/K 11) Sample 11 MAR03011 8270 94-0092 MSD soil, 3.0 g/1 mL, 12) Sample 12 MAR03012 8270 94-0091 soil, 3.0 g/1 mL 13) Sample 13 MAR03013 8270 TCLP ref std, 50.0 ppm 14) Sample 14 MAR03014 8270 Blank Last Modified: Wed Apr 06 11:24:37 1994 Page: 1 Data File C:\HPCHEM\1\DATA\MAR03\DFTPP-1.D Acq Time 3 Mar 94 8:45 am Operator: mw/jp Sanple dftpp, 50.0 ppm, Inst : Semivol Misc em voltage lowered by 50 Multiplr: 1,00 Method C: \HP(3JEM\1\METH0DS\ B270STD. M Title Method 8270 Scam Number 297 Target Rel. to Lower Upper Rel. Raw Result Mass Mass Limit% Limit% Abn% Abn Pass/Fail 1 51 1 198 30 1 60 ' 45.1 ' 64584 PASS 1 68 69 0 2 0.0 0 PASS 69 198 0 100 65.1 93200 PASS 70 69 0 2 0.0 0 PASS 127 198 40 60 50.3 72024 PASS 197 198 0 1 0.0 0 PASS . 198 198 100 100 100.0 143104 PASS 199 198 5 9 6.5 9285 PASS 275 198 10 30 21.8 31224 PASS 365 198 1 100 2.5 3579 PASS 441 443 0 100 94.2 18528 PASS 442 198 40 100 70.7 101120 PASS 443 442 17 23 19.4 1 19664 PASS 1 DFTPP-l.D 8270STD.M Thu Mar 03 08:58:22 1994 Data File C: \HPCHEM\1\DATA\MAR03\MAR03001 .D Acq Time 3 Meu: 94 9:06 am Operator: jp -w Sanple 8270 mix #1, 50.0 ppm Inst : Set. vt. Misc Multiplr: I.L Quant Time Mar 4 10:12 1994 Method : C:\HPCHEM\1\METHODS\8270.M Title : Method 8270 Last Update : Fri Mar 04 09:52:25 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev 1) 1,4-dichloroben2ene-d4 8 .40 152 392345 40 .00 ug/mL C 19) naphthalene-dB 11 .19 136 1560894 40 .00 ug/mL 0 34) a c enapht hene-dl0 15 .39 164 750489 40 .00 ug/mL -0. 53) phenanthrene-dl0 19 .34 188 1148407 40 .00 ug/mL 0. 67) chrysene-dl2 27 .08 240 1027368 40 .00 ug/mL 0. 75) perylene-dl2 31 .47 264 1221866 40 .00 ug/mL 0. Syst em Monitoring Compounds %Recove 4) 2-fluorophenol (surr) 6 .04 112 679644 48 .01 ug/mL •d.^. 5) phenol-dS (surr) 7 .87 99 777438 45 .25 ug/mL 22^ 20) nitrobenzene-d5 (surr) 9 .67 82 715144 46 .06 ug/mL 4«-r 38) 2-fluorobiphenyl (surr) 13 .80 172 1147693 52 .l€ ug/mL 52^ 58) 2,4,6-tribromophenol (surr 17 .51 330 208249 94 .61 ug/mL A=^-^ 69) terphenyl-dl4 (surr) 24 .11 244 1182519 48 .53 ug/mL -«^ Targ et Compounds <3val 3) N-nitrosodimethylamine 3 .95 42 275562 39 .16 ug/mL 6) phenol 7 .91 94 829442 44 .73 ug/mL n 1 \ J .J 1 XtjUtjl^ -^ 0 8) bis(2-chloroethyl)ether 6 02 93 716080 42 69 ug/mL# 9) 2-chlorophenol B 06 128 685433 49 .00 ug/mL 15) bis(2-chloroisopropyl)ethe 9 14 45 659039 30 .62 ug/mL 17) N-nitrosodi-n-propylamine 9 47 70 514339 41 22 ug/mL 23) 2-nitrophenol 10 41 139 472256 S3 3 8 ug/mL 24) 2,4-dimethylphenol 10 60 122 495195 50 25 ug/mL 25) bis(2 -chloroethoxy)methane 10 82 93 840819 44 93 ug/mL 26) 2,4-dichlorophenol 10 95 162 504569 S3 65 ug/mL 29) naphthalene 11 24 128 1706767 46 76 ug/mL 32) 4 -chloro-3-methyiphenoi 12. 65 107 560444 45. 02 ug/-mL 33) 2-methylnaphthalene 12 65 142 440445 19. 63 ug/mL# 36) 2,4,6-trichlorophenol 13. 60 196 280ieo 56. 10' ug/mL •3 T 1 1 -1 r n 1 or A -1 1-1 .... / — T T J .-irr—Ug-T'-miT— 41) dimethylphthalate 14. 99 163 120e626 46. 26 ug/mL 42) acenaphthylene 15. 00 152 isoeese 44. 62 ug/mL ^ T )•— 2 , 6 -dinitrotoluene 14. 99 165 12752 1. 91 ug/mL# 45) acenaphthene 15. 48 154 964776 48. 56 ug/mL 46) 2,4-dinitrophenol 15. 69 184 117290 33. 31 ug/mL 47) 4-nitrophenol 16. 01 139 318109 46. 13 ug/mL SO) diethylphthalate 16. 87 149 1316481 SO. 86 ug/mL 51) fluorene 16. 80 166 1125088 54. 29 ug/mL 52) 4-chlorophenyl phenyl ethe 16. 90 204 476047 50. 32 ug/mL 55) 4,6-dinitro-2-methylphenol 17. 18 198 200828 42. 85 ug/mL# 56) N-nitrosodiphenylamine 17. 26 169 808810 55. 24 ug/mL ^74- ^ r\r\^ A 0 ^ ^ - ' •• T 11 -> -IT^ — iT7V;^4 0 r-r-x.\j ug/mLiff (#) = qualifier out of range (m) • manual integration MAR03001.D 8270.M Fri Mar 04 10:13:38 1994 Page Data File C:\HPCHEM\1\DATA\MAR03\MAR03001.D Acq Time 3 Mar 94 9:06 am Operator: jp m Sanple 8270 mix #1, 50.0 ppm Inst : Se- i^ Misc Multiplr: 1.;.:; Quant Time Mar 4 10:12 1994 Method : C:\HPCHEM\1\METHODS\8270.M Title : Method 8270 Last l^date : Fri Mar 04 09:52:25 1994 Response via Multiple Level Calibration Compound R.T. Qlon Response Cone Unit Q\ 59 4-bromophenyl phenyl ether 18.20 248 "302677 60,04 ug/mL 61 pentachlorophenol 19.07 266 245809 67.41 ug/mL 62 phenanthrene 19.42 178 1537846 48.49 ug/mL 63 anthracene 19.54 178 1530966 48.05 ug/mL 64 di-n-butylphthalate 21.48 149 2397934 48.22 ug/mL 65 fluoranthene 22.81 202 1509813 48.49 ug/mL 68 pyrene 23.43 202 1540995 41.94 ug/mL 70 butyl benzyl phthalate 25.81 149 1077681 41.82 ug/mL 71 benzo (a) anthracene 27.02 228 1391665 46.86 ug/mL 73 chrysene 27.17 228 1188482 45.55 ug/mL 74 bis (2-ethylhexyl) phthala 27.79 149 1540843 40.78 ug/mL 76 di-n-octylphthalate 29.74 149 2776479 38.56 ug/mL 77 benzo(b)fluoranthene 30.34 252 1537219 44.92 ug/mL# 76 benzo(k)fluoranthene 30.44 252 1404724 54.11 ug/mL 79 benzo(a)pyrene 31.29 252 1422095 48.03 ug/mL 80 benzo(g,h,i)perylene 34.47 276 1387006 49.15 ug/mL# 81 dibenzo(a,h)anthracene 34.59 278 1348059 50.80 ug/mL# 82 indeno(1,2,3-c,d)pyrene 35.23 276 1382936 50.41 ug/mL# (#) = qualifier out of range (m) » manual integration MAR03001.D 8270.M Fri Mar 04 10:13:41 1994 Page Data File C:\HPCHEM\1\DATA\M7^03\MAR03001.D Acq Time 3 Mar 94 9:06 am Operator: jp i\\ Sanple 8270 mix #1, 50.0 ppm Inst : Se i^ Misc Multiplr: 1. ) Quant Time Mar 4 10:12 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Fri Mar 04 09:52:25 1994 Response via Multiple Level Calibration Abundance TIC: MAR03001.D 2800000 23C 2600000 20S 74T 17M m 2400000 29T II 2200000 < SM 9M 38S 63T 57T 2000000 6MLST ^gj S6C 62T 76C 64T 1800000 8T SIT SOT 7T 26|C 73-: 41 70T 1600000 68M 78T 5S SffS 671 1400000 25T :i 1 4S 247 32tt,^' 1 -1 ^5%9S •'7T ] i 1200000 751 Bfe-gT 7:1 3flC 59T 79C 1000000 ^T l 5P |61 1 800000 8CT 600000 ly 400000 200000 I ik iL ml iHL '-••''«• -L rrime--> 5.00 10.00 15.00 20.00 25.00 30.00 35.00 MAR03001.D 8270.M Fri Mar 04 10:13:53 1994 Page Data File C:\HPCHEM\1\DATA\MAR03\MAR03002.D Acq Time 3 Mar 94 9:56 am Operator: j p nv Sanple 8270 mix #2, 50.0 ppm Inst : Set..v Misc Multiplr: l.C Quant Time Mar 4 10:23 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Fri Mar 04 09:52:25 1994 Response via Multiple Level Calibration Internal Stamdards R.T. Qlon Response Cone Units Dev 1) 1,4-diehlorobenzene-d4 8.41 152 410525 40.00 ug/mL C 19) naphthalene-dB 11 .20 136 1624982 40.00 ug/mL 0 34) acenaphthene-dl0 15 .40 164 806676 40.00 ug/mL 0. S3) phenanthrene-dl0 19 .34 188 1214651 40.00 ug/mL 0. 67) chrysene-dl2 27 .06 240 1130929 40.00 ug/mL 0. 75) perylene-dl2 31 .45 264 1261596 40.00 ug/mL 0. System Monitoring Compounds % Re cove 4) 2-fluorophenol (surr) 0.00 112 0 0.00 ug/mL 0. 5) phenol-dS (surr) 0 .00 99 0 0.00 ug/mL 0. 20) nitrobenzene-dS (surr) 9.46 82 65688 4.06. ug/mL 4. 38) 2-fluorobiphenyl (surr) 13 .68 172 1108 0.05 ug/mL 0. 58) 2,4,6-tribromophenol (surr 17 .49 330 216 0.09 ug/mL 0. 69) terphenyl-dl4 (surr) 24 .08 244 631 0.02 ug/mL 0. Target Compounds Qval 2) pyridine 3 .87 79 797680 47.78 ug/mL 7B?-fl-ft 5-4- 71 un7/ t . \)H. ug / mLiff • 7) aniline 7 87 93 1086601 43.42 ug/mL n\ u.^ ^ ;n :»v^i ^«.^n*-v«<<»i \ :M,*>u««.«. 7 87 9T 1 nfififim fjT o n iin/inT % 10) 1,3-dichlorobenzene 8 33 146 752375 49.68 ug/mL 11) 1,4-dichlorobenzene 8 45 146 719488 48.35 ug/mL 12) benzyl alcohol 8 82 108 450354 41.38 ug/mL 13) 1,2-dichlorobenzene 8 63 146 677811 46.89 ug/mL 14) o-cresol 9 12 108 650709 44.19 ug/mL 16) p-cresol 9 44 108 665053 42.67 ug/mL 18) hexachloroethane 9 46 117 281649 45.79 ug/mL 21) nitrobenzene 9 71 77 746042 47.92 ug/mL 22) isophorone 10 25 82 1438736 45.83 ug/mL "'I) -?i^ • ' 1 '4<) ' -"^Lfl9 fl 1 -71 yyi.. 1 m l 44 X .) J -ug/ ITUJW 27) benzoic acid 11 09 122 404055 46.63 ug/mL 28) 1,2,4-trichlorobenzene 11 12 180 536466 51.60 ug/mL 2 29J -jiaphthalene - - 11 48 128 72874 1.92 ug/mL# 30) 4-chloroaniline 11 48 127 829403 47.64 ug/mL 31) hexachlorobutadiene 11. 70 225 256674 53.45 ug/mL 33) 2-methylnaphthalene 12. 84 142 1132053 48.47 ug/mL 35) hexachlorocyclopentadiene 13. 38 237 182983 34.45 ug/mL tnc —3^5^1-6— —67-^99-ug-/mL— 37) 2,4,5-trichlorophenol 13. 68 196 365016 52.28 ug/mL 39) 2 -chloronaphthalene 13. 97 162 1135748 49.59 ug/mL 40) 2-nitroaniline 14. 38 65 416364 44.73 ug/mL 43) 2,6-dinitrotoluene 15. 14 165 364503 50.67 ug/tnL 44) 3-nitroaniline 15. 46 138 433971 50.82 ug/mL# 47) —3-6- ITO 7n il ^ X J . X^ J (#) = qualifier out of range (m) « manual integration MAR03002.D 8270.M Fri Mar 04 10:25:37 1994 Page Data File C:\HPCHEM\1\DATA\MAR03\MAR03002.D Acq Time 3 Mar 94 9:56 am Operator: jp m- Sanple 8270 mix #2, 50.0 ppm Inst : Se'ci^ Misc : Multiplr: l.:i) Quamt Time: Mar 4 10:23 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Fri Mar 04 09:52:25 1994 Response via Multiple Level Calibration Conpound R.T. Qlon Response Cone Unit 4 8) dibenzofuran 15.91 168 1517729 47.87 ug/mL 49) 2,4-dinitrotoluene 16,11 165 492745 49.57 ug/mL 54) 4-nitrosmiline 17.10 138 430420 49.88 ug/mL 57) azobenzene 17.31 77 1526781 45.40 ug/mL 6 0) hexachlorobenzene 18.52 284 395154 70.6 0 ug/mL# 66) benzidine 23,37 184 758921 37.28 ug/mL 72) 3,3'-dichlorobenzidine 27.14 252 617824 56.52 ug/mL (#) = cjualifier out of range (m) - manual integration MAR03002.D 8270.M Fri Mar 04 10:25:40 1994 Page Data File C:\HPCHEM\1\DATA\MAR03\MAR03002.D Acq Time 3 Mar 94 9:56 am Operator: jp/-nw Sanple 8270 mix #2, 50.0 ppm Inst : Sem vt Misc Multiplr: l.c: Quant Time Mar 4 10:23 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Fri Mar 04 09:52:25 1994 Response via Multiple Level Calibration jAbundance 2200000 I 2000000 1800000 I 1600000 I 1400000 A 1200000 1000000 I 800000 600000 I 400000 200000 . ^"^-^— —r-^ rrime--> 5.00 10.00 15.00 20.00 25.00 ' 30.00 35.00 MAR03002.D 8270.M Fri Mar 04 10:25:50 1994 Page Data File C:\HPCHEM\l\nATA\MAR03\MAR03003 .D Acq Time 3 Mar 94 10:47 am Operator: jp/inw Sanple Blamk Inst : Semivc Misc Multiplr: l.OD Quant Time Mar 4 10:26 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Fri Mar 04 09:52:25 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Devf^: 1) l,4-dichlorobenzene-d4 8.41 152 355605 40.00 ug/mL 0. 19) naphthalene-dB 11.19 136 1375586 40.00 ug/mL 0. 34) acenaphthene-dlO 15.40 164 655789 40.00 ug/mL 0. 5 3) phenanthrene-dl0 19.34 188 940897 40.00 ug/mL 0. 67) chrysene-dl2 27.06 240 946177 40.00 ug/mL 0. 75) perylene-dl2 31.44 264 1065601 40.00 ug/mL 0. System Monitoring Compounds %Recov€ 4) 2-fluorophenol (surr) 6.05 112 641168 49.97 ug/mL 2*-: 5) phenol-dS (surr) 7.87 99 735518 47.24 ug/mL -23-^ 20) nitrobenzene-dS (surr) 9.67 82 679478 49.65 ug/mL 49-7 38) 2-fluorobiphenyl (surr) 13.80 172 1040769 54.13 ug/mL 54-7 58) 2,4,6-tribromophenol (surr 17.50 330 184374 102.23 ug/mL Si-r 69) terphenyl-dl4 (surr) 24.12 244 1105192 49.25 ug/mL 4 ^ Target Compounds Qval 1-7-)- -N -nitrosodi-n-propylami-ne— —9-.-6^ 9^ 94DDG B-r40 -ug/mL# 43) -2,6-dinitrotoluene— - 15 .40—i-G5 -8634-7 •^<—77-ug/tnL# (#) = cjualifier out of ramge (m) • manual integration MAR03003.D 8270.M Fri Mar 04 10:27:05 1994 Page Data File C:\HPCHEM\1\DATA\MAR03\MAR03003.D Acq Time 3 Mar 94 10:47 am Operator: jp/m Sanple Blamk Inst : Serai' Misc Multiplr: l.CO Quant Time Mar 4 10:26 1994 Method : C:\HPCHEM\1\METHODS\8270.M Title : Method 8270 Last Update : Fri Mau: 04 09:52:25 1994 Response via Multiple Level Calibration Abundance TIC: MAR03003.D 2000000 1800000 1600000 1400000 3ST 1200000 531 69S • 671 1000000 751 800000 58S 600000 400000 200000 0 -i —-1 I . . I I +—, — If- r —-,r - ^ j , , , , ^ frime--> 5.00 10.00 15.00 20.00 25.00 30.00 35.00 MAR03003.D 8270.M Fri Mar 04 10:27:11 1994 Pag* Data File C:\HPCHEM\1\DATA\MAR03\MAR03004.D Acq Time 3 Mar 94 11:38 am Operator: jp/mv Sanple 94-0090 TCLP, 0.1 L/l mL Inst : Semiv Misc Multiplr: 1.00 Quant Time Mar 4 10:27 1994 Method : C:\HPCHEM\1\METHODS\8270.M Title : Method 8270 Last Update : Fri Mar 04 09:52:25 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev (I 1) 1,4-dichlorobenzene-d4 8.41 152 340510 40.00 ug/mL 0 19) naphthalene-dB 11.19 136 126740 8 40.00 ug/mL 0 34) acenaphthene-dlO 15.40 164 616221 40.00 ug/mL -0 53) phenanthrene-dlO 19.33 188 860236 40.00 ug/mL 0 67) chrysene-dl2 27.05 240 846938 40.00 ug/mL 0 75) perylene-dl2 31.44 264 988844 40.00 ug/mL 0 System Monitoring Compounds %Recov( 4) 2-fluorophenol (surr) 6.07 112 127436 4 103.73 ug/mL 51 5) phenol-dS (surr) 7.89 99 133116 3 89.28 ug/mL 44 20) nitrobenzene-dS (surr) 9.68 82 86339 2 68.48 ug/mL 68 38) 2-fluorobiphenyl (surr) 13.81 172 140873 8 77.97 ug/mL 77 58) 2,4,6-tribromophenol (surr 17.54 330 499553 302.97 ug/mL 151 69) terphenyl-dl4 (surr) 24.13 244 176758 7 88.00 ug/mL 88 Target Compounds Qva IIZJ N-ni rrosodi -n-prnpylaminfi 9 . 68 7.0— 13141 4 11.31 ug/mL# 4-34—3 , 6-dinitrotoluens ..15_,-4^ 3-&^ -76891 14.36 ug/mL# 50) diethylphthalate 16.85 149 143630 6.76 ug/mL -ErS^—N-nit robodiphenyl amine 17.53 169 17901 1.63 ug/mL# 74) bis (2-ethylhexyl) phthala 27.77 149 93722 3.01 ug/mL (#) = qualifier out of range (m) » manual integration MAR03004.D 8270.M Fri Mar 04 10:28:04 1994 Page Data File C:\HPCHEM\l\nATA\MAR03\MAR03004.D Acq Time 3 Mar 94 11:38 am Operator: jp/mv Sanple 94-0090 TCLP, Cl L/l niL Inst : Semi\ Misc Multiplr: 1.00 Quant Time Mar 4 10:27 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Fri Mar 04 09:52:25 1994 Response via Multiple Level Calibration Abundance TIC: MAR03004.D 2400000 2200000 2000000 1800000 1600000 -1 69S 1 i 1400000 -1 ] ] 1200000 -i I 1 531 1000000 -: 671 800000 751 600000 -I 400000 74T 200000 -I -4-^ k rrime--> 5.00 10.00 15.00 20.00 25.00 30.00 35.00 MAR03004.D 8270.M Fri Mar 04 10:28:11 1994 Page Data File C: \HPCHEM\1\DATA\MAR03\MAR03005 .D Acq Time 3 Mair 94 12:29 pm Operator: jp/mv Sanple 94-0091 TCLP, 0.1 L/l mL Inst : Semiv Misc Multiplr: 1.00 Quamt Time Mar 4 10:28 1994 Method : C:\HPCHEM\1\METHODS\8270.M Title : Method 8270 Last Update : Fri Mar 04 09:52:25 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev(f 1) l,4-dichlorobenzene-d4 8 .42 152 359425 40 .00 ug/mL 0 19) naphthalene-dB 11 .20 136 1378605 40 .00 ug/mL 0 3 4) acenaphthene-dl0 15 .41 164 667188 40 .00 ug/mL 0 5 3) phenanthrene-dl0 19 .34 188 964786 40 .00 ug/mL 0. 67) chrysene-dl2 27 .06 240 959983 40 .00 ug/mL 0 75) perylene-dl2 31 .45 264 1120731 40 .00 ug/roL 0 System Monitoring Compounds %Recov( 4) 2 -fluorophenol (surr) 6 .07 112 1097208 84 .61 ug/mL 42. 5) phenol-dS (surr) 7 .88 99 1086155 69 .01 ug/mL 34 20) nitrobenzene-dS (surr) 9 68 82 815525 59 47 ug/mL 59 38) 2-fluorobiphenyl (surr) 13 81 172 1367115 69 89 ug/mL 69 SB) 2,4,6-tribromophenol (surr 17 55 330 514972 278 47 ug/mL 139 69) terphenyl-dl4 (surr) 24 14 244 1915195 84 12 ug/mL 84 Target Compounds Qva: r r\ -^ n .. ^ .\ .\ A ^ « r. -. 154—N'nitrooodi n propylamine 9.-b- c — 70 113340 y--Sr 4 3)—2-r^ - dinitrotoluene 15.-4 1 -1-65 86684 —1-4. 57 -ug/«t4» 56) N-nitrosodiphenylamine 17. 54 169 -18883 - 1. 53 ug/mL# 74) bis (2-ethylhexyl) phthala 27. 77 149 67720 1. 92 ug/mL (#) = cjualifier out of range (m) • manual integration MAR03005.D 8270.M Fri Mar 04 10:29:00 1994 Page Data File C:\HPCHEM\l\nATA\MAR03\MAR03005.D Acq Time 3 Mar 94 12:29 pm Operator: jp/mw Sanple 94-0091 TCLP, 0.1 L/l mL Inst : Semivc. Misc Multiplr: 1.00 Quamt Time Mar 4 10:28 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Fri Mar 04 09:52:25 1994 Response via Multiple Level Calibration MAR0300S.D 8270.M Fri Mar 04 10:29:07 1994 Page Data File C:\HPCHEM\1\DATA\MAR03\MAR03006.D Acq Time 3 Mar 94 1:20 pm Operator: jp/mw Sanple 94-0092 TCLP, 0.1 L/l mL Inst : Semivc Misc Multiplr: 1.00 Quant Time Mar 4 10:30 1994 Method : C:\HPCHEM\1\METHODS\8270.M Title : Method 8270 Last Update : Fri Mar 04 09:52:25 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev(F 1) l,4-dichlorobenzene-d4 8.42 152 325008 40.00 ug/mL 0. 19) naphthalene-dB 11.20 136 1235474 40.00 ug/mL 0. 3 4) acenaphthene-dl0 15.41 164 597133 40.00 ug/mL 0. 53) phenanthrene-dlO 19.34 188 862387 40.00 ug/mL 0. 6 7) chrysene-dl2 27.06 240 857575 40.00 ug/mL 0. 75) perylene-dl2 31.45 264 1002572 40.00 ug/mL 0. System Monitoring Compounds %Recov€ 4) 2-fluorophenol (surr) 6.07 112 910108 77.61 ug/mL 38. 5) phenol-dS (surr) 7.87 99 911089 64.02 ug/mL 32. 20) nitrobenzene-ds (surr) 9.68 82 885346 72.04 ug/mL 72. 38) 2-fluorobiphenyl (surr) 13.81 172 1426516 81.48 ug/mL 81. 58) 2,4,6-tribromophenol (surr 17.54 330 390223 236.07 ug/mL 118. 69) terphenyl-dl4 (surr) 24.14 244 1768291 86.94 ug/mL 86. Target Compounds Qval 174—N-nitroBodi-n-propylamine -9^r6€ ^ 121D51 11.00 ug/mL#— 43) 2,6-dinitrotoluene 15.44—165 -77214 14.50 ug/mL# -S£J—N-nitrosodiphenylamine 17.52 1-^^ —3^^^ ^ 1.27 ug/mL#— -6-i^—pentaehleyophonol 10.OC i*^ 1P741 -^23r-«g7%L# 74) bis (2-ethylhexyl) phthala 27.77 149 59552 1.89 ug/mL (#) = cjualifier out of range (m) « manual integration MAR03006.D 8270.M Fri Mar 04 10:30:14 1994 Page Data File C:\HPCBEM\1\DATA\MAR03\MAR03006.D Acq Time 3 Naur 94 1:20 pm Operator: jp/m Sanple 94-0092 TCLP, 0.1 L/l mL Inst : Semi' Misc Multiplr: 1.00 Quamt Time Mar 4 10:30 1994 Method : C:\HPCHEM\1\METHODS\8270.M Title : Method 8270 Last I^date : Fri Mar 04 09:52:25 1994 Response via Multiple Level Calibration Abundance TIC: MAR03006.D 2400000 2200000 38S 191 2000000 20S 1800000 17M 69S 1600000 4S SSS 1400000 531 5^1 ««T 56C 1200000 1000000 671 800000 751 600000 400000 74T 200000 61'! 0 J^ %J4 kl X M- —, I 1 rrime--> 5.00 10.00 15.00 20.00 25.00 30.00 35.0 0 MAR03006.D 8270.M Fri Mar 04 10:30:21 1994 Pac Data File C:\HPCHEM\1\DATA\MAR03\MAR03007.D Acq Time 3 Mar 94 2:27 pm Operator: jp/mw Sanple 94-0090 SOIL, 3.0 g/1 mL Inst : Semivolat Misc Multiplr: 1.00 Quamt Time Mar 4 14:32 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Fri Mar 04 09:52:25 1994 Response via Multiple Level Calibration Internal Stamdards R.T. Qlon Response Cone Units Dev(Min 1) 1,4-diehlorobenzene-d4 8 .41 152 355103 40 .00 ug/mL 0.00 19) naphthalene-dB 11 ,19 136 1347099 40 .00 ug/mL 0.00 34) acenaphthene-dlO 15 .40 164 662555 40 .00 ug/mL 0.00 S3) phenanthrene-dl0 19 .34 188 921896 40 .00 ug/mL 0.00 67) chrysene-dl2 27 .08 240 918381 40 .00 ug/mL 0.03 75) perylene-dl2 31 .47 264 978109 40 .00 ug/mL 0.04 System Monitoring Compounds %Recover 4) 2-fluorophenol (surr) 6 .05 112 1127818 87 .78 ug/mL 43.89 5) phenol-dS (surr) 7 .86 99 1527338 97 .95 ug/mL 48.98 20) nitrobenzene-ds (surr) 9 .67 82 731864 54 .61 ug/mL 54.61' 38) 2-fluorobiphenyl (surr) 13 .81 172 1274840 65 .63 ug/mL 65.63 58) 2,4,6-tribromophenol (surr 17 .54 330 509603 288 .39 ug/mL 144.20 69) terphenyl-dl4 (surr) 24 .14 244 1626333 74 .67 ug/mL 74.67 Target Compounds (Rvalue 9, 67 -ir\ imfi77 Q 07 iifT /mT -H - i^ 4 0 "^ '^^ CLA . Iin/inT.J£- 1 1 454- 3,6-dinitrotol-u€Re -- 85899 — 14 3^ ug / llllJ (#) = cjualifier out of range (m) » manual integration MAR03007.D 8270.M Fri Mar 04 14:34:41 1994 Data File C:\HPCHEM\1\DATA\MAR03\MAR03007.D Acq Time 3 Mar 94 2:27 pm Operator: jp/mv Sanple 94-0090 SOIL, 3.0 g/1 mL Inst : Semiv Misc Multiplr: 1.00 Quant Time Mar 4 10:31 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Fri Mar 04 09:52:25 1994 Response via Multiple Level Calibration Sundance 2200000 2000000 1800000 1600000 1400000 1200000 1000000 -j t ] J eooooo -j 1I 600000 i 400000 200000 Time--> 5.00 MAR03007.D 8270.M Fri Mar 04 10:31:54 1994 Page Data File C:\HPCHEM\1\DATA\KAR03\MAR03008.D Acq Time 3 Mar 94 3:17 pm Operator: jp/mv Sanple 94-0092 SOIL, 3.0 g/1 mL Inst : Semi\ Misc Multiplr: 1.00 Quant Time Mar 4 10:34 1994 Method : C:\HPCHEMV1\METH0DS\8270.M Title : Method 8270 Last Update : Fri Mau: 04 09:52:25 1994 Response via Multiple Level Calibration Internal Stamdards R.T. Qlon Response Cone Units Dev( 1) l,4-dichlorobenzene-d4 8.41 152 350013 40.0 0 ug/mL 0 19) naphthalene-dB 11.19 136 1342553 40.00 ug/mL 0 34) acenaphthene-dlO 15.41 164 654112 40.0 0 ug/mL 0 53) phenanthrene-dlO 19.35 188 925050 40.0 0 ug/mL C 67) chrysene-dl2 27.09 240 941420 40.0 0 ug/mL C 75) perylene-dl2 31.47 264 1032573 40.00 ug/mL C System Monitoring Compounds VRecov 4) 2-fluorophenol (surr) 6.05 112 989359 78.35 ug/mL 3S 5) phenol-dS (surr) 7.89 99 1356602 88.52 ug/mL 44 20) nitrobenzene-dS (surr) 9.67 82 645688 48.35 ug/mL 46 38) 2-fluorobiphenyl (surr) 13.82 172 1114921 58.13 ug/mL 56 56) 2,4,6-tribromophenol (surr 17.55 330 478271 269.74 ug/mL 134 69) terphenyl-dl4 (surr) 24.16 244 1683946 75.42 ug/mL 7£ Target Compounds Qvc 174—N-nitrosodi-n-propylamine 9.67 -7J^ 90050 8.09 ug/mLtt 29) naphthalene 11.23 128 32636 1.04 ug/mL 33) 2-methylnaphthalene 12.83 142 20101 1.04 ug/mL 43i—2 ,6-dinitiuLuluene -15.41 -165 -BSe^S i4^-56-ttgyndj# 62) phenanthrene 19.39 176 35719 1.40 ug/mL 63) anthracene 19.39 i-78- 35719 1.39-ug/mL — 64) di-n-butylphthalate 21.49 149 90622 2.27 ug/mL 65) fluoranthene 22.62 202 29413 1.17 ug/mL iM) = cjualifier out of range (m) • manual integration MAR03008.D 8270.M Fri Mar 04 10:35:05 1994 Pag Data File C:\HPCHEM\l\nATA\MAR03\MAR03008 .D Acq Time 3 Mar 94 3:17 pm Operator: jp/mw Sanple 94-0092 SOIL, 3.0 g/1 mL Inst : Semivc Misc Multiplr: 1.00 Quant Time Mar 4 10:34 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Fri Mar 04 09:52:25 1994 Response via Multiple Level Calibration Sundance TIC: MAR03008.D 2000000 1800000 38S SS 69S 20S 1600000 4S 17M 43T II 191 1400000 341 1200000 5IISS3I 671 751 1000000 800000 600000 400000 2:iT 200000 B3T >^Js.Ji J}\UU m Time--> 5.00 10.00 15.00 20.00 25.00 30.00 35.00 MAR03008.D 8270.M Fri Mar 04 10:35:12 1994 Page Data File C:\HPCHEM\1\DATA\MAR03\MAR03009.D Acq Time 3 Mar 94 4:23 pm Operator: jp/mw Sanple 94-0092 SOIL MS, 3.0 g/1 mL Inst : Semivc Misc Multiplr: 1.00 Quant Time Mar 4 10:36 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Fri Mar 04 09:52:25 1994 Response via Multiple Level Calibration Internal Stamdards R .T. Qlon Response Cone 1Units Dev(^ 1) i,4-dichlorobenzene-d4 8 .41 152 413358 40.00 ug/mL 0. 19) naphthalenie-dB 11 .19 136 1579753 40.00 ug/mL 0. 3 4) acenaphthene-dl0 15 .41 164 772088 40,00 ug/mL 0. 5 3) phenamt hrene - dl 0 19 .36 188 1066562 40.00 ug/mL 0. 67) chrysene-dl2 27 .09 240 1041997 40.00 ug/mL 0. 75) perylene-dl2 31 48 264 1136702 40.00 ug/mL 0. System Monitoring Compounds %Recove 4) 2-fluorophenol (surr) 6 07 112 1496416 100.34 ug/mL 50. 5) phenol-dS (surr) 7 90 99 2091663 115.56 ug/mL 57. 20) nitrobenzene-dS (surr) 9 69 82 965604 61.44 ug/mL 61. 38) 2-fluorobiphenyl (surr) 13, 83 172 1650532 72.91 ug/mL 72. 58) 2,4,6-tribromophenol (surr 17. 55 330 632490 309.39 ug/mL 154. 69) terphenyl-dl4 (surr) 24. 17 244 1902457 76.98 ug/mL 76. Target Compounds Qval 2) pyridine 3.90 79 623677 37.10 ug/mL 2M- 1,3-dichlorobenzene •^^-45- 678456 ug/mL 11) 1,4-dichlorobenzene 8.45 146 678458 45.28 ug/mL 14) o-cresol 9.12 108 766457 51.70 ug/mL 16) p-cresol 9.49 108 1468921 93.61 ug/mL N nitroaedi n-propylamrrte- D.GO 13D031 3^.34 ug/mL# 16) hexachloroethane 9.47 117 205915 33.25 ug/mL 21) nitrobenzene 9.74 77 739257 48.85 ug/mL 29) naphthalene 11.23 128 38428 1.04 ug/mL 31) hexachlorobutadiene 11.71 225 262227 56.17 ug/mL 36) 2,4,6-trichlorophenol 13.61 196 411026 79.99 ug/mL 37) 2,4,5-trichlorophenol 13.70 196 501241 75.01 ug/mL 43) -a-rS- -di-ni trotoluene 15.41 3r&5- 99721 14.48 ug/mLft 49) 2,4-dinitrotoluene 16.13 165 559235 58.76 ug/mL 5-64- N-fvi-E^-esedipheRyi^mine 1-7 -.-2-5 —3t^* 1-4-05 6 ^i-_0:3-.ug/mL— 60) hexachlorobenzene 16.54 284 524006 106.61 ug/mL# 61) pentachlorophenol 19.09 266 360911 106.56 ug/mL 62) phenanthrene 19.40 176 51675 1.75 ug/mL 63) anthracene 19.4 0 176 51675 1.75 ug/mL 65) fluoranthene 22.83 202 43260 1.50 ug/mL 68) pyrene 23.42 202 44095 1.18 ug/mL# (#) = cjualifier out of range (m) « mamual integration MAR03009.D 8270.M Fri Mar 04 10:40:22 1994 Page Data File C:\HPCHEM\1\DATA\MAR03\MAR03009.D Acq Time 3 Mar 94 4:23 pm Operator: jp/mw Sanple 94-0092 SOIL MS, 3.0 g/l mL Inst : Semiv Misc Multiplr: 1.00 Quamt Time Mar 4 10:36 1994 Method : C:\HPCHEMV1\METHODS\8270.M Title : Method 8270 Last Update : Fri Mar 04 09:52:25 1994 Response via Multiple Level Calibration Abundance TIC: MAR03009.D 3000000 2800000 SS^fTB-T 4S 38S 2600000 lOT 2400000 1(;T 2200000 II 2000000 2 IT iiM 1800000 2DSi^j 1600000 1 7M 1 1400000 -^ 1 1200000 1000000 800000 600000 400000 -I 2:iT 200000 JLAL OIUIULL' iJjUj I" I • T 1 r • I '"T 1 I T I •• -T I I 1 I 1 ^ r rrime--> 5 . 00 10^00 isioo 20.00 25.00 30.00 35.00 MAR03009.D 8270.M Fri Mar 04 10:40:31 1994 Page Data File C:\HPCHEM\1\DATA\MAR03\MAR03010.D Acq Time 3 Mar 94 6:07 pm Operator: jp/mw Sanple 94-0092 MSD SOIL, 3.0 g/l mL Inst : Semivc Misc Multiplr: 1.00 Quant Time Mar 4 10:41 1994 Method : C:\HPCHEM\1\METHODS\8270.M Title : Method 8270 Last Update : Fri Mar 04 09:52:25 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev(^ 1) i,4-dichlorobenzene-d4 8.42 152 389112 40.00 ug/mL 0. 19) naphthalene-dB 11.20 136 1507463 40.00 ug/mL 0. 34) acenaphthene-dlO 15,41 164 738448 40.00 ug/mL 0. 5 3) phenanthrene-dl0 19,36 188 1044544 40.00 ug/mL 0. 67) chrysene-dl2 27.09 240 1012464 40.00 ug/mL 0. 75) perylene-dl2 31.47 264 1081464 40.00 ug/mL 0. System Monitoring Compounds %Recov€ 4) 2-fluorophenol (surr) 6.08 112 1415148 100.80 ug/mL 50. 5) phenol-dS (surr) 7.91 99 1950291 114.47 ug/mL 57. 20) nitrobenzene-dS (surr) 9.69 82 918217 61.23 ug/mL 61. 38) 2-fluorobiphenyl (surr) 13.83 172 1565260 72.29 ug/mL 72. 58) 2,4,6-tribromophenol (surr 17.55 330 596004 297.68 ug/mL 148. 69) terphenyl-dl4 (surr) 24.16 244 1868434 77.81 ug/mL 77. Target Compounds - Ova] 2) pyridine 3.92 79 581895 36.78 ug/mL -iO-)—1,3 dichlorobengene n AT 14G A A H / T 11) 1,4-dichlorobenzene 8.46 146 641984 45.52 ug/mL 14) o-cresol 9.13 108 731502 52.42 ug/mL 16) p-cresol 9.49 108 1424441 96.43 ug/mL 17) N nitroBodi n pr-epylamine •9.-6-9-- 70 - -129681 10.48 ug/mL-# 16) hexachloroethane 9.47 117 166404 31.97 ug/mL ; 21) nitrobenzene 9.74 77 715208 4 9.52 ug/mL 29) naphthalene 11.23 128 36552 1.04 ug/mL 31) hexachlorobutadiene 11.71 225 248391 55.76 ug/mL 36) 2,4,6-trichlorophenol 13.62 196 391635 79.69 ug/mL 37) 2,4,5-trichlorophenol 13.70 196 477012 74.63 ug/mL -49-) 2,€ dinitrotoluene 15-.-41 ^65 - 97616 14.8 2 ug/mL# ... 49) 2,4-dinitrotoluene 16.13 165 511019 56.16 ug/mL 56) N-nitrosodiphenylamine 17.25 169 13754 1.03 ug/mL 60) hexachlorobenzene 18.54 264 498819 103.63 ug/mL# 61) pentachlorophenol 19.09 266 347401 104.75 ug/mL 62) phenanthrene 19.40 176 51092 1.77 ug/mL 63) anthracene 19.40 176 51092 1.76 ug/mL 65) fluoranthene 22.83 202 43786 1.55 ug/mL 68) pyrene 23.42 202 43253 1.19 ug/mL# (#) = cjualifier out of range (m) « manual integration MAR03010.D 8270.M Fri Mar 04 10:41:44 1994 Page Data File : C:\HP(3EM\l\DATA\MAR03\MAR03010.D Acq Time 3 Mar 94 6:07 pm Operator: jp/mw Sanple : 94-0092 MSD SOIL, 3.0 g/1 mL Inst : Semiv Misc Multiplr: i.OO Quant Time: Mar 4 10:41 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Fri Mar 04 09:52:25 1994 Response via Multiple Level Calibration Abiindamce TIC: MAR03010.D 2800000 38S 5S 2600000 4S 14T 10 2400000 fj 2200000 1 2000000 II SSS ll*T 69S 1800000 T43T lii^ 531 1600000 2DS 341 61M 7M 1400000 -I 60T 3< C 1200000 - 19M 1 1000000 •;T 800000 600000 400000 21t 200000 SIT LjJdiJL' I"uj^JlfJAJL , . . . I I . . i I I I I I I I I rrime--> 5.00 10.00 15.00 20.00 25.00 30.00 35.00 MAR03010.D 8270.M Fri Mar 04 10:41:53 1994 Page Data File : C:\HPCHEM\1\DATA\MAR03\MAR03011.D Acq Time 3 Mar 94 5:16 pm Operator: jp/mv Sanple : 94-0091 SOIL, 3.0 g/1 mL, 1/10 dil'n Inst : Semiv Misc : Multiplr: 1.00 Quant Time: Mar 4 10:44 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last l^date Fri Mar 04 09:52:25 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev( 1) l,4-dichlorobenzene-d4 8.42 152 373394 40,00 ug/mL 0 19) naphthalene-dB 11.20 136 1448125 40.00 ug/mL 0 3 4) acenaphthene-dl0 15,40 164 701427 40,00 ug/mL 0 5 3) phenanthrene-dl0 19.35 188 992805 40.00 ug/mL 0 67) chrysene-dl2 27.07 240 999326 40.00 ug/mL 0 75) perylene-dl2 31.46 264 1153090 40.00 ug/mL 0 System Monitoring Compounds VRecov 4) 2-fluorophenol (surr) 6.05 112 152995 11.36 ug/mL 5 5) phenol-dS (surr) 7.86 99 222148 13.59 ug/mL 6 20) nitrobenzene-dS (surr) 9.66 82 99971 6.94 ug/mL 6 38) 2-fluorobiphenyl (surr) 13.79 172 197469 9.60 ug/mL 9 56) 2,4,6-tribromophenol (surr 17.50 330 84146 44.22 ug/mL 22 69) terphenyl-dl4 (surr) 24,10 244 259506 10.95 ug/mL 10 Target Compounds Qva -1-7-)—W—nit-roaodi—«-propylamiT»e - -9.-66 76 14423 i.21 ug/-mt# — 24) 2,4-dimethylphenol 10.58 122 43918 4.80 ug/mL 27) benzoic acid 10, 65 122 16247 2.10 ug/mL# 43) 2,6-dinitrotoluene— - -- 15. 40 165 -91105 14--5-7-t»gy-fRt# 62) phenanthrene 19 40 178 70864 2.56 ug/mL -&34- anthracene 19.40 1^8 70BC4 3.57 ug/mL 65) fluoranthene 22.79 202 86725 3.22 ug/mL 68) pyrene 23.40 202 98545 2.76 ug/mL 75r)—benze—(a)—anthr-aoono 37.12 22B 3848P 1.33 ug/mL 73) chrysene 27.12 228 38469 1.52 ug/mL# 76) benzo(k)fluoranthene 30.29 252 30796 1.26 ug/mL 79) benzo(a)pyrene 31.21 252 37239 1.33 ug/mL (#) = cjualifier out of range (m) « manual integration MAR03011.D 8270.M Fri Mar 04 10:45:18 1994 Page Data File C:\HPCHEM\l\nATA\MAR03\MAR03011.D Acq Time 3 Mar 94 5:16 pm Operator: jp/mw Sanple 94-0091 SOIL, 3.0 g/1 mL, 1/10 dil'n Inst : Semiv Misc Multiplr: 1.00 Quant Time Mar* 4 10:44 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Fri Mau: 04 09:52:25 1994 Response via Multiple Level Calibration Abundance TIC: MAR03011.D 1800000 1700000 43T 1600000 191 1500000 II 1400000 341 1300000 531 1200000 ^ 671 I 1100000 -! 751 i , 1000000 1 aaPF 900000 20S 800000 SS 17M 700000 ^ 600000 4S 69S 500000 J 38S 6:tT 585 68N 400000 7 .T 300000 200000 100000 -1 L J. li ., . iiJJLJJ^ Time- 0 5.00 10.00 15.00 20.00 25.00 30.00 35.00 MAR03011.D 8270.M Fri Mar 04 10:45:26 1994 Pagt Data File C:\HPCHEM\1\DATA\MAR03\MAR03012.D Acq Time 3 Mar 94 6:58 pm Operator: jp/mw Sanple 94-0091 SOIL, 3.0 g/1 mL Inst : Semivolat Misc Multiplr: 1.00 Quant Time Mar 4 15:00 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Fri Mar 04 09:52:25 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-dichlorcbenzene-d4 8 .42 152 485221 40.00 ug/mL 0.02 19) naphthalene-dB 11 .20 136 1897949 40.00 ug/mL 0.00 34) acenaphthene-dlO 15 .42 164 939377 40.00 ug/mL 0.00 S 3) phenamthrene-dl0 19 .38 188 1295959 .40.00 ug/mL 0.04 67) ehrysene-dl2 27 .13 240 1215129 40.00 ug/mL 0.08 75) perylene-dl2 31 .53 264 1276016 40.00 ug/mL 0.10 System Monitoring Compounds tRecover^ 4) 2-fluorophenol (surr) 6 .08 112 1383400 79.02 ug/mL 39.51^ 5) phenol-dS (surr) 7 .90 99 1958755 92.19 ug/mL 46,10) 20) nitrobenzene-ds (surr) 9 .69 82 948949 50.26 ug/mL 50.26) 38) 2-fluorobiphenyl (surr) 13 .82 172 1683968 61.14 ug/mL 61.14) 58) 2,4,6-tribromophenol (surr 17 .57 330 676632 272.39 ug/mL 136.20< 69) terphenyl-dl4 (surr) 24 .19 244 2096611 72.75 ug/mL 72.75) Target Compounds Qvalue 3^—W- nit^KJSodiHBethyJramifte- 3..-89 - --42- — 3-6941- -—4-v25-ug/raL#- 1 16) p-cresol 9..43 108 130730 7.10 ug/mL 97 -N-nitr-o&odi—n-propylam^ine 9..69 -70 132555 6.59 ug/mL# 76 24) 2,4-dimethylphenol 10..6 1 122 434918 • 36.29 ug/mL 96 29) naphthalene 11..2 3 128 97678 2.20 ug/mL 99 33) 2-methylnaphthalene 12..8 2 142 53319 1.95 ug/mL 99 41) dimethylphthalate 14.,8 7 163 104062 3.16 ug/mL# 76 42) acenaphthylene 14.,9 9 152 106754 2.57 ug/mL 99 1 c 1 -1 •1- 1 /I -in-l T 1 R 0 iia /mT tt -lyl -43-)—3,6 dinitrotoluene— X J . TXt J r.^) 45) acenaphthene 15..4 8 154 47672 1.92 ug/mL 98 48) dibenzofuran 15..8 9 166 49466 1.34 ug/mL 98 51) fluorene 16..7 9 166 65349 3.29 ug/mL# 95 56-)—N-ni t-rog odiphenylamine 17-,.-2-8 - •1-6 9- 1-844^- l-rl3-ug/mL#- 4-3 62) phenanthrene 19..4 3 176 651456 16.20 ug/mL 99 63) anthracene 19,.5 4 178 176999 4.92 ug/mLm 99 64) di-n-butylphthalate 21..5 0 149 60896 1.09 ug/mL# 96 65) fluoranthene 22..8 4 202 629116 23.60 ug/mL 99 66) pyrene 23..4 6 202 935816 21.54 ug/mL 100 71) benzo (a) .anthracene 27,.0 7 226 360387 10.26 ug/mLm 94 73) chrysene 27,.2 0 228 370673 12.02 ug/mL 98 74) bis (2-ethylhexyl) phthala 27.,8 2 149 50464 1.13 ug/mL 98 77) benzo(b)fluoranthene 30,.3 7 252 320165 6.96 ug/mLm 97 76) benzo(k)fluoranthene 30..4 4 252 276393 10.19 ug/mL 98 79) benzo(a)pyrene 31.,3 2 252 335439 10.85 ug/mL 92 62) indenod, 2, 3-c,d) pyrene 35.,1 9 276 114864 4.01 ug/mL# 89 (#) = cjualifier out of range (m) « manual integration MAR03012.D 8270.M Fri Mar 04 15:03:58 1994 Data File C:\HPCHEM\1\DATA\MAR03\MAR03012.D Acq Time 3 Mar 94 6:58 pm Operator: jp/mw Sanple 94-0091 SOIL, 3.0 g/1 mL Inst : Semivi Misc Multiplr: 1.00 Quant Time Mar 4 10:50 1994 Method : C:\HPCHEM\1\METHODS\8270.M Title : Method 8270 Last Update : Fri Mar 04 09:52:25 1994 Response via Multiple Level Calibration lAbundance TIC: MAR03012.D 2800000 rrime--> 5.00 10.00 isioo 20.00 25.00 30.00 MAR03012.D 8270.M Fri Mar 04 10:51:37 1994 Page Data File C:\HPCHEM\1\DATA\MAR03\MAR03013.D Acq Time 3 Mar 94 7:50 pm Operator: jp/mw Sanple TCLP ref std, 50.0 ppm. Inst : Semiv Misc Multiplr: 1.00 Quant Time Mar 4 10:52 1994 Method : C:\HPCHEM\1\METHODS\8270.M Title : Method 8270 Last Upciate : Fri Mar 04 09:52:25 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev(! 1) i,4-dichlorobenzene-d4 8.42 152 392391 4 0.00 ug/mL 0 19) naphthalene-dB 11.20 136 1530091 40,00 ug/mL 0 34) acenaphthene-dlO 15.40 164 777977 40,00 ug/mL 0 53) phenanthrene-dlO 19.35 188 1143251 40.00 ug/mL 0 67) chrysene-dl2 27.07 240 1076733 40.00 ug/mL 0 75) perylene-dl2 31.45 264 1149879 4 0.00 ug/mL 0 System Monitoring Compounds %Recov 4) 2-fluorophenol (surr) 6.08 112 681212 48.1 2 ug/mL 24 5) phenol-dS (surr) 7.88 99 800167 46.57 ug/mL 23 20) nitrobenzene-dS (surr) 9.69 82 726649 47.74 ug/mL 47 38) 2-fluorobiphenyl (surr) 13.81 172 1150187 50.42 ug/mL 50 58) 2,4,6-tribromophenol (surr 17.51 330 220815 100.7 7 ug/mL 50 69) terphenyl-dl4 (surr) 24.12 244 1205855 47.22 ug/mL 47 Target Compounds Qva 2) pyridine 3.88 79 743260 46.58 ug/mL -37^4—11 3-c3icb-Iorobenaene 8 • 45 ^-4-6- 700013 48. 42 ug/mL' 11) 1,4-dichlorobenzene 6.45 146 700913 49.28 ug/mL 14) o-cresol 9.13 108 609745 43.33 ug/mL 16) p-cresol 9.49 106 1141606 76.64 ug/mL i-T-j—N- n i t i'ci3oeii-'T>-prc?pylamine - --9--6« 70 102451 8.21 ug/mL# 16) hexachloroethane 9.47 117 190625 32.46 ug/mL 21) nitrobenzene 9.73 77 670604 45.75 ug/mL 31) hexachlorobutadiene 11.70 225 238566 52.76 ug/mL 36) 2,4,6-trichlorophenol 13.61 196 293762 56.74 ug/mL 37) 2,4,5-trichlorophenol 13.69 196 346509 51.46 ug/mL 4 34—3-r)- g-dinitrotolueno 15 . 40 h&5 101303 14. GO ug/mL# 49) 2,4-dinitrotoluene 16.12 1655 344358 35.92 ug/mL 60) hexachlorobenzene 18.53 284 379552 72.04 ug/mL« 61) pentachlorophenol 19.07 266 259771 71.56 ug/mL (#) = cjualifier out of range (m) « manual integration MAR03013.D 8270.M Fri Mar 04 10:54:04 1994 Pag« Data File : C:\HPCHEM\1\DATA\MAR03\MAR03013.D Acq Time 3 Mar 94 7:50 pm Operator: jp/mw Sanple : TCLP ref std, 50.0 ppm. Inst : Semivc Misc : Multiplr: 1.00 Quant Time: Mar 4 10:52 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Fri Mau: 04 09:52:25 1994 Response via Multiple Level Calibration Abundance TIC; MAR03013.D 2600000 14T 2400000 "fsT 38S 2200000 2000000 KT IIM 1800000 - II 531 2tLTL9I 5S 1600000 -1 4S : ic IIT 3: 1400000 2 3S 69S .'T 36C 1200000 7M •w 671 1000000 i9M I 751 58S 800000 j 600000 I 400000-1 i I 200000 f .^-j LiLi J• t I 1 frime--> 5.00 10.00 15.00 20.00 25.00 30.00 35.00 MAR03013.D 8270.M Fri Mar 04 10:54:12 1994 Page Data Pile C:\HPCHEM\l\nATA\MAR03\MAR03014.D Acq Time 3 Mar 94 8:43 pm Operator: jp/mw Sanple Blank Inst : Semiv Misc Multiplr: 1.00 Quant Time Mar 4 10:54 1994 Method C:\HPCHEM\1\METHODS\8270.M Title Method 8270 Last Update Fri Mar 04 09:52:25 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev(l 1) l,4-dichloroben2ene-d4 8.41 152 391829 40.00 ug/mL 0 19) naphthalene-dB 11.20 136 1465846 40.00 ug/mL 0 34) acenaphthene-dlO 15.41 164 736667 40,00 ug/mL 0 53) phenanthrene-dlO 19.34 188 1036457 40.00 ug/mL 0 67) chrysene-dl2 27.07 240 105743i 40,00 ug/mL 0 75) perylene-dl2 31,45 264 1050691 40.00 ug/mL 0 System Monitoring Compounds %Recov( 4) 2-fluorophenol (surr) 6.05 112 695984 49.23 ug/mL 24 5) phenol-dS (surr) 7.87 99 805142 46.93 ug/mL -23 20) nitrobenzene-dS (surr) 9,68 82 722912 49.58 ug/mL 4* 38) 2-fluorobiphenyl (surr) 13.81 172 1157603 53.60 ug/mL .53. 58) 2,4,6-tribromophenol (surr 17.51 330 220963 111.2 2 ug/mL 55 69) terphenyl-dl4 (surr) 24.13 244 1214633 48.43 ug/mL 4& Target Compounds Qva 17) N nitroaodi n propylamine 9"r-fr6 7<} are3206 0.20 ug/mL# 4-3-)—^,6-dinitrotoluene 15.41 165 94576 -14.40 (#) = cjualifier out of range (m) « manual integration MAR03014.D 8270.M Fri Mar 04 10:56:14 1994 Page Data File C:\HPCHEM\1\DATA\MAR03\MAR03014.D Acq Time 3 Mar 94 8:43 pm Operator: jp/mw Sample Blank Inst : Semivo Misc Multiplr: 1,00 Quamt Time Mar 4 10:54 1994 Method : C:\HPCHEM\1\METHODS\8270.M Title : Method 8270 Last Update : Fri Mar 04 09:52:25 1994 Response via Multiple Level Calibration Abundance 2000000 1800000 1600000 1400000 1200000 i 1000000 800000 600000 400000 200000 rrime--> 5.00 10.00 15.00 20.00 25.00 30.00 35.00 MAR03014.D 8270.M Fri Mar 04 10:56:21 1994 Page Data File : C:\HPCHEM\l\DATA\MAR02\MAR02014.D Acq Time : 2 Mar 94 10:36 pm Operator: jp Sample : 94-0091 SLP Inst : Volatil Misc : Multiplr: 1.00 Quant.Time: Mar 3 10:15 1994 Method C:\HPCHEM\1\METHODS\8240.M Title target compounds Last Update Thu Mar 03 09:53:12 1994 Response via Multiple Level Calibration Abundance TIC: MAR02014.D 240000 -I 220000 200000 42S 29S 180000 351 160000 221 140000 120000 100000 II 80000 60000 19S 3 0 4, C 40000 36 1^?^ 9T 20000 23M 28 39T ^Z^y^-A.J:iJ\ JU w UJ — 1 — I — I 1 1 — l l l l l — 1 1 1 I I r - Time--> 5.00 10.00 15.00 20.00 25.00 MAR02014.D 8240.M Thu Mar 03 10:16:22 1994 Page Data File C:\HPCHEM\1\DATA\MAR02\MAR02015,D Acq Time 2 Mar 94 11:27 pm Operator: jp Sanple 94-0092 SLP Inst : Volatil Misc Multiplr: 1,00 Quant .Time Mar 3 10:16 1994 Method : C:\HPCHEM\1\METHODS\8240.M Title : target compounds Last Update : Thu Mar 03 09:53:12 1994 Response via Multiple Level Calibration Internal Standards R,T. Qlon Response Cone Units Dev(Mi 1) bromochloromethane 12.41 128 64860 50.0 0 ug/L 0,C 22) 1,4 -di fluorobenz ene 15.38 114 403669 50.0 0 ug/L O.C 35) chlorobenzene-dS 24.68 117 319638 50.0 0 ug/L O.C System Monitoring Compounds %Reeovei 19) 1,2-dichloroethane-d4 (sur 14.02 65 133807 58.66 ug/L 117.; 29) toluene-d8 (surr.) 19.91 98 386683 51.00 ug/L 101,5 42) bromofluorcbenzene 28.86 95 286894 50.56 ug/L 101,] Target Compounds Qvalv 6) acetone 7.17 43 6017 6.44 ug/L # 9) carbon disulfide 7.60 76 1119 0.18 ug/L # 14) 2-butanone (MEK) 11.78 43 7664 5.03 ug/L # 26) 4-methyl-2-pentanone (MIBK 19.56 43 11758 3.56 ug/L # 30) toluene 20.12 92 17866 3.20 ug/L # 33) tetrachloroethene 21.95 164 5203 1.86 ug/L 37) ethylbenzene 25.22 91 6797 0.58 ug/L # 38) m&p-xylenes 25.63 106 12970 3.22 ug/L 39) o-xylene 27.01 106 5033 1.29 ug/L # (#) = cjualifier out of range (m) = manual integration MAR02015.D 8240.M Thu Mar 03 10:19:10 1994 Page UUOXIUJ.b.B^^«.^^x iy,^^\jM. >. Data File C:\HPCHEM\1\DATA\MAR02\MAR02015.D Acq Time 2 Mar 94 11:27 pm Operator DP Sample 94-0092 SLP Inst Volatil Misc Multiplr 1.00 Quant .Time Mar 3 10:16 1994 Method : C:\HPCHEM\1\METHODS\8240.M Title : target compounds Last Update : Thu Mar 03 09:53:12 1994 Response via : Multiple Level Calibration Abundance TIC: MAR02015 .D 260000 240000 220000 200000- 42S 29S 180000 351 1 160000 221 140000 120000 100000 11 80000 60000 IS) S 30 ^,C 40000 \ 9T 7C 20000 38T { 33T . A 14T 28 I 3 9T V V_i^ .A . I \.I\ ll 0 - , , , 1 1 . , . 1 , , 1 , 1 , , \ 1 , , , 1 . 1 1 ' Time--> 5.00 10.00 15.00 20.00 25.00 MAR02015.D 8240.M Thu Mar 03 10:19:14 1994 Page Data File C:\HPCHEM\1\DATA\MAR02\MAR02016.D Acq Time 3 Mar 94 12:21 am Operator: jp Sample 94-0092 MS SLP, 50.0 ppb Inst : Volatil Misc Multiplr: 1.00 Quant .Time Mar 3 10:19 1994 Method : C:\HPCHEM\i\METHODS\8240,M Title : target compounds Last Update : Thu Mar 03 09:53:12 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev(Mi 1) bromochloromethane 12.41 128 65945 50.00 ug/L O.C 22) 1,4 -di fluorobenzene 15.40 114 394933 50.00 ug/L O.C 35) chlorobenzene-dS 24.69 117 313831 50.00 ug/L O.C System Monitoring Compounds %Recovei 19) 1,2-dichloroethane-d4 (sur 14.02 65 134650 58.06 ug/L 116.1 29) toluene-de (surr.) 19.92 98 381564 51.41 ug/L 102. f 42) bromofluorcbenzene 28.88 95 280443 50.36 ug/L IOO.'; Target Compounds Qvalv 7) 1,1-dichloroethene 7.10 96 105150 47.45 ug/L 8) acetone 7.17 43 18098 19.05 ug/L 9) carbon disulfide 7.60 76 2451 0.40 ug/L 14) 2-butanone (MEK) 11.79 43 15464 9.96 ug/L 21) benzene 14.24 78 381690 52.23 ug/L 23) trichloroethene 16.17 130 146137 45.65 ug/L 28) 4-methyl-2-pentanone (MIBK 19.56 43 12799 3.96 ug/L 3 0) toluene 20.14 92 277384 50.79 ug/L 33) tetrachloroethene 21.95 164 5544 2.04 ug/L 36) chlorobenzene 24.79 112 309369 47.40 ug/L 37) ethylbenzene 25.23 91 8084 0.70 ug/L 38) mficp-xylenes 25.65 106 13562 3.43 ug/L 39) o-xylene 27.04 106 4635 1.26 ug/L (#) = qualifier out of range (m) = mamual integration MAR02016.D 8240.M Thu Mar 03 10:20:50 1994 Page yuiciiAi Data File : C:\HPCHEM\l\DATA\MAR02\MAR02016.D Acq Time : 3 Mar 94 12:21 am Operator: jp Sample : 94-0092 MS SLP, 50.0 ppb Inst : Volatil Misc : Multiplr: 1.00 Quant .Time: Mar 3 10:19 1994 Method C:\HPCHEM\1\METHODS\8240.M Title target compounds Last Update Thu Mar 03 09:53:12 1994 Response via Multiple Level Calibration Abundance TIC: MAR02016.D 260000 240000 220000 30M,C 36M,P 200000 42S 29S 180000 3EI 160000 21H2I 140000 23M 120000 100000 II 80000 8T 60000 195 7M, C 40000 9T B7C 20000 38T 288ff l •^•^'^ 3 9T 1-AJL^: \J U J V- ft li -I 1 r - _/L—. rime--> 5.00 10.00 15.00 20.00 25.00 MAR02016.D 8240.M Thu Mar 03 10:20:55 1994 Page Data File C:\HPCHEM\1\DATA\MAR02\MAR02017.D Acq Time 3 Mar 94 1:15 am Operator: jp Sample 94-0092 MSD SLP, 50.0 ppb Inst : Volatil Misc Multiplr: 1.00 Quant Time Mar 3 10:21 1994 Method : C:\HPCHEM\1\METHODS\8240.M Title : target compounds Last Update : Thu Mar 03 09:53:12 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev(Mi 1) bromochloromethane 12.41 128 65737 50.00 ug/L O.C 22) 1,4-difluorobenzene 15.40 114 402195 50.00 ug/L O.C 35) chlorobenzene-dS 24.70 117 317366 50.00 ug/L O.C System Monitoring Compounds %Recover 19) 1,2-diehloroethane-d4 (sur 14.02 65 133388 57.70 ug/L 115.4 29) toluene-d6 (surr.) 19.92 98 383391 50.72 ug/L 101.4 42) bromofluorcbenzene 28.89 95 280131 49.74 ug/L 99.4 Target Compounds Qvalv 7) 1,1-dichloroethene 7.10 96 104016 47.09 ug/L c 8) acetone 7.19 43 17204 16.16 ug/L # £ 9) carbon disulfide 7.63 76 3797 0.62 ug/L # ; 14) 2-butanone (MEK) 11.76 43 14946 9.65 ug/L # i 21) benzene 14.24 78 385129 52.87 ug/L c 23) trichloroethene 16.17 130 144982 44.66 ug/L c 28) 4-methyl-2-pentanone (MIBK 19.56 43 11973 3.64 ug/L # < 30) toluene 20.15 92 277056 49.81 ug/L c 33) tetrachloroethene 21.94 164 2309 0.84 ug/L # 36) chlorobenzene 24.60 112 310074 46.98 ug/L c 37) ethylbenzene 25.23 91 7464 0.64 ug/L # 1 38) mScp-xylenes 25.66 106 13289 3.32 ug/L c 39) o-xylene 27.04 106 4602 1.19 ug/L # f (#) = cjualifier out of range (m) = manual integration MAR02017.D 6240.M Thu Mar 03 10:22:12 1994 Page Data File : C:\HPCHEM\l\DATA\MAR02\MAR02017.D Acq Time : 3 Mar 94 1:15 am Operator: jp Sample : 94-0092 MSD SLP, 50.0 ppb Inst : Volatil Misc : Multiplr: 1.00 Quant .Time: Mar 3 10:21 1994 Method C:\HPCHEM\i\METHODS\8240.M Title target compounds Last Update Thu Mar 03 09:53:12 1994 Response via Multiple Level Calibration Abundance TIC: MAR02017.D 260000 240000 220000 30M,C 36M,P 200000 42S 29S 180000 31 I 160000 21I42I 140000 23M 120000 100000 II 80000 60000 - 8T ISS 7M,C 40000- bT :)7C 20000 38T 33T 261 LAJL ill VJ u _JL. JUl L • "—1—'—'—'—'—I—'—'—'—'—I—'—'—'—'—I—'—'— ' — ' — I — ' — I — I — ^ rime--> 5.00 10.00 15.00 20.00 25.00 MAR02017.D 8240.M Thu Mar 03 10:22:18 1994 Page •^f-'— — J — Method C:\HPCHEM\1\METHODS\8240.M Title target compounds Last Update Thu Mar 03 09:53:12 1994 Response via Initial Calibration Non-Spiked Sample: MAR02015.D spiKe Sample Duplicate Sample File ID : MAR02016.D 1 MAR02017.D Sample : 94-0092 MS SLP, 50.0 ppb 1 94-0092 MSD SLP, 50.0 ppi Acq Time: 3 Mar 94 12:21 am 1 3 Mar 94 1:15 am Compound Sample Spike Spike Dup Spike Dup RPD QC Limits Cone Added Res Res %Rec %Ree RPD % Rec 1,1-dichloroethene 0.0 50 47 47 95 94 1 14 61-145 benzene 0.0 50 52 53 104 106 1 11 76-127 trichloroethene 0.0 50 46 45 92 89 3 14 71-120 toluene 3.2 50 51 50 95 93 2 13 76-125 chlorobenzene 0.0 SO 47 47 95 94 1 13 75-130 6240.M Thu Mar 03 10:24:13 1994 Data File C:\HPCHEM\1\DATA\MAR02\MAR02018.D Acq Time 3 Mar 94 2:09 am Operator: jp Sample Ref std purgeable B, 50.0 ppb Inst : Volatil Misc Multiplr: 1.00 Quant .Time Mar 3 10:22 1994 Method C:\HPCHEM\1\METHODS\8240.M Title target compoimds Last Update Thu Mar 03 09:53:12 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev(Mi 1) bromoehloromethame 12.43 128 65318 50.00 ug/L O.C 22) 1,4-difluorobenzene 15.41 114 393643 50.00 ug/L O.C 35) chlorobenzene-ds 24.71 117 308584 50.00 ug/L O.C System Monitoring Compounds %Recovei 19) l,2-dichloroethane-d4 (sur 14.03 65 132818 57.82 ug/L 115.6 29) toluene-d8 (surr.) 19.94 98 374575 50.63 ug/L 101.: 42) bromofluorcbenzene 28.89 95 277491 50.67 ug/L 101.Z Target Compounds Qvalv 8) acetone 7.16 43 5805 6.17 ug/L # 11) trans-1,2-dichloroethene 9.OB 96 109268 54.48 ug/L 14) 2-butanone (MEK) 11.79 43 16282 10.59 ug/L # 17) 1,1,1-trichloroethane 13.20 97 142579 44.42 ug/L 18T carbon ueLiaL-niuiirdet 13.21 irir9 1SGG5 43.10 20) 1,2-dichloroethane 14.24 62 161587 54.20 ug/L 21) benzene 14.24 76 379009 52.36 ug/L 23) trichloroethene 16.18 130 9401 2.96 ug/L 25) bromodichloromethane 17.64 83 9576 12.43 ug/L 26) 2-chloroethylvinyl ether 16.56 63 2040 1.07 ug/L 27) cis-1,3-dichloropropene 19.04 75 106505 39.12 ug/L 28) 4-methyl-2-pentanone (MIBK 19.91 43 513 0.16 ug/L 30) toluene 20.15 92 256659 47.15 ug/L 31) trans-1,3-dichloropropene 20.83 75 111053 44.41 ug/L 37) ethylbenzene 25.24 91 539820 47.53 ug/L 38-) m&p xylcineo 25 . 24 14377G 3G.DD ug/L # 41) bromoform 27.65 173 106245 42.71 ug/L 43) 1,1,2,2-tetraehloroethane 29.42 83 197296 46.10 ug/L (#) = cjualifier out of range (m) = manual integration MAR02018.D 6240.M Thu Mar 03 10:23:32 1994 Page Data File C:\HPCHEM\1\DATA\MAR02\MAR0201B.D Acq Time 3 Mar 94 2:09 am Operator: jp Sample Ref std purgeable B, 50.0 ppb Inst : Volati] Misc Multiplr: 1,00 Quant Time Mar 3 10:22 1994 Method C:\HPCHEM\i\METHODS\8240.M Title target conpounds Last Update Thu Mar 03 09:53:12 1994 Response via Multiple Level Calibration Abundance TIC: MAR02018.D 280000 260000 240000 37C 220000 30M,C 21M 200000 38T 42S 29S 180000 20T 19S 3s: 160000 IBT 140000 lJ7T 221 2(;r ':3 120000 IIT 100000 8000.0 -\ 27T 14T 41P 60000 IT 6T 40000 20000 23M uU uu u T r 1 1 1 1 1 1 1 I 1 1 1 j 1 1 1 I 1 1 p - Time--> 5.00 10.00 15.00 20.00 2S.00 MAR02018.D 8240.M Thu Mar 03 10:23:37 1994 Page secjuence rtame:: \Ji-r^.nr Line Type Vial DataFile Method Sample Name 1 Sample 1 MAR03001 8240 TCL STD, 50.0, 150 (vinyl ace 2 Sample 2 MAR03002 8240 Blank 3 Sample 3 MAR03003 8240 TCLP extraction fluid #1 4 Sample 4 MAR03004 8240 94-0090 TCLP 5 Sample 5 MAR03005 8240 94-0091 TCLP 6 Sample 6 MAR03006 8240 94-0092 TCLP 7 Sample 7 MAR03007 8240 94-0090 soil. 1.0 g/5 mL 8 Sample 8 MAR03008 8240 94-0092 soil. 1.0 g/5 mL 9 Sample 9 MAR03009 8240 94-0091 soil. 3.0 g/3 mL, 50 10 Sample 10 MAR03010 8240 94-0090 MS soil, 1.0 g/5 mL, 11 Sample 11 MAR03011 8240 94-0090 MSD soil, 1.0 g/5 mL, 12 Sample 12 MAR03012 8240 DI H20 for SLP & ELT 13 Sample 13 MAR03013 8240 94-0091 soil, 1.0 g/5 mL 14 Last Modified: Wed Apr 06 11:18:03 1994 Page; Data Pile C:\HPCHEM\1\DATA\MAR03\BFB-1,D Acq Time 3 Mar 94 8:58 am Operator: jp Sample bfb, 50.0 ppm, 1 ul inj. Inst : Volatiles Misc EM = 200 above autotune Multiplr: 1,00 Method C:\HPCHEM\1\METHODS\8240,M Title target compoimds Scan Number 306 Target Rel. to Lower Upper Rel. Raw Result Mass Mass Limit% Limit% Abn% Abn Pass/Fail 1 ^° 95 15 40 21.7 8111 PASS 1 75 95 30 60 49.2 18400 PASS 95 95 100 100 100.0 37392 PASS 96 95 5 9 7.2 2688 PASS 173 174 0 2 0.0 0 PASS . 174 95 50 100 50.6 18912 PASS 175 174 5 9 8.9 1681 PASS 176 174 95 101 99.8 18880 PASS 1 177 176 5 9 7.3 1387 PASS 1 BFB-l.D 8240.M Wed Apr 06 11:05:41 1994 Data File C:\HPCHEM\1\DATA\MAR03\MAR03001.D Acq Time 3 Mar 94 9:47 am Operator: jp Sample TGL std, 50.0, Vinyl acetate 150 ppb. Inst : Volatil Misc Multiplr: 1.00 Quant .Time Mar 3 10:57 1994 Method C:\HPCHEM\1\METHODS\8240.M Title target compounds Last Update Thu Mar 03 09:53:12 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev(Mi 1) bromochloromethane 12.46 128 69395 50 .0 0 ug/L 0.1 22) 1,4-difluorobenzene 15.43 114 394732 50 .O O ug/L 0.0 35) chlorobenzene-dS 24 .74 117 312398 50 .0 0 ug/L 0.0 System Monitoring Compounds %Recover 19) l,2-diehloroethane-d4 (sur 14.06 65 132832 54 .4 3 ug/L •L08.8 29) toluene-dB (surr.) 19.97 98 382272 51 .5 3 ug/L 103. 0 42) bromofluorcbenzene 28.92 95 281177 50 .7 2 ug/L :LOl.4 Target Compounds Qvalu 2) chloromethane 3.90 50 82759 46 .87 . ug/L # 9 3) vinyl chloride 4.13 62 109182 52 .5 3 ug/L # 9 4) bromomethane 4.86 94 29642 33 .4 8 ug/L m 5) chloroethane 5.16 64 71355 69 .1 7 ug/L m 6) trichlorofluoromethane 5.86 101 280937 65 .0 9 ug/L m 7) 1,l-dichloroethene 7.14 96 120370 51 .6 2 ug/L S 8) acetone 7.19 43 36244 36 .2 5 ug/L # 5 9) carbon disulfide 7.66 76 332865 51 43 ug/L 10 10) methylene chloride 8.37 84 124159 52 76 ug/L 9 11) trans-1,2-dichloroethene 9.13 96 110536 51 67 ug/L o 12) 1,1-dichloroethane 10.25 63 226764 SO 97 ug/L c 13) vinyl acetate 10.40 43 9437 106 46 ug/L # 14) 2-butanone (MEK) 11.81 43 68157 41 71 ug/L # c 15) cis-1,2-dichloroethene 11.82 96 144620 51 83 ug/L c 16) chloroform 12.72 83 180171 52 79 ug/L IC 17) 1,1,1-trichloroethane 13.23 97 192917 56 57 ug/L c 18) carbon tetrachloride 13.23 117 22251 57 62 ug/L # 20) 1,2-dichloroethane 14.28 62 169767 53 60 ug/L 21) benzene 14.28 76 406990 52 93 ug/L 23) trichloroethene 16.22 130 161178 50 59 ug/L 24) 1,2-dichloropropane 16.81 63 161752 52 09 ug/L 25) bromodichloromethane 17.67 83 36124 46 75 ug/L # 26) 2-chloroethylvinyl ether 18.65 63 103250 54 12 ug/L 27) cis-1,3-dichloropropene 19.06 75 135704 49 71 ug/L 28) 4-methyl-2-pentanone (MIBK 19.59 43 149938 46. 39 ug/L 30) toluene 20.18 92 297165 54. 44 ug/L 31) trans-1,3-dichloropropene 20.67 75 125708 50. 13 ug/L 32) 1,1,2-trichloroethane 21.43 97 134155 SO. 65 ug/L IC 33) tetrachloroethene 22.00 164 136062 SO. 17 ug/L 34) chlorodibromomethane 22.73 129 80471 45. 10 ug/L # 36) chlorobenzene 24.83 112 330351 50. 84 ug/L 37) ethylbenzene 25.27 91 586094 51. 15 ug/L 38) m&p-xylenes 25.70 106 399390 101. 51 ug/L 39) o-xylene 27.07 106 192934 SO. 50 ug/L ; (#) = cjualifier out of range (m) = manual integration MAR03001.D 6240.M Thu Mar 03 11:01:51 1994 Page Data File C:\HPCHEM\1\DATA\MAR03\MAR03001.D Acq Time 3 Mar 94 9:47 am Operator: jp Sanple TGL std, 50.0, Vinyl acetate 150 ppb, Inst : Volati] Misc Multiplr: 1.00 Quant .Time Mar 3 10:57 1994 Method : C:\HPCHEM\i\METHODS\8240.M Title : target compounds Last Update : Thu Mar 03 09:53:12 1994 Response via : Multiple Level Calibration Compound R.T. Qlon Response Cone Unit Qvali 40) styrene 27.12 104 338017 50.45 ug/L 41) bromoform 27.67 173 118090 46.89 ug/L 43) 1,1,2,2-tetraehloroethane 29.44 83 215175 49.66 ug/L (#) = qualifier out of range (m) = manual integration MAR03001.D 8240.M Thu Mar 03 11:01:52 1994 Page Data File C:\HPCHEM\1\DATA\MAR03\MAR03001.D Acq Time 3 Mar 94 9:47 am Operator: jp Sample TGL Std, 50.0, Vinyl acetate 150 ppb. Inst : Volatil Misc Multiplr: 1.00 Quant .Time Mar 3 10:57 1994 Method : C:\HPCHEM\1\METHODS\8240.M Title : target compounds Last Update : Thu Mar 03 09:53:12 1994 Response via : Multiple Level Calibration Abundance TIC: MAR03001.D IT^S 450000 IS,^ ' 38T 400000 14T 40T 350000 ll-fl^P 3 25T l i l t 1 r - 1 T—r——[— T 1 I 1 I I UI lJ l l u l l I l l l l Time--> 5.00 10.00 15.00 20.00 25.00 MAR03001.D 8240.M Thu Mar 03 11:01:59 1994 Page Data File C:\HPCHEM\1\DATA\MAR02\MAR02015.D Acq Time 2 Mar 94 11:27 pm Operator: jp Sample 94-0092 SLP Inst : Volatil Misc Multiplr: 1.00 Quant .Time Mar 3 10:16 1994 Method C:\HPCHEM\1\METHODS\8240.M Title target compounds Last Update Thu Mar 03 09:53:12 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev(Mi 1) bromochloromethane 12.41 128 64860 50.00 ug/L O.C 22) 1,4-difluorobenzene 15.38 114 403669 50.00 ug/L 0.C 35) chlorobenzene-dS 24.68 117 319638 50.00 ug/L 0.C System Monitoring Compounds %Reeovei 19) l,2-dichloroethane-d4 (sur 14.02 65 133807 58.66 ug/L 117,: 29) toluene-de (surr.) 19.91 98 386883 51.00 ug/L 101,5 42) bromofluorcbenzene 28.86 95 286894 50.58 ug/L 101.j Target Compounds Qvalv 8) acetone 7.17 43 6017 6.44 ug/L # 9) carbon disulfide 7.60 76 1119 0.18 ug/L # 14) 2-butanone (MEK) 11.78 43 7684 5.03 ug/L # ( 28) 4-methyl-2-pentanone (MIBK 19.56 43 11758 3.56 ug/L # 30) toluene 20.12 92 17866 3.20 ug/L # i 33) tetrachloroethene 21.95 164 5203 1.88 ug/L 5 37) ethylbenzene 25.22 91 6797 0.58 ug/L # 38) mficp-xylenes 25.63 106 12970 3.22 ug/L i 39) o-xylene 27.01 106 5033 1.29 ug/L # i (#) = cjualifier out of range (m) = manual integration MAR02015.D 8240.M Thu Mar 03 10:19:10 1994 Page WUCUXL.J.( X\.C^Vi/A. w Data File C:\HPCHEM\1\DATA\MAR02\MAR02015.D Acq Time 2 Mar 94 11:27 pm Operator: jp Sample 94-0092 SLP Inst : Volatil Misc Multiplr: 1.00 Quant .Time Mar 3 10:16 1994 Method : C:\HPCHEM\1\METHODS\8240,M Title : target compounds Last Update : Thu Mar 03 09:53:12 1994 Response via Multiple Level Calibration Abundance TIC: MAR02015 .D 260000 240000 220000 200000 42S 29S 160000 351 1 160000 221 140000 120000 100000 11 60000 60000 IS) S 30 ^,C 40000 - • 1 9T f7C 20000 38T [ 33T VO^ . A 14-] 28 1 1 39T V \j ^ I A. \.l\ r, . 0 , , , 1 , , , 1 , , , , 1 , , , 1 1 1 1 1 1 1 1 1 1 1 1 Time--> 5.00 10.00 15.00 20.00 25.00 MAR02015.D 8240.M Thu Mar 03 10:19:14 1994 Page Data File C:\HPCHEM\1\DATA\MAR02\MAR02016.D Acq Time 3 Mar 94 12:21 am Operator; DP Sample 94-0092 MS SLP, 50.0 ppb Inst Volatil Misc Multiplr: 1.00 Quant .Time Mar 3 10:19 1994 Method C:\HPCHEM\1\METHODS\8240.M Title target compounds Last Update Thu Mar 03 09:53:12 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev(Mi 1) bromochloromethane 12.41 128 65945 50.00 ug/L O.C 22) 1,4-difluorobenzene 15.40 114 394933 50.00 ug/L O.C 35) chlorobenzene-dS 24.69 117 313831 50.00 ug/L O.C ,System Monitoring Compounds %Recover 19) 1,2-dichloroethane-d4 (sur 14.02 65 134650 58.06 ug/L 116.1 29) toluene-d6 (surr.) 19.92 98 381564 51.41 ug/L 102,6 42) bromofluorcbenzene 28.88 95 280443 50.36 ug/L 100.' Target Compounds Qvalv 7) 1,1-dichloroethene 7.10 96 105150 47.45 ug/L c 8) acetone 7.17 43 18098 19.05 ug/L # 5 9) carbon disulfide 7.60 76 2451 0.40 ug/L # : 14) 2-butanone (MEK) 11.79 43 15464 9.96 ug/L # e 21) benzene 14.24 78 381690 52.23 ug/L c 23) trichloroethene 16.17 130 146137 45.85 ug/L 5 28) 4-methyl-2-pentanone (MIBK 19.56 43 12799 3.96 ug/L # I 30) toluene 20.14 92 277384 50.79 ug/L c 33) tetrachloroethene 21.95 164 5544 2.04 ug/L # I 36) chlorobenzene 24.79 112 309389 47.40 ug/L c 37) ethylbenzene 25.23 91 8084 0.70 ug/L # ^ 38) mficp-xylenes 25.65 106 13562 3.43 ug/L f 3 9) o-xylene 27.04 106 4835 1.26 ug/L # i (#) = qualifier out of range (m) = manual integration MAR02016.D 8240.M Thu Mar 03 10:20:50 1994 Page Data File C:\HPCHEM\1\DATA\MAR02\MAR02016,D Acq Time 3 Mar 94 12:21 am Operator: jp Sample 94-0092 MS SLP, 50.0 ppb Inst : Volatil Misc Multiplr: 1.00 Quant .Time Mar 3 10:19 1994 Method : C:\HPCHEM\1\METH0DS\8240,M Title : target compounds Last Update : Thu Mar 03 09:53:12 1994 Response via Multiple Level Calibration Abundance TIC: MAR02016,D 260000 240000 220000 30M,C 36M,P 200000 42S 29S 160000 3E I 160000 -I 211121 140000 23M 120000 100000 II 80000-1 8T 60000 ISB 7M, C 40000 9T :i7C 20000 38T 33T 281 3 9T \ ^. JLi^i uu AJ Li -I 1 1 1 1 r T -1 r T ? 1 1 1 1 r- I I r Time--> 5.00 10.00 15.00 20.00 25.00 MAR02016.D 8240.M Thu Mar 03 10:20:55 1994 Page Data File C:\HPCHEM\1\DATA\MAR02\MAR02017.D Acq Time 3 Mar 94 1:15 am Operator: jp Sample 94-0092 MSD SLP, 50.0 ppb Inst : Volatil Misc Multiplr: 1.00 Quant.Time Mar 3 10:21 1994 Method : C:\HPCHEM\i\METHODS\8240.M Title : target compounds Last Update : Thu Mar 03 09:53:12 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev(Md 1) bromoehlorcsmethane 12.41 128 65737 50.00 ug/L O.C 22) 1,4-difluorobenzene 15.40 114 402195 50.00 ug/L O.C 35) chlorobenzene-dS 24.70 117 317368 50.00 ug/L O.C System Monitoring Compounds %Recove2 19) l,2-dichloroethane-d4 (sur 14.02 65 133388 57.70 ug/L 115.4 29) toluene-d8 (surr.) 19.92 98 383391 50.72 ug/L 101.-^ 42) bromofluorcbenzene 28.89 95 280131 49.74 ug/L 99.4 Target Compounds Qvalv 7) 1,1-dichloroethene 7.10 96 104016 47.09 ug/L 5 8) acetone 7.19 43 17204 18.16 ug/L # E 9) carbon disulfide 7.63 76 3797 0.62 ug/L # 14) 2-butanone (MEK) 11.78 43 14946 9.65 ug/L # ( 21) benzene 14.24 78 385129 52.87 ug/L 5 23) trichloroethene 16.17 130 144982 44.66 ug/L i 28) 4-methyl-2-pentanone (MIBK 19.56 43 11973 3.64 ug/L # 30) toluene 20.15 92 277056 49.81 ug/L 5 33) tetrachloroethene 21.94 164 230-9 0.84 ug/L # 36) chlorobenzene 24.80 112 310074 46.96 ug/L 37) ethylbenzene 25.23 91 7484 0.64 ug/L # 38) mficp-xylenes 25.66 106 13289 3.32 ug/L i 39) o-xylene 27.04 106 4602 1.19 ug/L # (#) = cjualifier out of range (m) = manual integration MAR02017.D 8240.M Thu Mar 03 10:22:12 1994 Page Data File C: \HPCniEM\l\DATA\MAR02\MAR02017 -D Acq Time 3 Mar 94 1:15 am Operator: jp Sample 94-0092 MSD SLP, 50.0 ppb Inst : Volatil Misc Multiplr: 1.00 Quant .Time Mar 3 10:21 1994 Method : C:\HPC3ffiM\l\METHODS\B240.M Title : target compounds Last Update : Thu Mar 03 09:53:12 1994 Response via Multiple Level Calibration Abundance TIC: MAR02017.D 260000 240000 220000 30M,C 36M,P 200000 42S 29S 180000 3EI 160000 21I42I 140000 23M 120000 100000 II 80000 60000 ISS 40000 :J7C 20000 38T 281^ 33T 39T L-A_ JLilJl VJUl li_ J C I I T I I T -1 1 1 r - ~ -1 -II1 I1 r~ • -7 • - T 1 1 1 1 1 Time--> 5.00 10.00 15.00 20.00 25.00 MAR02017.D 8240.M Thu Mar 03 10:22:18 1994 Page Method C:\HPCHEM\1\METHODS\8240.M Title target compounds Last Update Thu Mar 03 09:53:12 1994 Response via Initial Calibration Non-Spiked Sample: MAR02015.D Spike Spike Sample Duplicate Sample File ID : MAR02016.D 1 MAR02017.D Sample : 94-0092 MS SLP, 50.0 ppb 1 94-0092 MSD SLP, 50.0 ppb Acq Time: 3 Mar 94 12:21 am 1 3 Mar 94 1:15 am Compound Sample Spike Spike Dup Spike Dup RPD QC Limits Cone Added Res Res %Ree %Ree RPD % Rec 1,1-dichloroethene 1 0.0 50 47 47 95 94 1 14 61-145 benzene 0.0 50 52 53 104 106 1 11 76-127 trichloroethene 0.0 50 46 45 92 89 3 14 71-120 toluene 3.2 SO 51 50 95 93 2 13 76-125 chlorobenzene 0.0 50 47 47 95 94 1 13 75-130 8240.M Thu Mar 03 10:24:13 1994 Data File : C:\HPCHEM\l\DATA\MAR02\MAR02018.D Acq Time : 3 Mar 94 2:09 am Operator: jp Sample : Ref std purgeaJale B, 50.0 ppb Inst : Volatil Multiplr: 1.00 Misc : Quant .Time: Mar 3 10:22 1994 Method : C:\HPCHEM\1\METHODS\8240.M Title : target compounds Last Update : Thu Mar 03 09:53:12 1994 Response via : Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev(Mi 1) bromochloromethane 12 .43 128 65318 50 .00 ug/L 0. C 22) 1,4-difluorobenzene 15 .41 114 393643 50 .00 ug/L 0. C 35) chlorobenzene-dS 24 .71 117 306584 50 .00 ug/L 0. c System Monitoring Compounds %Recovei 19) 1,2-dichloroethane-d4 (sur 14 .03 65 132818 57 .82 ug/L 115. 6 29) toluene-dB (surr.) 19 .94 98 374575 50 .63 ug/L 101. ^ 42) bromo fluorobenz ene 28 .89 95 277491 50 .67 ug/L 101. -" Target Compounds Qval.V 8) acetone 7 .16 43 5805 6 .17 ug/L # c 11) trans-1,2-dichloroethene 9 08 96 109268 54 .48 ug/L c 14) 2-butanone (MEK) 11 79 43 16282 10 .59 ug/L # 6 17) 1,1,1-trichloroethane 13 20 97 142579 44 42 ug/L c A n # £ IB j carbon LyLzauhluiidt; U zl - 11 r x'jxjij'j -J.-tr- Vtgf-is- C 20) 1,2-dichloroethane 14 .24 62 161587 54 .20 ug/L t 21) benzene 14 24 78 379009 52 36 ug/L c 23) trichloroethene 16 18 130 9401 2 96 ug/L c 25) bromodichloromethane 17 64 83 9576 12 43 ug/L # E 26) 2-chloroethylvinyl ether 18 56 63 2040 1 07 ug/L # r 27) cis-1,3-dichloropropene 19 .04 75 106505 39 .12 ug/L c 28) 4-methyl-2-pentanone (MIBK 19 .91 43 513 0 16 ug/L # i 30) toluene 20 15 92 256659 47 15 ug/L c 31) trans-1,3-dichloropropene 20 83 75 111053 44 41 ug/L c 37) ethylbenzene 25 24 91 539820 47 53 ug/L c -\ rt \ 1 A -KT]r 0 0 nn /T U inc 1 r TT _; 3iTi- mficp—xyicneo xvo -f J ug/ iJ 41) bromoform 27 .65 173 106245 42 71 ug/L C 43) 1,1,2,2-tetrachloroethane 29 42 83 197296 46 10 ug/L < (#) = cjualifier out of range (m) = manual integration MAR02018.D 8240.M Thu Mar 03 10:23:32 1994 Page Data File C:\HPC3ffiM\l\DATA\MAR02\MAR02018.D Acq Time 3 Mar 94 2:09 am Operator: jp Sample Ref std purgeable B, 50.0 ppb Inst : Volati] Misc Multiplr: 1.00 Quant Time Mar 3 10:22 1994 Method : C:\HPCHEM\i\METHODS\8240.M Title : target compounds Last Update : Thu Mar 03 09:53:12 1994 Response via Multiple Level Calibration Abundance TIC: MAR02018.D 280000 260000 240000 37C 220000 H 30M,C 21M 200000 38T 42S 29S 180000 -J 20T 19S 35 160000 IBT 140000 117T 221 2( T '3 120000 -J IIT 100000 80000 -I 27T 14T 41P 60000 IT BT 40000 20000 -H iJ. ULilMJ —ly C I I j — I I —I ] 1 1 1 r Time--> 5.00 10.00 15.00 20.00 25.00 MAR02016.D 8240.M Thu Mar 03 10:23:37 1994 Page 3BV^UCX,IV.;C XVailICi . Comment: Operator: 3 P Data Path: C: \HP(3IEM\l\DATA\mar07\ Pre-Seq C^md: Post-Seq Cmd: Method Sections To Run On A Barcode Mismatch (X) Full Method (X) Inject Anyway { ) Reprocessing Only ( ) Don't Inject Line Type Vial DataFile Method Sample Name 1) Sample 1 MAR03001 8240 TCL STD, 50.0, 150 (vinyl aeet 2) Sample 2 MAR03002 8240 Blank 3) Sample 3 MAR03003 8240 TCLP extraction fluid #1 4) Sample 4 MAR03004 8240 94-0090 TCLP 5) Sample 5 MAR03005 8240 94-0091 TCLP . 6) Sample 6 MAR03006 8240 94-0092 TCLP 7) Sample 7 MAR03007 8240 94-0090 soil, 1.0 g/5 mL 8) Sample 8 MAR03008 8240 94-0092 soil, 1.0 g/5 mL 9) Sample 9 MAR03009 8240 94-0091 soil, 3.0 g/3 mL, 50 V 10) Sample 10 MAR03010 8240 94-0090 MS soil 1.0 g/5 mL, 5 11) Sample 11 MAR03011 8240 94-0090 MSD soil, 1.0 g/5 mL, 12) Sample 12 MAR03012 8240 DI H20 for SLP & ELT 13) Sample 13 MAR03013 8240 94-0091 soil, 1.6 g/5 mL 14) Last Modified: Wed Apr 06 11:18:03 1994 Page: 1 Data File C: \HPC3IEM\1\DATA\MAR03\BFB-1 .D Acq Time 3 Mar 94 8:58 am Operator: jp Sample bfb, 50.0 ppm, 1 ul inj. Inst : Volatiles Misc EM = 200 above autotune Multiplr: 1.00 Method C:\HPCHEM\1\METHODS\8240.M Title targe t compounds Scan Number 306 Target Rel. to Lower Upper Rel. Raw Result Mass Mass Limit% Limit% Abn% Abn Pass/Fail 1 ^° 95 15 40 21.7 8111 PASS 1 75 95 30 60 49.2 18400 PASS 95 95 100 100 100.0 37392 PASS 96 95 5 9 7,2 2688 PASS 173 174 0 2 0.0 0 PASS . 174 95 50 100 50.6 18912 PASS 175 174 5 9 8.9 1681 PASS 176 174 95 101 99.8 18880 PASS 1 177 176 5 9 7.3 1387 PASS BFB-l.D 8240.M Wed Apr 06 11:05:41 1994 Data File C:\HPCHEM\1\DATA\MAR03\MAR03001,D Acq Time 3 Mar 94 9:47 am Operator: jp Sample TGL std, 50.0, Vinyl acetate 150 ppb. Inst : Volatil Misc Multiplr: 1.00 Quant .Time Mar 3 10:57 1994 Method C:\HPCHEM\1\METHODS\8240.M Title target compounds Last Update Thu Mar 03 09:53:12 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev(Mi 1) bromo chloromethane 12 .46 128 69395 50 .00 ug/L 0,1 22) 1,4-difluorobenzene 15 .43 114 394732 SO .00 ug/L 0.0 35) chlorobenzene-dS 24 .74 117 312398 50 .00 ug/L 0.0 Syst em Monitoring Compounds %Il e cover 19) l,2-dichloroethane-d4 (sur 14 .06 65 132832 54 .43 ug/L 108.8 29) toluene-d8 (surr.) 19 .97 98 382272 51 .53 ug/L 103.0 42) bromofluorcbenzene 28 .92 95 281177 50 .72 ug/L 101.4 Target Compounds (3valu 2) chloromethane 3 .90 SO 82759 46 .87 ug/L # 9 3) vinyl chloride 4 .13 62 109182 52 .53 ug/L # 9 4) bromomethane 4 .86 94 29642 33 .48 ug/L m 5) chloroethane 5 .16 64 71355 69 .17 ug/L m 6) trichlorofluoromethane 5 .66 101 280937 65 .09 ug/L m 7) 1,1-dichloroethene 7 14 96 120370 51 .62 ug/L 9 8) acetone 7 19 43 36244 36 .25 ug/L # 5 9) carbon disulfide 7 66 76 332865 51 .43 ug/L 10 10) methylene chloride 8 37 84 124159 52 .76 ug/L 9 11) trans-l,2-dichloroethene 9 13 96 110536 51 .87 ug/L 9 12) 1,1-dichloroethane 10 25 63 226764 SO .97 ug/L 9 13) vinyl acetate 10 40 43 9437 106 46 ug/L # 14) 2-butanone (MEK) 11 61 43 68157 41 71 ug/L # 9 15) cis-1,2-dichloroethene 11 82 96 144620 51 83 ug/L 9 16) chloroform 12 72 83 180171 52 79 ug/L 10 17) 1,1,1-trichloroethane 13 23 97 192917 56 57 ug/L 9 18) carbon tetrachloride 13 23 117 22251 57 62 ug/L # 9 20) 1,2-dichloroethane 14 26 62 169767 53 60 ug/L 9 21) benzene 14 26 78 406990 52 93 ug/L 9 23) trichloroethene 16 22 130 161178 50 59 ug/L c .24) 1,2-dichloropropane 16 81 63 161752 52 09 ug/L c 25) bromodichloromethane 17 67 83 36124 46 75 ug/L # c 26) 2-chloroethylvinyl ether 16 65 63 103250 54 12 ug/L c 27) cis-1,3-dichloropropene 19 08 75 135704 49 71 ug/L c 28) 4-methyl-2-pentanone (MIBK 19 59 43 149938 46 39 ug/L c 30) toluene 20. 16 92 297165 54. 44 ug/L c 31) trans-1,3-dichloropropene 20. 87 75 125708 50. 13 ug/L c 32) 1,1,2-trichloroethane 21. 43 97 134155 50. 65 ug/L IC 33) tetrachloroethene 22. 00 164 136062 SO. 17 ug/L c 34) chlorodibromomethane 22. 73 129 80471 45. 10 ug/L # c 36) chlorobenzene 24. 83 112 330351 SO. 84 ug/L c 37) ethylbenzene 25. 27 91 588094 51. 15 ug/L c 38) mficp-xylenes 25. 70 106 399390 101. 51 ug/L c 39) o-xylene 27. 07 106 192934 50. 50 ug/L c (#) = cjualifier out of range (m) = manual integration MAR03001.D 8240.M Thu Mar 03 11:01:51 1994 Page ] Data File C:\HPCHEM\1\DATA\MAR03\MAR03001,D Acq Time 3 Mar 94 9:47 am Operator: jp Sample TGL std, 50.0, Vinyl acetate 150 ppb. Inst : Volatil Misc Multiplr: 1.00 Quant .Time Mar 3 10:57 1994 Method C:\HPC3ffiM\i\METHODS\8240.M Title target compounds Last Update Thu Mar 03 09:53:12 1994 Response via Multiple Level Calibration Compound R.T. Qlon Response Cone Unit Qvalu 40) styrene 27.12 104 338017 50.45 ug/L S 41) bromoform 27.67 173 118090 46.89 ug/L c 43) 1,1,2,2-tetraehloroethane 29.44 83 215175 49.66 ug/L (#) = cjualifier out of range (m) = manual integration MAR03001.D 8240.M Thu Mar 03 11:01:52 1994 Page Data File C:\HPCHEM\1\DATA\MAR03\MAR03001.D Acq Time 3 Mar 94 9:47 am Operator: jp Sample TGL Std, 50.0, Vinyl acetate 150 ppb. Inst : Volatil Misc Multiplr: 1.00 Quant .Time Mar 3 10:57 1994 Method : C:\HPCHEM\1\METHODS\8240.M Title : target compounds Last Update : Thu Mar 03 09:53:12 1994 Response via Multiple Level Calibration MAR03001.D 8240.M Thu Mar 03 11:01:59 1994 Page -*"-"- Data File C:\HPCHEM\1\DATA\MAR02\MAR02013.D Acq Time 2 Mar 94 9:46 pm Operator: jp Sample 94-0090 SLP Inst : Volatil Misc Multiplr: 1.00 Quant .Time Mar 3 10:14 1994 Method : C:\HPCHEM\1\METHODS\8240.M Title : target compounds Last Update : Thu Mar 03 09:53:12 1994 Response via Multiple Level Calibration Abundance 260000 240000 220000 200000 180000 MAR02013.D 8240.M Thu Mar 03 10:15:06 1994 Page : Data File C:\HPCHEM\1\DATA\MAR02\MAR02014.D Acq Time 2 Mar 94 10:36 pm Operator; 3P , Sanple 94-0091 SLP Inst Volatil Misc Multiplr: 1.00 Quant .Time Mar 3 10:15 1994 Method : C:\HPCHEM\i\METHODS\8240.M Title : target compounds Last Update : Thu Mar 03 09:53:12 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev(Mi 1) bromochloromethane 12.38 128 64187 50.00 ug/L O.C 22) 1,4-difluorobenzene 15.35 114 400184 50.00 ug/L O.C 35) chlorobenzene-dS 24.65 117 316925 50.00 ug/L -O.C .System Monitoring Compounds %Recover 19) 1,2-dichloroethane-d4 (sur 13.99 65 132080 58.51 ug/L 117.C 29) toluene-dB (surr.) 19.88 98 381556 50.73 ug/L 101.4 42) bromofluorcbenzene 28.84 95 285445 50.75 ug/L 101.E Target Compounds Qvalv 8) acetone 7.12 43 3531 3.82- ug/L # E 9) carbon disulfide 7.59 76 4303 0.72 ug/L # n 14) 2-butanone (MEK) 11.74 43 12095 8.00 ug/L # 6 23) trichloroethene 16.12 130 12051 3.73 ug/L S 28) 4-methyl-2-pentanone (MIBK 19.50 43 26644 8.13 ug/L # E 30) toluene 20.10 92 30325 5.46 ug/L S 36) chlorobenzene 24.75 112 5143 0.78 ug/L # 6 37) ethylbenzene 25.19 91 21719 1.86 ug/L # E 38) mficp-xylenes 25.62 106 36353 9.61 ug/L S 39) o-xylene 26.98 106 12677 3.27 ug/L S (#) = cjualifier out of range (m) = manual integration MAR02014.D 8240.M Thu Mar 03 10:16:18 1994 Page Data File : C:\HPCHEM\1\DATA\MAR03\MAR03007.D Acq Time 3 Mar 94 3:06 pm Operator: jp Sample 94-0090 soil, 1.0 g/5 mL Inst : Volatil Misc Multiplr: 1.00 Quant .Time: Mar 3 17:43 1994 Method : C:\HPCHEM\1\METHODS\8240,M Title : target compounds Last Update : Thu Mar 03 15:52:03 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev(Mi 1) bromochloromethane 12 .38 128 62962 50 .00 ug/L 0.C 22) 1,4-difluorobenzene 15,.3 7 114 345480 50 .00 ug/L 0,C 35) chlorobenzene-dS 24 .67 117 235752 50 .00 ug/L 0.C System Monitoring Compounds %Reeover 19) l,2-dichloroethane-d4 (sur 13,.9 9 65 117882 53,.2 4 ug/L 106,4 29) toluene-d8 (surr.) 19,.8 9 98 316195 48,.7 0 ug/L 97.4 42) bromofluorcbenzene 28..8 5 95 190781 45,.6 0 ug/L 91,2 Target Compounds Qvalu 8) acetone 7,.1 4 43 324 0,,3 6 ug/L # E 14) 2-butanone (MEK) 11..7 6 43 3173 2..1 4 ug/L # 6 28) 4-methyl-2-pentanone (MIBK 19..8 8 43 3228 1.. 14 ug/L # 30) toluene 20..1 1 92 3931 0.. 82 ug/L # € (#) = qualifier out of range (m) = manual integration MAR03007.D 8240.M Thu Mar 03 17:46:48 1994 Page Data File C:\HPCHEM\1\DATA\MAR03\MAR03007.D Acq Time 3 Mar 94 3:06 pm Operator: jp Sample 94-0090 soil, 1.0 g/5 mL Inst : Volatile Misc Multiplr: 1.00 Quant .Time Mar 3 17:43 1994 Method C:\HPCHEM\l\METHODS\8240.M Title target compounds Last Update Thu Mar 03 15:52:03 1994 Response via Multiple Level Calibration Abundance TIC: MAR03007,D 1 360000^ 340000 320000 300000: 280000 : 260000 240000^ 220000 200000 IBOOOO 29S 160000 140000 4:> s 211 1 2« IT 35i l 120000 100000 11 80000 60000 30 -i,c 19S 40000 20000 \ V___^8T (\ 14': __ n I k U Time--> 5.00 10.00 15.00 20.00 25.00 MAR03007.D 8240.M Thu Mar 03 17:46:51 1994 Page Data File C:\HPCHEM\1\DATA\MAR03\MAR0300B.D Acq Time 3 Mar 94 3:56 pm Operator: jp Sample 94-0092 soil, 1.0 g/5 mL Inst : Volatiles Misc Multiplr: 1.00 3uant Timei Mar 3 17:47 1994 Method C:\HPCHEM\1\METHODS\8240.M Title target compounds Last Update Thu Mar 03 15:52:03 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) bromochloromethane 12 .41 128 60101 50.00 ug/L 0 .05 22) 1,4-difluorobenzene 15 .38 114 341579 50.00 ug/L 0 .03 35) chlorobenzene-dS 24 .67 117 237427 50.00 ug/L 0.00 System Monitoring Compounds %Recovery 19) 1,2-dichloroethane-d4 (sur 14 .00 65 113092 53.51 ug/L :L07 .02% 29) toluene-d8 (surr.) 19 .89 98 317766 49.50 ug/L 99 .00% 42) bromofluorcbenzene 28 .85 95 195758 46.46 ug/L 92 .92% Target Compounds Qvalue 8) acetone 7 14 43 1613 1.86 ug/L # 54 9) carbon disulfide 7 61 76 57567 10.27 ug/L # 75 10) methylene chloride 8 29 84 988 0.48 ug/L # 1 14) 2-butanone (MEK) 11 79 43 7230 5.11 ug/L # 61 21) benzene 14 21 78 2286 0.34 ug/L # 54 28) 4-methyl-2-pentanone (MIBK 19 88 43 2090 0.75 ug/L # 1 30) toluene 20. 11 92 6268 1.33 ug/L # 81 37) ethylbenzene 25. 20 91 20461 2.34 ug/L 92 38) mficp-xylenes 25. 62 106 6183 • 2.07 ug/L 76 (#) = qualifier out of range (m) = manual integration MAR0300B.D 8240.M Mon Mar 07 08:40:28 1994 ^LAaML.A.W«k w>«M.i»^^rfAA XV^^^^-*^ w Data File C:\HPCHEM\1\DATA\MAR03\MAR03008,D Acq Time 3 Mar 94 3:56 pm Operator: jp Sample 94-0092 soil, 1,0 g/5 mL Inst : Volati." Misc Multiplr: 1,00 Quant .Time Mar 3 17:47 1994 Method : C:\HPCHEM\1\METHODS\8240,M Title : target compounds Last Update : Thu Mar 03 15:52:03 1994 Response via Multiple Level Calibration Abundance TIC: MAR0300B,D 320000 300000 260000H 260000 240000 220000 200000 180000 29S 160000 140000 1 42S J 351 221 2(IT 120000 100000 II 80000 60000 19S 30 -I,C 9T 40000 2LM : 7C 20000 38T 81S-0T 2131 \ -, \ r Time--> 5.00 10.00 15.00 20.00 25.00 MAR03008.D 8240.M Thu Mar 03 17:49:19 1994 Page Data File C:\HPCHEM\1\DATA\MARO 3\MARO3 0 0 9.D Acq Time 3 Mar 94 4:46 pm Operator: jp Sample 94-0091 soil, 3.0g/3 mL MeOH, 50 uL Inst : Volatil Misc Multiplr: 1.00 Quant.Time Mar 3 17:49 1994 Method : C:\HPCHEM\i\METHODS\8240.M Title : target compounds Last Update : Thu Mar 03 15:52:03 1994 Response via : Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev(Mi 1) bromochloromethane 12 .38 128 73617 50.00 ug/L 0,0 22) 1,4-difluorobenzene 15 .37 114 413316 50.00 ug/L 0.0 35) chlorobenzene-dS 24 .67 117 329743 50.00 ug/L O.C Syst sm Monitoring Compounds %Reeover 19) l,2-dichloroethane-d4 (sur 14 .00 65 140423 54 .24 ug/L 108.4 29) toluene-d8 (surr.) 19 .90 98 399350 51.41 ug/L 102.6 42) bromofluorcbenzene 28 .85 95 302957 51.77 ug/L 103.5 Target Compounds • Qvalu 4) bromomethane 4 .72 94 1586 1.69 ug/L # 1 8) acetone 7 .16 43 13269 12.51 ug/L # 5 13) vinyl acetate 10 .67 43 1015 10.79 ug/L # 14) 2-butanone (MEK) 11 .79 43 65012 37.50 ug/L # £ 23) trichloroethene 16 14 130 2836 0.85 ug/L # 6 28) 4-methyl-2-pentanone (MIBK 19 20 43 1492 0.44 ug/L # 4 30) toluene 20 11 92 19041 3.33 ug/L S 36) chlorobenzene 24 76 112 2371 0.35 ug/L # 4 37) ethylbenzene 25 20 91 5963 0.49 ug/L # 4 38) mficp-xylenes 25. 62 106 25392 6.11 ug/L S 39) o-xylene 27 02 106 8046 2.00 ug/L "i (#) = cjualifier out of range (m) = manual integration MAR03009.D 8240.M Thu Mar 03 17:50:23 1994 Page M«»~ Data File C:\HPCHEM\1\DATA\MAR03\MAR03009.D Acq Time 3 Mar 94 4:46 pm Operator: jp Sample 94-0091 soil, 3.0g/3 mL MeOH, 50 uL Inst : Volatil Misc Multiplr: 1.00 Quant .Time Mar 3 17:49 1994 Method : C:\HPCHEM\1\METHODS\8240.M Title : target compounds Last Update : Thu Mar 03 15:52:03 1994 Response via : Multiple Level Calibration Abundance TIC: MAR03009.D 340000 320000 300000 280000: 260000 240000: 220000 42S 29S 200000 : 3E5 1 180000 1. 160000 : 221 i 140000 ] 120000 100000 11 80000 60000 - IS) S 3 6 17© 40000 38T 20000 - 30 ^,c Wi_8T__^ 23M ^ 28-1 \ . A \ . .itsAAl J\Jj[l^ u* n , 1 • , , , 1 , , , , 1 , , , , , , , 1 , , , ,• , - 1 Time--> 5.00 10.00 15.00 20.00 25.00 MAR03009.D 8240.M Thu Mar 03 17:50:27 1994 Page Data File C:\HPCHEM\1\DATA\MAR03\MAR03010.D Acq Time 3 Mar 94 5:36 pm Operator: jp Sample 94-0090 MS soil, 50.0 ppb Inst : Volatil Misc : Multiplr: 1.00 Quant .Time: Mar 4 8:50 1994 Method C:\HPCHEM\1\METHODS\8240.M Title target compounds Last Update Thu Mar 03 15:52:03 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev(Mi 1) bromochloromethane 12 .41 128 62211 50.00 ug/L 0.0 22) 1,4-difluorobenzene 15 .38 114 341121 50.00 ug/L 0.0 35) chlorobenzene-d5 24 .67 117 237678 50.00 ug/L 0.0 System Monitoring Compounds %Reeover 19) 1,2-dichloroethane-d4 (sur 14,.0 0 65 118683 54.25 ug/L 108.5 29) toluene-dB (surr.) 19,.9 1 98 316842 49.42 ug/L 98.8 42) bromofluorcbenzene 28,.8 5 95 191425 45.38 ug/L 90.7 Target Compounds Qvalu 7) 1,l-dichloroethene 7,.0 7 96 97467 46.63 ug/L 9 8) acetone 7..1 4 43 7303 8.15 ug/L # 5 14) 2-butanone (MEK) 11,.7 9 43 15183 10.36 ug/L # 6 21) benzene 14.,2 3 78 343704 49.86 ug/L S 23) trichloroethene 16..1 5 130 119205 43.30 ug/L 9 28) 4-methyl-2-pentanone (MIBK 19..6 8 43 954 0.34 ug/L # 7 30) toluene 20.,1 1 92 217941 46.20 ug/L 9 36) chlorobenzene 24. 77 112 230580 46.65 ug/L 9 (#) = cjualifier out of range (m) = manual integration MAR03010.D 8240.M Fri Mar 04 08:52:02 1994 Page ^U,CU.1U.^ ^w.^<»««.M. AN.v.^^'* — Data File C:\HPCHEM\1\DATA\MAR03\MAR03010.D Acq Time 3 Mar 94 5:36 pm Operator: jp Sample 94-0090 MS soil, 50.0 ppb Inst : Volatilt Misc Multiplr: 1.00 Quant .Time Mar 4 8:50 1994 Method : C:\HPCHEM\l\METHODS\8240.M Title : target compounds Last Update : Thu Mar 03 15:52:03 1994 Response via : Multiple Level Calibration Abundance TIC: MAR03010.D 350000 300000 250000 200000 30M,C 36M,P 29S 150000 21M 3EI 42S 221 21T 100000 23M II 50000 ISS 14i3\_ J u I 1 1 I I I T" I I I 1 I I 1 [ I I 1 r Time--> 5.00 10.00 ISioO 20.00 25.00 MAR03010.D 8240.M Fri Mar 04 08:52:06 1994 Page 2 Data File C:\HPCHEM\1\DATA\MAR03\MAR03011.D Acq Time 3 Mar 94 6:28 pm Operator: jp Sample 94-0090 MSD soil, 50.0 ppb Inst : Volati: Misc Multiplr: 1.00 Quant .Time Mar 4 8:52 1994 Method : C:\HPCHEM\i\METHODS\8240.M Title : target compounds Last Update : Thu Mar 03 15:52:03 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone 1Units Dev(M; 1) bromochloromethane 12.41 128 56403 50.00 ug/L O.C 22) 1,4-difluorobenzene 15.40 114 331485 50.00 ug/L 0. ( 35) chlorobenzene-dS 24.68 117 221315 50.00 ug/L 0. ( System Monitoring Compounds %Reeove: 19) 1,2-dichloroethane-d4 (sur 14.02 65 115175 58.07 ug/L 116.: 29) toluene-dB (surr.) 19.91 98 295104 47.37 ug/L 94.' 42) bromofluorcbenzene 28.86 95 178972 45.57 ug/L 91.: Target Compounds Qval I 7) 1,1-dichloroethene 7.11 96 92063 48.57 ug/L 8) acetone 7.17 43 7745 9.53 ug/L # 14) 2-butanone (MEK) 11.79 43 15320 11.53 ug/L # ( 21) benzene 14.23 78 330425 52.87 ug/L ! 23) trichloroethene 16.15 130 115056 43.01 ug/L ! 28) 4-methyl-2-pentanone (MIBK 19.92 43 968 0.36 ug/L # 30) toluene 20.12 92 205120 44.75 ug/L 36) chlorobenzene 24.79 112 218319 47.43 ug/L i (#) = cjualifier out of range (m) = manual integration MAR03011.D 8240.M Fri Mar 04 08:59:16 1994 Page MUGLllb.bw~.-_.,.. -f— Data File C:\HPCHEM\1\DATA\MAR03\MAR03011.D Acq Time 3 Mar 94 6:28 pm Operator: jp Sample 94-0090 MSD soil, 50.0 ppb Inst : Volatil Misc Multiplr: 1.00 Quant .Time Mar 4 8:52 1994 Method : C:\HPCHEM\1\METHODS\8240.M Title : target compounds Last Update : Thu Mar 03 15:52:03 1994 Response via Multiple Level Calibration Abundance TIC: MAR03011.D 340000 320000 300000 280000 260000 240000 220000 200000 30M,C 180000 36M,P 160000 28T 140000 21M 29|S 3E I 120000 221 42S 100000 23M II 80000 60000 19S 40000 I 20000 l ^ v_JU -T^-^T^—r—r- rime--> 5.00 10.00 15.00 20.00 25.00 MAR03011.D 8240.M Fri Mar 04 06:59:20 1994 Page • J ""-f Method : C:\HPCHEM\1\METHODS\8240.M Title : target compounds Last Update : Thu Mar 03 15:52:03 1994 Response via Initial Calibration Non-Spiked Sample: MAR03007.D Spike Spike Sample Duplicate Sample File ID MAR03010.D MAR03011.D Sample 94-0090 MS soil, 50.0 ppb I 94-0090 MSD soil, 50.0 p Acq Time 3 Mar 94 5:36 pm 3 Mar 94 6:28 pm Compound Sample Spike Spike Dup Spike Dup RPD QC Limits Cone Added Res Res %Rec %Rec RPD % Rec 1,1-dichloroethene 0.0 50 47 49 93 97 4 22 59-172 benzene 0.0 50 SO 53 100 106 6 21 66-142 trichloroethene 0.0 50 43 '43 87 86 1 24 62-137 toluene 0.8 50 46 45 91 88 3 21 59-139 chlorobenzene 0.0 50 47 47 93 95 2 21 60-133 8240.M Fri Mar 04 09:08:01 1994 ^hACLLXk Data File C:\HPCHEM\1\DATA\MAR03\MAR03012.D Acq Time 3 Mar 94 8:12 pm Operator: jp Sample DI H20 for SLP & ELT. Inst : Volatil Misc : Multiplr: 1.00 Quant .Time: Mar 4 8:59 1994 Method C:\HPCHEM\1\METHODS\8240.M Title target compounds Last Update Thu Mar 03 15:52:03 1994 Response via Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev(Mi 1) bromochloromethane 12.35 128 70596 50.00 ug/L 0,0 22) 1,4 -di fluorobenzene 15.35 114 406010 50.00 ug/L 0.0 35) chlorobenzene-dS 24.67 117 332025 50.00 ug/L 0.0 System Monitoring Compounds %Recover 19) l,2-diehloroethane-d4 (sur 13.97 65 135184 54.45 ug/L 108.S 29) toluene-dB (surr.) 19.90 98 399566 52.36 ug/L 104.7 42) bromofluorcbenzene 28.86 95 306609 52.04 ug/L 104.C Target Compounds Qvalv 8) acetone 7.10 43 150 0.15-ug/L # E 14) 2-butanone (MEK) 11.73 43 3117 1.87 ug/L # 6 28) 4-methyl-2-pentanone (MIBK 19.90 43 2608 0.78 ug/L # 30) toluene 20.09 92 1828 0.33 ug/L # (#) = cjualifier out of range (m) = manual integration MAR03012.D 8240.M Fri Mar 04 09:01:25 1994 Page — B Data File C:\HPCHEM\1\DATA\MAR03\MAR03012.D Acq Time 3 Mar 94 8:12 pm Operator: jp Sample DI H20 for SLP & ELT. Inst : Volatil Misc Multiplr: 1.00 Quant .Time Mar 4 8:59 1994 Method C:\HPCHEM\1\METHODS\8240.M Title target compounds Last Update Thu Mar 03 15:52:03 1994 Response via Multiple Level Calibration Abundance TIC: MAR03012.D 260000 28T 240000 220000 221 42S 200000 180000 351 29S 160000 140000 120000 II 19S 100000 30*1,C 80000 60000 40000 14T 20000 LAJ l_JV. JV. -1 1 : 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1—1 1 1 1 r- Time--> 5.00 10.00 15.00 20.00 25.00 MAR03012.D 8240.M Fri Mar 04 09:01:29 1994 Page : Data File C:\HPCHEM\1\DATA\MAR03\MAR03013.D Acq Time 3 Mar 94 7:18 pm Operator: jp Sample 94-0091 soil, 1.0 g/5 mL Inst : Volatile Misc Multiplr: 1.00 Quant .Time Mar 4 9:06 1994 Method : C:\HPCHEM\1\METHODS\8240.M Title : target compounds Last Update : Thu Mar 03 15:52:03 1994 Response via : Multiple Level Calibration Internal Standards R.T. Qlon Response Cone Units Dev(Mi: 1) bromochloromethane 12.43 128 60771 SO . 00 ug/ L 0.0 22) 1,4-difluorobenzene 15.41 114 351397 50.00 ug/L 0.0 35) chlorobenzene-dS 24.71 117 256001 50.00 ug/L 0.0 System Monitoring Compounds %Reeover 19) 1,2-dichloroethane-d4 (sur 14.03 65 118308 55.36 ug/L 110.7 29) toluene-dB (surr.) 19.94 98 330083 49.98 ug/L 99.9 42) bromofluorcbenzene 28.89 95 213914 47.09 ug/L 94.1 Target Compounds Qvalu 8) acetone 7.22 43 4090 4.67 ug/L # 5 9) carbon disulfide 7.63 76 6069 1.07 ug/L # 7 14) 2-butanone (MEK) 11.82 43 7280 5.09 ug/L # 6 26) 4-methyl-2-pentanone (MIBK 19.91 43 1569 0.55 ug/L # 4 30) toluene 20.15 92 3967 0.82 ug/L # 6 32) 1,1,2-trichloroethane 21.04 97 1006 0.43 ug/L # 1 36) chlorobenzene 24.80 112 8046 1.51 ug/L # 6 38) mficp-xylenes 25.68 106 6525 2.02 ug/L 8 (#) = cjualifier out of range (m) = manual integration MAR03013.D 8240.M Fri Mar 04 09:07:16 1994 Page ] Data File C:\HPCHEM\1\DATA\MAR03\MAR03013.D Acq Time 3 Mar 94 7:18 pm Operator: jp Sample 94-0091 soil, 1.0 g/5 mL Inst : Volatil Misc Multiplr: 1.00 Quant .Time Mar 4 9:06 1994 Method C:\HPCHEM\iVMETHODS\8240.M Title target compounds Last Update Thu Mar 03 15:52:03 1994 Response via Multiple Level Calibration TIC: MAR03013.D 300000 280000 260000 240000 220000 : 200000 : 180000 29S • 160000 42S 140000 351 221 120000 2( T 100000 II 80000 60000 19S 30<,C 36:i,P 40000 20000 38T iJl l^L^Wi^J AJV__A-AAUJ u. 0 —^ I I 1 I 1 I——I 1 1 1 1 1 1 •] 1 1 1 1 1 1 1 r Time--> 5.00 10.00 15.00 20.00 25.00 MAR03013.D 8240.M Fri Mar 04 09:07:19 1994 Page SAMPLE 1 DATE ANALYCT FILENAME SAMPLE ID MATRIX CONC. DILUTION MTH STD ID REMARKS P'31-^^ b\an^ lhs>lr. tickle ^.EXiCUiRS C)?H1' \/\oo ^M-o^m 0 0.'^^U.J.?|.io) 1 0 . 0 (iWI V\oooo <^M'0??W/ \ ' 0 p^imcLOiHi '')-2y94 r-^( ^\ar\\^ \nbtY. tl^nid Ob^\ ylooo q^-o>)-(i o 0.iJ.'»1^l0rhL->l MCOO f)),m V»oj vU 0 iy il'.pO ^ fciqr»"d^ In^^r. Uqr>t Wecfis 9 }fi,9-b^i itD;.,.M .s' a.o.D.vf.b.'i' KrvAfcvfc .1L (lle»Ao(|tlon 1,^ D.'vsWtx.i 'b-il-'iH JP 5tT>l.j.M,'^ ^t.o.O.^.O.T H^ftftS vl/ vl dy ^ vl/ 0.lL/lr, L K/»rHfeu: ,|L (VkWutdVjltJnlc > ^ O0PDTCi,(>.iL qS-bO^OTCuf A a. (XfloeuT.iL qM-Dcfloai A. vl/ OWo SLP.IL q^-OO^O^Lf ^ vb • (WoTiU'ms HH-oDfloTS:'' ^ .^l!!."J?f f " vl/ 9-^^,9 •^'* 009oiCzr(hSD qw-OC^o^»^ K vb I OO^lTOf.iL qvl-OO^l TXif h i/ (Wl eu .IL ^M'OOqiar f^ vl; V Q|-ci /j\ ^d i Q \ O"*?! JcTpQJy wJ^o-^Q'TCl 1 >lK».t;'> / N rj^cvd Yimo-^ • [ro y-o • 0 Ab^e /.b fl^'*^' Itb'i^U ^ 0 ' Ooo •i\^h'^ Q iKO-KVj QOOI/I \hlO sy(ji:«D^ >I/Jtn9 >»Mi/i l l / \ l/^/CWi'Q'o'l T^^l^'o/v't oi ^ ja y a ^sn'otoo- Kb QSiOOtQQ-Kb ^ 1 ^ h IFLIER: 1.00000 RS: PEAKS SP-2100 100/120 SLPELCOPCRT OW 60> RANGEI. 3 UL IN>.ECTION T SPEED 0.1 CM/MIN h\an^ N: 12& ZERO: 12?< 5 riN.'TICK :i! ^FEtb' 12.316 E: AROCLORS 16:43 23 MAP NEL NO : 1 SAMPLE: BLANK METHOD: HERBS PEAK RESULT TIME AREA SEP NAME UG/ML (MIN) COUNTS CODE 100.0000 2 .502 113438 VV LS: 100.0000 113438 IFLIER: 1.00000 RS: AK STORAGE FULL SP-2100 100/120 SLPELCOPCRT OU 60> RANGEI> 3 UL INFECTION a - 1 2VMIN 210* 4 20VriN 230 • 19 ^•te9 a,w-a ^'O A O ^T : INJECT" 12.475 13.893 .E: AROCLORS 17:06 23 MAR ^NEL NO: 1 SAMPLE: STD 2...4,.5 METHOD: HERBS PEAK RESULT TIME AREA SEP NAME UG/ML (MIN) COUNTS CODE 22.492 1 S .288 687061 BV : SILVEX ME 25.2354 7 .-3 06 77Q858 VV ; 245-T ME E 48.9808 e .503 1496200 VV ::).2917 11.125 10QS51 VB ^LS: 100.0000 305'-670 IFLIER: 1.00000 :;s :SP-210 0 100/120 SLPELCOPCRT .OU 60. RANGEI. 3 UL INFECTION .0* 5 MIN 2 '/MIN TO 2 10" IT SPEED 0.1 CM/MIN tAeiA>oc< hiar\^ 0.iL./\mU :N: 128 ZERO: 12SS 5 riN/TICK tT : INJEC E: AROCLORS 17:25 23 MAR NEL NO: 1 SAMPLE: MTH BLK . IL METHOD: HERBS PEAK RESULT TIME AREA SEP NAME UG/ML (MIN) COUNTS CODE FLIER: 1.00000 SP-2100 100/120 SLPELCOPCRT Ul 60, RANGEI. 3 UL INwECTIQN I* 5 MIN 2'/MIN TO 210 • ' SPEED 0.1 CM/MIN 4: 12Q ZERO: 12?« rIN/TICK r :INJEC .2J56 12.506 E: AROCLORS 9:19 24 MAR NEL NO: 1 SAMPLE: STD 2...4..5 METHOD: HERBS PEAK RESULT TIME AREA SEP NAME UG/ML (MIN) COUNTS CODE SILVEX ME 33.39S4 7 .256 781499 BV 66.6006 g .326 1558360 VV LS: 100.0000 2339860 IFLIER: 1.00000 SP-2J00 100/120 SLPELCOPCRT OU 60> RANGEI. 3 UL INFECTION a* 5 MIN 2'/MIN TO 210" • 'T SPEED d.1 CM/MIN Sfei :N: 128 ZERO: 12% 5 riN/TICK >T : INJECT •* • 11 Cl • If Ifl tl -trim II- Mil* LE: AROCLORS 9:37 24 MAR iNNEL NO: 1 SAMPLE 4, .5 METHOD: HERBS iK PEAK RESULT TIME AREA SEP NAME UG/ML (MIN) COUNTS CODE 1 7.01=2 2.117 246295 BV 2 5.7350 532 201374 VB 3 2O.38E0 120 7 15386 VV 4 SILVEX ME 22.6267 260 79-^009 '^^' 5 . 44.22S2 338 1551800 VV <^.W /o "ALS 100.0000 35OEI860 TIFLIEP: 1.00000 "ES: % SP-2100 100/120 SLPELCOPCRT LOW 60. RANGE 1 3 LL INJ. 160* 5 MIN 2'/MIN TO 2 10" MRT SPEED 0.1 CM/MIN TEN: 126 ZERO: 12% riN/TICK ^oHod Wa^i^ O.i^l^^L TAT :INJEC TLE: AROCLORS 9 :5& 24 MAR CiNNEL NO: 1. SAMPLE: MTH BLK .1 L METHOD: HERBS AK PEAK RESULT TIME AREA SEP C NAME UG/ML (MIN) COUNTS CODE 1 7.6729 2.094 147715 BB 2 14.0952 2.503 271395 BB , 3 245-T ME E 72.6722 £.305 1396870 VV <2fl.« A 4 5.5S47 12.074 106922 VV TALS: 100.0000 192*^900 LTIFHER: 1.00000 TES: ;.% SP-2100 100/120 SLPELCOPCRT f l ni.i cn . scKir:? i . t i i TNJ . ^T :INJEC a.299 10.141 LE: AROCLORS 10:12 24 MAR NNEL NO: 1 SAMPLE: 0690 TCLP.IL METHOD: HERBS K PEAK RESULT TIME AREA SEP NAME UG/ML (MIN) COUNTS CODE I 10.5545 2 .099 190507 2 245-T ME E 82.4557 6 .299 1488940 VV ^'^.*i/« 3 6. 9859 1 1 . 130 126218 VV ALS: 100.0000 1805740 TIFLIER: 1.00000 ES: 5» SP-2100 100/120 SLPELCOPCRT LOW 60. RANGE 1: 3 LL INJ. 60" 5 MIN 2 '/MIN TO 2 10" iRT SPEED 0. 1 CM/MIN lEN: 126 ZERO: 12% 5 riN/TICK qv/-oo^O euT .vu/l l^^ iAT :INJECT" 2.543 TLE: AROCLORS 10 :3Q 24 MAR 'I •• i^iNNEL NO: I SAMPLE: 0290 ELT . IL METHOD: HERBS f^iK PEAK RESULT TIME AREA SEP C NAME UG/ML (MIN) COUNTS CODE I 13.4147 2.111 252008 BB 2 24.4837 2.543 459950 BB o 3 245-T ME E 62.1016 6.315 1 166640 BV IM.q /. 1a7AAfla ES: '< SP-2100 100/120 SLPELCOPCRT .OW 60. RANGE 1: 3 LL INJ. 50* 5 MIN 2 '/MIN TO 2 10" c^' (XRO Sl-f ^>.)^/^ 1^^ ?T SPEED 0.1 CM/MIN zN: 126 ZERO: 12% 5 riN/TICK ^T : INJECT" 8. 326 17.497 .E: AROCLORS 10:45 2 4 rii->.? >INEL NO: 1 SAMPLE: 0290 SLP . IL METHOD: HERBS ( PEAK RESULT TIME AREA SEP NAME UG/ML (MIN) COUNTS CODE a I 245-T ME E 85.2325 6 .326 1 135920 BV-^1. <:s :SP-210 0 100/120 SLPELCOPCRT .OW 60. RANGE 1: 3 LL INJ. i0» 5 MIN 2VMIN TO 210 q^ •oo^O Or\S 0.vu/\ W.O ;T SPEED 0.1 CM/MIN £N: 128 ZERO: 12% riN/TICK ^T : INJECT" aouu u a.M.'^-T 5 n In 2 '/ II It-i TO 2 10 LC E: AROCLORS 1 1 :06 2 4 MAR '= i- OOPOTCLf tr\S '*»\^ IFLIER 1 .000Q(] 3: SP-2100 100/120 SLPELCOPCRT 3W 60. RANGE 1: 3 LL INJ. a- 5 MIN 2 '/MIN TO 2 10" qy-ooRo («<.D <5.ic/im(_ T SPEED 0.1 CM/MIN M: 126 ZERO: 12% 5 riN/TICK T :INJEC ;: AROCLORS 11:22 24 MAR lEL NO: 1 SAMPLE: 0e90TCLP MSD METHOD: HERBS PEAK RESULT TIME AREA SEP NAME UG/ML tMIN) COUNTS CODE _.9. 5114 2. 120 303971 VV , 11.3325 2.552 362170 2,4-D ME E 18.0756 5. 122 577669 VV l.bl -> *?-^ . SILVEX ME 20.1221 7.241 643070 vv0.'biw-><4l.o /» 245-T ME E 37.6825 E.321 120<-31O VV '^-^. 1 '/o 3.2748 12.163 10*.657 VV IFLIER: 1 .00000 :S: SP-2100 100/120 SLPELCOPCRT OW 60. RANGE 1: 3 LL INJ. 0* 5 MIN 2VMIt4 TO 210* qH-ooa t -rO-P 0.i«-/\ mL. T SPEED 0.1 CM/MIN N: 128 ZERO: 12% 5 riN/TICK iT : INJECT 9.30S E: HERBICIDES 11:39 24 MAR 'i »• INEL NO: 1 SAMPLE: 0e91TCLP .IL METHOD: HERBS PEAK RESULT TIME AREA SEP NAME UG/ML (MIN) COUNTS CODE 1..53i9 2.104 175346 VB , 245-T ME E 81.8109 £.305 1243210 VV'^*^.**/<» 6.6503 11.112 101058 VV tLS: 100.0000 1519610 IFLIER: 1.00000 ;s: ; SP-2100 100/120-SLPELCOPCRT OW 60. RANGE 1. 3 LL INJ. ,0" 5 MIN 2 '/MIN TO 210- qM-oo^< SLT o.ii^/^ ^ ^ :T SPEED 0.1 CM/MIN IN: 128 ZERO: 12% 5 riN/TICK »T : INJECT— 10. 152 I Q ITO LE: HERBICIDES 11:55 24 MA= NNEL NO: 1 SAMPLE: 029 1 ELT IL METHOD: HERBS. PEAK RESULT TIME AREA SEP . NAME UG/ML (MIN) COUNTS CODE 1 9.5558 2 .096 213140 VV 2 12 5972 2 .532 280859 '^B „^ , 3 ;4S-T ME E 50 5057 £ .228 1 30<-410 VV %^.-\ /a 3373 15. 179 4 19 431 13 1 VB ALS; 100.0000 2229540 TIFL lER: I .00000 ES: % SP-2100 100/120 SLPELCOPCRT LOW 60. RANGE 1. 3 LL INJ. 60 - 5 MIN 2 -/MIM TO 2 10" qV-CO ^u«> 0-"-/l '-' iRT SPEED 0. 1 CM/MIN EN: 126 ZERO: 12% 5 riN/TICK AT : INJECT" t:lk^ 174 10.240 12,385 LE: HERBICIDES 12:25 24 MA!? iNNEL NO : 1 SAMPLE: 029 1 SLP .I L METHOD: HERBS iK PEAK RESULT TIME AREA SEP NAME UG/ML (MIN) COUNTS CODE I 15.6779 2 .093 306484 BB 2 245-T ME E 77.4045 £.274 1523040 VV R?.>/'o 3 6.9177 11.110 1361 15 VV iALS: 100.0000 1967640 TIFLIER: 1.00000 ES: % SP-2100 100/120 SLPELCOPCRT LOW 60. RANGE 1: 3 LL INJ. 60- 5 MIN 2VMIN TO 210 (^-ocy^X'^^^ o.\u/^i^t^ iRT SPEED 0. 1 CM/MIN EN: 126 ZERO: 12% 5 rIN/TICK AT :INJECT^: TTT 06 1 432 Jl 3.320 10.280 ^''411 9 . 148 LE: HERBICIDES 12 : 4^ 2 4 ;1A.? •: NNEL NO: 1 SAMPLE: 0e92TCLP . L METHOD: HERBS :< PEAK RESULT TIME AREA SEP NAME UG/ML (MIN) COUNTS CODE I 10.062 5 2.118 265870 VV 2 9.7443 2 .557 257437 VB 3 245-T ME E 55.71E4 £ .320 1472040 VV <^M.*5 /• 4 4.9964 1 1 . 182 13 2 002 VV 5 10.8525 12.532 286715 VV 3 8.6249 15.148 227865 VB ^LS: 100.0000 2641930 riFLIER: 1.00000 IS: < SP-2100 100/120 SLPELCOPCRT .OW 60. RANGE 1: 3 LL INJ. iO- 5 MIN 2'/MIN TO 2 10 Ly !T SPEED 0.1 CM/MIN OfM-00^1. €X.-r o.»»-/l \i*\ •N: 128 ZERO: 12% 5 riN/TICK «T : INJECT"' 2.542 8.563 11. 177 12.524 NAME UG/ML (MIN) COUNTS CODE 7.5258 2.117 172732 BB 14.9155 2 .542 342339 BB ^ ^ • Z45-T ME E 67.4007 €.563 1546970 BV V.I) / * 5.6052 11.177 128741 VV 4.54E9 12.133 10'-405 VV >LS: 100.OOOO 2295190 IFLIER: 1.00000 S: SP-2100 100/120 SLPELCOPCRT OW 60. RANGE 1: 3 LL INJ. 0- 5 MIN 2 -/MIN TO 2 10" T SPEED 0.1 CM/MIN ^^ 00^1- ^L-P 0.'^/' v»-iO Hi 128 ZERO: 12% 5 MN/TICK T : INJECT" 2.547 5.551 2 371 3.5 14 I: HERBICIDES 14:00 24 MAR "i «• ^lEL NO: 1 SAMPLE: 0292 SLP .IL METHOD: HERBS PEAK RESULT TIME AREA SEP NAME UG/ML (MIN) COUNTS CODE 11.3177 2.119 289459 BB 21.7907 2.547 557313 BB ^a 245-T ME E 62.0759. £.514 1587630 BvlOI-T/-* 4.8156 11.198 123162 VV S: 99.9959 2557560 FLIER: 1.00000 SP-2100 100/120 SLPELCOPCRT W 60> RANGE 1: 3 LL INJ. :• 5 MIN 2VMIN TO 210 O.a^jJ,^ S;iv4>^ SPEED 0.1 CM/MIN I •5Q •ycDfi . 1 •^^^ 6.653 .E: HERBICIDES 14:19 24 MAR 'IFLlER: 1.00000 IS: i SP-2100 100/120 SLPELCOPCRT .OW 60. RANGE 1: 3 LL IMJ. iO- 5 MIN 2 '/MIN TO 2 10" bOlUS NV ?T SPEED 0.1 CM/MIN £N: 128 ZERO: 12% 5 riN/TICK •^T : INJECT— .E: HERBICIDES 14:36 24 MAR >INEL NO: 1 SAMPLE: STD 2, . 4, . 5 METHOD: HERBS < PEAK RESULT TIME AREA SEP NAME UG/ML (MINJ COUNTS CODE I 10.0222 0.484 1012370 BB 2 2.4-D ME E 23.0100 5 .035 232^300 VV 3 SILVEX ME 30.5025 7.292 3081250 VV 4 S45-T ME E 36.4643 E.355 3683370 VV :TES: 2% SP-2100 100/120 SLPELCOPCRT FLOW 60. RANGE 1. 3 LL INJ. 160- 5 MIN 2VMIN TO 210 ^ART SPEED 0.1 CM/MIN TTEN: 128 ZERO: 12% r IN/TICK y\U, h\0^^ 1.0aA^^^ .TTAT : INJECT TLE: HERBICIDES 14:5^ 24 MHIR 1ANNEL NO: 1 SAMPLE: MTH BLK METHOD: HERBS ;AK PEAK RESULT TIME AREA SEP IC NAME UG/ML (MIN) COUNTS CODE VV \0\. LTIFLIER: 1.00000 TES: :•% SP-2100 100/120 SLPELCOPCRT FLOW 60. RANGE 1: 3 LL INJ. 160- 5 MIN 2'/MIN TO 2 10 !ART SPEED 0. 1 CM/MIN TEN: 128 ZERO: 12% 5 riN/TICK q^'0Q90 ^.o«/3ivnt. .TAT : INJECT" i;°5-i^ :i. :' 16.206 .E: HERBICIDES 15:15 24 MAP •; )NEL NO: 1 SAMPLE: 54-0090 SOIL METHOD: HERBS PEAK RESULT TIME AREA SEP NAME UG/ML (MIN) COUNTS CODE , i 245-T ME E 100.0000 £.376 3876060 VV [Of\.\ / a ^LS: 100.0000 3876060 'IFLIER: 1.00000 "S: i SP-2100 100/120 SLPELCOPCRT -OW 60. RANGE 1: 3 LL INJ. .0- 5 MIN 2 -/MIN TO 2 10" T SPEED 0.1 CM/MIN ^ . ^^^ 1 .0 11.02 1 12.601 -E? HERBICIDES 15:36 24 MAR 4NEL NO: 1 SAMPLE: 54-0091 SOIL METHOD: HERBS : PEAK RESULT TIME AREA SEP NAME UG/ML (MIN) COUNTS CODE ^^ •. 1 a45-T ME E 100.0000 6 .346 4030260 ^LS: 100.0000 4030260 riFLIER: 1.00000 £S: i SP-2100 100/120 SLPELCOPCRT .OU 60> RANGE 1: 3 LL INJ. iO- 5 MIN 2VMIN TO 210 «\ _ 11.122 a12.820 E: HERBICIDES 15:53 24 MAR NEL NO: I SAMPLE: 5 4-0092 SOIL METHOD: HERBS PEAK RESULT TIME AREA SEP NAME UG/ML (MIN) COUNTS CODE o 3565070 VV qV,."J /» 245-T ME E 100.0000 £.305 LSI 100.0000 3565070 IFL lER: 1 .00000 SP-2100 100/120 SLPELCOPCRT OW 60. RANGE I: 3 LL INJ. 0" 5 MIN 2 '/MIN TO 2 10" T SPEED 0.1 CM/MIN 9M-0(y?o ^s. 3i.o^/a».vi- N: 126 ZERO: 12% 5 riN/TICK \ T :INJECT ;b3 11.182 HOyiL 0^ a,V-ti IOO fp ^ 12.382 >uL 14,715 0 ^ C,'l\yti6. rr E: HERBICIDES 16:07 24 MAR HEL NO: 1 SAMPLE: 54-009 0 MS METHOD: HERBS PEAK RESULT TIME AREA SEP NAME UG/ML (MIN) COUNTS CODE \0'5.T /• 2.4-D ME E 23.7518 4.971 2452590 VV ;i.U ^ ,,, ^ y . SILVEX ME 33.3358 7.260 3442230 VV (J.MH^-^ \\\ .? I " 245-T ME E 42.9 124 £.232 4431110 VV \ao.b /" S: 100.0000 10325900 IFLIER: 1.00000 Itl 3 run i •.-• II if'i ro i I j JT SPEED 0.1 CM/MIN •IN: 128 ZERO: 12% 5 riN/TICK 9^'0090 ^^ ^ ^T : INJECT" :7b i;;. 9 46 .£: HERBICIDES 16:25 24 I1,^R ^NEL NO: 1 SAMPLE: 54-0090 MSD METHOD: HERBS : PEAK RESULT TIME AREA SEP NAME UG/ML (MIN) COUNTS CODE 1 2.4-D ME E 2 3.3 95 7 4. 989 2 12 6 9 8 0 VV l.^'b I SILVEX ME 33.4713 7 .276 3045320 VV 0.^9'r-^*? IFLIER: 1.00000 i SP-2100 100/120 SLPELCOPCRT .OW 60. RANGE 1: 3 LL INJ. iO- 5 MIN 2VMIN TO 210 fu^ Sid ^^f-o ?T SPEED 0.1 CM/MIN -:N: 128 ZERO: 12% 5 rIN/TICK fl ^T : INJECT" 5. 108 293 12.942 14.435 [Z- : HERBICIDES 16:25 2 4 ;1.^R EL NO: 1 SAMPLE: 54-0090 MSD METHOD: HERBS PEAK RESULT TIME AREA SEP NAME UG/ML (MIN) COUNTS CODE qi.^^ 2.4-D ME E 23. 3957 4.989 2 126980 VV \l'i^ ^ _ SILVEX ME 3 3 47 13 7 .27 6 3 045320 VV ^.'^^•^^9H.% /^ 245-T ME E 43 1250 £ .29 8 392*-000 VV lOlo."^ /* SJ 100.0000 9090300 FLlER: 1.00000 SP-2100 100/120 SLPELCOPCRT W 60. RANGE 1 3 LL INJ. - 5 niN 2 -/MIN TO 2 10" IU 8. 556 10.420 •12, 942 14.435 C .: HERBICIDES 16:4^ 24 MAR 'i '• lEL NO: 1 SAMPLE: REF STD METHOD: HERBS PEAK RESULT TIME AREA SEP NAME UG/ML (MIN) COUNTS CODE 50.8244 0.472 1932690 2.4-D ME E 27.9413 5. 108 1062520 Bvo.^w^'^?!.'* <; SILVEX ME 21.2343 7.293 807473 VV o.lo'^-^\D.*r ^» S: 10Q.0000 3802680 FLIER: 1.00000 SP-2100 100/120 SLPELCOPCRT W 60. RANGE 1: 3 LL INJ. STD SAMPLE DATE ANALYST FILENAME SAMPLE ID MATRIX CONC. DILUTION MTH SI DID REMARKS Q.n-'iH rr^tV nn ^c.-.e\,rt.^\K fcafcrU/C \ 1 feLrtNK fjLrtNK \v o.'i<:-'1^l I f btAMK C)LrtHVC Aenia^)?? <1W00C«0 EtT 1'1-QryjiO ^u T ,•7 It » IM / IH nQ'il ft T 9^ooQ/ ELT 0 iL ^ !«' aW-oo«fJ>-euT 9^/00.12 EUT Oil -» 1 ..,1. /;ife2 /o.vm ^to^top ia/,2 1.0 np'h f-^b ^ If"- '' " ft ^H-ao'io .ILP O.-L * l^V \ '/-I-00^1 'JLP •?4 0Oi) 6LP OIL » l^\ Ij.aL, -fH •^.9 . 'IH 00=(A 5t^ ^^ OOIP .^LP OU •ifo ^ 'W.nn:»n Hxlfl, ^V oa?r) T/L P O.U'»\«\ '»*<-oo^i r^ vf Vl-a^l JLP o^\. •»i.«l (fV-rTOt^l e^T«. 'f'i -oo^l TdL p O.IL »»^»l. •. WH oo'ia 6 Ijma s.o »P<»> >^AoaoA iJ< ai.2 /o ypM KttOaoii iat2 \ P-IL, biH to ri;^ iJ**^ i.On/i,T^ ; ' 1. OO'W 1 TOO qn oo<^o 6 on<^l, »:«^ 'Jf-oooii 5 oo«ia. / /o niw^; ftLrtNK ^ 6Lft^h^ AROlSMS . /3t1. ro ff.n /11101.3^2 ^ Otp\n f-iu. F<^f*'r Jf^iy^ If' f^MO. i.a^o n.\-HH Kv\u) t\Lft(VH< (^LANK tifidCLofyj \2Hl I.Ofi^n AurjtLod. MV.1 /. f> //^n » r-^^? V '^^ L*^^ ' la'O.a.o /AH t y 7 0 /'/:>»n \ . ,. ij \ 1 ^ i^HL^^f^ V il_ k ^«P ZftK'^V EAK ff' ' RESULT TIME AREA SEP ^/ NC ' NAME UG/ML CMIN) COUNTS CODE -t:- 1 25.5721 0.436 2092370 BV 2 31.5B06 0.675 2583990 VV r.- 3 17. 1810 4.212 1405790 BB 4 25.6664 36.791 2 100080 BB 1^ ALS: 100.0000 6182230 MLLTIFLIER: 1.00000 NCTES: :% SP-2100 100/120 SLPELCOPCRT T'LOW 60> RANGEI > 3 UL INwECTION CHART SPEED 0.1 CM/MIN ATTEN: 12£i ZERO: 12% 5 riN/TICK "3TAT : INJECT"^ 0) r T6.604 8 36.73' "^9 o tt t* aS pe^ "^'Z prnLE: AROCLORS 17 :0£: l^pH^iNNEL NO: 1 SAMPLE: BLANK METHOD: AR01248 u S'EffK PEAK. RESULT TIME AREA SI:P NIC NAME UG/ML (MIN) COUNTS CODE tt 1 23.9829 0.431 1821030 BV a •5 32.9674 0.667 2503120 VV "3a.HA^-c^ii''"-'>'i»«**-«' 16 1546 4.216 1226570 BI) 8941 36 .794 2041990 BE) 4'tCccajorvbi(iWtrw| 2 6 7592710 p 1ALS: Too. 0000 M KDLL TIFLlER 1.00000 w TES: :% £;P-2 100 100/120 SLPELCOPCRT TLOW 60. RANGEI, 3 X UL IN..ECTION n • a N I JjJ^TAT : INJECT 3o . 2 a5'--<=^6''^ TITLE. AROCLORS 20 :3- 1^-^ CHhiNNEL NCi : ] SAMPLE: 126£ 1.0 PPM METHOD: h-R01248 PEHI: PEAf RESULT TIME AREA SEF NL NAMi; UG "ML (MINI COUNTS COIE 1 10.06=7 &. 44 1 1220240 BV "j 19.09c7 Gl. 6 7 7 231-120 VV (S) 3 2 f) . 6 D = 9 31 .904 3473710 Bi) 0) 4 1C3. 8 7 E 6 32.997 1316!250 Bf) 3 . 28=2 3= .273 3791590 BB 1m ' ;: lOO.OOC-iQ 12117900 fj-CTALS P TlFLlEf: ] . O000t) 'e^lCTEB: i ': i :.P-2lOG lQO'i;:0 SLPELCOPCRT 5" fiDUl 6Q, Ri-it-IGEl. 3 UL IH.ECIION a ^ O tt 2 o ,»J;HI-IPT SPEI:D O.I cn-MiN I^TTEN: 12£: ZERO: 12% 5 r I I-l ' T I c i: 0> -if..; c VR p_ O "O tt a ^§ F£(i> ^^9 u^ 1 > . £ O 1 I 2 18. 5726 ,521 2416310 VB 3 8. 0352 487 1045390 4 12. 56E8 4 ,214 16352 10 BB !«.*» yt. 5 20, 5617 36 732 2675100 BB l^l.o5'.• Tf-TALS; 100.0000 13Q1Q1O0 MLL TIFLIER: 1 .00000 ERPORS: ADC OVERANGE NCTES: 3% c;p_2)00 100/120 SLPELCOPCRT TLOW 60. RANGEI. 3 UL INFECTION CHf^iRT SPEED 0.1 CM/MIN ATTEN: 12£; ZERO: 12% 5 r IN/TICK ,r-i:TMT : INJECT"' =g" •' cn .^ O z o 5 o tt jpf FE6 '^V •^ITLE: AROCLCiFS -:>i III -:; M (•> 1 •iinriPL E: r4-C"0? 1 tIETHOD: MRr:il24i OCHhiNNEL NCi OB •gPE.Mi; F!E5ULT 1 irlE AF' E M 5i;p Q. MC UG 'ML 1 HI 11 i CCiiJl-ITS COE'E 2\i . 1710 : .433 1 3 7 ^. 3 S 0 Itl :9t 7 •1.2 0:' 1 4 3 t. 7 7 Q o 3t.746 2651560 Bi; \i.^J\ A tt 40. 53CI3 frCTALE: 5463710 100.0O&O M t3lLL TIFL lEP : 1 . OOOOO -NCTES: c o^ '•% =.P-2)00 100-120 SLPELCOPCRT FLOW 60. RHHGEI'. 3 UL INFECTION wa 1 £>• S • ^ ll/ I i U rs. t^TAT : INJECT 9S f^^ '^^ THLE : AROCLORS 0:13 JQ-rrt=rA CHMNNEL NO: 1 SJAMPLE: =4-Ei092 5LP METHOD: AR01243 PEMI; PEAK F!ESULT TIME AREA SEP MC NI=IME; UG 'ML (MINI COUNTS CODE , 1 3 fi . 6 7 £ 1 •1.215 1285800 BE) iC>*.l / ' (5) 2 6 4.321? 3c -! --> i 23 1£!09 0 (A CTCTALS.: lOC^. OOC-iO 3603890 giLL TIFL lEF' OOOOO =-TE5: % =:p-2 I OQ 100 ' i::o SL PELCOPCRT f LOl'l 1=0 • RHNUE 1 . 3 UL IN-EC!ION 9 3 O tt ^HMPT SPELD 0.1 C n ' MIN ^TIEN: 12c: ZERO: 12*< 5 r-III'TMi: ~:i «T I N J E L N> j_i4— w 05— 00 a tt Z M I M O gi^ f=^£> PW TS oFITLE: .AROCLORS 0:57 8—T-r-i •: ;• ri-Ui;iUE L NO : 1 ;_MDi r 1 'I o J M^THO' i : _.c> ri 1 0 J. •:• cn 3 44.6361 36.719 2042810 BB lOO.O r> .TCTALS: 100.0000 4576580 MLLTIFLIER: 1.00000 'ES: i% SP-2100 100/120 SLPELCOPCRT FLOW 60> RANGEI. 3 UL IN..ECTION CHART SPEED 0.1 CM/MIN ATTEN: 128 ZERO: 12% 5 riN/TICK "ETTAT : INJECT ^ ^ ^ 8.655 CD ;6 . 780 PO oz o .H*v«l si/ H^l'^-^" '.^IlLE: AROCLORS 18:3 g., ji'iM i: ;• )> CH^INNEL NO: 1 SAMPLE: METHOD: ARCI1248 O r^EnK PEAK FJESULT 1 IME AtEA SEP Z NC NAME UG/ML fMlN> COUNTS CCiDE^ V P 1 3 9.99=8 2 .494 1 3 7J.960 BE) 112.2-7'' 60.0042 3£.780 206^300 Bi) lOl.t /o M 0)rCTAL=:: 100.0000 3440260 0 5.MLL TIFL lER 1.00000 _NCrES; :% SP-2)00 100/120 SLPELCOPCRT FLOW 60. RANGEI.'3 UL IN.ECTION z o O X -?T SPEED 0. 1 CM/MIN (TEN: 12£i ZERO: 12% 5 riN/TICK TnAT : INJECT .-0.5 30 13.489 tc,K '.^^d.zA :^ i'^i^^ •" TITLE: AROCLORS 19: IJ: 3 Jr.. CHANNEL NO: 1 SAMPLE: g 1 QOi? 1 n J 3L METHOD: h^RO 124:3 PEHK PEAK RESULT TIME MPEA SEP NC NAME UG/ML ( M 1 N < COUNTS CODE 1 4. 39£5 : . 434 5 6 5 3 6 2 VV "3 :. . 35&6 2 . 326 173604 VV 3 2.3126 •1.212 1 5 8:: 600 v\' lat 4 ;. . 475 3 5.019 13 9627 • /•• 5 1.1163 5 .756 143483 V.' t> 3. 177 1 c .376 4Q&37 1 VV 7 2.0419 " . 834 262449 VV 3 :. . 15 46 £ . 993 14£!409 V,' 9 ;. . 8 3 3 2 = .613 2 3 =. 6 3 2 •••/•: ' ,530 (5) )Q '' . 1 "* = 2 IGi 2 7 :•: 6 7 3 ••/': ' ,6 15 W 1 1 ii! 6 9Gii 1 1 73)473 ••/•:• C 12 4. 38=6 13 489 56-213 VV :.' . 9 7 1 8 1 -1 6 13 33)975 VV :;. 3 42 7 lc 57 D 4 2 =1 7 3 2 V\' 8 '5 3.2918 1 7 426 42 3 1 15 VV 1 = 522 755.639 VV ] o Ji . 8 7 £ 9 ... 13 3 9 •5 327 1 5 ;: I b 9 VV Z 17 •5 p 13 i] 4 lCi3 532 I 031010 VV 19 Q5t2 —t C <- 270 3 9 3086 y.' ;o 7 04 5 3 1 904 3 6 17 6 0 V'.' ; 1 63 15 3 J 35 1 730274 VV IE) 40=5 3 t: 30" 236^.740 BV ifS 3 5rri .^f 9 ?) . 9 9 = 9 12 35-:500 5 f^LL TIFL lEF' : I . OOOOO tt HNICTES: f ':% :,P-2 100 100'120 SLP ELC 0 P C R T 1^ FLOW 60. RMNGEI. 3 UL I N> EC! ION I M W O) OD 'S" tt o. o tt ' 5:HMRT SPEED O.J -CM/MIN yiTTEN: 12£: ZERO: 12% 5 rI N 'TICK •(J-TTAT : INJECT"' J w r s.oci V^7 . 9 3 3 ] 1 :, •'I 6 . 648 19.6 37 22.382 3-)- 905 ^?). 3bS 32.405 -' 38.!)45 afe fBb °t^} TITLE: AROCLORS 20:08 •NNEL NO: 1 SAMPLE: S4-0092 EXTR METHOD: AR01248 i:.AK PEAK RESULT TIME . AREA SEP NC NAME UG/ML (MIN) COUNTS CODE 1 8.3 144 0.532 121^^060 VV 2 4.5663 2 .509 666758 VV 3 2.2906 2 .782 33^468 VV 4 1 . 16S9 2 .357 170826 VV 5 10.0170 4.246 1462660 VVlKf.Z/' 6 1.3978 5 .066 20^098 vv 7 0.9523 5 .841 139196 VV . 8 1.557 0 379 227354 VV 9 0.7922 046 1 15827 VV 10 0.9542 833 139328 VV 1 1 0.9002 325 13 1446 VV 12 0.9446 130 137922 VV 13 ..9606 S .763 286284 VV 14 32.7727 11.769 4785410 VV 15 3.4173 22.675 498986 VV 16 1.9700 25.906 287649 VV 17 1.6019 2E.368 233904 VV 1 8 6 9012 32.405 1007700 VV 1 9 16 6249 3€ .929 2427540 BV ll«. JCTES: % =;P-2]00 100/120 SLPELCOPCRT LOW 60 . RANGE 1 . 3 UL INFECTION o 3 o tt r Z:HI:IRT SPEED 0.1 CM/MIN PATTEN: i2£: ZERO: 12% 5 riN/TlCK •)*~H:TAT : INJEC s o • o X •9 tt ^ITLE: AROCLORS 20:58 ti JHN •: .. " CHf^iNNEL NO: 1 SAMPLE: 1242 3.0 PPM METHOD: ARO1248 cn a 3.2748 7 .455 546160 VV 00 9 8.0452 E .705 )C 1342440 10 7.2355 c . 190 JC 1207390 VV ; -T^'^BU 1 1 4.446 1 10 .728 741521 12 3.7967 1 1.580 633209 vvSftV 13 5.03E0 12 . 150 84Q232 VV ^ 14 7.6444 12 .955 Y127^930 VV ; 15 4.5766 14 .975 763274 VV y 16 1.8114 15 .673 302101 VV 17 2. 1230 17 .281 35^080 VV 18 2.5269 17 .903 421769 VV 19 1.9757 15 .844 329498 VV 20 1.731 1 21 .487 28B706 VV 2 1 0.9347 22 .465 155895 VV 22 5. 1754 32 .939 863141 VV VV TCTALS: 100.0000 16677900 MLLTIFLIEF 1.00000 NCTES: 3% SP-2 100 100/1 30 SLPELCOPCRT FLOW 60. RANGEI> 3 UL INwECTION (5) (A C SH^IRT SPEED 0. 1 CM/MIN BTTEN: 12E: ZERO: 12% 5 riN/TICK CTH'TAT : IN 3^ o tt M I fO W 0> GB B I f f^0> ^v s "THLE : AROCLORS 21 :43 o SAMPLE: 0691 SLP MS METHOD: AR01248 SCHf^iNNEL NO: 1 Z RESULT TIME AREA ppEi^iK PEAK: UG/ML (MIN^ COUNTS M NC NAME 9. 17E6 2 .473 235^860 M 1 1.5315 3 . 329 392917 w , 9 13 1 <1 . 2 0 1 1517070 ."? /' •J 50=8 4.699 - 3 4.17 i 5.191 130801 ff 4 795 1 5 .776 620141 5 96E7 € 707 203994 6 587 1 7 393 761655 7 4269 641 663744 E »'1392830 S 8 21 12 c 136 •e 9 7312 684 Ji 1336990 It 3.32 = )'0.-7 % Uc. g. 10 5373 10 5 17 957285 a. 11 1 1 907542 D 18 ^. /a 74 1 7 ' i-:n 1 Xi 1 n'*f u "* 19 2.3020 21 .421 590857 VV 2 0 0.5609 22 .350 143893 VV 2 1 4.1873 22 .541 107^280 VV 22 2.2822 24 .917 585782 VV VV 23 1.04E2 27 .718 268914 '4 1.B355 2£ .240 470916 VV VV D 2.2512 31 .856 577564 VV - 6 5.403 4 32 .204 1386290 27 2.7246 32 .770 699028 VV BV ll|.'> /' 2 8 8.8706 36 .812 2275850 T 29 1.36E9 35 .452 350698 TCTALS 99.9959 25656000 MLLTIFLIER: 1.00000 NCTES: 3% SP-2100 100/120 SLPELCOPCRT FLOW 60> RANGEI> 3 UL INFECTION eCHART SPEED 0. 1 CM/MIN S^TTEN: 12£! ZERO: 12% 5 riN/TICK m >TAT : INJEC L -9 5.216 8.682 U.5 fi2 3.937 3 . 290 31' . 9 2 3 ^ > ^^_^'' .-, 's . f t3f o ? z p M M W 0> OB «^ « a• O STITLE: AROCLORS _ 22:3 1 8 JAH i: :i z PCH(:iNNEL . NO : 1 SAMPLE: eG91 SLP METHOD: AR01248 M KPEAK F>EAK RESULT TIME AREA SEP " NC hVIAME UG/ML (MIN) COUNTS CODE - 1 9, 16E4 2 . 494 2522380 VV : .59E0 3 .355 439627 VV 5.8 155 4.224 1599950 VV l'>>C>.M li f" 4i 0.5259 4.726 145787 VV k 5 2.44 18 5 .216 671766 VV 0.8176 5 .802 22'-946 VV L 6 820148 VV ^ ^ 2.981 1 6 .735 a 8 2.5773 7 .422 709057 VV t 9 5.4247 E .682 14924 10 VV 10 5.0553 = . 173 1390800 VV ) 1 3.6146 1&.728 99-^439 VV \.t* .iCALC ^ f£e> ^v TITLE: AROCLORS 22 :31 =&-3TfN !: -T CHANNEL NO: 1 SAMPLE: 0e91 SLP MS D METHOD: AR01248 PEAK PEAK RESULT TIME AREA SEP ^C NAME UG/ML (MIN) COUNTS CODE 1 9. 16E4 2.494 2522380 VV 2 -.5960 2 .355 439627 VV 3 5.8155 4.224 1599950 VV |3^.S >, 4 0.5259 4.726 145787 VV 5 2.4418 5 .216 671766 VV 6 0.8176 5 .802 22^946 VV 7 2.981 1 e.735 820148 VV 8 2.5773 7 .422 709057 VV 9 5.4247 E .682 * 1492410 VV ; 10 5.0553 5 . 173 K 1390800 VV / 1 1 3.6146 10.728 99-^439 VV S -Z^^'l^n 1m^^o i^c, 12 3.4752 11.562 956082 VV / 13 4.3255 12.131 1 191 1 10 VV ) 14 5.6277 13.937 y- 1548270 VV / 15 5. 17 7 4 14.966 142^390 VV ^ 16 ..9254 17.276 530802 VV (A 1 7 2.4546 17.888 675308 VV C 1 8 2.4857 15.812 68^945 VV m 19 2.02E2 21.485 557990 VV O 20 0.5070 22.422 139497 VV 2 1 3.7155 23.601 1022 190 VV P 2 2 ..8958 2 4.963 5 2 2 6 7 0 VV z 2 3 0.7965 27.793 219140 VV 2 4 - .31 15 2£.297 360804 VV 25 6. 18 6 3 33.290 1701960 VV M 2 6 ..92E7 33.876 5 306 11 VE) A 7 2 7 f). 2208 3 e . 9 2 3 226)670 BV 1(0.4 /• 3 2 8 7.8979 3=.464 2 172830 T 5 n ALE.: 9 ?i . 9 9 = 9 27511600 S^ . L TIFL IEF' : 1 . 00000 ZJCTE5: p 3% =;P-21O0 100/120 SLPELCOPCRT M FLOW 60. RANGEI . 3 UL IN.ECTIO N M W o> 6"CO tt ZIHART SPEED 0. 1 CM/MIN ft^TTEN: 12E: ZERO: 12% 5 riN/TICK g3TAT :lNJECT-^=f=^, — O "O |1;L'I=^5HI:tt ' 39.446 ITLE: AROCLORS 16:0; IB jnM -IZ. CHANNEL NO: 1 SAMPLE: BLANK METHOD: ARO1248 PEAK PEAK RESULT TIME AREA SEP NC NAME UG/ML (MIN) COUNTS CODE 1 20.2059 0.433 1739870 VV 2 30.2867 0.671 2607380 VV 3 2.4107 2 .501 207535 VV 4 18.5406 4.230 1596160 VV 5 18.5356 16.552 1595730 VV 6 10.0166 22.995 862326 VV TCTAL S: 100.0000 8609000 MLLTIFLIER: 1 . OOOOO ERF ORE-: FEAK STORAGE FULL (ftCTES: CO 3% =;P-2100 100/120 SLPELCOPCRT C FLOW 60. RANGEI. 3 UL INFECTION m v O o ^HART SPEED 0.1 CM/MIN g^TTEN: 12£: ZERO: 12% 5 riN/TICK ,*~rTAT : INJECfgl 5— '^ O p_ W OT 0B_ tt a. O tt p KCHART SPEED 0. 1 CM/MlN IJiTTEN: 12£! ZERO: 12% 5 riHyJlCK HA T : INJECT"^ ii\=^Fm^ •a a. 28.95^ i«B ro TITLE: AROCLORS 18 :40 CHANNEL NO: 1 SAMPLE: 126E. 1 PPM METHOD: AR 1 £AK PEAK RESULT TIME AREA SEP I NC NAME UG/ML (MIN) COUNTS CODE 30.7600 0.435 1253500 VV 2 69.2400 0.669 2821600 VV { TCTALS: 100.0000 4075100 ' i i MLLTIFLIER: 1 .00000 ; ERFORS: • FEAK STORAGE FULL NCTES: 3% SP-2100 100/120 SLPELCOPCRT FLOW 60. RANGEI. 3 UL INFECTION cCO IB •EHART SPEED 0. 1 CM/MIN StTTEN: 12£: ZERO: 12% 5 riN/TICK p-crn AT : INJECT" 3 r 3c .763 o tt p M I M W e> es •S" tt & ^ITLE: AROCLORS 2 0:03 i-a_ J I'lH—(: ;; O •fHf^iNNEL NO : 1 SAMPLE: 126E. 1 PPM METHOD: AR01248 f EAK PEAK RESULT TIME - AREA hi NC NAME UG/ML (MIN) COUNTS hi 1 7.6 145 0, 442 1 1 9 2:7 6 0 w 2 20 6059 0, 676 3227770 26 002 9 3 1 .868 n 4073170 o.\oa.\ 'S> (A c ;i« eet ^"Z (5^ 23 fS^ITLE: AROCLORS 5(P0 .CHANNE2 L NO: i SAMPLE: 0290.1:f9&9 METHOD: ARO1249 ^EAK PEAK RESULT TIME AREA SEP • NAME UG/ML (MIN) COUNTS CODE 1 13.7804 2 .482 347943 BB •> 40.5921 31 .838 » 102^910 vv"^ I 3 9.5014 32 .919 ,. 239902 *^^'S= 0.(''» ^^^° I 4 13.0454 33 .636 329385 VV / ii-^---— 3'.5 "^/-j J 5 23.0806 35 .21 1 " 582765 VV J 3 5-CTAL5.: 99 . 99=9 252-900 O rriLL TIFL lER : 1 .00000 Z ?V^CTES: •^ 3% SP-2 100 100/120 SLPELCOPCRT J»» FLOW 60. RANGEI . 3 UL IN..ECTION 9> S 3" a a. » z ^CHART SPEED 0. 1 CM/MIN 5 riN/TICK •H^TTEN: 12& ZERO: 12% Ul TAT : INJECT 3 189 AB f^t ^V -E: AROCLORS 0:0' .11 iia-i \ ''CHANNEL NO: 1 SAMPLE: 029 1,1:250O METHOD: AR01248 PEAK PEAK RESULT TIME AREA SEP NC NAME UG/ML (MIN) COUNTS CODE 1 55.2657 31 .831 480921 VV 2 15.5653 32 .619 135439 VB 3 29. 1650 35.189 253775 BV TCTALS: 100.0000 870135 MLL TIFLlER: 1 .00000 NCTES: 3% SP-2100 100/120 SLPELCOPCRT FLOW 60. RANGEI, 3 UL INwECTION S) (A c m JEHART SPEE:ED: 0. 1 CM/MIN CS«TTEN: 12£! ZERO: 12% 5 riN/TICK '.TTTAT : INJECT"'2 Y: 11.6 o •«-!-r niy^ 33.679 M t hi W 0> OB ;ta fB(t> ^ H or I TLE: AROCLORS 0:5^ W—-^M i 1. •' >*tt af HANNEL NO: 1 SAMPLE: 0292.1:1000 METHOD: AR01248 p M'E^iK PEAK; RESULT TIME AREA SEP M NC NAME UG/ML IMIN) COUNTS CODE " 1 76.2768 1 1,662 4608950 BB - 2 1 682 1 31 ,880 7 05 940 VV ? 3 31E2 32 , 949 140077 VV 4 5073 33 ,679 211922 VB 5 6 2145 35 ,249 375507 BV 3'C TALS 99.9959 6042400 •o a• •KILL TIFLIER .OOOOO NCTES: II I •! I Ifl ^-tk m immtmHiamam^titiiSSMiet Jl RT SPEED 0.1 CM/MIN EN: 128 ZERO: 12% SriN/TICK =:TAT : INJECT"* /3l?Ai, r Jb CS) cn a<\ eBb"^"^ c ;?i^i-E AROCLORS 16 : 25 ftHANNEL NO: J SAMPLE: BLANK METHOD: AR !48 ^-EAK PEAK RESULT TIME AREA SEP ONC NAME UG/ML (MIN) COUNTS CODE 1 19.5467 0.430 1775010 BV -J 29.2356 0.667 265^840 VV , 3 13.4663 4.206 1222850 BB ? •* 4.093 4 32 . 190 37)714 BV 1 5 - .9849 33.115 180249 VV ? 6 2.5 170 35.189 2 2 E: 5 6 8 VV 5 ^ 29. 156 1 3c .721 2647620 VV „TCTALS ,: 100.0000 908G850 tt •• ^LLTIFLIER: 1.00000 Jf^CTES: JJ ':.% =;P-2100 100/120 SLPELCOPCRT « FLOW 60. RANGEI. 3 UL INwECTION 5OD" «a a Z p ^CHART SPEED 0.1 CM/MIN S^TTEN 128 ZERO: 12% 5 rlN/TICK TAT :INJECT 3_ y CD 30.845 TIILE: AROCLORS 19:01 M JAN 1. .. CHhiNNEL NO: ] SAMPLE: 12bE. l.OPPM METHOD: AR01248 (5) F!ESULT TIME AREA SEP CftPE^iK PEAK UG/ML (MIN) COUNTS CODE C NC NAME 7.81E2 0, 444 1 159710 BV iS 1 19 2 44 8 0. 677 285^660 VV O 3 26 0637 31 , 852 3866140 VV 4 1 . 74=6 32 , 936 17 42870 VV 5 4 8338 32 .629 717024 VV 6 2 5i 37=3 35 , 202 376-620 VV 9 104 72£;385 VB OD 7 4 3e ,736 •TCI AL£.: 9 9.99=8 14833400 o 3 .• MLL TIFL IEF- : 1 . OOOOO "V NCTES: O 2% =:P-2 100 100/120 SLPELCOPCRT tt FLOW 60. RANGEI, 3 UL INwECTION J* z p hi liJ w o> OB •S" att ^CHART SPEED 0. 1 XM/MIN OATTEN: 12£: ZERO: 12% IN/TICK tt f^:TAT : INJE Z p IO hi — ©• 39 ^.^iV' att. Af i^£e> 9v TITLE: AROCLORS 19:57 lo - jHiu i:-!: CHANNEL NO: 1 SAMPLE: 0290, 1:250 METHOD: ARO1248 P^AK PEAK RESULT TIME AREA SEP NAME UG/ML tMIN) COUNTS CODE 1 7.4129 486 312022 BB 2 4016 31 843 178^750 VV/ 3 9 6626 32 925 4067 12 VV S = O.Sifc K 9^0 , 4 14 2216 32 641 598610 VV t '•^ ""' n.i -V^ i 5 26 3013 35 213 , 1107060 vvj TCTAL S: 100.0000 4209150 MLLTIFLIER 1.00000 NCTES: 3% SP-2100 100/120 SLPELCOPCRT FLOW 60. RANGEI> 3 UL INwECTION CD CCHART SPEED 0.1 CM/MIN SATTEN: 128 ZERO: 12% 5 riN/TICK 5-H:TAT :INJECT" p z— o 3 5 o tt p M hi W 0) OB S" ^9 FB^ 97 tt 2 1 : 21. .T TITLE: AROCLORS SAMPLE: 829 1. 1:500 METHOD: AR01243 PCHANNEL NO: 1 PEAK PEAK RESULT TIME AFEA p NC NAME UG/ML I M I N 1 COUNTS M 1 46.3412 3 1 .860 I 1922'710 N •5 10' 380 5 32.927 ta 3 15. 33 .642 430690 957 1 662062 4 27, 321 2 35 .2 13 1 133560 = SnS^^ o TCTALS: 100.0000 X 4149020 B att » C oo 5<^ F£& "fi TITLE: AROCLORS 2 1:26 CHANNEL NO: 1 SAMPLE: 0291. 1:50O METHOD: AR01243 PEAK PEAK RESULT TIME AREA SEP NC NAME UG/ML (MIN) COUNTS CODE 1 46.3412 31 .860 1922710 VV 2 10 3 8 05 32 .927 430690 VV 3 15 957 1 32.642 662062 VV 4 27 3212 35 .213 1 133560 VV (^ ^TCTALS; 100.0000 4149020 pOML L TIFLlER: 1 .00000 WNCTES: O 3% SP-2100 100/120 SLPELCOPCRT FLOW 60. RANGEI. 3 UL INwECTION o 3 o "CHART SPEED 0.1 CM/MIN ZATTEN: 12 8 ZERO: 12% 5 riN/TICK o _L_ M~^'TAT : INJEC" M o>— 1 1' 'SOB' tt — a. O f»tt . z p n^l'"' M t M o X -O A9 /^e6 '^H tt &TITLE: AROCLORS 22:2 1 U JAM != :: CHi^iNNEL NCi : 1 SAMPLE: Cie9 2 1 : 25e METHOD: ARO1248 7 . 1.9 X.d •3 1 . d ^ 1 pfc^.jDias o Y V 1 4 1.9758 32.891 % 5 10817 vvc - Q.*\\^ %iso 5 3.0612 32.609 789856 VV < 6 5.0902 35. 178 f 1313380 VV y ^ ^ S^.H ^^IH^ 7 0.3926 36.709 101565 VV -TALS: 100.0000 25802100 MLLTIFLIER: 1.00000 NCTES: 3% SP-2100 100/120 SLPELCOPCR T FLOW 60. RANGEI > 3 UL INwECTION CHART SPEED 0.1 CM/MIN ATTEN: 128 ZERO: 12% rIN/TICK "STAT :INJEC ^" 38.068 3 3q F^ft ''"^ ZTITLE: AROCLORS 2 3: 12 r 1 jHi'< i: » "•CHANNEL NO: 1 SAMPLE: 029 1 1:500 METHOD: ARO1248 0 ftPEAK PEAK RESULT TIME AREA • NC NAME UG/ML (MIN) COUNTS r 1 46.4408 31 .889 t 1923980 10, 2807 32 .958 c 425914 r 3 15, 957 1 33 .680 661082 0.5^4 ^Soo -•4 27, 3214 35.248 X 1 131890 r 5 7.4 TCTALS: 100.0000 4 142870 MLL TIFLlEP: 1 .OOOOO NCTES: 3% SP-2JO0 100/120 SLPELCOPCRT FLOW 60. RANGEI. 3 UL INwECTION Cbi^iSI. SPEED 0.^I_CM/aiN i O ?TAT : INJECT"* 36.773 QCf f£e> «»*/ TITLE: AROCLORS 0:28 J^CHANN EL NO: 1 SAMPLE: 126E > 1 .0PP M METHOD: AR 3PEAK PEAK RESULT TIME AREA SEP fS NC NAME UG/ML (MIN) COUNTS CODE 8 » 7.5906 0.436 1220350 BV P 2 19.3654 0.670 «• 3 113410 v\;3 3 2ii. 105 9 31 .872 •*• 4197070 sytTi 4 1 1 .62=6 32 . 964 > 1869700 VV L Vo a^^' 0.3O 5 4.8 3 46 33 .661 777262 VV f ? 6 25. 177 3 35 .233 Tt 4047790 VV J nep= .0^»*7 y ^ 5.2967 3c.773 85 1556 VB 3TCTAL 100.0000 16077100 :• = • 5nLL TIFL IEF': 1.OOOOO ?NCTES: f* :% SP-2 100 100/120 SLPELCOPCRT Zp FLOW 60. RANGEI . 3 UL INwECTION N hi b) O) OB •S" tt a ?CHART SPEED 0.1 CM/MIN •ATTEN 128 ZERO: 12% 5 riN/TICK Z-r o O" •a. 36.787 tt 39.627 a Extraction Sample Time Particle Weight SUrtiflg Final Volume of Date/ Sample Percent Size (grams) Pressure Pressure Filtrate pHof inalysi Solids Phases Reduction sUrt slop filt (ml) Filtrate Remarks 0|^(c? Zco ^:0 0 ITT? z ^2^ ;6«i iiio ).->£: 2Dr>t. •^ O ^ - o\3^ loo AJO :2iiil fli/S g. ^ ^ DlU> (b . JVJ. P^.o lu^ S. o iC 01^ i" )OCi /i;6 ;2S,o 9'.2i S,o ^ 0\\^ Ibu V^5 J'^.o ^•i) So < 0/9 ? yo^ y^j: Jl^yO T% r. 6^ cCT ;2.0O 2/v-9y LUM. /Do yii aS.o ?.«t. ?.oO > r'>r ^f^^x ^OC^vvl iS n Ol'g^ [OO ^$.o -p.flS ^ ;fii 0(^'> /oo 1 Vii x<;io ?.(0 o\^\ -2.5,0 ?:/5 QO^Q \<^g /3-S.O 5" ^^T^ : :=^^, ^'Ju l(^^nm ^ \ZS.o y-i" V^-^^x ^y/^r: '2«S.D 7.5S "2, f c " f A i 1 RESULTS OF ANALYSIS: DIGESTION DATEIDQIO: M ANALYST: m CONCENTRATION SAMPLE mENTUIEK: CA JMH Oi.-tA EU SAMFLE NUMBER: 94 - oo^o Sox\, -fo^«.I metis ANALYSIS DATE ANALYST ^>I. UNITS Aluminum -yvv^ IDO Antimony' y.jK Digestion Dale: PJJM-q>^ Analyst: *>* ncy^al .91 '^S'lA -for th'L. ma+TiA. Sp'^^i. Sfl"ipii- of 4hiS Lafcn . / .—N y «: lestHs rtfwW. an dn| «^^. bosii RESULTS OF ANALYSIS: DIGESTION DATEZJM: 4 ANALYST: ^^ CONCENTRATION (ygiL) SAMPLE IDENTIFIER: E U SAMnJE NUMBER: ANALYSIS DATE ANALYST UNITS — Aluminum 'i^lP y. -321. ug/L . >^oo Antimony' ng/L Arsenic «g/L Barium yuc ng/L ^^c Beryllium I «g/L Cadmium 6f>L -IP ug/L Calcium CA Ci ii Digestion Date: ^f^^'^^ Analyst: £A_ -IM ^-\ r. ^^fitixccr^ Tor rolaSS.u.v\ Was cars.J, cP ncrmal laboia-itr^ Cco-bti l.Tiik (jf 75 • 35 ^Vt j +y^ 4j,<^ matrix Sp.M^ oP -fiMs. ba ^ Ail pine/ (X)/7c u.-05 a^rfh.r, nutp^iblc \ixh:.ckir^ Cc(\hoi l,m(h , i£l tijn - ICifi -tluid t'orirttni iJcCM - Co-f^'^t'^ run £»' Sciyam RESULTS OF ANALYSIS: DIGESnON DATE: ^'a^l^^-l ANALYST: PA- CONCENTRATION (ng/L) SAMn£ IDENTIFIER: £&^fi 0Z-o»\ EU SAMPLE NUMBER: ANALYSIS DATE ANALYST UNITS Aluminum aDL ' Digestion Date: -•o''Xintj Analyst P>^ -•'-• lr. . rcu^^ri^ -fix Pc4aAi.a^ i^cs o^l^J ^ ^f'n..,.r,c-Jl Co,-,i,v/ U,/^ (.T To ,l-^<^y^ ,;.,- IJ,^ U:YI*T.-J (lv..Auj RESULTS OF ANALYSIS: DIGECTION DATE: aU^t J ANALYST: ^''^ CONCENTRATION (««/L) SAMPLE IDENTIFIER: F U SAMPLE NUMBER: ANALYSIS DATE ANALYST UNITS 1 Aluminum ' Digestion Date: ^I^MI-I-^ Analyst i>i^ labi .J^^.tv..* CONCENTRATION •/.5o//tt-J£M. SAMPLE IDENTUIUR: EU SAMPLE NUMBER <^A'0o ANALYSIS DATE ANALYST 2>-£. UNITS Aluminum 'y •'<'¥*, ffl •Od •an Antimony' ti\h Calcium j VSI :•. • P"^ -<7^ Chromium JSi: rt:^ •n 'iH Cobalt r^- Q'i 'H Copper j±2K L r.1 C? -i.^ U Iron iCig t ly r^- qj r^- <•» « Magnesium pj- 0= OM Manganese p^ •< ^-.w Mercury r-^ v'f- nq Nickefi; ff? '-T -H Potassium li t •9l5. ^ r j IC <-H Selenium r £iLS2lJ£J <^r7 -cj-r-j ^ Silver i ' r cn '•H Sodium hll n a .•7M Thallium Nl> ' Digestion Date: Oi-:i.A- Q 4 Analyst: 1^ 0 Rtic^enfS ^(.y Zn.M., H^a>Tl 6.1- art nd uM+nni ncf(ry(Ll libcri^civ| IcrifDi lim.^ /or 75 /55'' ii-r- ftlc ri\i4rijL SpiKO 6amDI^ c^"-i-hiS ba46\. 'Mil o-fhtrv Qfl/u-J, UJf'l o^v-Hiiri ^jcft; p+"-tiij^ labofa.-bnj CL'n4rt,| limife eU£p^ -for /^Q. I^ut'entrs -b>- '^fJ u-^^L C-UL-^ O-P Dormcul {fr Mit LCS of -l-hiS £annplv b ^ Sire.- co'*^y^»iy /h^ . AW ftsiJfs Itfff^u/ an dry u^. ixsi^ RESULTS OF ANALYSIS: DiGESnON DATE: jls*^!^ ANALYST: J t CONCENTRATION («f/L) SAMPLE IDENTIFIER: E U SAMFUB NUMBER: ANALYSIS DATE ANALYST UNITS JX. Altiminum Antimony' ug/L Arsenic JSL ug/L Barium ..iiUP— -aa. ug/L .isia?— Beryllium ug/L Cadmium ug/L —UL_ Calcium -W) ug/L. .too Chromium O-i ii-'^'l Jd. uf/L Cobalt Mp<.ior» -2ErL ug/L Copper '^='•^r^^ •: i !::i-4tj ug/L •k?0O Iron HOP ug/L _jco_ Lead .3Slf .OCC IJLg:^ Xt' 3 ovVv JQ. ug/L •^igffa Magnesium ,'i-rj J2JL ug/L __!«>_ Manganese ,;•- VV •>>Tl «g/L _<-.^ Mercury ^•V-'^V _EL ug/L Nickel C^ ug/L —1»_ Potassium^ .JSJL ug/L -•'•"PC Seletiium .hlb< 0.0^ ^ ug/L Silver _ f\i*.20 ug/L SodiunL'^ ug/L Thallium (i^i> ' Digestion Date: j£j[iilil _ Analyst: P>V i\UC:i re ^r.<: i^,n.-x\ CLV /^^ <'Jr'^ . lu-rt ^ JifTe co'-^/ii^^/ett^e^ ( ^ Stx.' Cc^ryietT finu^, RESULTS OF ANALYSIS: DIGESnONDATE: aU^ihl^ ANALYST: »>^ CONCENTRATION (ug/L) SAMPLE IDENTDIER: ,SR-> o4'OtM EU SAMPLE NUMBER: qii-/>oQl 5L 0 ANALYSIS DATE ANALYST UNITS ' Aliimimim ug/L Antimony' /55-t5/-9V ug/L Arsenic kth Digestion Date: J'^'^'''^'^ Aaalytt: P •H. The r,-,<.av'/_ Sp.lU_ ^-.P ••-buS ta.U U ^ H C-^He» tfA/tJC. (-Msi. LUtViLi". ^rl:.,L^^b.'oiil• laU-T-t-^ CtJ.il.vl l,m.»5 ixi-tp+ ftl 4hi -niuil CLiI (>C c qc"/:) ••^iow^v/ . ^ ) ^€G C^ymf^-f* y ^V^»*-» RESULTS OF ANALYSIS: DIGECTION DATE: akdisi ANALYST: P* CONCENTRATION (ug/L) SAMPLE IDENTIFIER: ELI SAMPLE NUMBER: ANALYSIS DATE ANALYST UNTTS J L Aluminum 0-^- c-^ Oti >TV1 Antimony' ±ih^niSo^ /7'3.-0/-7y Arsenic ^^h ' Digestion Date: .^loalQ'^ Analyst PA (j) l^e ^fCu-vv.-j ^..- Po^^lu.A .cu . oa.-»i..cJt, oC ncvma> I.Lbo,-a.4z,v, a-n-lr.l l.rv„W ^-f nS . CONCENTRATION '^'>Stil SAMPLE IDENTIFIER: EU SAMPLE NUMBER: ANALYSIS DATE ANALYST "kii UNITS Aluminum ^3'lr2l (:.3 -OQ-1'I >7V ^ *0O Pf\l Antimony' ttjh Digestion Date: OJ-a4-QtV Analyst " ^ '^ ' flLtO.-t.\x-:a ^o / 2n . M'.t^O n.-^d 6cv. £\tf2, nc-^ Ub\+i'>'.'\ r'_.rrr.,^. |aJ>e.ra-ft,-U Cvrrlrx,! Iw-ni-ls /e/ ^ur -Ihd LCS c-T-lhlS S(3rr>pL boL^ci^. ^ "^ AIL KtsiUfS- ftforW on dry lul. kuis (^ .iSac-' c-'^'^ t> CONCENTRATION (ug/L) SAMPLE IDENTDFIER: EU SAMPLE NUMBER: 9«l-ooqau TCLP ANALYSIS DATE ANALYST UNITS Aluminum »20C Antimony' Arsenic Barium Hi[? t) 3 jj; : -«,V yrr. Beryllium 1 Cadmiiun d — \/ <' Calcium •>r»l Chromium ^5 1 <••»•< •mt Cobalt —U£ c' i ,;;.•• <;i/ -VTl Ug/I IflO^ Copper Magnesium —"-•I':'' c ? • C ^ '/'' Ti;' ug/L _:ioq_ Manganese ,-v, •:;..'J •»>1 ug/L _^r _ Mercury yi ' Digestion Date:J>|-:-)|0'-l Analyst: ?H ® N> 7^,^' ;'u ^ ,^w Ay..// ,^,,/, ^ Q, ^^^j ^ (2/ 3€T ^jLiyyiyn*^ y yOs^^ RESULTS OF ANALYSIS: DIGESnON DATE: ^^^i'^- ANALYST: P^ CONCENTRATION (ug/L) SAMPLE IDENTU'IER: ELI SAMPLE NUMBER: ANALYSIS DATE ANALYST UNTTS DL Aluminum i->^ :yp. ' Digestion Date: ^l-J'^l^'^ Analyst ^ i The. fc<.fA-<.^ •bl Uli.ss, ti€. maAriK. SpiU. of"-i :-.<•.» bcx-^^A. AW o+r\e. Ckfi'oc t.-.rj^ a.-.4-hio f>«.: f^+n-hl.:^ ia bc'.i^tf. '•^ ( ^ .Sa^ <^^*^yi e/ y y)fy^ •, RESULTS OF ANALYSIS: DIGESnON DATE: 5?b^|g>J ANALYST: ^^ CONCENTRATION (ug/L) SAMIIE IDENTIFIER: SB ^? Ol0-Ot EU SAMPLE NUMBER: ANALYSIS DATE ANALYST UNITS ^ Aluminum r>^ 'TJ ug/L -^P£ CrM • ^ Antimony' r?- o/-•?y ug/L Arsenic Kib' ' Digestion Date: jl^^l'^^ Analyst P*^ ttrt^Oi ecu c-X-^ q^^^ ^^. LtnucAJ^, ^ e do^iyi^ y^^,ti' ^ '^ Sse. Ci.yT't/yie/C^ ''A - ^or„.l y,,^u^ W.//.,^ ^.^^ ^. „, ^. - - -^'"^ ' > yy.i Comments to accompany results for sample numbers 94-0090 - 94-0092. / . \y Analytical spike recovery associated with this sample was outside of normal laboratory control •^jfjiyy^mits, which is indicative of a severe matrix interference. All other QA/QC associated with this I samplCOT e was within acceptable limits, therefore, the data was considered to be acceptable. ^ Analytical and matrix spike recoveries associated with this sample were outside of normal laboratory control limits which is indicative of a severe matrix interference. All other QA/QC associated with this sample was considered to be acceptable. Matrix spike recovery associated with this sample was outside of normal laboratory control limits which is indicative of a severe matrix interference. All other QAIQC associated with this sample was within acceptable limits, therefore, the data was considered to be acceptable. . . . Youaggptt SOL, usnte/*.-/ MAim MODOIKB: tf'i^^g, *l^//OBy{ VOUMESAMnxSIKED: /.r^JL Mgt.MAltaXUOD.VSBk flWALVOUMBOrglPtr y.y,yyJ Al •to SHnplent>iidvd D«ati « Aaaiyiii S^npfe 1 FinlSknpfe San Duuliun Batch Difadiaa FiDS Fador Ninber KKtar (ppn) (PPB) Bbnk > CQI'\-U O.iri.rinA.4 » Wj-}//l.Mr./}fiM nosn o.cy? » tir?A 'r>. r-ar. fJif^CCoS' • ^.<.^. OlnAk' III DO 6}-c%ni 1 "tt ryTi ' LC^ z^-.^'T 1 ' inc /.;JfD O.C^fT » /9/?7^, /?fX /•,co d.O^ 1 ' /?^75. /r?s — f}.C!53 ,' Ki^Si ii/.\f^ /nh /.-/nc Dii... rJ.. II < • .I' /?;< i ^1^. nJ. nn^O /•^OC 1 Otm-CJI ^ L/^ • IJ/.^. .^/O --^^.3^ /••ycD OiMrrrJ / /.J^.L.^ /. VOO v Doer. rJ. J'/,-7<^;<^ — Ourr. Gtl. rr/b f.cor aZYD.O'/:. rnlA /J.03/ /c?,-^ " I^.OV^ J> ,''.'^?/ 0.OD9 1 1 1 1 ' ^/) Ur, r{J 1 Jlt^.fl • ^ fr . »1 (DO''. /-TD^rkJ 1 ! U-iiJ p^^yr*-' // >AJa • '—I .™ DAXI: CiiQ^yV DAISKDOKlUh Mgr. MAnOZ MOO. VSBk^, ^ fINAL VOLUME (V am: /'Qy^ Ajido aMHplc/Maiiiltig A^^t^HM lini Fhal Sanple jif—.pi»r Untificaiian DOnfiaB Batch DifarfiaB Cooooateitiaa FUHIMM • ladnaBeoft NBDHT (PP-O (ppn) I ^/T/.CA ^./flO/W;/! 1 I -CZ/ A/;VO«W\ 0.09.7 co^-/ » J2ry^ "A/Ono Mh^n.noS • /?>/5. A/rr.i K I'l on m.rA-9^1 /tyao '0. cCiCi A/^ <0.S Q 1 Zr<* m^SS moo 1 Clo /:.2oiX> n.o?3-7 -3,V ' onriO /n. s 1 ^.^ a.oCV i ^}I.S ^1^ ^'^ in-Dc 1 /•/D /:jooo COGS C>^. [}Ycf)6,?>.i; ^ , — /no /.AO o.oya ^^/: & , DCQO I'-lbo A-jd^ /).0'/C -c/.r^ 1 ' ncPl /'I do ] /''/oe> 0.030 ^,ro ( 9y 1 t 1 HrJ.X^f /.•fo«? /•yOO /? oy/ vy t >i ^yJleJ>k ^ n.nCno — 1 ' nrfi> ' — /)./)/! 7^ Aih z > * (? -n.c; ff.. Vift W/TS rcpywi^^ c a I •^^^ /Tl/rA-iy Oiv/ /^H 1.1 / -Iirft. ^-DI-Ki'C a my^-h^< 'nrf^yJ, yrt>fir.r. ^ Blank Ck. HI ' fJh<^O.CK/)' ICV-1 T.V ••(j.OHo Found: ^.037 % Recoveiy: C^^^ , ^ ANALYTE: fls Blank Ck. IH:' AJh Analyst: Final CVT.V.:^^^^ Found: ^. ^yj^ % Recovery: /yy^7~^ Analytical Original Cone: Spike Added: <^««'//M' Cone. Spike Added: ^.oSo % Recovery: Spike: ^ 9v,oo^/ Sa/t/tl >/tf/ Obs. Spk Cone; /, 0(^0 <^o.^ Analytical Duplicate: ^ f Original Cone: D.Q^ o Duplicate: //.Q'// RPD: Ln. TV:X Found: >< % Recovery: "j^ Original Cone: Spike Added: C.Ol ft~^ Cone, Spike Added: ^,oyh % Recovery Oba. Spk Conc.:^t,^y^(^^ Original Gone: C.DJ'X Duplicate: (Q, p-p J ^ ^^'- /}'(io ISryC. Found: ^>^ % Recovery: "V^^ Analyst pj!^ Blank Chk.; UW^fXi^ Duplicate C^^_QQ<^gi^ Original Cone: il niJ ^ Duplicate: ^^ ^ RPD: /rc3 Original Cone: Spike Added: /\0y^€/ Obs. Spike Cone: ^.0( ^ % Recoveiy CotK. Spk Added: ^, ^/ ^ T^- ^^-^.-^ Found: % Recoveiyr ^ ^ ^^^-<^ Analyst Blank Chk.: Original Qxmit.'.^A^Q Duplicate^^ /?^.35 P"P"'*'"V^t7^ /;{ Spike: Original Cone: Spike Added: /Otfy <^ Obs. Spike Cone: O'TO % Recoveiy 5^ 1 BlankCk.«'l:^2><'c;.c^5^ ICV-lT.V.r^.^y^.^ Found: ^.^3;^ % Recoveiy: Q^,( ^ ANALYTE:/^5 Blank Ck. Wl'. CV-l T.V.: Found: % Recoveiy: D.le;ft?-(PV-7V Blank Ck.«:^^^^.^07^ CV-2 T.V.: Found: % Recoveiy: CV-3 T.V.: Found: % Recoveiy: Andyst: ^ ^ FinalCVT.V.:^^^0 ^'*^'' 0.010 % Recoveiy: /^^^ Q Analytical Original Cooc: Spike Added: Cooc. Spike Added: % Recoveiy: See, fi-HhriLpA Obs. Spk Cone: Analytical D«plicale:;i)/^ Original Cooc: DupUcale: RPD: 1 LCS#: K)/3 TV: Found: % Recoveiy: | Analytical Original Cooc: Spike Added: Cone Spike Added: % Recovery Spike: ^ ^ Obs. Spk Cone: Analytical Duplicate: i// ^ Original Cone: Duplicate: RPD: LCS#: /JHy^ TV: Found: % Recoveiy: DIGECTiON DATA: Analyrt^:; /^-/^J Blank Chk.; | Batch #:^^-^J-fy/ Duplicate ^.^^_^^ Original Cone; Duplicate; RPD: Spike: Origtiul Cone: Spike Added; Obs. Spike Cone; % Recoveiy Cone. Spk Added: LCS#: TV: Found: % Recoveiy: | DIGESTION DATA: Analyst Blank Chk.: 1 Batch IT: Duplicate Original Cone; Duplicate; RPD: Spike: Original Cone: Spike Added; Obs. Spike Cone; % Recovery 1 Cooc. Spk Added: LCSf: TV: Found; % Recoveiy; J GSAA SPIKE LOG Analyte Spike Soln. ID #: A Cooc SpBceSidic S'.co man Date r>£-Ol''l^& t Vohone Spike Sob Hied: 0.0 / ml Analyst: ^Mi Vohmi* ^•wiplf .Qpflfit* ^"^ ml Final Volune of Spike: Sample IDf Spiked Sample Sample Concentration Spike Added (ppm) (ppm) (ppm) /^/^'^ n^;•:^^ O./i?.'--^ r/^,'p /;v/9.To ^Q. 0 fi) \^/r?fl /^. /Vl') /.r*/r / •y^/.a 1 ^Or^/ /I ^-'? /?..oy? ^9.0 _ . n.-.92 /^/?''/ /^.0^(< f ^ ^ 0 , 1 1 A 1 > /l") /],..i.v 'c .e /^ 'T^/'i^' f^Gii-I^T^ 1 C. /r^yf! - e-»^' ^ (^f t ^ rrri 1 f^iT^^ly^n^y^y / S Gr-J*./ -r.. ^. ei.^* ^ y ^ f^e/^^j^y / r - ^ ^ . ^ • - • 1 ANALYSE .^^ _ STANIMIDDNDMBBb /f^-^S^ VOUME m x sou USED:,2.a^^ . ^, - SDG/t AV/tf^ , . YOUMESAMIUamBs ^^32^ BATE MrURIMlte J^z^^/fi ikMT.M4niXMI».1BED: ^^^^ IINAL VOLUME or anCB: /:c3/.^ AidD Kaal Bompie Final Snpfe Difadion Batch DifadiaB DihdiaB ^ Factor Nnmbo- Factor (PPoq) (ppq) BbiA I M'^Jn.n.li'QiiH (^./)/^ /^.o M If 1* 17 ^ H U » a 1 B II B 1 M 31 at r a 1 » 1 M 1 - ' ai 1 B 1 n 1 14 1 V 1 M 1 ^ r a M «• 1 . P GFAA QA/i^v. LOG SHEET ICV-IT.V.:^^^^ % Recoveiy: ^yj^^ ^ Blank a . /Vl:MS2 L g/f Found: ^ OY.^ ANALYTE J.(^'i) Blank Ck. #2: CV-l T.V.: Found: % Recoveiy: Blank Ck. UT CV-2 T.V. Found: % Recoveiy: Date: ^"-^f: P ^ /JlXOiC^-^ CV-3 T.V.: Found: % Recoveiy: Found: Analyst; / ^ Final CV T.V. :^^2^ '^•'7rr % Recoveiy: Ay^iy ^ Analytical Original Cone: Spike Added: Cone Spike Added: % Recoveiy: Spike:.,^ Jl dod. Obs. Spk Cone: Analytical Duplicate:)J^ Original Cone: Duplicate: RPD: LCS#:LOii b TV: Found: % Recoveiy: Analytical Original Cone: Spike Added: Cone Spike Added: % Recoveiy Spike: Bt- Obs. Spk Cone: : Analytical Duplicate: j\/jp Original Cone Duplicate: RPD; LCS'JLML . TV: Found: % Recoveiy: DIGESTION DATA: A°-"y"^^ jJs Py,/^ Blank Chk.: Batch #:r,^-^,o..>.>7 LCS*: TV: Found: % Recoveiy: • II IIB DIGESTION DATA: Analyst Blank Chk.: Batch #: Duplicate Origiiul Cone Duplicate: RPD: Spike: Original Cone Spike Added: Obs. Spike Cone: ff Recovery Cone Spk Added: Found: ff Recovery: GFAA SPIKE LOG Analyte: £ l / ^ Spike Sob. ID f: CoBb SidkeSolK .^yr£> nam Volame ^nke Soln Cxd: Analyst* M l t^i^' jnl y T OuBBC SBO^WC ^dUKCB* / SnnpleID# SpilwH gampi* Saflsnle Cum Hll If**"" Spike Added (ppm) (ppm) (pp«n) /ly'^, cr;\'^ 1 D /)V3 /./>P^^ A^o-?^ //^($^. o on'-f': IA.'^.'».V; A/> ' > - — • '1^ AWALWR P» SMNnAIDD SDCf: « (ppn) n..9^J.l).inn^, -pry a.ClMCi D^rt /?|P37 j2.iL22L 'n.nOQ. /o^ dlMmkl f f ^o> inn itui /'A^x r^rr.i/eT;^t, nr-tk tct^f. rnnfg q.SSoe n*. nxnT±Lr '• ^ z^^-*- 2±i /rt A 'ts/ <^>V^ i^.< 1^ rsomp/o^. .<^P Sej2 >^>t^ 6,9 (22/54^ AT - rJ.lfi^.*J ^n ^ iddL. J2S iiJds±. 't^ Rf-ii^i CH^ rtr^<^-pT--^aa, Xa^OJl [^i^fi t r,-. 1% TAi^ C'^AJ-I (y.m^ (^y>rt^i^yJ I*/r.) fk^-^ikf ^/iryft> •py /^\ nyrr^. '!.< -5gw/)/ g>c /hihy^-^i/- y=i.^ GFAA QA/QC LOG SHEET Blank Ck. 01.-^,Y;,^,>-7 lev -'T-V-: /'.CV,-, Found: ^^P ff Recovery: C7^, ^T 1 Blank Ck. #2 CV-l T.V Found: ff Recovery: //-!> Final CV T.V.: ff Recoveiy; Analyst: / ^ >^^'^ Aiulylical Origiiul Cone: Spike Added: ^-^^^.MhL LCS#: TV: Found: *" ff Recovery: — ML - Analytical ./AA^ Original Cone: %^UMAtA:^.V//^it>'' Cooc. Spike MAeA: ^^ p*~Jjtf ff Recoveiy Spike: 4} ^^ C\ ^ ^ /.D^ fjrt^i Obs. Spk Cone;; ^^^/^/[ ^ ^ ^ ^ Analytical Duplicate: >y Original Cov/c.'.Qj^,^^^y Duplicate: Qjfr/Zt/ RPD: — LCS/T: ^ TV:_ Found: — ff Recoveiy: DIGESTION DATA: Analyst / ^ Blank Chk.: ^J, ^p.^gty Batch »:^,^^,.;>/^ Duplicate ^^^^^^ Original Cone: A/b Duplicate: jjh WD: AJ/^^Z^>1 Spike: Origiiul Cone: Spike Added; X-^^^ Obs. Spike Cone: ^"^^^ ff Recovery 9r-oQ?^ Cone Spk Added: ^ ^9.^ /^C? LCSf: ,^^ TV: 22J. Foundi_^2: L ff Recoveiy: ^^.^,j>^ /^^ ^ ^^..^^^c Z..,^') DIGESTION DATA: Analyst Blank Chk.: Batch #: Duplica.e^ty^.^^^5' Original Ctyac.-O^iQ^ Duplicate:^^^^^^ ^ ^ RPD: -^1 Spike: Original Cone: ^ Spike Added:/>:> ^'^ c' Obs. Spike Cone 6'v«''^'' ff Recovery "^T.' tl ^ /tf g iH f}ftV1fU t Cone. Spk Added:^.^fj LCS«: TV: — Found: ff Recovery; OAIE: /K=fi2-fV STANIMUDD vouME snac s(x. usn^^^^ 'ANAursr:.^^!.. MATES MOMflBb ^>^, /jrotUMESAMTlEWIEBte .^Lflaa/ aic#i ^iA- ilMT. BUTUXMOO. IBDI: ^IDMLVOUMEOranX: />/>y BAIEl (ppn) CaL^JjLmffA -i^r.i/a. .£,^a£. .A^Zil :£££i. 'f>. oQQ /Jt>^y>.n:>'^ Alk^C />?A^4^^ *t.^y.f^/ / r /m U.DlS 2. A^y^/>^^ /:, tft> /•r /•5oo ^.O/g" ,1 ^^/^ D.OG6 /.• ^e^ ^^o /'tOX> /ro Q. CO/ t^lX^^' Ur../W. A£^jL ££2^ /•/o^ /•/?> /••Jboa - p •»<•>/ ^±^2^SL i'/i^/fyilr £:£M. O'^^') /•loo /'Sh /r L0 /^f\nP^iirn^' (I te/ yio tri i ^.\ ll^ fPO- J^/iP^ //lyy/rT. ' ^ ^^Tyy'y yy^y^ ^^yy^C^. cTS-^cii h2k^ C ^ 2^ ii^ui &Z2»^y>/^r . -h/yy^^ ^ , ty . ^ 5^Wr ""^J^ ^ ^Jy<^ 1^^ ^'-'^'^ ^y^^i-r-y ^ y>rf/)jrOi. ^^^^-H:7" ^'yi r^ s^iL y /P^y./P'^^i a^n^y^ ,.^ /^^rrf^ y ^^^y)(>^K y:A/^yy / y^^ y t^^^ GFAA QA/QC LOG SHEET Blank Ck. /Tl ICV-IT.V.: ^.^^ ^ Found: ^039 ff Recoveiy; y^-; ANALYTE: 5e/fe>*''^ ^ <> <<^iOOp Blank Ck. f2 CV-l T.V. Found: ff Recoveiy; Found: ff Recoveiy; Date: ^:J/^{^y ^lankCk.#3:^^^^^^tr " CV-2 T.V. CV-3 T.V, Found: ff Recovery: ff Recoveiy; ^ ^ Q t:/^ Analytical Origiiul Cone: Spike Added: drCIT^ Cone Spike Added: ff Recoveiy; fc/ 'j3ii LCS#: TV: Found: ff Recoveiy: Analytical Origiiul Cone: Spike Added: Cooc. Spike Added: ff Recoveiy Spike: Obs. Spk Cone; Analytical Duplicate: Origiiul Cone Duplicate: RPD: LCS#; TV: Found: ff Recoveiy: DIGESTION DATA: Analyst Blank Chk. Batch #:^-^;}-f/ / Duplicate/^ 5^^^^ Original Cone: ^.o/ ^ Duplicate; C^^oJ^ RPD: ^ ^ ^ Spike:^ Original Cone:, Spike Added: Obs. Spike Cone: ff Recoveiy Cone Spk Added: LCS#: TV: Found: ff Recoveiy; DIGESTION DATA: Analyst Blank Chk. Batch #; Duplicate Original Cone Duplicate: RPD: Spike: Original Cone: Spike Added; Obs. Spike COIK.; ff Recovery Cooc. Spk Added: LCSf: TV: Found: ff Recoveiy: C^AA SPIKE LOG Analyte: ^ - ^^-^^ Spike Sola. ID #: |Date: n-0%-^H CoBc Spike Sofac •^^'•-^ nam 'Analyst: f^ Vofaane Spike Soln Umd: £,^L Vivliiiiiy jgaiipU gptl^f^f* /'OO Bd Fmal Vofaane of Spike: J:^j_ -Od Sample ID # Spiked Sample Saiiiplf Concentration SpikeAdded c^ (ppm) (ppm) 1 (ppm) lA//?.,1^7 pA \^ 1 ^^. > .9 <;;^ 77rh- .-.y^ -• • 1 1 J^ 1 1 1 1 •>rf/^ a^^(y*^OjL/iic^ BATEEPOKIEDr^J^O^ TY AMT. MATHS IDOL VOUME o r aiKB: (.•7'r4 (PPB) (ppn) {jal2di^AiQSiffU Tri//).f>^.ojyM Ai2f^ A^»i2. 3yfi .^^220 Al^ ' />c' /^ 5- -^^-Z* Ot/^r- /^^^2o//>,>1-e;tys - ^ . ^ /-/• 1^ fi/ialyiicoii ?/>' (£y /Atijirr.i. oy-J ^i^T/Ct J ^j 4 /^.<^^^*^/eS .^yy^yey SrANIMSDlD />f'SV 09X/i/(^. fINAL VOLUME or ggg; /.oA DATE! utt.waaxuao. ) (ppm) 0090 r 02. />^a g) /^^^^ Y-^rr^ ^:r hi rp rrfiffrf'r" / n rJt r rtj^^ ->V.»' ^tf^.y^rr n-/ n tcirr•/ LCS IT: Found: ff Recoveiy: . Analytical Spike Added: Cooc. Spike Added: ff Recoveiy Spike: Obs. Spk Cone: Analytical Duplicate; Original Cone: Duplicate: RPD: LCS/T: TV; Found: ff Recoveiy: DIGESTION DATA: Analyst /^/^ Blank Chk.; /;2> <-b.^r Batch »; o;^~xV-?y';iS Duplicate i Spike; Original Cone SpikeAdded: l-O^rA® Obs. Spike Cone: O.OCS % Recoveiy 9V-oo7C^ Cone Spk Added: 0,0 v^p /3QO LCSf:^,^^ TV; 0,/2^ Found: o,/Z^ ff Recoveiy: /x)V,V DIGESTION DATA: Analyst y ^ Blank Chk.; ^t/yPsboT Batch l:^;t^y^jrjt^ Duplicate 9*/'Oo9'X. Original Cone L&zk Duplicate: y^J^ '"'P- NA<^^/^ Spike; Original Cone: SpikeAdded: /> O > ^ Obs. Spike Cone: ^. ^''^ ff Recoveiy 9^-c^c^9:X. Cooc. Spk Added; g, ^;g^ /C^^O LCS»; /17'S'S Found: 'JAUL % Recoveiy: /, ^ e)^/^;^^ >^^.^.^^ /., j \ GFAA SPIKE LOG jDate: o.^^-yy'-<>*/ ^pikeSob.IDf: 'Analyst: PA- Cone Spike KaW,. VoliBDe Spike SolnUmd: Vohnne Sample Spiked: Final Voltme of Spike: afi:^ t y 17T. -.UULYSR C^^//^.f insz. IDUL VOUME or -.Ol^2±9V_ •Q DATE Fa (ppn) rJ^/& T~ T.CC P GFAA QA/QNLOG SHEET ^ Blank Ck.»l:^>^^^j^ ICV-l T.V.: f^^^^ Found: ^wo:?^ ff Recoveiy; ^^3 " ANALVTE; #5 ff Recoveiy: ^^r.^ Blank Ck. 91:... ^ ^"•'^•"•^ n.r.^o ^°""''= ^.^3g^ plank Ck. fJ: Q.S-1 TV Found: ff Recoveiy: Date;^j?-;S'-7f H\> Final CV T.V. Found: ff Recovery: Analyst; /?j^ Q.^-^/O ££^^ ^ ^ Analytical Original Cone: Spike Added: /?• <3''^ t^ Cone Spike Added;^^^ ff Recovery; Spike: o /tl> i 00*^ Obs. Spk Cone; ^gy ^ 'P<''0 Analytical Duplicate: ^ r Original Cone: /li^^Q.on'f Duplicate: ju/x'o.ooT RPD; /i/y Analytical Original Cone: Spike Added: ^. CZ/v^ &/ Cone. Spike Added; ^^ ^J<:3 ff Recoveiy A)^ Batch f; X)^ Duplicate Original Cone Duplicate: RPD: Spike; Original Cone Spike Added: Obs. Spike Cone: ff Recoveiy Cone. Spk Added: LCS#: TV: Found: ff Recoveiy: m 1 m m B \ SOFT METAL DIGESTIONS Date/Time; Ol -^V- 9 V LCS ID.: Analyst: Pl i Volume: SAMPLE SAMPLE FINAL NUMBER DIGESTION PROCEDURE WT./VOL. VOLUME MATRIX COMMENTS "fV.noOm^iP ^-e^ tL ^a o ^ IQOIQA -jy-tY^/rrLf C^P ^Dc^ %Ji^-Jir /] I nu.oo^JrnP \uJ^ i \ ' fytfa*^ li - cTRn ue 7v-ooq/ <:iP (^lA^m^Q.€^ JSL^ Q^.nn^o eir IH'O^ H ^^-T 11-0090. fir •• ((B - A) - (C - A)l X IOO - ff Difference (Limit => ^ 10 ff) (B-A) tJOFT METAL DIGESTIONS jfi fci.al>M Dale/Time: QTI- ^V 9^ LCS ID. Analyst: Plr Voliime;: oi- SAMPLE NUMBER DIGESTION PROCEDURE COMMENTS p^nn^PaiALP ?/-t?gfr /^ ]i/.COfj U.P I't-QjyiiW /^^/^^J^i?^-c?V as i 'V Z.CJ -vSrv iK MATESMOBOIBb I CJ S>/i* filoc^M » 'TrU ().Ci^f>lrl^A /?./7<^^ /?.*7 0) (\r... Lhr^^ nn-^l n n-f-r^\' 'Y>,'li r^r . <.o , ^•c <" 1 It —I,'- ''-r ' . n Mr i-y, /V r/t ii("-e. n rrr ^.ry^..y. .,,//y •// \ ^IT-'*'^/ /'.i^^S /) J/7^/7^ yi^ -• / r^i/y. rr. ^.. r ^ , ™^ GFAA QA/QCTCOCTE(G SHEET M Blank Ck.OI:^^ Cg.CCi: ICV-IT.V.: ^^^y^ . Found: ^•C>Y^ ff Recoveiy: //*? ^ ANALVTE: / / Blank Ck. f2: CV-l T.V.: Found: ff Recoveiy M)s Date:^;'.<9.j-// BlankCk. *3:^.^^^oo,:,^ cy-i TV. Found: ff Recoveiy; CV-3 T.V.: Found: ff Recoveiy; Final CV T.V. Found: Analyst; ^ QO^ O .^^^ ^ ff Recoveiy: y^C.tO Analytical Original Cone: Spike Added: fi-Oz/i-l € ' Cooc. Spike Added: ^ ^yz ff Recoveiy: Spike: ,, A/6 ^o. arp 5^ Obs. Spk Cone: ^,oo2._ ^.0 Analytical Duplicate: ]/ Original Cone: jjf^ Duplicale: /^/^ RPP- U/f^x£>yL ff Recoveiy: ^ ^ LCS*: i^ TV: X Found^: Analytical Original Cone. Spike Added: <^j^« / B' Cone Spike Added;^.o_j^ ff Recoveiy Obs. Spk Cone; ^/ ^ /0yO ^ \rr\ •** /<°y ^ ^mrt/f'^trtitlCl L Analytical Duplicate:Jf Original Cone: /J ^ Duplicate: ^;^ RPD: /Jjf <^/> A LCS IT: TV: Found M. ^ ^ _ % Rtcoytty:/) ^ <:Z:P/ i DIGESTION DATA: Analyst / ^ Blank Chk.: J^/JJ^V^QOS' y. Batch f;/^j?-t);i-yi// Duplicate' ^^^;2 _ Original Cone: ^^y Duplicale: i A ^^P /t/zf^C-JZA^ Spike: Original Cone SpikeAdded: /oy 4 ^ Obs. Spike Cone: i^^ ff Recoveiy Cone. Spk Added: /f.o$lh LCS*: ^1 ^ Found: i^Ll ff Recoveiy: /c^^ , Q DIGESTION DATA: Blank Chk.: Batch #: - Duplicale Original Cone Duplicate: RPD; Spike: Original Cone Spike Added: Obs. Spike Cone: ff Recoveiy Cone. Spk Added; LCSf: TV: Found: ff Recoveiy: VOLUME aoEE sou uaihTir:^::^ y OGis yi/y*^ MATBIEMO«n»^*?^/«/^i^ ^M)0;yW VOUMESAMFLBSnEBfe /or^^. RNAL VOUME o r sm : /T^^^y A a * _ Al liHi final Sample S« jpla- likiiliraetinn DibdMB Batdi DilBfian ^ (ppq) Fadar Fador (PPB) # I rJRJn C.ltyr^^it 1 .1 -rri/ n r>,^; "APDC «' A.'^'^/ /.')00 /•^o /Xoo b A/Ja-^ /Jh<'in. '') 1 /. /I.J^ —o.o^ .— 1 nc^9l A7 60 A;IO /•,lo»>a *gj. CCC ^/><^/r' S . \y/l,J'^y^' -0. 0 0/ »• /./v/c rw^iss" /-:/<>* v/ Aao /•Ao»J OOOC AJ/S < /O L :v/iA.i^ip yf.OOl — I « ^c.^ '^n.Ocii Ali^y^.nnr C» en//),oVo/.n/»i /s.Ot/ t 0. f> V II • M 1 % U H a z .//>^.. > .-^r,-^ »«« / />^ :^. V c •^/^a^ fP. "^ . /.fi,-}j>r z t/:^ n y 7 (^^^/V yfr^Cr=' . TSSor- yry e rJ z ^.^.//"'^ -r4< V •r,-,n.>,/)/ P /^ r/<^ ^.-Ti n' - ^ .-'T'i.^yyp 1 / • » -C./.V -v.^ r/j. 6.. /Vrifl Vy^Y^-"-, / a k../// /O .y^Lr , ^K ^ ai T a -• a M jg X a X a t ir r a M «> GFAA QA/Q(^O(^( G SHEET Blank g. 01: ^/Xa-.^vg ICV-IT.V.: ^j .^^ ^ Found: ^. ,^///' ff Recoveiy: /Q^S ANALVTE: // ^^^-^ Blank Ck. Itl: CV-l TV.: Found: ff Recoveiy: Blank Ck.*3:^j^ooD5 CV.2T.V.: Found: ff Recoveiy: CV-3 TV.: Found: ff Recoveiy Found: Analyst: / ^ Final CV T.V. 0 oy p 0-1^1' ff Recoveiy: Analytical Original Cone. Spike Added: Cone Spike Added: Obs. Spk Cone '^<.' /ft:-!, ^ Analytical Duplicale: Original Cooc. Duplicate: RPD: TV: Found: ff Recoveiy: Analytical Original Cone Spike Added: Cone Spike Added; Spike: Obs. Spk Cone Analytical Duplicale: Original Cone Duplicate: RPD: LCSf: TV: Found: ff Recoveiy; • DIGESTION DATA: Analyst Blank Chk. Batch f:^^,/0j?-97/ Duplicale Original Cone: Duplicate: RPD: Spike Original Cone Spike Added: Obs. Spike Cone: ff Recoveiy S>^fell^/ Cone. Spk Added; LCSf: TV: Found: ff Recoveiy: •i DIGESTION DATA: Analyst Blank Chk. Batch f: Duplicate Original Cone: Duplicate: RPD: Spike: Original Cone Spike Added: Obs. Spike Cone; ff Recovery Cone Spk Added: LCSf; TV: Found: ff Recoveiy: CT'AA SPIKE LOG Spike SofaL ID #: //f-^y Cone ^ake Sofac Xr>r> _ppoi Volnne Spike Sofai Used: <^. i'l/ _nd /. .-»o ml Final Vofaane of Spike: /.o/ ml Sample ID f Spiked Sample Smpte Conoeatration SpikeAdded % Reuivcij r-™-*. (ppm) (ppm) (ppm) '^'/'•^' /t<^5r? jiff ^y^' ^ yv- >9/ ; il CJOjaauoKmyaancxngm ^y ^ ..' UUllXSti^^±^ VOUMESAMnXffSD: />o^ ^ •nuL VOUME or SIXZ: /-o/^ BATE moKmh ^>:21:f f ^I^« »• AMIJM FiHl FinlSnpk Adto /'mr Difadiim Batih DifadkB ^ Fador NianiMr Fador Fador (ppm) (ppm) C J firJA O.ISCOtm 1 /?iP3C X/^:/ A C^C> o*/ii ^^/^^(r -r«-^ '^ *"/» 1 no c /J^^O^S' Pr^D.Nr,^!^ /.l OL ;^-7v .55 AO -fj'CO O rJfi^JiXfO „ />ri9Q. "T. yni\ /•3L AO- "nifyo i tjb^O. OfO /• ,^ — (OOP-? 7" yn^ 1). r>.3 /Oi •'/>.y>n/ fjl)<^ 0.0^0 no'^'y T ) ocy?/ T /:2_ 1 "a.o^^l c y,n7:? -r /••> -a, oc> / u nO'TiD S A:^ J/ -/^.Jo / S u 1 /?„^. k./. /••^ -^ -«,«>^/ J. u ./ /}A..S>^uyi^ />.CI ^ M Cr.fii -ft.6*/ A/i>^r,.r.^if u rr.'/ o ry^n rtem 0^o9ZL ^./>y/2. M na^i S /•J f-.-si-'^y/Ss /a Qf^ i IT CO^r^ 5 / X 1 -rt. oo/ 1 a ( 1 no'Pn F /••^ "tf . 6 « / / 1 It nr9 / )cr /• u ~»'r»o/ 1 » ro'^2 F /:x^ } ~o.oo; / a 1 ^/.r,JPA.,r? ~(D 00 / .^ ti r .^ /?.^ c;.i^ .oo/ 1 TT D09o F 1 "o-oo; B tiCf\l B 1 1 1 -o-t.^*2_ - • « noff^B .> .1 }/ t' "o-o^/ 1 M D.^f k/y). ^ 1 "o•oo; • \ II ./ /I.^9<^ a,o B cn / DiOia nnrA ^.o^i^- y^.y>' ICV-l TV.: Found: ^^ ^3^ ^ ff Recoveiy; O^^ Q Blank Ck.yi: ^>, LCSf: ^t^ TV: , ^ Found: y<. ff Recoveiy; ^ -nacusamAM.4hJLXA « Analyst Blank Chk. bupii( Original Cone; Duplicate: "p''"'« 9p^?gLe / ^ i/^ ^^••lU/f Original Cone: fj^ Duplicate: f^j/^ RPD: Batch f; (?^.^^..9y ag P"p"'^"9vH90'y,i r ><; S ^ V /nn/>^ Sv^ -• "I-- " tj .unci I '— -" LCSf: n1-^3 TV: r..oa5 Found: r?,Q/? ff Recoveiy; y^.g /j^jj^^, ^^,j /.~i^ STAIOMBDD tt /^ry!^£2m 0 •lit IINAL VOUME or SratX: y,myjJ. BATE Fl Fl (ppn) (ppm) 0,c3<^ OicM' O.QOl M^^rt.rtoC 111 -O.oco /Jb •Q. pee? - ft.QOO •"Q.QOO A. JS^J-^ O. Qg / u/> fOior^ CS£L. O.PCO OJ Czj/JL r^Cji^i ./I ^21 CtO^ aQ2L.^5.. r.X. n-ii-'>'^:'s jii2^ il^l£l tJbco.010 no?:? S 0-600 n/^^O tr -T* .oO/ ^^9/ r "f> • O C f ^^r^f/g r JfL —o •o o/ j .^::^ 'O, •C'^/ -t^>^.^--^^ -2_ go<^.g ^ ^'^:-y^ Oor>o ///>-< OiroS nci/ y, r>*/o^^^ Oi'^y-y 7f* C'.n'bV G09l S Ml i^rjdJIUl. i-yo r. 10 'Q. OOI /J> r- Tree f)/fn-fi ^/•Z /Pr.-.'-^.' /y'yiai ^ o/yu/^L'S—^a/s^ ^ ^-P cuy/ A/ „y^^ m -'ZJ' y^z£_ r rr^i-r ^MiCLLL £ U "^Jl-/^ (I.'r y h^ryKi .^ _^u^ VI v£ ^ yr/f ^ Ja±rL ^ ^ - • ^ TIN METHOD FILE AUTO SAMPLER LOG 0.ltioK 3S. 1 %• 1 ELEMEKTS: ^ 1 1. CAUBRATION 1 ^^ 1 TJ. 1 DATE: <9l*l/9tJ > 2.B1ANKCA1 \ ^• 71. ANALYST: ->(m 1 3..CV I 41. 1 ''• $l«BSOLimON:IOBL io.gmSBVU^iS 4«. t6. DiuS \ tafi 1 11. c^-ooRx. ms 49. S7. 5PM4 -TO^ -fekl Sn ba+ch **• oa-5^-35 \ SO. i 12. t^J.pMC 5 1 13. qif-DMlSLf 51. 19. ! M. 'J.J-m"i siP 52. 90. >5- SBf 53. 91. 16. et^-i 54. 92. 1 n. ii-i C!>^o u r 55. 93. i 18. oj.^'), £( r 56. 94. f , 19. aJ />^,j; £( r 57. 95. V iJ-?.l iij ^^•%:P Sim" 58. 96. 21. 1X5 /W-6.?'" 59. 97. 22. i\.i.Qi^qr. 60. 98. 23. '/V ^^-7/ 61. 99. 2<- ^H iiOll.' 62. IOO. "• fvrwurwf 63. 101. 1 V 26- Q^'Omins 64. ICQ 1 27. OHD 65. 104 1 2«. fl:/-;i' 66. 105. 1 29. 67. 106. 1 30. 6S. 1 31. 69. 32. 70. 33. 71. 34. 72. 35. 73. 36. 74. 37. 75. ICP Sn Method Hie QA/QC Form Date/Analyst ; ^'^h'l ^ SDG #: M/i ) STANDARDS KPQ^nSIf ELEMENT CALIBRATION CCVS ' ICB CCB CCB Intensity T.V. (m-05) T.V. (m-53) ICV ff Recoveiy CCV ff Recoveiy CCV Sn23S J30l ^ 5.000 2.500 iSMZO q ANALYTICAL DUPLICATE ANALYTICAL SPIKE (M-53) ELEMENT U^WUmUwtitt Original Duplicate Relative ff DifT. Spike Added Spike Observed Spike - Original ff Recoveiy Sn235 1.00 ••"j/i/npk lf> ^ 9'\ooQ2.. _Ta.P_l^h^j>3 o^ -q^ as) (MATIUXI^OKlC^mCRlDJ/ MATRIX SraCE (MS) (M-53) ' LCS M.«^ ELEMENT M ll M* n ^ V«I«M «IM •! Relative ff Spike Spike - In House Always Aqueous original Duplicale DifTerence Spike Added Observed Original % Recoveiy TV Found ff Recovei Sn23S f.JO m — 2.00 iP.OS J.ot 164.0 4.00 *i.0O lOO.O jkfLCkiL i ND Date/Analyst: W V ^ ^ T> SDG#! _W* IAGE. .n — 1 STANDARDS n BLANK 1 ELEMENT CALIBRATION CCVS ICB CCB CCB Inlensily T.V. (m^5) T.V. (m-53) ICV ff Recoveiy CCV CCV Sn235 y^"^ - ... 5.000 2.500 ^•—-, ^ — • - ' ANALYTICAL DUPLICATE ANALYTICAL SPIKE (M-53) ELEMENT UtthttUwtitt Original Duplicale Relative ff DifT. Spike Added Spike Observed Spike - Original % Recoveiy Sn235 1.00 6i»ipiE. ^^ -^ qMooq,!. (Sc.l - bJch^oa ju TI 3s^ ^MATRn DUPUCATS:(MDr MATRIX SPIKE (MS) (M-53) LCSM-Sy ELEMENT M il M* Ital T«taM «IM al Relative ff Spike Spike - In House Always Aqueous Origiiul Duplicale DifTerence Spike Added Observed Original ff Recoveiy TV Found ff Recover Sn23S 3(* IT 2.00 ^g.q-f Cn 4.00 *I-35Q» /o^, /J0 \ O.RiMe 3S. 76. EUMENTS: rv. I n P'^.^. I'A >J,.V'.A., A-. W. ./i . H 1. CALIBRATION 39. 77. DATE: thriail .3iih4 2. BLANK CAL. 40. TS. ANALYST: Krn 3. ICV 41. 79. SPIKESOLUTKm:100uL(M-35) 6. ICSA 44. t2. 1 7. ICSAB 45. t3. ^aufllorR -rrea-labil.n; «=;-n^flv '• 1 «• ^fPr Blanf 46. /?tfy7*.i -. •4. TtlLP . <- P EL.7" PaMm^ 9- U-.^ in-^^ ' 47. DilitliaiS 15. 03 - ja -04 - ( S /{=? I i, -r.r)0 • 10. 9i/-DC>norai> 48. IO/ t6. ^^•'•N-OOrii TCLP 49. aeg^ t7. 12. q.i rc^i. TO-i^ so. q.^.oo1c -rcxfi ts. PiiitTi'^2- (iiliL^ons -fem Abex.. &• Cu. an£ fit) OMII,. - J \3.^-f,nT^mol 51. ci.l.coni rctfi S9. 1 ''^^ '<• Qi-009^ rns 52. q4-0C^2. TOP 90. 17. C44 nr.-).\ £,J) 55. fi»fl3/ 93. r>nrilLj<;iS no4 all Ac.\a \i.:,n% ^^\r)t«6. 18. yV ;i:"'V' i^A' 56. fiCV. 94. S^c -t^nrd eci>\j i>i'n4eu+. 19. _ j r^^c.,,^' 57. 95. • 20. r:'.;•>''>:? r, r 58. 96. 21. 'jJ ^«v/ •• : " 59. 97. 22. ;';_ .'. .-,7 / ' r 60. 98 23. 1-:..:;^ 61. 99. 2<- XC'.-z^A 62. too. 25. rro^t 63. 101. 1 26. CCV-i 64. 103. 1 2'' 65. 104. 28. 66. t05. 29. 67. 106. 30. 68. 31. 69. 32. 70. 33. 71. 34. 72. 35. 73. 36. 74. 37. 75. 1 DISntUMEMT DL OC. CM-S. MX) \ DUrUCATE mcE at-Tb ^ M-J5) \ RE1> T ANAI • »acE- / % S sracE oasEavQ) tAMriE y\ 1 £LEMENT« ACTUAL FOUND OMCINAL ' Dur DIFT ADDED srocE RESULT 1 1 Cf »s OJOI — N IJOD CfX t OJOI — o.oos SC r IA Zs21) OJCS C o 25 li b 0 IA a 214 omi OJO niZD 0.10 — (0 (Ol •C' c UOD • NiZ2l OM \ IA coza e « o.oso ICD O ijeo aia 0X05 O OOLf 150.0 -OJO \ NISI 0A< C.£?H? iteo o IA Nizn OM IA ••zu 0.10 ' UO ••zx OJODS • 0.10 y V»2 OJOS O.PH'7 U-V.c IA ••3I> OJODS 0. 00.1 ??.p aw CUZK OJB23 0. Dk3 9i.o / IA Atn oai O.Oiti - /lin.C' / CJD y B.4U 0.10 0. Q.lh 9u.O SA 1 — Lsacr WBCUM ~-~ II-.-/7,rt.':ig y^r hiL/> ^yf^^rid m ^fi/^.^ FRE-DIGESnON DATA Date/Analvst "Prop ^ba/ Sample ID qW-opga, TCLP Amounts of Sample Used .5o mJ5> - lOOmOs -iinaJt Voluncfc^ /:2 Tmf^ i-CS/pJ I / TmD mn nnH m«; hplm,-^ Dehtre. W l /-Z ifO Analvtes to be Detennined Cr.ln. dr^., Ph.Pn.^:.\f.i>^.CiL,fic J aid A.^ J Analytes .Spiked; with M-S4 <» I mis. SOOopm « Ba.Cn and Ph. lOOnpni = Cr.Co.NJ.Ag V and Zn. lOOnnm = Cd. 20ppm « Be. r^.f^pptr): Pb.Cu-gndL Ra-. ;OpiLm : Pr.To ,>d< ./9^ .v/cuid 7in , \^^-.(^ri aopin. rf^ Spike added:D. 5p««fl rftiiti! o.sc ^(illuilMl '/iC METALS fv Zn Pb ^ Cci Nl, 1 V w c;. lAq 6- Ca Original A Sample 6D1- i.W li.f O.01, 0.0)7 ^."i-i AID 6DL AID 0.V. m{^ pi^licate/ 0.01 [».o3 4^7 D.oy o.»7 D.1Z hiO 60L- AiO \o.z\ \\M - — - 0.11 "•'.o/^ Dt ^fr 0% — • ^ v.7r. A.ll ^STerencie^ -5 Observed Spike l.fl 7.7i 95.i, I.9Z CHll Jt.ll /.?? 0.115 1\l.l3 .'/.9// I.5U Spike- Original S D-flO Q 1.11 /.(/? -?.^ l-?l^ I.n I-n D.IS5 1.13 V.7V Result 1 0.513 % Recovery f5.5 tio 5t.o 93.0 12.0 93.5 Ho 12.S -H. $1,6 9^? \nJit Bft-< M0< N0<. Hie 601. fdl. agwgy Nt( uie — <0.02. OtO C.OIO O.OJ p.io <0.0IO COiO 0.91 IJTS Digesf ^ T.V.M-Ja* P^SM •afe 04aa 0J7S 0.150 •.u» 040S 0 ^ P.S0O 04 Found O.-Zt? C.ai^ cwi O.lbl 0.13^ 0.?'/1 0.073 0.051 o.«f 0. 1 % Recovery «>9i.<, %Z f9.r 9j,) 92.0 9S.(, ti.l, 7;.;. 9/.(/ ?j.9 7/5 NOTES : 0 /Tioir.i ^S);A^ OU.I oP ISitiS^c, PttovtNin/iat, • Svnbk. done >*/x SoAt. Cone. Ihercfor^ ela.L •• linPld " ^ ana. Alalia.. ^ ICP ZKTERFEREHCE CBECK SAKPI£ Lab Naae: Contract: lAb Code: Case Ko: SAS No.: SDC No. ICP ID Nuaber: 1^ Plasma- MOQ ICS Source: xte^ . rr..u.;i- Concentration Dnits: ug/L 1 1 1 True 1 Initia l Found Pinal-^'Tound 1 1 Sol. Sol. 1 Sol. Sol. 1 Sol. Sol. 1 1 Analyte A AB A AB %R 1 A AB %R 1 1 •.6"L-)r,Cf.T> \.^,tr\ rym IAntimony" 1Arsenic 1 1 Barium ! -^oo /j - 1 ^fil.Ci 1 '^^.-y 1 13 1 t^UI.D ( 9^?-/ 1 1 Beryllium \ 'OCO ^ \ lUh.C 1 1 Cadmium - • ^ ^lO^.D 90.ll •o \ ^HO.P 1 SS.O 1 i Calcium ••i-n.i^rr' 1 Chromium •^rv: USL- H15.0 'li.o • n Hia.o 1 */.«y 1 1 Cobalt viOO 1 D%it.n gb.f^ - 1 ws^.o 1 «5.K 1 1 Copper • •ir>ri .\o y/t-^i.n ^b.SL. - 7 ^n.p 1 it^.A 1 llron ILead '.ccy i«n 1053.P (CS.;5 aij.. IO ONE - 24 Revision 1 December 1987 azzti ti. ijyy ng/ J 1231 2.306 mg/] .292 1. 167 »g/J be313 e. lie ng/] CU324 1. 19S mg/J ag32e e.si4 mg/J ba4SS 2.373 •g/1 cr2e6 1.232 •0/1 I SD 0.0098 CV 0.79 zn2l3 1.220 •Q/l I SD 0.O10S CV 0.86 pb22e 2.361 •fl/J L SD 0.0342 CV 1.4S C022B 1.202 •g/J L SD 0.0117 CV 0.97 Cd228 •.£04 •fl/J 1 SO 0.0067 cv 1. 11 nl231 2.506 •g/J L SD 0.0011 cv 0.03 v292 1. 171 •g/J L SD 0.00S3 cv 0.43 b«313 0.110 •g/i L SD 0.0001 cv 0.03 oii32« i.iee •g/J I SD 0.0148 cv 1.24 •S328 0.914 -g/l I SD 0.0002 cv 0.04 ba4SS 2.37S •g/l L SO •.••76 cv 0.32 ib22e AV 1.048 •g/1 SD 0.0198 cv 1.1 6228 AV 0.429 •g/1 SD 0.0040 CV 0.9 .d228 AV 0.880 •g/1 SD 0.eeos cv 0.0b nl231 AV 0. 891 •g/1 SD 0.0064 CV 0.72 v292 AV 0.408 •g/l SD 0.0020 cv 0.49 be313 AV 0. 433 •g/1 SD 0.0024 CV 0.32 CU324 AV 0.417 •g/l SD 0.0017 cv 0.42 •g328 AV 0.892 •g/l SO 0.0021 cv 0.23 ba4SS AV 0.467 •g/l SD 0.0069 cv 1.47 f^GSf REPLICATE * i 1736 cr2e6 o.eee •g/l «lndo*-edge zn213 0.011 •g/1 pb22e 9.003 •g/1 wlndov-edgv co22e 0.003 •g/1 p»ak-•nolBy Cd228 a. 001 •g/1 ni231 0.004 •g/1 vindo«-edg« v292 0.000 •g/1 pvak-•nolay b»313 0.004 •g/1 windov-edgv CU324 0.000 •g/1 pcalc--noisy •g328 0.001 •g/1 peak-noisy ba4SS 0.004 •g/1 csom RERI.-ICATE * 2 cr206 0.007 •g/1 paak-noisy zn213 0.011 •g/1 pb220 0.06S •g/1 paak-noisy 00228 -0.001 •g/1 peak-noisy Cd22e -0.002 •g/1 «lndo»-»dga nl231 0.008 •g/1 v292 0.002 •g/1 p»ak -nolay b»313 0.004 •g/1 vlndow-adga CU324 0.001 •g/1 •g328 0.001 •g/1 p»ak'-nola y ba433 0.002 •g/1 pvak -noisy ar2e6 •.•03 •g/1 SD 0.0O4S CV 132.33 xn213 0.011 •g/l SD 0.0001 CV 0.34 pb220 0.034 •g/l SD 0.0434 CV 128.40 00228 0.001 •g/l SD 0.0023 CV 209.80 Cd22a -0.000 •g/l SD 0.0017 CV 490.72 nl231 •.••6 •g/l SD 0.0029 CV 47.03 v292 •.001 •g/l SD 0.0010 CV 103.39 b>313 •.••4 •g/l SD 0.0001 CV 2.76 au324 •. ••• •g/l SO 0.0002 CV 42.30 •0328 •.••1 •g/l SO o.oe^4 CV 31.39 bM45S •.••3 •g/l SO •.••le CV 32.91 CC V — 2 REPLICAT E 4f X 1743 cr206 1.223 •g/l zn213 1.227 •g/1 pb220 2.337 •g/1 C0228 1.193 •g/l Cd228 0.609 •g/1 . nl231 2. 303 •g/1 v292 1. 175 •g/1 b»313 0. 118 •g/1 CU324 1.177 •g/1 ag328 0.514 •g/1 ba4SS 2.384 •g/1 CC V — 2 REF»LICAT E #^2 or206 1.239 •g/l iCS A REPLICATE ^i 17J -02/94 r2e6 0.013 mg/1 zn213 0.043' •g/l pb220 0. 216 ng/1 peak•noisy co228 -0.002 •g/1 peak -noisy Cd228 -0.000 •g/1 prak•noisy nl231 -0.001 •g/l v292 -0.013 •g/1 «lndo«-»dge ba313 0.004 •g/1 «Indow-edgr CU324 -0.007 •g/1 ag328 0.001 •g/1 peak-noisy ba433 0.013 •g/1 peak-noisy ICS A 1 REPLICAT E *2 cr206 0.002 •g/1 peak-noisy zn213 0.032 •g/1 pb220 0.207 •g/1 co228 -0.001 •g/1 peak-noisy Cd228 -0.000 •g/1 peak-noisy nl231 0.008 •g/l v292 -0.011 •g/l wlndiav-edg e ba313 0.004 •g/1 vlndi9«-edg » cu324 -0.007 •g/1 ag328 0.001 •g/1 peak -noisy ba4S3 0.013 •g/1 or206 0.007 •g/1 SD o.oeao CV 107.93 zn213 0.038 •g/l SD 0.0076 CV 20.21 pb22^ 0.212 •g/l SD 0.0061 CV 2.90 0022a -0.001 •g/l SD 0.0007 cv 33.37 Cd22a -0.000 •g/l SD 0.0001 cv 29.32 nl231 0.004 •g/l SD 0.0061 cv 170.18 v292 -0.012 •g/l SD 0.0020 cv 16.94 b»313 0.004 •g/l SD o.ooeo cv 0.97 ou324 -0.007 •g/l SD Oa OVWW cv 0. 48 •0328 O.OOl •g/l SD 0.0004 cv 47.38 b^4SS 0.O13 •g/1 SD 0.0000 cv 0.21 XCSAB REPLICAT E ^X 1727 cr206 0.463 mg/1 zn213 0.844 •g/1 pb220 1.062 •g/1 oo228 0.426 •g/1 Cd228 0.881 •g/1 nl231 0.896 •g/1 v292 0.407 •g/1 b*313 0.433 •g/1 cu324 0.416 •g/1 • g328 0.891 •g/1 ba455 0.462 •g/1 ICSAB REPLICATE 4fZZ or 206 0. 479 •g/1 zn213 0.860 •g/1 pb220 1.034 •g/1 C0228 0.432 •g/1 Cd228 0.880 •g/1 nl231 0.887 •g/1 v292 0.410 •g/1 ba313 0.437 •g/l OU324 0.418 •g/l •g328 0.894 •g/1 ba45S 0.472 •g/l «g32e 0. 001 mg/1 .a4S5 0.060, mg/1 94-009 1 ELT REPLICATE * 2 cr206 e.eie mg/1 zn213 1. 469 mg/1 pb22e 0.238 mg/1 C0228 0.008 •g/1 Cd22a 0.002 •g/1 nl231 0.038 •g/1 v292 0.004 •g/1 be313 0.004 •g/1 «indo«-edge CU324 0.031 •g/1 ag328 A.004 •g/1 peak •noisy ba4SS , 0.061 •g/l / i J,nt) /-(^l SOi.1.0 .OU. ar206«n 94-0092 ELT REPLICATE 4^ X 1708 or206 0.036 •g/ l zn213 8.035 •g/1 pb220 3. 492 •g/1 00228 0. 106 •g/1 Cd228 0.010 •g/1 nl231 1. 171 •g/1 v292 -0.001 •g/1 peak -noisy be313 0.004 •g/1 «lnd( 3«-edge CU324 0.788 •g/l •g328 0.002 •g/1 peak-noisy ba455 0.048 •g/1 94-0092 ELT REPLICATE m-2. cr206 0.032 •g/ l peak -noisy zn213 8.098 •g/l pb220 3.399 •g/l eo228 0. 101 •g/l Cd228 0.010 •g/l nl231 1. 192 •g/l v292 0.002 •g/l bs313 0.004 •g/l windi 3«-edgs CU324 0.782 •g/l •g328 0.002 •g/l peak-noisy ba4S5 0.049 ng/1 / .1 WW My o.oo arTmbiM. ,AV •••34 •g/1 0.03 80 ••27 CV 7.99 Hf.lUer 10,i • zn213/».'«JA? a. •76 •g/l t.it SO •399 CV 0.38 b.9t> pb220(r.fM> 'AV 3.446 •g/lvJ/5 SO •698 cv 1.91 e.jo 00228 MO.' AV •. 1^4 WQ/l C.IC 80 0032 cv 3.13 O.0»o Cd22aJt>>' >v •.•!• •g/lo.o/o so ••• 3 cv 2.77 J.Su ntZ31J.*.o /*^ 1.1B2 •g/1 lit SO •193 c» 1.29 ni<010 ,292 "'" "ty' ••••1 •g/1 so ••21 CV 374.93 0OL*» OIO b»ai3«tiKy V. ••••4 •g/1 80 •••1 cv 2.74 1-51 au324 i.Sio^.k^ •.789 •g/l^'ni SD ••4^ CV •.94 •292 -0.002 mg/i window-edge e313 0.004, rag/1 V lndo»-edge CU324 0. 400 mg/1 ag328 0.004 •g/1 ba433 0.072 mg/1 / ; //-'/) i^-V' ) . f*r~ir •J.I.- cr206 »i\. //AV 0.007 •g/1 SD 0.0O36 CV 49.57 S bJ- zn213 Jfci/AV 2.813 •g/l 7ii SD 0.0216 CV 0.77 •1 u< - pb22e 1.1.>./AV 2.339 •g/1 ; W SD 0.0042 CV 0. 18 BH:.C •(< co228 (W. -./AV 0.034 mQ/lttlL SD 0.0028 CV 8. 10 C VIO Cd228 "• -^ AV 0.005 •Q/lOOii SD 0.0014 CV 30.26 0 'lo nl231'>w. "•' AV 0.478 •g/l ci'^iT SD 0.0O26 CV 0.53 n J . . IO v292 '-.'• 1"."! AV -•.••1 mQ/1 nl- SD 0.O90O CV 55.60 60. 1 r I I.t be313.*»' • -^AV • .•04 •g/l^'i- SD 0.eooi CV 2.83 ll H< CU324 fJ.^ .^>V •.401 •g/1 Oiii'l SD 0.0O19 cv 0.37 nj c Ji- •g328''./ >o AV •.••2 •g/l .iL 80 0.0018 cv 79.78 nt.. : H ba499<'-c / AV •.072 •g/1 l>ru 80 0.0003 cv 0.42 0, 94-0090 ELT REPLICATE * 1 16SO cr206 0.002 •g/l zn213 0.551 ng/l pb220 0.963 •g/l C0228 0.006 •g/1 Cd228 0.002 •g/1 peak-•noisy nl231 0.081 •g/1 v292 -0.000 •g/1 peak-noisy bs313 0.004 •g/l »lndo«-edge OU324 0.300 •g/1 ag328 0.003 •g/1 peak-•noisy ba455 0. 169•g/ l 94—0090 ELT REPLICATE * 2 cr206 0.002 •g/1 peak--noisy zn213 0.557 •g/l pb220 0.930 •g/l 00228 0.005 •g/l Cd228 0.003 mg/1 peak--noisy ni231 0.069 •g/l v292 0.001 •g/l bs313 0.004 mg/1 vlndo«-edge OU324 0.305 •g/1 •g328 0.003 •g/l peak--noisy bs4S5 0. 176 •g/l / J. imo fV/ )^ ili.CI.Oi, tsT296nJ. .li AV •.••2 •g/1 80 0.0001 CV 9.39 1 10 zn213l.MD/'AV •. 594 mg/liJ.S5 80 0.0041 CV 0.79 ini. pb22e I,'NI/AV •.956 mQ/lO.lL, 80 0.e^96 CV 1.00 ni, 0 13 00228 .W.'>.J 94-0091 ELT REPLICATE » 1 1699 or206 0.009 •g/1 zn213 1.473 •g/l pb220 0.228 •g/l co22a 0.004 •g/l Cd228 •.002 •g/l nl231 0.046 •g/l 'IJ. ( ~ •.d228"" •• AV 0.OO2 sg/l «'(.- SD 0.0003 CV 12. '*' • 1231W'W'AV 0.026 ag/l ("a SD O.eo7i CV 27. i "'•' . 292 "'-''<'-A V 0.002. •g/l niL SD 0.0021 cv 93.76 1. 19 /.>'AV 0.004 ag/im^ SD O.OOOO CV oniL, CU324'/7t/' AV 0.488 mg/lC.iiSi SD O.0075 cv 1.33 njlidi Bg328't/ /:> AV 0.003 mg/ini SD 0.0013 cv 52.98 Aiiito ,o ba499'Vv J AV 0.088 •g/l ('('L SD 0.0O12 cv 1.35 94—0091 SLP REPLICA TE * J. 1632 3/02/94 cr206 0.002 sg/l peak-noisy zn213 0.241 •g/l pb220 0. 103 mg/1 co228 0.006 mg/1 peak-noisy Cd228 0.002 mg/1 peak-noisy nl231 0.010 mg/l peak-noisy v292 0.002 ag/l be313 0.004 •g/l »lndo«-edg« ou324 0.113 •g/l ag328 0.003 •g/l peak-noisy ba4S9 0.117 ag/l 94—0091 SLP REPLICA TE 4^2 cr206 000 ag/l peak-noisy zn213 238 •g/l pb220 152 ag/l co228 003 ag/l Cd228 000 •g/1 peak-noisy ni231 OlS /I peak-noisy v292 002 ag/l peak-noisy be313 004 ag/l vlndov-edge cu324 111 •g/1 ag328 001 •g/1 peak-noisy / J. T.nt ba499 , 116 ag/l riiit.f.V ar2«6aA./,i''AV •.••1 ag/l 80 ••••19 cv 109.23 zn213 <«(7^AV • .239 mQ/lDjJ 80 •.••23 cv 0.98 O.Jit pb22^ '"O-'AV •. 127 mQ/lOi4 80 •.•346 CV 27. 19 niyo 10 00228'*^ «A/''AV • .••9 •g/ l nii. 80 •.0O23 CV 49.92 niit vic Cd22a''/'/i>''AV •. ••! •g/l 80 0.0012 CV 172.98 ni •009 2 SLP REPLIC A TE * JL 1641 3/02/94 or2e6 0.010 Bg/l zn213 2.828 »qll pb220 2.336 •g/l co228 0.032 •g/l Cd228 0.004 mg/1 nl23l 0.476 mg/1 v292 -0.001 mg/l peak-noisy bs3l3 0.004 ag/l ' vlndov-edgs OU324 0.403 •g/l •g328 0.001 •g/l peak-noisy ba499 0.072 ag/l •0092 SLP REPLIC A TE * 2 cr2e6 0.005 ag/l zn2l3 2.798 ag/l pb220 2.342 ng/l co228 0.036 mn/l •n213 1. 231 •g/1 b220 2. 471 mg/l co228 1.199'mg/l Cd22e 0.621 mg/l ni231 2.310 mg/l v292 1 198 »g/l be313 O 119 mg/l cu324 1 164 mg/l ag32B 0. 328 •g/1 ba4SS 2. 424 •g/1 X R E P LICATE ¥»2 czc^ cr2e6 1. 242 •g/1 zn213 1. 227 •g/1 pb220 2.466 mg/l co228 1.203 •g/1 Cd228 0.622 •g/l ni231 2..54 3 •g/1 v292 1..210 •g/1 b»313 • . 118 •g/1 cu324 1. 188 •g/1 •g338 • . 536 •g/1 ba4S5 2. 403 •g/l or 306 1.393 •g/1 SO • •147 CV 1. 18 ZB213 1.339 •g/l 80 • ••34 CV •.19 pb22« 3.46a •g/l SO • ••34 CV •. 14 ao22a 1.3«3 •g/l SO • ••46 CV • .38 Cd228 •.633 •g/l SO • ••11 CV • . 18 nl231 3.937 •g/l SO • •339 CV • .93 v292 1.3*4 ag/l SO • 3 CV •.68 b*313 •.119 •g/l SO • CV C. 47 ou324 1. 186 •g/l SO • ••33 CV •.28 •g328 •.937 ag/l SO • •••9 CV • . 17 ba453 3.419 •g/l SO • •13^ CV •.54 »4-0090 SLP R EP LICATE * X 1623 3/02/94 cr206 0.003 •g/1 peak-noisy zn213 0.309 •g/1 pb220 2.929 •g/1 oo228 0.003 •g/1 peak-noisy Cd228 0.002 •g/l 1)1231 0.021 •g/1 v292 0.004 •g/1 be313 0.004 •g/l vlndow-edge ou324 0. 483 •g/l • g328 0.002 •g/1 ba45S 0.089 •g/l »4 —0090 SLP R EPI • ICATE or2^6 AV i.909 •g/1 111 SO 0.0741 CV 3.88 zn213 AV 7.724 •g/l I li- SD 0.2902 CV 3.76 pb22^ AV 99.361 •g/l 'M.U SO 2.7176 CV 2.84 co228 AV 1.918 •g/l 1 'IJ- 80 0.0533 CV 2.78 Cd228 AV •.927 •g/l o.ial 80 0.0271 CV 2.92 nl231 AV 2.789 •g/l J 11 SO 0.0505 CV 1.81 v292 AV 1.878 •g/l l.U 60 0.0603 CV 3.21 be313 AV •.189 •g/l a 11% SO 0.0033 CV 1.77 #»ti i'iAl.iii.1 _ ^ cu32 4 AV 7.969 •g/l —» 80 0.0O91 CV •.12 ag328 AV 1.731 •g/l 1 7J SO 0. 02«1 CV 1.16 ba499 AV 4.998 •g/l V'K. SD 0.0877 CV 1.77 tSKi^ REP LICATE ¥H 1605 cr206 -0.002 •g/l zn213 0.004 •g/1 pb220 0.037 •g/1 window-edge co22e 0.001 •g/1 Cd228 0.001 •g/1 peak-noiay ni231 0.003 •g/1 window-edge v292 0.003 •g/1 peak-noiay be313 0.004 -g/1 window-edge cu324 0.001 •g/1 ag328 0.002 •g/1 ba4S5 0.001 •g/1 peak-noisy vma/ REP LICATE 4f:2 or206 0.001 •g/1 peak-noiay zn213 o.eos •g/1 pb220 0.053 •g/1 C0228 0.003 •g/1 Cd228 0.002 •g/1 peak-noisy nl231 0.007 •g/1 v292 0.002 •g/1 bs313 0.004 •g/l window-edge CU324 0.001 •g/l ag328 0.003 •g/l peak-noisy ba499 0.001 ng/1 peak-noisy BMWK/ or206 -0.001 •g/1 80 0.0O24 CV 302.48 zn213 •.••4 •g/l 80 0.oee4 CV 9.03 pb220 •••99 •g/l 80 •.••27 CV 9.00 00228 ••••2 •g/l 80 •.••12 CV 61.13 Cd228 ••••2 •g/l SO •.•••6 CV 37.97 nl231 •.••9 •g/l 80 ••••33 CV 66.79 v292 ••••3 •g/l SO •.•••9 CV 36.46 b»313 ••••4 •g/l SO •.•••1 CV 3.04 au324 ••••1 •g/l SD •.•••2 CV 13.13 •g32a ••••2 •g/l 80 •.•••7 CV 28.23 ba499 •.••1 •g/l SO •••••2 CV 19.71 -:u324 7.663 mg/l over-range g328 0.002 mg/l peak-noisy oa45S. 0.221'mg/l /./. Illll< y riUL.".;.t cr2a6«i.'-!'.'AV 0.0O9 ag/l SD 0.0009 CV 10.23 V !• If . •: U.l zn213'.^,'<|.^V 6.040 •g/lC/.bV SO 0.0165 CV 0.27 ^••-r.< TCLf». .MO' REPLICATE *f X 1547 3/02/94 cr20e 0.011 ag/l window-edge zn213 5.999 mg/l pb220 94.016 •g/l co228 0.059 •g/l Cd228 0.007 •g/l nl231 0.909 •g/l v292 -0.004 •g/l peak-noisy be313 0.004 •g/l window-edga cu324 7.637 •g/l over-range aB328 0.003 ag/l peak-noisy ba4S5 0.209 •g/l ,94r- •0092 TCLP MS REPLICATE 4f X 1356 3/02/94 or206 1.857 ag/l zn213 7.519 ag/l pb22e 93.640 ag/l co228 1.881 ag/l Cd228 0.908 ag/l nl23l 2.733 ag/l v292 1.836 ag/l b»313 0.183 ag/l ;.Jvi f292i'J>.ir . AV 0.002 ng/1 SD 0. oeie CV 53. . .'.Ml-'.I, < ie313«oi..ii'"'AV 0. 004 •g/l SD 0. oeei CV 3.1 •.,,(,1 1 JU324 • >AV 7.631' ng/l SD 0. 0043 CV O.t. nUc),!- Bg328''y.;o'AV 0.002 ag/l SD 0. OOOl CV 7.96 O.nu ba4SSyi<«. AV 0.434 ag/l t'l) SD 0. eeie CV 0.43 94-0091 TCL P REPLICAT E 4t X 1529 cr2e6 0.010 mg/l peak-noiay zn213 8.273 •g/1 pb220 138.538 mg/l co22B 0.011 mg/l Cd22a 0.014 mg/l nl231 0.214 mg/l v292 -0.000 mg/l be313 0.004 mg/l window-edge CU324 6.791 mg/l over-range •g328 0.003 ng/l window-edge ba455 0.602 ng/l 94-0091 TCLP REPLICAT E <» 2 cr206 0.005 •g/1 window-edge zn213 8.398 •g/l pb220 140.122 •g/1 C0228 0.013 •g/1 Cd228 0.013 •g/1 nl231 0. 188 •g/1 v292 -0.000 •g/l be313 0.004 •g/1 window-edge CU324 6.775 •g/1 over-range ag328 0.002 •g/l window-edge /J. rmo ba4SS 0.618 •g/1 O0i.io.ox or206iVlL<2OA^'"'X V 0. O07 ag/l , 80 0031 CV 41.74 lom.'. I0.7 „213.u. IOO-'AV 8.335 ag/l If « 80 0878 CV 1.09 i^lLhui—>pb220 -»AV 139.330 ag/17LK. 80 1199 CV 0.80 >ii 94—0092 TCLP REPLICATE 4^ X 1938 3/a2/94 er206 0.009 •g/1 peak-noiay zn213 6.029 •g/l pb220 92.664 •g/l eo228 0.061 •g/l Cd228 0.006 ag/l 1)1231 0.905 •g/l v292 0.001 •g/1 peak-noisy be313 0.004 •g/l window-edge CU324 7.676 •g/l . over-range •g328 0.003 •g/ l peak-noiay ba499 0.214 -g/1 94—009 2 TCLP REPLICATE ¥»2 cr206 0.008 •g/l zn2l3 6.052 •g/ l pb22e 92.931 ag/l ao228 0.057 ag/l Cd22a 0.007 ag/l o228 O. 163 mg/l d22e 0. 137 mg/l nl231 0.254 mg/l v292 0.093 mg/l be313 0.059 mg/l cu324 0.462 mg/l ag328 0.047 mg/l ba43S O.149 mg/l LCS M —03 R EP LICATE ^ 2 cr206 0. 467 mg/l zn213 0.228 mg/l pb220 0.451 mg/l 00228 0. 159 mg/l Cd228 9- 138 ag/l nl231 0.243 ag/l v292 0.093 ag/l be313 0.059 ag/l cu324 0.454 ag/l ag328 0.046 •g/l ba435 0. 148 • g/l ar2»6 0.468 ag/l 80 •.^^22 CV 0.47 zn213 .22a l/l 80 •.•••5 CV 0.20 pb22» •.449 l/l 80 •.0^35 CV 0.78 00228 •. 161 l/l 80 •.^^24 CV 1.51 Cd22a •.138 ag/l 80 •.••11 CV 0.78 nl231 •.249 |/1 80 •.••78 CV 3. 14 «292 •.•93 |/1 SO • . MMl CV 0.07 ba313 •.•59 ag/l 80 •.•••5 CV 0.84 ou324 •.458 ag/l 80 O. 0OS9 CV 1.28 Bg32a •.•46 ag/l 80 0.eOO7 CV 1.55 ba499 •:i49 ag/l 80 CV 0.52 94 —00< >0 TCLP R EP LICATE 4* X 1519 3/02/94 or206 -0.006 •g/l zn213 0.835 •g/1 pb220 67.902 •g/l C0228 0.007 •g/1 Cd228 0.004 •g/1 nl231 0.077 •g/1 v292 0.003 •g/1 b»313 0.003 ag/l window-edge cu324 7.635 ag/l over-range ag328 0.002 •g/1 ba455 0.436 •g/l 94 —00< »0 TCLP REPLICATE 4^2 cr206 0.001 •g/l peak-noisy zn2l3 0.834 •g/l pb220 66.813 •g/1 co228 0.006 •g/l Cd228 0.003 •g/l ni231 0.066 •g/l v292 0.001 ag/l peak-noisy baSlS 0.004 ag/l vlndow-edgi cu324 7.628 ag/l over-rang* •g32a 0.002 ag/l peak-noiay 0.433 ag/l / 4. imo nit.0 oi or2e6ni4i/AV -••••2 ag/l 80 ••••49 CV 190.la i.bl xn213hkll^AV •.839 ag/l 0 14 80 •.•••9 CV •.1* li-i-ii. •«. lit . pb22tt'ii.<»<'AT 67.337 ag/l fc-r.ib SO •.7698 CV 1.14 ..I.. ,. -r206 0. 479 mg/l n213 0. 685 mg/l pb220 1.045 mg/l co22a 0. 435 mg/l Cd228 0.906 •g/1 nl231 0.889 mg/l v292 0.426 mg/l be313 0.464 mg/l cu324 0.428 •g/1 ag328 0.914 •g/1 ba455 0.489 •g/1 or206 0.475 •g/1 SD 0.0O64 CV 1.35 zn213 •.874 •g/l SO 0.0162 CV 1.85 pb220 1.^53 ag/l 80 0.0111 CV 1.05 eo228 0.434 •g/l 80 0.0009 CV 0.22 Cd228 •.9^4 ag/l SD 0. 0O17 CV 0.19 nl231 •.891 ag/l 80 0.0O30 CV 0.33 «292 •.428 ag/l 80 0.0038 cv 0.88 ba313 •.466 •g/1 SO O.0022 cv 0.47 au324 •.431 ag/l 80 0.0046 cv 1.06 ag328 •.919 ag/l 80 0.0O22 cv 0.24 ba4S5 •.487 •g/1 80 0.O030 cv 0.61 PREP BLANK REPLICATE mX 1459 3/02/94 *-*^'fci-206'*~ 0.001 •g/1 window-edge zn213 0.013 •g/1 pb220 0.007 •g/1 peak noisy co228 0.004 •g/1 peak •nolay Cd228 0.001 •g/1 window-edge nl231 0.018 •g/1 peak -noisy v292 0.000 •g/1 peak •noisy be313 0.004 •g/1 window-edge cu324 0.000 •g/1 peak •noisy ag328 0.003 •g/1 peak -noisy ba4S5 0.003 -g/1 REPLICATE *2 0.001 •g/1 peak -noisy zn213 0.008 •g/1 pb220 0.059 •g/1 ao228 0.004 •g/1 peak -noisy Cd228 0.002 •g/1 peak -noisy nl231 0.009 •g/1 v292 0.001 •g/l be313 0.004 •g/l window-edge ou324 0.000 •g/l peak -noisy. ag328 0.001 •g/1 ba455 0.001 •g/l peak -noisy ufiksma or206 O.OOl ag/l 80 0.0003 CV 24.81 601. jr206 AV 0. 003' ag/l SD 0. 0008 cv 17.8*. zn213 AV 0.025 ag/l SD 0.0001 cv 0.59 pb220 AV 0. 101 ag/l SD 0.O289 cv 28.68 C0228 AV O.OSO ag/l SD 0.0003 cv 0.56 Cd228 AV 0. O06 ag/l SD 0.0010 cv 17. 14 ni231 AV 0.048 ag/l SD 0.0037 cv 7.71 v292 AV 0.047 ag/l SD 0.eO33 cv 6.95 be313 AV 0.004 ag/l SO 0.eeoi cv 2.23 OU324 AV 0.023 •g/1 SD 0.0013 cv 5.73 ag328 AV 0.012 •g/1 SD 0.eoi6 cv 13.50 ba499 AV 0.096 •g/1 SD 0.0006 cv 0.60 ICSA REPLICAT E 4f X 1440 cr206 0.013 •g/1 zn213 0.028 •g/1 pb220 0.201 •g/1 peak nolay ca228 0.003 •g/1 peak nolay Cd328 -0.004 •g/1 ni331 0.021 •g/1 wlnde w-edge w392 0.003 •g/1 wlndc w-edge be313 0.004 •g/1 wlnde w-edge OU324 ••.•06 •g/1 ag338 0.003 ag/l ba455 0.013 •g/1 peah noisy XCI fl KPLXCAT B « 2 cr306 0.010 •g/l zn213 0.033 •g/1 pb220 0. 193 •g/1 peak noisy eo228 0.001 •g/l peak- noisy Cd238 -0.001 •g/1 nl231 0.001 •g/1 peak- noisy v292 0.001 •g/1 window-edge be313 0.004 •g/1 window-edge CU324 -0.007 •g/1 •g328 0.001 •g/1 ba455 0.011 •g/1 cr206 0.012 •g/1 80 0.0021 CV 18.23 zn213 0.O30 •g/l SO 0.0O3O CV 9.70 pb220 0. 197 •g/l SO 0. eo68 CV 3.43 0022a •.••1 •g/l SO 0.0O07 CV 56.86 Cd22a -•.••3 •g/l 80 0.0017 CV 68.33 1)1231 •.•11 •g/l SD 0.0139 CV 129.91 v292 • .••2 •g/l 80 0. 0O08 CV 39.73 ba313 • .•04 ag/l 80 0.0001 CV 1.32 OU324 -•.•06 ag/l 80 0.0006 CV 10.44 •g328 • ••02 •g/1 80 0.OOO8 CV 47.99 ba459 0.012 •g/1 SD o.oeo2 CV 1.66 ICSAB REPLICATE 4f X 1490 cr2e6 0. 470 •g/l . zn213 0.862 •g/l pb22e 1.061 •g/l ^ 00228 0.433 •g/l Cd228 0.903 •g/l nl231 0.893 ag/l v292 0.431 ag/l ba3l3 0.467 ag/l OU324 0.435 ag/l •g32a 0.917 ag/l cu324 AV 0.244 •g/1 SD 0.0028 CV 1. .g328 AV 0. 101 •g/1 SD 0.0006 cv 0.1 Da4S5 AV 0. 496 •g/1 SD 0.0032 cv O.6. ICB' REPLICAT E *t X 1420 cr206 -0.002 mg/l zn213 -0.001 mg/l pb220 0.028 mg/l peak- noisy co228 0.004 mg/l Cd228 0.002 mg/l ni231 0.007 •g/1 peak•noisy v292 0.002 •g/1 peak-noisy be313 0.004 •g/1 wlndow-edge cu324 -0.001 •g/1 ag328 0. 003 •g/1 peak-•noisy ba455 0.001 •g/1 window-edge REPLICAT E #^2 cr206 -0.001 •g/1 peak-noisy zn213 -0.000 •g/l pb220 0.016 •g/l C0228 0.003 •g/1 peak^•nois y Cd228 0.001 •g/1 peak•noisy nl231 0.011 •g/1 peak-noisy v292 0.003 •g/1 peak-noisy be313 0.003 •g/1 window-edge CU324 0.001 •g/1 peak-noisy ag328 0.003 •g/1 ba455 0.001 •g/1 MMH)/ or206 AV -0.001 •g/1 SD 0.eoea CV 53.72 zn213 AV -0.001 •g/l 80 0.0007 CV 76.22 pb220 AV 0.022 •g/1 80 0.0085 cv 38.07 00228 AV 0.004 •g/l SD 0. o«e6 cv 14.63 Cd228 AV 0.001 •g/l SD O.OOIO cv 77.10 nl231 AV 0.009 •g/l SD 0.0028 cv 30.58 v292 AV 0.003 •g/l SD 0.oeo9 cv 31.29 be313 AV 0.004 •g/l SD 0.0001 cv 3.35 OU324 AV O.OOO •g/l SD 0.0008 cv 3252.69 •g32a AV 0.003 •g/l SD o.oeos cv 14.70 ba499 AV 0.001 •g/l 80 0.OOOl cv 9.43 D L — I X REPLICATE 4f X 1430 cr206 0.005 •g/1 -. zn213 0.025 mg/l pb220 0. 121 •g/1 co228 O.OSO ng/l Cd228 0.007 •g/l nl23l 0.045 •g/l v292 0.050 •g/l be313 0.004 •g/1 cu324 0.022 •g/l Bg328 0.011 •g/l ba499 0.096 •g/l . D L ± x REPLICAT E 4^2 or206 0.004 •g/l peak-noisy zn213 0.025 •g/l pb22e 0.080 •g/l eo228 0.049 •g/l Cd228 0.005 •g/1 nl231 0.051 •g/1 v292 0.045 •g/1 v292 en 226 be313 EH -704 CU324 EH 647 ag328 EH -^88 ba455 EH 1222 BLANK REPLICAT E m-z cr206 EH 126 zn213 EH 1272 pb220 EH 110 C0228 EH -9 Cd22a EH -143 nl231 EH -108 v292 EH 1 42 be313 EH -832 CU324 EH • 881 ag328 EH -25 ba455 EH 1268 ar2«6 176.0 80 7^.7 cv 40. 2 CONC •.••• zn213 12B9.S SO 24.7 cv 1. 9 CONC •.•00 pb220 9^.« SD 28.3 cv 31. CONC 0.000 00228 36. • 80 63.6 cv 176. CONC 0.000 Cd228 62.5 80 29a. 6 cv 465. CONC 0.000 nl231 !•. 5 80 167.6 cv 1596. CONC 0.000 v292 134. • SD 13«. 1 cv 97. CONC 0.000 b»313 -768.• 80 9^.9 cv 11. CONC O.OOO CU324 764.8 SD 165.5 cv 21. CONC O.OOO ag328 -156.3 SO 186.8 cv 118. CONC O.OOO ba4SS 1245.* 80 32.5 cv 2. 6 CONC 0.000 ICV REPLICATE It X 1410 3/02/94 cr206 0. 247 mg/l zn213 0. 240 mg/l pb220 0. 492 mg/l O0228 0. 243 mg/l Cd228 0. 098 •g/l nl231 0. 2S6 •g/l v292 0. 245 •g/l b»313 0. 049 «g/l OU324 0. 246 •g/l •g328 0. 102 •g/l ba455 0. 499 •g/l ICV REPLICATE 4^2 cr206 0. 245 ag/l zn213 0. 243 •g/l pb220 0. 498 •g/l C0228 0. 240 •g/l Cd228 0. 100 mg/l nl231 0. 246 mg/l v292 0. 242 mg/l be313 0. 049 mg/l OU324 0. 242 mg/l •g328 0. 101 •g/l ba455 0. 494 •g/l ar206 i 0. 246 ag/l 80 •. B0e9 CV •.39 zn213 i •.241 ag/l 80 e. 8021 cv •.89 pb22B i •. 499 ag/l 80 •. 8043 f.a7 00228 i •.242 ag/l 80 •. •021 s ; •.98 Cd22a i •. •99 ag/l SO •. ••13 cv 1.29 nl231 i • 3S1 Mi/l SD 0. M71 rv 2.81 RESULTS OF ANALYSIS: DIGESnON DATE: ,^\a^W ANALYST: PA CONCENTRATION (ugfL) SAMPLE IDENTIFIER: EU SAMPLE NUMBER: ANALYSIS DATE ANALYST UNITS Aliiminiim r-T-^'? oV ng/L Antimony' Ai\ Digestion Dale: -Ol'^Mia^ Analyst: P^ '^ PLASHA 400 Analysis 4. 10 Wed 03/02/94 - 13t47i34 Hethod File Naae: RHK Replicatesi2 Read Delayt 70 Reaarkai Rayaark treatability! TCLP, SLP, ELT. Data File) 0228 ID/«t file ia RHK-2 STANDARD X REPLICATE 4f X 1349 3/02/94 cr206 EH 110873 zn213 EH 206062 pb220 EH 46508 co228 EH 96788 Cd228 EH 123420 nl231 EH 80795 v292 EH 205671 be313 EH 275941 cu324 EH 497343 ag328 EH 112814 ba455 EH 129405 STANDARD ^1 REPLICATE ¥1^2 cr206 EH 116793 zn213 EH 206906 pb220 EH 46826 co228 EH 95141 Cd228 EH 122961 nl231 EH 88657 v292 EH 204021 be313 EH 2880S2 cu324 EH 496973 ag328 EH 118966 ba45S EH 129441 or2e6 AV 113833. • SD 4186.I CV 3.7 CONC 2.9^^ zn213 AV 286484. • SO 996.8 CV •.3 CON C 2.9^^ pb220 AV 46667. • SD 224.9 CV •.9 COH C 9.^^^ oo228 AV 95964. 9 SD 1164.6 CV 1.2 CONC 2.9^^ Cd228 AV 12319a. 9 SD 324.6 CV •.3 COH C l.^^^ nl231 AV 84726. • SD 9999.3 CV 6.6 CONC 2.9^^ v292 AV 284846. • ^0 1166.7 CV •.6 CON C 2.9^^ ba313 AV 281996. 9 SD 8963.8 CV 3.^ COM C •.290 ou324 AV 497158. • 80 261.6 CV •. 1 COM C 2.9^« •g32B AT 119898. • 80 4398.1 CV 3.8 COMC l.^^S ba499 AV 129423. • SO 29.9 CV ••• COHC 9.^0« BLAN K REPLICATE m X 1401 3/S2/94 cr2^6 EH 226 zn213 EH 1307 n»..>.}A PM TA lU — ^iU :u324 002 mg/l window -edgf CCB.' tlEPLICATE ^ 2 pb220 006 mg/l peak-noiay cu324 003 mg/l kiiJiiaiJ pb22e AV .002 ag/ l SD 0.0110 CV 594.95 CU324 AV ,002 ag/ l SD O.O0O8 CV 36.35 CCV REPLICAT E mX 1635 3/03/94 pb220 605 mg/l cu324 319 mg/l CC V REPLICAT E 4^2 pb220 680 ag/l cu324 297 ag/l itiAeimuy fcf.f' pb22« AV 642 ag/l 80 0.0533 CV 2.02 /<»V. U • OU324 AV 308 ag/l 80 0.0155 CV 1. 19 rb antli Cu. -rap d.LUs 'VZ.^16 te.V^b mg/l wlndow-edgj J324 0.002,mg/l ICB ( REPLICAT E 94-C9(a9CO TCL P REPLICAT E 4f X 1615 3/03/94 pb22e 7.913 mg/l CU324 1.216 mg/l 94—<2»e>9e TCLP REPLICATE 4V 2 pb220 8.015 •g/l cu324 1.231 ag/l n rmfl £J UI.Ut,„ pb220 AV 7.964 ag/l SO •.•721 CV •.91 Kli^.iiU'tl ott324 / AV 1.224 ag/l 8 0 •.•1*9 CV •.89 p m .i^.U,.. A.fn. 9'«- 94-0091 TCLP RBPLXCATK « 2 pb33a 19.860 ag/l ou334 6.645 ag/l urm a is> •'.,,/.LA.1^ (A^\ ' 0 1 i,i • tjt.i, Bb22^<4kA«AV 16.3«9 ag/l ' * ^ SO 8.6297 CV 3.86 U>.r/.4. /ii«^" Bi]it}24 / AV 6.673 ag/l BO •.•383 CV O. 37 ». Iti ' U «.«. -f/J 94—0092 TCLP REPLICATE « 1. 1633 3/03/94 pb220 l^.466 ag/l cu324 0.965 ag/l 9 4 — 0092 TCLP REPLICATE m ZZ pb220 10.070 ag/l iri** cu324 0.969 ag/l •»«4 pb220 «;<.«««V 10.268 •g/l «»^'H 8 0 •.2886 CV 2.73 0.967 •g/l O.Oul 8 0 •.••29 CV 0. 30 iaa.:;:.T.OX.EU.:..np R E P L I C A T E 4 f X 1629 3/03/94 pb220 11.355 •g/l CU324 1.075 •g/l a.;'ju'f C3X.,^R.uMiy REPLICATE 4^2 pb220 11.321 •g/l CU324 0.942 •g/l , pb22e AV 11.338 •g/l*^^ 8 0 8.0237 CV 0.21 ltou324 AV 1.008 •g/l[|.oo/lSD 8.0939 CV 9.31 2 TCLP M S REPLICATE 4 f X 1628 3/03/94 pb220 11.191 •g/l ou324 1.561 ag/l » 4 —0092 TCLP MS REPLICATE pb22e 11.022 •g/l ou324 1.560 •g/l pb220 AV 11.1^7 ag/l«fT+f- SO • . 1194 CV i.^a Hethod File Naaei NaK2 .'\ , Repllcatesi2 Read Delayi1 99 Reaarkai Rayaark treatab^il\yi TCLP, SLP, ELT. Data Filei 03038 / PLASHA 400 Analyais Ver. 4. 10 Thu 03/03/94 15i57i54 Hethod File Naaei RHK Replicatest2 Read Delayi 90 Reaarkai Rayaark treatability! TCLP - dilutions 9 1/0. Data File I 0303D ID/Nt flla Is R-DIL STANDARD *I REPLICATE m X 1601 3/03/94 pb220 EH 38406 cu324 EH 408832 STANDAR D 4^1 REPLICAT E m-z pb22e EH 40356 wl.ndow • edge CU324 EH 403177 pb220 AV 39381.0 SD 1378.9 cv 3. 5 CONC 9. OOO au324 AV 486MI4.5 50 3998.7 CV 1. 0 CONC 2.900 BLANK REPLICATE m X 1609 3/03/94 pb220 EH 294 CU324 EH 427 BLANK REPLICATE «r2 pb220 EH -103 OU324 EH 631 pb220 AV 99.9 80 288.7 cv 293., 9 CONC 0.000 CU324 AV 929.• SD 144.2 cv 27.. 3 CONC 0.000 XCV REPLICATE ^^x 1608 3/03/94 pb220 0.497 ag/l CU324 0.252 ag/l IC V REPLICAT E 4»2 pb220 0.529 ag/l OU324 0.291 ag/l *lkktMMM 103.C pb220 AV •.913 ag/l SO •.•221 CV 4.32 RAYMAKK MEIHOD FILE AUTO SAMPLER LOG O.SiMB 38. «. 1 EUMEKIS: O.r.In .Ph-Cc^il. K ] Xj.Uu.^oA a 1. CAUBRATKW 39. Tl. 9ujn*A^ DATE: ahh4 ^ k 2.BLAfaCCAL. 40. 78. ICV ANALYST: KhS w [a. ICV 41. 79. wmmm SI1KESOLUT1(»(:IOOsL(M-aS)-t-50iiL(M-30)OIOOppoi -^ NIA S 42. ""• |\L -1^^ H_ SAMPLE AMOUKT: 10 mb \ 4|0 CA 1, 5.1%.-IX 9 43. 81. XCSA »«*»:Oa-(a^/)ael ID wuik:-ra+-i.. 6. KSA 44. 82. iCSi^B 7. ICSAB 45. o- QM-ooqo f?oufnrtrk- ~TreA+ai>iliKi .<;^uiv' - S.ls. — C2-CS- JO- q'^-ooqn 4S. •6. Wlooq» hiR^ •* n. q«^-oo9i 49. «7- q«<-ooqi ms OI L Sampl»<: -C).' "T^IOLI rVJc'laii 12. P-i-DDQa., 50. ««• JCSA 6o.4c>i*OA- ' ><• t^-ooQa. ni5 52. «»• Hl^ IS. OBlBSf 53. 91- OCV 16. CCV-/ 54. 92. '?un^'^_ ^.PbandZn w-e3-w 17- Pffffi Alo.-;!^ 55. 93. /?„nA? ^n,|mnrk 4r*a.-(ab.l.iij f^-^cU Oa-oa-qU-/ ^ 18. C|.^.ci3u 56. 94. J:OJ (;3 i^odiliJioo o/^ 1 oo-rmO \ 19. C.J.-,::; i 57. 95. |m(« "Dida. t oa.cn6 Tn Lof : D*!- - 1 20. .'•'.J .(-M?--' 58. 96 DL- nc Foi' LCS ano. Prfp ftlnntC nnri. nfC nihfv 21. 1/..I . f (,j,-N 59. 97. ICSA 22 •R«r--ftl4n rrtW 60. «• XCSAO, / 23. Qii.oigp^s 61. 99 qM - OC)«^ \ 24. JCS*^ 62. ' " ZCS.A ^n^.? : r... 25. ICS^Q 63. 101. jcsflB Pnitmn.iL -kfn4nhilik{ Samr^lr H (^4-009 i 26. SWT? 64. iV. B3C9 IS) liioc c^^uL^1an o r o~ l too -rrrij\ 27- C^V/-rl 65. '°» GCV/ Dfl-la. nsLD^R> JDa:>+ ^ C.tx^ - 1 7t. 66. 105. P>' ^il n>filn>r. . 30. 6«. 31. 69. 32. 70. 33. 71. 1 34. 72. k 35. 73. 1 w 36. 74. 1 37. 75. 1 • ^ -mue>um • .^^ 1 cuMuatm muNocns Ullt. •muL T.V. T.V. CALB. KMt rat (UJO) nXMD RNMO •MO) POUND VALUE c VALUE % OMS) VAUIC lOlMD BBIDfr OMI) oa •m. T.V. rv cv lEC CCV.1 •BC CCV. crvc uc T.V. VALUE • a jjpo UB UB Or» CLBD IJ S OJDS OrSM 0.001 0.0)2- INS05 UB us 0.355 I0S.O 1.191 05.3 I.J5/ 'JS.I OSB lou.S I.BD 1.25? OJB IMTO -o.wo <9.a'5 l L. OJOI a.ue n «aM IAD OLMO OJDD 2JB OJB IkZS 0.001 O.Oi? 'J590-7 US 0.^3 q«4.(> i.i^i ni.^- 5.?^/. 93.(, mat 2jgD OJS ISO OJB h\q, IJB oirn CoBi -0003 O.OA;?. q57l^ UBO eoB D-aso lOD-O R5.^ 1.(73 v.^ J OdSf 1400 am I04.D OJB OLIB O'OO'i 0.003 laitiao O.IO'i D.bp3 %.5 0.5?(p (f3.^ r'v' ij NIBI o.oo? 0.010 85917 UBD OBO o.an»i l&'J'j 34l,(} NISI uae 02* UBO oos f ^f^ oiao UB ••ZS3 aioi ^ -^ ••JM OJB 0«D ens OJSM V192 ir>^S(«i UOD a3» qs.o IJS /./il O.MS O.DDl D'CCS o.ifS i.iU3 93-p %(} ej» OJOS OLQI •M t k)!] O.0f"J O-ooJ ^gksao 0.D52. IN.D Dil9 %5.2. (D<'iDlortccYer.f IDIsOCa ,J ^-. "D,3;'.^-hnr-| OAlnC^ oanuMSKT ta. ex. MOD. IOO - \ DUPUCATE trKEAMDai«M-li) / •ELAT ANAl. s > vms. OBSaVB) tAMTLE > y ELEM EXT* ACTUAL FOUND uc. OMCINAIN DUP DOFF ADDED trocE KEIULT / 1 N Cr 3B 0X1 — X IJB C.X6 / OJI - O.OiC' IOO O \ IJB Zs2l3 OXB ^ IJB O.OlJ (t5 p \ / a]i4 OAS \ OJO N / Lo, OLIO — O.O^i q:?.c N " » y HiUI AM ^N IJB ; Cos OM O.CHI Q-^.O \at/ Cd2B QJD5 O.OOl HO.O ^ \ NIBI AM O.o^S 19.0 •O / \m \ .-•• NIB: 0« \m \ ••ZD 0.10 ' XOO \ . / \ ••»• OJOOS aio / v w 0JB9 O.C«JP IJB \ OAU / ••31) O.D05 \DD. C •.B \ CnZM OAS o.oai / \m \ • > A«ja •Al •JD 0.001 -ID.D / •. •.4U \ •.M C'./o-:i. 109.0 / UO ^oai :c6 fZ';'c"Kj.:p,r''"^2;>/-^ "^^_^'T.!.1.'L FRE-DIGESnON DATA Date/Analyst l^rep- jkloti PA ^ ?i i/}ji) ^gn . zhlnu >>v. SampkID 9'I-OOR2..^ Amounts of Sample Used ) cm^ • loomDs . -hn^r- / v>l,.-n.,- I -'OO T . Commeiltsl^fl.^ch ^ O^-OQ-q^J-/ - gg^jnnr.H S:-vl£ --^g»4r.k.l.-k^ nng:-..>'>^. mn find fn<: hD>r^ L^lru- [-J.>%AJ2 1 ion T m.O OtOr.. o...-iiffv<.^ PfecmlLCS ic; CT^I/^^. I IQQ -rmC Analytes to be Detennined ^r.7n.flb • ^r . Cc^. V, 6>, /!j .V ^n/j 7^ Analytes Spiked; with M-S4 Ob \ mk. SOOppin « Ba.Cu and Pb. lOOppm = Cr.Co.NJ.Ag V and Zn. lOOppm = Cd. 20ppm = Be. Spike added: ."^^^^ l^s.^.P^n. o2pp-.T:/"V Vr KI. ./^-V^^n lp|^m - T-d 0 •) ^.-^lYiy. - fi^ @7iO(JiUio C .••) <: n METALS Jo P6 Cc dd \f k a. ^ Ba. Pb Original O'Dl MD Sample 6.?D (,.3S Di4 BDL 3.n /IO /5.5iffercncei i:. - i'^: — i.l': O^^o — .v.sr. (B'5*' 'V.O'I Observed C.'?/ Spike y.V2 9.^? I.SD l>.$24 iS3 i-i4 i?./i 15.33 /S.-IS ll*X Spike- ® Original /.^;2. ^.H\ l.l^L £)«V i.3u i.ul D.ni aii ^7^ 0i3-l Result (1) id) % Recovery Si.O W5.5 i3 0 .?.?.'J USD i3.5 S55 (p.5 nd nd no 0.5 ndc 1 % Recovery 05.? g/V wo ilU, S-5-V Si.V K.'i 10.11 }{5.U NOTES: (Dnia-trif SciN.. -To- Zn.A.!../l3* fefi (jrc nol icjftrn Ia[if)ra7yv' ^-liDi Umih /op75-/3g%\. /»// rr'^lvy OHlnr r?.v Li-i-fhm |.-i r^r,^,rvi ^-rrt,^' )•>!•«; . r<(er^ /'tr. (?•• ^ompt Ci^nc. 7 ^t SP,^-- ^-n^ (V. Pr,.-,^r^ n.-f ..-.i^h.o 7r; •,.?q'Vr" fonki limi/s pA^a f'pOfkd ItnrJj^jrL FRE-DIGESnON DATA Date/Anahst Pfgp" ^klpd Pfi ^Ji^.-. ! Al,. a^ilcrj •vxc Sample ID P*/- OIMQ . Amounts of Sample Used^ p. ^ q^wim - 5ortdS, -hn/tP I vJi.m/ z. \ \00 T.m.C^ ^ Comments ftnrh ^ 05 - r>:^ • QM - I Un L.C<> ni^iin'cL -fL m^Xr',,. rv^-t^h - fnp and m^ ^' C^.^'^ Wr-|) Analytes to be Detennined_ ^r.Pbflnd cl Analytes Spiked; with M-54 Gt I mis. SOQppm « Ba.Cn and Pb. 200ppm = Cr.Co.NJ.Ag V and Zn. lOOnnrn = Cd. 20DPm g Be. Spike added: Pb • lOfNpm ^.'. ^ypm Cd •- ^ o^ry-) IMETALS ^^h eJ Original Sample CCI ND BD.. Duplicate f o.:t 1^0 BD- Relative % | — 1 Difference 1 Cl: Observed Spike 3.% S'.oo ''5? Spike 1 Original j.W J.oo /•5f 1 Result % Recovery ns SO.O 79.0 Whgf&tOi nLl r^ilO LCS Digest ') y. T.V. M - Jc , c \ ^••^ m*'- 1 If" < M.)r!. .'- 1 Found 1 1 % Recovery 1 / NOTES: 2CP INTERFERENCE CHECK SAMPLE Lab Nane: Contract: Lab Code: Case No: SAS No.: SDG No.: ICP ID Nxanber: l^U Concentration Dnits: ug/L True Initial Found Final-^'Tound Sol. Sol. Sol. Sol. Sol. Sol. Analyte A AB A AB %R A AB %R Aluaxnuin_ .'Sno.Qnn 600.000 ^ - t Antimony" Arsenic Bariun SOO 1 1 M7§.0 qs-u l£lL •/77.f Beryllixan ^C^Q ^UO.O q<9.0 V6/.0 Cadaiua iSSH. -I Poo.o QO.D 'g'sq.Q Calcixun •^'-^ i>^ " ^ i^o ^ — I Chromiua_ ij^lXL •^53 O .£a:l£. juru L I Cobalt Z ff^' * • JnHia^ (Ji^rj ONE - 24 Revision I December 1987 CTMOMBI Q ^ 1 CAunxnoN i Bon law. BmiAL T.V. T.V. CALB. FOt RMt FOUNO RNMO OMO) POUND VALUE VALUC i ELEUBKr AMI) VALUE • « OMB) s RNMD ICV OCV-I 1 uc 1 CCVt 1 CCV.3 1 nc 1 T.V. 1 VALUE 1 • Cl ca 1 wm. T.V. rv IK 1 a» UB •so 1 I.3B 1 OLBO 1 om UB asB I.3B OJB IJB -n.DDS •6.071 Iff?(/(j0 UB OJB D.aif>i lOSiln 1.178' P«/.,2, OJB 1 01»4 IJOB •LNO •Lfi5 •LIB 1 MSB o.ni^ O.DOl ws UO OUB P-W qq.f? iS.1^9 ^7-i' U B / OJB 1 NISI 2JB us UB ,1 OJB Si 1 CoSi UB OSO IJB -c cm r 1 QI2B • JOB CNO •JB - ^ e.UD ^ • 1 NISI ZJB aas U B ^ OJB 1 -H- ~ 1 NIZK UB oas UB OJB r^ 1 1 ••zn IBO OJB UB :? aMi 1 kZM 0J» OOB •.IS OJOM -3: 1 * 1 VJ95 U B OJB 1 IJB •.WI •^ 1 1 kJIS a.2B OJBS OLOS OuOM 1 OiIM -0 oo\ 'Ci.CO^l Mifl ZBO OSS O.J$,? /0(.,2. y./?^ '^..^ IJB OJB ) A«ni liB CLMB { OJB { •JM* 1 / \ 1 1 o.tu MB 1 OJB ZJB 1 - 1 Ml 1 Dior 0C< •»'. ' I 1 BOnUWEKT OLOL tW-X. KM T \ OUIUCATE SPKE •ELAT ANAL. tna.. • mcE OBSEKVQ) tAMTLE / 1 1 ELEMOrt 0 ACTUAL FOUND OWC04Al^ DUP DIFT ADDED snKE 1 USULT ' \ Ci»5 0.01 — \ IJB I C>3Dt 0.01 — \, IJB 1 ZB}I) OJB c.oai lOt o \ IJB 1 Cd in OBS \ •JD / .' \ H,7X> O.W — [j. ii4 ilU ' \ UO ^ \ NiZIl ftst \ IJB / \ / 1 Co2a om MJB -^ 1 Cd33i oat •Ik 1 NiSI ' OM IB \ 1 NiZB •JM IJB \, 1 UTa 0.10 / UO • ' \ ktZM CODS •.M \ y 1 vjn om IJB \ ••Jl) y yf* aw \ 1 ,. Q.I M OJU C-OZ^ ^lij>.C y \m \ \ | / ^J A<» OM OJB { \ \ ••4U e.M / UO 1 " .Lo-ru«nilV L -^~ ^ (liK,Pti a.^ri Ir^ 1 ICP INTERFERENCE CHECK SAMPLE Lab Name: Contract: Lab Code: Case No: SAS No.: SDG No. ICP ID Nunber: p)ncmn Moo ICS Source: SCSfi z rrt .us.. Concentration Units: ug/L 1 1 1 1 1 1 1 True 1 Initial Found j Final^'Tound | 1 1 Sol. Sol. 1 Sol. Sol. I Sol. Sol. 1 1 Analyte | A AB | A AB %R | A AB %R | I I I ! 1 lAluminum I.XV^IMQI 'vr>.oool 1 I I 1 1 i I 1Antimon y I I ! i l l 1 i l1Arseni c l l l I I I t 1 1 Barium I 1 ^uin '^(Z da'In and P\> ONE - 24 Revision 1 December 1987 ^^^^" £»i»un •^ aim unoN •nwc •aK» LOM •onAL T.V. T.V. CALB. IW rot oun «MJO) FOUND fOUNO «M0) RNMD OHB VALUE % VALUE s AMD VALUC S FOUND ELDIBNT out) RBC OCV-I •BC OCVt 0CV.2 • r» oa MTS. T.V. icv KV U C T.V. VALUE IJS OLBO O S UB •JS - IJB OLBD OraH UB OJB IJB ban UB um OJB 1 on ais 01314 l«D aMo 1 i i M OJB ZSO OJB nzs / • < MBI UB (Las ISO ( OJB k Co as ZJB aas IJS T am ^ etas •JBD am OLO ^ ais MSI a.Bo •JS ISO ^. •JS ^ 1 *"" 2JB OJB UB OJB ^ ••20 UB •JB UB ^ aMi ....^ -a - oas BAB an •UOM ^ VJ»S ZJB oas IJB 1 aiof hll) oas u s atai / •Mt \ Cam D.OCQ. 0DC2 53055/ UB oas ^.il,Z id^S I.S3.2 95.6 IJ S •JB ] A ' DfarQCi ^-.^ Dicy.'t;^ rT'fr/.O'-- inihdi P.u MznuMBn-DLacoMaMMi i \ DUFLICAT E SFKEiM-B^M-aS) KEIAT ANAl- araa • S SPKE OBSESVED CAMFLE / OXMEKT* ACTUAL FOUND KEC. oucbtAL Dur DOT ADDED SFSCE KESULT / CiBS Ul - \ IJB / \ CtZX OJOI — \ IJB y Z«2I] niw \ IA / a 114 0.009 \l •LB / Fkax aw — \ XOO / . Niaii OAt \ tm / CIS OitS \ ,M y i '^^^ OAB . ^ 1 "l^' OM / i - \ II "I™ •At / IJB \ ••zn aM / 2JB \ \_ >.iy •JOB / aio 1 ^™ OB y IJB v y ••31) OJOB / aw ' \ CkZM •BB 0.035 /OO.O / I.B \ A(Si OOI X as \ •,4U aw X 3JB r ^. ^ ICP INTERFERENCE CHECK SAMPLE Lab Name: Contract: Lab code: Case No: SAS No.: SDG No.: ICP ID Number: '^aejrta. '^oo ICS Source: JJos.A rr\.(j,^ Concentration Dnits: ug/L 1 1 True 1 Initia l Found j Final^'Tound 1 1 Sol. Sol. 1 Sol. Sol. 1 Sol. Sol. 1 Analyte j A AB j A AB %R | A AB %R l l l l {Aluminum t^oOjOoo.. 1,50(0,0001 1 I I 1 1 i lAntimony 1 I I I I I I 1 1 l{Arseni c l l l I I I t 1 1 Barium 1 1 >^oo 1 I I I 1 I I IBervlliumI 1 ^oo i 1 I I I t 1 1 Cadmium I I i,coo 1 1 I I I I I ICalcixjm 1 ^^,fjc'^ 1 '^jo.flonl 1 I I I 1 1 •Chromium 1 1 soo 1 1 I I I 1 i 1 Cobalt 1 1 .fbO 1 1 I I 1 I I ICODoer 1 1 v5D0 1 -J? 1 USS.O 1 T1.0 I « 1 *f3S.O 1 ^.t# •! llron lomnrr) l.9on.ay)l 1 I I I I I ILead 1 I 1 I.DO O I I I H I I IMagnesixial^T), nop 1 .'ionia->n\ 1 I I I I I 1 Manganese! | SYJTN 1 1 I I I I I I1 Mercur y I I ! I l l I I 1 Nickel 1 I 1 i.nnD I I I I I I |Potassi\2a| I I I I I I I I ltSeleniu a l l l I I I I I 1 Silver j j ), noIo I 1 1 1 I I l1Sodiu a l l l I I I I I IThalliua | | | | | | 1 ... 1 1 {Vanadium j j c^rr. t 1 I I I I I IZinc 1 I1 ),nt> ^ I I I I I I 1 l l l l I I I I I R v«.n CUL ONE 24 Revision 1 December 1987 PWO METHOD FILE AUTO SAMPLER LOG CUMB N. 76. 1 ELEMENTS: mr\l'' 1)7. On , Cu nnrI A\ 39. • 77. ^^i2A 1 DATE: ;jitM 2. BLANK CAL. 1 40. 71. Za/ 1 ANALYST; -JlW XCB \ SPOCE SOUmON: IOO al(M-74) 3. EV / 1 ^'' 79. 4jgB 42. ao. PftpBlanK. | SAMPLE AMOUNT: 10 •». 5. 'rr<:-rtr-m 43. •1. LCSm-SS «««*«= i^O.- OiDib IDWlJik: PUO - «l. '• «^'^-0/5A 44. t2. LCS/n-SS 'ItO II 7-9)3:srR^ 45. 13. 9*1-0090 4/0 1 1 7^-Miililiy/' .. . Ct\\iS fiaxvmark.^ fl «• M.qu.^nP; '/W-/ 52. 90. '^ R.\in^J-. •- hdoi. nn i K_ 1 "• flWf 53. 1 Ooiabilki -for KJO, plus .... ^uniar/c— ^ diliLivn .J u "• CL\I- 1 54. 92. uif- / lOO-rmO >7ai4-"ocqiftny 55. 93:^ fifi^Ch > ^5-03-0^-1 /S^ iioo-rmo. 56. 94. Dcrta: M»4 i XOiL^f. pu,».«4 '9 fCCfff 57. 95. Niofr: LCSm-^3 rtohr^A u.->/Lis nr75 20. tcv-i. 58. 96. 21. 59. 97. Icr »Ja or\i K — Sre iCP pr.n-l 22. 60. 9«. cx:+ -for OA/OC Da.+a, • 23. 61. 99. . 24. 62. IOO. 1 23. 63. 101. f^un .:?^ -. K_ 26. 64. 103. Da-fa. O^lo lOiLri- : K-l | 1 2'' 65. 104. 1 ^' 66. 105. 1 "• 67. 106. 1 '°' 6>. 1 3' 69. 32. 70. 1 ^^' 71. ^ 72. 35. 73. 36. 74. 37. 75. FWO METHOD FILE QA/QC FORM Date/Analvst: HJ^U^ STANDARDS »3S0 CALIBRATION REFI 3UMCE ICB CCB CCB lau T.V. TV for ICV a ICV %RK CCV %Rac CCV % M-73 CCV(M.72) ZDe213 2300 1.000 Fee23S D.tD:L O.OIO 0.00% Hi>3mn 5.000 iMO 61.03') io>..i. j.cn lOI^'l S.OI2. iOi fi. M1I0257 O.DOl COOl ooo^ 3^^^9? IMO 0300 0.$P7 lOI.-l o.^n ic3 '1 O-bcl to IL Fe«259 O'DPil C-ODIJ O.OOifi I'I9UIL- SMO 2J00 ^.Q^J 101-I 5.C5"7 lOS.'l a.DdiU io MnO260 O.DOl D :'D3 O.oo4 Ql9?S.^ IMO 0300 D.52I iD'l.i' 0-521 /PV.^ G.50% ID' 50M0 25M0 t Mc0 279 -D.CC/} -0.003 -Opr^^ 3mn •^if-^l /C5 .i- au.sv 101^.3 sn.a^ iO' MC0 285 -COOS -O-CDZ. - .- r»n5 V-J^/)?*/ 50.000 25JI00 iS-Oif^ IDO.3 35^Tl4 103.1 3i5.5^ lOB L Ca«317 o.cco 0 mip •0 DOO ?^sm 50X00 25JMW iS.iU. IOO. 5 JISSS^ IDS.:L dS^iiil \Di t> Cae324 D.COl 0 0n\ c.pr» ShlJo^^ 2300 IJMO i.oil 101-9 lOlU lOI-U 1.017 fOI /. AIO 396 D'OOi. COOly o.o 15 '3'51g 5.000 2M0 Ue>3Z io\.\ ^.0^3 WS.U. iP.osrt lOi Sample Id for OA/OC Analysis; '^•^•O'S^L / 0. ia& ^v'^ j-rc OiO*-i>-nc/i Q(>IIGC \OY raiirnarL, irea4n.b«l. IU/ •DUPLICATE f ANALYTICAL SPKE (M-74) ELEMENT Orig Dup. Rfl. « SpikeAdded Spike Observed Original - Spike % Recovery DifT. ZngiZU 2.50 Fe ® 238 10.00 E. MI102S7 BDW 80i- — 1.00 I.OO I.OO »on • o E Fe ® 259 BDi- fsJD ^ 10.00 1003 10 05 IOO.3 Mn®260 1.00 t Ms® 279 l.SS I.n • •l'r, 20.00 J^.^L P c^l.Ol IDS 'i M«®2S5 20.00 (L Ca0 3I7 i3-^A i /^ffepcrlca ittjutjenffrtv.. FRE-DIGESnON DATA Date/Analvst Pirg.p- cikh^l P.A, (\r\oLj/^!^i Sample ID q*/-oc93 Amounts of Sample Used Inmjvt - iDomJs Ln.u? \)r,himt^ -• I'OD rmc ^^ifimMHits Saith ^ o^.-Ooi-'^^-\ mnrrnH m^ o<; irp r^oH^t-f boJA.: i 7^^? T^O OdhJtJi^fK y Analytes to be DetCTmined TCiriiU.i Oh . Ca , UJ . nn/l Al . kin K Analytes .Spiked; witli M.54 Oi I mk. SOOnnm ^ Ba.Cu and Pb. 200DDm « Cr.Co.NJ.Ag V and Zn. lOOppm = Cd. lOnnm a= Be. c ; Iml. fe.\(nx\)'\,Da)pom «ilm-\h\ wcnfipm Q.Smls • m/a3>gl" looopfltn /\lafpi 7t;\icQ -pl: .^ fl (mm)ioooppm (maq^Ca loccfipiri Spike added: ^ppm : <^n f;° nnWtfl--topp m *sppm : mr>.>Jn .da .K.anA ma \ ^^^"" f2^'/ipdilu^rM K"-. onri Al : Ippm ^n,*Ja. ^'A •><. and nOt?: D.5ppm yf Spiki addfci METALS mn k f(\o ^a_ 4^ Lqi Nia K Original A, Sample 0-^1 •/•5i %!i3 1.71 M.^^3 6oi • 3.i5 Duplicated 0.34 i3.i\ 21.1,1 I'S^i ii o 6DL .375 Hdative %.f Difference f i?.i i'.i •i.S 13 l».5 — (i^ Observed Spike D.^l ,3.37 33 it J.i5 53^ o.*a /u.ih chisX S.05 Spike * = • ; Original © 5.50 0.75 D.i4 /.3(p Result 'J.-¥iit i-.'io (i) % Recovery ICDO TS.O lOS.O .. i3fe.C f/q.i iDi.C AlDc NO SOL 1 ^5 IP o?.5 10 <5r NOTES: 0 Ctt * MA f^e^ls -Ucia -from rkI run : Sec (fa4a. »/•»/ 0. 16. gamns; ftl, Co., ft^ .ma and fflm • ^la atxil K. T l.CAUBRATXm 39. 77. DATE: ^l3/l4 2.BLANKCAI. 40. ANALYST: >L 3. ICV 4t. '^•^*3ani*3 SHKESOUniOH:l00ri(M.T4) ) ^/^ £^^ diaUlt. •0 • -lai SAMPLE AMOUKT: 10 a b } ff^lOC fa flfi>ffl. 11. Oaia.0303 tOWLFOe: puiCt-t <• LCS in-?3* ^g^6iflfj|C^ 1. ITS ifl-VS^ Ai. O\JK>W^75» "k'n,p»fi<- ->r 70^ 9l-DD9iL -WLP M- <>A-mi. mP 49. "tfHiwBlS/ '^- 9^-0092.. ^ so. tt-q4-ooQa.'ms' ii-9-1-0090 ^Lf> 51. «9. 04 -OMO 5cP ^un ^;Z •- Kin. C>dfl03 16. CCY- J 54. 92. JS. IL^ and Cal im-li.] 3.500 ppm 17. 9-l-DCliStJ> 55. w. gy- t!ki ICp pimi fttti and c/iorsfen Q^/o^ hrm IB. O'l-ceic U.T 56. 94. QJ.(>;»-. CLT •{V all QW^'C da fa. 19. i?"^ /)^?/ ttr 57. 95. fl^.a>7/ £.L-r 20. n.{-CD1J- U T 51. »6- ^'^ 00?.- et"^ 21. 59. 97. .fiZL Cc/'^ 60. 9t. ttV-,J- fiim »5 • ^ Oa^g JO u> ft^^c-,^ 23. 61. 99. 24. 62. 100. Oa.^^J•^^^^ SitJ \li\li \ iSopopCuvf 25. 63. 101. ICV iin.'J CCV ' mi3}\ SSOO pprr\ 26. 64. 103. '5(1 iCP P'lnf^ oa-l onff ciiOt^hort. Q^lac 27. 65. 104. •frrm fiy a\\ Q^IQ C tJoL^o 2>. 66. 105. 29. 67. 106. 30. 6S. 31. 69. 32. 70. 33. 71. 34. 72. 35. 73. 36. 74. 37. 75. FWO MEIBOD FILE QA/QC FORM Date/Analyst: 'ihli'l •STAHDAROS o - *"' CALDBATION unatENCE ICB CCB CCB im T.V. TVferlCVA ICV %Bac CCV %Vm CCV « M.13 CCV(M.73) ZaeS U 2J00 1.000 F*e23S O.OOl «n?T 5X00 2M0 MB e 257 -0.003 3D>II9'I \XM OJOO DJo\ loo.a Pe0259 D-DDI •O.OoS -OJol in ll o SMO 2M0 S.Oi[, 101.« ^.a6'\ 112.1* ^.li S IC Miie260 D.DOI 0.00 3 -D.DDO Mil S IMO 0300 o.s\^ 103.1/ 0.5i^ \\3.i* 0'3i^ iC Mice279 -0.D2O 2733iO 50.000 25.000 35.33^ iO\.3 e. M(e285 -o.Dsi -0.051, -D^&Sl 3UI3I5 50.000 25JW0 36.h1 101.5 ait.ido IOO.? ss.ni 10 CaC317 -DDD5 -coot -ceil ^I3i>30 50JNN> 25.000 3l.flD q9.7 30. OIO lao-i* a9.f3e> Hf Die334 2300 1.000 ' 410 396 D.OO^ coon O.ODl I15S35 5.000 2.000 a.Mj.' lOD.L* a.m lOl.f i.q ( •« > nolo Recot/cfij ) Sample Id for QA/QC Analysis: NIA -Set digiJift-. i^*^l<^ DUPLICATE ANALYTICAL SPKE (M-74) Fl.FMENT Orig Dup. Rd. « Spike Added Spike Observed Original - Spike DifT. y ZnQlU 2.50 yy Fe@23g \ ^ 10.00 X' Mn®257 ""^v.J.00 / Fe @ 259 10.00^>< ^ Mn@260 M. " ^^^ Mg0 279 / ^ 20.00 M«0285 ^ 20.00 ^-v ^ .^ Ca®317 20.00 ^"\ ru®324 y y 2.50 \ •il®396 y 10.00 •"^ f\:i^v\d tuiiJt;/wf^ PRE-DIGESnON DATA Date/Analvgt>p ^3U^ p/t- firalijftii^ iCu yg/a/^/ >w Sample ID W-gg?«z> ittP Amoimts of Sample Used ;fgm>s - too mJs hnJL \iolafu.y /.^ -vno LLS'siP i ir/r. Cmnments Pxiir'n ^ /?? -aV- mil (xnL m beJau) hJtrt Imd i-i TmO CyUcdtJtn,- Analytes to be I>etenniiied_ ftl, (U-TL ,Plo .mn , kla. and. H^ Analytes .<;plked; iHth \I.Sd tm I mk. SOOomn « Ba.Cu and Pb. 200Dnni = Cr.Co.Ni.Ay V and Zn. lOftnnm s Cd. 20nom « Be. 1ml />l//r-/5^lOJOPPffl , fL/in-Zl)lOiy)fLfUf D5rn)i lni-39]U\0onpOrri, m-i&)^is.\mffin (Ml)r>i3limMrn (in-ii\mn ICc uni ^mnnj K lat Spike added: Te and A\ •- in ppm (?a.>Ja,)c,/ri/; and n\f.: Spflm METAL S ^ /Hn /rid LV /ll tic /L J Original M. Sample 0.^3 ^./^ 5.05 /1».0 o.sJ |.M«} o ^.^3 ^.^^ i.oi /S.T 0.?5 1.51 a(aafiuE3(^ ^ a 0% '^ ^ o.«iL 6.01,1 Ul. C l».6 Observed l-r 70.3 7.i/ 9.V«' ioi P.?/ G. k. ^.71 Spike e'-2 Wl Spike- •5» . —o Original w Il.l1 J.^r "/."/J 4.SD 3.30 Result if.'?? % Recovery iCCif lO'/.O :rs.i# %.D ?n H MD Hi nU 0.0L m^ O.IO 0.iD o.;{0 % Recovery? 98.0 «?io 92.1 Mil IIU.O tM.9 %3 NOTES: (D T^V. frxtlrn SP.KC -QI ^.1a<.<.iun\ IS nt>^ uJMrtifi normeLl UhtrainiLj gtiT/tef limih of [iS-li: /til c-fh^y 0«/G>C IS IPIUI ^ norm? I 1^/K' RE:PLXCATE : 4»2 {•23a -0.000 •g/1 paak nolay Hn2S7 0.000 •g/1 paak nolay i>2S9 -0.003 •g/l paak nolay Hn26e 0.001 •g/1 p«ak•nolay Hg279 -0.047 •g/1 Hg283 -o.0sa •g/1 paak-nolsy Ca317 -0.011 •g/1 paak- nolay • 1396 0. 004 •g/1 *lndo«-adg* /•238 «v -•.••1 •g/1 SO •.••13 cv i^6.sa Mn2S7 A« -••••• •g/1 SO •••8 CV 483.88 .f»2S9 A« -••••4 •g/1 SO ••21 cv 3^.3« fe23a AV 2. 197 •g/1 so 0.0224 cv 1.92 Hn2S7 AV e. 51S •g/l SD 0.0143 cv 2.81 fe2S9 AV 2. 12S •fl/l SD 0.0384 cv 1.81 Hn2«-' AV 0.329 •g/1 SD 0.0132 cv 2.88 Hg. AV 28.166 •g/1 SO 0.3600 cv 1.28 Hg:t AV 25.172 •Q/l SD 0 .2887 cv 1.15 •g/x fa2S9 e. 018 g/1 Hn26e 0.238 ag/l Hg279 3.304 ag/l Hg28S 3.041 ag/l Ca317 8.312 •g/ l a 1396 0.126 •g/ l IJi tmo i*>it\ 94 —0092 . E:L:.T REPI^XCATE : #2. 1144 3/^3/94 fa238 0.014 ag/l paak-nolay Hn237 0.248 ag/l fa2S9 0.010 ag/l nn260 0.236 •g/l Hg279 13.195 •g/l Hg2a3 11.711 ag/l Ca317 16.625 ag/l • 1396 0.017 ag/l paak-nolay 9 4 — 0091 E:I_T REF»L-ICATE 4^2 fe23a 0.015 ag/l nn257 0.243 ag/l fa2S9 0. 016 ag/l paak-nolay nn260 0.248 ag/l ng279 14.027 ag/l Hg2a3 12.713 ag/l Ca3l7 13.620 ag/l • 1396 0.027 ag/l r J. !"io M'-) fc238 AV 0.013 ag/l SD ••13 CV 8.73 Iln237 ,/ ** 0.246 •g/ l SO ••27 CV 1.89 niio IC fe239'iiJ.dvA V 0.013 •g/ln.l SO ••38 CV 28.88 O'OO Hn260.Vt/AV 0.232 mg/in 94-0092 EL-T RERLIGATE 4H2 fe238 0.014 ng/l Hn257 5.012 ng/l ovar- -range fe259 0.010 ng/l nn260 4.817 ng/l Mg?- 15.824 mg/l Ma 14.465 mg/l CB J 42.657 mg/l Hg279 29.342 ag/l Hg2BS 27.448 ag/l Ca317 30.304 ag/l • 1396 2.036 ag/l CC V X RERLXCATE 4»2 Xa23B 2. 304 ag/l Hn237 0.361 ag/l Xa23B AV 2.299 •g/1 SO 0.••88 CV •.33 Hn237 • AV •. SS0 -g/1 SO 0.8166 CV 3.^3 la239 AV 2.234 •fl/l SD •.•176 CV •.78 nn268 AV •.569 •fl/l SO •.•156 CV 2.73 Hg279 AV 29.133 •fl/l SD •.3788 CV 1.98 Hg2B3 AV 26.7aa •fl/l SD 1.8369 CV 3.96 Ca317 AV 3^.016 -g/1 SD •.4^67 CV 1.33 al396 AV 2.033 -g/1 SD •.•••9 CV •.•4 94-0092 SUR RERL-XCATE •i 1134 i»23B o.oia ag/l Mn237 1.313 ng/l fa239 0.016 ag/l I1n260 1. 602 •g/1 Mg279 4.843 ag/l Hg2a3 4.036 ag/l CB317 13.941 ag/l • 1396 0.097 ag/l 94-0092 SLR RERLXCATE 4» 2 fa23a 0.011 ag/l paak-•nolay Mn237 1.510 ag/l 94 — 001 >2. SLR RERLXCA TE m X 1118 3/83/94 fa23a 0.019 ag/l Hn2S7 0.062 ag/l fa239 0.014 ag/l Hn260 0.069 ag/l Hg279 2.913 ag/l Hg285 2.472 ag/l Ca317 6.003 •g/l al396 0.013 •g/l >00« »X SLR RERLXCA TE 4^2 fe238 AV -O.OOl •g/1 SD O.0009 CV 103.24 nn257 AV -0.OO2 •g/1 SO 0.0014 CV 56. 27 >fe259 AV -O.eos •g/1 SD 0.0009 cv 17.83 •nn260 AV 0.003 ag/l SD O.0023 CV 69.84 rig279 AV -0.O49 ag/l SD 0.0010 cv 2. 12 •ng28S AV -0.056 ag/l SD 0.0013 cv 2.28 .Ca317 AV SD O.0002 cv -o.ooa -g/1 2.21 «B1396 AV SD 0.0041 cv 55.23 0.007 -g/1 CCV — X RER LICATE ^ X 1128 3/o: 2.293 mg/l \.,m^A / lO. / iJ, • y/ X ,.,,.,., al396 0.879 ag/l 94-0092 TCLR MS RERLXCATE 4^ X 1187 fa23a 10.812 •g/ l Hn237 3.001 •g/1 ovar- •range fa239 10.324 •g/1 Hn260 7.284 •g/1 Hg279 11.002 •g/1 Ha285 9. 273 •g/1 Ca317 20.636 •g/l a 1396 9.812 •g/1 94-0092 TCLR MS RERLXCATE ^ 2 fe238 10.333 •g/1 Hn2S7 3.002 •g/1 ovar- •ranga fe238 AV 10.683 •fl/i 60 0.1832 CV 1.71 Hn237 AV 3.002 •fl/l SD 8.8806 CV 8.81 10.3 fe2S9 AV 10.327 •g/1 60 0.0033 cv 8.83 /ilHn26a AV 7.343 •g/1 SO 0.0837 cv 1.14 ng279 AV 10.838 •fl/l SO 0.2310 cv 2.13 y ./K Hg283 AV 9.473 •fl/l SD 0.2863 cv 3.82 Je.r Ca317 AV 20.771 •fl/l 60 8.1903 cv 8.92 im al396 AV 9. SOS •fl/l 60 0.0109 CV 8.11 94-009 0 SLR RERLXCATE 4^ X 1112 ia23a 0. 040 •g/1 nn237 O.OSS •g/1 fa239 0.032 •g/1 Mn260 0.052 •g/1 Mg279 0. 464 •g/1 llg28S 0. 406 •g/1 Ca317 2.654 •g/1 . a 1396 0. 088 •g/1 1 94-0090 SLR RERLXCATE <» 2 la23a 0.021 •g/1 peak--nolay Mn257 0.044 ng/l fe259 0.018 mg/l Hn26e 0.051 ng/l Mg279 0. 473 ng/l Ng283 0.419 •g/1 Ca317 2.760 ng/l a 1396 0. 104 ng/l / z ymo „',1'V te r AV 0.031 •g/1 SD 0.0136 CV 44.28 *»•**> Mn: / *v 0.050 •g/1 Wt> SD 0.0077 CV 15.52 noi-»o.iofe; 'IWAV 0. 02S •g/lHI'i- SD 0.0099 CV 39.59 94—009X TCLR RERLXCATE •2 /•238 0.203 ag/l Hn237 0.380 •g/1 fa2S9 0.199 ag/l Hn26a 0. 40a ag/l Hg279 4.3B5 •g/1 Hg2a3 4.233 •g/1 Ca317 33.132 •g/1 a 1396 0.673 •g/1 / u.tmo i>i) fa238 AV 0.210 ag/l SD a.8898 CV 4.67 Hn2S7 . AV 0.401 -g/1 SO a.8306 CV 7.62 C.-io le259V*i AV 0.200 »g/10JO SD 8.8812 CV a. 62 O.i-I Iln26a rvc'^ AV 0.419 -g/lO.VJ- SO 8.8136 CV 3.71 "g279 ^ AV 4.393 •fl/l 80 a. 8138 CV 8.33 til) Hg2B3r >•(>>* 4.149 •g/iV./i 80 8.1189 CV 2.87 uil Ca317fc*.«'-' 32.713 •g/l i.i.1 SO a.3928 CV 1.81 I JJL. •1396'-'."' 94-0092 TCLR RERLXCATE 4» X 1836 fa23a 0.230 ag/l Hn257 1.924 ag/l la239 0.228 ag/l Hn260 2.018 ag/l Hg279 3.360 ag/l Hg2a3 3.026 ag/l Ca317 16.217 ag/l a 1396 0.840 ag/l 94-0092 TCLR RERLXCATE 4» 2 fa23a 0.242 ag/l Mn237 3. 131 ag/l fa2S9 0. 228 ag/l Hn260 3.233 -g/l Hg279 3.498 -g/l ng2e3 3.071 -g/l Ca317 13.722 -g/l al396 0.830 -g/1 / J ""Cl (-•A) la238 AV 0.236 •g/1 SO 8.8888 CV 3.74 Hn237 y AV 3.038 •g/1 SO 8.1683 CV 7.88 O.ill. • Xa239 <-c >* 8.228 -g/lO-Ji 80 8.8882 CV a. 11 1,it Hn26a/''«> AV 3. 136 -g/1 nl SD 8.1661 CV 7.78 Mg279 ^. AV 3.329 •g/1 80 8.8438 CV a. 79 10.1 Hg283'<'-'» AV 3.848 -g/l If • 80 a.8328 CV 8.63 ll.O CaSl7 *«••«'»''AV 13.978 -g/l'i/.c. SO 8.3497 cv 2.19 i,tf .1396'.4lo '^AV 8.833 •g/1 t'Jy SO 8.8866 cv a.78 '0092 TCLR MD RERLXCATE 4^ . 1182 3/83/94 fe23a 0.223 -g/1 «n237 2.164 ng/l fe239 0.227 ng/l nn26e 2.132 mg/l Mg279 3.493 ng/l Hg283 4.901 ng/l CB317 13.136 ng/l • 1396 0.826 mg/l •0092 TCLR MD RERLXCATE * : le238 0.222 mg/l Mn2^- 2. 116 mg/l le: 0.233 mg/l Hnl 2.326 ng/l Hn2S7 -0.002 ag/l paak-nolay Xa2S9 0.001 ag/l paak-nolay Hn260 O.OOS ag/l Hg279 76.S34 ag/l Hg2aS 78.971 ag/l Ca317 95.612 ag/l al396 0.143 ag/l LCS M —-^S* RERLXCAT E 4^2 1-238 AV 0.003 -g/1 SO 0.0832 CV 63.89 Hn237 AV -0.001 -g/l 80 8.8813 CV 133.91 fa2S9 AV 0.001 •g/1 80 8.8881 CV 6.86 Hn26a AV 0.003 -g/1 80 8.8826 CV 78.63 Hg279 AV 76.693 l/l SD a. 2232 CV 8.29 llg28S AV 78.4S4 i/l »1i 80 8.7319 CV 8.93 Ca317 AV 94.633 -g/l 94—0090 TCLR RERLXCATE mX 1046 3/83/94 fa238 0. 003 -g/1 nn2S7 0. 133 -g/1 94-0090 TCLR RERLXCA TK 94—009X TCLR RERLXCA T E <• X 1831 3/83/94 le238 0. 216 ag/l Hn237 0.423 ag/l le259 0.201 ng/l Mn2'-- 0.430 mg/l Hg: 4.606 mg/l Mg2 4.065 mg/l Hn26a AV a.aai ag/i 80 8.8843 CT 314.2a Mg279 AT -8.828 ag/l SO a.aisi CT 74.87 80 Hg28S AT -8.834 -g/l 8.8894 CT 27.31 80 Ca317 AV -8.883 ag/l 8.8269 CT 387.44 SO •1396 AV 8.889 ag/l 8.8828 CT 32.34 RRER B L RERLXCATE 4» X 1838 3/83/94 -0.O04 ag/l Hn237 -0.003 ag/l wlndo«-adga fa2S9 0.001 ag/l paak-nolay Hn260 -0.000 ag/l Mg279 -0.043 •g/l Mg283 -0.052 •g/l paak-nolay Ca317 -0.013 •g/l paak-nolay a 1396 0.003 •g/l paak-nolay RRER RERLXCATE •WW • a ll « • fa23a -0.002 •g/l nn2S7 -0.004 •g/l fa239 -0.005 ng/l paak-nolay Hn26e -0.000 ng/l paak-nolay Hg279 -0.048 ag/l Hg2B3 -0.055 ag/l Ca317 -0.007 ng/l paak-nolay a 1396 0.008 mg/l paak-nolay ffTgwmt le238 AV -0.003 -g/1 60 0.0011 CV 39.40 Hn2S7 AV -0.004 -g/1 SD 0.0003 CV 13.19 niivio fe2S9 AV -0.0O2 -g/1 60 O.0042 CV 178.37 '•die,).)- Hn260 AV -O.OOO -g/l 60 0.0003 CV 138.81 Ilg279 AV -0.047 -g/l SD 0.0019 CV 4.17 0j<». LCS M —a3' RERLXCATE 4f X 1033 3/03/94 le23a 0.253 ag/l nn2S7 0.246 ag/l fa259 0.245 ag/l nn260 0.233 ag/l ng279 -0.039 ag/l Hg2as -0.049 ag/l Ca317 0.091 ag/l • 1396 0.224 ag/l LCS M-as ? RERLXCATE Ie23a 0. 249 ag/l Hn2S7 0.251 •g/l le259 0.246 ag/l nn260 0.237 mg/l Mg279 -0.039 ng/l Mg285 -0.047 ng/l paak-nolay CB317 0.066 ng/l • 1396 0.240 ng/l le23a AV 0.252 ng/l SD O. 0045 CV 1.77 I1n257 AV 0.249 -g/1 SD 0.0O33 cv 1.32 le259 AV 0.245 ng/l SD o.oooa cv 0.31 Hn260 AV O. 235 •g/l SD O.0025 cv i.oa Ng279 AV -0.039 •g/l SD O. OOOO cv o.oo l1g2P"^ AV -0.048 •g/l SD o.eoii cv 2.25 Car 0.078 •g/l SD 22.90 AV 0.0179 cv alo 0.232 ag/l SD 4.97 AV 0.0115 cv ..y^/ i bt* A W>> — Hg28S EH 310 ^ Ca317 CN 193 al396 EH 0 fa238 AV 84.3 80 28.3 cv 24. 3 coac a. Iln237 AV 1843.3 80 387.6 cv 36. 2 CONC a. IC V RERLXCAT E m X 1828 3/83/9 fa23a 2.009 ng/l Hn257 0.501 ag/l fa2S9 2.030 ag/l Hn260 0.513 •g/l Hg279 25.757 ng/l ng2a5 25.826 mg/l Ca317 24.753 •g/l a 1396 2.027 ng/l IC V RERLXCATE • 2 fe238 2.050 ng/l Mn257 0.301 ng/l /e2S9 2.042 ng/l Mn260 0. 513 ng/l Mg279 24.699 ng/l ng28S 24.906 ng/l Ca317 23.086 ng/l • 1396 1.996 ng/l la23B AV 2.029 -g/l 60 a. 0298 cv 1.43 Hn2S7 AV 0.581 -g/1 SO 8. 0802 cv 8.84 la239 AV 2.836 -g/1 60 a. •888 cv 8.43 Hn26a AV 8.313 -g/l 60 8. •884 CV 8.88 Hg279 AV 23.328 -g/1 60 a. 6863 CV 2.39 Hg2a3 AV 25.367 -g/l 80 8. 6323 CV 2.37 Ca317 AV 24.928 -g/l SO a. 2333 CV 8.94 al396 AV 2.812 -g/1 80 a. •228 CV 1.89 crcs^B* RERLXCATE 4^X 1823 3/83/9 le23a 0.002 -g/l nn2S7 -0.001 -g/l peak -nolay fe239 0.003 •g/l »lndo» adga Hn260 0.004 •g/l paali -nolay Mg279 -0.010 •g/l Hg283 -0.028 •g/l ' €•317 0.014 •g/l • 1396 0.011 ng/l ;x-CB' RERLXCAT E 4^2 ie238 0.001 ng/l Mn257 -0.002 ng/l peak -nolay fe259 0.002 mg/l paali -nolay Mn260 -0.002 ng/l peah -nolay Mg279 -0.031 ng/l ng285 -0.041 ng/l CB3'" -0.024 mg/l Bi: 0.007 mg/l wind o«- edge ^•v.rr.or'r PLASHA 400 Analyala Ver. 4.10 Thu 03/03/94 lOiOSiOB Hethod File Nanei PWO RepllcBtaai2 Read Delayi 70 Reaarkai Rayaark treatabilityi TCLP, SLP, ELT. Data Fllei 0303 ID/Ht STANDARD 4t X RERLXCAT E 4^ X 1089 3/83/94 le23a EM 122311 Hn257 EM 306987 fe2S9 EM 117887 Hn260 EM 171057 Mg279 EM 278822 ng265 EM 365406 CB31 7 EH 209719 a1396 EH 116304 STANDAR D » X RERLXCAT E 0^2 fe238 EH 121663 Hn257 EH 301401 fe239 EH 116592 Hn260 EH 167169 Hg279 EH 267818 Hg2B3 EH 357223 CB317 E H 216341 al396 EH 11476S fe23a AV 121987.0 60 458.2 CV 8.4 CONC 3. O00 Hn2S7 AV 304194.0 8D 3949.9 CV 1.3 CONC 1.000 1-259 AV 117239.3 80 915.7 CV 8.8 CONC 3. 000 Hn260 AV 169113.0 SD 2749.2 CV 1.6 CONC 1.000 Hg279 AV 273320.0 60 7781.8 CV 2.8 CONC 30.008 Hg2aS AV 361314.3 80 S7B6.3 CV 1.6 CONC 38.888 Ca317 AV 213030.0 60 4682.3 CV 2.2 CONC 38.888 al396 AV 11SS34.3 SD 18aa.2 CV 8.9 CONC s.e^^ BLAN K RE R LICAT E * X 1014 3/03/94 le238 EH 99 Mn257 EM 630 fe259 EM 187 nn260 EM 335 Mg279 EM 369 Mg285 EM 557 Ca317 EM 84 • 1396 EM 73 BLANK RERLXCATE 4^2 !38 EH 70 57 EM 1461 94-0090 ELT RERLXCATE 4^ X 1244 3/83/94 NBSBB 1.739 ag/l NaS89 1.374 •g/l 94-0090 ELT RERLXCATE ^ 2 NB388 1.783 wg/l 1.233 •g/l NaSBS / AV 1.761 ag/l SO 8.8313 CT 1.78 v.ojL Na589'.(./a AV 1.383 -g/ l l.)l SO 8.8989 CT 7.38 94-009X ELT RERLXCATE 4^ X 1246 3/03/94 Hasaa 3.902 ag/l NBS89 2.663 ag/l 94-009X ELT RERLXCATE 4»2 NaSaO 3.513 •g/l NBSa9 3.371 -g/1 ' * '""> luf •> NaSBB / AV 3.787 -g/l 80 8.2749 CT 7.42 (.0.1 HaSe9('.r«'<' AV 3.818 tta/llDi.. 80 8.4997 CT 16.96 94-0092 ELT RERLXCATE 4^ X 1249 3/83/94 NB38B 1.124 -g/1 Na5a9 0.7BS -g/1 94-0092 ELT RERLXCATE ¥»2 Hasea 0.910 -g/ l peak--nolay NB5a9 0.S3B -g/l • . . . j ^ li'il'L 1 1 J if'iO "'^ NaSBS / AV 1.817 ag/l SO 8.1311 CT 14.86 1 i.L HaS894l UKCl'Uf RERLXCATE 4^ X 1291 3/03/94 Hasaa -0.109 -g/l vlndoa-adga NaS89 -0.047 -g/1 paak-nolay ttPBSMIf RERLXCATE ^ 2 Nasaa 0.079 ag/l peak--nolay NBSa9 O.OSO -g/1 NaSBB AV -0.813 -g/ l 80 a.1323 CT 888.49 cp«w9rr AV a.aa2 -g/i so a. 8689 CT 4823. 44 CCV 2 RERLXCATE 4^ X 1233 3/a3/94 NaSBB 32.224 -g/1 NaSB9 26.231 -g/l CCV - 2 RERLXCATE 4^2 Nasaa 34.022 mg/l NBSa9 20.710 -g/l HaSBB AV 33.123 -g/l 80 1.2717 CT 3.84 «%6c. 9.3,1 Ila389 AV 23.481 ag/l 80 3.9178 CT 16.69 W?/) ^ —^5 KL yn 94-0je>92 TCL R MS RERLXCATE 4^ X 1231 3/83/94 NaSeO -0. 183 -g/1 ovar-ranga NBS89 -0.209 -g/1 over-range 94-0092 TCLR MS RERLXCATE 4»2 Nasea -0.197 ng/l vlndov-adga NB589 -0.192 mg/l ovar-ranga HaSaa AV -8.198 -g/1 SO 8.8896 CT 9.86 Na3a9 AV -a.281 -g/ l 80 8.8116 CT 9.8« 94-0090 SLR RERLXCATE 4» X 12^ 3/03/94 Hasaa 0.641 ag/l HaSa9 0.042 ag/l 94—0090 SLR RERLXCATE 4^2 Hasaa 0.306 -g/1 3.2BB ag/l I 1 irnO Nasag NaSBB / AV 8.714 -g/l 80 a. 1797 CT 29.19 J ii Ha389 J,4'/«AV 1.663 ag/lMtl 80 2.2937 CT 137.86 94-009X SLR RERLXCATE 1239 3/03/94 NaSBB 8.777 ag/l NaSag 0.929 ag/l 94-009X SLR RERLXCATE 4^2 Hasaa 1.22B ag/l HB3a9 0.934 ag/l '•"'•"' ,;,o NaSBS y AT 1.883 ag/l 80 8.3189 CT 31.81 >rf NaS89'.tro AV a. 942 ag/l 0.11 80 a. 8178 CT 1.89 94-0092 SLR RERLXCATE 4^ X 1238 NaSBB 0.37S ag/l Hasag 0.447 ag/l 94-0092 SLR RERLXCATE 4^tZ NBSBB 0.346 ag/l NaSB9 0.268 -g/l 1 1 in'b ,,jli) NaSBB AT a. 361 ag/l 80 •.•206 CT 3.72 NOOc NaSagnJ / AT •.337 •g/ieOL. SO 0.1272 CT 33.98 CBBf RERLXCATE 4» X 124a NaSBB 0.031 ng/l alndow-adga NaSB9 0.091 ng/l paak-nolay tscsnw RERLXCATE 4^2 Nasaa -0.021 ng/l «lndov-adga NaSB9 0.098 ng/l NaSBB AT 0.883 ag/l SO 8.8364 CT 747.96 raiisaaT AT 8.893 ag/l SO 8.8846 CT 4.86 CCV X RERLXCATE •X 1242 NaSBB 25.087 ng/l NaSB9 21.899 ng/l CCV X RERLXCATE 4»2 U.nt%n RRER BLANK RERLXCATE 4fX 1218 3/bd/94 RSSBT^ -0.073 ng/l «lndo«-adg» NBSa9 -0.012 ng/l RRER BLANK RERLXCATE 4»2 -0.067 ag/l vlndoa-adga HBSS9 0.077 •g/l paak-nolay NaSBB AV -8.871 -g/l 80 a.aasa CT 8.38 m.lt'i' NaS89 AV 8.833 -g/l 80 8.0629 CT 191.14 LCS M RERLXCATE 4^ X 1228 3/a3/94 NB5B8 13.B93 ng/l NB389 10.304 ag/l LCS M-'7SJ RERLXCATE 4»2 NBSBB 13.099 ag/l NBS89 10.744 ng/l NaSSB AV 14.496 ng/l 80 •. 8926 CT 9.88 lO.U •a389r AV 1^.624 -g/l so •.17^e CT 1.6* 94-0090 TCLR RERLXCATE 4^ X 1222 3/03/94 NaSBB -0.199 ag/l vlndo«-adga NaS89 -8.194 ag/l ovar-ranga 94-0090 TCLR RERLXCATE *2 NaSBB -0.190 ag/l ovar-ranga Na3a9 -0.220 ag/l ovar-ranga Ha 388 AV -8.193 ag/l SO a. 8064 CT 3.29 Na389 AV -•.2^7 ag/l 80 a.8187 CT 9.80 94 -0« t9X TCLR RERLXCATE 4»X 1224 3/03/94 HaSBB -0.186 ag/l «lndo«-adga NaS89 -0.207 ag/l ovar-ranga 94 - »9X TCLR RERLXCATE 4»2 Nasaa -0.176 ag/l ovar-ranga Na589 -0.220 ag/l ovar-ranga NaSBB AT -0.181 -g/ l 80 8.8067 CT 3.72 NaS89 AV -8.214 ag/l SO 0.0091 CT 4.29 94-00 >2 TCLR RERLXCATE 4^X 1227 3/03/94 NaSBB -0.196 ag/l vlndow-adga NaS69 -0.231 ag/l wlndov-adga 92 TCLR RERLXCATE • 2 Nasaa -0.131 ng/l over-range NBS89 -0.209 ng/l over-range NaSBB AV -0.163 ag/l SO 0.046O CV 28.19 NaSB9 AV -0.220 ag/l SO 0.0161 CV 7.32 94-00^ • 2 TCLR MD RERLXCATE 4f X 1229 3/03/94 NaSBB -0.189 ng/l vlndov-edga NB389 -0.20B ng/l over-range 94-001 ! TCLR MD RERLXCATE 4»2 NaSBB -0.196 ng/l over-range PLASHA 400 Analyala Ver. 4. 10 Thu 03/03/94 12103110 Hethod File Namei NBM2 Rapllcataai2 Rea d Delayt 99 Renarkai Raymark treatabilityi TCLP. SLP, ELT. Data FllaI 03O3B lO/Ht file la PHO-2 STANDARD 4^ X RERLXCATE 4^X 1209 3/03/94 NBSBB EH 2SS33 6 HBS69 EH 3014S B STANDARD 4f X RERLXCATE 4^2 Nasaa EH 209247 NB3a9 EH 2a4Bll NaSBB AV 232291.3 SO 32389.8 CT 14.0 CONC 90.000 Nasag AV 293134.9 SO 11771.2 CT 4.0 CONC 90.eoo BLANK RERLXCATE 4fX 1211 3/03/9 4 NBSBB EH BBB NB5B9 EH 976 BLANK RERLXCATE 4^2 NaSBB EH 1007 NaSB9 EH 1397 NaSBB AT 947.9 80 84.1 CT 8.9 CONC Oa M v Na389 AT 1286.9 SO 439.1 CT 34.1 COHC XCV RERLXCATE 4^ X 1213 3/03/94 NaSBB 29.321 ag/l NaSB9 23.480 ag/l ICV RERLXCATE 4^2 NaSBB 31.008 ag/l NaSB9 23.60S ng/l NaSBB AT 30.263 ag/l SO 1.0313 CT 3.47 9tAc: in,x R*S89 AT 23.342 Bg/l SO 0.0884 CT 0.3S BBCBf RERLXCAT E 4^ X 1216 NaSBB -0.197 ag/l window -adga NaSB9 0.080 ag/l tXTSWI RERLXCAT E 4» 2 Na^nn -a i'?7 .../I 41 ng/l peak- -nolay limb ' 'vf) . o. lnii.o R766MI( / AT 0. 41 •g/1 BD 0. 007 CT 1.99 iKO RERLXCAT E 4H. 1421 3/03/94 K766 0. IB ng/l peak- -noiajr RERLXCAT E 4^2 K766 0. 28 ng/l AT 0. .23 •g/1 BD 0. •69 CT 29.88 CCV - X' RERLXCATE 4PX 1424 3/03/94 K766 23. ,37 ng/l "CCV - X RERLXCATE K766 23.91 ag/l *%tAC: <»9;e R766< AT 23.74 ag/l SO .242 CT 1.02 94-0090 ELT RERLXCATE 4ax 1426 3/03/94 K766 2.33 ng/l 94-0090 ELT RERLICATE K766 2.67 ng/l I a »n* IVJhi J •Hi K766 J,tto AT 2.61 ag/l SO ,081 CT 3.11 94-009X ELT RERLICATE 4ai 1428 3/03/94 K766 2.04 ng/l 94-009X ELT RERLICATE K766 2.31 -g/1 I i rnift /OJ/L) / ll J'I R766 4!jV(rAV 2.17 ag/l BD 0.186 CT 8.97 94-0092 ELT RERLXCATE 4» X 1431 3/03/94 K766 3.24 ag/l 94-0092 ELT RERLXCATE 4»2 K7e6 3.99 ag/l I 8 imo (ujli.) , I'tp R766 r.Jeo AT 3. 68 ag/l 80 0.906 CT 14. 06 RERLICATE 4ax 1433 3/03/94 K766 -0.03 -g/l RERLICATE 4^2 K766 0.06 ag/l AT 0.02 ag/l SO 006. 4 CT 412.80 CCV — RERLICATE 4»X 1439 3/03/94 K766 20.86 •g/l !CCV — 2 RERLICATE 4^2 K766 21.01 ag/l ^ f&CLCt ffS.f K766' AT 20.94 ag/l BD O.106 CT ^Cti/-3. t loin rfrrt^.i .intrliA^ iili*n -•xM.Vt/W /^A«^ • 130S-1j!.-M-^V3r RERLICATE 4^2 K766 110.03 ng/l ' 1 •' itMirvrear AT 109.oa ag/l 80 1.361 CT 1.29 94-0090 TCLR RERLICATE 4^ X 1402 3/03/94 K766 2.76 ng/l 94-0090 TCLR RERLICATE 4^2 K766 3.12 ng/l / J. rmi (ufli) yf.tt R766 J,|« AT 2.94 ag/l BD 029. 8 CT 8.77 94-009X TCLR RERLICATE 4»X 1409 3/03/94 K766 1.34 ng/l 94-009X TCLR RERLICATE 4^2 1.36 ng/l K766 1.49 ag/l 80 0.196 CT 10.77 rf-'O R766 .».<»(«'AT RERLICATE 1407 3/03/94 94-0092 TCLR 1.49 ng/l K766 94-0092 TCLR RERLICATE 4^2 K766, I.48 ng/l .?^l R766.?.«»/ AT 1.49 ag/l BD 0.007 CT 0;44 RERLICATE 1409 3/03/94 K766 1.31 ng/l • r RERLICATE K7e6 1.67 ng/l '$1 R766 AT 1.99 ag/l BD O. 112 CT 7.07 0092 TbLf* HS RERLICATE 4^X 1412 3/03/94 K766 4.77 ag/l 0092 TCLf» MS RERLICATE 4»2 K766 4.62 ag/l ^71 R766 AT 4.79 ag/l 80 003. 9 CT 0.82 0090 SLR RERLICATE 4^X 1414 3/03/94 K766 0.86 ag/l 94—0090 SLR RERLICATE 4»2 K766 0.73 ag/l I:A -miO |q(J BOL ID/Wt llle la PWO-2 STANDARD '4^ X REPLICAT E 4^X 1348 3/03/94 K766 EH 96069 STANDARD 4» X RERLICATE 4^2 K7e6 EH 61330 R766 4.1 COHC 90.i AT 39799.9 BD 2447.3 CT BLANK 1391 3/03/94 K766 RERLICATE 4» X EH 172 BLANK RERLICATE 4^2 K766 EH 279 R766 AT 223.9 SD 72.8 CT 32.6 CONC O.OO ICV RERLICATE 4^ X 1393 3/03/94 K766 26.18 ag/l ICV RERLICATE 4^2 - K766 23.86 ag/l 7«be:'M4:| R766' AT 26.82 ag/l BO a.230 CT O.BO K766 RERLICATE 4^ X 1399 3/03/94 0.12 ag/l wlndov-adga RERLICATE 4^2 K766 -8.02 ag/l AT 0.09 ag/l BD 0.099 CT 214.70 RRER BLANK K766 RERLICATE 4» X 1398 3/03/94 RRER BLAMlg 0.02 ag/l paak-nolay K766 RERLICATE 4»2 -0.02 ag/l paak-nolay Hg Log DmtdAaiAnl. <^M^'/ yvl Chart Spood. JQAJ .RedudanR l UndJ^j!^ /mm PM0 I or t^ Comlstioa Cocffidcnl__£lj3V 'KaafiiorlC Tr«Jatil. L SlinW * SDGi A//A' Vcttdf Swnpio ID# AlMOriNUI08 gm/mb Samplie Final Volume Dilutioa Factor Final Coocciitnitioa Digested mg/l 1 Bluik 0.^£?l 100 mb. Del 100 mb. —. .2. O.OOlt o.oa 3 lOuL Iran lOppm (M-22) lOOmb. _ O.OOO') <3 t.0020 0.0^X. 20uL rrom lOppm (M-22) 100 mb. _ O.OOll ^ 0.0050 O.IOf SOuL rhMn lOppm (M-22) lOOmb. ... 0 a«4 .... v5 0.0100 o.ao4 lOOuL rrom lOppm (M-22) 100 mb. o.oios U 0.0200 0.312/ 200uL rrom lOppm (M-22) lOOmb. _~ y Di q tn 009O TCU> 0 oo3 momli — AIO < O.OOPfi 10 9*10091 TCL|> ooo?^ loomb _, Hfi< D.cnnf, M fl"! Ooqj, TOP 0 OOI v5cnL/s — M0< 0.t-C05 li^ pp^(^?i;sifffjlP ' OOOl tJi'oili ^i' _ NO 1*^ 9-i-DOHO 6L P DOcA iOOMti NO l(« 9'\-tlOU 614^ - Q.00\ \ y s/ NOtO.OOOi -_ n CCV • 0.0080 0.161 80uL rrom lOppm (M-S2) 100 mb. n.on^o ^lAr.ior.r — \% S-l-ooSo BUT 0 003 lOQvA 1 /»/o/< Ol>D05 _ii flfWK CJ'T' ..O.QO^ /L)6 I "•'•••- ' 0.OCO5 HgLog Date/Analyrt <.9/i//«?7 y^^ Chart Speed ID/J Redudant Uied //)% SnC.i //nm ' Conrdation Coeffidcnt Vcisclf Sample 1D# Abaortianoe gm/mb Sample Final Volume Dilutioa Factor Final Conccntratioa Digcs^d mg/l — olO W /)^?^ etr 0.on\ IOO mii . ioomk /ltd < 0. ooon «?/ e.t\lto.ao9o D.iSi ffM ftm irtAjUrt rri 5 5 IOO wis — 0.D09I, ^oHiC- iSO.o • . ( h— -.J . - -.1 OOI 0(^1 08 0< Mt; r- I i ^ iTl IO 7 ^ AndJU^fkAy '• /^otr^AoL ^^cJiclui^X • ~Ta^' (M . 5LP . spn r. m^ 1 J I i I I I no 40 50 60 I 70 80 I 90 100 ~ r- • u ,_. lt^^ * a,I t>o% 9 M»**» «nj-oofli eo' n 7 I rii.- CCjV i O OOTO^fJ ^ n TO I r I i : < q^i-ooii. SLP r I Ot^ 0 0 q\ 5tP I o • f 0010 5LP 15 M-ooio ^LP ! ' I I n 3 «»M-oo< a. Ini TciLp -^h ._i --q^-Ooaa* f»l(N -TCfP -1 ~ 0 I 00 (' in ?o 30 40 so 60 I 90 too I . I I I I . i I qM-0041 TCLP ( "t> 4... LUin«» Prtp fo\(U,k. J Oi \ r "^'—H-. « 4 _. ! 1 -—-L,-_ Aitni ttirri n nnnn rm rM-BL.IVIB ,1-1 CtadNe CP32aM-0 (. l~i 1 i ! o j i ! _o . i ... • " ' ... . 1 1 ! 1 1 ! 1 : ! ^ • _"i -il . • ~ 1 ! 1 ; 1 ; 1 • ! 1 ; : : ' , ; ' - • • 1 j i i ' ' ] _o . 1 05 _;. -- rSl " ' 1 1 i M 1 ; ^ : • ••I-- 1—«H ... ' ! ' : ' -' - • .-i " ... 1 . i i M i _ o • : ' • • ' • eo" ' 1 ' •••.:. i 1 . i ! 1 : ' • .._. , Hg Log /Omrtl//n,^. J Dale!Analyst r.^-CA- i?V Chart Speed Redudant MiitA^Cf^ //>% PMge_^of ^ ComlaUon Coeffident A ??fy SDG n tM -I k ry.H \tsstkt Sample DXT Absorbance gm/mb Sample Dilution Factor Final Concentration Digested mg/l Blank CiOSi 100 mb. Del 100 mb. 0.0010 , 025 lOuL rrom lOppm (M-22) 100 mb. 0.0020 i0^7 20uL rrom lOppm (M-22) 100 mb. 100 mb. 0.0050 -//^ SOuL rrom lOppm (M-22) 0.0100 . 7l( lOOuL rrom lOppm (M-22) 100 mb. 0.0200 1£L 200uL rrom lOppm (M-22) 100 mb. Prep Blank JUMJL 100 mb. Del 100 mb. A)ig> HgLog /Oy>ji/y>^/A Date/Analyst n.:?./^/- (?V Chart Redudant Used .5-/1 rr/. /oVa ?wsi or Q CorrdaUon CodTldent d 999^ Sample nxr Absorbance gm/mb Sample Final Volume Dilution Factor Final Concentration Digested mg/l 7V-0/70 ^ no/ O ^r, . /no IJ / Soc t}b JIL XL^L 'O0I (9 ?8iO/o ..11. ^ yn U.ooSTi 33 /^^ blatJc •r^riQ^ //?0 ^ (iL Haf) hjbKo.ano^ CCV .1^ ^ '/iO^<^ yycn iiP.jA.n lOr^tl./il J - (l'nnC>^ U3% IT >0 /y^y). ./ y. /yi. yff.^.-^ /.no.../ ^.fi/l/y^ >*: *^./ / ^y ^AV 16.122 •g/l't' 1 SD 7188 CV 4.41 •lilt p-it> ml39e III../kV •.•22 Bg/lrvt ED ••73 CV 33.44 JO, . 94-0092 E LT REi=>L.XCAT E m X 1149 fa23a 0.013 ag/l Hn237 3.023 ag/l ovar-ranga