CHAPTER 1 Genesis and evolution in the chemistry of organogermanium, organotin and organolead compounds MIKHAIL G. VORONKOV and KLAVDIYA A. ABZAEVA A. E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russia e-mail:
[email protected] The task of science is to induce the future from the past Heinrich Herz I. INTRODUCTION ..................................... 2 II. ORGANOGERMANIUM COMPOUNDS ...................... 5 A. Re-flowering after Half a Century of Oblivion ................. 5 B. Organometallic Approaches to a CGe and GeGe Bond ......... 6 C. Nonorganometallic Approaches to a CGe Bond ............... 11 D. CGe Bond Cleavage. Organylhalogermanes ................. 13 E. Compounds having a GeH Bond ........................ 14 F. Organogermanium Chalcogen Derivatives .................... 17 G. Organogermanium Pnicogen Derivatives ..................... 26 H. Compounds having a Hypovalent and Hypervalent Germanium Atom .................................... 29 I. Biological Activity ................................... 32 III. ORGANOTIN COMPOUNDS ............................. 33 A. How it All Began ................................... 33 B. Direct Synthesis ..................................... 36 C. Organometallic Synthesis from Inorganic and Organic Tin Halides ... 39 D. Organotin Hydrides .................................. 41 E. Organylhalostannanes. The CSn Bond Cleavage .............. 43 The chemistry of organic germanium, tin and lead compounds —Vol.2 Edited by