Journal of Mechanical Engineering Research and Developments ISSN: 1024-1752 CODEN: JERDFO Vol. 44, No. 6, pp. 186-194 Published Year 2021
Study of the Physical Properties of Barium Titanate (BaTiO3) Nanopowder Doping with Silicon Dioxide (SiO2)
Ghadeer S. Jassim†, Mojahid M. Najim†, Wafaa Mahdi Salih‡ †Material branch, applied science department, University of technology, Baghdad, Iraq ‡Materials engineering department, university of technology, Baghdad, Iraq.
*Corresponding Author Email: [email protected]; [email protected]; [email protected]
ABSTRACT
The homogeneous fine nano-powder of barium titanate (BaTiO3) was doped with silicon dioxide with different ratio (1, 1.5, 2, 2.5) wt % using the weight ratio. then sintering with different temperature (1000c -1300◦c) in temperature raising rate (8-9◦c / 1min) , and Study of the physical properties of the pure and doped mixture. It was observed that the addition of SiO2 on BaTiO3 influence on physical properties, water absorption ability decreases with the decrease in the apparent pores when temperature increase and that the volumetric shrinkage decrease with bulk density decreasing when the ratio of SiO2 content increased.
KEYWORDS perovskite, barium titanate (BaTiO3), physical tests.
INTRODUCTION
Perovskite structure
The perovskite structure is supported by several oxides which have the chemical formula (ABO3). Barium titanite (BaTiO3) is a member of the perovskite family. This structure takes it’s name from the mineral CaTiO3 ]1[.the general crystal structure is a primitive cube with the larger A cation in the corner, the smaller B cation in the middle of the cube and the anion commonly. Oxygen is in the center of the edges of the face where A is a monovalent, or trivalent mineral, and B is a pentavalent, tetravalent or trivalent element. Geometrical packing of ions in the lattice is a very important factor determining the structure type. The perovskite structure can be considered as a (3D) three dimensional framework of BO6 octahedral fig.(1.A) but it can also be consider as a cubic close packed arrangement of A and O Ions with the B ions filling the interstitial positions (Fig 1.B) [2,3].
(a) (b)
Figure 1. perovskite-type cubic structure ABO [2] 3
The perovskites family includes not only compounds with the perfect cubic lattice of perovskites, but also all compounds with structures that can be derived from the ideal compound by small lattice deformations or deletions of some atoms. [3]
186 Study of the Physical Properties of Barium Titanate (BaTiO3) Nanopowder Doping with Silicon Dioxide (SiO2)
Barium titanite (BaTiO3)
Barium titanate (BaTiO3) has interest of more than 60 years, due to its attractive properties. Firstly, its properties are chemically and mechanically stable, secondly, due to its ferro-electric properties at room temperature, and finally, because it is used in the form of polycrystalline ceramics samples and can be easily prepared at low cost ] 4[. Barium Titanate (BaTiO3) is one of the most important ferro-electrics materials which have many application [5]. It belongs to peroviskite structures as ceramics so it needs ultrafine powders (BaTiO3) in order to reduce (calcination temperature, porosity, sintering time, and sintering temperature) [5]. All above parameters will lead to less the cost through reducing the energy and increasing efficiency. Barium titanate is the first ferroelectric perovskite substance to be discovered. Varieties of ferroelectric properties with a o series of structural phases transitions. The Curies point T of barium titanate (BaTiO3) is 1200 C , illustrates the C crystallographic changes of BaTiO [6]. 3
Figure 2. Unit cells of the. four phases, of BaTiO 3
(a)Cubic, stable above 120c (b)Tetragonal, stable between (5 Figure 3. Ions positions in the tetragonal phase (BaTiO )[8] 3 187 Study of the Physical Properties of Barium Titanate (BaTiO3) Nanopowder Doping with Silicon Dioxide (SiO2) The phase transition is considered as a function of the temperature and the size of the ion present in the unit cells [9,10]. There is a strong influence by temperature on crystal, barium titanate, BaTiO3 structures. [11]. The wide range of applications of BaTiO3 includes preparing multi-layer ceramic capacitors (MLCCs), electro optical device, PTC and NTC resistors, piezo-electric actuators, transducers and chemical gas sensors. So that ultrafine powder is very necessary for these applications especially in (MLCCs) [12-18]. EXPERIMENTAL WORK Doping The weight ratio was used for doping barium titanate with nanopartical SiO2 as additives. Pure raw material used to prepare doped Barium titanate with silicon dioxide (BTSi), with four ratio (x=1,1.5,2,2.5) % wt. to study the changes in properties. Mixing powders and Drying doping powders are prepared to be mixed dry and then mixed wet in the presence of ethanol (3h) for (1days), then put the doped mixture in the oven at a temperature(80-90)° C for (6h). This is to evaporate the ethanol from the doped mixture., Finally, the powder is manually mixed for 30 min. Pressing sample Samples were pressed using a hydraulic piston, paraffin oils used as a lubricant. (with constant diameter, thickness and weight, die have 1.30 mm) with constant condition (3 tons for 2 sec). Calcination All samples of (BTSi) with four ratio (X= 1, 1.5, 2, 2.5) wt% were calcination at (1000°C to 1300°C) by using electric furnace (Nabertherm/Germany) using different heating program. Heating program All samples are heated with the same program (2 stage) .as shown below: Sintering program 1400 215; 1300 1400 335; 1300 1300 205; 1200 1200 325; 1200 1200 207; 1100 327; 1100 1100 1000 210; 1000 330; 1000 1000 900 800 60; 800 85; 800 800 700 T (C ) 600 600 500 400 400 300 200 200 100 0 0; 25 0 0 50 100 150 200 250 300 350 400 Time (min) Figure 4. Heating program of doping pure barium titanate (BTsi). 188 Study of the Physical Properties of Barium Titanate (BaTiO3) Nanopowder Doping with Silicon Dioxide (SiO2) Figure 5. Flowchart of the work RESULTS AND DISCUSSION physical test shrinkage Measure the dimension of samples before &after sintering process by using sensitive balance and Dimensional measuring machine (vernier ). 1000C- Nano BaTiO3 0.3 0.25 0.2 0.15 0.1 0.05 0 0 0.01 0.02 0.03 Figure 6. volumetric shrinkage of Nano BaTiO3 with SiO2 after calcination at 1000 c. 189 Study of the Physical Properties of Barium Titanate (BaTiO3) Nanopowder Doping with Silicon Dioxide (SiO2) 1300C- Nano BaTiO3 0.25 0.2 0.15 0.1 0.05 0 0 0.005 0.01 0.015 0.02 0.025 0.03 Figure 7. Volumetric shrinkage of Nano BaTiO3 with SiO2 after calcination at 1300 c. Apparent porosity Apparent porosity was calculated by using Archimedes rule by immersing the samples in Deionized water and put the container on heat source at 80-90◦ c for (2h) then taking the weights by sensitive balance. Then samples were put in the sensitive balance basket and immersed in de ionized water then taking weight of immersed samples was taken. 1.2 1 0.8 0.6 0.4 0.2 0 0 0.5 1 1.5 2 2.5 3 Figure 8. Apparent porosity of Nano BaTiO3 with SiO2 after calcination at 1000 c. 190 Study of the Physical Properties of Barium Titanate (BaTiO3) Nanopowder Doping with Silicon Dioxide (SiO2) 0.035 0.03 0.025 0.02 0.015 0.01 0.005 0 0 0.5 1 1.5 2 2.5 3 Figure 9. Apparent porosity of Nano BaTiO3 with SiO2 after calcination at 1300 c Water absorption. The water absorption was calculated by immersing the samples in de ionized water and placing the container on a heat source at 80-90 ° C for a period of (2 hours), then taking the weights with the sensitive balance. Then the samples are placed in the sensitive scale basket and dipped in deionized water, then the submerged samples are weighed. 12 10 8 6 4 2 0 0 0.005 0.01 0.015 0.02 0.025 0.03 Figure 10. Water absorption of Nano BaTiO3 with SiO2 after calcination at 1000 c. 191 Study of the Physical Properties of Barium Titanate (BaTiO3) Nanopowder Doping with Silicon Dioxide (SiO2) 0.6 0.5 0.4 0.3 0.2 0.1 0 0 0.5 1 1.5 2 2.5 3 Figure 11. Water absorption of BaTiO3 with SiO2 after calcination at 1300c. Bulk density measurement Bulk Density was measured using a sensitive balance four-digit (0.0001) type (Sartorius. PRACTUM,224_1S analytical balance, 220 G X 0.01 MG // GERMANY) for all samples by taking their weight while they were dry. 5 4.5 4 3.5 3 2.5 2 1.5 1 0.5 0 0 0.5 1 1.5 2 2.5 3 Figure 12. bulk density of BaTiO3 after calcination at 1000 c. 192 Study of the Physical Properties of Barium Titanate (BaTiO3) Nanopowder Doping with Silicon Dioxide (SiO2) 9 8 7 6 5 4 3 2 1 0 0 0.5 1 1.5 2 2.5 3 Figure 13. bulk density of BaTiO3 after calcination at 1300 c. CONCLUSION From the figures shown above, we can conclude the following, that the volumetric shrinkage of the dimensions of the samples reduce with increasing temperature, and this is scientifically correct as the pores in the samples are reduced when the temperature increases. This supports the idea of increasing the bulk density. As for water absorption, we notice a decrease in water absorption with a reduce porosity]1[ , due to the contraction of pores and reaching to the stage of glazing in some sample. Volumetric shrinkage the figures (6)(7) show the volumetric shrinkage of Nano BaTiO3 after calcination at (1000◦c and 1300◦c) , It was observed that the volumetric shrinkage decreased with increasing the percentage of nano silicon dioxide content at both temperatures (1000◦c and 1300◦c). This is the result of ethanol evaporation and dimensional contraction. Apparent porosity the figures (8)(9) show the apparent porosity of Nano BaTiO3 after calcination at (1000◦c and 1300◦c), Where it was observed that when adding nano silicon dioxide particles at a different ratio, the apparent porosity begin to decrease as the addition increases due to the interference of nano silicon dioxide particles between the particles of nano barium titanate, which leads to the formation of grain. Water absorption the figures (10)(11) show the water absorption of Nano BaTiO3 after calcination at (1000◦c and 1300◦c),The water absorption is related to the size of the pores, as the smaller the pores, the less the material’s ability to absorb. When adding nano silicon dioxide, porous will reduce pores, which leads to a decrease in water absorption. Bulk density the figures (12)(13) show the bulk density of Nano BaTiO3 after calcination at (1000◦c and 1300◦c),The density gradually decreases with increasing temperature and increasing the ratio of addition, as the addition of silicon dioxide lead to close the pores and increase the agglutination of barium titanate and increase the density. 193 Study of the Physical Properties of Barium Titanate (BaTiO3) Nanopowder Doping with Silicon Dioxide (SiO2) ACKNOWLEDGEMENTS Thanks to God for help us in this work, University of Technology for their help and support, Besides, I would like to thank the Department of the Applied Sciences, Material engineering department, University of Technology, Baghdad, Iraq. for conducting physical tests. REFERENCES [1] S.H. Ghanim, and H. AL-Kattan, “Preparation and Physical Properties of Barium Titanate with Some Added Oxides", MSC.Thesis, Applied Sciences Department / Unviersity of Technology, 2018. [2] M. Boulos, S. Guillement-Fritsch, F. Mathieu, B. Durand, T. Lebey, and V. Bley, “Solid State Ionics”, Vol. 176, Pp. 1301, 2005. [3] B. Wul and I.M. Goldman, C. R. Acad, Sci. U. R. S. S., 46, Pp. 177, 1945. [4] R. Höppener, and A. Daemen, “A New Tape Technology to Produce Multilayer Ceramic Capacitors,” Proceedings, in CARTS-Europe, 1994. [5] W. Sager, H.F. Eicke and W. Sun, “Precipitation of nanometer-sized uniform ceramic particles in emulsions,” Coll. Surf.: Phys. Eng. A., Vol. 79, Pp. 199-216, 1993. [6] M.M. Vijatović, J.D. Bobić, and B.D. Stojanović, "History and challenges of barium titanate: Part I." Science of Sintering, Vol. 40, No. 2, Pp. 155-165, 2008. [7] M.E. Lines and A.M. Glass, "Principles and Applications of Ferroelectrics and Related Materials", Clarendon Press, Oxford, 1977. [8] F. Jona, and G. Shirane, "Ferroelectric crystals", Dover Publications, INC, New York, 1993. [9] L. Simon-Seveyrat, A. Hajjaji, Y. Emziane, B. Guiffard, and D. Guyomar, Ceram. Int., 33, Pp. 35, 2007. [10] L. Wang, L. Liu, D. Xue, H. Kang, and C. Liu, J. Alloys Comp., Vol. 440, Pp. 78, 2007. [11] H. Lin, "Structure and Dielectric Properties of Perovskite-Barium Titanate (BaTiO3)", Ph. D Theses, San Jose State University, Dec. 2002. [12] Y.D. Hyok, "Tetragonality of barium titanate powder for a ceramic capacitor application", J. Ceramic Processing Research, Vol. 7, No. 4, Pp. 343-354, 2006. [13] S.M.A. Ridha and M.M. Najim, "Synthesis and Study the Dielectric Properties of La-Doped and Undoped Barium Titanate Nanopowders", Eng & Tech. J., Vol. 33, No. 2, 2015. [14] B.D. Stojanovic, "Barium titanate screen-printed thick films," Ceramics International, Vol. 28, No. 3, Pp. 293-298, 2002. [15] G.H. Haertling, J. Am. Ceram. Soc., 82 (1999),p 797, 1999. [16] Richerson, David W., Modern ceramic engineering: properties, processing, and use in design. CRC press, 2005. [17] W. Hans-Rudolf and B. Andrei, “Minerals: Their Constitution and Origin”, New York, NY: Cambridge University Press, Pp. 413, 2004. [18] L. Hongyu, "Colloidal processing of PMN-PT thick films for piezoelectric sensor applications," 2005. 194