Electrically switchable structural color using electrowetting on superhydrophobic surface Deming , , He , Yifei , Yuanrui , , Yunxiang Wang, Boxiang and Wei * Ming Hsieh Department of Electrical Engineering, University of Southern California, Los Angeles, CA, 90089

Triple-layer stacked display Fabrication process Electrowetting on flat/ patterned surface

Electrowetting: When potential was applied between the droplet and counter electrode, the contact angle 2-D high contrast gratings: will decrease. Top layer: Titanium dioxide A thin dielectric layer is used between droplet and Bottom layer: Silicon dioxide counter electrode to prevent electrolysis.

Full color reflective display For electrically switchable cos = cos + 2 needed, a Teflon layer will be 𝜀𝜀0𝜀𝜀𝑑𝑑 2 spin coated on the top. 𝜗𝜗 𝜗𝜗𝑌𝑌 𝑈𝑈 Triple-layer Architecture Due to the 2-D grating𝑑𝑑 𝜎𝜎structures,𝑙𝑙𝑙𝑙 the surface become Ideal efficiency: 100 % superhydrophobic. Operations: Colored or Transparent Fabricated by interference lithography and nanoimprint a: Wenzel’s model lithography. C 2 cosϑϑ=⋅+ r cosY U r: roughness ration 2σ lv b: Cassie-Baxter’s model

C 2 cosϑϑ= f ⋅ cosY + f −+1 U f: fraction of solid surface 2σ lv

Electrowetting to change contact angle (not enough)

Gamut and Switchable structural color by adding liquid Irreversible for electrowetting on superhydrophobic surface.

Both Wenzel State and Cassie-Baxter State are stable.

Electrowetting to move liquid (our solution) Generation of mixed color Drive the liquid by a pair of electrodes instead of relying on wetting and dewetting of the superhydrophobic surface.

The whole process was achieved within 0.1s.

Not only move the droplet back and forth on flat surface, but also realize it moving on superhydrophobic surface. References: Contact Information: [1] He Liu, Yuanrui Li, Yuhan , Yifei Wang, and Wei Wu. Full color reflective display based on high contrast gratings. EIPBN 2016. Department of Electrical Engineering-Electrophysics Successfully achieved droplet moving in [2] He Liu, Hao Yang, Yuanrui Li, Yifei Wang, Haneol Lim†, Jongseung Yoon†, 3737 Watt Way, Powell Hall of Engineering, PHE 632 centimeter scale, which is much beyond the Wei Wu. Switchable and Stackable Color Filters for a Transparent Full-color Los Angeles, CA 90089-0271 Tel: (213) 740-3085 need for high reflective display in nanoscale. Reflective Display. Email: [email protected]* 1cm [3] He Liu, Yuhan Yao, Yifei Wang, and Wei Wu. Full-color reflective display That proved the feasibility of electrically system based on high contrast gratings. Journal of Vacuum Science & Technology B, Nanotechnology and Microelectronics: Materials, Processing, switchable full color reflective display using Measurement, and Phenomena,2014. http://wugroup.usc.edu/ electrowetting.