DOCUMENT NO REVISION DATE OF REVISION
HSE-E-075-SUM 4 14 OCTOBER 2019
Perth Basin Well Intervention Activities Environment Plan Summary
Perth Basin Well Intervention Activities Environment Plan Summary
TABLE OF CONTENTS 1.0 INTRODUCTION ...... 7 1.1 Contact Details ...... 7 1.2 Purpose ...... 9 1.3 Environment Plan Implementation ...... 9 2.0 DESCRIPTION OF THE ACTIVITY ...... 10 2.1 Scope ...... 10 2.2 Location ...... 10 2.3 WIA related activities ...... 15 2.4 Well Intervention Activities ...... 15 2.4.1 Timeframes ...... 15 2.4.2 Chemical Disclosure for Products, Additives, Chemicals and Other Substances ...... 15 2.4.3 Decommissioning (Plug and Abandonment) Activities ...... 16 2.5 Demobilisation ...... 16 2.6 Rehabilitation ...... 16 2.7 Utilities and Services ...... 16 2.7.1 Water ...... 16 2.7.2 Refuelling ...... 16 2.7.3 Electricity ...... 17 2.7.4 Offices and Storage Areas ...... 17 2.7.5 Chemical Storage ...... 17 2.7.6 Waste Disposal ...... 18 3.0 DESCRIPTION OF THE ENVIRONMENT ...... 20 3.1 Physical Environment ...... 20 3.1.1 Climate ...... 20 3.1.2 Soil ...... 20 3.1.3 Surface and Groundwater Systems ...... 20 3.2 Biological Environment ...... 20 3.2.1 WA Biodiversity Search ...... 21 3.2.2 Australian Protected Matters Search ...... 21 3.2.3 Conservation Area ...... 22 3.2.4 Environmentally Sensitive Areas ...... 24 3.2.5 Groundwater Dependent Ecosystems ...... 24 3.2.6 Vegetation Communities and Flora ...... 24 3.2.7 Weeds ...... 25 3.2.8 Dieback ...... 26 3.2.9 Fauna ...... 26 3.3 Heritage ...... 28 3.3.1 Aboriginal Heritage ...... 28
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3.3.2 European Heritage ...... 30 3.4 Socio-economic Environment ...... 30 4.0 ENVIRONMENTAL RISK ASSESSMENT AND MANAGEMENT ...... 31 4.1 Risk Management and Justification of ALARP ...... 31 4.2 Risk Classification and Reporting Requirements ...... 31 5.0 IMPLEMENTATION STRATEGY ...... 35 5.1 Systems, Practices and Procedures...... 36 5.2 Record Keeping ...... 38 6.0 CONSULTATION ...... 39 7.0 REFERENCES ...... 40
LIST OF FIGURES Figure 1: Map of MEPAU Perth Basin Permits and Producing Fields ...... 8 Figure 2: Map of Potential Wells to be intervened in the L1 (Hovea Area) ...... 11 Figure 3: Map of Potential Wells to be intervened in the L1 (Dongara) and L2 ...... 12 Figure 4: Map of Potential Wells to be intervened in L4 and L5 (Woodada) ...... 13 Figure 5: Map of Potential Wells to be intervened in L1 (Waitsia) ...... 14 Figure 6: Nature Reserves, ESAs and Water Supply Areas within MEPAU Permit Areas ...... 23 Figure 7: Registered Aboriginal Heritage Sites Perth Basin Permit Areas ...... 29
LIST OF TABLES Table 1 Acronyms ...... 6 Table 2: WIA Waste Disposal ...... 18 Table 3: NatureMap Species Search Summary ...... 21 Table 4: EPBC Act Protected matters report search summary ...... 21 Table 5: Conservation Significant Fauna Desktop Search (incorporating Field Survey Results) ...... 27 Table 6: WIA Risk Assessment ...... 32 Table 7: Systems, Practices and Procedures...... 36 Table 8a: System Details ...... 43 Table 8b: Product List ...... 43 Table 8c: Chemical List ...... 51 Table 9: Products, additives, chemicals and other substances (Cementing) ...... 54 Table 9a: System Details ...... 54 Table 9b: Product List ...... 54 Table 9c: Chemical List ...... 59
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LIST OF APPENDICES APPENDIX 1 WIA FLUIDS CHEMICAL DISCLOSURE TABLES ...... 42 APPENDIX 2 SAFETY DATA SHEETS – FLUIDS ...... 52 APPENDIX 3 WIA CEMENTING CHEMICAL DISCLOSURE TABLES ...... 53 APPENDIX 4 SAFETY DATA SHEETS - CEMENTING ...... 61
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The following acronyms have been used throughout this Plan and are defined in Table 1. Table 1 Acronyms
Acronym Definition ALARP As Low As Reasonably Practicable ASRIS Australian Soil Resource Information System BAM Act 2007 Biosecurity and Agricultural Management Act 2007 BoM Bureau of Meteorology Department of Biodiversity, Conservation and Attractions (previously DBCA Department of Parks and Wildlife (DPaW)) Department of Fire and Emergency Services (formerly Fire and Emergency DFES Services Authority (FESA)) DG Dangerous Goods Department of Minerals, Industry Regulation and Safety (previously DMIRS Department of Mines and Petroleum (DMP)) DPF Dongara Production Facility Department of Water and Environmental Regulation (formerly Department DWER of Water (DoW) and Department of Environment Regulation (DER) / Department of Environment Conservation (DEC)) E&Ds Emissions and Discharges EARS DMIRS Environmental Assessment and Regulatory System EP Environment Plan EPBC Act Environment Biodiversity Conservation Act 1999 ERP Emergency Response Plan ESA Environmentally Sensitive Area EWSWA Environmental Weed Strategy West Australia GDE Groundwater Dependent Ecosystem HSEQ Health, Safety, Environment and Quality JHA Job Hazard Analysis Lead Contractor The main contractor involved with the WIA or WIA related activity. MNES Matters of National Environmental Significance MyOSH Upstream PS/AWE HSEQ Database NGER National Greenhouse and Energy Reporting Act 2007 OSCP Oil Spill Contingency Plan PTW Permit to Work WoNS Weeds of National Significance WIA Well Intervention Activities
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1.0 INTRODUCTION
AWE Perth Pty Ltd is a wholly owned subsidiary of AWE Limited. Mitsui E&P Australia Pty Ltd and AWE Ltd (including subsidiaries) are wholly owned subsidiaries of Mitsui & Co. Ltd. Combined they form the unified brand Mitsui E&P Australia (MEPAU).
MEPAU has a Perth based operations office and one active gas production facility in the Mid- West region, the Xyris Production Facility (XPF), with the Dongara Production Facility (DPF) and Hovea Production Facility (HPF) active in part and with Central Control at DPF. The Woodada Gas Production Facility is in care and maintenance (Figure 1). MEPAU also has an operator presence in New Zealand.
In addition to these operations, MEPAU is a non-operating joint venture partner with petroleum activities in Australia’s onshore (Queensland) and offshore regions (Western Australia and Victoria) and Indonesia.
1.1 Contact Details External Affairs Manager MEPAU (08) 9480 1300 PO Box 574 WEST PERTH 6782
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Figure 1: Map of MEPAU Perth Basin Permits and Producing Fields
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1.2 Purpose The purpose of this document is to provide a summary of the Perth Basin Well Intervention Activities (WIA) Environment Plan [HSE-E-075].
This summary document has been prepared to in accordance with requirements of subregulation (7) of the Petroleum and Geothermal Energy Resources (Environment) Regulations 2012.
1.3 Environment Plan Implementation MEPAU is the custodian of this EP and has overall responsibility for its implementation, compliance and revision.
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2.0 DESCRIPTION OF THE ACTIVITY
2.1 Scope The scope of this document includes the environmental aspects of all Perth Basin WIAs within AWE Perth Pty Ltd permit areas (Figure 1).
The activities listed in Sections 2.3 to 2.7 of this document could potentially be conducted on all wells in the Perth Basin.
2.2 Location There are potentially fifty-five (55) wells (plus any new drilled wells) that could be worked over in the Perth Basin. Forty-four (44) of these wells are located on cleared farmland; and eleven (11) are located within Nature Reserve (Figure 2 to Figure 5).
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Figure 2: Map of Potential Wells to be intervened in the L1 (Hovea Area)
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Figure 3: Map of Potential Wells to be intervened in the L1 (Dongara) and L2
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Figure 4: Map of Potential Wells to be intervened in L4 and L5 (Woodada)
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Figure 5: Map of Potential Wells to be intervened in L1 (Waitsia)
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2.3 WIA related activities The WIA related activities include:
• Possible modifications to the existing well site pad area to ensure the ground can support the WIA, and ancillary equipment; • Mobilisation of WIA Equipment, personnel and supplies to and from the site; • Conducting the WIA; • Demobilisation of WIA Equipment, personnel and supplies; and • Restoration of the site following the completion of activities. 2.4 Well Intervention Activities WIA are remedial operations undertaken by MEPAU to maintain maximum oil or gas producing rates and well integrity. WIA are any operation carried out on an oil or gas well during, or at the end of its productive life, that alters the state of the well and or well geometry, provides well diagnostics or manages the production of the well. The types of WIA conducted on the Perth Basin Production facilities can be summarised as follows:
• General WIA (covered under this EP): • Wellhead Maintenance; • Pumping; • Wireline/Slickline operations; • Well diagnostics; and • Acid wash treatments. • WIA requiring an Environmental Bridging Document: • Pulling and Replacing a Completion; • Snubbing; • Coiled tubing; • Well workover; • Well testing; • Remedial Cement Squeezing; and • Plug and Abandonment. 2.4.1 Timeframes
WIA generally run for approximately 14 days or less (including both mobilisation/demobilisation time). Noise and light disturbance to surrounding landowners is not generally a concern due to the remote location of the wells and due to WIA being typically conducted during daylight hours.
2.4.2 Chemical Disclosure for Products, Additives, Chemicals and Other Substances
DMIRS set out the requirements for chemical disclosure within the Chemical Disclosure Guideline released August 2013. The guideline details the chemical disclosure requirements for products, additives, chemicals and other substances used ‘down-hole’ in petroleum or
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geothermal related activities regulated under regulation 15(9) of the Petroleum and Geothermal Energy Resources (Environment) Regulations 2012.
For General WIA requiring down-hole chemical use (refer to Section 2.4), the proposed chemicals are outlined within the disclosure tables within Appendix 1 and the corresponding Safety Data Sheets are listed within Appendix 2.
2.4.3 Decommissioning (Plug and Abandonment) Activities
When a well has reached the end of its life due to economic, integrity or reservoir reasons, the well will be decommissioned. The objective of decommissioning operations is to isolate the reservoir communication via the wellbore to surface as well as any other zones that may be in communication with the well. Well decommissioning is undertaken in accordance with the applicable Well Management Plan approved under the Petroleum and Geothermal Energy Resources (Resource Management and Administration) Regulations 2015.
2.5 Demobilisation Upon completion of the WIA work scope, all WIA equipment, personnel and supplies will be demobilised. Equipment will be transferred to the next WIA location or stacked awaiting further work.
2.6 Rehabilitation A rehabilitation EP will be submitted to the DMIRS for approval within 12 months of well decommissioning. Rehabilitation will commence as soon as practicable, usually within two years of the well decommissioning.
2.7 Utilities and Services The utilities and services for WIA are described below.
2.7.1 Water
Water cartage equipment for WIA includes a mobile tanker (38 kL) and two to four (depending on well volume) cylindrical and / or open-topped water tanks (16 to 60 kL sized) for the storage of water at a well site. The water is supplied by licensed onsite water bores or to the site via mobile truck mounted water tankers either collected from the HPF or Dongara townsite.
Bottled drinking water is supplied and available to personnel at the site office.
2.7.2 Refuelling
Diesel fuel is delivered by mobile diesel tank (mounted on a 4WD vehicle) to equipment diesel tanks on site. Refuelling will occur at the WIA site. Storage of flammable or combustible liquids will be designed to contain not less than 110% of the volume of the largest storage vessel, and at least 25% of the total volume of substances stored.
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For small WIA, if refuelling is required, it will be via a vehicle-mounted mobile diesel tank or portable cans. For larger WIA, a dual skinned diesel tank is set up for refuelling the mobile tank with bulk fuel being delivered by an off-site contractor.
2.7.3 Electricity
Portable on-site diesel generation provides power during WIA.
2.7.4 Offices and Storage Areas
Temporary offices, workshops and storage areas for typical WIA are as follows:
• 37 m3 (2.4 mW x 6 mL x 2.6 mH) break room • 20 m3 (2.4 mW x 3.2 mL x 2.6 mH) Rig Manager/HSE office • 20 m3 (2.4 mW x 3.2 mL x 2.6 mH) Company Man office • 20 m3 (2.4 mW x 3.2 mL x 2.6 mH) workshop • 50 m3 (2.4 mW x 7.9 mL x 2.6 mH) workshop Additional ancillary offices or work areas may be supplied by the Lead Contractor or MEPAU depending on the nature and scale of the WIA.
2.7.5 Chemical Storage
The chemicals required for WIA will be stored and handled as follows:
Onsite storage:
• A Lease Liner (polypropylene composite) (maximum infiltration rate: 10-9 m/s) will be in place for each well and used as a means of secondary containment for the returned fluids expected as part of the well-decommissioning activity. The polypropylene composite Lease Liner is four times more puncture resistant than commonly used HDPE liners, and its nonslip surface helps prevent slips and falls. The liner is a three- layer polypropylene composite consisting of three barrier films sandwiched by double layers of needle punched geotextile with heat fused surfaces. • The WIA fluids will be mixed onsite within a water cart, a mud mixing tank or storage vessel(s) with secondary containment (Lease Liner and/or drip trays) to capture any spillage should it occur. The chemicals will be stored in the portable bunding as described above. The process of mixing chemicals on location will be supervised by site personnel. Secondary containment for freshwater storage is not required. • Chemical storage (environmentally hazardous) will be within a 20 ft internally bunded Dangerous Goods container. Storage of flammable or combustible liquids will be designed to contain not less than 110% of the volume of the largest storage vessel, and at least 25% of the total volume of substances stored. • Liquid hydrocarbon products such as lubricants will be stored within bunded pallets or the 20 ft internally bunded Dangerous Goods container designed to contain not less than 110% of the volume of the largest storage vessel. Offsite storage:
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• WIA chemicals stored offsite will be stored at the Hovea Production Facility Chemical Shed (this is a permanent bunded storage shed) or within a lease liner. Dangerous Goods are stored in compliance with the Dangerous Goods Site Licence (DGS016892). 2.7.6 Waste Disposal
WIA waste will be disposed of in accordance with the Landfill Waste Classification and Waste Definitions 1996 (as amended 2018) and the Perth Basin Waste Management Plan [PB-HSE- PLN-001] as summarised in Table 2.
Table 2: WIA Waste Disposal
Waste Stream Minimisation Strategy Onsite storage Disposal location Purchase items in bulk General waste Covered skip Class I Landfill to minimise packaging <10m3 bagged and Asbestos containing Historic asbestos handled according to assets, (i.e. containing assets, are Class I Landfill Asbestos Management Asbestos Gaskets) no longer procured Plan1
Significant Solid oily waste maintenance activities Covered oil waste skip Class III Landfill conducted off-site
DPF condensate Significant storage for export / Liquid oily waste maintenance activities Drum, IBC or tank hydrocarbon recycling conducted off-site facility / Class III Landfill
DPF waste water Separation of liquid system / hydrocarbon Oily water oily waste and water Drum, IBC or tank recycling facility / Class where possible III Landfill
Class I Landfill or Open top skip/back Wood Recycle pallets returned to the freighted supplier
Scrap steel recycling Scrap steel Recycle Open top skip facility
Class I Landfill or Empty drums and Stored in a bunded Use reusable IBCs returned to the IBCs area supplier
1 Disposal of >10m3 of bonded (non-friable) asbestos requires a Restricted Asbestos Removal Licence
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Waste Stream Minimisation Strategy Onsite storage Disposal location Septic liquid waste Prevent spills Approved Class III Landfill Facility from ablutions Waste management Evaporate on site, plan contractor/Approved Returned Returned fluids tank/ fit for purpose volume evaporation pond/ fluids/WIA fluids WIA open top tank for WIA disposal well (i.e. Eremia-04, DPF WDW).
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3.0 DESCRIPTION OF THE ENVIRONMENT
3.1 Physical Environment 3.1.1 Climate
The WIA are located across the permit areas in the Perth Basin region, situated approximately 300 km north of Perth (Figure 1). The region has a Mediterranean-type climate characterised by seasonal patterns of hot, dry summers and mild, wet winters. The area is subject to high wind speeds, dust storms, lightning storms, high summer temperatures and low winter night temperatures.
3.1.2 Soil
Generally, soils within the Perth Basin are light and sandy and well drained. Beard (1976) described the soils as “calcareous sand soils of minimal development”. The soils consist of calcareous and siliceous sand underlain by aeolianite, which is often exposed.
The Perth Basin is situated entirely within the Geraldton Sandplains Biogeographical Region. Within this region, three broad physiographical units are recognised; the Swan Coastal Plain, the Arrowsmith Region and the Dandaragan Plateau. The areas in which WIA will be undertaken will generally be located entirely within the Swan Coastal Plain unit, which forms an elongated strip approximately 40 km wide running along the coast.
3.1.3 Surface and Groundwater Systems
The hydrology of the region is dominated by the landform units described in Section 3.1.2. Drainage is westward but the Irwin River valley to the north of the region is the only major coordinated drainage indentation. A number of swamps surrounded by dense scrub, frequent limestone outcrops and the occasional laterite outcrop are the other major features in the region. The sub-surface geology of the area consists of the Late Jurassic Yarragadee Formation, which is overlain by Tertiary Sediments. Groundwater is present in the Tertiary Sediments and the Yarragadee Formation, and the groundwater level is near, or at surface in the aforementioned swamps and low-lying areas, following the surface topography, but with lower relief. The porous and permeable coastal limestone and dune systems tend to allow rainwater to percolate vertically to the water table rather than running laterally off the surface.
3.2 Biological Environment Information on the fauna assemblage of the Perth Basin Permit WIA areas was drawn from a wide range of sources. These included State and Federal government databases. Databases accessed were the DPaW Naturemap (incorporating the Western Australian Museum’s Fauna Base and the DPaW Threatened and Priority Fauna Database), BirdLife Australia’s Atlas Database (BA), the EPBC Protected Matters Search Tool and the BCE database as described in Sections 3.2.1 to 3.2.9.
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3.2.1 WA Biodiversity Search
A WA Biodiversity search (Naturemap) – Department of Parks and Wildlife (DPaW) was conducted (12/11/2018), a summary of the conservation significant species identified within the permit areas is provided (Table 3).
Table 3: NatureMap Species Search Summary
Conservation Status Species Records Non-conservation taxon 2436 22061 Other specially protected fauna 1 2 Priority 1 24 132 Priority 2 59 509 Priority 3 94 888 Priority 4 45 821 Protected under international agreement 12 37 Rare or likely to become extinct 41 888 Total 2712 25338
3.2.2 Australian Protected Matters Search
The EPBC Act Protected Matters Report provides general guidance on matters of national environmental significance (MNES) and other matters protected by the EPBC Act. A summary of MNES in the permit areas is provided (Table 4).
Table 4: EPBC Act Protected matters report search summary
MNES Presence Status World Heritage Properties None - National Heritage Places 1 Lesueur National Park – located west of EP455 Wetlands of International None - Importance Great Barrier Reef Marine None - Park Commonwealth Marine Area 1 Not located within Permit areas. Listed Threatened Ecological 3 Refer to Section 3.2.6 for likely Communities occurrence. Listed Threatened Species 131 Refer to Section 3.2.9 for likely occurrence. Listed Migratory Species 50 Refer to Section 3.2.9 for likely occurrence.
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3.2.3 Conservation Area
The Department of Biodiversity, Conservation and Attractions (DBCA) manages 23 million hectares of national parks, conservation parks, regional parks, nature reserves, state forest and timber reserves in WA. DBCA manages these areas for the conservation of biodiversity in ecosystems within these areas. Major conservation areas across the MEPAU Perth Basin permit areas (refer to Figure 6). Wells within Nature Reserves are Drakea-02 (Yardanogo Nature Reserve), East Lake Logue 01 & 02, Woodada-06, 08, 11, 12, 14, 15, 16 and 19, and Woodada Deep-01 (Lake Logue Nature Reserve) (Figure 4).
3.2.3.1 Red Book
Red Book recommendations, released by the EPA between 1976 and 1984, were made on areas to be classed as conservation reserves. These EPA tenures are part of a listing of Crown Land areas identified in 'Conservation Reserves for Western Australia' and identify different systems which the EPA considered to be of environmental significance and proposed conservation areas.
The proposed WIA will not be within any Red Book areas.
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Figure 6: Nature Reserves, ESAs and Water Supply Areas within MEPAU Permit Areas
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3.2.4 Environmentally Sensitive Areas
Environmentally Sensitive Areas (ESAs) are declared under the Environmental Protection (Clearing of Native Vegetation) Regulations 2004 and cover:
• Declared World Heritage property sites; • An area that is registered on the Register of the National Estate; • A defined wetland and the area within 50 m of the wetland; • The area covered by vegetation within 50 m of rare flora; • The area covered by a threatened ecological community; • Bush Forever sites; • The areas covered by the following policies: • the Environmental Protection (Gnangara Mound Crown Land) Policy 1992 • the Environmental Protection (Western Swamp Tortoise Habitat) Policy 2002 • The areas covered by the lakes to which the Environmental Protection (Swan Coastal Plain Lakes) Policy 1992 applies; • Protected wetlands as defined in the Environmental Protection (South West Agricultural Zone Wetlands) Policy 1998. • Areas of fringing native vegetation in the policy area as defined in the Environmental Protection (Swan and Canning Rivers) Policy 1997 The potential WIA wells are located within the Perth Basin permit areas (Figure 4). Wells within ESAs are East Lake Logue 01 & 02, Woodada-06, 08, 11, 12, 14, 15, and 16 and Woodada Deep-01.
3.2.5 Groundwater Dependent Ecosystems
A previous Groundwater Dependent Ecosystem (GDE) study was undertaken by Rutherford et al (2005) for the Northern Perth Basin. This study considered sites to be potentially reliant on groundwater only if the depth to groundwater was less than 20 m. Any remnant vegetation in areas of shallow groundwater could potentially be groundwater dependent. Most areas across the permits are classified as having low/moderate potential for GDEs (BoM, 2018).
3.2.6 Vegetation Communities and Flora
The Perth Basin is located within the Irwin Botanical District (Northern Sandplains Region), within the Southwest Botanical Province as defined by Beard (1976). Under the Interim Biogeographic Regionalisation for Australia (IBRA) (Environment Australia 2000), the area lies on the Geraldton Sandplain, which is described as ‘mainly proteaceous scrub-heaths, rich in endemics, on the sandy earths of an extensive, undulating, lateritic sandplain mantling Permian to Cretaceous strata’.
Vegetation surveys have been undertaken in the Perth Basin in support of petroleum activities and include surveys. Vegetation in the region ranges from native vegetation with
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little or no disturbance in the Beekeepers, Yardanogo and Lake Logue Nature Reserves to cleared areas for broad acre cropping and grazing with little remnant native vegetation. A summary of the Threatened Flora across the region is provided in the following sections.
3.2.6.1 Threatened Ecological Communities (TECs)
The EPBC Act Protected Matters Search identified three Listed TECs likely to occur within the Permit areas as listed below:
• Banksia Woodlands of the Swan Coastal Plain ecological community (Endangered) • Eucalypt Woodlands of the Western Australian Wheatbelt (Critically Endangered) • Subtropical and Temperate Coastal Saltmarsh (Vulnerable) As WIA are on existing sites, which require minimal clearing, the potential risk of impacting TECs is low.
3.2.6.2 Declared Rare Flora (DRF)
A desktop search of the Declared Rare Flora List (DBCA, Threatened and Priority Flora List, 2018), identified 122 Threatened Flora2 distributed across the Mid-west region.
WIA are on existing sites, which require minimal clearing. AWE has a clearing permit (CPS 8207) to cover the clearing of native vegetation regrowth in the Woodada Gas Field area. A targeted flora and vegetation survey will be contracted for clearing of native vegetation where no clearing permit (or clearing exemption) is in place. The survey will include a search for the presence of Threatened Flora.
3.2.7 Weeds
Weeds commonly found across the key Perth Basin permit areas are summarised in the following text.
L1/L2
A total of 38 weed taxa were recorded within a recent weed assessment of Waitsia-03 (Permit L1). Of these taxa, three are rated as High under the EWSWA (CALM 1999) and are therefore considered to be significant weed species. There were no taxa listed as a Declared Pests under BAM Act (DAF 2017) or WoNS (AWC 2017) recorded during the survey (Woodman, 2017).
The L2 permit areas consist mainly of previously cleared agricultural land (excluding the Dongara /Beekeepers Nature Reserves). The common weed species found across the Dongara region Golden Crownbeard (Dongara Daisy) Verbesina encelioides, African Boxthorn
2 Threatened Flora - Specially protected under the Wildlife Conservation Act 1950, listed under Schedules 1, 2 and 3 of the Wildlife Conservation (Rare Flora) Notice (which may also be referred to as Declared Rare Flora).
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Lycium ferocissimum Miers, African Love Grass Eragrostis curvula (Schrad.) Nees, Walkaway Burr Cenchrus echinatus L. (Shire of Irwin, Pest Plant Advice Notes).
L4/L5
Weed foliage cover is low at the majority of sites assessed (total weed covers of 5% or less) with the exception of Woodada-02 and sumps and drainage gullies associated with a number of well pads. The majority of the tracks around Woodada had only scattered minor weeds. However, there were some areas along the tracks which had a high cover of weeds (Woodman, 2012).
3.2.8 Dieback
The project area lies at the northern limit of the portion of Western Australia where significant plant disease caused by Phytophthora cinnamomi is known to occur. The environmental conditions of the area significantly affect the pathogens ability to survive or flourish and spread over time. All land with an annual average rainfall of more than 400 millimetres and suitable soil composition is considered vulnerable to Phytophthora Dieback (Department of Parks and Wildlife, 2015).
Dieback is known to occur in permit areas L4 and L5. Phytopthora cinnamomi, the most destructive species, is known to occur over a large area in Eneabba Creek and Lake Logue and at several small sites along the Leeman and Erindoon Roads (Glevan Consulting, 2012).
3.2.9 Fauna
Fauna diversity is closely aligned with landform-vegetation characteristics.
The area surrounding the L1/L2 permits is predominantly pasture land. Broad-acre cropping and sheep and cattle grazing predominate. The Waitsia wells are generally within existing cleared land (although there was clearing to establish the Waitsia-03 site).
A recent desktop survey identified 251 vertebrate fauna species as potentially occurring in the survey area and this assemblage included 30 species of conservation significance (Bamford, 2015). Of those species, only 7 conservation significant are considered likely to use the broader area on a regular basis (see Table 5).
.
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Table 5: Conservation Significant Fauna Desktop Search (incorporating Field Survey Results)
CS Expected CS Species Status Level3 presence Waitsia INVERTEBRATES Shield-backed Trapdoor Idiosoma nigrum V S1 CS1 Locally extinct? Spider millipede Antichiropus Eneabba 1 CS3 Resident AMPHIBIANS Slender Tree Frog Litoria adelaidensis CS3 Resident REPTILES White-spotted Ground Diplodactylus CS3 Resident Gecko alboguttatus Western Spiny-tailed Skink Egernia stokesii badia En S1 CS1 Locally extinct? Woma Aspidites ramsayi S4 P1 CS1 Resident or locally extinct? Carpet Python Morelia spilota subsp. S4 CS1 Resident imbricata Tiger Snake Notechis scutatus CS3 Resident Black-striped Snake Neelaps calonotos P3 CS2 Resident BIRDS Malleefowl Leipoa ocellata V S1 CS1 Vagrant (formerly resident) Blue-billed Duck Oxyura australis P4 CS2 Irregular visitor Fork-tailed Swift Apus pacificus M S3 CS1 Irregular visitor Eastern Great Egret Ardea modesta M S3 CS1 Regular visitor Cattle Egret Ardea ibis M S3 CS1 Vagrant White-bellied Sea-Eagle Haliaeetus leucogaster M S3 CS1 Vagrant Peregrine Falcon Falco peregrinus S4 CS1 Irregular visitor Australian Bustard Ardeotis australis P4 CS2 Regular visitor Hooded Plover Thinornis rubricollis V CS1 Vagrant Common Sandpiper Actitis hypoleucos M S3 CS1 Irregular visitor Curlew Sandpiper Calidris ferruginea M S1 CS1 Irregular visitor S3 Red-necked Stint Calidris ruficollis M S3 CS1 Irregular visitor Common Greenshank Tringa nebularia M S3 CS1 Irregular visitor Western Corella Cacatua pastinator CS3 Irregular visitor Carnaby's Black-Cockatoo Calyptorhynchus E S1 CS1 Regular migrant latirostris Western Ground Parrot Pezoporus flaviventris Cr S1 CS1 Possible resident Rainbow Bee-eater Merops ornatus M S3 CS1 Regular migrant Rufous Fieldwren Calamanthus campestris P4 CS2 Resident montanellus
3 EPBC Act listed species: V = Vulnerable, E = Endangered, Cr = Critically Endangered, M = Migratory.
WC Act listed species: S1 - S4 = Schedule 1 - 4, DEC Priority Species: P1 - P5 = Priority 1 - 5.
(based on desktop review) and the likelihood of their presence in the project area, bold indicates species recorded in the field survey.
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CS Expected CS Species Status Level3 presence Waitsia Shy Heathwren Calamanthus cautus P4 CS2 Resident Crested Bellbird Oreoica gutturalis P4 CS2 Resident Southern Scrub-robin Drymodes brunneopygia CS3 Resident White-breasted Robin Eopsaltria georgiana CS3 Resident MAMMALS Brush Wallaby Macropus irma P4 CS2 Resident Total Number of Species: 32 Recorded: 7 A Level 1 Vertebrate Fauna Assessment within the L4/L5 permit area identified two mammal, 27 bird and four reptile species of conservation significance potentially occur within the survey area. However, based on the habitats present, only 10 of these species have a medium or high likelihood of occurrence within the survey area. The majority of the remaining species with a low likelihood of occurrence within the survey area consist of waterbirds and waders that have been recorded in previous surveys and databases based on the general region (Eastern Great Egret, Cattle Egret, Glossy Ibis, Eastern Osprey, White‐bellied Sea‐eagle, Hooded Plover, Terek Sandpiper, Common Sandpiper, Common Greenshank, Wood Sandpiper, Red‐necked Stint, Sharp‐tailed Sandpiper, and Curlew Sandpiper). These species may occur in the nearby Lake Logue and associated lakes. (Ecologia, 2011)
There is no significant native fauna habitat which could be impacted by the proposed WIA. Although protected fauna is known to reside within the broader region, the WIA are within agricultural or highly disturbed land, only minimal clearing of native vegetation is proposed and there are limited activities taking place outside of established sites or fenced compounds therefore impacts to native fauna are anticipated to be negligible.
3.3 Heritage 3.3.1 Aboriginal Heritage
MEPAU will abide by the provisions of the WA Aboriginal Heritage Act 1972. Field and desktop ethnographic surveys have been carried out to determine if operations are likely to impact upon areas of cultural heritage significance.
A search of the Aboriginal Heritage Inquiry System – Department of Aboriginal Affairs (Desktop search), across all permit areas identified the sites depicted within Figure 7. As a result of the field and desktop surveys it has been established that except for the Irwin River (Site 18907), the individual well sites where WIA could occur do not overlap any registered sites or any areas of significance to the Aboriginal people who participated in the process. There are 15 WIA wells in the Dongara region are <1 km from the Irwin River (Site 18907).
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Figure 7: Registered Aboriginal Heritage Sites Perth Basin Permit Areas
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3.3.2 European Heritage
A State Heritage Register – Heritage Council – www.stateheritage.wa.gov.au search was completed (19/11/2018). A total of 16 State Registered Heritage Sites are found within the Irwin Shire, the majority within the immediate Township of Dongara.
The Australian Protected Matters Search Tool referenced in Section 3.2.2 also provides information regarding National Heritage Places, Commonwealth Heritage Places, and World Heritage Properties. No Commonwealth Heritage Places or World Heritage Properties were within 65 kilometres of the petroleum activity area. One National Heritage Place (Lesueur National Park) is within proximity to EP455, however there is currently no wells within the EP455 permit.
3.4 Socio-economic Environment The Mid West region has a diversified economy that varies with the geography and climate. Near the coast, annual rainfall of between 400 and 500 millimetres allows intensive agriculture. Further inland, annual rainfall decreases to less than 250 millimetres and here the economy is dominated by mining of iron ore, gold, nickel and other mineral resources.
The nearest townships to the Perth Basin Permit Areas are the town of Dongara - Port Denison (L1/L2) and Eneabba (L4/L5).
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4.0 ENVIRONMENTAL RISK ASSESSMENT AND MANAGEMENT
4.1 Risk Management and Justification of ALARP The approach undertaken towards risk management for each aspect involves a review of the residual risk post treatment to determine if the environmental impacts and risks of the activity will be managed to an acceptable level. Where additional implementation measures are necessary to reach a level of acceptability they have been considered and adopted
The environmental risks and management identified for the WIA ranked medium or above are presented in Table 6.
4.2 Risk Classification and Reporting Requirements Under the definition in the Guideline for the Development of Petroleum and Geothermal Environment Plans in Western Australia, November 2016 in Western Australia the risk consequence of Moderate is equivalent to High on the MEPAU matrix.
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Table 6: WIA Risk Assessment
Risk identification Residual risk assessment Risk treatment Potential Environmental Aspect Source of Risk (Existing Safeguards / Management Methods) Consequence Likelihood Risk Ranking Impact
1. Fauna • Stored pipework • Death to conservation • Pipework capped to prevent fauna entry significant native fauna • Vehicle interaction • Fencing in place around facilities • Fauna entrapment • Caging on waste skips
• Wellhead cellar grates in place 3 2 M5 • Speed limits adhered to on site. • All fauna related incidents are recorded and reported • Vehicles and equipment are mobilised via established access tracks and roads • Induction covers fauna interaction protocols 2. Air emissions – • Venting associated with • GHG + VOC emissions • Minimise venting/flaring to meet WIA operational requirements venting/flaring WIA (cold venting) reduced air quality • Venting/flaring is under a controlled release 1 4 M5 • Emergency flaring • Visual disturbance • Flaring only under emergency situations associated WIA • Emissions reporting (NGER, Emissions & Discharges) 3. Surface water • WIA spill/loss of • Contamination of • Routine inspection of hydrocarbon and chemical storage areas (HSE-FR-06] containment within surface water (Irwin • Limited volume (Minor Storage) of hydrocarbons stored on site dependent on WIA proximity to a surface River or Lake Logue) requirements water body • Secondary containment will be provided for hydrocarbons and hazardous chemical storage, with capacity >110% of largest container and >25% of total storage (whichever greater); portable bunded containers (spill pallets) will be utilised for minor storage. 3 2 M5 • WIA fluids are stored within tanks with secondary containment (i.e. Lease Liner) • Drip tray utilised during transfer operations • Spill response equipment available on site as per OSCP [HSE-OP-030] • Further risk assessment is undertaken where there is a credible risk of loss of containment reaching water body. • Barrier/surface flow management in place based on risk assessment • WIA Biosecurity Procedure [HSE-E-051] 3 2 M5 4. Weeds • Transfer and spread of • Land weeds due to WIA degradation/decreased • Weed control measures (herbicide treatment, slashing) undertaken in accordance with the biodiversity Weed & Vegetation Management Plan [HSE-E-116] • Induction covers biosecurity requirements • Vehicle/ Equipment Inspection Check Sheet [HSE-FR-018] conducted prior to mobilisation into Environmentally Sensitive Areas, equipment and vehicles are clean upon arrival to site • WIA Biosecurity Procedure [HSE-E-051] 3 2 M5 5. Dieback • Transfer and spread of • Land and vegetation Dieback due to WIA degradation due to • Vehicle/ Equipment Inspection Check Sheet [HSE-FR-018] conducted prior to mobilisation into equipment and vehicles spread of Dieback Environmentally Sensitive Areas, equipment and vehicles are clean upon arrival to site (P.Cinnamomi) • Importation of • Weed control measures (herbicide treatment, slashing) undertaken in accordance with the gravel/sheeting material Weed & Vegetation Management Plan [HSE-E-116]
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Risk identification Residual risk assessment Risk treatment Potential Environmental Aspect Source of Risk (Existing Safeguards / Management Methods) Consequence Likelihood Risk Ranking Impact
• Induction covers biosecurity requirements for activities in dieback prone areas • DBCA approved gravel source for WIA activities within dieback prone areas (i.e. Woodada Gas Field) or alternately assessed as low risk by a DBCA accredited dieback interpreter 4 2 M5 6. Fire • Site not maintained • Release of noxious gases • Liaison with the Department of Fire & Emergency Services (DFES) prior to activities clear of vegetation commencing (during restricted burning periods) and observation of any local fire restrictions • Bushfire – loss of • Ignition sources e.g. vegetation, fauna • Provision of a suitable fire break around the worksite vehicle exhaust, and/or habitat • Induction covers awareness / response to a fire and highlights the need for good housekeeping smokers • Disruption of operations • Only diesel fuel vehicles / equipment to be used at the worksite • Hot work and site access • Permit to work system used to control hot work activities • Flaring of gaseous waste • Damage to equipment • Smoking allowed at designated smoking location only. • Lightning strike • Damage to site offices • Equipment classified for hazardous areas • Ignited gas release • Loss of crops • Adequate fire equipment (including extinguisher) located on-site and personnel trained in its • Vehicle incident use • Arson • Mobile fire-fighting unit available on site • Offsite uncontrolled • Emergency Response Plan [HSE-OP-089], including fire emergency response available at bushfire Dongara and Geraldton 3 2 M5 7. Surface loss of • Spill or loss of • Localised soil or ground • Induction covers OSCP requirements containment containment resulting in and surface water • Keeping chemicals offsite until necessary. a significant release of contamination liquid hydrocarbons/ • Equipment and chemicals oriented within bunded areas to ensure no impact on water bodies returned WIA fluids • Routine inspection of hydrocarbon and chemical storage areas (HSE-FR-06] • SDSs located in site office and chemical storage shed. • Containers checked to ensure that they are in sound order. • Flammable and corrosive materials are segregated within the wellsite chemical storage area. • Open top tank for temporary storage of returned WIA fluids, additional capacity available for urgent storage • Secondary containment will be provided for hydrocarbons and hazardous chemical storage, with capacity >110% of largest container and >25% of total storage (whichever greater); portable bunded containers (spill pallets) will be utilised for minor storage. • OSCP [HSE-OP-030] and ERP [HSE-OP-089] in place and personnel trained in their implementation. 3 2 M5 8. Gas/liquid • Uncontrolled gas/liquid • Increased GHG • Operating procedures, PTW system and JHAs for well operations release release from well during emissions • Pressure testing WIA • Contaminated soil • Hazardous area maintained around wellhead (reducing the potential for ignition) • Contaminated • Portable gas detectors used when working in vicinity of the well groundwater
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Risk identification Residual risk assessment Risk treatment Potential Environmental Aspect Source of Risk (Existing Safeguards / Management Methods) Consequence Likelihood Risk Ranking Impact
• Routine maintenance and inspections • Induction covers OSCP requirements • OSCP [HSE-OP-030] and ERP [HSE-OP-089] in place • Blow Out Preventer or Wireline pressure control equipment as required and regularly tested.
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5.0 IMPLEMENTATION STRATEGY
The objective of the implementation strategy is to describe how all aspects of the activity will be directed, reviewed and managed to ensure that all potential impacts and risks are continuously reduced to ALARP.
The specific objectives with reference to the relevant section of the EP are listed below:
1. Ensure that the agreed environmental performance objectives and standards are met (Section 5.0) 2. Identify specific systems, practices and procedures to be used to ensure that environmental risks and effects are reduced to ALARP (Section 7.0) 3. Establish a commitment to the protection of the environment (Section 7.1) 4. Establish a clear chain of command that sets out the roles and responsibilities of personnel in relation to the implementation, management and review of the EP (Section 7.3) 5. Ensure that each employee or contractor working on or in connection with Perth Basin WIA has the appropriate skills and training (Section 7.4) 6. Monitor, audit and review environmental performance and the Implementation Strategy (Section 7.5) 7. Maintain quantitative records (Section 5.2) 8. Develop and implement emergency and spill preparedness planning and response capability (Section 7.1 and 8.0) 9. Report on environmental performance (Section 9.0) 10. Provide for appropriate consultation with relevant government authorities and other interested persons or organisations (Section 10.0)
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5.1 Systems, Practices and Procedures Details of MEPAU systems, practices and procedures relating to the management of all potential impacts and risks of the activity are detailed in Table 7. The objective of these are to continually reduce the potential impacts and risks of the activity to ALARP.
Table 7: Systems, Practices and Procedures
Item Objective to achieve ALARP Documentation Location Code of Practice for MEPAU To outline the main HSE criteria to be MEPAU Limited Health Safety & • MEPAU intranet site sites observed by MEPAU and its contractors Environment Policy [MEP HSE-POL-001] • Displayed on site in the WIA MEPAU Authority to Stop An Unsafe office practice [MEP-HSE-POL-002] HSE Management System To provide a framework for HSE systems MEPAU Health, Safety and Environment • MEPAU intranet site Standards and outline the elements Management System [MEP-HSE-MAN- 002] Environment Plan or To document environmental management Perth Basin Well Intervention Activities • MEPAU intranet site Environmental Bridging for WIA Environment Plan [HSE-E-075] • Lead WIA Contractor (via Document electronic distribution) Oil Spill Preparedness and To provide guidance on the management Oil Spill Contingency Plan [HSE-OP-030] • MEPAU intranet site Response of a spill • Lead WIA Contractor (via electronic distribution) Completion Criteria To set the criteria required to be achieved Rehabilitation Completion Criteria table • MEPAU intranet site for rehabilitation with sign off by the and relevant Land Access Agreement (internal) landowner/stakeholder (LAA) • Landowner (via electronic distribution) Emergency Response Plan To provide guidance on the management Emergency Response Plan for MEPAU • MEPAU intranet site of an emergency related to WIA Onshore Well Intervention Operations • Lead WIA Contractor (via [HSE-OP-094] electronic distribution) Hazard and Incident To outline the processes and requirements Lead WIA Contractor and MEPAU hazard • MEPAU intranet site Reporting for hazard and incident reporting and incident reporting forms [HSE-FR-08] • MyOSH System for hazard
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Item Objective to achieve ALARP Documentation Location and incident tracking Hygiene Management To document the completion of hygiene WIA Biosecurity Procedure [HSE-E-051] • MEPAU intranet site inspections for personnel entrance into and Hygiene Inspection Form [HSE-FR- • MyOSH System for hazard environmentally sensitive areas (Woodada 018] and incident tracking Gas Field, Drakea-01, Waitsia-03) Environmental Compliance Schedule internal compliance audits to Perth Basin Audit Schedule [HSE-OP-098] • MEPAU intranet site Scheduling verify WIA are being undertaken in compliance to legislation commitments Clearing Vegetation To ensure clearing of native vegetation is Clearing Vegetation Record Form [PB- • MEPAU intranet site Recording undertaken in compliance with the HSE-FRM-001] • Lead WIA Contractor (via relevant legislative instrument electronic distribution) Weed and Vegetation Provide management strategies to Perth Basin Weed and Vegetation • MEPAU intranet site Management minimise the introduction of weed species Management Plan [HSE-E-116] • Lead WIA Contractor (via into operational areas to acceptable levels electronic distribution) Waste Management To provide guidance on the management Perth Basin Waste Management Plan [PB- • MEPAU intranet site of waste in relation to MEPAU Perth Basin HSE-PLN-001] activities. Stakeholder Engagement Assists Company to establish and/or Stakeholder Engagement Plan – Perth • MEPAU intranet site maintain its standing with key Basin [CP-PM-039] stakeholders that Company is a valued and trusted partner of the Mid West community as well as the broader WA community. Landowner Communications Ensure landowners are aware of the Landowner and General Community • MEPAU intranet site proposed activities on their property Communication Procedure [HSE-PR-059] before they occur.
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5.2 Record Keeping The following records will be kept for a minimum of five years and made available to DMIRS on request:
• Induction and training records; • Emissions & Discharges records; • Waste disposal records; • Details of incidents and associated investigations undertaken; • Audit and inspection records (including non-conformances and corrective action tracking); • Current and archived controlled documents; and • Regulatory submissions.
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6.0 CONSULTATION
Consultation has been undertaken with stakeholders over the life of WIA in the Perth Basin with:
• DMIRS; • DBCA; • DFES; • DWER; • Shire of Irwin; • Local landowners; • Local stakeholders; • Dongara and Port Denison Residents; and • Traditional Owners. Ongoing consultation regarding WIA are documented within activity specific Environment Plan Bridging Documents.
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7.0 REFERENCES
Beard, J.S. (1976). The Vegetation of the Dongara Area Western Australia. Map and explanatory memoir 1:250 000 series. Vegmap Publications, Perth. Department of Water (2017), Northern Perth Basin: Geology, hydrogeology and groundwater resources, Hydrogeological bulletin series, report no. HB1, Department of Water, Government of Western Australia, Perth. Ecologia Environment (2011) AWE Limited Woodada Deep-01 Level 1 Vertebrate Fauna Assessment, February 2011 Glevan Consulting (2012). Access tracks to wells and infrastructure at Woodada gas fields – Phytophthora cinnamomi occurrence and assessment. Unpublished report (Document No.: V1) for AWE Ltd, March 2012. Rutherford, J., Roy, V. and Johnson, S.L., (2005), The Hydrogeology of Groundwater Dependent Ecosystems in the Northern Perth Basin, Department of Environment, Hydrogeological Record Series, HG11. Smith M.G. & Jones A. (2018) Threatened and Priority Flora List, 16 January 2018. Department of Biodiversity, Conservation and Attractions: Kensington, WA. Woodman Consulting, (2012) Woodada Gas Field Dieback, Weed and Rehabilitation Assessment, Spring 2012. Woodman Consulting, (2017) Waitsia-03 Weed Assessment 2017. Bamford M.J. & A.R Consulting Ecologists (2015), Waitsia Wells, Dongara Fauna Assessment, 2015.
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APPENDICES
HSE-E-075-SUM Rev 4 Perth Basin Well Intervention Activities Environment Plan Summary
Appendix 1 WIA Fluids Chemical Disclosure Tables
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Table 8: Products, Additives, Chemicals and Other Substances (Fluids) Table 8a: System Details
Operator AWE Perth Pty Ltd
Project/Well Potentially any well listed in Section 2.2 System WIA Fluids
Total Volume of System (per well) 3000 bbl (477,000 L)
Table 8b: Product List
Product Name Supplier Purpose Toxicity, Ecotoxicity & Biodegradability data % Product in System Fluid SDS Attached Water Town or Bore water Base fluid N/A – Natural product. 77.631% Yes
Idcide 20 Newpark Drilling Fluids Biocide Acute Toxicity: 0.051% Yes 75% Tetrakis (hydroxymethyl) Phosphonium Sulphate (55566-30-8): LC50 (Rainbow Trout) = 119 mg/L/96 hr LC50(Bluegill Sunfish) = 93 mg/L/ 96 hr EC50 (Daphnia Magna) = 19 mg/L/48 hr LC50 (Brown Shrimp) = 340 mg/L/96 hr LC50 (Mysid Shrimp ) = 9.5 mg/L/96 hr LC50 (Sheepshead Minnow) = 94 mg/L/96 hr LC50 (Juvenile Plaice) = 86 mg/L/96 hr Waste Water management EC50 (Activated Sludge) = 24mg/L/3 hr. Water: 25% Natural product. Biodegradation/bioaccumulation: No specific studies undertaken to date.
Sodium sulphite Newpark Drilling Fluids Oxygen Acute Toxicity: 0.021% Yes Scavenger LD50 (ingestion) 820 mg/kg (mouse) LD50 (intraperitoneal) 950 mg/kg (mouse) LD50 (intravenous) 175 mg/kg (mouse) LDLo (ingestion) 2825 mg/kg (rabbit) LDLo (intravenous) 400 mg/kg (cat) LDLo (subcutaneous) 600 mg/kg (rabbit) Biodegradation/bioaccumulation: This product is completely biodegradable.
HSE-E-075-SUM Rev 4 Perth Basin Well Intervention Activities Environment Plan Summary
Product Name Supplier Purpose Toxicity, Ecotoxicity & Biodegradability data % Product in System Fluid SDS Attached Sodium Sulphite is an oxygen scavenger when introduced to water. Bioaccumulation of this product has not been determined.
Ancor 1 Newpark Drilling Fluids Corrosion Acute Toxicity: 0.705% Yes Inhibitor May be harmful if swallowed, in contact with skin, and/or if inhaled. Toxicity Data available for the ingredient: TRIETHANOLAMINE (102-71-6): LD50 (Ingestion): 2200 mg/kg (rabbit) LD50 (Intraperitoneal): 1450 mg/kg (mouse) LD50 (Skin): > 20 mL/kg (rabbit) TDLo (Ingestion): 16 g/kg/64 weeks (mouse – cancer) Biodegradation/bioaccumulation: In soil and water, triethanolamine will biodegrade fairly rapidly following acclamation (half-life in the order of days to weeks).
Xanthan Gum (P) Newpark Drilling Fluids Viscosifier Acute/Chronic toxicity Xanthan Gum as an ingredient: 90%: 0.049% Yes LD50 (Oral): >1000 mg/kg (mouse)88.885 LD50 (Intraperitoneal): >50 mg/kg (mouse) LD50 (Intravenous): 100-250 mg/kg (mouse) LD50 (Oral): >45,000 mg/kg (rat) LD50 (Oral): >20,000 mg/kg (dog) Biodegradation/Bioaccumulation: This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate. Water: 10% Natural product. SAPP Newpark Drilling Fluids Water Wetting Toxicity (SAPP) 0.001% Yes Agent Oral Toxicity LD50: 5,100 mg/kg (Rat) Fish Toxicity LC50/48h: >1,500 mg/l (Golden orfe) Chronic Toxicity (SAPP): No data available to indicate product or components present at greater than 1% are chronic health hazards. Not ranked as a Chronic Health Hazard under the Sara 311/312 Tier II Hazard Ratings. Biodegradation/bioaccumulation (SAPP): This product is readily biodegradable. It is an edible product.
HSE-E-075-SUM Rev 4 Perth Basin Well Intervention Activities Environment Plan Summary
Product Name Supplier Purpose Toxicity, Ecotoxicity & Biodegradability data % Product in System Fluid SDS Attached HCL 15% Telford Acid to remove Acute/Chronic toxicity HCL as an ingredient: 15% 1.302% Yes scale LD50 (Oral): >900mg/Kg (rat) LC50 (Inhalation): 300 ppm/hr (rat) Biodegradation/Bioaccumulation: When released into the soil, this material is not expected to biodegrade. When released into the soil, this material may leach into groundwater. Water: 58% Natural product.
Fracseal Newpark Drilling Fluids Prevent lost Acute Toxicity: 0.385% Yes Fine/Cellplug/NDFT circulation Cellulose (9004-34-6) 377 LC50 (inhalation) > 5800 mg/m³/4 hours (rat) (LCM – cellulose fibre) LD50 (ingestion) > 5000 mg/kg (rat) LD50 (intraperitoneal) > 31600 mg/kg (rat) LD50 (skin) > 2000 mg/kg (rabbit) Biodegradation/bioaccumulation: Main ingredient is Cellulose, an organic material which is readily biodegradable. Quickseal F/M/C Newpark Drilling Fluids Lost circulation This product consists of 100% organic fibres (plant material) and is therefore not anticipated to 0.256% Yes material cause adverse effects to animal or plant life if released to the environment in small quantities Acute Toxicity: No LD50 data available for this product. Biodegradation/bioaccumulation: This product is not expected to bioaccumulate.
Rheopac LV Newpark Drilling Fluids Viscosifier Acute Toxicity: 0.087% Yes Aquatic toxicity: LC50 (Fresh Water Trout) > 21,000 ppm/96hrs. LC50 (Salt Water Stickel Back) > 56,000 ppm/96hrs. Biodegradation/bioaccumulation: This product is not anticipated to cause adverse effects on animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate. KCL Newpark Drilling Fluids Weighting Acute Toxicity: 10.907% Yes Agent LD50 (Ingestion): 1500 mg/kg (mouse) LD50 (Intraperitoneal): 620 mg/kg (mouse) Chronic Toxicity: Not listed as a carcinogen. No data available to indicate product or components present at
HSE-E-075-SUM Rev 4 Perth Basin Well Intervention Activities Environment Plan Summary
Product Name Supplier Purpose Toxicity, Ecotoxicity & Biodegradability data % Product in System Fluid SDS Attached greater than 1% are chronic health hazards. Biodegradation/bioaccumulation: Low bioaccumulation in water/soil. High mobility.
Salt/NaCl Newpark Drilling Fluids Weighting Acute Toxicity: 2.150% Yes Agent Oral Toxicity LD50: 3000 mg/kg (Rat) Oral Toxicity LD50: 4,000 mg/kg (Mouse) Dermal Toxicity LD50: >10,000 mg/kg (Rabbit) Chronic Toxicity: Not listed as a carcinogen. No data available to indicate product or components present at greater than 1% are chronic health hazards. Biodegradation/bioaccumulation: Low bioaccumulation in water/soil. High mobility.
Calcium Chloride Newpark Drilling Fluids Weighting Acute Toxicity: 6.180% Yes Agent CALCIUM CHLORIDE ANHYDROUS as an ingredient (10043-52-4): LD50 (Ingestion): 1000 mg/kg (rat) LD50 (Intraperitoneal): 210 mg/kg (mouse) LD50 (Intravenous): 42 mg/kg (mouse) LD50 (Subcutaneous): 823 mg/kg (mouse) LDLo (Ingestion): 1384 mg/kg (rabbit) LDLo (Intravenous): 150 mg/kg (guinea pig) LDLo (Subcutaneous): 249 mg/kg (cat) TDLo (Intravenous): 20 mg/kg/1 hour (woman) SODIUM CHLORIDE (7647-14-5): LC50 (Inhalation): > 42000 mg/m3/1 hour (rat) LD50 (Ingestion): 3000 mg/kg (rat) LD50 (Intraperitoneal): 2602 mg/kg (mouse) LD50 (Intravenous): 645 mg/kg (mouse) LD50 (Skin): > 10000 mg/kg (rabbit) LD50 (Subcutaneous): 3000 mg/kg (mouse) LDLo (Ingestion): 8000 mg/kg (rabbit) LDLo (Intravenous): 300 mg/kg (guinea pig) LDLo (Subcutaneous): 2160 mg/kg (guinea pig)
HSE-E-075-SUM Rev 4 Perth Basin Well Intervention Activities Environment Plan Summary
Product Name Supplier Purpose Toxicity, Ecotoxicity & Biodegradability data % Product in System Fluid SDS Attached TDLo (Ingestion): 12357 mg/kg (human) Biodegradation/bioaccumulation: Biodegradability does not pertain to inorganic substances. This product does not bioaccumulate.
Contingency Volumes
TEA (Contingent Newpark Drilling Fluids Corrosion Acute Toxicity: 0.705% Yes Chemical) Inhibitor May be harmful if swallowed, in contact with skin, and/or if inhaled. Toxicity Data available for the ingredient: TRIETHANOLAMINE (102-71-6): LD50 (Ingestion): 2200 mg/kg (rabbit) LD50 (Intraperitoneal): 1450 mg/kg (mouse) LD50 (Skin): > 20 mL/kg (rabbit) TDLo (Ingestion): 16 g/kg/64 weeks (mouse – cancer) Biodegradation/bioaccumulation: In soil and water, triethanolamine will biodegrade fairly rapidly following acclamation (half-life in the order of days to weeks). The substance is expected to be readily biodegradable according to the AS 4351 Part 2 test method. Condensate (Xyris) AWE Perth Pty Ltd Production by- Acute Toxicity: 3.333% Yes product May be harmful if swallowed, in contact with skin, and/or if inhaled. Toxicity Data available for the ingredient: NATURAL GAS CONDENSATES (PETROLEUM) (64741-47-5): LC50 (inhalation): 600mg/m3 (rat) TOLUENE (108-88-3): LD50 (oral): 5,580 mg/kg (rat) LD50 (dermal): 5,000 mg/kg (rabbit) LC50 (inhalation): 25.7-30 mg/L/4hrs (rat) 1,2,4-TRIMETHLYBENZENE (95-63-6): LD50 (oral): 6,000 mg/kg (rat) LD50 (dermal): None LC50 (inhalation): 18 g/m3/4hrs (rat) BENZENE (71-43-2): LD50 (oral): 930 mg/kg (rat) LD50 (dermal): 48 mg/kg (mouse)
HSE-E-075-SUM Rev 4 Perth Basin Well Intervention Activities Environment Plan Summary
Product Name Supplier Purpose Toxicity, Ecotoxicity & Biodegradability data % Product in System Fluid SDS Attached LC50 (inhalation): 9,980 ppm (mouse) ETHYLBENZENE (100-41-4): LD50 (oral): 3,500 mg/kg (rat) LD50 (dermal): 17,800 mg/kg (rabbit) LC50 (inhalation): 50 g/m3/2 hours (mouse) N-HEXANE (110-54-3): LD50 (oral): 25 g/kg (rat) LD50 (dermal): 3.000 mg/kg (rabbit) LC50 (inhalation): 48,000 ppm/4 hours (rat) MERCURY (7439-97-6): LD50 (oral): 10-40 mg/kg (expected) LD50 (dermal): None LC50 (inhalation): 0.014 mg/L/4 hours (rat) Toxicity Harmful to aquatic life with long lasting effects. Biodegradation/bioaccumulation: No information provided.
RX-7492 NewPark Drilling Cleaning agent Acute toxicity: 0.267% Yes Fluids/Roemex (substitute for Acute Toxicity – Fish PAO24273) LC50 96 hours 0.71 mg/l Pimephales promelas (Fat-head Minnow) Acute Toxicity – Aquatic Invertebrates EC50 0.4 mg/l Daphnia magna Acute Toxicity – Aquatic Plants IC50 4 mg/l Selenastrum capricornutum Biodegradation/bioaccumulation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Bromine Chammas Cutters Oxidizer for Acute/Chronic toxicity of Bromine fluoride (BrF3) as an ingredient: 100% 0.007% Yes Trifluoride cutting steel Bromine Trifluoride is irritating and corrosive to all living tissues. Product is supplied inside a tubing sealed cylinder for transportation Purpose and handled by trained personnel; seal discs can only be sheared at carefully controlled temperature and pressure.
HSE-E-075-SUM Rev 4 Perth Basin Well Intervention Activities Environment Plan Summary
Product Name Supplier Purpose Toxicity, Ecotoxicity & Biodegradability data % Product in System Fluid SDS Attached LC50 (Inhalation): >230 ppm/hr (monkey) LC50 (Inhalation): >299 ppm/hr (rat) Biodegradation/bioaccumulation: Products of degradation: halogenated compounds.
Guar Gum Newpark Drilling Fluids Viscosifier Acute Toxicity: 0.049% Yes (Substitute for GUAR GUM (9000-30-0) Xanthem Gum) This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated. Oral Toxicity (LD50) 6000 mg/kg (Hamster) TDLo (oral) 228,000 mg/kg/13 weeks continuous (rat) Biodegradation/bioaccumulation: This product is not anticipated to cause adverse effects on animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate.
Rheoplug / Newpark Drilling Fluids LCM Acute Toxicity: 0.052% Yes Rheoplug Ultra This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated. Acute Oral Toxicity: LD50 (rat) is > 40 g/kg. Biodegradation/bioaccumulation: This product is not anticipated to cause adverse effects on animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate.
Calcium Carbonate Newpark Drilling Fluids LCM Acute Toxicity: 0.098% Yes Oral Toxicity LD50: 7,340 mg/kg (Rat) Fish Toxicity TLM96: 100-500 ppm (Oncorhynchus mykiss) Crustaceans Toxicity TLM96: 478,520 ppm (Mysidopsis bahia) SPP @ 8 ppb. Chronic Toxicity: No data available to indicate product or components present at greater than 1% are chronic health hazards. Biodegradation/bioaccumulation: Sparingly soluble in water as hydroxide to form an alkaline solution. Low mobility in most ground conditions. Not expected to bioaccumulate. Fluorodye UC Newpark Drilling Fluids/Nalco Tracer Acute Toxicity: 0.0524% Yes Ethylene glycol has moderate toxicity to aquatic life on both a short term and long-term basis. ACETIC ACID (64-19-7) LC50 (Inhalation): 5620 ppm/1 hour LCLo (Inhalation): 16000 ppm/4 hours (rat) LD50 (Ingestion): 3310 mg/kg (rat)
HSE-E-075-SUM Rev 4 Perth Basin Well Intervention Activities Environment Plan Summary
Product Name Supplier Purpose Toxicity, Ecotoxicity & Biodegradability data % Product in System Fluid SDS Attached LD50 (Intravenous): 525 mg/kg (mouse) LD50 (Skin): 1.06 g/kg (rabbit) LDLo (Ingestion): 600 mg/kg (rabbit) LDLo (Subcutaneous): 600 mg/kg (rabbit) TCLo (Inhalation): 816 ppm/3 minutes (human) TDLo (Ingestion): 1470 ug/kg (human) ETHYLENE GLYCOL (1,2-ETHANEDIOL) (107-21-1) LC50 (Inhalation): 10876 mg/kg (rat) LD50 (Ingestion): 1670 mg/kg (cat);> 2000 mg/kg (rat) LD50 (Skin): 9530 mg/kg (rabbit) LDLo (Ingestion): 398 mg/kg (human) TCLo (Inhalation): 10,000 mg/m³ (human - cough) TDLo (Ingestion): 5,500 mg/kg (child - anaesthesia) RHODAMINE (81-88-9) LD50 (Ingestion): 887 mg/kg (mouse) LD50 (Intraperitoneal): 112 mg/kg (rat) LD50 (Intravenous): 89 mg/kg (rat) LD50 (Subcutaneous): 180 mg/kg (mouse) LDLo (Ingestion): 500 mg/kg (rat) Biodegradation/bioaccumulation: In water and soil ethylene glycol is expected to degrade in several days to a week. The major degradation product is hydroxyacetaldehyde. Ethylene glycol is not expected to bioaccumulate.
HSE-E-075-SUM Rev 4 Perth Basin Well Intervention Activities Environment Plan Summary
Table 8c: Chemical List
Chemicals Name CAS number Mass fraction (%) Water 7732-18-5 78.941 Tetrakis (hydroxymethyl) Phosphonium Sulphate 55566-30-8 0.724 Sodium sulphite 7757-83-7 0.021 Triethanolamine 102-71-6 0.705 Xanthan Gum 11138-66-2 0.044 Disodium Pyrophosphate 7758-16-9 0.001 Hydrochloric Acid 7647-01-0 0.195 Cellulose 9004-34-6 0.116 Sodium Carboxymethyl Cellulose 9004-32-4 0.077 Sodium Chloride 7647-14-5 2.337 Sodium Glycolate 2836-32-0 0.001 Potassium Chloride 7447-40-7 10.907 Calcium Chloride Anhydrous 10043-52-4 5.933 Triethanolamine 102-71-6 0.426 Diethanolamine 111-42-2 0.213 Ethanolamine 141-43-5 0.071 Natural Gas Condensate 64741-47-5 0.820 Toluene 108-88-3 0.100 1,2,4-Trimethlybenzene 95-63-6 0.030 Benzene 71-43-2 0.030 Ethylbenzene 100-41-4 0.010 N-hexane 110-54-3 0.010 Mercury 7439-97-6 <0.001 D-Limonene 5989-27-5 0.160 Bromine Trifluoride 7787-71-5 0.007 Water 7732-18-5 0.107 Guar gum 9000-30-0 0.044 Poly(acrylic acid sodium salt) 9003-04-7 0.052 Quartz (Crystalline Silica) 14808-60-7 0.0098 Calcium Carbonate 471-34-1 0.09702 Orange terpenes 8028-48-6 0.1869 Terpene Hydrocarbons 68956-56-9 0.0801 Ethylene Glycol 107-21-1 0.01572 Acetic Acid 64-19-7 0.01572 C.I. Basic Violet 10 (Rhodamine B or D&C Red No 19) 81-88-9 0.01572 Total: 100.00% (excluding contingency volumes)
HSE-E-075-SUM Rev 4 Perth Basin Well Intervention Activities Environment Plan Summary
Appendix 2 Safety Data Sheets – Fluids
HSE-E-075-SUM Rev 4
THRU TUBING SYSTEMS SAFETY DATA SHEET Document # Version Prepared by: Issue Date: November 14, 2017 SDS – ACE Mix 1.1 Brad Cook Supersedes: All previous Cement (Portland/Oilwell) Page 1 of 12
SECTION 1: IDENTIFICATION Product Identifier: Portland Cement (cement) Product Name(s): ACE Mix Cement, ACE Mix-HTE, ACE Mix-LTX, ACE Mix-SSW, ACE Mix-EX Synonyms: Cement, Portland Cement, Hydraulic Cement, Oil Well Cement, OWH,OW Class H HSR Recommended Use: This product is intended to be used as an Oilwell Cement Manufacturer: Thru Tubing Systems, Inc 1806B Highway 90 East New Iberia, LA 70560 +1 337-606-0031 Responsible Party Thru Tubing Systems, Inc. and Emergency +1 337-606-0031 Contact:
SECTION 2: HAZARD(S) IDENTIFICATION Hazard Classification: Skin Corrosive 1C H314 Eye Damage 1 H318 Skin Sensitivity 1 H317 Carcinogen 1A H350 STOT SE 3 H335 Label Elements: Pictograms
Signal Word: Danger Hazard Statements: H314 – Causes severe skin burns and eye damage H315 – Causes skin irritation H317 – May cause an allergic skin reaction H318 – Causes serious eye damage H335 – May cause respiratory irritation H350 – May cause cancer (inhalation) H372 – Causes damage to organs through prolonged or repeated exposure Precautionary Statements: P201 – Obtain special instructions before use P202 – Do not handle until all safety precautions have been read and understood P260 – Do not breathe dust P264 – Wash hands, forearms, and exposed areas thoroughly after handling P271 – Use only outdoors or in a well-ventilated area P272 – Contaminated work clothing should not be allowed out of the workplace P280 – Wear protective gloves, protective clothing, face protection, eye protection
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P301+P330+P331 – IF SWALLOWED: rinse mouth. Do NOT induce vomiting P303+P361+P353+P352 – IF ON SKIN (or hair): Remove/Take off Immediately all Contaminated clothing. Rinse skin with water/shower. Wash with plenty of soap and water P304+P340 – IF INHALED: Remove person to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 – Immediately call a POISON CENTER or doctor/physician P321 – Specific treatment (see Section 4) P333+P313 – If skin irritation or rash occurs: Get medical advice/attention P362+364 – Take off contaminated clothing and wash it before reuse P403+P233 – Store in a well-ventilated place. Keep container tightly closed P405 – Store locked up P501 – Dispose of contents/container according to local, regional, state, national, territorial, provincial, and international regulations Other Hazards: Other Hazards not Inhalation can cause serious, potentially irreversible lung/respiratory tract tissue Contributing to the damage due to chemical (caustic) burns, including third degree burns. Individuals Classification: with lung disease (e.g. bronchitis, emphysema, COPD, pulmonary disease) or sensitivity to hexavealent chromium can be aggravated by exposure Unknown Acute Toxicity Not Available
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Mixture Name Product Identifier %(w/w) Classification (GHS-US) Skin Irritant 2, H315 Eye Damage 1, H318 Cement, Portland, chemicals CAS# 65997-15-1 58-70 Skin Sensitivity 1, H317 STOT SE 3, H335 Carc. 1A, H350 Crystalline Silica (quartz) CAS# 14808-60-7 28-35 STOT SE 3, H335 STOT RE 1, H372 Gypsum, Calcium Sulfate CAS# 13397-24-5 <5 Not Classified Magnesium Oxide CAS# 1309-48-4 <5 Not Classified Skin Corr. 1C,H314 Calcium Oxide CAS# 1305-78-8 <3 Eye Dam. 1, H318 STOT SE 3, H335 The specific percentage concentration of the mixture is withheld because it is a proprietary trade secret.
SECTION 4: FIRST AID MEASURES
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Description of First Aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show label if possible). Inhalation: When symptoms occur: go into open air and ventilate suspected area. Keep at rest and in a position comfortable for breathing. If you feel unwell, see medical advice. Skin Contact: Remove contaminated clothing. Immediately flush skin with plenty of water for at least 60 minutes. Immediately call POISON CENTER or doctor/physician. Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing for at least 60 minutes. Immediately call POISON CENTER or doctor/physician. Ingestion: Rinse mouth. Do not induce vomiting. Immediately call POISON CENTER or doctor/physician. Most Important Symptoms and Effects Both Acute and Delayed General: Corrosive to eyes, respiratory system and skin. Exposure may produce an allergic reaction. Inhalation: The three types of silicosis include: 1) Simple chronic silicosis – which results from long- term exposure (more than 20 years) to low amounts of respirable crystalline silica. Nodules of chronic inflammation and scarring provoked by the respirable crystalline silica form in the lungs and chest lymph nodes. This disease may feature breathlessness and may resemble chronic obstructive pulmonary disease (COPD); 2) Accelerated silicosis – occurs after exposure to larger amounts of respirable crystalline silica over a shorter period of time (5-15 years); 3) Acute silicosis – results from short-term exposure to very large amounts of respirable crystalline silica. The lungs become very inflamed and may fill with fluid, causing severe shortness of breath and low blood oxygen levels. Inflammation, scarring, and symptoms progress faster in accelerated silicosis than in simple silicosis. Progressive massive fibrosis may occur in simple or accelerated silicosis, but is more common in the accelerated form. Progressive massive fibrosis results from severe scarring and leads to the destruction of normal lung structures. Some studies show that exposure to repairable crystalline silica (without silicosis) or that the disease silicosis may be associated with the increased incidence of several autoimmune disorders such as scleroderma (thickening of the skin), systemic lupus erythematosus, rheumatoid arthritis, and diseases affecting the kidneys. Silicosis increases the risk of tuberculosis. Some studies show an increased incidence of chronic kidney disease and end-stage renal disease in workers exposed to respirable crystalline silica. Corrosive to the respiratory tract. Skin Contact: Cement may cause dry skin, discomfort, irritation, severe burns, and dermatitis. Exposure to sufficient duration to wet cement, or to dry cement on moist areas of the body, can cause serious potentially irreversible damage to skin, eye, respiratory, and digestive tracts due to chemical (caustic) burns, including third degree burns. A skin exposure may be hazardous even if there is no pain or discomfort. Cement is capable of causing dermatitis by irrigation and allergy. Skin affected by dermatitis may include symptoms such as; redness, itching, rash, scaling, and cracking. Irritant dermatitis is caused by the physical properties of cement including alkalinity and abrasion. Allergic contact dermatitis is caused by sensitization to hexavalent chromium (chromate) present in cement. The reaction can range from a mild rash to severe skin ulcers. Persons already sensitized may react to the
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first contact with cement. Others may develop allergic dermatitis after years of repeated contact with cement. Eye Contact: Airborne dust may cause immediate or delayed irritation or inflammation. Eye contact with large amounts of dry powder or with wet cement can cause moderate eye irritation, chemical burns, and blindness. Eye exposures require immediate first aid and medical attention to prevent significant damage to the eye. Ingestion: May cause burns or irritation of the linings of the mouth, throat, and gastrointestinal tract. Chronic Symptoms: If dust is generated, repeated exposure through inhalation may cause cancer or lung disease. Indication of Any Immediate Medical Attention and Special Treatment Needed If exposed or concerned, get medical advice and attention.
SECTION 5: FIRE-FIGHTING MEASURES Extinguishing Media Suitable Extinguishing Use extinguishing Media appropriate for surrounding fire. Media: Unsuitable Do not use a heavy water stream. Use of heavy stream of water may spread fire. Extinguishing Media: Special Hazards Arising From the Substance or Mixture Fire Hazard Not flammable. Explosion Hazard: Product is not explosive. Reactivity: Wet cement is alkaline and is incompatible with acids, ammonium salts, and aluminum metal. Cement dissolves in hydrofluoric acid, producing corrosive tetraflouride gas. Cement reacts with water to form silicates and calcium hydroxide. Silicates react with powerful oxidizers such as fluorine, boron triflouride, chlorine triflouride, manganese triflouride, and oxygen diflouride. Advice for Firefighters Precautionary Exercise caution when fighting any chemical fire. Measures Fire: Firefighting Do not get water inside containers. Do not apply water stream directly at source of leak. Instructions: Protection During Do not enter fire area without proper protective equipment, including respiratory Firefighting: protection. Hazardous None. Combustion Products: Reference to Other Sections Refer to Section 9 for flammability properties.
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SECTION 6: ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Do not breathe dust. Do not get in eyes, on skin, or on clothing. For Non-Emergency Personnel Protective Use appropriate personal protection equipment (PPE) Equipment: Emergency Evacuate unnecessary personnel. Procedures: For Emergency Personnel Protective Equip cleanup crew with proper protection. Equipment: Emergency Ventilate area. Procedures: Environmental Precautions Prevent entry to sewers and public waters Methods and Material for Containment and Cleaning Up For Containment: Place spilled material into a container. Avoid actions that cause the cement to become airborne. Avoid inhalation of e and contact with skin. Wear appropriate protective equipment as described in Section 8. Scrape wet cement and place in container. Allow material to dry or solidify before disposal. Do not wash cement down sewage and drainage systems or into bodies of water (e.g. streams). Methods for Avoid actions that cause dust to become airborne during clean-up such as sweeping or Cleaning Up: using compressed air. Use HEPA vacuum or thoroughly wet with water to clean up dust. Use PPE described in Section 8. Reference to Other Sections See Section 8, Exposure Controls and Personal Protection. Concerning disposal elimination after cleaning, see Section 13.
SECTION 7: HANDLING AND STORAGE Precautions for Safe Handling Additional Hazards Keep totes and bagged cement dry until used. Stack totes and/or bagged material in a When Processed: secure manner to prevent falling. Packaged cement is heavy and poses risks such as sprains to the back, arms, shoulders, and legs during lifting and mixing. Handle with care and use appropriate control measures. Cutting, crushing, or grinding hardened cement will release respirable crystalline silica. Use all appropriate measures of dust control or suppression, and Personal Protective Equipment (PPE) described in Section 8 below. Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas with mild soap and water before eating, drinking, or smoking, and again when leaving work. Wash contaminated clothing before reuse. Conditions for Safe Storage, Including Any Incompatibilities Storage Conditions: Store in a dry, cool, and well-ventilated place. Keep containers closed when not in use. Incompatible Wet cement is alkaline and is incompatible with acids, ammonium salts, and aluminum
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Materials: metal. Cement dissolves in hydrofluoric acid, producing corrosive silicon tetraflouride gas. Cement reacts with water to form silicates and calcium hydroxide. Silicates react with powerful oxidizers such as fluorine, boron, triflouride, chlorine triflouride, manganese triflouride, and oxygen diflouride. Storage Unlimited. Temperature: Specific End Use(s) This product is intended to be used as an oilwell cement.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE GUIDELINES Component OSHA PEL ACGIH TLV NIOSH REL Cement, Portland (TWA) 5 mg/m3 (TWA) 1 mg/m3 (TWA) 5 mg/m3 3 3 3 Crystalline Silica, Quartz 10 mg/m %SiO2 + 2 TWA (TWA) 0.025 mg/m (TWA) 0.05 mg/m Gypsum, Calcium Sulfate (TWA) 5 mg/m3 (TWA) 10 mg/m3 (TWA) 5 mg/m3 Calcium Oxide (TWA) 5 mg/m3 (TWA) 2 mg/m3 (TWA) 2 mg/m3 Magnesium Oxide (TWA) 15 mg/m3 (TWA) 10 mg/m3
EXPOSURE CONTROLS Appropriate Engineering Controls. Use adequate general or local exhaust ventilation to maintain concentrations in the workplace below the applicable exposure limits listed above. Emergency eye wash stations should be available in the immediate vicinity or any potential exposure. Personal Protective Equipment. Gloves. Protective goggles. Dust Mask. Materials for Protective Clothing. Chemically resistant materials and fabrics. Hand Protection. Wear gloves impervious to water to prevent skin contact. Eye Protection. Wear ANSI approved glasses or safety goggles when handling dust. Wearing contact lenses is not recommended. Skin and Body Protection. Wear gloves, boot covers, and protective clothing impervious to water to prevent skin contact. Respiratory Protection. Wear a NIOSH approved respirator that is properly fitted and is in good condition when exposed to dust over exposure limits. Other Information. Do not eat, drink, or smoke when using.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Information on Basic Physical and Chemical Properties Appearance: Gray, White, or Off-white powder Odor: Odorless Odor Threshold: Not Available pH: 12-13 in water Melting Point/Freezing Point: Not Available Initial Boiling Point/Range: >1000o C (>1832o F) Flash Point: Not Available Evaporation Rate: Not Available
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Flammability (solid/gas): Not Available Upper/Lower Flammability Limits: Not Available Vapor Pressure: Not Available Vapor Density: Not Available Relative Density: 2.97 Solubility: Water: 0.1 -1% (slightly soluble) Partition Coefficient: n-octonal/water: Not Available Auto-Ignition Temperature: Not Determined Decomposition Temperature: Not Determined Viscosity: Not Available
SECTION 10: STABILITY AND REACTIVITY Wet cement is alkaline and is incompatible with acids, ammonium salts, and aluminum metal. Cement dissolves in hydrofluoric acid, producing corrosive silicon tetraflouride gas. Cement reacts with water to form silicates and Reactivity: calcium hydroxide. Silicates react with powerful oxidizers such as fluorine, boron trifouride, chlorine triflouride, manganese triflouride, and oxygen diflouride. Chemical Stability: Stable under recommended handling and storage conditions (see Section 7) Contact with powerful oxidizing agents, such as fluorine, chlorine triflouride Possibility of Hazardous Reactions: and oxygen diflouride, may cause fires. Silica will dissolve in hydrofluoric acid and produce a corrosive gas, silicon Hazardous Decomposition: tetraflouride. Adding water results in hydration and produces (caustic) calcium hydroxide. Hazardous Polymerization: Will not occur Extremely high or low temperatures. Incompatible materials. Avoid Conditions to Avoid: generation of dust in handling and use. Acids. Ammonium Salts. Aluminum. Hydrofluoric acid. Water. Oxidizers such Incompatible Materials: as fluorine, chlorine triflouride, oxygen diflouride.
SECTION 11: TOXICOLOGICAL INFORMATION Acute Effects of Exposure: Inhalation of dust may cause respiratory tract irritation. Symptoms of Inhalation: exposure may include cough, sore throat, nasal congestion, sneezing, wheezing, and shortness of breath. Ingestion is an unlikely route of exposure. If dust is swallowed, it may Ingestion: irritate the mouth and throat. Skin contact: May cause an allergic skin reaction. Eye Contact: Causes serious eye damage. Prolonged inhalation of repairable crystalline silica may cause lung disease, Chronic Effects of Exposure: silicosis, lung cancer, and other effects.
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Numerical Measures of Toxicity of Portland Cement: OSHA PEL (TWA) 5 mg/m3. NIOSH REL (TWA) 5 mg/m3. Ingredients: IDLH 5000 mg/m3 Crystalline Silica (quartz): OSHA PEL (TWA) 5 mg/m3. NIOSH REL (TWA) 5
mg/m3. IDLH 5000 mg/m3. LD50 Oral Rat > 5000mg/kg Calcium Oxide: OSHA PEL (TWA) 5 mg/m3. NIOSH REL (TWA) 2 mg/m3. IDLH
25 mg/m3 Gypsum: OSHA PEL (TWA) 15 mg/m3 (Total) 5 mg/m3 (Resp). NIOSH REL
(TWA) 10 mg/m3 (Total) 5 mg/m3 (Resp). Magnesium Oxide: OSHA PEL (TWA) 15 mg/m3. IDLH 750 mg/m3
The three types of silicosis include: 1) Simple chronic silicosis – which results from long-term exposure (more than 20 years) to low amounts of respirable crystalline silica. Nodules of chronic inflammation and scarring provoked by the respirable crystalline silica form in the lungs and chest lymph nodes. This disease may feature breathlessness and may resemble chronic obstructive pulmonary disease (COPD); 2) Accelerated silicosis – occurs after exposure to larger amounts of respirable crystalline silica over a shorter period of time (5-15 years); 3) Acute silicosis – results from short-term exposure to very large amounts of respirable crystalline silica. The lungs become very inflamed and may fill with fluid, causing severe shortness of breath and low blood oxygen levels. Inflammation, scarring, and symptoms progress faster Symptoms/Injuries After in accelerated silicosis than in simple silicosis. Progressive massive fibrosis Inhalation: may occur in simple or accelerated silicosis, but is more common in the accelerated form. Progressive massive fibrosis results from severe scarring and leads to the destruction of normal lung structures. Some studies show that exposure to repairable crystalline silica (without silicosis) or that the disease silicosis may be associated with the increased incidence of several autoimmune disorders such as scleroderma (thickening of the skin), systemic lupus erythematosus, rheumatoid arthritis, and diseases affecting the kidneys. Silicosis increases the risk of tuberculosis. Some studies show an increased incidence of chronic kidney disease and end-stage renal disease in workers exposed to respirable crystalline silica. Corrosive to the respiratory tract. Cement may cause dry skin, discomfort, irritation, severe burns, and dermatitis. Exposure to sufficient duration to wet cement, or to dry cement on moist areas of the body, can cause serious potentially irreversible damage to skin, eye, respiratory, and digestive tracts due to chemical (caustic) burns, including third degree burns. A skin exposure may be Symptoms/Injuries After Skin hazardous even if there is no pain or discomfort. Cement is capable of Contact: causing dermatitis by irrigation and allergy. Skin affected by dermatitis may include symptoms such as; redness, itching, rash, scaling, and cracking. Irritant dermatitis is caused by the physical properties of cement including alkalinity and abrasion. Allergic contact dermatitis is caused by sensitization to hexavalent chromium (chromate) present in cement. The reaction can
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range from a mild rash to severe skin ulcers. Persons already sensitized may react to the first contact with cement. Others may develop allergic dermatitis after years of repeated contact with cement. Airborne dust may cause immediate or delayed irritation or inflammation. Eye contact with large amounts of dry powder or with wet cement can cause Symptoms/Injuries After Eye moderate eye irritation, chemical burns, and blindness. Eye exposures Contact: require immediate first aid and medical attention to prevent significant damage to the eye. May cause burns or irritation of the linings of the mouth, throat, and Symptoms/Injuries After Ingestion gastrointestinal tract. If dust is generated, repeated exposure through inhalation may cause cancer Chronic Symptoms: or lung disease. Information on Carcinogenicity of Ingredients: Portland Cement: TLV-A4 Crystalline Silica: IARC Group 1 Calcium Oxide: Gypsum: Magnesium Oxide: TLV-A4
SECTION 12: ECOLOGICAL INFORMATION Toxicity: Not Classified. No recognized unusual toxicity to plants or animals. Calcium Oxide (1305-78-8) : LC50 Fish: 1070 mg/l (Exposure time: 96 h – Species: Cyprinus carpio [static]) Persistence and Degradability: Crystalline Silica is not degradable. Bioaccumulation Potential: Crystalline Silica is not bioaccumulative. Calcium Oxide (1305-78-8) : BCF fish 1 (no bioaccumulation). Mobility in Soil: Crystalline Silica is not mobile in soil. Other Adverse Effects: No data available.
SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Dispose of waste material in accordance with all local, regional, state, Recommendations: national, provincial, territorial and international regulations. If discarded in its purchased form, this product would not be a hazardous waste either by listing or characteristic. However, under RCRA, it is the Additional Information: responsibility of the product user to determine at the time of disposal, whether a material containing or derived from the product should be classified as a hazardous waste.
SECTION 14: TRANSPORT INFORMATION
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UN Number: None UN Proper Shipping Name: Not regulated Transport Hazard Class(es): None Packing Group, if applicable: None Environmental hazards: None Not regulated for transport by DOT, IMDG,IATA, TDG
SECTION 15: REGULATORY INFORMATION US Federal Regulations USDOL-OSHA Hazard Portland cement is considered a “hazardous chemical” under this regulation, Communication Rule 29CFR and should be part of any hazard communication program. 1900.1200 CERCLA/Superfund 40 CFR 117 and Not classified as a hazardous substance under regulations of this Act. 302(v) Hazard Category under SARA (Title Portland cement qualifies as a “hazardous substance” with immediate III) Section 311 and 312 (acute) and delayed (chronic) health effects Status Under SARA (Title III) Not subject to reporting requirements under Section 313. Section 313 Portland Cement (65997-15-1), Quartz (14808-60-7), Calcium Oxide (1305- Status under TSCA 78-8), Magnesium Oxide (1309-48-4) are listed on United States TSCA (Toxic Substances Control Act) inventory Status under the Federal Portland cement is a “hazardous substance” subject to statutes promulgated Hazardous Substances Act under the subject act. US State Regulations WARNING: This product contains chemicals known to the State of California California Prop 65 to cause cancer. California established a chronic non-cancer effect REL of 3μg for silica California Inhalation Reference (crystalline, respirable). A chronic REL is an airborne level of a substance at Exposure Level (REL) or below which no non-cancer health effects are anticipated in individuals indefinitely exposed to the substance at the level. Portland Cement (65997-15-1), Quartz (14808-60-7), Calcium Oxide (1305- Massachusetts 78-8), Magnesium Oxide (1309-48-4) and Gypsum (13397-24-5) are listed on Right to Know List Portland Cement (65997-15-1), Quartz (14808-60-7), Calcium Oxide (1305- Pennsylvania 78-8), Magnesium Oxide (1309-48-4) and Gypsum (13397-24-5) are listed on RTK (Right to Know) List Portland Cement (65997-15-1), Quartz (14808-60-7), Calcium Oxide (1305- New Jersey 78-8), Magnesium Oxide (1309-48-4) and Gypsum (13397-24-5) are listed on Right to Know Hazardous Substance List CANADA Regulations CANADA Regulations WHMIS Classification Cement, Portland (65997-15-1) Listed on Canadian DSL Inventory. E – Corrosive Material
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Listed on the Canadian Ingredient Disclosure List. D2A – Very toxic material causing Silica, Quartz (14808-60-7) Listed on Canadian DSL Inventory. other toxic effects. Listed on Canadian DSL Inventory. Calcium Oxide (1305-78-8) Listed on the Canadian Ingredient E – Corrosive Material Disclosure List. Listed on Canadian DSL Inventory. Uncontrolled product according to Magnesium Oxide (1309-48-4) Listed on the Canadian Ingredient WHMIS classification criteria. Disclosure List.
SECTION 16: OTHER INFORMATION Date of Preparation: May 10, 2016 Thru Tubing Systems, Inc. 1806B Highway 90 East Prepared By: New Iberia, LA 70560 +1 (337) 606-0031 GHS Full Text Phrases: Carc. 1A Carcinogenicity Category 1A Eye Dam. 1 Serious eye damage/eye irritation Category 1 Skin Corr. 1C Skin corrosion/irritation Category 1C Skin Irrit. 2 Skin corrosion/irritation Category 2 Skin Sens. 1 Skin sensitization Category 1 STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1 STOT SE 3 Specific target organ toxicity (single exposure) Category 3 H314 Causes severe burns and eye damage H315 Causes skin irritation H317 May cause allergic skin reaction H318 Causes serious eye damage H335 May cause respiratory irritation H350 May cause cancer (Inhalation) H372 Causes damage to organs through prolonged or repeated exposure P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust. P264 Wash hands, forearms, and exposed areas thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of workplace. P280 Wear protective gloves, protective clothing, face protection, eye protection. P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P303+P361+P353+P352 IF ON SKIN (or hair): Remove/Take off immediately all contaminated
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clothing. Rinse skin with water/shower. Wash with plenty of soap and water IF INHALED: Remove person to fresh air and keep at rest in a position P304+P340 comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact P305+P351+P338 lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P321 Specific treatment (see Section 4). P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. Dispose of contents/container according to local, regional, state, national, P501 territorial, provincial, and international regulations.
Other Important Information: Portland cement should only be used by knowledgeable persons. Inexperienced product users must obtain proper training before using this product. A key to using the product safely requires the user to recognize the Portland cement chemically reacts with water, and that some of the intermediate products of this reaction (that is, those present while a Portland cement product is “setting “) pose a far more severe hazard than does Portland cement itself. While the information provided in this Safety Data Sheet is believed to provide a useful summary of the hazards of Portland cement as it is commonly used, the sheet cannot, and does not, anticipate and provide all of the information that might be needed in every situation. In particular, the data furnished in this sheet does not address hazards that may be posed by other materials mixed with Portland cement products. Users therefore, should review other applicable material safety data sheets before working with this Portland cement or working on Portland cement or working Portland cement products, for example, Portland cement concrete.
THRU TUBING SYSTEMS, INC. (TTS) MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE OR CONCERNING THE ACCURACY OF ANY INFORMATION PROVIDED BY TTS EXCEPT THAT THE PRODUCT SHALL CONFORM TO CONTRACTED SPECIFICATIONS. THE INFORMATION PROVIDED HEREIN WAS BELIEVED BY TTS TO BE ACCURATE AT THE TIME FO PERPARATION OR PREPARED FROM SOURCES BELIEVED TO BE RELIABLE, BUT IT IS THE RESPONSIBILITY OF THE USER TO INVESTIGATE AND UNDERSTAND OTHER PERTINENT SOURCES OF INFORMATION, TO COMPLY WITH ALL LAWS AND PROCEDURES APPLICABLE TO THE SAFE HANDLING AND USE OF PRODUCT, AND TO DETERMINE THE SUITABILITY OF THE PRODUCT FOR ITS INTENDED USE. BUYER’S EXCLUSIVE REMEDY SHALL BE FOR DAMAGES AND NO CLAIM OF ANY KIND, WHETHER AS TO PRODUCT DELIVERED OR FOR NON-DELIVERY OF PRODUCT, AND WHETHER BASED ON CONTRACT, BREACH OF WARRANTY, NEGLIGENCE, OR OTHERWISE SHALL BE GREATER IN AMOUNT THAN THE PURCHASE PRICE OF THE QUANTITY OF PRODUCT IN RESPECT OF WHICH DAMAGES ARE CLAIMED. IN NO EVENT SHALL TTS BE LIABLE FOR INCIDENTAL OR CONSEQUENTIAL DAMAGES, WHETHER BUYER’S CLAIM IS BASED ON CONTRACT, BREACH OF WARRANTY, NEGLIGENCE, OR OTHERWISE.
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name CONDENSATE (XYRIS) Synonyms HSE-SDS-006 ● PETROLEUM, HYDROCARBON, STABILISED CONDENSATE ● WAITSIA STAGE 1A CONDENSATE ● XPF CONDENSATE ● XYRIS CONDENSATE ● XYRIS PROCESSING FACILITY CONDENSATE ● XYRIS PRODUCTION FACILITY CONDENSATE
1.2 Uses and uses advised against Uses PETROLEUM REFINING
1.3 Details of the supplier of the product Supplier name AWE PERTH PTY LTD (WHOLLY OWNED SUBSIDIARY OF MITSUI & CO LTD) Address Level 3, 1101 Hay Street, West Perth, WA, 6005, AUSTRALIA Telephone (08) 9480 1300 Fax (08) 9480 1388 Email [email protected] Website www.mitsui.com.au/mepau
1.4 Emergency telephone numbers Emergency 1800 882 118
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA Physical Hazards Flammable Liquids: Category 2
Health Hazards Aspiration Hazard: Category 1 Skin Corrosion/Irritation: Category 2 Germ Cell Mutagenicity: Category 1B Carcinogenicity: Category 1A Toxic to Reproduction: Category 1A Specific Target Organ Toxicity (Repeated Exposure): Category 2
Environmental Hazards Aquatic Toxicity (Chronic): Category 3
2.2 GHS Label elements Signal word DANGER Pictograms
SDS Date: 23 Jan 2019 Page 1 of 8 Version No: 1 PRODUCT NAME CONDENSATE (XYRIS)
Hazard statements H225 Highly flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H340 May cause genetic defects. H350 May cause cancer. H360 May damage fertility or the unborn child. H373 May cause damage to organs through prolonged or repeated exposure. H412 Harmful to aquatic life with long lasting effects. Prevention statements P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. Response statements P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P321 Specific treatment is advised - see first aid instructions. P331 Do NOT induce vomiting. P362 Take off contaminated clothing and wash before re-use. P370 + P378 In case of fire: Use appropriate media for extinction. Storage statements P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. Disposal statements P501 Dispose of contents/container in accordance with relevant regulations.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content NATURAL GAS CONDENSATES (PETROLEUM) 64741-47-5 265-047-3 >80% TOLUENE 108-88-3 203-625-9 3 to <10% 1,2,4-TRIMETHYLBENZENE 95-63-6 202-436-9 1 to 3% BENZENE 71-43-2 200-753-7 1 to 3% ETHYLBENZENE 100-41-4 202-849-4 <1% N-HEXANE 110-54-3 203-777-6 <1% MERCURY 7439-97-6 231-106-7 <0.001%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. To protect rescuer, use a Type A (Organic vapour) respirator or an Air-line respirator (in poorly ventilated areas). Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.
SDS Date: 23 Jan 2019 Page 2 of 8 Version No: 1 PRODUCT NAME CONDENSATE (XYRIS)
Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. First aid facilities None allocated.
4.2 Most important symptoms and effects, both acute and delayed See Section 11 for more detailed information on health effects and symptoms.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Dry agent, carbon dioxide or foam. Prevent contamination of drains and waterways.
5.2 Special hazards arising from the substance or mixture Highly flammable. May evolve carbon oxides and hydrocarbons when heated to decomposition. Eliminate all ignition sources including cigarettes, open flames, spark producing switches/tools, heaters, naked lights, pilot lights, mobile phones, etc when handling. Earth containers when dispensing fluids.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code 3YE 3 Normal Foam (protein based foam that is not alcohol resistant). Y Risk of violent reaction or explosion. Wear full fire kit and breathing apparatus. Contain spill and run-off. E Evacuation of people in and around the immediate vicinity of the incident should be considered.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Ventilate area where possible.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place in suitable containers for disposal.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills. Large storage areas should have appropriate fire protection systems.
7.3 Specific end uses No information provided.
SDS Date: 23 Jan 2019 Page 3 of 8 Version No: 1 PRODUCT NAME CONDENSATE (XYRIS)
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ 1,2,4-Trimethylbenzene (as Trimethyl benzene) SWA [AUS] 25 123 -- -- Benzene SWA [AUS] 1 3.2 -- -- Ethyl benzene SWA [AUS] 100 434 125 543 Mercury, elemental vapour (as Hg) SWA [AUS] 0.003 0.025 -- -- Toluene SWA [AUS] 50 191 150 574 n-Hexane SWA [AUS] 20 72 -- --
Biological limits
Ingredient Determinant Sampling Time BEI BENZENE S-Phenylmercapturic acid in urine End of shift 25 µg/g creatinine t,t-Muconic acid in urine End of shift 500 µg/g creatine ETHYLBENZENE Sum of mandelic acid and phenylglyoxylic End of shift at 0.7 g/g creatinine acid in urine end of workweek Ethyl benzene in end-exhaled air Not critical - MERCURY Total inorganic mercury in urine Prior to shift 20 µg/g creatinine N-HEXANE 2,5-Hexanedione in urine (without hydrolysis) End of shift at 0.4 mg/L end of workweek TOLUENE o-Cresol in urine End of shift 0.02 mg/L Toluene in urine End of shift 0.03 mg/L Toluene in blood Prior to last shift 0.02 mg/L of workweek Reference: ACGIH Biological Exposure Indices
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended. Flammable/explosive vapours may accumulate in poorly ventilated areas. Vapours are heavier than air and may travel some distance to an ignition source and flash back.
PPE Eye / Face Wear splash-proof goggles. Hands Wear PVC or rubber gloves. With prolonged use, wear viton (R) or nitrile gloves. Body With prolonged use, wear coveralls. Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance CLEAR YELLOW/BROWN LIQUID Odour HYDROCARBON ODOUR Flammability HIGHLY FLAMMABLE Flash point > 20°C Boiling point 63°C Melting point NOT AVAILABLE Evaporation rate NOT AVAILABLE pH NOT AVAILABLE
SDS Date: 23 Jan 2019 Page 4 of 8 Version No: 1 PRODUCT NAME CONDENSATE (XYRIS)
9.1 Information on basic physical and chemical properties Vapour density NOT AVAILABLE Specific gravity 0.85 Solubility (water) INSOLUBLE Vapour pressure 6.2 kPag @ 37.8°C Upper explosion limit NOT AVAILABLE Lower explosion limit NOT AVAILABLE Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity 1.778 cSt @ 20°C Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles 100 %
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), alkalis (e.g. sodium hydroxide), heat and ignition sources.
10.6 Hazardous decomposition products May evolve carbon oxides and hydrocarbons when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity May be harmful if swallowed, in contact with skin, and/or if inhaled. Information available for the ingredients:
Oral LD50 Dermal LD50 Inhalation LC50 Ingredient
NATURAL GAS CONDENSATES (PETROLEUM) -- -- 600 mg/m³ (rat) TOLUENE 5580 mg/kg (rat) 5000 mg/kg (rabbit) 25.7 - 30 mg/L/4hrs (rat) 1,2,4-TRIMETHYLBENZENE 6000 mg/kg (rat) -- 18 g/m³/4hrs (rat) BENZENE 930 mg/kg (rat) 48 mg/kg (mouse) 9980 ppm (mouse) ETHYLBENZENE 3500 mg/kg (rat) 17800 mg/kg (rabbit) 50 g/m³/2 hours (mouse) N-HEXANE 25 g/kg (rat) 3000 mg/kg (rabbit) 48000 ppm/4 hours (rat) MERCURY 10 - 40 mg/kg -- 0.014 mg/L/4 hours (rat) (expected) Skin Contact may result in drying and defatting of the skin, rash and dermatitis. Eye Contact may result in irritation, lacrimation and redness. Sensitisation Not classified as causing skin or respiratory sensitisation. Mutagenicity May cause genetic defects. Several studies have demonstrated induction of both numerical and structural chromosomal aberrations, sister chromatid exchanges and micronuclei in experimental animals and humans after in vivo benzene exposure.
SDS Date: 23 Jan 2019 Page 5 of 8 Version No: 1 PRODUCT NAME CONDENSATE (XYRIS)
Carcinogenicity May cause cancer. Benzene is classified as carcinogenic to humans (IARC Group 1). Ethylbenzene is classified as possibly carcinogenic to humans (IARC Group 2B). Condensates may contain other polycyclic aromatic hydrocarbons (PCAHs), some of which are classified as probably carcinogenic to humans (IARC Group 2A). Reproductive Over exposure to toluene may damage fertility or the unborn child. STOT - single Over exposure may result in irritation of the nose and throat, coughing, dizziness, drowsiness and headache. exposure STOT - repeated Available evidence from animal studies indicate that repeated or prolonged exposure to this material could exposure result in adverse skin effects. Effects to lungs and central nervous system have also been reported. Chronic exposure to benzene may result in loss of appetite, tremors, anaemia (bone marrow depression), liver and kidney damage. Aspiration Aspiration or inhalation may cause chemical pneumonitis and pulmonary oedema.
12. ECOLOGICAL INFORMATION
12.1 Toxicity Harmful to aquatic life with long lasting effects.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal For small amounts, absorb with sand, vermiculite or similar and dispose of to an approved landfill site. Contact the manufacturer/supplier for additional information if disposing of large quantities (if required). Prevent contamination of drains and waterways as aquatic life may be threatened and environmental damage may result. Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION
CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
14.1 UN Number 3295 3295 3295 14.2 Proper HYDROCARBONS, LIQUID, HYDROCARBONS, LIQUID, HYDROCARBONS, LIQUID, Shipping Name N.O.S. (natural gas condensate) N.O.S. (natural gas condensate) N.O.S. (natural gas condensate)
14.3 Transport 3 3 3 hazard class 14.4 Packing Group II II II 14.5 Environmental hazards Not a Marine Pollutant 14.6 Special precautions for user
SDS Date: 23 Jan 2019 Page 6 of 8 Version No: 1 PRODUCT NAME CONDENSATE (XYRIS)
Hazchem code 3YE GTEPG 3A1 EMS F-E, S-D
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule Classified as a Schedule 7 (S7) Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. Inventory listings AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information MINERAL OILS - NON REFINED: Animal experiments and human experience have shown cancer risks when handling mineral oils. Such cases are reported to have occurred in conditions where poor occupational hygiene practices resulted in prolonged skin contact. CLEANING MINERAL OIL CONTAMINATED CLOTHING: Cleaners are advised that when cleaning oil contaminated clothing it is essential that freshly distilled solvent is used for each batch, including final rinse, as even filtered solvent will leave oil residues.
EXPOSURE STANDARDS - TIME WEIGHTED AVERAGES: Exposure standards are established on the premise of an 8 hour work period of normal intensity, under normal climatic conditions and where a 16 hour break between shifts exists to enable the body to eliminate absorbed contaminants. In the following circumstances, exposure standards must be reduced: Strenuous work conditions; hot, humid climates; high altitude conditions; extended shifts (which increase the exposure period and shorten the period of recuperation).
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as form of product, method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: form of product; frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
SDS Date: 23 Jan 2019 Page 7 of 8 Version No: 1 PRODUCT NAME CONDENSATE (XYRIS)
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com [ End of SDS ]
SDS Date: 23 Jan 2019 Page 8 of 8 Version No: 1 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name ANCOR 1 Synonym(s) CORROSION INHIBITOR
1.2 Uses and uses advised against Use(s) BRINE • CORROSION INHIBITOR • DRILLING FLUID ADDITIVE • OIL AND GAS INDUSTRY
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS GHS classification(s) Serious Eye Damage / Eye Irritation: Category 2A
2.2 Label elements Signal word WARNING
Pictogram(s)
Hazard statement(s) H319 Causes serious eye irritation. Prevention statement(s) P264 Wash thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. Response statement(s) P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/attention. Storage statement(s) None allocated.
Disposal statement(s) None allocated.
2.3 Other hazards No information provided.
SDS Date: 06 May 2015 Page 1 of 6 Version No: 2.2 PRODUCT NAME ANCOR 1
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content TRIETHANOLAMINE 102-71-6 203-049-8 68 to 72% NON HAZARDOUS INGREDIENTS Not Available Not Available 28 to 32%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. To protect rescuer, use a Type A (Organic vapour) respirator or an Air-line respirator (in poorly ventilated areas). Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. First aid facilities Eye wash facilities and safety shower should be available.
4.2 Most important symptoms and effects, both acute and delayed Over exposure may result in irritation to the eyes, nose and respiratory system. May cause allergic contact dermatitis.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains and waterways.
5.2 Special hazards arising from the substance or mixture Combustible. May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Ventilate area where possible. Contact emergency services where appropriate.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place in suitable containers for disposal.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
SDS Date: 06 May 2015 Page 2 of 6 Version No: 2.2 PRODUCT NAME ANCOR 1
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills. Store as a Class C1 Combustible Liquid (AS1940).
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Triethanolamine SWA (AUS) -- 5 -- --
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended. Maintain vapour levels below the recommended exposure standard.
PPE Eye / Face Wear splash-proof goggles. Hands Wear PVC or rubber gloves. Body Wear coveralls. Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator. If spraying, wear a Type A-Class P1 (Organic gases/vapours and Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance COLOURLESS LIQUID Odour SLIGHT ODOUR Flammability CLASS C1 COMBUSTIBLE Flash point > 100°C Boiling point NOT AVAILABLE Melting point NOT AVAILABLE Evaporation rate NOT AVAILABLE pH NOT AVAILABLE Vapour density NOT AVAILABLE Specific gravity 1.1 Solubility (water) SOLUBLE Vapour pressure NOT AVAILABLE Upper explosion limit NOT AVAILABLE Lower explosion limit NOT AVAILABLE Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE
SDS Date: 06 May 2015 Page 3 of 6 Version No: 2.2 PRODUCT NAME ANCOR 1
9.1 Information on basic physical and chemical properties Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Hazardous polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), nitrites, heat and ignition sources.
10.6 Hazardous decomposition products May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity May be harmful if swallowed, in contact with skin, and/or if inhaled. Toxicity Data available for the ingredient: TRIETHANOLAMINE (102-71-6): LD50 (Ingestion): 2200 mg/kg (rabbit) LD50 (Intraperitoneal): 1450 mg/kg (mouse) LD50 (Skin): > 20 mL/kg (rabbit) TDLo (Ingestion): 16 g/kg/64 weeks (mouse - cancer) Skin Contact may result in mild irritation, redness, pain and rash. Eye Contact may result in irritation, lacrimation, pain and redness. May result in burns with prolonged contact. Sensitization Triethanolamine has been reported to cause allergic contact dermatitis. It is not known to cause respiratory sensitisation. Mutagenicity Insufficient data available to classify as a mutagen. Carcinogenicity Triethanolamine is not classifiable as to its carcinogenicity to humans (IARC Group 3). Reproductive Insufficient data available to classify as a reproductive toxin. STOT – single Over exposure may result in irritation of the nose and throat, with coughing. High level exposure may result in exposure breathing difficulties. STOT – repeated Not classified as causing organ effects from repeated exposure. exposure Aspiration This product is not expected to present an aspiration hazard.
12. ECOLOGICAL INFORMATION
12.1 Toxicity LC50 (shrimp): > 100 ppm.
12.2 Persistence and degradability In soil and water, triethanolamine will biodegrade fairly rapidly following acclamation (half-life in the order of days to weeks).
12.3 Bioaccumulative potential Not expected to bioaccumulate.
SDS Date: 06 May 2015 Page 4 of 6 Version No: 2.2 PRODUCT NAME ANCOR 1
12.4 Mobility in soil In soil, residual triethanolamine may leach to groundwater.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Reduce with sodium thiosulphate/ bisulphite (not strong reducing agent), acidify with 3M sulphuric acid. Scoop into a container of water and neutralise with soda ash. Absorb with sand or similar and dispose of to an approved landfill site. Contact the manufacturer/supplier for additional information (if required). Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule Classified as a Schedule 5 (S5) Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes Xi Irritant Risk phrases R36 Irritating to eyes. Safety phrases S36 Wear suitable protective clothing. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
SDS Date: 06 May 2015 Page 5 of 6 Version No: 2.2 PRODUCT NAME ANCOR 1
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au. [ End of SDS ]
SDS Date: 06 May 2015 Page 6 of 6 Version No: 2.2 Material Safety Data Sheet
EMERGENCY PHONE PRODUCT NAME 1-800-255-3924 BROMINE TRIFLUORIDE CAS #7787-71-5 TRADE NAME AND SYNONYMS Pipe Recovery Systems, Inc. Bromine Trifluoride UN - 1746 PACKING GROUP I Houston, Texas, USA CHEMICAL NAME AND SYNONYMS (713) 461-7770 Bromine Trifluoride
ISSUE DATE 04/78, 02/84 FORMULA CHEMICAL FAMILY REVISION DATE 5/95, 7/99, 8/02, 2/03, 4/04, BrF3 Halogen Fluoride 6/06, 6/07, 8/07, 05/09, 10/11 HEALTH HAZARD DATA TIME WEIGHTED AVERAGE EXPOSURE LIMIT See last page SYMPTOMS OF EXPOSURE Corrosive and extremely irritating to the upper and lower respiratory tracts, skin, and eyes. BrF3 hydrolyzes to form hydrofluoric acid, therefore skin burns and mucous membrane irritation are similar to those caused by the acid. Symptoms include tearing of the eyes, cough, difficult breathing, abnormal fluids formation in the nose, mouth and throat. Inhalation of BrF3 may cause pneumonitis ( deep lung inflammation) and pulmonary edema (abnormal fluid buildup in the lungs) which can be fatal. Symptons of hydrofluoric acid burns are severe pain, redness, possible swelling and tissue destruction. TOXICOLOGICAL PROPERTIES Bromine Trifluoride is irritating and corrosive to all living tissues. Toxic level exposure to skin tissue causes hydrofluoric acid burns and skin lesions resulting in tissue destruction and eventual scarring. Burn activity continues while any residual active fluorides remain. Chemical pneumonitis and pulmonary edema result from exposure to the lower respiratory tract and deep lung. Residual pulmonary malfunction might also occur. Burns of the eye result in lesions and possible loss of vision. Extended low level systemic absorption of fluorides may cause fluorosis, an abnormal calcium accumulation in the bone structure. RECOMMENDED FIRST AID TREATMENT PROMPT MEDICAL ATTENTION IS REQUIRED IN ALL CASES OF OVEREXPOSURE. BROMINE TRIFLUORIDE RESCUE PERSONNEL SHOULD BE EQUIPPED WITH APPROPRIATE PROTECTIVE EQUIPMENT (SELF-CONTAINED BREATHING APPARATUS, ETC.) TO PREVENT UNNECESSARY EXPOSURE. Inhalation: Move exposed personnel to an uncontaminated area. If not breathing, give artifical respiration, preferably mouth-to-mouth. If breathing is difficult, give oxygen. Keep victim warm and quiet. Assure that mucus or vomited material does not obstruct the airway by use of positional drainage. Delayed pulmonary edema may occur. Keep patient under medical observation for at least 24 hours. Eye Contact: PERSONS WITH POTENTIAL EXPOSURE TO BROMINE TRIFLUORIDE SHOULD NOT WEAR CONTACT LENSES. Flush contaminated eye(s) with large quantites of water. Hold eyelids open with fingers to assure complete flushing. Continue for minimum of 30 minutes. Skin Contact: Flush affected area with large quantities of water. Remove affected clothing as rapidly as possible. Skin burns may be treated with a calcium gluconate gel or slurry in water or glycerine. This compound binds the active fluorides in an insoluble form and limits burn extension and relieves pain. HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES Bromine Trifluoride is a very reactive halogen fluoride. It reacts with virtually all organic and most inorganic substances. Some of the perfluorinated organic substances in their pure form will not be oxidized by Bromine Trifluoride. It reacts violently with water or fuels. PHYSICAL DATA BOILING POINT 258.4°F (125.8°C) LIQUID DENSITY AT BOILING 157.2 lb/ft 3 (2518Kg/m 3 ) VAPOR PRESSURE @70°F (21.1°C) 0.145psia (1.0 kPa) GAS DENSITY AT 79°F 1 atm Liquid SOLUBILITY IN WATER Reacts violently FREEZING POINT 47.8°F (8.8°C) APPEARANCE AND ODOR Colorless, fuming liquid with a choking, pungent odor. FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Method used) AUTO IGNITION TEMPERATURE FLAMMABLE LIMITS % BY VOLUME N/A N/A LEL UEL N/A EXTINGUISHING MEDIA ELECTRICAL CLASSIFICATION Nonflammable Nonhazardous SPECIAL FIRE FIGHTING PROCEDURES UNUSUAL FIRE AND EXPLOSION HAZARDS Fires with bromine trifluoride as the oxidizer can only be extinguished Reacts violently or explodes on contact with water or organic mate- by shutting off the source of bromine trifluoride. Do not use water, rials. Combustion products, including hydrogen fluoride, are toxic chemicals, carbon dixide or other extinguishing media as these will and reactive. only add more fuel to the fire. REACTIVITY DATA STABILITY CONDITIONS TO AVOID Unstable
Stable X Reacts violently or explodes on contact with water and organic materials. INCOMPATIBILITY (Material to avoid) Water, plastics, hydrocarbons, other organic materials. HAZARDOUS DECOMPOSITION PRODUCTS Bromine, fluorine, bromine monofluoride; hydrogen fluoride in reactions HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID
May Occur Will Not Occur X SPILL OR LEAK PROCEDURES STEPS TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Evacuate all personnel from affected area. Use appropriate protective equipment. Call company technical supervisor or Pipe Recovery phone number (713)461-7770. WASTE DISPOSAL METHOD All Federal, State and Local Regulations regarding health and pollution should be followed in waste disposal. Contact Pipe Recovery Systems for specific recommendations. Do not dispose of unused quantities. Contact Tech Manager or Pipe Recovery Systems for instructions. SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (Specify type) Full face respirator, positive pressure airline or self breathing apparatus. VENTILATION INDOOR: Hood with forced ventilation OUTDOOR: Open area, none required PROTECTIVE GLOVES EYE PROTECTION Neoprene Rubber Full face piece respirator OTHER PROTECTIVE EQUIPMENT Safety shoes, eyewash and acid resistant overgarments. SPECIAL PRECAUTIONS* SPECIAL LABELING INFORMATION D.O.T.Shipping Name:Bromine Trifluoride D.O.T.Shipping Label:Oxidizer, corrosive,poison, inhalation hazard. D.O.T.Shipping Class: Oxidizer I.D. No.: UN 1746 Zone B SPECIAL HANDLING RECOMMENDATIONS Use in only well-ventilated areas. Do not drag, slide or roll cylinder. SPECIAL STORAGE RECOMMENDATIONS Protect cylinders from physical damage. Store in cool, dry, well-ventilated area away from heavily trafficked areas and emergency exits. Do not allow the temperature where cylinders are stored to exceed 130°F (54°C) Full and empty cylinders should be segregated. Use a "first-in-first-out" inventory system. TIME WEIGHTED AVERAGE EXPOSURE LIMIT None established (ACGIH 1984-85). Observation of the exposure limits for hydrogen fluoride, which forms when BrF3 is hydrolyzed, is recommended. The TWA for HF is 3 molar ppm; the STEL is 6 molar ppm (ACGIH 1984-85) Note: ACGIH (1984-85) has proposed adoption of a ceiling value of 3 molar for HF. Local Exhaust: To prevent accumulation above the TWA for hydrogen fluoride
*Various Government agencies (I.e., Department of Transportation, Occupational Safety and Health Administration, Food and Drug Administration and others) may have specific regulations concerning the transportation, handling, storage or use of this product which will not be reflected in this data sheet. The customer should review these regulations to ensure that he is in full compliance.
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name CALCIUM CARBONATE Synonym(s) ABGRIT ● CIRCAL ● LIMESTONE ● MARBLE ● NEWCARB, AG LIMESTONE, UNICAL 20, UNICAL 40 AND UNICAL C300C ● OMYACAL ● OMYACARB ● RHEOCARB ● STONEDUST
1.2 Uses and uses advised against Use(s) DRILLING FLUID ADDITIVE ● WEIGHTING AGENT
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content LIMESTONE (CALCIUM CARBONATE) 1317-65-3 215-279-6 >96% QUARTZ (CRYSTALLINE SILICA) 14808-60-7 238-878-4 <1%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Ingestion For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. First aid facilities Eye wash facilities and safety shower should be available.
SDS Date: 24 Feb 2017 Page 1 of 6 Version No: 2.3 PRODUCT NAME CALCIUM CARBONATE
4.2 Most important symptoms and effects, both acute and delayed May cause irritation to the eyes, skin and respiratory system.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture Non flammable. May evolve toxic gases if strongly heated.
5.3 Advice for firefighters No fire or explosion hazard exists.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up If spilt, collect and reuse where possible. If reuse is not possible, contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Calcium carbonate (Limestone, Marble, Whiting) SWA (AUS) -- 10 -- -- Quartz (respirable dust) SWA (AUS) -- 0.1 -- --
Biological limits No Biological Limit Value allocated.
SDS Date: 24 Feb 2017 Page 2 of 6 Version No: 2.3 PRODUCT NAME CALCIUM CARBONATE
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended. Maintain dust levels below the recommended exposure standard.
PPE Eye / Face Wear dust-proof goggles. Hands When using large quantities or where heavy contamination is likely, wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance OFF-WHITE POWDER Odour ODOURLESS Flammability NON FLAMMABLE Flash point NOT RELEVANT Boiling point 840°C (Decomposes) Melting point 825°C Evaporation rate NOT AVAILABLE pH 9 Vapour density NOT AVAILABLE Specific gravity 2.7 Solubility (water) INSOLUBLE Vapour pressure NOT AVAILABLE Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization will not occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with acids (e.g. nitric acid), fluorine, aluminium (hot) and ammonium salts. Incompatible with oxidising agents (e.g. hypochlorites).
10.6 Hazardous decomposition products May evolve toxic gases if heated to decomposition.
SDS Date: 24 Feb 2017 Page 3 of 6 Version No: 2.3 PRODUCT NAME CALCIUM CARBONATE
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity This product is expected to be of low toxicity. Based on available data, the classification criteria are not met. LD50 (Ingestion) = 6450 mg/kg (rat). Information available for the ingredient(s):
Oral Toxicity (LD50) Dermal Toxicity (LD50) Inhalation Toxicity Ingredient (LC50) LIMESTONE (CALCIUM CARBONATE) > 5000 mg/kg (rat) -- -- Skin Not classified as a skin irritant. Contact may result in mild irritation, redness and rash. Eye Not classified as an eye irritant. However, direct contact may result in mild irritation, lacrimation, pain and redness. Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness. Sensitisation Not classified as causing skin or respiratory sensitisation. Mutagenicity Not classified as a mutagen. Insufficient data available to classify as a mutagen. Carcinogenicity Insufficient data available to classify as a carcinogen. Reproductive Insufficient data available to classify as a reproductive toxin. STOT - single Not classified as causing organ damage from single exposure. exposure STOT - repeated Not classified as causing organ damage from repeated exposure. Chronic exposure to respirable silica may exposure result in pulmonary fibrosis (silicosis). However, given the low levels present, over exposure is not anticipated. Aspiration This product does not present an aspiration hazard.
12. ECOLOGICAL INFORMATION
12.1 Toxicity Calcium carbonate occurs naturally in a wide variety of substances including limestone, marble and egg shells. It is not anticipated to cause adverse environmental effects.
12.2 Persistence and degradability Dissolved calcium carbonate dissociates into calcium and carbonate ions. Calcium ions will be assimilated by living organisms in the water and the carbonate will become part of the carbon cycle.
12.3 Bioaccumulative potential This product does not bioaccumulate.
12.4 Mobility in soil Due to its limited solubility, calcium carbonate precipitates and deposits on the sediment.
12.5 Other adverse effects Avoid contamination of drains and waterways.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Council landfill. Contact the manufacturer/supplier for additional information (if required). Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
SDS Date: 24 Feb 2017 Page 4 of 6 Version No: 2.3 PRODUCT NAME CALCIUM CARBONATE
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
14.1 UN Number None allocated. None allocated. None allocated. 14.2 Proper None allocated. None allocated. None allocated. Shipping Name
14.3 Transport None allocated. None allocated. None allocated. hazard class 14.4 Packing Group None allocated. None allocated. None allocated. 14.5 Environmental hazards No information provided. 14.6 Special precautions for user Hazchem code None allocated.
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
EXPOSURE CONTROL: If utilised in a closed system the potential for over exposure is reduced. If not used in a closed system, local exhaust ventilation is recommended to control exposure. Provide eye wash and safety shower in close proximity to points of potential exposure. Where the potential for an inhalation risk exists, an approved respirator may be required. Do not eat, store, consume food, tobacco or drink in areas where product is used.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as form of product, method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: form of product; frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
SDS Date: 24 Feb 2017 Page 5 of 6 Version No: 2.3 PRODUCT NAME CALCIUM CARBONATE
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au
[ End of SDS ]
SDS Date: 24 Feb 2017 Page 6 of 6 Version No: 2.3 SAFETY DATA SHEET Fluorodye UC
Section: 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : Fluorodye UC
Other means of identification : Not applicable.
Recommended use : PROCESS AID
Restrictions on use : Refer to available product literature or ask your local Sales Representative for restrictions on use and dose limits.
Company : ECOLAB PTY LTD 2 Drake Avenue Macquarie Park NSW 2113 Australia A.B.N. 59 000 449 990 TEL: 1300 654 224 FAX: +61 2 8870 8680
Emergency telephone : 1800 205 506 number International: +64 7 958 2372
Issuing date : 19.02.2017
Section: 2. HAZARDS IDENTIFICATION
GHS Classification Skin corrosion/irritation : Category 2 Serious eye damage/eye : Category 1 irritation Specific target organ toxicity : Category 2 (Kidney) - repeated exposure
GHS Label element Hazard pictograms :
Signal Word : Danger
Hazard Statements : Causes skin irritation. Causes serious eye damage. May cause damage to organs (Kidney) through prolonged or repeated exposure.
Precautionary Statements : Prevention: Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/ eye protection/ face protection. Wash skin thoroughly after handling. Response: IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Get medical advice/ attention if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Disposal: Dispose of contents/ container to an approved waste disposal plant.
1 / 9 SAFETY DATA SHEET
Fluorodye UC
Other hazards : Do not mix with bleach or other chlorinated products – will cause chlorine gas.
Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS-No. Concentration: (%) Ethylene Glycol 107-21-1 10 - 30 Acetic Acid 64-19-7 10 - 30 C.I. Basic Violet 10 (Rhodamine B or D&C Red No 19) 81-88-9 10 - 30
Section: 4. FIRST AID MEASURES
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately.
In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Get medical attention if irritation develops and persists.
If swallowed : Rinse mouth. Get medical attention if symptoms occur.
Contact the Poison's Information Centre (eg Australia 13 1126; New Zealand 0800 764 766).
If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention if symptoms occur.
Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put yourself at risk of injury. If in doubt, contact emergency responders. Use personal protective equipment as required.
Notes to physician : Treat symptomatically.
Most important symptoms : See Section 11 for more detailed information on health effects and symptoms. and effects, both acute and delayed
Section: 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing : None known. media
Specific hazards during : Not flammable or combustible. firefighting
Hazardous combustion : Decomposition products may include the following materials: Carbon oxides products
Special protective equipment : Use personal protective equipment. for firefighters
Specific extinguishing : Fire residues and contaminated fire extinguishing water must be disposed of in methods accordance with local regulations.
Section: 6. ACCIDENTAL RELEASE MEASURES
2 / 9 SAFETY DATA SHEET
Fluorodye UC
Personal precautions, : Ensure adequate ventilation. Keep people away from and upwind of spill/leak. protective equipment and Avoid inhalation, ingestion and contact with skin and eyes. When workers are emergency procedures facing concentrations above the exposure limit they must use appropriate certified respirators. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8.
Environmental precautions : Do not allow contact with soil, surface or ground water.
Methods and materials for : Stop leak if safe to do so. Contain spillage, and then collect with non- containment and cleaning up combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway.
Section: 7. HANDLING AND STORAGE
Advice on safe handling : Avoid contact with skin and eyes. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Wash hands thoroughly after handling. Do not mix with bleach or other chlorinated products – will cause chlorine gas.
Conditions for safe storage : Keep out of reach of children. Keep container tightly closed. Store in suitable labelled containers.
Suitable material : Keep in properly labelled containers.
Unsuitable material : not determined
Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters Exposure guidelines have not been established for this product. Available exposure limits for the substance(s) are shown below. Components CAS-No. Form of exposure Permissible Basis concentration Ethylene Glycol 107-21-1 TWA (Vapour.) 20 ppm AU OEL 52 mg/m3 VLE (Vapour.) 40 ppm AU OEL 104 mg/m3 TWA 10 mg/m3 AU OEL (Particulate.) Ethylene Glycol 107-21-1 WES-Ceiling 50 ppm NZ OEL (Vapour and mist) 127 mg/m3 Ethylene Glycol 107-21-1 Ceiling (Aerosol 100 mg/m3 ACGIH only) Acetic Acid 64-19-7 VLE 15 ppm AU OEL 37 mg/m3 TWA 10 ppm AU OEL 25 mg/m3 Acetic Acid 64-19-7 WES-TWA 10 ppm NZ OEL 25 mg/m3 WES-STEL 15 ppm NZ OEL 37 mg/m3 Acetic Acid 64-19-7 TWA 10 ppm ACGIH STEL 15 ppm ACGIH
3 / 9 SAFETY DATA SHEET
Fluorodye UC
STEL 15 ppm NIOSH REL 37 mg/m3 TWA 10 ppm NIOSH REL 25 mg/m3 TWA 10 ppm OSHA Z1 25 mg/m3
Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards.
Personal protective equipment
Eye protection : Safety goggles Face-shield
Hand protection : Wear the following personal protective equipment: Standard glove type. Laminate film Nitrile Unsupported neoprene PVC Natural rubber Neoprene/natural rubber blend Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
Skin protection : Wear suitable protective clothing.
Respiratory protection : No personal respiratory protective equipment normally required.
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling. Provide suitable facilities for quick drenching or flushing of the eyes and body in case of contact or splash hazard.
Section: 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : liquid Colour : dark Odour : stinging Flash point : Not applicable. pH : 3.1, 1 - 10 %, (as aqueous solution) Odour Threshold : no data available Melting point/freezing point : not determined Initial boiling point and boiling : ca. 100 °C range Evaporation rate : not determined Flammability (solid, gas) : no data available Upper explosion limit : not determined Lower explosion limit : not determined Vapour pressure : 15.7 hPa, (20 °C), Relative vapour density : not determined
4 / 9 SAFETY DATA SHEET
Fluorodye UC
Relative density : 1.052 - 1.082, (20 °C), Density : no data available Water solubility : soluble Solubility in other solvents : no data available Partition coefficient: n- : no data available octanol/water Auto-ignition temperature : > 400 °C Thermal decomposition : no data available temperature Viscosity, dynamic : ca. 50 - 100 mPa.s (20 °C) Viscosity, kinematic : no data available Molecular weight : no data available VOC : no data available
Section: 10. STABILITY AND REACTIVITY
Chemical stability : Stable under normal conditions.
Possibility of hazardous : Do not mix with bleach or other chlorinated products – will cause chlorine gas. reactions
Conditions to avoid : None known.
Incompatible materials : Strong acids Strong bases Strong oxidizing agents
Hazardous decomposition : Decomposition products may include the following materials: products Carbon oxides
Section: 11. TOXICOLOGICAL INFORMATION
Information on likely routes of : Inhalation, Eye contact, Skin contact exposure
Potential Health Effects
Eyes : Causes serious eye damage.
Skin : Causes skin irritation.
Ingestion : Health injuries are not known or expected under normal use.
Inhalation : Health injuries are not known or expected under normal use.
Chronic Exposure : May cause damage to organs through prolonged or repeated exposure.
Experience with human exposure
Eye contact : Redness, Pain, Corrosion
Skin contact : Redness, Irritation
Ingestion : No symptoms known or expected.
5 / 9 SAFETY DATA SHEET
Fluorodye UC
Inhalation : No symptoms known or expected.
Toxicity
Product Acute oral toxicity : Acute toxicity estimate: > 2,000 mg/kg Acute inhalation toxicity : no data available Acute dermal toxicity : Acute toxicity estimate: > 2,000 mg/kg Skin corrosion/irritation : no data available Serious eye damage/eye : no data available irritation Respiratory or skin : no data available sensitization Carcinogenicity : no data available Reproductive effects : no data available Germ cell mutagenicity : no data available Teratogenicity : no data available STOT - single exposure : no data available STOT - repeated exposure : no data available Aspiration toxicity : no data available Human Hazard Characterization Based on our hazard characterization, the potential human hazard is: High
Section: 12. ECOLOGICAL INFORMATION
Ecotoxicity
Environmental Effects : This product has no known ecotoxicological effects.
Product Toxicity to fish : no data available
Toxicity to daphnia and other : no data available aquatic invertebrates
Toxicity to algae : no data available
Components Toxicity to fish : Ethylene Glycol LC50 : 72,860 mg/l Exposure time: 96 h
Acetic Acid LC50 Oncorhynchus mykiss (rainbow trout): 1,000 mg/l Exposure time: 96 h
Components Toxicity to daphnia and other : Ethylene Glycol aquatic invertebrates EC50 : > 100 mg/l
6 / 9 SAFETY DATA SHEET
Fluorodye UC
Exposure time: 48 h
Acetic Acid EC50 Daphnia magna (Water flea): 39.6 mg/l Exposure time: 48 h
Components Toxicity to algae : Ethylene Glycol EC50 : 6,500 mg/l Exposure time: 96 h
Acetic Acid EC50 Skeletonema costatum (marine diatom): 1,000 mg/l Exposure time: 72 h
Components Toxicity to bacteria : Ethylene Glycol > 1,995 mg/l
Components Toxicity to fish (Chronic : Ethylene Glycol toxicity) NOEC: 15,380 mg/l Exposure time: 7 d
Components Toxicity to daphnia and other : Ethylene Glycol aquatic invertebrates NOEC: 8,590 mg/l (Chronic toxicity) Exposure time: 7 d
Persistence and degradability no data available
Mobility no data available
Bioaccumulative potential no data available
Other information no data available
ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION Based on our hazard characterization, the potential environmental hazard is: Low
Section: 13. DISPOSAL CONSIDERATIONS
Disposal methods : Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility.
Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or
7 / 9 SAFETY DATA SHEET
Fluorodye UC
disposal. Do not re-use empty containers.
Section: 14. TRANSPORT INFORMATION
The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport.
Land transport
Proper shipping name : Dye, liquid, corrosive, n.o.s. Technical name(s): : Acetic Acid UN/ID No. : UN 2801 Transport hazard class(es) : 8 Packing group : III Air transport (IATA)
UN/ID No. : UN 2801 Proper shipping name : Dye, liquid, corrosive, n.o.s. Technical name(s) : Acetic Acid Transport hazard class(es) : 8 Packing group : III
Sea transport (IMDG/IMO)
UN/ID No. : UN 2801 Proper shipping name : Dye, liquid, corrosive, n.o.s. Technical name(s) : Acetic Acid Transport hazard class(es) : 8 Packing group : III
Section: 15. REGULATORY INFORMATION
Standard for the Uniform : Schedule 6 Scheduling of Medicines and Poisons INTERNATIONAL CHEMICAL CONTROL LAWS :
Australia. Industrial Chemical (Notification and Assessment) Act All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme (NICNAS).
Section: 16. OTHER INFORMATION
REFERENCES
Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer.
Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.
8 / 9 SAFETY DATA SHEET
Fluorodye UC
Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
Revision Date : 19.02.2017 Version Number : 1.0 Prepared By : Regulatory Affairs
REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. For additional copies of an SDS visit www.nalco.com and request access.
9 / 9 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name FRACSEAL FINE/MEDIUM Synonym(s) FRACSEAL F • FRACSEAL FINE • FRACSEAL M • FRACSEAL MEDIUM
1.2 Uses and uses advised against Use(s) DRILLING FLUID ADDITIVE
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content CELLULOSE 9004-34-6 232-674-9 100%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin Exposure is considered unlikely. Skin irritation is not anticipated. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Due to product form and application, ingestion is considered unlikely. First aid facilities No information provided.
4.2 Most important symptoms and effects, both acute and delayed This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated.
Page 1 of 6 SDS Date: 25 Nov 2014 PRODUCT NAME FRACSEAL FINE/MEDIUM
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains and waterways.
5.2 Special hazards arising from the substance or mixture Combustible. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Finely divided dust may form explosive mixtures with air.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Moisten with water to prevent a dust hazard and place in sealable containers for disposal.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for damage to containers.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Cellulose (paper fibre) (a) SWA (AUS) -- 10 -- --
Biological limits No biological limit values have been entered for this product.
Page 2 of 6 SDS Date: 25 Nov 2014 PRODUCT NAME FRACSEAL FINE/MEDIUM
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Maintain dust levels below the recommended exposure standard.
PPE Eye / Face When using large quantities or where heavy contamination is likely, wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance YELLOW TO BROWN SOLID Odour ODOURLESS Flammability COMBUSTIBLE Flash point NOT AVAILABLE Boiling point NOT AVAILABLE Melting point 500°C to 518°C Evaporation rate NOT AVAILABLE pH 6.5 to 7.5 Vapour density NOT AVAILABLE Specific gravity 0.9 Solubility (water) INSOLUBLE Vapour pressure NOT AVAILABLE Upper explosion limit NOT AVAILABLE Lower explosion limit NOT AVAILABLE Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (e.g. hypochlorites).
10.6 Hazardous decomposition products May evolve carbon oxides and hydrocarbons when heated to decomposition.
Page 3 of 6 SDS Date: 25 Nov 2014 PRODUCT NAME FRACSEAL FINE/MEDIUM
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated. Oral LD50 (rat) is > 5000 mg/kg. Dermal LD50 (rabbit) is > 2000 mg/kg. LC50 (rat) is 510 mg/m³/2 hours. Skin Not classified as a skin irritant. Eye Not classified as an eye irritant. Contact may cause mild discomfort. Sensitization This product is not known to be a skin or respiratory sensitiser. Mutagenicity No evidence of mutagenic effects. Carcinogenicity No evidence of carcinogenic effects. Reproductive No evidence of reproductive effects. STOT – single Not classified as causing organ effects from single exposure. exposure STOT – repeated Not classified as causing organ effects from repeated exposure. exposure Aspiration Not relevant.
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Reuse where possible. No special precautions are normally required when handling this product. Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user
Page 4 of 6 SDS Date: 25 Nov 2014 PRODUCT NAME FRACSEAL FINE/MEDIUM
Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Page 5 of 6 SDS Date: 25 Nov 2014 PRODUCT NAME FRACSEAL FINE/MEDIUM
Revision history Revision Description 3.2 Standard SDS Review. 3.1 Standard SDS Review. 3.0 Converted to GHS. 2.0 Standard SDS Review 1.0 Initial SDS creation
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 3.2 SDS date: 25 November 2014 [ End of SDS ]
Page 6 of 6 SDS Date: 25 Nov 2014 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name GUAR GUM Synonym(s) CYNOPSIS TETRAGONALOBA • GUARGUM • VISCOSIFIER
1.2 Uses and uses advised against Use(s) EMULSIFIER • FOOD ADDITIVE • PAPER COATING • STABILISER • THICKENING AGENT
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content GUAR GUM 9000-30-0 232-536-8 >90%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. First aid facilities Eye wash facilities and safety shower are recommended.
SDS Date: 02 Jun 2015 Page 1 of 6 Version No: 2.3 PRODUCT NAME GUAR GUM
4.2 Most important symptoms and effects, both acute and delayed Individuals with pre-existing respiratory impairment (eg asthmatics) may be more susceptible to adverse health effects.
4.3 Immediate medical attention and special treatment needed Treat symptomatically. Material swells on contact with water.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Dry agent, carbon dioxide or water fog. Prevent contamination of drains and waterways.
5.2 Special hazards arising from the substance or mixture Combustible. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Finely divided dust may form explosive mixtures with air.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contact emergency services where appropriate.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately labelled and tightly closed when not in use.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards No exposure standards have been entered for this product.
Biological limits No Biological Limit Value allocated.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Maintain dust levels below the recommended exposure standard.
SDS Date: 02 Jun 2015 Page 2 of 6 Version No: 2.3 PRODUCT NAME GUAR GUM
PPE Eye / Face Wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body Wear safety boots. When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator. At high dust levels, wear a Class P3 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance OFF-WHITE POWDER Odour SLIGHT ODOUR Flammability COMBUSTIBLE Flash point NOT AVAILABLE Boiling point NOT AVAILABLE Melting point NOT AVAILABLE Evaporation rate NOT AVAILABLE pH 6.8 - 7.5 (1.0% slurry) Vapour density NOT AVAILABLE Specific gravity NOT AVAILABLE Solubility (water) SOLUBLE Vapour pressure NOT AVAILABLE Upper explosion limit NOT AVAILABLE Lower explosion limit NOT AVAILABLE Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
10.6 Hazardous decomposition products May evolve carbon oxides and hydrocarbons when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
SDS Date: 02 Jun 2015 Page 3 of 6 Version No: 2.3 PRODUCT NAME GUAR GUM
Acute toxicity Information available for the product: This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated. Information available for the ingredient(s):
Oral Toxicity Dermal Toxicity Inhalation Toxicity Ingredient (LD50) (LD50) (LC50) GUAR GUM 6000 mg/kg (Hamster) -- -- Additional ingredient toxicity value(s): GUAR GUM (9000-30-0) TDLo (oral) 228,000 mg/kg/13 weeks continuous (rat) Skin Not classified as a skin irritant. Contact may result in mild irritation. Eye Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness. Sensitization This product is not classified to be a skin or respiratory sensitiser. However, individuals with pre-existing respiratory impairment (eg asthmatics) may be more susceptible to adverse health effects. Mutagenicity No evidence of mutagenic effects. Carcinogenicity No evidence of carcinogenic effects. Reproductive No evidence of reproductive effects. STOT – single No known effects from this product. exposure STOT – repeated No known effects from this product. exposure Aspiration This product does not present an aspiration hazard.
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Council landfill. Contact the manufacturer/supplier for additional information (if required). Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
SDS Date: 02 Jun 2015 Page 4 of 6 Version No: 2.3 PRODUCT NAME GUAR GUM
LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
SDS Date: 02 Jun 2015 Page 5 of 6 Version No: 2.3 PRODUCT NAME GUAR GUM
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au. [ End of SDS ]
SDS Date: 02 Jun 2015 Page 6 of 6 Version No: 2.3 Issue Date: September 2017 SDS No: 722 Version: V.0.0.2 TelChem Hydrochloric Acid 15%
Telford Industries Safety Data Sheet according to WHS and ADG requirements
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
Product name TelChem Hydrochloric Acid 15% Chemical Name Hydrochloric Acid 15 % Synonyms Muriatic Acid Proper shipping name HYDROCHLORIC ACID Chemical formula HCl Other means of identification Not Available
Relevant identified uses of the substance or mixture and uses advised against
Relevant Identified Uses Acidising of petroleum wells, Boiler scale removal, Chemical intermediate, Ore reduction, Pickling and metal cleaning, Alcohol denaturant, pH adjusting of swimming pool water.
Details of the supplier of the safety data sheet
Company Name Telford Industries Address 7 Valentine Street Kewdale WA 6105 Australia Telephone +61 8 9353 2053 / 1800 835 115 Fax +61 8 9353 2054 Website https://www.telfordindustries.com.au/ Email [email protected]
Emergency telephone number
Association/Organisation Not Available Emergency telephone numbers 1800 774 557 Other Emergency telephone numbers 1800 SPILLS
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.
Poisons Schedule S6 Classification Metal Corrosion Category 1, Acute Toxicity (Inhalation) Category 2, Skin Corrosion/Irritation Category 1A, Serious Eye Damage Category 1 Label Elements
GHS label elements
SIGNAL WORD DANGER
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Issue Date: September 2017 SDS No: 722 Version: V.0.0.2 Hazard statement(s)
H290 May be corrosive to metals. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage. H330 Fatal if inhaled.
Precautionary statement(s) Prevention
P260 Do not breathe dust/fume/gas/mist/vapours/spray. P270 Do not eat, drink or smoke when using this product P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P234 Keep only in original container. P284 Wear respiratory protection.
Precautionary statement(s) Response
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and P305+P351+P338 easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P363 Wash contaminated clothing before reuse. P390 Absorb spillage to prevent material damage. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Precautionary statement(s) Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.
Precautionary statement(s) Disposal
P501 Dispose of contents/container in accordance with local regulations.
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Substances
CAS No % [weight] Name 7647-01-0 15 hydrochloric acid Not Available <0.1 silica 7440-32-6 <1 titanium 7732-18-5 balance water
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Issue Date: September 2017 SDS No: 722 Version: V.0.0.2
SECTION 4 FIRST AID MEASURES
Description of first aid measures
If this product comes in contact with the eyes: Immediately hold eyelids apart and flush the eye continuously with running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Eye Contact Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If skin or hair contact occurs: Immediately flush body and clothes with large amounts of water, using safety shower if available. Quickly remove all contaminated clothing, including footwear. Skin Contact Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre. Transport to hospital, or doctor. If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to Inhalation initiating first aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor, without delay. For advice, contact a Poisons Information Centre or a doctor at once. Urgent hospital treatment is likely to be needed. If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Ingestion Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Transport to hospital or doctor without delay.
Indication of any immediate medical attention and special treatment needed
Treat symptomatically. For acute or short term repeated exposures to strong acids:
Airway problems may arise from laryngeal edema and inhalation exposure. Treat with 100% oxygen initially. Respiratory distress may require cricothyroidotomy if endotracheal intubation is contraindicated by excessive swelling Intravenous lines should be established immediately in all cases where there is evidence of circulatory compromise. Strong acids produce a coagulation necrosis characterised by formation of a coagulum (eschar) as a result of the dessicating action of the acid on proteins in specific tissues. INGESTION:
Immediate dilution (milk or water) within 30 minutes post ingestion is recommended. DO NOT attempt to neutralise the acid since exothermic reaction may extend the corrosive injury. Be careful to avoid further vomit since re-exposure of the mucosa to the acid is harmful. Limit fluids to one or two glasses in an adult. Charcoal has no place in acid management. Some authors suggest the use of lavage within 1 hour of ingestion. SKIN:
Skin lesions require copious saline irrigation. Treat chemical burns as thermal burns with non-adherent gauze and wrapping. Deep second-degree burns may benefit from topical silver sulfadiazine. EYE:
Eye injuries require retraction of the eyelids to ensure thorough irrigation of the conjuctival cul-de-sacs. Irrigation should last at least 20-30 minutes. DO NOT use neutralising agents or any other additives. Several litres of saline are required. Cycloplegic drops, (1% cyclopentolate for short-term use or 5% homatropine for longer term use) antibiotic drops, vasoconstrictive agents or artificial tears may be indicated dependent on the severity of the injury. Steroid eye drops should only be administered with the approval of a consulting ophthalmologist).
[Ellenhorn and Barceloux: Medical Toxicology]
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Issue Date: September 2017 SDS No: 722 Version: V.0.0.2
SECTION 5 FIREFIGHTING MEASURES
Extinguishing Media
Water spray or fog Foam
Special hazards arising from the substrate or mixture
Fire Incompatibility None known.
Advice for firefighters
Alert Fire Brigade and tell them location and nature of hazard. Wear full body protective clothing with breathing apparatus. Prevent, by any means available, spillage from entering drains or water course. Use fire fighting procedures suitable for surrounding area. Fire Fighting Do not approach containers suspected to be hot. Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire. Equipment should be thoroughly decontaminated after use. May evolve toxic gases (chlorine) when heated to decomposition. Non combustible. Not considered to be a significant fire risk. Acids may react with metals to produce hydrogen, a highly flammable and explosive gas. Heating may cause expansion or decomposition leading to violent rupture of containers. Fire/Explosion Hazard May emit corrosive, poisonous fumes. May emit acrid smoke.
Decomposition may produce toxic fumes of: hydrogen chloride HAZCHEM 2R
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
See section 8
Environmental precautions
See section 12
Methods and material for containment and cleaning up
Drains for storage or use areas should have retention basins for pH adjustments and dilution of spills before discharge or disposal of material. Check regularly for spills and leaks. Clean up all spills immediately. Minor Spills Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Contain and absorb spill with sand, earth, inert material or vermiculite. Wipe up. Place in a suitable, labelled container for waste disposal. Chemical Class: acidic compounds, inorganic For release onto land: recommended sorbents listed in order of priority.
Major Spills SORBENT TYPE RANK APPLICATION COLLECTION LIMITATIONS
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Issue Date: September 2017 SDS No: 722 Version: V.0.0.2
LAND SPILL – SMALL
foamed glass - pillows 1 throw pitchfork R, P, DGC, RT expanded mineral - particulate 2 shovel shovel R, I, W, P, DGC foamed glass - particulate 2 shovel shovel R, W, P, DGC
LAND SPILL – MEDIUM
expanded mineral -particulate 1 blower skiploader R, I, W, P, DGC foamed glass- particulate 2 blower skiploader R, W, P, DGC foamed glass - particulate 3 throw skiploader R, W, P, DGC
Legend DGC: Not effective where ground cover is dense R; Not reusable I: Not incinerable P: Effectiveness reduced when rainy RT: Not effective where terrain is rugged SS: Not for use within environmentally sensitive sites W: Effectiveness reduced when windy Reference: Sorbents for Liquid Hazardous Substance Cleanup and Control; R.W Melvold et al: Pollution Technology Review No. 150: Noyes Data Corporation 1988
Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear full body protective clothing with breathing apparatus. Prevent, by any means available, spillage from entering drains or water course. Stop leak if safe to do so. Contain spill with sand, earth or vermiculite. Collect recoverable product into labelled containers for recycling. Neutralise/decontaminate residue (see Section 13 for specific agent). Collect solid residues and seal in labelled drums for disposal. Wash area and prevent runoff into drains. After clean up operations, decontaminate and launder all protective clothing and equipment before storing and re-using. If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the SDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
DO NOT allow clothing wet with material to stay in contact with skin Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. WARNING: To avoid violent reaction, ALWAYS add material to water and NEVER water to material. Avoid smoking, naked lights or ignition sources. Avoid contact with incompatible materials. When handling, DO NOT eat, drink or smoke. Safe handling Keep containers securely sealed when not in use. Avoid physical damage to containers. Always wash hands with soap and water after handling. Work clothes should be laundered separately. Launder contaminated clothing before re -use. Use good occupational work practice. Observe manufacturer's storage and handling recommendations contained within this SDS. Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are maintained. Store in original containers. Keep containers securely sealed. Store in a cool, dry, well-ventilated area. Other Information Store away from incompatible materials and foodstuff containers. Protect containers against physical damage and check regularly for leaks. Observe manufacturer's storage and handling recommendations contained within this SDS.
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Issue Date: September 2017 SDS No: 722 Version: V.0.0.2 Conditions for safe storage, including any incompatibilities
DO NOT use aluminium or galvanised containers Check regularly for spills and leaks Lined metal can, lined metal pail/ can. Suitable Container Plastic pail. Polyliner drum. Packing as recommended by manufacturer. Check all containers are clearly labelled and free from leaks. Inorganic acids neutralise chemical bases (for example: amines and inorganic hydroxides) to form salts - neutralisation can generate dangerously large amounts of heat in small spaces. The dissolution of inorganic acids in water or the dilution of their concentrated solutions with additional water may generate significant heat. The addition of water to inorganic acids often generates sufficient heat in the small region of mixing to cause some of the water to boil explosively. The resulting "bumping" can spatter the acid. Inorganic acids react with active metals, including such structural metals as aluminum and iron, to release hydrogen, a flammable gas. Storage Incompatibility Inorganic acids react with cyanide compounds to release gaseous hydrogen cyanide. Inorganic acids generate flammable and/or toxic gases in contact with dithiocarbamates, isocyanates, mercaptans, nitrides, nitriles, sulfides, and strong reducing agents. Additional gas-generating reactions occur with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), and even carbonates. Reacts vigorously with alkalis. Reacts with mild steel, galvanised steel / zinc producing hydrogen gas which may form an explosive mixture with air. Contact with acids, organics, reducing agents (eg. amines), metallic powders and heat sources produces toxic fumes of chlorine. May be decomposed by hot water releasing chlorine fumes.
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Source Ingredient Material Name TWA STEL Peak Notes Australia Exposure hydrochloric acid Hydrogen chloride Not Not Available 7.5 mg/m3 / Not Available Standards Available 5ppm Australia Exposure titanium Fume (thermally generated) 2 mg/m3 Not Available Not Available Not Available Standards (respirable dust) EMERGENCY LIMITS
Ingredient Material Name TEEL-1 TEEL-2 TEEL-3 hydrochloric acid Hydrogen chloride; (Hydrochloric acid) Not Available Not Available Not Available hydrochloric acid Deuterochloric acid; (Deuterium chloride) 1.8 ppm 22 ppm 100 ppm titanium Titanium 30 mg/m3 330 mg/m3 2,000 mg/m3
Ingredient Original IDLH Revised IDLH hydrochloric acid 100 ppm 50 ppm silica Not Available Not Available titanium Not Available Not Available water Not Available Not Available
MATERIAL DATA
Exposure controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well- Appropriate engineering designed engineering controls can be highly effective in protecting workers and will typically be independent of controls worker interactions to provide this high level of protection.
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Issue Date: September 2017 SDS No: 722 Version: V.0.0.2
Personal Protection
Safety glasses with imperforated side shields may be used where continuous eye protection is desirable, as in laboratories; spectacles are not sufficient where complete eye protection is needed such as when handling bulk-quantities, where there is a danger of splashing, or if the material may be under pressure. Eye and Face protection Chemical goggles whenever there is a danger of the material coming in contact with the eyes; goggles must be properly fitted. Full face shield (20 cm, 8 in minimum) may be required for supplementary but never for primary protection of eyes. Alternatively a gas mask may replace splash goggles and face shields.
Skin protection See Hand protection below Elbow length PVC gloves Wear chemical protective gloves, e.g. PVC. Wear safety footwear or safety gumboots, e.g. Rubber Hands/feet protection When handling corrosive liquids, wear trousers or overalls outside of boots, to avoid spills entering boots. Select gloves tested to a relevant standard (e.g. Europe EN 374, US F739, AS/NZS 2161.1 or national equivalent). Body protection See Other protection below Overalls. PVC Apron. Other protection PVC protective suit may be required if exposure severe. Eyewash unit. Ensure there is ready access to a safety shower. Thermal hazards Not Available
Respiratory protection
Type B-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance Colourless to slightly yellow corrosive liquid with a pungent acidic odour; miscible with water.
Physical state Liquid Flash point (°C) Not Applicable Odour Not Available Evaporation rate Not Available Odour threshold Not Available Flammability Not Applicable Relative density (water=1) 1.07 – 1.08 Upper Explosive Limit (%) Not Applicable Colour Colourless - slightly yellow Lower Explosive Limit (%) Not Applicable pH (as supplied) < 1 Vapour pressure (kPa) Not Available Melting point/Freezing point < 0 Solubility in water (g/L) Miscible (°C) Initial boiling point and > 100 Vapour density (Air = 1) Not Available boiling range (°C)
SECTION 10 STABILITY AND REACTIVITY
Reactivity See section 7 Chemical stability Contact with alkaline material liberates heat Possibility of hazardous reactions See section 7 Conditions to avoid See section 7 Incompatible materials See section 7
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Issue Date: September 2017 SDS No: 722 Version: V.0.0.2 Hazardous decomposition See section 5 products
SECTION 11 TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acidic corrosives produce respiratory tract irritation with coughing, choking and mucous membrane damage. Symptoms of exposure may include dizziness, headache, nausea and weakness. Hydrogen chloride (HCl) vapour or fumes present a hazard from a single acute exposure. Exposures of 1300 to 2000 ppm have been lethal to Inhaled humans in a few minutes. Inhalation of aerosols (mists, fumes), generated by the material during the course of normal handling, may produce toxic effects; these may be fatal. Inhalation of the vapour is hazardous and may even be fatal. Ingestion of acidic corrosives may produce circumoral burns with a distinct discolouration of the mucous Ingestion membranes of the mouth, throat and oesophagus. Immediate pain and difficulties in swallowing and speaking may also be evident. Skin contact with acidic corrosives may result in pain and burns; these may be deep with distinct edges and may heal slowly with the formation of scar tissue. Skin contact with the material may damage the health of the individual; systemic effects may result following Skin Contact absorption. Open cuts, abraded or irritated skin should not be exposed to this material Entry into the blood-stream through, for example, cuts, abrasions, puncture wounds or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected. When applied to the eye(s) of animals, the material produces severe ocular lesions which are present twenty -four hours or more after instillation. Direct eye contact with acid corrosives may produce pain, lachrymation, photophobia and burns. Mild burns of the Eye epithelia generally recover rapidly and completely. Severe burns produce long-lasting and possible irreversible damage. The appearance of the burn may not be apparent for several weeks after the initial contact. The cornea may ultimately become deeply vascularised and opaque resulting in blindness. Repeated or prolonged exposure to acids may result in the erosion of teeth, inflammatory and ulcerative changes in the mouth and necrosis (rarely) of the jaw. Bronchial irritation, with cough, and frequent attacks of bronchial pneumonia may ensue. Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effects involving organs or biochemical systems. Chronic Chronic minor exposure to hydrogen chloride (HCl) vapour or fume may cause discolouration or erosion of the teeth, bleeding of the nose and gums; and ulceration of the nasal mucous membranes. Repeated exposures of animals to concentrations of about 34 ppm HCl produced no immediate toxic effects. Workers exposed to hydrochloric acid suffered from gastritis and a number of cases of chronic bronchitis have also been reported. Repeated or prolonged exposure to dilute solutions of HCl may cause dermatitis.
Product Name TOXICITY IRRITATION
TelChem Hydrochloric Not Available Not Available Acid 15 %
hydrochloric acid Inhalation (rat) LC50: 3124 ppm/1hr[2] Eye (rabbit): 5mg/30s - mild [2] Oral (rat) LD50: 900 mg/kg titanium Oral (rat) LD50: >2000 mg/kg[1] Not Available Water Oral (rat) LD50: >90000 mg/kg[2] Not Available 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances
Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can occur
following exposure to high levels of highly irritating compound. For acid mists, aerosols, vapours; Data from assays for genotoxic activity in vitro suggest that eukaryotic cells are susceptible to genetic damage HYDROCHLORIC ACID when the pH falls to about 6.5. Cells from the respiratory tract have not been examined in this respect. The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis. The substance is classified by IARC as Group 3: NOT classifiable as to its carcinogenicity to humans. Evidence of carcinogenicity may be inadequate or limited in animal testing. HYDROCHLORIC ACID & No significant acute toxicological data identified in literature search. TITANIUM & WATER
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Issue Date: September 2017 SDS No: 722 Version: V.0.0.2 Acute Toxicity Carcinogenicity Skin Irritation/Corrosion Reproductivity Serious Eye STOT – single exposure Damage/Irritation Respiratory or Skin STOT – repeated exposure sensitisation Mutagenicity Aspiration Hazard Legend: – Data available but does not fill the criteria for classification – Data required to make classification available – Data Not Available to make classification
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
Ingredient Endpoint Test Duration (hr) Species Value Source hydrochloric acid LC50 96 Fish 70.057mg/L 3 hydrochloric acid EC50 96 Algae or other aquatic plants 344.947mg/L 3 hydrochloric acid EC50 9.33 Fish 0.014000mg/L 4 hydrochloric acid NOEC 0.08 Fish 10mg/L 4 titanium EC50 4.5 Algae or other aquatic plants >100mg/L 2 titanium NOEC 48 Crustacean 1mg/L 2 Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Legend: Suite V3.12 - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data
Ecotoxicity
Prevent, by any means available, spillage from entering drains or water courses. DO NOT discharge into sewer or waterways.
Persistence and degradability
Ingredient Persistence: Water/Soil Persistence: Air hydrochloric acid LOW LOW water LOW LOW
Bio accumulative potential
Ingredient Bioaccumulation hydrochloric acid LOW (Log KOW = 0.5392) water LOW (Log KOW = -1.38)
Mobility in Soil
Ingredient Mobility hydrochloric acid LOW (KOC = 14.3) water LOW (KOC = 14.3)
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Issue Date: September 2017 SDS No: 722 Version: V.0.0.2
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods Containers may still present a chemical hazard/ danger when empty. Return to supplier for reuse/ recycling if possible. Otherwise: If container can’t be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill. Product/Packaging disposal Where possible retain label warnings and SDS and observe all notices pertaining to the product. Recycle wherever possible. Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified. Treat and neutralise at an approved treatment plant. Treatment should involve: Neutralisation with soda -ash or soda-lime followed by: burial in a land-fill specifically licensed to accept chemical and / or pharmaceutical wastes or incineration in a licensed apparatus (after admixture with suitable combustible material). Decontaminate empty containers with 5% aqueous sodium hydroxide or soda ash, followed by water. Observe all label safeguards until containers are cleaned and destroyed.
SECTION 14 TRANSPORT INFORMATION
Labels Required
Marine Pollutant NO HAZCHEM 2R
Land transport (ADG)
UN Number 1789 UN proper shipping name HYDROCHLORIC ACID Class 8 Transport Hazard class(es) Sub Risk Not Applicable Packing group II Environmental Hazard Not Applicable Special provisions Not Applicable Special precautions for user Limited quantity 1 L
Air transport (ICAO-IATA / DGR)
UN Number 1789 UN proper shipping name HYDROCHLORIC ACID ICAO/IATA Class 8 Transport Hazard class(es) ICAO/IATA Sub Risk Not Applicable Packing group II Environmental Hazard Not Applicable
Special provisions Not Applicable
Cargo Only Packing Instructions Not Available
Special precautions for user Cargo Only Maximum Qty/Pack Not Available
Passenger and Cargo Packing Instructions 851
Passenger and Cargo Maximum Qty/Pack 1 L
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Issue Date: September 2017 SDS No: 722 Version: V.0.0.2 Passenger and Cargo Limited Quantity Packing Instructions Y840
Passenger and Cargo Limited Maximum Qty / Pack 0.5 L
Sea transport (IMDG-Code / GGVSee)
UN Number 1789
UN proper shipping name HYDROCHLORIC ACID
IMDG Class 8 Transport Hazard class(es) IMDG Sub Risk Not Applicable Packing group II Environmental Hazard Not Applicable EMS, Fire F-A Special precautions for user EMS, Spillage S-B
Transport in bulk according to Annex II of MARPOL and the IBC code
Source Product Name Pollution Category Ship Type IMO MARPOL (Annex II) – List of Noxious Liquid Substances Carried in Bulk Hydrochloric acid Z 3
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture
HYDROCHLORIC ACID (7647-01-0) IS FOUND ON THE FOLLOWING REGULATORY LISTS
Australia Exposure Standards Australia Inventory of Chemical Substances (AICS) Australia Hazardous Substances Information System - Consolidated Lists
TITANIUM (7440-32-6) IS FOUND ON THE FOLLOWING REGULATORY LISTS
Australia Exposure Standards International Air Transport Association (IATA) Dangerous Goods Regulations Prohibited List Passenger and Cargo Aircraft Australia Inventory of Chemical Substances (AICS)
WATER (7732-18-5) IS FOUND ON THE FOLLOWING REGULATORY LISTS
Australia Inventory of Chemical Substances (AICS)
National Inventory Status
Australia - AICS Y Canada - DSL Y Canada - NDSL N (titanium; hydrochloric acid; water) China - IECSC Y Europe - EINEC / ELINCS / NLP Y Japan - ENCS N (titanium; water) Korea - KECI Y New Zealand - NZIoC Y Philippines - PICCS Y USA - TSCA Y Y = All ingredients are on the inventory Legend: N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)
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Issue Date: September 2017 SDS No: 722 Version: V.0.0.2 SECTION 16 OTHER INFORMATION
The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether th e reported Hazards are risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.
Definitions and abbreviations
Name CAS No Permissible Concentration-Short Term Exposure Limit PC－TWA Permissible Concentration-Time Weighted Average PC－STEL IARC International Agency for Research on Cancer ACGIH American Conference of Governmental Industrial Hygienists STEL Short Term Exposure Limit TEEL Temporary Emergency Exposure Limit IDLH Immediately Dangerous to Life or Health Concentrations OSF Odour Safety Factor NOAEL No Observed Adverse Effect Level LOAEL Lowest Observed Adverse Effect Level TLV Threshold Limit Value LOD Limit Of Detection OTV Odour Threshold Value BCF BioConcentration Factors BEI Biological Exposure Index
END OF SDS
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1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name IDCIDE-20 Synonym(s) IDCIDE 20
1.2 Uses and uses advised against Use(s) BIOCIDE • DRILLING FLUID ADDITIVE • WATER TREATMENT
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA GHS classification Skin Sensitization: Category 1 Skin Corrosion/Irritation: Category 2 Serious Eye Damage / Eye Irritation: Category 2A
2.2 Label elements Signal word WARNING
Pictograms
Hazard statement(s) H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. Prevention statement(s) P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection. Response statement(s) P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P321 Specific treatment is advised - see first aid instructions. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P362 Take off contaminated clothing and wash before re-use.
Page 1 of 7 SDS Date: 28 Jul 2014 PRODUCT NAME IDCIDE-20
Storage statement(s) None allocated.
Disposal statement(s) P501 Dispose of contents/container in accordance with relevant regulations.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient Identification Classification Content GHS Risk TETRAKIS(HYDROXYMETHYL)PHOSPHONI CAS: 55566-30-8 Not Available Not Available 18 to 25% UM SULPHATE EC: 259-709-0 WATER CAS: 7732-18-5 Not Available Not Available Remainder EC: 231-791-2
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. First aid facilities Eye wash facilities should be available.
4.2 Most important symptoms and effects, both acute and delayed See Section 11 for more detailed information on health effects and symptoms.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture Non flammable. May evolve toxic gases if strongly heated. May evolve carbon oxides, sulphur oxides and phosphates when heated to decomposition.
5.3 Advice for firefighters Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in Section 8. Clear area of all unprotected personnel. Ventilate area where possible.
Page 2 of 7 SDS Date: 28 Jul 2014 PRODUCT NAME IDCIDE-20
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then cover/absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place in suitable containers for disposal.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards No exposure standards have been entered for this product.
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended.
PPE Eye / Face Wear a faceshield and splash-proof goggles. Hands Wear PVC or rubber gloves. Body Not required under normal conditions of use. Respiratory Not required under normal conditions of use.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance COLOURLESS TO PALE YELLOW LIQUID Odour SLIGHT ODOUR Flammability NON FLAMMABLE Flash point NOT RELEVANT Boiling point > 100°C Melting point < 0°C Evaporation rate AS FOR WATER pH 3.0 to 3.5 Vapour density NOT AVAILABLE Specific gravity 1.08 Solubility (water) SOLUBLE
Page 3 of 7 SDS Date: 28 Jul 2014 PRODUCT NAME IDCIDE-20
9.1 Information on basic physical and chemical properties Vapour pressure 18 mm Hg @ 20°C Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles > 60 % (Water)
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (eg. hypochlorites) and acids (eg. nitric acid).
10.6 Hazardous decomposition products May evolve carbon oxides, sulphur oxides and phosphates when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Health hazard May be harmful - irritant. This product has the potential to cause adverse health effects with over exposure. summary Upon dilution, the potential for adverse health effects may be reduced. Eye Irritant. Contact may result in irritation, lacrimation, pain and redness. Inhalation Low to moderate irritant. Over exposure to vapours may result in irritation of the nose and throat, with coughing. High level exposure may result in dizziness, nausea and headache. Due to the low vapour pressure, an inhalation hazard is not anticipated with normal use. Skin Irritant. Contact may result in irritation. May cause sensitisation by skin contact. Ingestion May be harmful. Ingestion may result in gastrointestinal irritation, nausea, vomiting, abdominal pain and diarrhoea. Toxicity data TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE (55566-30-8) LD50 (ingestion) 248 mg/kg (rat) TDLo (ingestion) 650 mg/kg/13 weeks - intermittent (rat)
Page 4 of 7 SDS Date: 28 Jul 2014 PRODUCT NAME IDCIDE-20
12. ECOLOGICAL INFORMATION
12.1 Toxicity 75% TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE (55566-30-8): LC50 (Rainbow Trout) = 119 mg/L/96 hr LC50(Bluegill Sunfish) = 93 mg/L/ 96 hr EC50 (Daphnia Magna) = 19 mg/L/48 hr LC50 (Brown Shrimp) = 340 mg/L/96 hr LC50 (Mysid Shrimp ) = 9.5 mg/L/96 hr LC50 (Sheepshead Minnow) = 94 mg/L/96 hr LC50 (Jevenile Plaice) = 86 mg/L/96 hr
Waste Water management EC50 (Activated Sludge) = 24 mg/L/3 hr
12.2 Persistence and degradability This product is readily biodegradable.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal For small amounts, absorb with sand, vermiculite or similar and dispose of to an approved landfill site. For larger amounts, contact the manufacturer for additional information. Prevent contamination of drains or waterways as aquatic life may be threatened and environmental damage may result. Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)].
Page 5 of 7 SDS Date: 28 Jul 2014 PRODUCT NAME IDCIDE-20
Hazard codes Xi Irritant Risk phrases R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact.
Safety phrases S23 Do not breathe gas/fumes/vapour/spray (where applicable). S24/25 Avoid contact with skin and eyes. S36 Wear suitable protective clothing. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information EXPOSURE CONTROL: If utilised in a closed system the potential for over exposure is reduced. If not used in a closed system, local exhaust ventilation is recommended to control exposure. Provide eye wash and safety shower in close proximity to points of potential exposure. Where the potential for an inhalation risk exists, an approved respirator may be required. Do not eat, store, consume food, tobacco or drink in areas where product is used.
RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit PEL Permissible Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million REACH Regulation on Registration, Evaluation, Authorisation and Restriction of Chemicals STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Page 6 of 7 SDS Date: 28 Jul 2014 PRODUCT NAME IDCIDE-20
Revision history Revision Description 2.0 Converted to GHS. 1.0 Initial SDS creation
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 2 SDS date: 28 July 2014 [ End of SDS ]
Page 7 of 7 SDS Date: 28 Jul 2014 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name POTASSIUM CHLORIDE Synonym(s) KCL • MURIATE OF POTASH • POTASH • SYLVITE
1.2 Uses and uses advised against Use(s) DRILLING FLUID ADDITIVE • FERTILISER • INHIBITOR
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content POTASSIUM CHLORIDE 7447-40-7 231-211-8 >97%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. First aid facilities No information provided.
SDS Date: 16 Apr 2015 Page 1 of 6 Version No: 2.1 PRODUCT NAME POTASSIUM CHLORIDE
4.2 Most important symptoms and effects, both acute and delayed Adverse effects not expected from this product under normal conditions of use.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture Non flammable. May evolve toxic gases (potassium oxides, chlorides) when heated to decomposition.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards No exposure standards have been entered for this product.
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended.
SDS Date: 16 Apr 2015 Page 2 of 6 Version No: 2.1 PRODUCT NAME POTASSIUM CHLORIDE
PPE Eye / Face At high dust levels, wear dust-proof goggles. Hands With prolonged use, wear PVC or rubber or cotton gloves. Body With prolonged use, wear coveralls. Respiratory At high dust levels, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance WHITE SOLID Odour ODOURLESS Flammability NON FLAMMABLE Flash point NOT RELEVANT Boiling point 1413°C Melting point 773°C Evaporation rate NOT AVAILABLE pH NOT AVAILABLE Vapour density NOT AVAILABLE Specific gravity 2.0 Solubility (water) 340 g/L @ 20°C Vapour pressure NOT AVAILABLE Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization will not occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible (potentially explosive) with oxidising agents (e.g. hypochlorites).
10.6 Hazardous decomposition products May evolve toxic gases (potassium oxides, chlorides) when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity May be harmful if swallowed. Oral Toxicity: An oral LD50 in rats of 2600 mg/kg was reported for potassium chloride. Additional toxicity data for potassium chloride: LD50 (Intraperitoneal): 620 mg/kg (mouse) LD50 (Intravenous): 117 mg/kg (mouse) LDLo (Ingestion): 20 mg/kg (man)
SDS Date: 16 Apr 2015 Page 3 of 6 Version No: 2.1 PRODUCT NAME POTASSIUM CHLORIDE
LDLo (Intraperitoneal): 900 mg/kg (guinea pig) LDLo (Intravenous): 77 mg/kg (guinea pig) LDLo (Subcutaneous): 2120 mg/kg (frog) TDLo (Ingestion): 60 mg/kg/days (woman) Skin Not classified as a skin irritant. Contact may result in mild irritation and rash. Eye Not classified as an eye irritant. Contact may cause mild irritation and lacrimation. Sensitization This product is not known to be a skin or respiratory sensitiser. Mutagenicity No evidence of mutagenic effects. Carcinogenicity No evidence of carcinogenic effects. Reproductive No evidence of reproductive effects. STOT – single Acute potassium poisoning via ingestion is rare as a large single dose usually induces vomiting, and exposure potassium is rapidly excreted by the body, however this product does have the potential to cause cardiovascular disorders. STOT – repeated Not classified as causing organ effects from repeated exposure. exposure Aspiration Not relevant.
12. ECOLOGICAL INFORMATION
12.1 Toxicity In short-term acute toxicity tests with fish, daphnia and algae the following results were found (lowest test result values): Ictalurus punctulus 48h-LC50 = 720 mg/l; Daphnia magna: 48h-LC50 = 177 mg/l; Nitzschia linearis: 120 h-EC50 = 1337 mg/l. A chronic reproductive test with the invertebrate Daphnia magna gave a LOEC of 101 mg/l. All the studies compiled on the acute and chronic aquatic toxicity were > 100 mg/L. Thus it is concluded that KCl is not hazardous to freshwater organisms. Taking into considerations the background concentrations of KCl in seawater (380 mg/l K+ and 19,000 mg/l Cl-), it is concluded that there is no reason for further investigations of KCl on marine species. The low concern for the environment is supported by the absence of a bioaccumulation potential for the substance.
12.2 Persistence and degradability Biodegradability does not pertain to inorganic substances.
12.3 Bioaccumulative potential Does not bioaccumulate.
12.4 Mobility in soil No impact if small amount is released to the soil.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Collect and place in sealable containers and dispose of to an approved landfill site. Contact the manufacturer/supplier for additional information (if required). Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided
SDS Date: 16 Apr 2015 Page 4 of 6 Version No: 2.1 PRODUCT NAME POTASSIUM CHLORIDE
14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
SDS Date: 16 Apr 2015 Page 5 of 6 Version No: 2.1 PRODUCT NAME POTASSIUM CHLORIDE
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au. [ End of SDS ]
SDS Date: 16 Apr 2015 Page 6 of 6 Version No: 2.1 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name NEWPAC LV/RD Synonym(s) NEWPAC RD ● POLICELL RG ● RHEOPAC LV ● RHEOPAC R ● RHEOPAC R/LV/UL/RD/LVD ● RHEOPAC UL
1.2 Uses and uses advised against Use(s) DRILLING FLUID ADDITIVE
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content SODIUM CARBOXYMETHYL CELLULOSE 9004-32-4 618-378-6 >88% SODIUM CHLORIDE 7647-14-5 231-598-3 <1.8% WATER 7732-18-5 231-791-2 <10% SODIUM GLYCOLATE 2836-32-0 212-730-9 <0.7%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. Ingestion is considered unlikely due to product form.
SDS Date: 07 Dec 2016 Page 1 of 7 Version No: 1.6 PRODUCT NAME NEWPAC LV/RD
First aid facilities None allocated.
4.2 Most important symptoms and effects, both acute and delayed Adverse effects not expected from this product under normal conditions of use.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains and waterways.
5.2 Special hazards arising from the substance or mixture Combustible. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Finely divided dust may form explosive mixtures with air.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contact emergency services where appropriate.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately labelled and tightly closed when not in use.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards No exposure standards have been entered for this product.
Biological limits No biological limit values have been entered for this product.
SDS Date: 07 Dec 2016 Page 2 of 7 Version No: 1.6 PRODUCT NAME NEWPAC LV/RD
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Maintain dust levels below the recommended exposure standard.
PPE Eye / Face Wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance WHITE OR YELLOWISH POWDER/GRANULES Odour SLIGHT ODOUR Flammability COMBUSTIBLE Flash point NOT AVAILABLE Boiling point NOT AVAILABLE Melting point NOT AVAILABLE Evaporation rate NOT AVAILABLE pH 6.0 to 8.5 (1 % solution) Vapour density NOT AVAILABLE Specific gravity NOT AVAILABLE Solubility (water) SOLUBLE Vapour pressure NOT AVAILABLE Upper explosion limit NOT AVAILABLE Lower explosion limit NOT AVAILABLE Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
10.6 Hazardous decomposition products May evolve carbon oxides and hydrocarbons when heated to decomposition.
SDS Date: 07 Dec 2016 Page 3 of 7 Version No: 1.6 PRODUCT NAME NEWPAC LV/RD
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity This product is expected to be of low acute toxicity. Under normal conditions of use, adverse health effects are not anticipated. Toxicity Data available on the ingredients: SODIUM CARBOXYMETHYL CELLULOSE (9004-32-4) LD50 (Ingestion): 16000 mg/kg (guinea pig) LD50 (Skin): > 2000 mg/kg (rabbit) TDLo (Ingestion): 140 mg/kg (rat) SODIUM CHLORIDE (7647-14-5) LC50 (Inhalation): > 42000 mg/m3/1 hour (rat) LD50 (Ingestion): 3000 mg/kg (rat) LD50 (Intraperitoneal): 2602 mg/kg (mouse) LD50 (Intravenous): 645 mg/kg (mouse) LD50 (Skin): > 10000 mg/kg (rabbit) LD50 (Subcutaneous): 3000 mg/kg (mouse) LDLo (Ingestion): 8000 mg/kg (rabbit) LDLo (Intravenous): 300 mg/kg (guinea pig) LDLo (Subcutaneous): 2160 mg/kg (guinea pig) TDLo (Ingestion): 12357 mg/kg (human) SODIUM GLYCOLATE (2836-32-0) LD50 (Ingestion): 6700 mg/kg (mouse) LDLo (Ingestion): 500 mg/kg (cat) Information available for the ingredient(s):
Oral Toxicity (LD50) Dermal Toxicity (LD50) Inhalation Toxicity Ingredient (LC50) SODIUM CARBOXYMETHYL CELLULOSE 16000 mg/kg (guinea > 2000 mg/kg (rabbit) -- SODIUM CHLORIDE 3000 mg/kg (rat) > 10000 mg/kg (rabbit) > 42000 mg/m³/1 hour SODIUM GLYCOLATE 6700 mg/kg (mouse) -- -- Additional ingredient toxicity value(s): SODIUM CARBOXYMETHYL CELLULOSE (9004-32-4) TDLo (oral) 140 mg/kg (rat) SODIUM CHLORIDE (7647-14-5) LD50 (intraperitoneal) 2602 mg/kg (mouse) LD50 (intravenous) 645 mg/kg (mouse) LD50 (subcutaneous) 3000 mg/kg (mouse) LDLo (intravenous) 300 mg/kg (guinea pig) LDLo (oral) 8000 mg/kg (rabbit) LDLo (subcutaneous) 2160 mg/kg (guinea pig) TDLo (oral) 12357 mg/kg (human) SODIUM GLYCOLATE (2836-32-0) LDLo (oral) 500 mg/kg (cat) Skin Not classified as a skin irritant. Contact may result in mild irritation. Eye Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness. Sensitisation Not classified as causing skin or respiratory sensitisation. Mutagenicity No evidence of mutagenic effects. Carcinogenicity No evidence of carcinogenic effects. Reproductive No relevant or reliable studies were identified. STOT – single Not classified as causing organ damage from single exposure. exposure STOT - repeated Not classified as causing organ damage from repeated exposure. exposure Aspiration This product does not present an aspiration hazard.
12. ECOLOGICAL INFORMATION
SDS Date: 07 Dec 2016 Page 4 of 7 Version No: 1.6 PRODUCT NAME NEWPAC LV/RD
12.1 Toxicity LC50 (Fresh Water Trout) > 21,000 ppm/96hrs. LC50 (Salt Water Stickel Back) > 56,000 ppm/96hrs.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential Not expected to bioaccumulate.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Council landfill. Contact the manufacturer/supplier for additional information (if required). Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
14.1 UN Number None allocated. None allocated. None allocated. 14.2 Proper None allocated. None allocated. None allocated. Shipping Name
14.3 Transport None allocated. None allocated. None allocated. hazard class 14.4 Packing Group None allocated. None allocated. None allocated. 14.5 Environmental hazards No information provided. 14.6 Special precautions for user Hazchem code None allocated.
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
SDS Date: 07 Dec 2016 Page 5 of 7 Version No: 1.6 PRODUCT NAME NEWPAC LV/RD
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
SDS Date: 07 Dec 2016 Page 6 of 7 Version No: 1.6 PRODUCT NAME NEWPAC LV/RD
[ End of SDS ]
SDS Date: 07 Dec 2016 Page 7 of 7 Version No: 1.6 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name QUICKSEAL (F,M,C) Synonym(s) QUICKSEAL
1.2 Uses and uses advised against Use(s) DRILLING FLUID ADDITIVE
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content CELLULOSE 9004-34-6 232-674-9 100%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. First aid facilities No information provided.
4.2 Most important symptoms and effects, both acute and delayed Adverse effects not expected from this product under normal conditions of use.
Page 1 of 6 SDS Date: 13 Feb 2015 PRODUCT NAME QUICKSEAL (F,M,C)
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains and waterways.
5.2 Special hazards arising from the substance or mixture Combustible. May evolve carbon oxides and hydrocarbons when heated to decomposition. Dust may form explosive mixtures with air.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Difficult to extinguish once burning.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Moisten with water to prevent a dust hazard and place in sealable containers for disposal.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensure containers are labelled, protected from light, freezing or physical damage and tightly sealed when not in use. Keep out of reach of children.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Cellulose (paper fibre) (a) SWA (AUS) -- 10 -- --
Biological limits No Biological Limit Value allocated.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas.
Page 2 of 6 SDS Date: 13 Feb 2015 PRODUCT NAME QUICKSEAL (F,M,C)
PPE Eye / Face Wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance YELLOW TO BROWN SOLID Odour SLIGHT ODOUR Flammability COMBUSTIBLE Flash point NOT AVAILABLE Boiling point NOT RELEVANT Melting point NOT AVAILABLE Evaporation rate NOT AVAILABLE pH 7 to 8 Vapour density NOT AVAILABLE Specific gravity 0.9 - 1.2 Solubility (water) INSOLUBLE Vapour pressure NOT AVAILABLE Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with calcium oxides, bleaching powder, perchlorates, perchloric acid, sodium chlorate, fluorine, nitric acid, sodium nitrate and sodium nitrite.
10.6 Hazardous decomposition products May evolve carbon oxides and hydrocarbons when heated to decomposition.
Page 3 of 6 SDS Date: 13 Feb 2015 PRODUCT NAME QUICKSEAL (F,M,C)
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated. Acute Oral Toxicity: LD50 (oral) > 5000 mg/kg (rats). Acute Dermal Toxicity: LD50 (dermal) > 2000 mg/kg (rats). Acute Inhalation Toxicity: LC50 (Inhalation) = 5800 mg/m3/4hrs (rat). Skin Not classified as a skin irritant. Contact may result in mechanical irritation, redness and rash. Eye Not classified as an eye irritant. However, this product may cause mechanical eye irritation with redness and lacrimation. Sensitization This product is not known to be a skin or respiratory sensitiser. Mutagenicity No evidence of mutagenic effects. Carcinogenicity No evidence of carcinogenic effects. Reproductive No evidence of reproductive effects. STOT – single Not classified as causing organ effects from single exposure. exposure STOT – repeated Not classified as causing organ effects from repeated exposure. exposure Aspiration This product does not present an aspiration hazard.
12. ECOLOGICAL INFORMATION
12.1 Toxicity Low toxicity to aquatic organisms.
12.2 Persistence and degradability This product is readily biodegradable.
12.3 Bioaccumulative potential This product is not expected to bioaccumulate.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Reuse where possible. No special precautions are normally required when handling this product. Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user
Page 4 of 6 SDS Date: 13 Feb 2015 PRODUCT NAME QUICKSEAL (F,M,C)
Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Page 5 of 6 SDS Date: 13 Feb 2015 PRODUCT NAME QUICKSEAL (F,M,C)
Revision history Revision Description 2.3 Standard SDS Review. 2.2 Standard SDS Review. 2.1 Provided Ingredient CAS No. 2.0 Converted to GHS. 1.0 Initial SDS creation
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 2.3 SDS date: 13 February 2015 [ End of SDS ]
Page 6 of 6 SDS Date: 13 Feb 2015 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name RHEOPLUG ULTRA Synonym(s) SUPER ABSORBENT POLYMER
1.2 Uses and uses advised against Use(s) ABSORBENT • LOSS CIRCULATION MATERIAL
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content POLYACRYLIC POLYMER - - >95%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. First aid facilities No information provided.
Page 1 of 6 SDS Date: 18 Nov 2014 PRODUCT NAME RHEOPLUG ULTRA
4.2 Most important symptoms and effects, both acute and delayed Adverse effects not expected from this product under normal conditions of use.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture Non flammable. May evolve toxic gases if strongly heated. May evolve carbon oxides and sodium oxides when heated to decomposition.
5.3 Advice for firefighters Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contact emergency services where appropriate.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately labelled and tightly closed when not in use.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards No exposure standards have been entered for this product.
Biological limits No biological limit values have been entered for this product.
Page 2 of 6 SDS Date: 18 Nov 2014 PRODUCT NAME RHEOPLUG ULTRA
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended.
PPE Eye / Face Wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory At high dust levels, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance WHITE POWDER Odour FAINT CHARACTERISTIC ODOUR Flammability NON FLAMMABLE Flash point NOT RELEVANT Boiling point NOT AVAILABLE Melting point NOT AVAILABLE Evaporation rate NOT AVAILABLE pH NOT AVAILABLE Vapour density NOT AVAILABLE Specific gravity 0.8 Solubility (water) INSOLUBLE Vapour pressure NOT AVAILABLE Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
10.6 Hazardous decomposition products May evolve carbon oxides and sodium oxides when heated to decomposition.
Page 3 of 6 SDS Date: 18 Nov 2014 PRODUCT NAME RHEOPLUG ULTRA
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated. Acute Oral Toxicity: LD50 (rat) is > 40 g/kg. Skin Not classified as a skin irritant. Contact may result in mild irritation. Eye Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness. Sensitization This product is not known to be a skin or respiratory sensitiser. Mutagenicity No evidence of mutagenic effects. Carcinogenicity No evidence of carcinogenic effects. Reproductive No evidence of reproductive effects. STOT – single Not classified as causing organ effects from single exposure. Sulphuric acid vapours may be generated exposure when product is overheated, oxidised or damaged. STOT – repeated Not classified as causing organ effects from repeated exposure. exposure Aspiration This product does not present an aspiration hazard.
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Council landfill. Contact the manufacturer/supplier for additional information (if required). Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
Page 4 of 6 SDS Date: 18 Nov 2014 PRODUCT NAME RHEOPLUG ULTRA
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Revision history Revision Description 2.0 Converted to GHS. 1.0 Initial SDS creation
Page 5 of 6 SDS Date: 18 Nov 2014 PRODUCT NAME RHEOPLUG ULTRA
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 2 SDS date: 18 November 2014 [ End of SDS ]
Page 6 of 6 SDS Date: 18 Nov 2014 SAFETY DATA SHEET RX-7492 Page: 1 Revision date: 02/11/2015 Revision No: 12
Section 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name: RX-7492
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of substance / mixture: Wax Dissolver PC35: Washing and cleaning products (including solvent based products).
1.3. Details of the supplier of the safety data sheet
Company name: Roemex Limited Badentoy Crescent Badentoy Park Portlethen Aberdeen AB12 4YD United Kingdom Tel: 01224 783444 Fax: 01224 783663 Email: [email protected]
1.4. Emergency telephone number
Emergency tel: +44(0)1224 783444 - 24 hour
Section 2: Hazards identification
2.1. Classification of the substance or mixture
Classification under CLP: Aquatic Acute 1: H400; Aquatic Chronic 1: H410; Asp. Tox. 1: H304; Flam. Liq. 3: H226; Skin Irrit. 2: H315; Skin Sens. 1: H317 Most important adverse effects: Flammable liquid and vapour. May be fatal if swallowed and enters airways. Causes skin irritation. May cause an allergic skin reaction. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.
2.2. Label elements
Label elements: Hazard statements: H226: Flammable liquid and vapour. H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H400: Very toxic to aquatic life. H410: Very toxic to aquatic life with long lasting effects.
[cont...] SAFETY DATA SHEET RX-7492 Page: 2 Hazard pictograms: GHS02: Flame GHS07: Exclamation mark GHS08: Health hazard GHS09: Environmental
Signal words: Danger Precautionary statements: P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P241: Use explosion-proof electrical/ventilating/lighting/.. equipment. P280: Wear protective gloves/protective clothing/eye protection/face protection. P301+310: IF SWALLOWED: Immediately call a POISON CENTER/doctor. P302+352: IF ON SKIN: Wash with plenty of water/soap. P303+361+353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
2.3. Other hazards
Other hazards: In use, may form flammable / explosive vapour-air mixture. PBT: This product is not identified as a PBT/vPvB substance.
Section 3: Composition/information on ingredients
3.2. Mixtures
Hazardous ingredients:
ORANGE TERPENES - REACH registered number(s): 01-2119493353-35-0000
EINECS CAS PBT / WEL CLP Classification Percent 232-433-8 8028-48-6 - Skin Irrit. 2: H315; Aquatic Chronic 1: 70-90% H410; Flam. Liq. 3: H226; Asp. Tox. 1: H304
TERPENE HYDROCARBONS, BY PRODUCT - REACH registered number(s): 01-2119980606-28-0000
273-309-3 68956-56-9 - Flam. Liq. 3: H226; Skin Irrit. 2: H315; 10-30% Skin Sens. 1: H317; Asp. Tox. 1: H304; Aquatic Acute 1: H400; Aquatic Chronic 1: H410
Section 4: First aid measures
4.1. Description of first aid measures
Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Wash immediately with plenty of soap and water. Eye contact: Bathe the eye with running water for 15 minutes. Consult a doctor. Ingestion: Wash out mouth with water. Consult a doctor. [cont...] SAFETY DATA SHEET RX-7492 Page: 3 Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Consult a doctor.
4.2. Most important symptoms and effects, both acute and delayed
Skin contact: There may be irritation and redness at the site of contact. Eye contact: There may be irritation and redness. The eyes may water profusely. Ingestion: There may be soreness and redness of the mouth and throat. Inhalation of fumes from the stomach may cause symptoms similar to direct inhalation. Nausea and stomach pain may occur. The breathing may become shallow and rapid. Inhalation: There may be irritation of the throat with a feeling of tightness in the chest. Exposure may cause coughing or wheezing. Delayed / immediate effects: Immediate effects can be expected after short-term exposure.
4.3. Indication of any immediate medical attention and special treatment needed
Immediate / special treatment: Eye bathing equipment should be available on the premises.
Section 5: Fire-fighting measures
5.1. Extinguishing media
Extinguishing media: Alcohol resistant foam. Water spray. Carbon dioxide. Dry chemical powder. Use water spray to cool containers.
5.2. Special hazards arising from the substance or mixture
Exposure hazards: Flammable. In combustion emits toxic fumes. Forms explosive air-vapour mixture.
5.3. Advice for fire-fighters
Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.
Section 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions: Refer to section 8 of SDS for personal protection details. If outside do not approach from downwind. If outside keep bystanders upwind and away from danger point. Mark out the contaminated area with signs and prevent access to unauthorised personnel. Turn leaking containers leak-side up to prevent the escape of liquid. Eliminate all sources of ignition.
6.2. Environmental precautions
Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.
6.3. Methods and material for containment and cleaning up
Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method. Do not use equipment in clean-up procedure which may produce sparks.
[cont...] SAFETY DATA SHEET RX-7492 Page: 4
6.4. Reference to other sections
Reference to other sections: Refer to section 8 of SDS.
Section 7: Handling and storage
7.1. Precautions for safe handling
Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Avoid the formation or spread of mists in the air. Smoking is forbidden. Use non-sparking tools.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions: Store in a cool, well ventilated area. Keep container tightly closed. Keep away from sources of ignition. Prevent the build up of electrostatic charge in the immediate area. Ensure lighting and electrical equipment are not a source of ignition. Suitable packaging: Must only be kept in original packaging.
7.3. Specific end use(s)
Specific end use(s): No data available.
Section 8: Exposure controls/personal protection
8.1. Control parameters
Workplace exposure limits: No data available.
DNEL/PNEC Values
DNEL / PNEC No data available.
8.2. Exposure controls
Engineering measures: Ensure there is sufficient ventilation of the area. Ensure lighting and electrical equipment are not a source of ignition. Respiratory protection: Self-contained breathing apparatus must be available in case of emergency. Hand protection: Nitrile gloves. Minimum protection: EN420 standard- 0.26 mm Eye protection: Safety glasses. Ensure eye bath is to hand. Skin protection: Protective clothing. Environmental: Prevent from entering in public sewers or the immediate environment.
Section 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
State: Liquid Colour: Colourless to yellow. Odour: Citrus. Evaporation rate: Slow Oxidising: Non-oxidising (by EC criteria) Solubility in water: Insoluble
[cont...] SAFETY DATA SHEET RX-7492 Page: 5 Also soluble in: Most organic solvents. Viscosity: <10cP Viscosity test method: Dynamic viscosity Boiling point/range°C: 176 Melting point/range°C: <0 Flammability limits %: lower: 0.6 upper: 6.1 Flash point°C: 48 Part.coeff. n-octanol/water: >3 Autoflammability°C: 236 Vapour pressure: ~1.4 mmHg Relative density: 0.84-0.88 pH: Not applicable. VOC g/l: No data available.
9.2. Other information
Other information: No data available.
Section 10: Stability and reactivity
10.1. Reactivity
Reactivity: Stable under recommended transport or storage conditions.
10.2. Chemical stability
Chemical stability: Stable under normal conditions. Stable at room temperature.
10.3. Possibility of hazardous reactions
Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions. Decomposition may occur on exposure to conditions or materials listed below.
10.4. Conditions to avoid
Conditions to avoid: Heat. Hot surfaces. Sources of ignition. Flames.
10.5. Incompatible materials
Materials to avoid: Strong oxidising agents. Strong acids.
10.6. Hazardous decomposition products
Haz. decomp. products: In combustion emits toxic fumes.
Section 11: Toxicological information
11.1. Information on toxicological effects
Relevant hazards for product:
Hazard Route Basis Skin corrosion/irritation DRM Hazardous: calculated Respiratory/skin sensitisation DRM Hazardous: calculated Aspiration hazard - Hazardous: calculated
[cont...] SAFETY DATA SHEET RX-7492 Page: 6
Symptoms / routes of exposure
Skin contact: There may be irritation and redness at the site of contact. Eye contact: There may be irritation and redness. The eyes may water profusely. Ingestion: There may be soreness and redness of the mouth and throat. Inhalation of fumes from the stomach may cause symptoms similar to direct inhalation. Nausea and stomach pain may occur. The breathing may become shallow and rapid. Inhalation: There may be irritation of the throat with a feeling of tightness in the chest. Exposure may cause coughing or wheezing. Delayed / immediate effects: Immediate effects can be expected after short-term exposure.
Section 12: Ecological information
12.1. Toxicity
Ecotoxicity values: No data available.
12.2. Persistence and degradability
Persistence and degradability: Biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential: No bioaccumulation potential.
12.4. Mobility in soil
Mobility: Readily absorbed into soil.
12.5. Results of PBT and vPvB assessment
PBT identification: This product is not identified as a PBT/vPvB substance.
12.6. Other adverse effects
Other adverse effects: Negligible ecotoxicity.
Section 13: Disposal considerations
13.1. Waste treatment methods
Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company. Recovery operations: Use principally as a fuel or other means to generate energy. Disposal of packaging: Arrange for collection by specialised disposal company. NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.
Section 14: Transport information
14.1. UN number
UN number: UN1169
[cont...] SAFETY DATA SHEET RX-7492 Page: 7
14.2. UN proper shipping name
Shipping name: EXTRACTS, AROMATIC, LIQUID
14.3. Transport hazard class(es)
Transport class: 3
14.4. Packing group
Packing group: III
14.5. Environmental hazards
Environmentally hazardous: Yes Marine pollutant: Yes
14.6. Special precautions for user
Special precautions: No special precautions. Tunnel code: D/E Transport category: 3
Section 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Specific regulations: Not applicable.
15.2. Chemical Safety Assessment
Section 16: Other information
Other information
Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 2015/830. * indicates text in the SDS which has changed since the last revision. RX-7492: Danish PR No-1934826 RX-7492: Norwegian PR No-86377 Phrases used in s.2 and s.3: H226: Flammable liquid and vapour. H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H400: Very toxic to aquatic life. H410: Very toxic to aquatic life with long lasting effects. Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.
[final page]
SAFETY DATA SHEET
SAPP
Revision Date: 27-Jun-2016 Revision Number: 21
1. Product Identifier & Identity for the Chemical
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the Globally Harmonised System of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goods according to the criteria of ADG.
1.1. Product Identifier Product Name SAPP
Other means of Identification Synonyms None Hazardous Material Number: HM003755
Recommended use of the chemical and restrictions on use Recommended Use ThinnerControl Agent Uses advised against No information available
Supplier's name, address and phone number Manufacturer/Supplier Halliburton/Baroid Australia Pty. Ltd. 15 Marriott Road Jandakot WA 6164 Australia
ACN Number: 009 000 775 Telephone Number: 61 (08) 9455 8300 Fax Number: 61 (08) 9455 5300
Product Emergency Telephone Australia: + 61 1 800 686 951 Papua New Guinea: + 61 1 800 686 951 NewZealand: +64 800 451719
Fire, Police & Ambulance - Emergency Telephone Australia: 000 Papua New Guinea: 000 New Zealand: 111 E-mail Address [email protected]
Emergency phone number + 61 1 800 686 951
Australian Poisons Information Centre 24 Hour Service: - 13 11 26 Police or Fire Brigade: - 000 (exchange): - 1100
2. Hazard Identification
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the Globally Harmonised System of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goods according to the criteria of ADG.
______Page 1 / 8 SAPP Revision Date: 27-Jun-2016 ______Classification of the hazardous chemical Acute Oral Toxicity Category 4 - H302 Serious Eye Damage/Irritation Category 2 - H319
Label elements, including precautionary statements
Hazard pictograms
Signal Word Warning
Hazard Statements: H302 - Harmful if swallowed H319 - Causes serious eye irritation
Precautionary Statements
Prevention P264 - Wash face, hands and any exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P280 - Wear eye protection/face protection Response P301+ P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell P330 - Rinse mouth P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337 + P313 - If eye irritation persists: Get medical advice/attention Storage None Disposal P501 - Dispose of contents/container in accordance with local/regional/national/international regulations
Contains Substances CAS Number Sodium acid pyrophosphate 7758-16-9
Other hazards which do not result in classification This substance is not considered to be persistent, bioaccumulating nor toxic (PBT). This substance is not considered to be very persistent nor very bioaccumulating (vPvB).
For the full text of the H-phrases mentioned in this Section, see Section 16
3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w) GHS Classification - Australia Sodium acid pyrophosphate 7758-16-9 60 - 100% Acute Tox. 4 (H302) Eye Irrit. 2A (H319)
4. First aid measures
Description of necessary first aid measures Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.
______Page 2 / 8 SAPP Revision Date: 27-Jun-2016 ______Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists. Skin Wash with soap and water. Get medical attention if irritation persists. Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical attention.
Symptoms caused by exposure Causes eye irritation Harmful if swallowed.
Medical Attention and Special Treatment Notes to Physician Treat symptomatically
5. Fire Fighting Measures
Suitable extinguishing equipment Suitable Extinguishing Media All standard fire fighting media Extinguishing media which must not be used for safety reasons None known.
Specific hazards arising from the chemical Special exposure hazards in a fire Not applicable
Special protective equipment and precautions for fire fighters Special protective equipment for firefighters Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Ensure adequate ventilation. Avoid contact with skin, eyes and clothing.
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Scoop up and remove.
7. Handling and storage
7.1. Precautions for safe handling Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Ensure adequate ventilation. Wash hands after use. Launder contaminated clothing before reuse. Use appropriate protective equipment. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities Storage Information Store in a cool, dry location. Other Guidelines No information available
8. Exposure Controls/Personal Protection
Control parameters - exposure standards, biological monitoring
______Page 3 / 8 SAPP Revision Date: 27-Jun-2016 ______Exposure Limits Substances CAS Number Australia NOHSC ACGIH TLV-TWA Sodium acid pyrophosphate 7758-16-9 Not applicable Not applicable
Appropriate engineering controls Engineering Controls Use in a well ventilated area.
Personal protective equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the selection and proper use of personal protective equipment should be determined by an industrial hygienist or other qualified professional based on the specific application of this product. Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational exposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection of and instruction on using all personal protective equipment, including respirators, should be performed by an Industrial Hygienist or other qualified professional. Dust/mist respirator. (N95, P2/P3) Hand Protection Normal work gloves. Skin Protection Normal work coveralls. Eye Protection Wear safety glasses or goggles to protect against exposure. Other Precautions None known. Environmental Exposure Controls Do not allow material to contaminate ground water system
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties Physical State: Solid Color White Odor: Odorless Odor Threshold: No information available
Property Values Remarks/ - Method pH: 4-4.6 Freezing Point / Range No data available Melting Point / Range No data available Boiling Point / Range No data available Flash Point No data available Evaporation rate No data available Vapor Pressure No data available Vapor Density No data available Specific Gravity 1.04 Water Solubility Soluble in water Solubility in other solvents No data available Partition coefficient: n-octanol/water No data available Autoignition Temperature No data available Decomposition Temperature No data available Viscosity No data available Explosive Properties No information available Oxidizing Properties No information available
9.2. Other information Molecular Weight 223.96 VOC Content (%) No data available
10. Stability and Reactivity
10.1. Reactivity Not expected to be reactive. 10.2. Chemical stability Stable 10.3. Possibility of hazardous reactions
______Page 4 / 8 SAPP Revision Date: 27-Jun-2016 ______Will Not Occur 10.4. Conditions to avoid None anticipated 10.5. Incompatible materials Strong oxidizers. 10.6. Hazardous decomposition products Oxides of phosphorus.
11. Toxicological Information
Information on routes of exposure Principle Route of Exposure Eye or skin contact, inhalation.
Symptoms related to exposure Most Important Symptoms/Effects Causes eye irritation Harmful if swallowed.
Numerical measures of toxicity
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation Sodium acid 7758-16-9 1800 mg/kg (Rat) > 2000 mg/kg (Rat) 0.58 mg/L (Rat) 4h pyrophosphate 2650 mg/kg (Mouse) > 7940 mg/kg (Rabbit) > 0.58 mg/L (Mouse) 4h 3600 mg/kg (Rat)
Immediate, delayed and chronic health effects from exposure Inhalation None known. Eye Contact Causes eye irritation. Skin Contact Not irritating to skin in rabbits. Ingestion Harmful if swallowed.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% are chronic health hazards.
Exposure Levels No data available
Interactive effects None known.
Data limitations No data available
Substances CAS Number Skin corrosion/irritation Sodium acid pyrophosphate 7758-16-9 Non-irritating to the skin (Rabbit)
Substances CAS Number Serious eye damage/irritation Sodium acid pyrophosphate 7758-16-9 Irritating to eyes (Rabbit)
Substances CAS Number Skin Sensitization Sodium acid pyrophosphate 7758-16-9 Did not cause sensitization on laboratory animals (mouse)
Substances CAS Number Respiratory Sensitization Sodium acid pyrophosphate 7758-16-9 No information available
Substances CAS Number Mutagenic Effects Sodium acid pyrophosphate 7758-16-9 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects.
Substances CAS Number Carcinogenic Effects Sodium acid pyrophosphate 7758-16-9 No data of sufficient quality are available.
______Page 5 / 8 SAPP Revision Date: 27-Jun-2016 ______Substances CAS Number Reproductive toxicity Sodium acid pyrophosphate 7758-16-9 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animal experiments.
Substances CAS Number STOT - single exposure Sodium acid pyrophosphate 7758-16-9 No information available
Substances CAS Number STOT - repeated exposure Sodium acid pyrophosphate 7758-16-9 No significant toxicity observed in animal studies at concentration requiring classification.
Substances CAS Number Aspiration hazard Sodium acid pyrophosphate 7758-16-9 Not applicable
12. Ecological Information
Ecotoxicity Product Ecotoxicity Data No data available
Substance Ecotoxicity Data Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to Toxicity to Invertebrates Microorganisms Sodium acid 7758-16-9 No information available LC50 (48h) > 1500 mg/L No information available No information available pyrophosphate (Goldorfen)
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability Sodium acid pyrophosphate 7758-16-9 The methods for determining biodegradability are not applicable to inorganic substances.
12.3. Bioaccumulative potential
Substances CAS Number Log Pow Sodium acid pyrophosphate 7758-16-9 No information available
12.4. Mobility in soil
Substances CAS Number Mobility Sodium acid pyrophosphate 7758-16-9 No information available
12.6. Other adverse effects Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
Safe handling and disposal methods Bury in a licensed landfill according to federal, state, and local regulations.
Disposal of any contaminated packaging Follow all applicable national or local regulations.
Environmental regulations Not applicable
14. Transport Information
Transportation Information
______Page 6 / 8 SAPP Revision Date: 27-Jun-2016 ______UN Number Not restricted UN proper shipping name: Not restricted Transport Hazard Class(es): Not applicable Packing Group: Not applicable Environmental Hazards: Not applicable
Special precautions during transport None
HazChem Code None Allocated
15. Regulatory Information
Safety, health and environmental regulations specific for the product
International Inventories Australian AICS Inventory All components are listed on the AICS or are subject to a relevant exemption, permit, or assessment certificate. New Zealand Inventory of All components are listed on the NZIoC or are subject to a relevant exemption, permit, or Chemicals assessment certificate. EINECS (European Inventory of This product, and all its components, complies with EINECS Existing Chemical Substances) US TSCA Inventory All components listed on inventory or are exempt. Canadian Domestic Substances List All components listed on inventory or are exempt. (DSL)
Poisons Schedule number None Allocated
International Agreements Montreal Protocol - Ozone Depleting Substances: Does not apply Stolkhom Convention - Persistent Organic Pollutants: Does not apply Rotterdam Convention - Prior Informed Consent: Does not apply Basel Convention - Hazardous Waste: Does not apply
16. Other information
Date of preparation or review
Revision Date: 27-Jun-2016
Revision Note SDS sections updated: 2
Full text of H-Statements referred to under sections 2 and 3 H302 - Harmful if swallowed H319 - Causes serious eye irritation
Additional information For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Stewardship at 1-580-251-4335.
Key abreviations or acronyms used bw – body weight CAS – Chemical Abstracts Service EC50 – Effective Concentration 50% LC50 – Lethal Concentration 50%
______Page 7 / 8 SAPP Revision Date: 27-Jun-2016 ______LD50 – Lethal Dose 50% LL50 – Lethal Loading 50% mg/kg – milligram/kilogram mg/L – milligram/liter NOEC – No Observed Effect Concentration OEL – Occupational Exposure Limit PBT – Persistent Bioaccumulative and Toxic ppm – parts per million STEL – Short Term Exposure Limit TWA – Time-Weighted Average vPvB – very Persistent and very Bioaccumulative h - hour mg/m3 - milligram/cubic meter mm - millimeter mmHg - millimeter mercury w/w - weight/weight d - day
Key literature references and sources for data www.ChemADVISOR.com/
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
______Page 8 / 8 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name SODIUM SULPHITE Synonym(s) SODIUM SULFITE
1.2 Uses and uses advised against Use(s) ANTIOXIDANT • FOOD PRESERVATIVE • LABORATORY REAGENT • PAPER INDUSTRY • PHOTOGRAPHIC DEVELOPER • REDUCING AGENT • WATER TREATMENT
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS GHS classification(s) Acute Toxicity: Oral: Category 4 Serious Eye Damage / Eye Irritation: Category 1
2.2 Label elements Signal word DANGER
Pictogram(s)
Hazard statement(s) H302 Harmful if swallowed. H318 Causes serious eye damage. AUH031 Contact with acids liberates toxic gas Prevention statement(s) P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/protective clothing/eye protection/face protection. Response statement(s) P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P330 Rinse mouth. Storage statement(s) None allocated.
SDS Date: 04 Aug 2016 Page 1 of 7 Version No: 2 PRODUCT NAME SODIUM SULPHITE
Disposal statement(s) P501 Dispose of contents/container in accordance with relevant regulations.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content SODIUM SULPHITE 7757-83-7 231-821-4 >97% SODIUM SULPHATE 7757-82-6 231-820-9 <2.5% SODIUM CARBONATE 497-19-8 207-838-8 <0.1% WATER 7732-18-5 231-791-2 <0.1%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Urgent hospital treatment is likely to be needed. If swallowed, do not induce vomiting. First aid facilities Eye wash facilities and safety shower are recommended.
4.2 Most important symptoms and effects, both acute and delayed See Section 11 for more detailed information on health effects and symptoms.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture Non flammable. May evolve toxic gases (sulphur oxides) when heated to decomposition.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contact emergency services where appropriate.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.
SDS Date: 04 Aug 2016 Page 2 of 7 Version No: 2 PRODUCT NAME SODIUM SULPHITE
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Sodium Carbonate (total dust) SWA (AUS) -- 10 -- --
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended.
PPE Eye / Face Wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator. At high dust levels, wear a Full-face Class P3 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance WHITE CRYSTALLINE SOLID Odour ODOURLESS Flammability NON FLAMMABLE Flash point NOT RELEVANT Boiling point NOT AVAILABLE Melting point NOT AVAILABLE Evaporation rate NOT AVAILABLE pH 9.0 to 10.5 Vapour density NOT AVAILABLE Specific gravity 2.6 Solubility (water) SOLUBLE Vapour pressure NOT AVAILABLE Upper explosion limit NOT RELEVANT
SDS Date: 04 Aug 2016 Page 3 of 7 Version No: 2 PRODUCT NAME SODIUM SULPHITE
9.1 Information on basic physical and chemical properties Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Contact with acids liberates toxic gas.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Sensitive to air and moisture.
10.5 Incompatible materials Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
10.6 Hazardous decomposition products May evolve toxic gases (sulphur oxides) when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity Information available for the product: Harmful if swallowed. Information available for the ingredient(s):
Oral Toxicity Dermal Toxicity Inhalation Toxicity Ingredient (LD50) (LD50) (LC50) SODIUM SULPHITE 820 mg/kg (mouse) -- -- SODIUM SULPHATE 5989 mg/kg (mouse) -- -- SODIUM CARBONATE 4090 mg/kg (rat) > 2000 mg/kg (rabbit) 800 mg/m³/2 hours Additional ingredient toxicity value(s): SODIUM SULPHITE (7757-83-7) LD50 (intraperitoneal) 950 mg/kg (mouse) LD50 (intravenous) 175 mg/kg (mouse) LDLo (intravenous) 400 mg/kg (cat) LDLo (oral) 2825 mg/kg (rabbit) LDLo (subcutaneous) 600 mg/kg (rabbit) SODIUM SULPHATE (7757-82-6) LD50 (intravenous) 1220 mg/kg (rabbit) LDLo (intravenous) 1220 mg/kg (mouse) TDLo (oral) 14 g/kg (mouse - 8-12 days pregnant) TDLo (subcutaneous) 806 mg/kg/26 weeks intermittently (mouse) SODIUM CARBONATE (497-19-8) LD50 (intraperitoneal) 117 mg/kg (mouse) LD50 (subcutaneous) 2210 mg/kg (mouse) Skin Not classified as a skin irritant. Contact may result in mild irritation, redness, rash and dermatitis. Eye Causes serious eye damage. Contact may result in irritation, lacrimation, pain and redness.
SDS Date: 04 Aug 2016 Page 4 of 7 Version No: 2 PRODUCT NAME SODIUM SULPHITE
Sensitisation Not classified as causing skin or respiratory sensitisation. Some individuals are hypersensitive to sulphites, and may experience asthma like symptoms (wheezing and shortness of breath) immediately following exposure. Mutagenicity Not classified as a mutagen. Carcinogenicity Not classified as a carcinogen. Reproductive Not classified as a reproductive toxin. STOT – single Over exposure may result in mucous membrane irritation of the respiratory tract, with coughing. exposure STOT – repeated Not classified as causing organ damage from repeated exposure. exposure Aspiration Not classified as causing aspiration.
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided.
12.2 Persistence and degradability Biodegradability does not pertain to inorganic substances.
12.3 Bioaccumulative potential This product does not bioaccumulate.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Cover spill with soda ash or sodium bicarbonate. Mix and spray with water, may be effervescent. Wait until reaction is complete, scoop into a large beaker and cautiously add equal volume of sodium hypochlorite (reaction may be vigorous). Add more water, stir and allow to stand (~1hr). Dilute and neutralise. Absorb with sand/similar dispose of to an approved landfill site, or alternatively (for small amounts) flush to sewer with large excess of water. Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated Hazard Class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
SDS Date: 04 Aug 2016 Page 5 of 7 Version No: 2 PRODUCT NAME SODIUM SULPHITE
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes T Toxic Xi Irritant Xn Harmful Risk phrases R22 Harmful if swallowed. R31 Contact with acids liberates toxic gas. R41 Risk of serious damage to eyes.
Safety phrases S25 Avoid contact with eyes. S46 If swallowed, contact a doctor or Poisons Information Centre immediately and show container or label. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
WORKPLACE CONTROLS AND PRACTICES: Unless a less toxic chemical can be substituted for a hazardous substance, ENGINEERING CONTROLS are the most effective way of reducing exposure. The best protection is to enclose operations and/or provide local exhaust ventilation at the site of chemical release. Isolating operations can also reduce exposure. Using respirators or protective equipment is less effective than the controls mentioned above, but is sometimes necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
SDS Date: 04 Aug 2016 Page 6 of 7 Version No: 2 PRODUCT NAME SODIUM SULPHITE
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au. [ End of SDS ]
SDS Date: 04 Aug 2016 Page 7 of 7 Version No: 2 SAFETY DATA SHEET
SODIUM CHLORIDE
Revision Date: 08-Sep-2015 Revision Number: 23
1. Product Identifier & Identity for the Chemical
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the Globally Harmonised System of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goods according to the criteria of ADG.
1.1. Product Identifier Product Name SODIUM CHLORIDE
Other means of Identification Synonyms: None Product Code: HM001682
Recommended use of the chemical and restrictions on use Recommended Use Additive Uses Advised Against No information available
Supplier's name, address and phone number Manufacturer/Supplier Halliburton Australia Pty. Ltd. 15 Marriott Road Jandakot WA 6164 Australia
ACN Number: 009 000 775 Telephone Number: + 61 1 800 686 951 Fax Number: 61 (08) 9455 5300 E-Mail address: [email protected]
Emergency phone number + 61 1 800 686 951
Australian Poisons Information Centre 24 Hour Service: - 13 11 26 Police or Fire Brigade: - 000 (exchange): - 1100
2. Hazard Identification
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the Globally Harmonised System of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goods according to the criteria of ADG.
Classification of the hazardous chemical Not classified
Label elements, including precautionary statements
Hazard Pictograms
Signal Word Not Hazardous
______Page 1 / 7 SODIUM CHLORIDE Revision Date: 08-Sep-2015 ______
Hazard Statements Not Classified
Precautionary Statements
Prevention None
Response None
Storage None
Disposal None
Contains Substances CAS Number Sodium chloride 7647-14-5
Other hazards which do not result in classification This substance is not considered to be persistent, bioaccumulating nor toxic (PBT). This substance is not considered to be very persistent nor very bioaccumulating (vPvB).
Australia Classification For the full text of the H-phrases mentioned in this Section, see Section 16
Classification Not Classified Risk Phrases None
3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w) GHS Classification - Australia Sodium chloride 7647-14-5 60 - 100%
4. First aid measures
Description of necessary first aid measures Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult. Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists. Skin Wash with soap and water. Get medical attention if irritation persists. Ingestion Under normal conditions, first aid procedures are not required.
Symptoms caused by exposure Causes mild eye irritation.
Medical Attention and Special Treatment Notes to Physician Treat symptomatically
5. Fire Fighting Measures
Suitable extinguishing equipment Suitable Extinguishing Media All standard fire fighting media Extinguishing media which must not be used for safety reasons None known.
Specific hazards arising from the chemical
______Page 2 / 7 SODIUM CHLORIDE Revision Date: 08-Sep-2015 ______Special Exposure Hazards None anticipated
Special protective equipment and precautions for fire fighters Special Protective Equipment for Fire-Fighters Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust.
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Scoop up and remove.
7. Handling and storage
7.1. Precautions for Safe Handling Handling Precautions Avoid creating or inhaling dust. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities Storage Information Store in a cool, dry location. Other Guidelines No information available
8. Exposure Controls/Personal Protection
Control parameters - exposure standards, biological monitoring Exposure Limits Substances CAS Number Australia NOHSC ACGIH TLV-TWA Sodium chloride 7647-14-5 Not applicable Not applicable
Appropriate engineering controls Engineering Controls Use in a well ventilated area.
Personal protective equipment (PPE) Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational exposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection of and instruction on using all personal protective equipment, including respirators, should be performed by an Industrial Hygienist or other qualified professional. Dust/mist respirator. (N95, P2/P3) Hand Protection Normal work gloves. Skin Protection Normal work coveralls. Eye Protection Wear safety glasses or goggles to protect against exposure. Other Precautions None known. Environmental Exposure Controls No information available
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
______Page 3 / 7 SODIUM CHLORIDE Revision Date: 08-Sep-2015 ______Physical State: Solid Color: White Odor: Odorless Odor Threshold: No information available
Property Values Remarks/ - Method pH: No data available Freezing Point/Range No data available Melting Point/Range 801 °C / 1473.8 °F Boiling Point/Range No data available Flash Point No data available Evaporation rate No data available Vapor Pressure No data available Vapor Density No data available Specific Gravity 2.16 Water Solubility Very soluble Solubility in other solvents No data available Partition coefficient: n-octanol/water No data available Autoignition Temperature No data available Decomposition Temperature No data available Viscosity No data available Explosive Properties No information available Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
10. Stability and Reactivity
10.1. Reactivity Not expected to be reactive. 10.2. Chemical Stability Stable 10.3. Possibility of Hazardous Reactions Will Not Occur 10.4. Conditions to Avoid None anticipated 10.5. Incompatible Materials None known. 10.6. Hazardous Decomposition Products None known.
11. Toxicological Information
Information on routes of exposure Principle Route of Exposure Eye or skin contact, inhalation.
Sympotoms related to exposure Most Important Symptoms/Effects Causes mild eye irritation.
Numerical measures of toxicity
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation Sodium chloride 7647-14-5 3000 mg/kg (Rat) >10000 mg/kg (Rabbit) 42 mg/L (Rat) 1h 3550 mg/kg (Rat)
Immediate, delayed and chronic health effects from exposure Inhalation May cause mild respiratory irritation. Eye Contact Causes mild eye irritation. Skin Contact May cause mild skin irritation.
______Page 4 / 7 SODIUM CHLORIDE Revision Date: 08-Sep-2015 ______Ingestion None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% are chronic health hazards.
Exposure Levels No data available
Interactive effects None known.
Data limitations No data available
Substances CAS Number Skin corrosion/irritation Sodium chloride 7647-14-5 Non-irritating to the skin (Rabbit)
Substances CAS Number Eye damage/irritation Sodium chloride 7647-14-5 May cause mild eye irritation. (Rabbit)
Substances CAS Number Skin Sensitization Sodium chloride 7647-14-5 No information available
Substances CAS Number Respiratory Sensitization Sodium chloride 7647-14-5 No information available
Substances CAS Number Mutagenic Effects Sodium chloride 7647-14-5 No information available
Substances CAS Number Carcinogenic Effects Sodium chloride 7647-14-5 Did not show carcinogenic effects in animal experiments
Substances CAS Number Reproductive toxicity Sodium chloride 7647-14-5 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animal experiments.
Substances CAS Number STOT - single exposure Sodium chloride 7647-14-5 No information available
Substances CAS Number STOT - repeated exposure Sodium chloride 7647-14-5 No significant toxicity observed in animal studies at concentration requiring classification.
Substances CAS Number Aspiration hazard Sodium chloride 7647-14-5 Not applicable
12. Ecological Information
Ecotoxicity Product Ecotoxicity Data No data available
Substance Ecotoxicity Data Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to Toxicity to Invertebrates Microorganisms Sodium chloride 7647-14-5 EC50 (120h) 2430 mg/L TLM96 > 1000 mg/L NOEC 5000 – 8000 mg/L TLM96 > 1,000,000 ppm (Nitzschia sp.) (Oncorhynchus mykiss) (activated sludge) (Mysidopsis bahia) LC50 (96h) 5840 mg/L NOEC 292-584 mg/L LC50 (48h) 874-4136 (Lepomis macrochirus) (Escherichia coli) mg/L (Daphnia magna) NOEC (33d) 252 mg/L NOEC (21d) 314 mg/L (Pimephales promelas) (Daphnia pulex)
12.2. Persistence and degradability ______Page 5 / 7 SODIUM CHLORIDE Revision Date: 08-Sep-2015 ______
Substances CAS Number Persistence and Degradability Sodium chloride 7647-14-5 No information available
12.3. Bioaccumulative potential
Substances CAS Number Log Pow Sodium chloride 7647-14-5 No information available
12.4. Mobility in soil
Substances CAS Number Mobility Sodium chloride 7647-14-5 No information available
12.6. Other adverse effects Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
Safe handling and disposal methods Bury in a licensed landfill according to federal, state, and local regulations.
Disposal of any contaminated packaging Follow all applicable national or local regulations. Contaminated packaging may be disposed of by: rendering packaging incapable of containing any substance, or treating packaging to remove residual contents, or treating packaging to make sure the residual contents are no longer hazardous, or by disposing of packaging into commercial waste collection.
Environmental regulations Not applicable
14. Transport Information
Transportation Information UN Number: Not restricted UN Proper Shipping Name: Not restricted Transport Hazard Class(es): Not applicable Packing Group: Not applicable Environmental Hazards: Not applicable
Special precautions during transport None
HazChem Code None Allocated
15. Regulatory Information
Safety, health and environmental regulations specific for the product
International Inventories Australian AICS Inventory All components listed on inventory or are exempt. New Zealand Inventory of All components listed on inventory or are exempt. Chemicals EINECS Inventory This product, and all its components, complies with EINECS US TSCA Inventory All components listed on inventory or are exempt. Canadian DSL Inventory All components listed on inventory or are exempt.
Poisons Schedule number
______Page 6 / 7 SODIUM CHLORIDE Revision Date: 08-Sep-2015 ______None Allocated
16. Other information
Date of preparation or review
Revision Date: 08-Sep-2015
Revision Note SDS sections updated: 2
Full text of R-phrases referred to under Sections 2 and 3 None
Full text of H-Statements referred to under sections 2 and 3 None
Additional information For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Stewardship at 1-580-251-4335.
Key abreviations or acronyms used bw – body weight CAS – Chemical Abstracts Service EC50 – Effective Concentration 50% LC50 – Lethal Concentration 50% LD50 – Lethal Dose 50% LL50 – Lethal Loading 50% mg/kg – milligram/kilogram mg/L – milligram/liter NOEC – No Observed Effect Concentration OEL – Occupational Exposure Limit PBT – Persistent Bioaccumulative and Toxic ppm – parts per million STEL – Short Term Exposure Limit TWA – Time-Weighted Average vPvB – very Persistent and very Bioaccumulative h - hour mg/m3 - milligram/cubic meter mm - millimeter mmHg - millimeter mercury w/w - weight/weight d - day
Key literature references and sources for data www.ChemADVISOR.com/ NZ CCID
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
______Page 7 / 7 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name TRIETHANOLAMINE Synonym(s) RHEOCHEM TRIETHANOLAMINE
1.2 Uses and uses advised against Use(s) CHEMICAL INTERMEDIATE • LABORATORY REAGENT • SOLVENT
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA GHS classification Serious Eye Damage / Eye Irritation: Category 1 Specific Target Organ Systemic Toxicity (Repeated Exposure): Category 2
2.2 Label elements Signal word DANGER
Pictograms
Hazard statement(s) H318 Causes serious eye damage. H373 May cause damage to organs through prolonged or repeated exposure. Prevention statement(s) P260 Do not breathe dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection. Response statement(s) P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P314 Get medical advice/attention if you feel unwell. Storage statement(s) None allocated.
Disposal statement(s) P501 Dispose of contents/container in accordance with relevant regulations.
Page 1 of 7 SDS Date: 25 Jul 2014 PRODUCT NAME TRIETHANOLAMINE
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient Identification Classification Content GHS Risk TRIETHANOLAMINE CAS: 102-71-6 Not Available Not Available >60% EC: 203-049-8 DIETHANOLAMINE CAS: 111-42-2 Acute Tox. 4, H302 Xn;R22, Xi;R38, 10 to <30% EC: 203-868-0 Skin Irrit. 2, H315 Xi;R41, Xn;R48/22 Eye Dam. 1, H318 STOT RE 2, H373 ETHANOLAMINE CAS: 141-43-5 Acute Tox. 4, H302 Xn;R20/21/22, <10% EC: 205-483-3 Acute Tox. 4, H312 C;R34 Skin Corr. 1B, H314 Acute Tox. 4, H332
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. To protect rescuer, use a Type A (Organic vapour) respirator or an Air-line respirator (in poorly ventilated areas). Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. Rinse mouth out with water and give plenty of water to drink. First aid facilities No information provided.
4.2 Most important symptoms and effects, both acute and delayed Over exposure may result in irritation to the eyes, nose and respiratory system. May cause allergic contact dermatitis.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains or waterways.
5.2 Special hazards arising from the substance or mixture Combustible. May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in Section 8. Clear area of all unprotected personnel. Ventilate area where possible. Contact emergency services where appropriate.
Page 2 of 7 SDS Date: 25 Jul 2014 PRODUCT NAME TRIETHANOLAMINE
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then cover/absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place in suitable containers for disposal.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills. Store as a Class C2 Combustible Liquid (AS1940).
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Diethanolamine (h) SWA (AUS) 3 13 -- -- Ethanolamine SWA (AUS) 3 7.5 6 15 Triethanolamine SWA (AUS) -- 5 -- --
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended. Maintain vapour levels below the recommended exposure standard.
PPE Eye / Face Wear splash-proof goggles. Hands Wear PVC or rubber gloves. Body Wear coveralls. Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator. If spraying, wear a Type A-Class P1 (Organic gases/vapours and Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance CLEAR LIQUID Odour MILD AMMONIACAL ODOUR Flammability CLASS C2 COMBUSTIBLE Flash point 190°C
Page 3 of 7 SDS Date: 25 Jul 2014 PRODUCT NAME TRIETHANOLAMINE
9.1 Information on basic physical and chemical properties Boiling point 335°C Melting point 12°C Evaporation rate < 0.01 (n-Butyl acetate = 1) pH 10.5 (1 % Solution) Vapour density 4.80 (Air = 1) Specific gravity 1.12 Solubility (water) SOLUBLE Vapour pressure < 1 kPa @ 20°C Upper explosion limit NOT AVAILABLE Lower explosion limit NOT AVAILABLE Partition coefficient NOT AVAILABLE Autoignition temperature 375°C Decomposition temperature NOT AVAILABLE Viscosity 450 cP @ 25°C Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Hazardous polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (eg. hypochlorites), acids (eg. nitric acid), nitrites, heat and ignition sources. Also incompatible with organic anhydrides, isocyanates, vinyl acetate, acrylates, substituted allyls, alkylene oxides, epichlorohydrin, aldehydes, copper, brass and aluminium.
10.6 Hazardous decomposition products May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity May be harmful if swallowed, in contact with skin, and/or if inhaled. LD50 (oral) = 2200 mg/kg (rabbit). Skin Contact may result in mild irritation, redness, pain and rash. Eye Contact may result in irritation, lacrimation, pain and redness. May result in burns with prolonged contact. Sensitization Triethanolamine has been reported to cause allergic contact dermatitis in humans. It is not known to cause respiratory sensitisation. Mutagenicity Insufficient data available to classify as a mutagen. Carcinogenicity Triethanolamine and diethanolamine are not classifiable as to carcinogenicity to humans (IARC Group 3). Reproductive Insufficient data available to classify as a reproductive toxin. STOT – single Over exposure may result in irritation of the nose and throat, with coughing. High level exposure may result in exposure breathing difficulties. STOT – repeated Diethanolamine may cause damage to organs (liver) through prolonged and repeated exposure. exposure Aspiration This product is not expected to present an aspiration hazard.
Page 4 of 7 SDS Date: 25 Jul 2014 PRODUCT NAME TRIETHANOLAMINE
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided.
12.2 Persistence and degradability The substance is expected to be readily biodegradable according to the AS 4351 Part 2 test method.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects In soil and water, triethanolamine will biodegrade fairly rapidly following acclamation (half-life in the order of days to weeks). In soil, residual triethanolamine may leach to groundwater. LC50 (shrimp): > 100 ppm.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Reduce with sodium thiosulphate/ bisulphite (not strong reducing agent), acidify with 3M sulphuric acid. Scoop into a container of water and neutralise with soda ash. Absorb with sand or similar and dispose of to approved landfill site. Contact the manufacturer for additional information. Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule Classified as a Schedule 5 (S5) Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes Xi Irritant Xn Harmful Risk phrases R41 Risk of serious damage to eyes. R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.
Safety phrases S25 Avoid contact with eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S39 Wear eye/face protection.
Page 5 of 7 SDS Date: 25 Jul 2014 PRODUCT NAME TRIETHANOLAMINE
Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit PEL Permissible Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million REACH Regulation on Registration, Evaluation, Authorisation and Restriction of Chemicals STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Revision history Revision Description 2.0 Converted to GHS. 1.0 Initial SDS creation
Page 6 of 7 SDS Date: 25 Jul 2014 PRODUCT NAME TRIETHANOLAMINE
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 2 SDS date: 25 July 2014 [ End of SDS ]
Page 7 of 7 SDS Date: 25 Jul 2014 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name XANTHAN GUM (P) Synonym(s) NEWZAN D ● VISCO XC 84 ● XANTHAN GUM (BIOPOLYMER)
1.2 Uses and uses advised against Use(s) DRILLING FLUID ADDITIVE ● VISCOSITY MODIFIER
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 4 917 9888 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content XANTHAN GUM 11138-66-2 234-394-2 >87% WATER 7732-18-5 231-791-2 <13%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. Ingestion is considered unlikely due to product form. First aid facilities Eye wash facilities and safety shower should be available.
SDS Date: 03 May 2017 Page 1 of 6 Version No: 1.5 PRODUCT NAME XANTHAN GUM (P)
4.2 Most important symptoms and effects, both acute and delayed Adverse effects not expected from this product under normal conditions of use.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains and waterways.
5.2 Special hazards arising from the substance or mixture Combustible. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Finely divided dust may form explosive mixtures with air.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contact emergency services where appropriate.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately labelled and tightly closed when not in use.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards No exposure standards have been entered for this product.
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas.
SDS Date: 03 May 2017 Page 2 of 6 Version No: 1.5 PRODUCT NAME XANTHAN GUM (P)
PPE Eye / Face Wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Wear a Class P1 (Particulate) respirator. Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance LIGHT BEIGE POWDER Odour SLIGHT ODOUR Flammability COMBUSTIBLE Flash point NOT RELEVANT Boiling point NOT AVAILABLE Melting point NOT AVAILABLE Evaporation rate NOT AVAILABLE pH NOT AVAILABLE Vapour density NOT AVAILABLE Specific gravity 1.5 Solubility (water) MISCIBLE Vapour pressure NOT AVAILABLE Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
10.6 Hazardous decomposition products May evolve carbon oxides and hydrocarbons when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
SDS Date: 03 May 2017 Page 3 of 6 Version No: 1.5 PRODUCT NAME XANTHAN GUM (P)
Acute toxicity This product is expected to be of low acute toxicity. Under normal conditions of use, adverse health effects are not anticipated. LD50 (oral) > 1000 mg/kg (mouse) LD50 (oral) > 45,000 mg/kg (rat) LD50 (oral) > 20,000 mg/kg (dog) LD50 (intraperitoneal): > 50 mg/kg (mouse) LD50 (intravenous): 100-250 mg/kg (mouse) Skin Not classified as a skin irritant. Contact may result in mild irritation. Eye Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness. Sensitisation Not classified as causing skin or respiratory sensitisation. Mutagenicity No evidence of mutagenic effects. Carcinogenicity No evidence of carcinogenic effects. Reproductive No relevant or reliable studies were identified. STOT - single Not classified as causing organ damage from single exposure. exposure STOT - repeated Not classified as causing organ damage from repeated exposure. exposure Aspiration This product does not present an aspiration hazard.
12. ECOLOGICAL INFORMATION
12.1 Toxicity This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential Not expected to bioaccumulate.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Council landfill. Contact the manufacturer/supplier for additional information (if required). Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
14.1 UN Number None allocated. None allocated. None allocated. 14.2 Proper None allocated. None allocated. None allocated. Shipping Name
14.3 Transport None allocated. None allocated. None allocated. hazard class 14.4 Packing Group None allocated. None allocated. None allocated. 14.5 Environmental hazards No information provided. 14.6 Special precautions for user Hazchem code None allocated.
SDS Date: 03 May 2017 Page 4 of 6 Version No: 1.5 PRODUCT NAME XANTHAN GUM (P)
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as form of product, method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: form of product; frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
SDS Date: 03 May 2017 Page 5 of 6 Version No: 1.5 PRODUCT NAME XANTHAN GUM (P)
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au [ End of SDS ]
SDS Date: 03 May 2017 Page 6 of 6 Version No: 1.5
CHEMALERT REPORT Full Report
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
1.1 Product identifier Product name CALCIUM CHLORIDE POWDER 94-97% Synonym(s) CALCIUM CHLORIDE ANHYDRATE 1.2 Uses and uses advised against Use(s) CONCRETE CONDITIONER • DESICCANT • DUST CONTROL AGENT • FOOD ADDITIVE • INDUSTRIAL APPLICATIONS 1.3 Details of the supplier of the safety data sheet Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, Australia, 6166 Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Email Not supplied Website http://www.newpark.com 1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International) 2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA Risk phrases R36 Irritating to eyes. Safety phrases S22 Do not breathe dust. S24 Avoid contact with skin.
Other Hazards No information provided. 3. COMPOSITION/ INFORMATION ON INGREDIENTS 3.1 Substances / Mixtures Ingredient CAS number EC number Content CALCIUM CHLORIDE ANHYDROUS 10043-52-4 233-140-8 94 - 97% SODIUM CHLORIDE 7647-14-5 231-598-3 1 - 5% WATER 7732-18-5 231-791-2 1%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. First aid facilities Eye wash facilities and safety shower should be available. 4.2 Most important symptoms and effects, both acute and delayed Irritating to the eyes and skin. 4.3 Immediate medical attention and special treatment needed Treat symptomatically.
Page 1 of 7 Reviewed: 17 Apr 2015 This report was compiled based on the SDS dated 17 Apr 2015 Printed: 29 Jul 2016
CHEMALERT REPORT Full Report
Product name CALCIUM CHLORIDE POWDER 94-97%
5. FIREFIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire. 5.2 Special hazards arising from the substance or mixture Non flammable. May evolve toxic gases (chlorides) when heated to decomposition. 5.3 Advice for firefighters Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas. 5.4 Hazchem code None allocated 6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contact emergency services where appropriate. 6.2 Environmental precautions Prevent product from entering drains and waterways. 6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust. 6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal. 7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas. 7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. 7.3 Specific end use(s) No information provided. 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION
8.1 Control parameters Exposure standards No exposure standards have been entered for this product. Biological limits No Biological Limit Value allocated. 8.2 Exposure controls Engineering Controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended. Maintain dust levels below the recommended exposure standard. PPE
Page 2 of 7 Reviewed: 17 Apr 2015 This report was compiled based on the SDS dated 17 Apr 2015 Printed: 29 Jul 2016
CHEMALERT REPORT Full Report
Product name CALCIUM CHLORIDE POWDER 94-97%
Eye/Face Wear dust-proof goggles. Hand Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance WHITE POWDER Odour ODOURLESS Odour Threshold NOT AVAILABLE pH 7.0 to 9.0 Melting Point 772°C Boiling Point > 1600°C Flash Point NOT RELEVANT Evaporation Rate NOT RELEVANT Flammability NON FLAMMABLE Upper Explosion Limit NOT RELEVANT Lower Explosion Limit NOT RELEVANT Vapour Pressure NOT AVAILABLE Vapour Density NOT AVAILABLE Solubility (water) 590 kg/m³ (Approximately) Partition Coefficient NOT AVAILABLE Autoignition Temperature NOT AVAILABLE Decomposition Temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive Properties NOT AVAILABLE Oxidising Properties NOT AVAILABLE Specific Gravity 2.15 9.2 Other information % Volatiles NOT AVAILABLE 10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information in sections 10.2 to 10.6. 10.2 Chemical stability Stable under recommended conditions of storage. 10.3 Possibility of hazardous reactions Polymerization is not expected to occur. 10.4 Conditions to avoid Avoid contact with incompatible substances. 10.5 Incompatible materials Incompatible with acids (e.g. nitric acid), methyl vinyl ether, zinc/ galvanised metals, bromine trifluoride, boron oxide and calcium oxide. May react exothermically with water (i.e. releasing heat). 10.6 Hazardous decomposition products
Page 3 of 7 Reviewed: 17 Apr 2015 This report was compiled based on the SDS dated 17 Apr 2015 Printed: 29 Jul 2016
CHEMALERT REPORT Full Report
Product name CALCIUM CHLORIDE POWDER 94-97%
May evolve toxic gases (chlorides) when heated to decomposition. 11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity Based on available data, the classification criteria are not met. Toxicity Data available for the ingredients: CALCIUM CHLORIDE ANHYDROUS (10043-52-4): LD50 (Ingestion): 1000 mg/kg (rat) LD50 (Intraperitoneal): 210 mg/kg (mouse) LD50 (Intravenous): 42 mg/kg (mouse) LD50 (Subcutaneous): 823 mg/kg (mouse) LDLo (Ingestion): 1384 mg/kg (rabbit) LDLo (Intravenous): 150 mg/kg (guinea pig) LDLo (Subcutaneous): 249 mg/kg (cat) TDLo (Intravenous): 20 mg/kg/1 hour (woman) SODIUM CHLORIDE (7647-14-5): LC50 (Inhalation): > 42000 mg/m3/1 hour (rat) LD50 (Ingestion): 3000 mg/kg (rat) LD50 (Intraperitoneal): 2602 mg/kg (mouse) LD50 (Intravenous): 645 mg/kg (mouse) LD50 (Skin): > 10000 mg/kg (rabbit) LD50 (Subcutaneous): 3000 mg/kg (mouse) LDLo (Ingestion): 8000 mg/kg (rabbit) LDLo (Intravenous): 300 mg/kg (guinea pig) LDLo (Subcutaneous): 2160 mg/kg (guinea pig) TDLo (Ingestion): 12357 mg/kg (human) Skin Not classified as a skin irritant. Contact may result in mechanical irritation, redness and rash. Eye Irritating to the eyes. Contact may result in irritation, lacrimation, pain and redness. Mutagenicity Insufficient data available to classify as a mutagen. Carcinogenicity Insufficient data available to classify as a carcinogen. Reproductive Insufficient data available to classify as a reproductive toxin. STOT - single Not classified as causing organ effects from single exposure. exposure STOT - repeated Not classified as causing organ damage from repeated exposure. exposure Aspiration This product does not present an aspiration hazard. Sensitisation Not classified as causing skin or respiratory sensitisation.
Page 4 of 7 Reviewed: 17 Apr 2015 This report was compiled based on the SDS dated 17 Apr 2015 Printed: 29 Jul 2016
CHEMALERT REPORT Full Report
Product name CALCIUM CHLORIDE POWDER 94-97%
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided. 12.2 Persistence and degradability Biodegradability does not pertain to inorganic substances. 12.3 Bioaccumulative potential This product does not bioaccumulate. 12.4 Mobility in soil No information provided. 12.5 Results of PBT and vPvB assessment No information provided. 12.6 Other adverse effects No information provided. 13. DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Council landfill. Contact the manufacturer/supplier for additional information (if required). Legislation Dispose of in accordance with relevant local legislation. 14. TRANSPORT INFORMATION
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
Land Transport Sea Transport Air Transport (ADG) (IMDG/IMO) (IATA/ICAO)
14.1 UN number None Allocated None Allocated None Allocated 14.2 UN proper shipping name None Allocated None Allocated None Allocated 14.3 Transport hazard classes DG Class None Allocated None Allocated None Allocated Subsidiary risk(s) None Allocated None Allocated None Allocated 14.4 Packing group None Allocated None Allocated None Allocated 14.5 Environmental hazards None Allocated 14.6 Special precautions for user Hazchem Code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Xi - Irritant
Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
15.2 Chemical safety assessment No information provided.
Page 5 of 7 Reviewed: 17 Apr 2015 This report was compiled based on the SDS dated 17 Apr 2015 Printed: 29 Jul 2016
CHEMALERT REPORT Full Report
Product name CALCIUM CHLORIDE POWDER 94-97%
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made. Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Report Status This ChemAlert report has been independently compiled by RMT's scientific department utilising the original Safety Data Sheet ('SDS') for the product provided to RMT by the manufacturer. The information is based on the latest chemical and toxicological research and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. It is an independent collation by RMT of information obtained from the original SDS for this product. Its content has not been authorised or verified by the manufacturer / distributor of the chemical to which it relates.
This ChemAlert report does not constitute the manufacturer's original SDS and is not intended to be a replacement for same. It is provided to subscribers of ChemAlert as a reference tool only, is not all-inclusive and does not represent any guarantee as to the properties of the product. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer.
Page 6 of 7 Reviewed: 17 Apr 2015 This report was compiled based on the SDS dated 17 Apr 2015 Printed: 29 Jul 2016
CHEMALERT REPORT Full Report
Product name CALCIUM CHLORIDE POWDER 94-97%
While RMT has taken all due care to include accurate and up-to-date information in this ChemAlert report, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this ChemAlert report. Prepared By Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au
Last Reviewed:17 Apr 2015 Date Printed:29 Jul 2016 Based on SDS dated:17 Apr 2015
End of Report
Page 7 of 7 Reviewed: 17 Apr 2015 This report was compiled based on the SDS dated 17 Apr 2015 Printed: 29 Jul 2016 Perth Basin Well Intervention Activities Environment Plan Summary
Appendix 3 WIA Cementing Chemical Disclosure Tables
HSE-E-075-SUM Rev 4 Perth Basin Well Intervention Activities Environment Plan Summary
Table 9: Products, additives, chemicals and other substances (Cementing) Table 9a: System Details
Operator AWE Perth Pty Ltd Project/Well Potentially any well listed in Error! Reference source not found. System Cementing Total Volume of System 300bbl (47,700 L) per well
Table 9b: Product List
% Product in SDS Product Name Supplier Purpose Toxicity, Ecotoxicity & Biodegradability data** System Fluid Attached Cement - Class G Halliburton Cement PRODUCT CEFAS LISTED 68.6% Yes 100% PLONOR CONSTITUENT 1 (≤100%): LD50 Oral: >2,000 mg/kg (Rat), LD50 Dermal: >2,000 mg/kg, LC50 Inhalation: >1.0 mg/L (4h) (Rat) After hardening with water or moister, cement presents no ecotoxicity risks. (Source: IUCLID 2000) Static Aquatic Toxicity - Freshwater and Marine Algae: 72 hour EC50: >1,000 mg/L Static Aquatic Toxicity -Freshwater and Marine Invertebrates: 48 hour LC50: >1,000 mg/L Static Aquatic Toxicity- Freshwater and Marine Fish: 96 hour LC50: >1,500 mg/L Partition Coefficient, n-Octanol/Water: Not Applicable for inorganics Oxygen Demand, Chemical Oxygen Demand: Not Applicable for inorganics Biodegradability, Seawater – Indigenous microbes: Not Applicable for inorganics CONSTITUENT 2 (≤10%): LD50 Oral: >15000 mg/kg (human) Freshwater Crustacean Toxicity 24h LL50: > 10,000 mg/L (Daphnia magna) [Health Canada] (similar substance); Freshwater Fish Toxicity 96h LL0: 10,000 mg/L (Danio rerio) [Health Canada] (similar substance); Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable. Customer Supplied Mix Customer To Mix Fluids No Hazard 30% No Water
Halad-413L Halliburton Fluid Loss Additive PRODUCT CEFAS LISTED 1.00% Yes CONSTITUENT 1 (≤30%): Oral LD50: >2,000 mg/kg (Rat) Marine Water Algae Toxicity 72h EC50: 1102 mg/L (Skeletonema costatum) [OSPAR]; Marine Water Crustacean Toxicity 48h LC50: > 2000 mg/L (Acartia tonsa) [OSPAR]; Marine Water Fish Toxicity 96h LC50: > 1,000 mg/L (Scophthalmus maximus) [OSPAR]; Bioaccumulation Log Kow: < 3.5 [Halliburton Funded Study]; Marine Water Biodegradation 28d: 6 % [Halliburton Funded Study]; CONSTITUENT 2 (≤100%): Product is naturally occurring and not intrinsically hazardous No data available to indicate product or components present at greater than 0.1% are chronic health hazards CFR-8L Halliburton Friction Reducer PRODUCT CEFAS LISTED 0.246% Yes CONSTITUENT 1 (≤60%): Oral LD50: >5,000 mg/kg (Rat) Marine Water Algae Toxicity 72h EC50: 7,631.73 mg/L (Skeletonema costatum); Marine Water Crustacean Toxicity 48h LC50: 2,200 mg/L (Acartia tonsa);
HSE-E-075-SUM Rev 4 Perth Basin Well Intervention Activities Environment Plan Summary
% Product in SDS Product Name Supplier Purpose Toxicity, Ecotoxicity & Biodegradability data** System Fluid Attached Marine Water Fish Toxicity 96h LC50: 1006 mg/L (Scophthalmus maximus); Fresh Water Crustacean Toxicity 48h LC50: >100 mg/L (Daphnia magna); Bioaccumulation Log Pow: < 0; Inherently biodegradable: Biodegradation 28d: 38%; CONSTITUENT 2 (≤100%): Component is naturally occurring and not intrinsically hazardous No data available to indicate product or components present at greater than 0.1% are chronic health hazards NF-6 Halliburton Reduces air PRODUCT DATA 0.0772% Yes entrainment into Marine Water Algae Toxicity 72h EC50: 1100 mg/L (Skeletonema costatum) [Halliburton Funded Study]; Marine Water Crustacean cement slurry Toxicity 48h LC50: > 1000 mg/L (Acartia tonsa) [Halliburton Funded Study]; Marine Water Fish Toxicity 96h LC50: > 1,000 mg/L (Scophthalmus maximus) [Halliburton Funded Study]; Marine Water Biodegradation 28d: 70% [Halliburton Funded Study]; CONSTITUENT 1 (≤10%) Marine Algae Toxicity 72h EC50: 991.02 mg/L (Skeletonema costatum) Marine Crustacean Toxicity 48h LC50: 2,500 mg/L (Acartia tonsa); Marine Fish Toxicity 96h LC50: >3,200 mg/L (Scophthalmus maximus); Bioaccumulation: Calculated Log Pow: 7.45 CONSTITUENT 2 (≤5%): Oral LD50: >15,900 mg/kg (Mouse), Inhalation LC50: >5 mg/L (4h) (Rat) Marine Algae Toxicity 72h EC50: 41 mg/L (Skeletonema costatum) Marine Crustacean Toxicity 48h LC50: >10,000 mg/L (Acartia tonsa); Marine Fish Toxicity 96h LC50: >1,800 mg/L (Scophthalmus maximus); Bioaccumulation: Calculated Log Pow: 4.28 CONSTITUENT 3 (≤5%) Oral LD50: > 5000 mg/kg (Rat), Dermal LD50: >5,000 mg/kg (Guinea Pig) Marine Algae Toxicity 72h EC50: 6,488.87 mg/L (Skeletonema costatum) Marine Crustacean Toxicity 48h LC50: 5,085.71 mg/L (Acartia tonsa); Marine Fish Toxicity 96h LC50: >5,600 mg/L (Scophthalmus maximus); Bioaccumulation: Calculated Log Pow: 22.69 (MW>700) CONSTITUENT 4 (≤10%) No Hazard Product is naturally occurring CONSTITUENT 5 (≤100%) Oral LD50: 90 mg/kg (Mouse) (Similar Substance) Marine Algae Toxicity 72h EC50: >3,200 mg/L (Skeletonema costatum) Marine Crustacean Toxicity 48h LC50: >10,000 mg/L (Acartia tonsa); Marine Fish Toxicity 96h LC50: >5,600 mg/L (Scophthalmus maximus); Bioaccumulation: Calculated Log Pow: 7.09 No data available to indicate product or components present at greater than 0.1% are chronic health hazards
HSE-E-075-SUM Rev 4 Perth Basin Well Intervention Activities Environment Plan Summary
% Product in SDS Product Name Supplier Purpose Toxicity, Ecotoxicity & Biodegradability data** System Fluid Attached HR-6L Halliburton Cement Retarder PRODUCT CEFAS LISTED 0.0754% Yes 100% PLONOR CONSTITUENT 1 (≤100%): Component is naturally occurring and is not intrinsically hazardous CONSTITUENT 2 (≤60%): Oral LC50: >5,000 mg/L, Inhalation LC50: > 480 mg/m3 Freshwater Fish Toxicity LC50: >1,000 mg/L (Danio rerio) Marine Water Algae Toxicity 72h EC50: 301 mg/L (Skeletonema costatum) [Halliburton Funded Study]; Marine Water Crustacean Toxicity 48h LC50: 1,261 mg/L (Acartia tonsa) [Halliburton Funded Study]; Bioaccumulation Log Pow: -3.45 (Calculated) [Halliburton Funded Study]; Biodegradation: No data - expected to be inherently biodegradable No data available to indicate product or components present at greater than 0.1% are chronic health hazards.
Contingency Volumes Water Town or Bore Base fluid N/A - Natural product. 53.749% N/A water
Dump Bailed Cement Thru Tubing Cement Toxicological Information 0.666% Yes Systems Inhalation of dust may cause respiratory tract irritation. Symptoms of exposure may include cough, sore throat, nasal congestion, Neo Products sneezing, wheezing, and shortness of breath. May cause an allergic skin reaction. Portland Cement: OSHA PEL (TWA) 5 mg/m3. NIOSH REL (TWA) 5 mg/m3. IDLH 5000 mg/m3 Crystalline Silica (quartz): OSHA PEL (TWA) 5 mg/m3. NIOSH REL (TWA) 5 mg/m3. IDLH 5000 mg/m3. LD50 Oral Rat > 5,000 mg/kg Calcium Oxide: OSHA PEL (TWA) 5 mg/m3. NIOSH REL (TWA) 2 mg/m3. IDLH 25 mg/m3 Gypsum: OSHA PEL (TWA) 15 mg/m3 (Total) 5 mg/m3 (Resp). NIOSH REL (TWA) 10 mg/m3 (Total) 5 mg/m3 (Resp). Magnesium Oxide: OSHA PEL (TWA) 15 mg/m3. IDLH 750 mg/m3 Chronic Toxicity
Prolonged inhalation of repairable crystalline silica may cause lung disease, silicosis, lung cancer, and other effects. Ecological Toxicity
Not Classified. No recognized unusual toxicity to plants or animals.
Calcium Oxide (1305-78-8): LC50 Fish: 1,070 mg/l (Exposure time: 96 h – Species: Cyprinus carpio [static])
Biodegradation / Bioaccumulation:
Biodegradation not applicable as cement is intended to remain long term in well and will be inert.
HSE-E-075-SUM Rev 4 Perth Basin Well Intervention Activities Environment Plan Summary
% Product in SDS Product Name Supplier Purpose Toxicity, Ecotoxicity & Biodegradability data** System Fluid Attached Cement (API Class G) Schlumberger Setting plugs to Toxicity - Constituent 1 (60-100%) 42.12% Yes D907 isolate hydrocarbon Fish Toxicity LC50 (96h): 41.2 mg/L (Oreochromis niloticus) producing reservoirs Toxicity - Constituent 2 (30-60%) from aquifers 96h LL0: 10,000 mg/L (Branchdanio rerio) Crustacean Toxicity 24h EL50: >10,000 mg/L (Daphnia magna) Na‐Al silicates: Fish Toxicity 96h LL0: 10,000 mg/L (Branchdanio rerio); Algae Toxicity 72h NOEL:10,000 mg/L (Scenedesmus subspicatus) Source: IUCLID 2,000 Addition of large amounts of cement to water may, however, cause a rise in pH and may, therefore be toxic to aquatic life under certain circumstances. Toxicity - Constituent 3 (5%) LD50 (Ingestion): > 5,000 mg/kg (rat) Toxicity - Constituent 4 (10%) TCLo (Inhalation): 194 g/m³/10 years intermittently (human) TDLo (Ingestion): 450 mg/kg/3 weeks intermittently (rat) Toxicity - Constituent 5 (5%) LD50 (Ingestion): 3,160 mg/kg (rat). Chronic Toxicity: Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms include a cough, shortness of breath, wheezing, non-specific chest illness, and reduced pulmonary function. Individuals with silicosis are predisposed to develop tuberculosis. Biodegradation/bioaccumulation: Biodegradation not applicable as cement is intended to remain long term in well and will be inert.
A-300L Baker Hughes Suspension agent Toxicity - Constituent 1 (60%) 0.22% Yes Silicon dioxide is a naturally occurring substance. Source: http://www.food.gov.uk/multimedia/pdfs/evm_silicon.pdf. (NOAEL) no observed adverse effect level = 7,500 mg/kg bw/day silicon dioxide for mice Toxicity - Constituent 2- (0.6%) Inhalation, mouse: LC50 = 1,200 mg/m3/2H; Inhalation, rat: LC50 = 2,300 mg/m3/2H; Oral, mouse: LD50 = 6,600 mg/kg; Oral, mouse: LD50 = 6,600 mg/kg; Oral, rat: LD50 = 4,090 mg/kg. Biodegradation/bioaccumulation: This product is not anticipated to cause adverse effects on animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate. Water: (69.4%) Natural product CD-31L Baker Hughes Dispersant Toxicity - Constituent 1 (20%) 1.12% Yes LC50: 135 ppm for Daphnia Magna Straus waterflea LD50: 2,000 mg/kg(Rat) Biodegradation/bioaccumulation: Possibly hazardous short-term degradation products are not likely. However, long term degradation products may arise. These products are sulfur oxides (SO2, SO3…), some metallic oxides.
HSE-E-075-SUM Rev 4 Perth Basin Well Intervention Activities Environment Plan Summary
% Product in SDS Product Name Supplier Purpose Toxicity, Ecotoxicity & Biodegradability data** System Fluid Attached Water: (80%) Natural product FL-66L Baker Hughes Cement fluid loss Toxicity - Constituent 1 (20%) Acrylic copolymer 2.24% Yes LD50 oral rat: 12,950 mg/kg. LD50 oral rabbit: 11,250 mg/kg. Biodegradation/bioaccumulation: Polyacrylamides are generally water-soluble, high molecular weight synthetic organic polymers that primarily interact with the clay fraction of soils. The degree of interaction depends on both the properties of the polymer and properties of the soil. For the most part, polyacrylamide is resistant to microbial attack, and its degradation is mainly through a physical breakdown. Polyacrylamide has been shown to be non-toxic to humans, animals, fish, and plants; the only concern has been the toxicity of its residual monomer (acrylamide) content, which is a known neurotoxin to humans. Polyacrylamide can also degrade to acrylamide under environmental conditions. The monomer degradable and does not accumulate in soils. Water: (80%) Natural product FP-9LS Baker Hughes Antifoaming agent Toxicity - Constituent 1 (60%) Isononanol 0.34% Yes LD50 oral rat: 3950 mg/kg LC0 Rat(male/female): > 0.21 mg/l / 7 h / vapour LD50 Rat(male/female): > 4,000 mg/kg dermal Biodegradation/bioaccumulation: Aerobic, Inoculum: Activated sludge Exposure time: 28 d Result: 79 % Readily biodegradable.
Method: (CO2; modif. Sturm test - 92/69/EEC part C.4-C) Bioconcentration factor (BCF): 15.2 Significant concentrations do not accumulate. The data are derived from the evaluations or test results achieved with similar products (conclusion by analogy). logKOC: 2.17 (Soil) Method: OECD TG 121 Water: (40%) Natural product R-21L Baker Hughes Cement retardant Toxicity - Constituent 1 (15%) 0.11% Yes LD50 oral rat >4,000 mg/Kg LC50 Rainbow Trout 7,300 ppm/48 h Toxicity - Constituent 2 (35%) LD50 oral rat >2,000 mg/Kg Biodegradation/bioaccumulation: Material is expected to biodegrade only very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability. Water: (55%) Natural product Calcium Chloride Newpark Weighting Agent Acute Toxicity: 0.09% Yes Drilling Fluids CALCIUM CHLORIDE ANHYDROUS as an ingredient (10043-52-4): LD50 (Ingestion): 1,000 mg/kg (rat)
HSE-E-075-SUM Rev 4 Perth Basin Well Intervention Activities Environment Plan Summary
% Product in SDS Product Name Supplier Purpose Toxicity, Ecotoxicity & Biodegradability data** System Fluid Attached LD50 (Intraperitoneal): 210 mg/kg (mouse) LD50 (Intravenous): 42 mg/kg (mouse) LD50 (Subcutaneous): 823 mg/kg (mouse) LDLo (Ingestion): 1,384 mg/kg (rabbit) LDLo (Intravenous): 150 mg/kg (guinea pig) LDLo (Subcutaneous): 249 mg/kg (cat) TDLo (Intravenous): 20 mg/kg/1 hour (woman) SODIUM CHLORIDE (7647-14-5): LC50 (Inhalation): > 42,000 mg/m3/1 hour (rat) LD50 (Ingestion): 3,000 mg/kg (rat) LD50 (Intraperitoneal): 2,602 mg/kg (mouse) LD50 (Intravenous): 645 mg/kg (mouse) LD50 (Skin): > 10,000 mg/kg (rabbit) LD50 (Subcutaneous): 3,000 mg/kg (mouse) LDLo (Ingestion): 8,000 mg/kg (rabbit) LDLo (Intravenous): 300 mg/kg (guinea pig) LDLo (Subcutaneous): 2,160 mg/kg (guinea pig) TDLo (Ingestion): 12,357 mg/kg (human) Biodegradation/bioaccumulation: Biodegradability does not pertain to inorganic substances. This product does not bioaccumulate.
Table 9c: Chemical List
Chemicals Name CAS number Mass fraction (%) Portland cement 65997-15-1 65.2% Customer Supplied Mix Water 7732-18-5 30.0% Crystalline silica, quartz 14808-60-7 3.43% Water in Products 7732-18-5 0.912% Humic acids, sodium salts, polymers with N,N-dimethyl-2- propenamide, sodium 2-methyl-2-[(1-oxo-2-propen- 473268-27-8 0.301% 1-yl)amino]-1- propanesulfonate (1:1) and 2-propenenitrile, sodium bisulfite- Sulfonated organic polymer 526203-62-3 0.0861% Rape Oil 8002-13-9 0.0680% Sodium Lignosulfonate 8061-51-6 0.0301% Monopropylene glycol monooleate 1330-80-9 0.00386% Aluminium stearate 637-12-7 0.000772% Sorbitan, monopalmitate 26266-57-9 0.000772% Contingency Volumes (Alternate Baker Hughes) Water 7732-18-5 56.72658 Portland cement 65997-15-1 31.59
HSE-E-075-SUM Rev 4 Perth Basin Well Intervention Activities Environment Plan Summary
Chemicals Name CAS number Mass fraction (%) Calcium Oxide 1305-78-8 2.106 Calcium Carbonate 1317-65-3 2.106 Gypsum 13397-24-5 4.212 Magnesium Oxide 1309-48-4 2.106 Silicon dioxide (colloidal) 69012-64-2 0.132 Na2O 1313-59-3 0.00132 Sodium Naphthalene Sulphonate 130-14-3 0.224 Acrylic copolymer 9003-06-9 0.448 Isononanol 27458-94-2 0.204 Sodium Lignosulphonate 8061-51-6 0.0165 Gluconic acid 526-95-4 0.0385 Calcium Chloride Anhydrous 10043-52-4 0.0873 Sodium Chloride 7647-14-5 0.0018 Total: 100.00% (excluding contingency)
HSE-E-075-SUM Rev 4 Perth Basin Well Intervention Activities Environment Plan Summary
Appendix 4 Safety Data Sheets - Cementing
HSE-E-075-SUM Rev 4
Product Name A-300L
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Supplier Name BAKER HUGHES PRESSURE PUMPING Address 108 Poole st , Welshpool , WA, AUSTRALIA, 6106 Telephone +61 8 9350 3800 Fax +61 8 9350 5453 Emergency 1800 988 778 Web Site http://www.bakerhughes.com
Synonym(s) A300L • BAKER HUGHES A-300L
Use(s) CEMENT ADDITIVE SDS Date 31 May 2011 2. HAZARDS IDENTIFICATION NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE UN No. None Allocated DG Class None Allocated Subsidiary Risk(s) None Allocated Packing Group None Allocated Hazchem Code None Allocated 3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient Formula CAS No. Content NON HAZARDOUS INGREDIENTS Not Available Not Available 100% 4. FIRST AID MEASURES Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. Advice to Doctor Treat symptomatically.
5. FIRE FIGHTING MEASURES Flammability Non flammable. May evolve toxic gases if strongly heated. Fire and No fire or explosion hazard exists. Explosion Extinguishing Prevent contamination of drains or waterways. Hazchem Code None Allocated
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Product Name A-300L
6. ACCIDENTAL RELEASE MEASURES Spillage If spilt (bulk), use personal protective equipment. Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place in suitable containers for disposal. Prevent spill entering drains or waterways. CAUTION: Spill site may be slippery. 7. STORAGE AND HANDLING Storage Store in a cool, dry, well ventilated area, removed from oxidising agents, acids and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas. 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION Exposure Stds No exposure standard(s) allocated.
Biological Limits No biological limit allocated.
Engineering Avoid inhalation. Use in well ventilated areas. Controls PPE Wear splash-proof goggles and PVC or rubber gloves. When using large quantities or where heavy contamination is likely, wear: coveralls.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance MILKY LIQUID Solubility (water) DISPERSIBLE Odour MILD ODOUR Specific Gravity 1.2 pH 10.5 % Volatiles NOT AVAILABLE Vapour Pressure NOT AVAILABLE Flammability NON FLAMMABLE Vapour Density NOT AVAILABLE Flash Point NOT RELEVANT Boiling Point 100°C Upper Explosion Limit NOT RELEVANT Melting Point 0°C Lower Explosion Limit NOT RELEVANT Evaporation Rate NOT AVAILABLE Autoignition Temperature NOT AVAILABLE Decomposition Temperature NOT AVAILABLE Partition Coefficient NOT AVAILABLE Viscosity NOT AVAILABLE 10. STABILITY AND REACTIVITY Chemical Stability Stable under recommended conditions of storage. Conditions to Avoid Avoid heat, sparks, open flames and other ignition sources. Material to Avoid Incompatible with oxidising agents and acids (eg. nitric acid). Contact with acids may cause product to form a gel. Hazardous May evolve toxic gases if heated to decomposition. Decomposition Products Hazardous Reactions Polymerization is not expected to occur.
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Product Name A-300L
11. TOXICOLOGICAL INFORMATION Health Hazard Low toxicity - low irritant. This product may present a hazard with direct eye contact or prolonged skin contact. Summary Chronic effects are not anticipated. Eye Low irritant. Contact may result in irritation, lacrimation and redness. Inhalation Low irritant. Over exposure may result in irritation of the nose and throat, with coughing. Skin Low irritant. Prolonged or repeated contact may result in mild irritation, rash and dermatitis. Ingestion Low toxicity. Ingestion of large quantities may result in nausea, vomiting and gastrointestinal irritation. Toxicity Data No LD50 data available for this product. 12. ECOLOGICAL INFORMATION Environment This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate.
13. DISPOSAL CONSIDERATIONS Waste Disposal For small amounts, absorb with sand or similar and dispose of to an approved landfill site. Contact the manufacturer for additional information. Ensure that appropriate personal protective equipment is used during disposal. Legislation Dispose of in accordance with relevant local legislation. 14. TRANSPORT INFORMATION
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE Shipping Name None Allocated UN No. None Allocated DG Class None Allocated Subsidiary Risk(s) None Allocated Packing Group None Allocated Hazchem Code None Allocated
15. REGULATORY INFORMATION Poison Schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP). AICS All chemicals listed on the Australian Inventory of Chemical Substances (AICS).
16. OTHER INFORMATION Additional ABBREVIATIONS: Information ACGIH - American Conference of Industrial Hygienists. ADG - Australian Dangerous Goods. BEI - Biological Exposure Indice(s). CAS# - Chemical Abstract Service number - used to uniquely identify chemical compounds. CNS - Central Nervous System. EC No - European Community Number. HSNO - Hazardous Substances and New Organisms. IARC - International Agency for Research on Cancer. mg/m³ - Milligrams per Cubic Metre. NOS - Not Otherwise Specified. pH - relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm - Parts Per Million. RTECS - Registry of Toxic Effects of Chemical Substances. STEL - Short Term Exposure Limit. SWA - Safe Work Australia. TWA - Time Weighted Average.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this ChemAlert report is provided as a guide only.
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Product Name A-300L
Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made. Report Status This document has been compiled by RMT on behalf of the manufacturer of the product and serves as the manufacturer's Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by the manufacturer or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS. Prepared By Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au
SDS Date31 May 2011 End of Report
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Product Name CD-31L
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Supplier Name BAKER HUGHES PRESSURE PUMPING Address 108 Poole st , Welshpool , WA, AUSTRALIA, 6106 Telephone +61 8 9350 3800 Fax +61 8 9350 5453 Emergency 1800 988 778 Web Site http://www.bakerhughes.com
Synonym(s) 100291 - ITEM NUMBER • 31L CD • BJ SERVICES CD-31L • CD 31L
Use(s) CEMENT ADDITIVE • DISPERSANT SDS Date 31 May 2011 2. HAZARDS IDENTIFICATION NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE UN No. None Allocated DG Class None Allocated Subsidiary Risk(s) None Allocated Packing Group None Allocated Hazchem Code None Allocated 3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient Formula CAS No. Content DISPERSANT Not Available Not Available Not Available SODIUM NAPHTHALENE SULPHONATE Not Available Not Available Not Available WATER H2O 7732-18-5 Not Available 4. FIRST AID MEASURES Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Advice to Doctor Treat symptomatically. First Aid Facilities Eye wash facilities should be available.
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Product Name CD-31L
5. FIRE FIGHTING MEASURES Flammability Non flammable. May evolve toxic gases if strongly heated. Fire and No fire or explosion hazard exists. Explosion Extinguishing Prevent contamination of drains or waterways. Hazchem Code None Allocated 6. ACCIDENTAL RELEASE MEASURES Spillage Contact emergency services where appropriate. Use personal protective equipment. Clear area of all unprotected personnel. Ventilate area where possible. Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place in suitable containers for disposal. Eliminate all ignition sources. 7. STORAGE AND HANDLING Storage Store in a cool, dry, well ventilated area, removed from oxidising agents, acids, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills. Large storage areas should have appropriate ventilation systems. Store below 4.4°C. Handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas. 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION Exposure Stds No exposure standard(s) allocated.
Biological Limits No biological limit allocated.
Engineering Avoid inhalation. Use in well ventilated areas. Controls PPE Wear splash-proof goggles and rubber or PVC gloves. When using large quantities or where heavy contamination is likely, wear: coveralls. Where an inhalation risk exists, wear: a Type A (Organic vapour) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance CLEAR DARK BROWN LIQUID Solubility (water) SOLUBLE Odour SLIGHT MOTH-BALL ODOUR Specific Gravity 1.0 (Approximately) pH 9.0 to 10.5 % Volatiles NOT AVAILABLE Vapour Pressure 18 mm Hg @ 20°C Flammability NON FLAMMABLE Vapour Density NOT AVAILABLE Flash Point NOT RELEVANT Boiling Point 87.8°C to 101.7°C Upper Explosion Limit NOT RELEVANT Melting Point 0°C (Approximately) Lower Explosion Limit NOT RELEVANT Evaporation Rate AS FOR WATER Autoignition Temperature NOT AVAILABLE Decomposition Temperature NOT AVAILABLE Partition Coefficient NOT AVAILABLE Viscosity NOT AVAILABLE
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Product Name CD-31L
10. STABILITY AND REACTIVITY Chemical Stability Stable under recommended conditions of storage. Conditions to Avoid Avoid heat, sparks, open flames and other ignition sources. Material to Avoid Incompatible with oxidising agents (eg. hypochlorites), acids (eg. nitric acid), heat and ignition sources. Hazardous May evolve toxic gases if heated to decomposition. Decomposition Products Hazardous Reactions Polymerization is not expected to occur. 11. TOXICOLOGICAL INFORMATION Health Hazard Low toxicity. This product has the potential to cause adverse health effects with direct eye contact, prolonged skin Summary contact or vapour inhalation in poorly ventilated areas. Use safe work practices to avoid eye or skin contact and vapour generation - inhalation. Eye Low irritant. Contact may result in irritation, lacrimation and redness. Inhalation Low irritant. Over exposure may result in irritation of the nose and throat, with coughing. Due to the low vapour pressure, an inhalation hazard is not anticipated with normal use. Skin Low irritant. Prolonged or repeated contact may result in mild irritation. Ingestion Low toxicity. Ingestion of large quantities may result in nausea, vomiting and gastrointestinal irritation. Toxicity Data No LD50 data available for this product. 12. ECOLOGICAL INFORMATION Environment Limited ecotoxicity data was available for this product at the time this report was prepared. Ensure appropriate measures are taken to prevent this product from entering the environment.
13. DISPOSAL CONSIDERATIONS Waste Disposal Dispose of to an approved landfill site. Contact the manufacturer for additional information. Legislation Dispose of in accordance with relevant local legislation. 14. TRANSPORT INFORMATION
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE Shipping Name None Allocated UN No. None Allocated DG Class None Allocated Subsidiary Risk(s) None Allocated Packing Group None Allocated Hazchem Code None Allocated
15. REGULATORY INFORMATION Poison Schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP). AICS All chemicals listed on the Australian Inventory of Chemical Substances (AICS).
16. OTHER INFORMATION Additional RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid Information exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
ABBREVIATIONS: ACGIH - American Conference of Industrial Hygienists. ADG - Australian Dangerous Goods. BEI - Biological Exposure Indice(s). CAS# - Chemical Abstract Service number - used to uniquely identify chemical compounds. CNS - Central Nervous System. EC No - European Community Number. HSNO - Hazardous Substances and New Organisms. IARC - International Agency for Research on Cancer.
Page 3 of 4 RMT Reviewed: 31 May 2011 Printed: 31 May 2011
Product Name CD-31L
mg/m³ - Milligrams per Cubic Metre. NOS - Not Otherwise Specified. pH - relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm - Parts Per Million. RTECS - Registry of Toxic Effects of Chemical Substances. STEL - Short Term Exposure Limit. SWA - Safe Work Australia. TWA - Time Weighted Average.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this ChemAlert report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made. Report Status This document has been compiled by RMT on behalf of the manufacturer of the product and serves as the manufacturer's Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by the manufacturer or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS. Prepared By Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au
SDS Date31 May 2011 End of Report
Page 4 of 4 RMT Reviewed: 31 May 2011 Printed: 31 May 2011 SAFETY DATA SHEET
CFR-8L
Revision Date: 24-Apr-2018 Revision Number: 21
1. Product Identifier & Identity for the Chemical
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the Globally Harmonised System of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goods according to the criteria of ADG.
1.1. Product Identifier Product Name CFR-8L
Other means of Identification Synonyms None Hazardous Material Number: HM005627
Recommended use of the chemical and restrictions on use Recommended Use Cement Dispersant Uses advised against No information available
Supplier's name, address and phone number Manufacturer/Supplier Halliburton Australia Pty. Ltd. 15 Marriott Road, Jandakot, WA 6164 Australia ACN Number: 009 000 775 Telephone Number: + 61 1 800 686 951 Fax Number: 61 (08) 9455 5300 E-mail Address [email protected]
Emergency phone number + 61 1 800 686 951 Global Incident Response Access Code: 334305 Contract Number: 14012
Australian Poisons Information Centre 24 Hour Service: - 13 11 26 Police or Fire Brigade: - 000 (exchange): - 1100
2. Hazard Identification
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the Globally Harmonised System of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goods according to the criteria of ADG.
Classification of the hazardous chemical Not classified
Label elements, including precautionary statements
Hazard Pictograms
Signal Word Not Hazardous
Hazard Statements: Not Classified
______Page 1 / 7 CFR-8L Revision Date: 24-Apr-2018 ______
Precautionary Statements
Prevention None Response None Storage None Disposal None
Contains Substances CAS Number Contains no hazardous substances in concentrations above NA cut-off values according to the competent authority
Other hazards which do not result in classification This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
For the full text of the H-phrases mentioned in this Section, see Section 16
3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w) GHS Classification - Australia Contains no hazardous substances in concentrations NA 60 - 100% Not classified above cut-off values according to the competent authority
4. First aid measures
Description of necessary first aid measures Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult. Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists. Skin Wash with soap and water. Get medical attention if irritation persists. Ingestion Under normal conditions, first aid procedures are not required.
Symptoms caused by exposure No significant hazards expected.
Medical Attention and Special Treatment Notes to Physician Treat symptomatically
5. Fire Fighting Measures
Suitable extinguishing equipment Suitable Extinguishing Media Water fog, carbon dioxide, foam, dry chemical. Extinguishing media which must not be used for safety reasons None known.
Specific hazards arising from the chemical Special exposure hazards in a fire Decomposition in fire may produce harmful gases.
Special protective equipment and precautions for fire fighters Special protective equipment for firefighters Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
______Page 2 / 7 CFR-8L Revision Date: 24-Apr-2018 ______
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid breathing vapors. Ensure adequate ventilation.
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.
7. Handling and storage
7.1. Precautions for safe handling Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Ensure adequate ventilation. Wash hands after use. Launder contaminated clothing before reuse. Use appropriate protective equipment. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities Storage Information Store away from oxidizers. Keep container closed when not in use. Other Guidelines No information available
8. Exposure Controls/Personal Protection
Control parameters - exposure standards, biological monitoring Exposure Limits Substances CAS Number Australia NOHSC ACGIH TLV-TWA Contains no hazardous substances in NA Not applicable Not applicable concentrations above cut-off values according to the competent authority
Appropriate engineering controls Engineering Controls Use in a well ventilated area.
Personal protective equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the selection and proper use of personal protective equipment should be determined by an industrial hygienist or other qualified professional based on the specific application of this product. Respiratory Protection Not normally necessary.
Hand Protection Nitrile gloves. Skin Protection Normal work coveralls. Eye Protection Wear safety glasses or goggles to protect against exposure. Other Precautions None known. Environmental Exposure Controls Do not allow material to contaminate ground water system
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties Physical State: Liquid Color Brown-black Odor: Characteristic Odor Threshold: No information available
______Page 3 / 7 CFR-8L Revision Date: 24-Apr-2018 ______Property Values Remarks/ - Method pH: 9 - 11.3 Freezing Point / Range -7 °C Melting Point / Range No data available Boiling Point / Range 100 °C / 212 °F Flash Point No data available Evaporation rate No data available Vapor Pressure < 18 mmHg Vapor Density No data available Specific Gravity 1.17 - 1.2 Water Solubility Soluble in water Solubility in other solvents No data available Partition coefficient: n-octanol/water No data available Autoignition Temperature No data available Decomposition Temperature No data available Viscosity No data available Explosive Properties No information available Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
10. Stability and Reactivity
10.1. Reactivity Not expected to be reactive. 10.2. Chemical stability Stable 10.3. Possibility of hazardous reactions Will Not Occur 10.4. Conditions to avoid None anticipated 10.5. Incompatible materials Strong oxidizers. 10.6. Hazardous decomposition products Oxides of sulfur.
11. Toxicological Information
Information on routes of exposure Principle Route of Exposure Eye or skin contact, inhalation.
Symptoms related to exposure Most Important Symptoms/Effects No significant hazards expected.
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation Contains no hazardous NA No data available No data available No data available substances in concentrations above cut-off values according to the competent authority
Immediate, delayed and chronic health effects from exposure Inhalation May cause mild respiratory irritation. Eye Contact May cause mechanical irritation to eye. Skin Contact None known.
______Page 4 / 7 CFR-8L Revision Date: 24-Apr-2018 ______Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% are chronic health hazards.
Exposure Levels No data available
Interactive effects None known.
Data limitations No data available
12. Ecological Information
Ecotoxicity
Substance Ecotoxicity Data Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to Toxicity to Invertebrates Microorganisms Contains no NA No information available No information available No information available No information available hazardous substances in concentrations above cut-off values according to the competent authority
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability Contains no hazardous substances in NA No information available concentrations above cut-off values according to the competent authority
12.3. Bioaccumulative potential
Substances CAS Number Log Pow Contains no hazardous substances in NA No information available concentrations above cut-off values according to the competent authority
12.4. Mobility in soil
Substances CAS Number Mobility Contains no hazardous substances in concentrations NA No information available above cut-off values according to the competent authority
12.6. Other adverse effects No information available Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors
______Page 5 / 7 CFR-8L Revision Date: 24-Apr-2018 ______
13. Disposal Considerations
Safe handling and disposal methods Disposal should be made in accordance with federal, state, and local regulations.
Disposal of any contaminated packaging Follow all applicable national or local regulations.
Environmental regulations Not applicable
14. Transport Information
Transportation Information Australia ADG UN Number Not restricted UN proper shipping name: Not restricted Transport Hazard Class(es): Not applicable Packing Group: Not applicable Environmental Hazards: Not applicable
IMDG/IMO UN Number Not restricted UN proper shipping name: Not restricted Transport Hazard Class(es): Not applicable Packing Group: Not applicable Environmental Hazards: Not applicable
IATA/ICAO UN Number Not restricted UN proper shipping name: Not restricted Transport Hazard Class(es): Not applicable Packing Group: Not applicable Environmental Hazards: Not applicable
Special precautions during transport None
HazChem Code None Allocated
15. Regulatory Information
Safety, health and environmental regulations specific for the product
International Inventories Australian AICS Inventory All components are listed on the AICS or are subject to a relevant exemption, permit, or assessment certificate. New Zealand Inventory of Product contains one or more components not listed on inventory. Chemicals EINECS (European Inventory of This product, and all its components, complies with EINECS Existing Chemical Substances) US TSCA Inventory Product contains one or more components not listed on the inventory. Canadian Domestic Substances List Product contains one or more components not listed on the inventory. (DSL)
Poisons Schedule number None Allocated
______Page 6 / 7 CFR-8L Revision Date: 24-Apr-2018 ______International Agreements Montreal Protocol - Ozone Depleting Substances: Does not apply. Stockholm Convention - Persistent Organic Pollutants: Does not apply Rotterdam Convention - Prior Informed Consent: Does not apply. Basel Convention - Hazardous Waste: Does not apply.
16. Other information
Date of preparation or review
Revision Date: 24-Apr-2018
Revision Note SDS sections updated: 2
Full text of H-Statements referred to under sections 2 and 3 None
Additional information For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Stewardship at 1-580-251-4335.
Key abreviations or acronyms used bw – body weight CAS – Chemical Abstracts Service EC50 – Effective Concentration 50% LC50 – Lethal Concentration 50% LD50 – Lethal Dose 50% LL50 – Lethal Loading 50% mg/kg – milligram/kilogram mg/L – milligram/liter NOEC – No Observed Effect Concentration OEL – Occupational Exposure Limit PBT – Persistent Bioaccumulative and Toxic ppm – parts per million STEL – Short Term Exposure Limit TWA – Time-Weighted Average vPvB – very Persistent and very Bioaccumulative h - hour mg/m3 - milligram/cubic meter mm - millimeter mmHg - millimeter mercury w/w - weight/weight d - day
Key literature references and sources for data www.ChemADVISOR.com/
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
______Page 7 / 7
CHEMALERT REPORT Full Report
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
1.1 Product identifier Product name CEMENT CLASS G Synonym(s) 100021 - PRODUCT CODE 1.2 Uses and uses advised against Use(s) CEMENT • MORTAR • OILFIELD APPLICATIONS 1.3 Details of the supplier of the safety data sheet Supplier name BAKER HUGHES PRESSURE PUMPING Address 108 Poole st, Welshpool, WA, Australia, 6106 Telephone +61 8 9350 3800 Fax +61 8 9350 5453 Email Not supplied Website http://www.bakerhughes.com 1.4 Emergency telephone number(s) Emergency 1800 988 778 2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA Risk phrases R37/38 Irritating to respiratory system and skin. R41 Risk of serious damage to eyes. Safety phrases S22 Do not breathe dust. S24/25 Avoid contact with skin and eyes. S37 Wear suitable gloves.
Other Hazards No information provided. 3. COMPOSITION/ INFORMATION ON INGREDIENTS 3.1 Substances / Mixtures Ingredient CAS number EC number Content PORTLAND CEMENT 65997-15-1 266-043-4 >60% CALCIUM OXIDE 1305-78-8 215-138-9 1 - 5% LIMESTONE (CALCIUM CARBONATE) 1317-65-3 215-279-6 1 - 5% GYPSUM 13397-24-5 603-783-2 5 - 10% MAGNESIUM OXIDE 1309-48-4 215-171-9 1 - 5%
4. FIRST AID MEASURES
Page 1 of 7 Reviewed: 26 Nov 2014 This report was compiled based on the SDS dated 05 Apr 2014 Printed: 03 Aug 2016
CHEMALERT REPORT Full Report
Product name CEMENT CLASS G
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. First aid facilities No information provided. 4.2 Most important symptoms and effects, both acute and delayed Irritating to the eyes, skin and respiratory system. Some Individuals may exhibit an allergic response upon exposure to this product, possibly due to the trace amounts of chromium present. Hexavalent chromium compounds are classified as carcinogenic to humans (IARC Group 1). 4.3 Immediate medical attention and special treatment needed Treat symptomatically. 5. FIREFIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire. 5.2 Special hazards arising from the substance or mixture Non flammable. May evolve toxic gases if strongly heated. 5.3 Advice for firefighters Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas. 5.4 Hazchem code None allocated 6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contact emergency services where appropriate. 6.2 Environmental precautions Prevent product from entering drains and waterways. 6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust. 6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal. 7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas. 7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from moisture, incompatible substances and foodstuffs. Ensure packages are adequately labelled, protected from physical damage and sealed when not in use. 7.3 Specific end use(s)
Page 2 of 7 Reviewed: 26 Nov 2014 This report was compiled based on the SDS dated 05 Apr 2014 Printed: 03 Aug 2016
CHEMALERT REPORT Full Report
Product name CEMENT CLASS G
No information provided. 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Substance Reference ppm mg/m³ ppm mg/m³ Calcium carbonate (Limestone, Marble, SWA (AUS) -- 10 -- -- Whiting) Calcium oxide SWA (AUS) -- 2 -- -- Gypsum (Calcium sulphate) SWA (AUS) -- 10 -- -- Magnesium oxide (fume) SWA (AUS) -- 10 -- -- Portland Cement SWA (AUS) -- 10 -- -- Biological limits No biological limit values have been entered for this product. 8.2 Exposure controls Engineering Controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended. PPE Eye/Face Wear dust-proof goggles. Hand Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator. At high dust levels, wear an Air-line respirator or a Full-face Class P3 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance GREY POWDER Odour ODOURLESS Odour Threshold NOT AVAILABLE pH NOT AVAILABLE Melting Point NOT RELEVANT Boiling Point NOT RELEVANT Flash Point NOT RELEVANT Evaporation Rate NOT AVAILABLE Flammability NON FLAMMABLE Upper Explosion Limit NOT RELEVANT Lower Explosion Limit NOT RELEVANT Vapour Pressure NOT AVAILABLE Vapour Density NOT AVAILABLE Solubility (water) SLIGHTLY SOLUBLE Partition Coefficient NOT AVAILABLE Autoignition Temperature NOT AVAILABLE Decomposition Temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive Properties NOT AVAILABLE
Page 3 of 7 Reviewed: 26 Nov 2014 This report was compiled based on the SDS dated 05 Apr 2014 Printed: 03 Aug 2016
CHEMALERT REPORT Full Report
Product name CEMENT CLASS G
Oxidising Properties NOT AVAILABLE Specific Gravity 3.15 9.2 Other information % Volatiles NOT AVAILABLE 10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information in sections 10.2 to 10.6. 10.2 Chemical stability Stable under recommended conditions of storage. 10.3 Possibility of hazardous reactions Polymerization is not expected to occur. 10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. 10.5 Incompatible materials Incompatible with oxidising agents (e.g. hypochlorites), ethanol, acids (e.g. hydrofluoric acid) and interhalogens (e.g. chlorine trifluoride). Water contact may increase product temperature 2°C to 3°C. 10.6 Hazardous decomposition products May evolve toxic gases if heated to decomposition. 11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Health hazard Slightly corrosive - irritant. This product has the potential to cause adverse health effects with over exposure. summary Use safe work practices to avoid eye or skin contact and inhalation. Once water is added, an inhalation hazard is not anticipated. Chronic respiratory effects are not anticipated with over exposure at high levels due to the immediate irritant and/or corrosive effects. Hexavalent chromium compounds are classified as carcinogenic to humans (IARC Group 1). Eye Corrosive - irritant. Contact may result in irritation, lacrimation, pain, redness, corneal burns and possible permanent damage. Severe irritant upon contact with powder/ dust. Inhalation Slightly corrosive - irritant. Over exposure may result in irritation of the nose and throat, coughing and bronchitis. Hexavalent chromium is reported to cause respiratory sensitisation, however due to the trace amount present, a hazard is not anticipated under normal conditions of use. Skin Slightly corrosive. Contact with powder or wetted form may result in rash and dermatitis. Some individuals may exhibit an allergic response upon exposure to cement, possibly due to trace amounts of chromium. Ingestion Slightly corrosive. Ingestion may result in burns to the mouth and throat, nausea, vomiting and abdominal pain. Ingestion is considered unlikely due to product form. Toxicity data LIMESTONE (CALCIUM CARBONATE) (1317-65-3) LD50 (Ingestion): > 5000 mg/kg (rat) GYPSUM (13397-24-5) TCLo (Inhalation): 194 g/m³/10 years intermittently (human) TDLo (Ingestion): 450 mg/kg/3 weeks intermittently (rat)
Page 4 of 7 Reviewed: 26 Nov 2014 This report was compiled based on the SDS dated 05 Apr 2014 Printed: 03 Aug 2016
CHEMALERT REPORT Full Report
Product name CEMENT CLASS G
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided. 12.2 Persistence and degradability No information provided. 12.3 Bioaccumulative potential No information provided. 12.4 Mobility in soil No information provided. 12.5 Results of PBT and vPvB assessment No information provided. 12.6 Other adverse effects No information provided. 13. DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Waste disposal Reuse or recycle where possible. Alternatively, ensure product is covered with moist soil to prevent dust generation and dispose of to an approved landfill site. Contact the manufacturer/supplier for additional information (if required). Legislation Dispose of in accordance with relevant local legislation. 14. TRANSPORT INFORMATION
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
Land Transport Sea Transport Air Transport (ADG) (IMDG/IMO) (IATA/ICAO)
14.1 UN number None Allocated None Allocated None Allocated 14.2 UN proper shipping name None Allocated None Allocated None Allocated 14.3 Transport hazard classes DG Class None Allocated None Allocated None Allocated Subsidiary risk(s) None Allocated None Allocated None Allocated 14.4 Packing group None Allocated None Allocated None Allocated 14.5 Environmental hazards None Allocated 14.6 Special precautions for user Hazchem Code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Xi - Irritant
Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
15.2 Chemical safety assessment No information provided.
Page 5 of 7 Reviewed: 26 Nov 2014 This report was compiled based on the SDS dated 05 Apr 2014 Printed: 03 Aug 2016
CHEMALERT REPORT Full Report
Product name CEMENT CLASS G
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
CEMENT CONTACT DERMATITIS - Individuals using wet cement, mortar, grout or concrete could be at risk of developing cement dermatitis. Symptoms of exposure include itchy, tender, swollen, hot, cracked or blistering skin with the potential for sensitisation. The dermatitis is due to the presence of soluble (hexavalent) chromium.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made. Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Report Status This ChemAlert report has been independently compiled by RMT's scientific department utilising the original Safety Data Sheet ('SDS') for the product provided to RMT by the manufacturer. The information is based on the latest chemical and toxicological research and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. It is an independent collation by RMT of information obtained from the original SDS for this product. Its content has not been authorised or verified by the manufacturer / distributor of the chemical to which it relates.
Page 6 of 7 Reviewed: 26 Nov 2014 This report was compiled based on the SDS dated 05 Apr 2014 Printed: 03 Aug 2016
CHEMALERT REPORT Full Report
Product name CEMENT CLASS G
This ChemAlert report does not constitute the manufacturer's original SDS and is not intended to be a replacement for same. It is provided to subscribers of ChemAlert as a reference tool only, is not all-inclusive and does not represent any guarantee as to the properties of the product. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer.
While RMT has taken all due care to include accurate and up-to-date information in this ChemAlert report, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this ChemAlert report. Prepared By Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au
Last Reviewed:26 Nov 2014 Date Printed:03 Aug 2016 Based on SDS dated:05 Apr 2014
End of Report
Page 7 of 7 Reviewed: 26 Nov 2014 This report was compiled based on the SDS dated 05 Apr 2014 Printed: 03 Aug 2016 Portland Cement - Dry Powder Blend
Safety Data Sheet QUICK IDENTIFIER (See Section 1 Product Name)
SECTION 1- IDENTIFICATION OF PRODUCT AND COMPANY
Product: Export NeoSlurry & NeoSuperSlurry Systems, P/Ns: E0105-350-017, E0105-450-017 & E0105-300-017
5 gallon batch of cement slurry for dump Application: bailers
Manufacturer’s NeoProducts, LLC
name:
Address: 1201 Dealers Ave. Emergency Telephone #: 504-731-1011
City, State, Zip: Harahan, LA 70123 e-mail: [email protected]
Signature of After hours calls will be answered by answering service.
person
responsible for preparation Date Prepared: May 2019
(Optional):
SECTION 2- HAZARD IDENTIFICATION
Fire: This preparation is not flammable.
Health: Potentially hazardous during normal handling and use as instructed.
Environment: No known hazards.
Other Hazards: CAUTION! – ACUTE HEALTH HAZZARD This dry powder blend contains crystalline silica and quartz. May cause eye and respiratory irritation.
DANGER! – CHRONIC HEALTH HAZZARD This dry powder blend contains crystalline silica and quartz. Breathing crystalline silica can cause lung disease including silicosis and lung cancer. Crystalline silica has also been associated with scleroderma and kidney disease.
This product contains quartz, cristobalite, and/or tridymite, which may become airborne without a visible cloud. Use only with adequate ventilation to keep exposures below recommended exposure limits. Wear a NIOSH certified, European Standard EN 149 or equivalent respirator when using this product. Review the Material Safety Data Sheet (MSDS) for this product, which has been provided to your employer.
Pictograms:
SIGNAL WORD:...... DANGER!
GHS HAZARD AND PRECAUTIONARY STATEMENTS: H303 H313 H333: May be harmful if swallowed, in contact with skin or if inhaled P101+102+103: If medical advice is needed, have product container or label at hand. Keep out of the reach of children. Read label before use. P202+270+280+281: Do not handle until all safety precautions have been read and understood. Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required.
SECTION 3- COMPOSITION/INFORMATION ON INGREDIENTS
Component(s) % OPT. Average Average CAS No. [chemical and common name(s)] (inhalable dust) (respirable dust)
Portland Cement #2104 60.0 – 65.0 wgt % 10.0 mg/m3 4 mg/m3 65997-15-1
Silica Sand #2162 30.0 – 35.0 wgt % 0.3mg/m3 N/A 14808-60-6
Magnesium Oxide #2151 0 – 6.0 wgt % 10.0mg/m3 4mg/m3 1309-48-4
Suspension Agent #2099 0.50 – 3.0 wgt % N/A N/A 103115-52-2
Friction Reducer #2105 0.25 wgt % N/A N/A 9084-06-4
Cement Slurry Retarder #2117 1.0 – 4.0 wgt % N/A N/A 8061-51-6
Symbol(s): Xi, Xn
Risk Phrases: R36, R37, R38, R40
Safety Phrases: S22, S25, S36/37/39, S38
SECTION 4- FIRST AID MEASURES
Inhalation: Remove from area to fresh air.
Ingestion: First aid procedures are not required.
Skin: Wash with soap and water.
Eyes: Flush with plenty of water for at least 15 minutes.
SECTION 5- FIRE FIGHTING MEASURES
Extinguishing media: Product does not burn.
Special fire fighting precautions: None. Product does not burn.
Unusual fire and explosion hazards: No fire hazards.
SECTION 6- ACCIDENTAL RELEASE MEASURES
Personal precautions: Wear dust/mist respirator, work gloves and dust proof goggles.
Environmental: No environmental hazards reported.
Spillage: Use protective equipment, avoid creating or inhaling dust, sweep up and attempt to reuse product if not contaminated. Prevent entry into drains, sewers and watercourses.
SECTION 7- HANDLING AND STORAGE
Avoid contact with skin and eyes. Wear Approved work gloves, dust proof goggles and dust/mist respirator. Avoid creating dust. Store in dry location in original container. Use only as instructed.
SECTION 8- EXPOSURE CONTROLS/ PERSONAL PROTECTION
Engineering controls: Use in well ventilated area.
Respiratory protection: Use approved dust/mist respirator.
Hand protection: Use normal work gloves.
Skin protection: Normal work coveralls.
Eye protection: Use dust proof goggles.
SECTION 9- PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Color: Odor: PH: Reactivity in Water:
Solid Gray Odorless Not Determined N/A
Vapor Density Solubility in Water Vapor Pressure Specific Gravity @ Flammable Limits in
(Air=1): (g/100ml): (mm HG): 20C (H2O=1): Air% by Volume:
Not Determined 0.5 Not Determined 3.15 Not Determined
Flash Point: LEL Lower: LEL Upper: Melting Point: Boiling Point:
Not Determined N/A N/A N/A Not Determined
SECTION 10- STABILITY AND REACTIVITY
Stability Data: Hazardous Conditions to avoid: Incompatibility Hazardous
Polymerization: (Materials to avoid): Decomposition or
Byproducts:
Stable Will not occur Avoid contact with water None known None known
SECTION 11- TOXICOLOGICAL INFORMATION
Principle route of exposure: Eye or Skin contact, Inhalation.
Inhalation: This dry powder blend contains crystalline silica and quartz. Inhaled crystalline silica in
the form of quartz or cristobalite from occupational sources is carcinogenic to humans
(IARC, Group 1). There is sufficient evidence in experimental animals for the
carcinogenicity of tridymite (IARC, Group 2A).
This dry powder blend contains crystalline silica and quartz. Breathing silica dust may
cause irritation of the nose, throat and respiratory passages. Breathing silica may cause
noticeable injury or illness even through permanent lung damage may be occurring.
Inhalation of dust may also have serious chronic health effects (See “Chronic Effects /
Carcinogenicity” subsection below).
Skin Contact: Wet cement can dry skin and cause Alkali burns.
Eye Contact: Dust can irritate eyes.
Ingestion: No harmful affects known.
Medical conditions aggravated by exposure: Dermatitis
Silicosis: Excessive inhalation of respirable crystalline silica dust may
Chronic effects/ Carcinogenicity: cause a progressive, disabling and sometime-fatal lung disease called
silicosis. Symptoms include cough, shortened of breath, wheezing, non-
specific chest illness, and reduced pulmonary function. This disease is
exacerbated by smoking. Individuals will silicosis are predisposed to
develop tuberculosis.
Cancer Status: The International Agency for Research on Cancer (IARC)
has determined that crystalline silica inhaled in the form of quartz or
crystallite from occupational sources can cause lung cancer in humans
(Group 1 – carcinogenic to humans) and has determined that there is
sufficient evidence in experimental animals for the carcinogenicity of
tridymite (Group 2A – possible carcinogen to humans). Refer to IARC
Monograph 68, Silica, Some Silicates and Organic Fibers (June 1997) in
conjunction with the use of these minerals. The National Toxicology
Program classifies respirable crystalline silica as “Known to be a human th carcinogen”. Refer to the 9 Report of Carcinogens (2000). The
American Conference of Governmental Industrial Hygienists (ACGIH)
classifies crystalline silica, quartz, as a suspected human carcinogen
(A2).
There is some evidence that breathing respirable crystalline silica or the
disease silicosis is associated with an increased incidence of significant
endpoints such as acleroderma (an immune system disorder manifested
by scarring of the lungs, skin, and other internal organs) and kidney
disease.
This dry powder blend contains quartz, crystalline, silica and quartz. For
Other Information further information consult “Adverse Effects of Crystalline Silica
Exposure” published by the American Journal of Respiratory and Critical
Care Medicine, Volume 155, pages 71-768 (1997).
Toxicity Tests/ Carcinogenicity: This dry powder blend contains quartz, crystalline, silica and quartz.
Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibers
(June 1997).
SECTION 12- ECOLOGICAL INFORMATION
Mobility (water/air/soil): Not Determined
Persistence/ Degradability: Not Applicable
Bio-Accumulation: Not Determined
Aquatic Toxicity: Not Determined
SECTION 13- DISPOSAL CONSIDERATIONS
Disposal Method: Consult Federal, State or Local regulations.
Contaminated Packaging: Follow all applicable national or local regulations.
SECTION 14- TRANSPORT INFORMATION
NO SPECIAL PRECAUTIONS NECESSARY
SECTION 15- REGULATORY INFORMATION
Hazardous Ingredients: None
Symbol(s): Xi , Xn
Risk Phrases:
R36 Irritating to eyes.
R37 Irritating to Respiratory System.
R38 Irritating to Skin. R40 Limited evidence of a carcinogenic effect. (Lab test results on silica sand have shown limited evidence of a carcinogenic effect.)
Safety Phrases:
S22 Do not breathe dust.
S25 Avoid contact with eyes.
S36/37/39 Wear suitable protective clothing, gloves, and eye/face protection.
S38 In case of insufficient ventilation, wear suitable respiratory equipment.
SECTION 16- ADDITIONAL INFORMATION
Please read the Safety Data Sheet before using this or any NeoProducts items. This product is intended for the stated application only. Do not use this product for any other application without first obtaining guidance from an approved NeoProducts employee beforehand.
If this product is for resale, make sure the purchaser receives a copy of this safety data sheet upon acceptance of this preparation. Make sure the employees of your company are aware of the hazards, both chronic and acute, before allowing them to use this product.
The information contained in this Safety Data Sheet is believed to be correct and reflects our best professional judgment. Because it is impossible to anticipate every condition under which this product will be used, this Safety Data Sheet shall only be used as a guide. It is imperative that each user of this product determines its suitability for his particular application and comply with all environmental and workplace regulations.
HMIS: HEALTH 1 FLAMMABILITY 0 REACTIVITY 0 PERSONAL PROTECTION B
*HMIS®HAZARD INDEX: 0=Minimal Hazard, 1=Slight Hazard, 2=Moderate Hazard, 3=Serious Hazard, 4=Severe Hazard. HMIS® rating involves data interpretations that may vary from company to company. They are intended only for rapid, general identification of the magnitude of the specific hazard. To deal adequately with the safe handling of this material, all the information contained in this SDS and product label must be considered.
REVISION STATEMENT: Changes have been made throughout this Safety Data Sheet (SDS). Please read the entire document. Prepared according to the OSHA Hazard Communication Standard (29 CFR 1910.1200) and The Globally Harmonized System of Classification and Labeling of Chemicals (GHS) by the Company Health and Risk Assessment Unit. DISCLAIMER: Although the information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed to be correct as of the date hereof, the Company makes no representations as to the completeness or accuracy thereof. Information is supplied upon the condition that the persons receiving this Safety Data Sheet (SDS) will make their own determination as to its suitability for their intended purposes prior to use. Since the product is within the exclusive control of the user, it is the user's obligation to determine the conditions of safe use of this product. Such conditions should comply with all Federal and State Regulations concerning the Product. It must be recognized that the physical and chemical properties of any product may not be fully understood and that new, possibly hazardous products may arise from reactions between chemicals. The information given in this data sheet is based on our present knowledge and shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH INFORMATION REFERS. ***This is the last page of this SDS***
Product Name FL-66L
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Supplier Name BAKER HUGHES PRESSURE PUMPING Address 108 Poole st , Welshpool , WA, AUSTRALIA, 6106 Telephone +61 8 9350 3800 Fax +61 8 9350 5453 Emergency 1800 988 778 Web Site http://www.bakerhughes.com
Synonym(s) 488270, 488273 - ITEM NUMBER • BJ SERVICES FL-66L • FL - 66L
Use(s) CEMENT FLUID LOSS SDS Date 31 May 2011 2. HAZARDS IDENTIFICATION NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE UN No. None Allocated DG Class None Allocated Subsidiary Risk(s) None Allocated Packing Group None Allocated Hazchem Code None Allocated 3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient Formula CAS No. Content NON HAZARDOUS INGREDIENTS Not Available Not Available 100% 4. FIRST AID MEASURES Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. Advice to Doctor Treat symptomatically.
5. FIRE FIGHTING MEASURES Flammability Non flammable. May evolve toxic gases if strongly heated. Fire and Treat as per requirements for Surrounding Fires: Evacuate area and contact emergency services. Remain upwind Explosion and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas. Extinguishing Prevent contamination of drains or waterways. Hazchem Code None Allocated
Page 1 of 4 RMT Reviewed: 31 May 2011 Printed: 31 May 2011
Product Name FL-66L
6. ACCIDENTAL RELEASE MEASURES Spillage Use personal protective equipment. Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place in suitable containers for disposal. CAUTION: Spill site may be slippery. 7. STORAGE AND HANDLING Storage Store in a cool, dry, well ventilated area, removed from foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas. 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION Exposure Stds No exposure standard(s) allocated.
Biological Limits No biological limit allocated.
Engineering Avoid inhalation. Use in well ventilated areas. Controls PPE Wear splash-proof goggles and rubber or neoprene or PVC gloves. When using large quantities or where heavy contamination is likely, wear: coveralls.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance BROWN LIQUID Solubility (water) SOLUBLE Odour SLIGHT ODOUR Specific Gravity 1.06 pH 7 % Volatiles NOT AVAILABLE Vapour Pressure NOT AVAILABLE Flammability NON FLAMMABLE Vapour Density NOT AVAILABLE Flash Point NOT RELEVANT Boiling Point NOT AVAILABLE Upper Explosion Limit NOT RELEVANT Melting Point NOT AVAILABLE Lower Explosion Limit NOT RELEVANT Evaporation Rate NOT AVAILABLE Autoignition Temperature NOT AVAILABLE Decomposition Temperature NOT AVAILABLE Partition Coefficient NOT AVAILABLE Viscosity NOT AVAILABLE 10. STABILITY AND REACTIVITY Chemical Stability Stable under recommended conditions of storage. Conditions to Avoid Avoid heat, sparks, open flames and other ignition sources. Material to Avoid Compatible with most commonly used materials. Hazardous May evolve toxic gases if heated to decomposition. Decomposition Products Hazardous Reactions Polymerization is not expected to occur.
Page 2 of 4 RMT Reviewed: 31 May 2011 Printed: 31 May 2011
Product Name FL-66L
11. TOXICOLOGICAL INFORMATION Health Hazard Low toxicity - low irritant. Use safe work practices to avoid eye or skin contact and inhalation. Due to the low Summary vapour pressure of this product, an inhalation hazard is not anticipated with normal use. Eye Low irritant. Contact may result in irritation, lacrimation and redness. Inhalation Low irritant. Over exposure may result in irritation of the nose and throat, with coughing. Skin Low irritant. Prolonged or repeated contact may result in mild irritation, rash and dermatitis. Ingestion Low toxicity. Ingestion of large quantities may result in nausea, vomiting and gastrointestinal irritation. Toxicity Data No LD50 data available for this product. 12. ECOLOGICAL INFORMATION Environment This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate.
13. DISPOSAL CONSIDERATIONS Waste Disposal Solutions: Cover with sodium carbonate (soda ash), lime or similar alkali to ensure pH greater than 8.5. Collect precipitated solids in sealable containers and label accordingly. Solids: Dampen if necessary and avoid dust generation. Collect solids and store in sealable labelled containers. Absorb with soil and contact the manufacturer for disposal instructions. Legislation Dispose of in accordance with relevant local legislation. 14. TRANSPORT INFORMATION
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE Shipping Name None Allocated UN No. None Allocated DG Class None Allocated Subsidiary Risk(s) None Allocated Packing Group None Allocated Hazchem Code None Allocated
15. REGULATORY INFORMATION Poison Schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP). AICS All chemicals listed on the Australian Inventory of Chemical Substances (AICS).
16. OTHER INFORMATION Additional ABBREVIATIONS: Information ACGIH - American Conference of Industrial Hygienists. ADG - Australian Dangerous Goods. BEI - Biological Exposure Indice(s). CAS# - Chemical Abstract Service number - used to uniquely identify chemical compounds. CNS - Central Nervous System. EC No - European Community Number. HSNO - Hazardous Substances and New Organisms. IARC - International Agency for Research on Cancer. mg/m³ - Milligrams per Cubic Metre. NOS - Not Otherwise Specified. pH - relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm - Parts Per Million. RTECS - Registry of Toxic Effects of Chemical Substances. STEL - Short Term Exposure Limit. SWA - Safe Work Australia. TWA - Time Weighted Average.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:
Page 3 of 4 RMT Reviewed: 31 May 2011 Printed: 31 May 2011
Product Name FL-66L
The recommendation for protective equipment contained within this ChemAlert report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made. Report Status This document has been compiled by RMT on behalf of the manufacturer of the product and serves as the manufacturer's Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by the manufacturer or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS. Prepared By Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au
SDS Date31 May 2011 End of Report
Page 4 of 4 RMT Reviewed: 31 May 2011 Printed: 31 May 2011
Product Name FP-9L
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Supplier Name BAKER HUGHES PRESSURE PUMPING Address 108 Poole st , Welshpool , WA, AUSTRALIA, 6106 Telephone +61 8 9350 3800 Fax +61 8 9350 5453 Emergency 1800 988 778 Web Site http://www.bakerhughes.com
Synonym(s) BAKER HUGHES FP-9L • FP 9L
Use(s) ANTIFOAMING AGENT SDS Date 17 May 2011 2. HAZARDS IDENTIFICATION CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA RISK PHRASES R36/37/38 Irritating to eyes, respiratory system and skin. SAFETY PHRASES S36/37 Wear suitable protective clothing and gloves. S46 If swallowed, contact a doctor or Poisons Information Centre immediately and show container or label.
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE UN No. None Allocated DG Class None Allocated Subsidiary Risk(s) None Allocated Packing Group None Allocated Hazchem Code None Allocated 3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient Formula CAS No. Content ISONONANOL C9-H20-O 27458-94-2 >60% 4. FIRST AID MEASURES Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. Advice to Doctor Treat symptomatically. First Aid Facilities Eye wash facilities and safety shower should be available.
Page 1 of 4 RMT Reviewed: 17 May 2011 Printed: 17 May 2011
Product Name FP-9L
5. FIRE FIGHTING MEASURES Flammability Combustible. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Fire and Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind Explosion and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas. Extinguishing Dry agent, carbon dioxide or foam. Prevent contamination of drains or waterways. Hazchem Code None Allocated 6. ACCIDENTAL RELEASE MEASURES Spillage Use personal protective equipment. Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place in suitable containers for disposal. CAUTION: Spill site may be slippery. 7. STORAGE AND HANDLING Storage Store in a cool, dry, well ventilated area, removed from oxidising agents, acids, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Large storage areas should have appropriate ventilation systems. Store as a Class C1 Combustible Liquid (AS1940). Handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas. 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION Exposure Stds No exposure standard(s) allocated.
Biological Limits No biological limit allocated.
Engineering Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is Controls recommended. PPE Wear splash-proof goggles and rubber or PVC gloves. When using large quantities or where heavy contamination is likely, wear: coveralls. Where an inhalation risk exists, wear: a Type A (Organic vapour) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance CLEAR COLOURLESS TO LIGHT Solubility (water) INSOLUBLE AMBER COLOURED LIQUID Odour MILD ODOUR Specific Gravity 0.98 to 1.0 pH NOT AVAILABLE % Volatiles NOT AVAILABLE Vapour Pressure NOT AVAILABLE Flammability CLASS C1 COMBUSTIBLE Vapour Density NOT AVAILABLE Flash Point 105°C Boiling Point > 200°C Upper Explosion Limit 6.0 % Melting Point NOT AVAILABLE Lower Explosion Limit 0.9 % Evaporation Rate NOT AVAILABLE Autoignition Temperature NOT AVAILABLE Decomposition Temperature NOT AVAILABLE Partition Coefficient NOT AVAILABLE Viscosity NOT AVAILABLE
Page 2 of 4 RMT Reviewed: 17 May 2011 Printed: 17 May 2011
Product Name FP-9L
10. STABILITY AND REACTIVITY Chemical Stability Stable under recommended conditions of storage. Conditions to Avoid Avoid heat, sparks, open flames and other ignition sources. Material to Avoid Incompatible with oxidising agents (eg. hypochlorites), acids (eg. nitric acid), heat and ignition sources. Hazardous May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Decomposition Products Hazardous Reactions Polymerization is not expected to occur. 11. TOXICOLOGICAL INFORMATION Health Hazard Low to moderate toxicity - irritant. This product has the potential to cause adverse health effects with over Summary exposure. Use safe work practices to avoid eye or skin contact and inhalation. Over exposure may result in central nervous system (CNS) effects. Eye Irritant. Contact may result in irritation, lacrimation, pain, redness and conjunctivitis. May result in burns with prolonged contact. Inhalation Irritant. Over exposure may result in irritation of the nose and throat, coughing and headache. High level exposure may result in nausea, dizziness and drowsiness. Skin Irritant. Contact may result in drying and defatting of the skin, rash and dermatitis. May be absorbed through skin with harmful effects. Ingestion Low to moderate toxicity. Ingestion may result in nausea, vomiting, abdominal pain, diarrhoea, dizziness and drowsiness. Aspiration may result in chemical pneumonitis and pulmonary oedema. Toxicity Data No LD50 data available for this product. 12. ECOLOGICAL INFORMATION Environment Limited ecotoxicity data was available for this product at the time this report was prepared. Ensure appropriate measures are taken to prevent this product from entering the environment.
13. DISPOSAL CONSIDERATIONS Waste Disposal For small amounts absorb with sand, vermiculite or similar and dispose of to an approved landfill site. Contact the manufacturer for additional information if larger amounts are involved. Prevent contamination of drains and waterways as aquatic life may be threatened and environmental damage may result. Legislation Dispose of in accordance with relevant local legislation. 14. TRANSPORT INFORMATION
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE Shipping Name None Allocated UN No. None Allocated DG Class None Allocated Subsidiary Risk(s) None Allocated Packing Group None Allocated Hazchem Code None Allocated
15. REGULATORY INFORMATION Poison Schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP). AICS All chemicals listed on the Australian Inventory of Chemical Substances (AICS).
16. OTHER INFORMATION Additional National Industrial Chemicals Notification and Assessment (NICNAS) Registration number: 2475. Information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
WORK PRACTICES - SOLVENTS: Organic solvents may present both a health and flammability hazard. It is recommended that engineering controls should be adopted to reduce exposure where practicable (for example, if using indoors, ensure explosion proof extraction ventilation is available). Flammable or combustible liquids with Page 3 of 4 RMT Reviewed: 17 May 2011 Printed: 17 May 2011
Product Name FP-9L
explosive limits have the potential for ignition from static discharge. Refer to AS 1020 (The control of undesirable static electricity) and AS 1940 (The storage and handling of flammable and combustible liquids) for control procedures.
ABBREVIATIONS: ACGIH - American Conference of Industrial Hygienists. ADG - Australian Dangerous Goods. BEI - Biological Exposure Indice(s). CAS# - Chemical Abstract Service number - used to uniquely identify chemical compounds. CNS - Central Nervous System. EC No - European Community Number. HSNO - Hazardous Substances and New Organisms. IARC - International Agency for Research on Cancer. mg/m³ - Milligrams per Cubic Metre. NOS - Not Otherwise Specified. pH - relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm - Parts Per Million. RTECS - Registry of Toxic Effects of Chemical Substances. STEL - Short Term Exposure Limit. SWA - Safe Work Australia. TWA - Time Weighted Average.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this ChemAlert report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made. Report Status This document has been compiled by RMT on behalf of the manufacturer of the product and serves as the manufacturer's Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by the manufacturer or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS. Prepared By Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au
SDS Date17 May 2011 End of Report
Page 4 of 4 RMT Reviewed: 17 May 2011 Printed: 17 May 2011 SAFETY DATA SHEET
HALAD® 413L CEMENT ADDITIVE
Revision Date: 07-May-2018 Revision Number: 26
1. Product Identifier & Identity for the Chemical
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the Globally Harmonised System of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goods according to the criteria of ADG.
1.1. Product Identifier Product Name HALAD® 413L CEMENT ADDITIVE
Other means of Identification Synonyms None Hazardous Material Number: HM000824
Recommended use of the chemical and restrictions on use Recommended Use Fluid Loss Additive Uses advised against No information available
Supplier's name, address and phone number Manufacturer/Supplier Halliburton Australia Pty. Ltd. 15 Marriott Road, Jandakot, WA 6164 Australia ACN Number: 009 000 775 Telephone Number: + 61 1 800 686 951 Fax Number: 61 (08) 9455 5300 E-mail Address [email protected]
Emergency phone number + 61 1 800 686 951 Global Incident Response Access Code: 334305 Contract Number: 14012
Australian Poisons Information Centre 24 Hour Service: - 13 11 26 Police or Fire Brigade: - 000 (exchange): - 1100
2. Hazard Identification
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the Globally Harmonised System of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goods according to the criteria of ADG.
Classification of the hazardous chemical Not classified
Label elements, including precautionary statements
Hazard Pictograms
Signal Word Not Hazardous
Hazard Statements: Not Classified
______Page 1 / 8 HALAD® 413L CEMENT ADDITIVE Revision Date: 07-May-2018 ______
Precautionary Statements
Prevention None Response None Storage None Disposal None
Contains Substances CAS Number Contains no hazardous substances in concentrations above NA cut-off values according to the competent authority
Other hazards which do not result in classification This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
For the full text of the H-phrases mentioned in this Section, see Section 16
3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w) GHS Classification - Australia Contains no hazardous substances in concentrations NA 60 - 100% Not classified above cut-off values according to the competent authority
4. First aid measures
Description of necessary first aid measures Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult. Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists. Skin Wash with soap and water. Get medical attention if irritation persists. Ingestion Under normal conditions, first aid procedures are not required.
Symptoms caused by exposure No significant hazards expected.
Medical Attention and Special Treatment Notes to Physician Treat symptomatically
5. Fire Fighting Measures
Suitable extinguishing equipment Suitable Extinguishing Media All standard fire fighting media Extinguishing media which must not be used for safety reasons None known.
Specific hazards arising from the chemical Special exposure hazards in a fire Decomposition in fire may produce harmful gases.
Special protective equipment and precautions for fire fighters Special protective equipment for firefighters Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
______Page 2 / 8 HALAD® 413L CEMENT ADDITIVE Revision Date: 07-May-2018 ______
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid breathing vapors.
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.
7. Handling and storage
7.1. Precautions for safe handling Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after use. Launder contaminated clothing before reuse. Use appropriate protective equipment. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities Storage Information Store away from oxidizers. Product has a shelf life of 24 months. Other Guidelines No information available
8. Exposure Controls/Personal Protection
Control parameters - exposure standards, biological monitoring Exposure Limits Substances CAS Number Australia NOHSC ACGIH TLV-TWA Contains no hazardous substances in NA Not applicable Not applicable concentrations above cut-off values according to the competent authority
Appropriate engineering controls Engineering Controls Use in a well ventilated area.
Personal protective equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the selection and proper use of personal protective equipment should be determined by an industrial hygienist or other qualified professional based on the specific application of this product. Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational exposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection of and instruction on using all personal protective equipment, including respirators, should be performed by an Industrial Hygienist or other qualified professional. Not normally needed. But if significant exposures are possible then the following respirator is recommended: Dust/mist respirator. (N95, P2/P3) Hand Protection Normal work gloves. Skin Protection Normal work coveralls. Eye Protection Wear safety glasses or goggles to protect against exposure. Other Precautions None known. Environmental Exposure Controls Do not allow material to contaminate ground water system
9. Physical and Chemical Properties
______Page 3 / 8 HALAD® 413L CEMENT ADDITIVE Revision Date: 07-May-2018 ______
9.1. Information on basic physical and chemical properties Physical State: Liquid Color Brown-black Odor: Sweet Odor Threshold: No information available
Property Values Remarks/ - Method pH: 7.5 Freezing Point / Range No data available Melting Point / Range No data available Boiling Point / Range No data available Flash Point No data available Evaporation rate No data available Vapor Pressure No data available Vapor Density No data available Specific Gravity 1.1 Water Solubility Miscible with water Solubility in other solvents No data available Partition coefficient: n-octanol/water No data available Autoignition Temperature No data available Decomposition Temperature No data available Viscosity No data available Explosive Properties No information available Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
10. Stability and Reactivity
10.1. Reactivity Not expected to be reactive. 10.2. Chemical stability Stable 10.3. Possibility of hazardous reactions Will Not Occur 10.4. Conditions to avoid None anticipated 10.5. Incompatible materials Strong oxidizers. 10.6. Hazardous decomposition products Oxides of nitrogen. Carbon monoxide and carbon dioxide.
11. Toxicological Information
Information on routes of exposure Principle Route of Exposure Eye or skin contact, inhalation.
Symptoms related to exposure Most Important Symptoms/Effects No significant hazards expected.
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation Contains no hazardous NA No data available No data available No data available substances in concentrations above cut-off values according to the competent authority
______Page 4 / 8 HALAD® 413L CEMENT ADDITIVE Revision Date: 07-May-2018 ______
Immediate, delayed and chronic health effects from exposure Inhalation None known. Eye Contact None known. Skin Contact None known. Ingestion None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% are chronic health hazards.
Exposure Levels No data available
Interactive effects None known.
Data limitations No data available
12. Ecological Information
Ecotoxicity
Substance Ecotoxicity Data Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to Toxicity to Invertebrates Microorganisms Contains no NA No information available No information available No information available No information available hazardous substances in concentrations above cut-off values according to the competent authority
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability Contains no hazardous substances in NA No information available concentrations above cut-off values according to the competent authority
12.3. Bioaccumulative potential
Substances CAS Number Log Pow Contains no hazardous substances in NA No information available concentrations above cut-off values according to the competent authority
12.4. Mobility in soil
Substances CAS Number Mobility Contains no hazardous substances in concentrations NA No information available above cut-off values according to the competent authority
______Page 5 / 8 HALAD® 413L CEMENT ADDITIVE Revision Date: 07-May-2018 ______
12.6. Other adverse effects Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
Safe handling and disposal methods Disposal should be made in accordance with federal, state, and local regulations.
Disposal of any contaminated packaging Follow all applicable national or local regulations.
Environmental regulations Not applicable
14. Transport Information
Transportation Information Australia ADG UN Number Not restricted UN proper shipping name: Not restricted Transport Hazard Class(es): Not applicable Packing Group: Not applicable Environmental Hazards: Not applicable
IMDG/IMO UN Number Not restricted UN proper shipping name: Not restricted Transport Hazard Class(es): Not applicable Packing Group: Not applicable Environmental Hazards: Not applicable
IATA/ICAO UN Number Not restricted UN proper shipping name: Not restricted Transport Hazard Class(es): Not applicable Packing Group: Not applicable Environmental Hazards: Not applicable
Special precautions during transport None
HazChem Code None Allocated
15. Regulatory Information
Safety, health and environmental regulations specific for the product
International Inventories Australian AICS Inventory All components are listed on the AICS or are subject to a relevant exemption, permit, or assessment certificate. New Zealand Inventory of All components are listed on the NZIoC or are subject to a relevant exemption, permit, or Chemicals assessment certificate. EINECS (European Inventory of This product, and all its components, complies with EINECS Existing Chemical Substances) US TSCA Inventory All components listed on inventory or are exempt. Canadian Domestic Substances List Product contains one or more components not listed on the inventory. (DSL)
______Page 6 / 8 HALAD® 413L CEMENT ADDITIVE Revision Date: 07-May-2018 ______
Poisons Schedule number None Allocated
International Agreements Montreal Protocol - Ozone Depleting Substances: Does not apply. Stockholm Convention - Persistent Organic Pollutants: Does not apply Rotterdam Convention - Prior Informed Consent: Does not apply. Basel Convention - Hazardous Waste: Does not apply.
16. Other information
Date of preparation or review
Revision Date: 07-May-2018
Revision Note SDS sections updated: 2
Full text of H-Statements referred to under sections 2 and 3 None
Additional information For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Stewardship at 1-580-251-4335.
Key abreviations or acronyms used bw – body weight CAS – Chemical Abstracts Service EC50 – Effective Concentration 50% LC50 – Lethal Concentration 50% LD50 – Lethal Dose 50% LL50 – Lethal Loading 50% mg/kg – milligram/kilogram mg/L – milligram/liter NOEC – No Observed Effect Concentration OEL – Occupational Exposure Limit PBT – Persistent Bioaccumulative and Toxic ppm – parts per million STEL – Short Term Exposure Limit TWA – Time-Weighted Average vPvB – very Persistent and very Bioaccumulative h - hour mg/m3 - milligram/cubic meter mm - millimeter mmHg - millimeter mercury w/w - weight/weight d - day
Key literature references and sources for data www.ChemADVISOR.com/ NZ CCID
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.
______Page 7 / 8 HALAD® 413L CEMENT ADDITIVE Revision Date: 07-May-2018 ______
End of Safety Data Sheet
______Page 8 / 8 SAFETY DATA SHEET
HR-6L
Revision Date: 29-Jan-2015 Revision Number: 13
1. Product Identifier & Identity for the Chemical
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the Globally Harmonised System of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goods according to the criteria of ADG.
1.1. Product Identifier Product Name HR-6L
Other means of Identification Synonyms: None Product Code: HM000901
Recommended use of the chemical and restrictions on use Recommended Use Cement Retarder Uses Advised Against No information available
Supplier's name, address and phone number Manufacturer/Supplier Halliburton Australia Pty. Ltd. 15 Marriott Road Jandakot WA 6164 Australia
ACN Number: 009 000 775 Telephone Number: + 61 1 800 686 951 Fax Number: 61 (08) 9455 5300 E-Mail address: [email protected]
Emergency phone number + 61 1 800 686 951
Australian Poisons Information Centre 24 Hour Service: - 13 11 26 Police or Fire Brigade: - 000 (exchange): - 1100
2. Hazard Identification
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the Globally Harmonised System of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goods according to the criteria of ADG.
Classification of the hazardous chemical Not classified
Label elements, including precautionary statements
Hazard Pictograms
Signal Word Not Hazardous
______Page 1 / 8 HR-6L Revision Date: 24-Feb-2015 ______
Hazard Statements Not Classified
Precautionary Statements
Prevention None
Response None
Storage None
Disposal None
Contains Substances CAS Number Contains no hazardous substances in concentrations above NA cut-off values according to the competent authority
Other hazards which do not result in classification None known
Australia Classification For the full text of the H-phrases mentioned in this Section, see Section 16
Classification Not Classified Risk Phrases None
3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w) GHS Classification - Australia Contains no hazardous substances in concentrations NA 60 - 100% Not Applicable above cut-off values according to the competent authority
4. First aid measures
Description of necessary first aid measures Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult. Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists. Skin Wash with soap and water. Get medical attention if irritation persists. Ingestion Under normal conditions, first aid procedures are not required.
Symptoms caused by exposure No significant hazards expected.
Medical Attention and Special Treatment Notes to Physician Treat symptomatically
5. Fire Fighting Measures
Suitable extinguishing equipment Suitable Extinguishing Media Water fog, carbon dioxide, foam, dry chemical. Extinguishing media which must not be used for safety reasons None known.
______Page 2 / 8 HR-6L Revision Date: 24-Feb-2015 ______Specific hazards arising from the chemical Special Exposure Hazards Decomposition in fire may produce harmful gases.
Special protective equipment and precautions for fire fighters Special Protective Equipment for Fire-Fighters Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment.
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.
7. Handling and storage
7.1. Precautions for Safe Handling Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities Storage Information Store away from oxidizers. Keep container closed when not in use. Other Guidelines No information available
8. Exposure Controls/Personal Protection
Control parameters - exposure standards, biological monitoring Exposure Limits Substances CAS Number Australia NOHSC ACGIH TLV-TWA Contains no hazardous substances in NA Not applicable Not applicable concentrations above cut-off values according to the competent authority
Appropriate engineering controls Engineering Controls Use in a well ventilated area.
Personal protective equipment (PPE) Respiratory Protection Not normally necessary.
Hand Protection Normal work gloves. Skin Protection Normal work coveralls. Eye Protection Wear safety glasses or goggles to protect against exposure. Other Precautions None known. Environmental Exposure Controls No information available
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
______Page 3 / 8 HR-6L Revision Date: 24-Feb-2015 ______Physical State: Liquid Color: Dark brown Odor: Molasses Odor Threshold: No information available
Property Values Remarks/ - Method pH: 9.5 Freezing Point/Range No data available Melting Point/Range No data available Boiling Point/Range No data available Flash Point > 98 °C / > 210 °F PMCC Evaporation rate No data available Vapor Pressure No data available Vapor Density No data available Specific Gravity 1.21 Water Solubility Soluble in water Solubility in other solvents No data available Partition coefficient: n-octanol/water No data available Autoignition Temperature No data available Decomposition Temperature No data available Viscosity No data available Explosive Properties No information available Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available Liquid Density 10.08 lbs/gal
10. Stability and Reactivity
10.1. Reactivity Not expected to be reactive. 10.2. Chemical Stability Stable 10.3. Possibility of Hazardous Reactions Will Not Occur 10.4. Conditions to Avoid None anticipated 10.5. Incompatible Materials Strong oxidizers. 10.6. Hazardous Decomposition Products Oxides of sulfur. Carbon monoxide and carbon dioxide.
11. Toxicological Information
Information on routes of exposure Principle Route of Exposure Eye or skin contact, inhalation.
Sympotoms related to exposure Most Important Symptoms/Effects No significant hazards expected.
Numerical measures of toxicity
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation Contains no hazardous NA No data available No data available No data available substances in concentrations above cut-off values according to the competent authority
______Page 4 / 8 HR-6L Revision Date: 24-Feb-2015 ______
Immediate, delayed and chronic health effects from exposure Inhalation May cause mild respiratory irritation. Eye Contact May cause mild eye irritation. Skin Contact None known. Ingestion None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% are chronic health hazards.
Exposure Levels No data available
Interactive effects None known.
Data limitations No data available
Substances CAS Number Skin corrosion/irritation Contains no hazardous NA Not applicable. substances in concentrations above cut-off values according to the competent authority
Substances CAS Number Eye damage/irritation Contains no hazardous NA Not applicable. substances in concentrations above cut-off values according to the competent authority
Substances CAS Number Skin Sensitization Contains no hazardous NA Not applicable substances in concentrations above cut-off values according to the competent authority
Substances CAS Number Respiratory Sensitization Contains no hazardous NA Not applicable substances in concentrations above cut-off values according to the competent authority
Substances CAS Number Mutagenic Effects Contains no hazardous NA Not applicable substances in concentrations above cut-off values according to the competent authority
Substances CAS Number Carcinogenic Effects Contains no hazardous NA Not applicable substances in concentrations above cut-off values according to the competent authority
Substances CAS Number Reproductive toxicity Contains no hazardous NA Not applicable substances in concentrations above cut-off
______Page 5 / 8 HR-6L Revision Date: 24-Feb-2015 ______values according to the competent authority
Substances CAS Number STOT - single exposure Contains no hazardous NA Not applicable substances in concentrations above cut-off values according to the competent authority
Substances CAS Number STOT - repeated exposure Contains no hazardous NA Not applicable substances in concentrations above cut-off values according to the competent authority
Substances CAS Number Aspiration hazard Contains no hazardous NA Not applicable substances in concentrations above cut-off values according to the competent authority
12. Ecological Information
Ecotoxicity Product Ecotoxicity Data No data available
Substance Ecotoxicity Data Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to Toxicity to Invertebrates Microorganisms Contains no NA No information available No information available No information available No information available hazardous substances in concentrations above cut-off values according to the competent authority
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability Contains no hazardous substances in NA No information available concentrations above cut-off values according to the competent authority
12.3. Bioaccumulative potential
Substances CAS Number Log Pow Contains no hazardous substances in NA No information available concentrations above cut-off values according to the competent authority
12.4. Mobility in soil
Substances CAS Number Mobility Contains no hazardous substances in concentrations NA No information available above cut-off values according to the competent authority
12.6. Other adverse effects Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors
______Page 6 / 8 HR-6L Revision Date: 24-Feb-2015 ______
13. Disposal Considerations
Safe handling and disposal methods This product is not regarded as hazardous waste. Dispose in accordance with local regulations.
Disposal of any contaminated packaging Follow all applicable national or local regulations.
Environmental regulations Not applicable
14. Transport Information
Transportation Information UN Number: Not restricted UN Proper Shipping Name: Not restricted Transport Hazard Class(es): Not applicable Packing Group: Not applicable Environmental Hazards: Not applicable
Special precautions during transport None
HazChem Code None Allocated
15. Regulatory Information
Safety, health and environmental regulations specific for the product
International Inventories Australian AICS Inventory All components listed on inventory or are exempt. New Zealand Inventory of All components listed on inventory or are exempt. Chemicals EINECS Inventory This product, and all its components, complies with EINECS US TSCA Inventory All components listed on inventory or are exempt. Canadian DSL Inventory All components listed on inventory or are exempt.
Poisons Schedule number None Allocated
16. Other information
Date of preparation or review
Revision Date: 29-Jan-2015
Revision Note SDS sections updated: 2
Full text of R-phrases referred to under Sections 2 and 3 None
Full text of H-Statements referred to under sections 2 and 3 None
Additional information For additional information on the use of this product, contact your local Halliburton representative.
______Page 7 / 8 HR-6L Revision Date: 24-Feb-2015 ______For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Stewardship at 1-580-251-4335.
Key abreviations or acronyms used bw – body weight CAS – Chemical Abstracts Service EC50 – Effective Concentration 50% LC50 – Lethal Concentration 50% LD50 – Lethal Dose 50% LL50 – Lethal Loading 50% mg/kg – milligram/kilogram mg/L – milligram/liter NOEC – No Observed Effect Concentration OEL – Occupational Exposure Limit PBT – Persistent Bioaccumulative and Toxic ppm – parts per million STEL – Short Term Exposure Limit TWA – Time-Weighted Average vPvB – very Persistent and very Bioaccumulative h - hour mg/m3 - milligram/cubic meter mm - millimeter mmHg - millimeter mercury w/w - weight/weight d - day
Key literature references and sources for data www.ChemADVISOR.com/ NZ CCID
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
______Page 8 / 8 SAFETY DATA SHEET
NF-6
Revision Date: 16-Aug-2016 Revision Number: 28
1. Product Identifier & Identity for the Chemical
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the Globally Harmonised System of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goods according to the criteria of ADG.
1.1. Product Identifier Product Name NF-6
Other means of Identification Synonyms None Hazardous Material Number: HM001971
Recommended use of the chemical and restrictions on use Recommended Use Defoamer Uses advised against No information available
Supplier's name, address and phone number Manufacturer/Supplier Halliburton Australia Pty. Ltd. 15 Marriott Road, Jandakot, WA 6164 Australia ACN Number: 009 000 775 Telephone Number: + 61 1 800 686 951 Fax Number: 61 (08) 9455 5300 E-mail Address [email protected]
Emergency phone number + 61 1 800 686 951 Global Incident Response Access Code: 334305 Contract Number: 14012
Australian Poisons Information Centre 24 Hour Service: - 13 11 26 Police or Fire Brigade: - 000 (exchange): - 1100
2. Hazard Identification
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the Globally Harmonised System of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goods according to the criteria of ADG.
Classification of the hazardous chemical Not classified
Label elements, including precautionary statements
Hazard Pictograms
Signal Word Not Hazardous
______Page 1 / 8 NF-6 Revision Date: 16-Aug-2016 ______Hazard Statements: Not Classified
Precautionary Statements
Prevention None Response None Storage None Disposal None
Contains Substances CAS Number Contains no hazardous substances in concentrations above NA cut-off values according to the competent authority
Other hazards which do not result in classification This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
For the full text of the H-phrases mentioned in this Section, see Section 16
3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w) GHS Classification - Australia Contains no hazardous substances in concentrations NA 60 - 100% Not Applicable above cut-off values according to the competent authority
4. First aid measures
Description of necessary first aid measures Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult. Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists. Skin Wash with soap and water. Get medical attention if irritation persists. Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical attention.
Symptoms caused by exposure No significant hazards expected.
Medical Attention and Special Treatment Notes to Physician Treat symptomatically
5. Fire Fighting Measures
Suitable extinguishing equipment Suitable Extinguishing Media Carbon dioxide, dry chemical, foam. Extinguishing media which must not be used for safety reasons None known.
Specific hazards arising from the chemical Special exposure hazards in a fire Use water spray to cool fire exposed surfaces. Decomposition in fire may produce harmful gases.
Special protective equipment and precautions for fire fighters
______Page 2 / 8 NF-6 Revision Date: 16-Aug-2016 ______Special protective equipment for firefighters Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid breathing vapors. Ensure adequate ventilation.
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.
7. Handling and storage
7.1. Precautions for safe handling Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Ensure adequate ventilation. Wash hands after use. Launder contaminated clothing before reuse. Use appropriate protective equipment. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities Storage Information Store away from oxidizers. Keep container closed when not in use. Other Guidelines No information available
8. Exposure Controls/Personal Protection
Control parameters - exposure standards, biological monitoring Exposure Limits Substances CAS Number Australia NOHSC ACGIH TLV-TWA Contains no hazardous substances in NA Not applicable Not applicable concentrations above cut-off values according to the competent authority
Appropriate engineering controls Engineering Controls A well ventilated area to control dust levels. Local exhaust ventilation should be used in areas without good cross ventilation.
Personal protective equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the selection and proper use of personal protective equipment should be determined by an industrial hygienist or other qualified professional based on the specific application of this product. Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational exposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection of and instruction on using all personal protective equipment, including respirators, should be performed by an Industrial Hygienist or other qualified professional. Organic vapor respirator with a dust/mist filter. (A2P2/P3) Hand Protection Chemical-resistant protective gloves (EN 374) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): Polyvinylchloride gloves. (>= 0.7 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter
______Page 3 / 8 NF-6 Revision Date: 16-Aug-2016 ______than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Manufacturer's directions for use should be observed because of great diversity of types. Skin Protection Normal work coveralls. Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists. Other Precautions None known. Environmental Exposure Controls Do not allow material to contaminate ground water system
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties Physical State: Liquid Color Yellow Odor: Mild Odor Threshold: No information available
Property Values Remarks/ - Method pH: No data available Freezing Point / Range No data available Melting Point / Range No data available Boiling Point / Range 182 °C / 360 °F Flash Point > 170 °C / > 340 °F Evaporation rate No data available Vapor Pressure No data available Vapor Density No data available Specific Gravity 0.93 Water Solubility Dispersible Solubility in other solvents No data available Partition coefficient: n-octanol/water No data available Autoignition Temperature 385 °C / 725 °F Decomposition Temperature No data available Viscosity No data available Explosive Properties No information available Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available Liquid Density 7.70 lbs/gal
10. Stability and Reactivity
10.1. Reactivity Not expected to be reactive. 10.2. Chemical stability Stable 10.3. Possibility of hazardous reactions Will Not Occur 10.4. Conditions to avoid None anticipated 10.5. Incompatible materials Strong oxidizers. 10.6. Hazardous decomposition products Hydrocarbons. Carbon monoxide and carbon dioxide.
11. Toxicological Information
Information on routes of exposure Principle Route of Exposure Eye or skin contact, inhalation.
Symptoms related to exposure Most Important Symptoms/Effects
______Page 4 / 8 NF-6 Revision Date: 16-Aug-2016 ______No significant hazards expected.
Numerical measures of toxicity
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation Contains no hazardous NA No data available No data available No data available substances in concentrations above cut-off values according to the competent authority
Immediate, delayed and chronic health effects from exposure Product Information Under certain conditions of use, some of the product ingredients may cause the following: Inhalation May cause mild respiratory irritation. Eye Contact None known. Skin Contact None known. Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% are chronic health hazards.
Exposure Levels No data available
Interactive effects None known.
Data limitations No data available
12. Ecological Information
Ecotoxicity Product Ecotoxicity Data
Substance Ecotoxicity Data Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to Toxicity to Invertebrates Microorganisms Contains no NA No information available No information available No information available No information available hazardous substances in concentrations above cut-off values according to the competent authority
12.2. Persistence and degradability
______Page 5 / 8 NF-6 Revision Date: 16-Aug-2016 ______Substances CAS Number Persistence and Degradability Contains no hazardous substances in NA No information available concentrations above cut-off values according to the competent authority
12.3. Bioaccumulative potential
Substances CAS Number Log Pow Contains no hazardous substances in NA No information available concentrations above cut-off values according to the competent authority
12.4. Mobility in soil
Substances CAS Number Mobility Contains no hazardous substances in concentrations NA No information available above cut-off values according to the competent authority
12.6. Other adverse effects Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
Safe handling and disposal methods Incineration recommended in approved incinerator according to federal, state, and local regulations. Substance should NOT be deposited into a sewage facility.
Disposal of any contaminated packaging Follow all applicable national or local regulations. Contaminated packaging may be disposed of by: rendering packaging incapable of containing any substance, or treating packaging to remove residual contents, or treating packaging to make sure the residual contents are no longer hazardous, or by disposing of packaging into commercial waste collection.
Environmental regulations Not applicable
14. Transport Information
Transportation Information Australia ADG UN Number Not restricted UN proper shipping name: Not restricted Transport Hazard Class(es): Not applicable Packing Group: Not applicable Environmental Hazards: Not applicable
IMDG/IMO UN Number Not restricted UN proper shipping name: Not restricted Transport Hazard Class(es): Not applicable Packing Group: Not applicable Environmental Hazards: Not applicable
IATA/ICAO UN Number Not restricted UN proper shipping name: Not restricted Transport Hazard Class(es): Not applicable Packing Group: Not applicable Environmental Hazards: Not applicable
Special precautions during transport
______Page 6 / 8 NF-6 Revision Date: 16-Aug-2016 ______None
HazChem Code None Allocated
15. Regulatory Information
Safety, health and environmental regulations specific for the product
International Inventories Australian AICS Inventory All components are listed on the AICS or are subject to a relevant exemption, permit, or assessment certificate. New Zealand Inventory of All components are listed on the NZIoC or are subject to a relevant exemption, permit, or Chemicals assessment certificate. EINECS (European Inventory of This product, and all its components, complies with EINECS Existing Chemical Substances) US TSCA Inventory All components listed on inventory or are exempt. Canadian Domestic Substances List All components listed on inventory or are exempt. (DSL)
Poisons Schedule number None Allocated
International Agreements Montreal Protocol - Ozone Depleting Substances: Does not apply Stockholm Convention - Persistent Organic Pollutants: Does not apply Rotterdam Convention - Prior Informed Consent: Does not apply Basel Convention - Hazardous Waste: Does not apply
16. Other information
Date of preparation or review
Revision Date: 16-Aug-2016
Revision Note SDS sections updated: 2
Full text of H-Statements referred to under sections 2 and 3 None
Additional information For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Stewardship at 1-580-251-4335.
Key abreviations or acronyms used bw – body weight CAS – Chemical Abstracts Service EC50 – Effective Concentration 50% LC50 – Lethal Concentration 50% LD50 – Lethal Dose 50% LL50 – Lethal Loading 50% mg/kg – milligram/kilogram mg/L – milligram/liter NOEC – No Observed Effect Concentration OEL – Occupational Exposure Limit PBT – Persistent Bioaccumulative and Toxic ppm – parts per million
______Page 7 / 8 NF-6 Revision Date: 16-Aug-2016 ______STEL – Short Term Exposure Limit TWA – Time-Weighted Average vPvB – very Persistent and very Bioaccumulative h - hour mg/m3 - milligram/cubic meter mm - millimeter mmHg - millimeter mercury w/w - weight/weight d - day
Key literature references and sources for data www.ChemADVISOR.com/ NZ CCID Cosmetic Ingredient Review
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
______Page 8 / 8
Product Name R-21L
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Supplier Name BAKER HUGHES PRESSURE PUMPING Address 108 Poole st , Welshpool , WA, AUSTRALIA, 6106 Telephone +61 8 9350 3800 Fax +61 8 9350 5453 Emergency 1800 988 778 Web Site http://www.bakerhughes.com
Synonym(s) 21L R • 488066 - ITEM NUMBER • BJ SERVICES R-21L • R 21L
Use(s) RETARDANT SDS Date 31 May 2011 2. HAZARDS IDENTIFICATION NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE UN No. None Allocated DG Class None Allocated Subsidiary Risk(s) None Allocated Packing Group None Allocated Hazchem Code None Allocated 3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient Formula CAS No. Content WATER H2O 7732-18-5 >60% SODIUM LIGNOSULPHONATE Not Available Not Available Not Available 4. FIRST AID MEASURES Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. Advice to Doctor Treat symptomatically. First Aid Facilities Eye wash facilities should be available.
5. FIRE FIGHTING MEASURES Flammability Non flammable. May evolve toxic gases if strongly heated. May evolve carbon oxides and sulphur oxides when heated to decomposition. Fire and Treat as per requirements for Surrounding Fires: Evacuate area and contact emergency services. Remain upwind Explosion and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
Page 1 of 4 RMT Reviewed: 31 May 2011 Printed: 31 May 2011
Product Name R-21L
Extinguishing Prevent contamination of drains or waterways. Hazchem Code None Allocated 6. ACCIDENTAL RELEASE MEASURES Spillage Use personal protective equipment. Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place in suitable containers for disposal. CAUTION: Spill site may be slippery. 7. STORAGE AND HANDLING Storage Store in a cool, dry, well ventilated area, removed from oxidising agents, acids and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills. Handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas. 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION Exposure Stds No exposure standard(s) allocated.
Biological Limits No biological limit allocated.
Engineering Avoid inhalation. Use in well ventilated areas. Controls PPE Wear splash-proof goggles and PVC or rubber gloves. When using large quantities or where heavy contamination is likely, wear: coveralls.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance BROWN LIQUID Solubility (water) SOLUBLE Odour SLIGHT ODOUR Specific Gravity 1.296 pH 9.5 to 10.5 (3% solution) % Volatiles NOT AVAILABLE Vapour Pressure NOT AVAILABLE Flammability NON FLAMMABLE Vapour Density 1.21 (Air = 1) Flash Point NOT RELEVANT Boiling Point 101.7°C Upper Explosion Limit NOT RELEVANT Melting Point -1.1°C Lower Explosion Limit NOT RELEVANT Evaporation Rate AS FOR WATER Autoignition Temperature NOT AVAILABLE Decomposition Temperature NOT AVAILABLE Partition Coefficient NOT AVAILABLE Viscosity NOT AVAILABLE 10. STABILITY AND REACTIVITY Chemical Stability Stable under recommended conditions of storage. Conditions to Avoid Avoid heat, sparks, open flames and other ignition sources. Material to Avoid Incompatible with oxidising agents and acids (eg. nitric acid). Hazardous May evolve carbon oxides and sulphur oxides when heated to decomposition. Decomposition Products Hazardous Reactions Polymerization is not expected to occur.
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Product Name R-21L
11. TOXICOLOGICAL INFORMATION Health Hazard Low toxicity - irritant. Use safe work practices to avoid eye or skin contact and inhalation. Over exposure may Summary result in irritation. Eye Irritant. Contact may result in irritation, lacrimation, pain, redness and conjunctivitis. May result in burns with prolonged contact. Inhalation Low irritant. Over exposure may result in irritation of the nose and throat, with coughing. Skin Irritant. Contact may result in irritation, redness, rash and dermatitis. Prolonged or repeated contact may result in burns. Ingestion Low toxicity. Ingestion of large quantities may result in nausea, vomiting and gastrointestinal irritation. Toxicity Data No LD50 data available for this product. 12. ECOLOGICAL INFORMATION Environment Limited ecotoxicity data was available for this product at the time this report was prepared. Ensure appropriate measures are taken to prevent this product from entering the environment.
13. DISPOSAL CONSIDERATIONS Waste Disposal For small amounts absorb with sand, vermiculite or similar and dispose of to an approved landfill site. Contact the manufacturer for additional information if larger amounts are involved. Prevent contamination of drains and waterways as aquatic life may be threatened and environmental damage may result. Legislation Dispose of in accordance with relevant local legislation. 14. TRANSPORT INFORMATION
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE Shipping Name None Allocated UN No. None Allocated DG Class None Allocated Subsidiary Risk(s) None Allocated Packing Group None Allocated Hazchem Code None Allocated
15. REGULATORY INFORMATION Poison Schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP). AICS All chemicals listed on the Australian Inventory of Chemical Substances (AICS).
16. OTHER INFORMATION Additional RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid Information exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
EXPOSURE STANDARDS - TIME WEIGHTED AVERAGES: Exposure standards are established on the premise of an 8 hour work period of normal intensity, under normal climatic conditions and where a 16 hour break between shifts exists to enable the body to eliminate absorbed contaminants. In the following circumstances, exposure standards must be reduced: strenuous work conditions; hot, humid climates; high altitude conditions; extended shifts (which increase the exposure period and shorten the period of recuperation).
ABBREVIATIONS: ACGIH - American Conference of Industrial Hygienists. ADG - Australian Dangerous Goods. BEI - Biological Exposure Indice(s). CAS# - Chemical Abstract Service number - used to uniquely identify chemical compounds. CNS - Central Nervous System. EC No - European Community Number. HSNO - Hazardous Substances and New Organisms. IARC - International Agency for Research on Cancer. mg/m³ - Milligrams per Cubic Metre. NOS - Not Otherwise Specified. pH - relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm - Parts Per Million.
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Product Name R-21L
RTECS - Registry of Toxic Effects of Chemical Substances. STEL - Short Term Exposure Limit. SWA - Safe Work Australia. TWA - Time Weighted Average.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this ChemAlert report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made. Report Status This document has been compiled by RMT on behalf of the manufacturer of the product and serves as the manufacturer's Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by the manufacturer or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS. Prepared By Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au
SDS Date31 May 2011 End of Report
Page 4 of 4 RMT Reviewed: 31 May 2011 Printed: 31 May 2011
CHEMALERT REPORT Full Report
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
1.1 Product identifier Product name CALCIUM CHLORIDE POWDER 94-97% Synonym(s) CALCIUM CHLORIDE ANHYDRATE 1.2 Uses and uses advised against Use(s) CONCRETE CONDITIONER • DESICCANT • DUST CONTROL AGENT • FOOD ADDITIVE • INDUSTRIAL APPLICATIONS 1.3 Details of the supplier of the safety data sheet Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, Australia, 6166 Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Email Not supplied Website http://www.newpark.com 1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International) 2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA Risk phrases R36 Irritating to eyes. Safety phrases S22 Do not breathe dust. S24 Avoid contact with skin.
Other Hazards No information provided. 3. COMPOSITION/ INFORMATION ON INGREDIENTS 3.1 Substances / Mixtures Ingredient CAS number EC number Content CALCIUM CHLORIDE ANHYDROUS 10043-52-4 233-140-8 94 - 97% SODIUM CHLORIDE 7647-14-5 231-598-3 1 - 5% WATER 7732-18-5 231-791-2 1%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. First aid facilities Eye wash facilities and safety shower should be available. 4.2 Most important symptoms and effects, both acute and delayed Irritating to the eyes and skin. 4.3 Immediate medical attention and special treatment needed Treat symptomatically.
Page 1 of 7 Reviewed: 17 Apr 2015 This report was compiled based on the SDS dated 17 Apr 2015 Printed: 29 Jul 2016
CHEMALERT REPORT Full Report
Product name CALCIUM CHLORIDE POWDER 94-97%
5. FIREFIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire. 5.2 Special hazards arising from the substance or mixture Non flammable. May evolve toxic gases (chlorides) when heated to decomposition. 5.3 Advice for firefighters Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas. 5.4 Hazchem code None allocated 6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contact emergency services where appropriate. 6.2 Environmental precautions Prevent product from entering drains and waterways. 6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust. 6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal. 7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas. 7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. 7.3 Specific end use(s) No information provided. 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION
8.1 Control parameters Exposure standards No exposure standards have been entered for this product. Biological limits No Biological Limit Value allocated. 8.2 Exposure controls Engineering Controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended. Maintain dust levels below the recommended exposure standard. PPE
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CHEMALERT REPORT Full Report
Product name CALCIUM CHLORIDE POWDER 94-97%
Eye/Face Wear dust-proof goggles. Hand Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance WHITE POWDER Odour ODOURLESS Odour Threshold NOT AVAILABLE pH 7.0 to 9.0 Melting Point 772°C Boiling Point > 1600°C Flash Point NOT RELEVANT Evaporation Rate NOT RELEVANT Flammability NON FLAMMABLE Upper Explosion Limit NOT RELEVANT Lower Explosion Limit NOT RELEVANT Vapour Pressure NOT AVAILABLE Vapour Density NOT AVAILABLE Solubility (water) 590 kg/m³ (Approximately) Partition Coefficient NOT AVAILABLE Autoignition Temperature NOT AVAILABLE Decomposition Temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive Properties NOT AVAILABLE Oxidising Properties NOT AVAILABLE Specific Gravity 2.15 9.2 Other information % Volatiles NOT AVAILABLE 10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information in sections 10.2 to 10.6. 10.2 Chemical stability Stable under recommended conditions of storage. 10.3 Possibility of hazardous reactions Polymerization is not expected to occur. 10.4 Conditions to avoid Avoid contact with incompatible substances. 10.5 Incompatible materials Incompatible with acids (e.g. nitric acid), methyl vinyl ether, zinc/ galvanised metals, bromine trifluoride, boron oxide and calcium oxide. May react exothermically with water (i.e. releasing heat). 10.6 Hazardous decomposition products
Page 3 of 7 Reviewed: 17 Apr 2015 This report was compiled based on the SDS dated 17 Apr 2015 Printed: 29 Jul 2016
CHEMALERT REPORT Full Report
Product name CALCIUM CHLORIDE POWDER 94-97%
May evolve toxic gases (chlorides) when heated to decomposition. 11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity Based on available data, the classification criteria are not met. Toxicity Data available for the ingredients: CALCIUM CHLORIDE ANHYDROUS (10043-52-4): LD50 (Ingestion): 1000 mg/kg (rat) LD50 (Intraperitoneal): 210 mg/kg (mouse) LD50 (Intravenous): 42 mg/kg (mouse) LD50 (Subcutaneous): 823 mg/kg (mouse) LDLo (Ingestion): 1384 mg/kg (rabbit) LDLo (Intravenous): 150 mg/kg (guinea pig) LDLo (Subcutaneous): 249 mg/kg (cat) TDLo (Intravenous): 20 mg/kg/1 hour (woman) SODIUM CHLORIDE (7647-14-5): LC50 (Inhalation): > 42000 mg/m3/1 hour (rat) LD50 (Ingestion): 3000 mg/kg (rat) LD50 (Intraperitoneal): 2602 mg/kg (mouse) LD50 (Intravenous): 645 mg/kg (mouse) LD50 (Skin): > 10000 mg/kg (rabbit) LD50 (Subcutaneous): 3000 mg/kg (mouse) LDLo (Ingestion): 8000 mg/kg (rabbit) LDLo (Intravenous): 300 mg/kg (guinea pig) LDLo (Subcutaneous): 2160 mg/kg (guinea pig) TDLo (Ingestion): 12357 mg/kg (human) Skin Not classified as a skin irritant. Contact may result in mechanical irritation, redness and rash. Eye Irritating to the eyes. Contact may result in irritation, lacrimation, pain and redness. Mutagenicity Insufficient data available to classify as a mutagen. Carcinogenicity Insufficient data available to classify as a carcinogen. Reproductive Insufficient data available to classify as a reproductive toxin. STOT - single Not classified as causing organ effects from single exposure. exposure STOT - repeated Not classified as causing organ damage from repeated exposure. exposure Aspiration This product does not present an aspiration hazard. Sensitisation Not classified as causing skin or respiratory sensitisation.
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CHEMALERT REPORT Full Report
Product name CALCIUM CHLORIDE POWDER 94-97%
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided. 12.2 Persistence and degradability Biodegradability does not pertain to inorganic substances. 12.3 Bioaccumulative potential This product does not bioaccumulate. 12.4 Mobility in soil No information provided. 12.5 Results of PBT and vPvB assessment No information provided. 12.6 Other adverse effects No information provided. 13. DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Council landfill. Contact the manufacturer/supplier for additional information (if required). Legislation Dispose of in accordance with relevant local legislation. 14. TRANSPORT INFORMATION
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
Land Transport Sea Transport Air Transport (ADG) (IMDG/IMO) (IATA/ICAO)
14.1 UN number None Allocated None Allocated None Allocated 14.2 UN proper shipping name None Allocated None Allocated None Allocated 14.3 Transport hazard classes DG Class None Allocated None Allocated None Allocated Subsidiary risk(s) None Allocated None Allocated None Allocated 14.4 Packing group None Allocated None Allocated None Allocated 14.5 Environmental hazards None Allocated 14.6 Special precautions for user Hazchem Code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Xi - Irritant
Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
15.2 Chemical safety assessment No information provided.
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CHEMALERT REPORT Full Report
Product name CALCIUM CHLORIDE POWDER 94-97%
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made. Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Report Status This ChemAlert report has been independently compiled by RMT's scientific department utilising the original Safety Data Sheet ('SDS') for the product provided to RMT by the manufacturer. The information is based on the latest chemical and toxicological research and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. It is an independent collation by RMT of information obtained from the original SDS for this product. Its content has not been authorised or verified by the manufacturer / distributor of the chemical to which it relates.
This ChemAlert report does not constitute the manufacturer's original SDS and is not intended to be a replacement for same. It is provided to subscribers of ChemAlert as a reference tool only, is not all-inclusive and does not represent any guarantee as to the properties of the product. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer.
Page 6 of 7 Reviewed: 17 Apr 2015 This report was compiled based on the SDS dated 17 Apr 2015 Printed: 29 Jul 2016
CHEMALERT REPORT Full Report
Product name CALCIUM CHLORIDE POWDER 94-97%
While RMT has taken all due care to include accurate and up-to-date information in this ChemAlert report, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this ChemAlert report. Prepared By Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au
Last Reviewed:17 Apr 2015 Date Printed:29 Jul 2016 Based on SDS dated:17 Apr 2015
End of Report
Page 7 of 7 Reviewed: 17 Apr 2015 This report was compiled based on the SDS dated 17 Apr 2015 Printed: 29 Jul 2016