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Waste Sodium Dichromate Solution Section 1 – Identification

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Waste Sodium Dichromate Solution Section 1 – Identification SDS ID No.: 9930 Safety Data Sheet (SDS) Waste Sodium Dichromate Solution Section 1 – Identification 1(a) Product Identifier used on Label: Waste Sodium Dichromate Solution 1(b) Other Means of Identification: 9930 1(c) Recommended use of the chemical and restrictions on use: Internally generated by-product material. 1(d) Name, Address, and Telephone Number: ArcelorMittal Dofasco, Inc. Phone number : 1-905-548-7200 x 4051 (By-Products Sales) P.O Box 2460 Hamilton, Ontario, Canada L8N 3J5 Supplier to Waste Recycler: Phone number : 1-416-299-0116 Network Environmental Services Inc. 31 Golden Gate Court Scarborough, Ontario, Canada M1P 3A4 1(e) Emergency Phone Number: 1-760-476-3962 (3E Company Code: 333211) Section 2 – Hazard(s) Identification 2(a) Classification of the Chemical: Waste Sodium Dichromate Solution is considered a hazardous material according to the criteria specified in REACH [REGULATION (EC) No 1907/2006] and CLP [REGULATION (EC) No 1272/2008] and OSHA 29 CFR 1910.1200 Hazard Communication Standard. The categories of Health Hazards as defined in “GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS (GHS), Third revised edition ST/SG/AC.10/30/Rev. 3” United Nations, New York and Geneva, 2009 have been evaluated. Refer to Section 3, 8 and 11 for additional information. 2(b) Signal Word, Hazard Statement(s), Symbols and Precautionary Statement(s): Hazard Signal Hazard Classification Hazard Statement(s) Symbol Word Sensitization/Respiratory - 1B Sensitization/Skin -1B Germ Cell Mutagenicity - 1B May cause allergy or asthma symptoms or breathing difficulties if Carcinogenicity - 1B inhaled. May cause genetic defects. Reproductive Toxicity - 1B May cause cancer. Single Target Organ Toxicity (STOT) Repeat May damage fertility or the unborn child. Exposure - 1 Danger Causes damage to liver and kidney through prolonged or repeated exposure. Acute Toxicity-Oral/Inhalation - 3 Toxic if swallowed or inhaled. Causes severe skin burns and serious eye damage. May cause an allergic skin reaction. Skin Irritation - 1B Eye Irritation - 2A Precautionary Statement(s): Prevention Response Storage/Disposal If exposed, concerned or feel unwell: Get medical advice/attention. Do not breathe mists, vapors or sprays. If inhaled: Remove person to fresh air and keep comfortable for Wear protective gloves/protective clothing/eye breathing. Immediately call a poison center or doctor. protection/face protection. If in eyes: Rinse cautiously with water for several minutes. Remove Do not eat, drink or smoke when using this product. Dispose of contents in contact lenses, if present and easy to do. Continue rinsing. If eye accordance with federal, Wash thoroughly after handling. irritation persists: Get medical advice/attention. state/provincial and local Use only outdoors or in a well ventilated area. If on skin (or hair): Take off immediately all contaminated clothing. regulations. In case of inadequate ventilation wear respiratory protection. Wash skin with plenty of water/shower. If irritation or rash occurs: Store locked up. Obtain special instructions before use. Get medical advice/attention. Wash contaminated clothing before reuse. Do not handle until all safety precautions have been read and understood. If swallowed: Immediately call a poison center or doctor. Rinse mouth. Do NOT induce vomiting. 2(c) Hazards not Otherwise Classified: None Known 2(d) Unknown Acute Toxicity Statement (Mixture): None Known Page 1 of 7 Waste Sodium Dichromate Solution SDS ID No.: 9930 Rev. NA (Original) Section 3 – Composition/Information on Ingredients 3(a-c) Chemical Name, Common Name (Synonyms), CAS Number and Other Identifiers, and Concentration: Chemical Name CAS Number EC Number % weight Sodium Dichromate 10588-01-9 234-190-3 20-30 Sodium Sulphate 7440-66-6 231-175-3 1.5-2.2 Water 7732-18-5 231-791-2 65-75 EC- European Community CAS- Chemical Abstract Service Section 4 – First-aid Measures 4(a) Description of Necessary Measures: If exposed, concerned or feel unwell: Get medical advice/attention. Inhalation If inhaled: Remove person to fresh air and keep comfortable for breathing. Immediately call a poison center or doctor. Eye Contact: If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin Contact: If on skin (or hair): Take off immediately all contaminated clothing. Wash skin with plenty of water/shower. If irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Ingestion: If swallowed: Immediately call a poison center or doctor. Rinse mouth. Do NOT induce vomiting. 4(b) Most Important Symptoms/Effects, Acute and Delayed (Chronic): Acute effects: Inhalation: Inhalation of vapors can cause inflammation of the nose, throat, and upper respiratory tract. May cause allergic reaction. Eye: Vapors may cause irritation to the eyes. Skin: Can cause redness, pain, severe skin burns and tissue destruction. May cause allergic reaction. Ingestion: May cause nausea, vomiting, and diarrhea. Swallowing may be fatal. Chronic Effects: Inhalation: May cause perforation of the nasal septum. May cause an asthma-like allergy or cause asthma attacks, shortness of breath, wheezing, coughing and/or chest tightness. Eye: Not Applicable Skin: May be a skin sensitizer for predisposed individuals. Prolonged contact can cause skin burns, blisters and deep ulcers. Ingestion: Not Applicable 4(c) Immediate Medical Attention and Special Treatment: Treat symptomatically. Section 5 – Fire-fighting Measures 5(a) Suitable (and Unsuitable) Extinguishing Media: Use extinguishers appropriate for surrounding materials. 5(b) Specific Hazards Arising from the Chemical: Not applicable for product. 5(c) Special Protective Equipment and Precautions for Fire-fighters: Self-contained NIOSH approved respiratory protection and full protective clothing should be worn when fumes and/or smoke from fire are present. Heat and flames cause emittance of acrid smoke and fumes. Do not release runoff from fire control methods to sewers or waterways. Firefighters should wear full face-piece self-contained breathing apparatus and chemical protective clothing with thermal protection. Direct water stream will scatter and spread flames and, therefore, should not be used. Section 6 - Accidental Release Measures 6(a) Personal Precautions, Protective Equipment and Emergency Procedures: For spills, personnel should be protected against contact with eyes and skin and avoid inhalation of vapor/mist. Ventilate area of leak or spill. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Do not flush to sewer. 6(b) Methods and Materials for Containment and Clean Up: Collect material in appropriate, labeled containers for recovery or disposal in accordance with Federal, Provincial/State, and Local regulations. Follow applicable OSHA regulations (29 CFR 1910.120) and all other pertinent Provincial/State and Federal requirements. Section 7 - Handling and Storage 7(a) Precautions for Safe Handling: Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Do not breathe mists, vapors or sprays. Wear protective gloves / protective clothing / eye protection / face protection. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. 7(b) Conditions for Safe Storage, Including any Incompatibilities: Whenever feasible, store locked up. Page 2 of 7 Waste Sodium Dichromate Solution SDS ID No.: 9930 Rev. NA (Original) Section 8 - Exposure Controls / Personal Protection 8(a) Occupational Exposure Limits (OELs):.The following exposure limits are offered as reference, for an experience industrial hygienist to review. Ingredients OSHA PEL 1 ACGIH TLV 2 NIOSH REL 3 MOL 4 Sodium 0.5 mg/m³ (as Cr II & III, inorganic 0.5 mg/m³ (as Cr III, inorganic 0.5 mg/m³ (as Cr II & III, 0.5 mg/m³ (as Cr III) Dichromate compounds) compounds) inorganic compounds) 0.05 mg/m³ (as water-soluble 0.005 mg/m³ (as Cr VI, inorganic 0.05 mg/m³ (as Cr VI, inorganic 0.001 mg/m³ (as Cr VI, Cr VI) compounds & certain water insoluble) compounds) inorganic compounds Sodium Sulphate NE NE NE NE NE - None Established 1. OSHA PELs (Permissible Exposure Limits) are 8-hour TWA (time-weighted average) concentrations unless otherwise noted. A (“C”) designation denotes a ceiling limit, which should not be exceeded during any part of the working exposure unless otherwise noted. An Action level (AL) is used by OSHA and NIOSH to express a health or physical hazard. They indicate the level of a harmful or toxic substance/activity, which requires medical surveillance, increased industrial hygiene monitoring, or biological monitoring. Action Levels are generally set at one half of the PEL but the actual level may vary from standard to standard. The intent is to identify a level at which the vast majority of randomly sampled exposures will be below the PEL. 2. Threshold Limit Values (TLV) established by the American Conference of Governmental Industrial Hygienists (ACGIH) are 8-hour TWA concentrations unless otherwise noted. ACGIH TLVs are for guideline purposes only and as such are not legal, regulatory limits for compliance purposes. A Short Term Exposure Limit (STEL) is defined as the maximum concentration to which workers can be exposed for a short period of time (15 minutes) for only four times throughout the day with at least one hour between
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