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1) Chemical Product and Company Identification In accordance with Regulation 1907/2006 SAFETY DATA SHEET (REACH), amended by Regulation 2015/830 3.01 / 20200501 SODIUM DICHROMATE 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY 1.1. Product identifier Name: Sodium dichromate (anhydrouS) SynonymS : Sodium bichromate anhydrouS CLP Annex I, index nr. 024-004-00-7 EC/EINECS No. : 234-190-3 CAS No. 10588-01-9, Chromic acid, Sodium Salt RegiStration nr : 01-2119435525-40-0015 1.2. Relevant identified uSeS of the SubStance or mixture and uSeS adviSed againSt 1.2.1 Intended use: USe of the SubStance iS limited to the authoriSation numberS: REACH/20/4/0: Formulation of mixtures for Surface treatment of metalS (Such aS aluminium, Steel, zinc, magnesium, titanium, alloys), compoSites, SealingS of anodic filmS and for uSe for electrolytic paSSivation of tin plated Steel for the packaging induStry intended excluSively for uSes REACH/20/4/1 and REACH/20/4/2 REACH/20/4/1: Surface treatment of metalS (such as aluminium, Steel, zinc, magnesium, titanium, alloys), compoSites and Sealings of anodic filmS for the aeroSpace induStry in Surface treatment procesSes in which any of the key functionalities liSted in the Annex iS required (See end of thiS MSDS) REACH/20/4/2: Electrolytic paSSivation of tin-plated Steel for the packaging induStry. SEE E-SDS FOR MORE INFORMATION 1.2.2 USeS adviSed againSt no information available 1.3 DetailS of the Supplier of the Safety dataSheet Supplier : GENTROCHEMA BV Lage Ham 190, NL-5102 AE Dongen, Nederland Tel.: +31.162.249020 E-mail : [email protected] WebSite : www.gentrochema.nl 1.4 Emergency telephone nr : during office hourS (08:30 - 17:00) : +31.183.304422 After office hourS (only for health profeSSionalS) : +44.844.892.01 2. HAZARDS IDENTIFICATION 2.1 ClaSSification of the SubStance 2.1.1. ClaSSification according to Regulation 1272/2008 EC Endpoint Hazard category Hazard Statement OxidiSing SolidS Oxid. Solid 2 H272: May intenSify fire; oxidiSer swallowed. Acute toxicity - Acute Tox. 3 H301: Toxic if Swallowed. oral: Acute toxicity - Acute Tox. 4 H312: Harmful in contact with Skin. 1 / 14 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. It is intended to describe the product in respect of safety requirements only. None of the information is to be taken to constitute a guarantee concerning the properties of this product. In accordance with Regulation 1907/2006 SAFETY DATA SHEET (REACH), amended by Regulation 2015/830 3.01 / 20200501 SODIUM DICHROMATE dermal: Acute toxicity - Acute Tox. 2 H330: Fatal if inhaled. inhalation: Skin corroSion / Skin Corr. 1B H314: CauSeS Severe Skin burnS and eye irritation: damage. ReSpiration ReSp. SenS. 1 H334: May cauSe allergy or aSthma sensitization: SymptomS or breathing difficultieS if inhaled. Skin SenSitation: Skin SenS. 1 H317: May cauSe an allergic Skin reaction. Reproductive Repr. 1B H360: May damage fertility or the Toxicity: unborn child Germ cell Muta. 1B H340: May cauSe genetic defectS mutagenicity: Carcinogenicity: Carc. 1B H350: May cauSe cancer Specific target STOT Rep. Exp. 1 H372: CauSeS damage to organS through organ toxicity - prolonged or repeated expoSure repeated: Affected organS: cardiovaScular/hematological: hematopoieSiS Route of expoSure: inhalation Specific concentration limitS: Concentration (%) ClaSSification >= 5.0 STOT SE3 / H335 >= 0.2 ReSp. SenS. 1 / H334 Skin SenS. 1 / H317 Endpoint Hazard category Hazard Statement HazardS to the Aquatic Acute 1 H400: Very toxic to aquatic life. aquatic environment (acute/short- term): HazardS to the Aquatic Chronic 1 H410: Very toxic to aquatic life with long aquatic laSting effectS. environment (long-term): 2.1.2. ClaSSification according to Regulation 67/548/EC Endpoint ClaSSification OxidiSing propertieS O; R8 Contact with combuStible material may cauSe fire Acute toxicity: Xn; R21 Harmful in contact with Skin. 2 / 14 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. It is intended to describe the product in respect of safety requirements only. None of the information is to be taken to constitute a guarantee concerning the properties of this product. In accordance with Regulation 1907/2006 SAFETY DATA SHEET (REACH), amended by Regulation 2015/830 3.01 / 20200501 SODIUM DICHROMATE T; R25 Toxic if Swallowed. Repeated doSe T; R48/23 Toxic: danger of SeriouS damage to health by prolonged toxicity: expoSure through inhalation. Irritation / CorroSion: C; R34 CauSeS burnS. Xi; R37 Irritating to reSpiratory SyStem SenSitiSation: R42/43 May cauSe SenSitiSation by inhalation and Skin contact. Carcinogenicity: Carc. Cat. 2; R45 May cauSe cancer. Mutagenicity - Muta. Cat. 2; R46 May cauSe heritable genetic damage. Genetic Toxicity: Toxicity to Repr. Cat. 2; R60 May impair fertility. reproduction - fertility: Toxicity to Repr. Cat. 2; R61 May cauSe harm to the unborn child. reproduction - development: Environment: N; R50/53 DangerouS for the environment; Very toxic to aquatic organiSmS, may cauSe long-term adverSe effectS in the aquatic environment. Specific concentration limitS: Concentration (%) ClaSSification >= 25.0 C; R34 CauSeS burnS. >= 5.0 — < 10.0 Xi; R36/37/38 Irritating to eyeS, reSpiratory SyStem and Skin. >= 0.2 R42/43 May cauSe SenSitization by inhalation and Skin contact. 2.2 Label elementS 2.2.1. Labelling according to Regulation 1272/2008 Product identifier : Sodium dichromate Index Nr : 024-004-00-7 Hazard Pictogram(S): Signal word : Danger Hazard Statement(S): 3 / 14 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. It is intended to describe the product in respect of safety requirements only. None of the information is to be taken to constitute a guarantee concerning the properties of this product. In accordance with Regulation 1907/2006 SAFETY DATA SHEET (REACH), amended by Regulation 2015/830 3.01 / 20200501 SODIUM DICHROMATE H272: May intenSify fire: oxidiSer H301: Toxic if Swallowed. H312: Harmful in contact with Skin. H314: CauSeS Severe Skin burnS and eye damage. H317: May cauSe an allergic Skin reaction. H330: Fatal if inhaled. H334: May cauSe allergy or aSthma SymptomS or breathing difficultieS if inhaled. H340: May cauSe genetic defectS H350: May cauSe cancer H360: May damage fertility or the unborn child. (FD) H372: CauSeS damage to organS through prolonged or repeated expoSure H410: Very toxic to aquatic life with long laSting effectS. Precautionary Statement(S) P202: Do not handle until all Safety precautionS have been read and underStood P281: USe perSonal protective equipment aS required P308+P313: IF expoSed or concerned: Get medical advice/attention P501: Dispose of contents/container to….. P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. RinSe Skin with water/Shower P301+P330+P331: IF SWALLOWED: rinSe mouth. Do NOT induce vomiting. P304+P340: IF INHALED: Remove victim to freSh air and keep at rest in a poSition comfortable for breathing. P305+P351+P338: IF IN EYES: RinSe cautiouSly with water for Several minuteS. Remove contact lenSeS, if preSent and eaSy to do. Continue rinSing. 2.3. Other hazardS PBT/vPvB criteria: Not relevant (inorganic SubStance) 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.1. SubStanceS Chemical characterization: Sodium dichromate, min 98,9 % Na2Cr2O7, with non hazardouS additionS CompoSition/information on ingredientS : EINECS nr : 234-190-3 CAS nr : 10588-01-9 Index No. 024-004-00-7 SubStance of Very High Concern : yes 4. FIRST AID MEASURES 4.1 DeScription of firSt aid meaSureS - General information: In caSe of contact, immediately fluSh eyeS or Skin with copiouS amountS of water for at leaSt 15 minutes while removing contaminated clothing and shoeS. - After inhalation: If inhaled, remove to freSh air. If not breathing, give artificial reSpiration. If breathing iS difficult, give oxygen. Get medical attention immediately. 4 / 14 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. It is intended to describe the product in respect of safety requirements only. None of the information is to be taken to constitute a guarantee concerning the properties of this product. In accordance with Regulation 1907/2006 SAFETY DATA SHEET (REACH), amended by Regulation 2015/830 3.01 / 20200501 SODIUM DICHROMATE Evacuate the victim to a Safe area aS Soon aS poSSible. LooSen tight clothing Such aS a collar, tie, belt or waiStband. If breathing iS difficult, adminiSter oxygen. It may be hazardouS to the perSon providing aid to give mouth-to-mouth reSuScitation aS the inhaled material iS toxic and corroSive. Seek immediate medical attention. - After skin contact: In caSe of contact, immediately fluSh Skin with plenty of water for at leaSt 15 minuteS while removing contaminated clothing and ShoeS. Cover the irritated Skin with an emollient. Cold water may be uSed.
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