Download (16Mb)

Total Page:16

File Type:pdf, Size:1020Kb

Download (16Mb) A Thesis Submitted for the Degree of PhD at the University of Warwick Permanent WRAP URL: http://wrap.warwick.ac.uk/127768 Copyright and reuse: This thesis is made available online and is protected by original copyright. Please scroll down to view the document itself. Please refer to the repository record for this item for information to help you to cite it. Our policy information is available from the repository home page. For more information, please contact the WRAP Team at: [email protected] warwick.ac.uk/lib-publications Dielectrics for Narrow Bandgap III-V Devices Oliver Vavasour School of Engineering University of Warwick Dissertation submitted for the degree of Doctor of Philosophy October 2018 Contents List of Figures vii List of Tables xiv List of Equations xvi Acknowledgements xvii Declaration xviii Abstract xx Nomenclature xxii 1 Introduction 1 1.1 Semiconductor Technology Applications . 1 1.1.1 Niches for Alternative Materials . 2 1.1.2 Use of Narrow Bandgap Materials . 2 1.2 III-V Semiconductor Materials . 2 1.2.1 Elemental and Compound Semiconductors . 2 1.2.2 Semiconductor Alloys . 3 1.3 Review of Narrow Bandgap Material Applications . 4 1.4 Thesis Outline . 5 2 Literature Review 7 2.1 Introduction . 7 2.1.1 Deposition Techniques . 8 2.1.2 Origin of Interface Trap States . 10 2.2 Dielectric Materials . 10 2.2.1 Silicon Dioxide . 11 2.2.2 Gadolinium/Gallium Oxide . 11 2.2.3 Aluminium Oxide . 11 2.2.4 Hafnium Oxide . 12 i Chapter 0 Section 0.0 2.2.5 Lanthanum Oxide . 14 2.2.6 Aluminium Nitride . 15 2.3 Trap Characteristics . 16 2.4 Pre-deposition Processing . 19 2.4.1 Wet Treatments . 19 2.4.2 Gas Treatments . 23 2.4.3 Plasma Treatments . 24 2.5 Post-deposition Processing . 29 2.6 Characterisation . 33 2.6.1 Methods . 33 2.6.2 Comparison . 34 2.7 Aluminium Indium Antimonide . 37 2.8 Conclusion . 39 3 Experimental Techniques 40 3.1 Introduction . 40 3.2 Process Technology Outline . 40 3.3 Material Growth . 42 3.3.1 Czochralski Growth . 42 3.3.2 Molecular Beam Epitaxy . 42 3.3.3 Alternative Techniques . 43 3.3.4 Doping . 45 3.4 Chemical Vapour Deposition (Dielectrics) . 45 3.4.1 Conventional Chemical Vapour Deposition . 45 3.4.2 Atomic Layer Deposition . 46 3.4.3 Choice of Precursors . 49 3.5 Physical Vapour Deposition (Metals) . 50 3.5.1 Evaporation . 50 3.5.2 Sputtering . 51 3.5.3 Choice of Metal . 51 3.6 Photolithography and Patterning . 52 3.6.1 Spin Deposition . 52 3.6.2 Photolithography Process . 52 3.6.3 Lift-off Patterning . 53 3.7 Wet Chemical Etching and Cleaning . 54 3.7.1 Acid Processes . 54 3.7.2 Alkali Processes . 54 3.7.3 Wet Chemical Cleaning . 55 ii Chapter 0 Section 0.0 3.7.4 Isotropy . 55 3.8 Annealing . 55 3.8.1 Annealing Modes . 55 3.8.2 Annealing Chemistry . 56 3.9 Electrical Characterisation . 56 3.9.1 Setup at University of Warwick . 57 3.9.2 Setup at University of Glasgow . 57 3.9.3 Measurement Correction . 58 3.10 Cryogenic and Vacuum Techniques . 58 3.10.1 Cryogenic System Architecture . 59 3.10.2 Heat Transfer . 59 3.10.3 Cryogenic Cooling . 60 3.10.4 Vacuum Techniques for Cryogenic Systems . 60 3.11 X-ray Photoelectron Spectroscopy . 62 3.11.1 XPS Fundamentals . 62 3.11.2 XPS Apparatus . 63 3.12 Transmission Electron Microscopy . 63 3.13 Atomic Force Microscopy . 64 3.14 Conclusion . 65 4 Theory of III-V MOS Capacitors 66 4.1 Introduction . 66 4.2 Ideal MOSCAP C-V Response . 66 4.2.1 Accumulation . 67 4.2.2 Depletion . 69 4.2.3 Inversion . 69 4.3 Effect of Trapped Charge on C-V Response and Data Extraction . 71 4.3.1 The High-Low Method . 72 4.3.2 The Terman Method . 76 4.4 Ideal Response of III-V MOSCAPs . 77 4.4.1 Band Structure of III-V Materials . 77 4.4.2 Modelling of III-V C-V Response . 78 4.5 Conductance Response and Analysis . 81 4.5.1 Conductance Modelling of Interface-trapped Charge Density . 83 4.5.2 Interface-trapped Charge Energy Level in Conductance Re- sponse Models . 84 4.6 Material Modelling . 85 4.6.1 Temperature Dependence of Material Parameters . 87 iii Chapter 0 Section 0.0 4.6.2 Ternary Alloys . 89 4.7 Conclusion . 89 5 Modelling and Analysis of InSb MOS Capacitors 91 5.1 Introduction . 91 5.2 Architecture of Modelling and Analysis Code . 91 5.2.1 Modelling Parameters and Optimisation . 94 5.2.2 Analysis and Key Figures of Merit . 95 5.3 Extraction of Key Data . 98 5.3.1 Dopant Concentration . 98 5.3.2 Oxide Capacitance . 99 5.4 Verification Against Literature Data . 100 5.4.1 C-V Curve for InGaAs . 101 5.4.2 Carrier Concentration for InSb . 101 5.5 Typical Features of Electrical Characterisation . 103 5.6 High-Field Narrow Bandgap Effects . 108 5.6.1 Zener Tunnelling . 109 5.6.2 Impact Ionisation . 112 5.6.3 Quantum Capacitance . 113 5.7 Conclusion . 116 6 Pre-Deposition Treatments 117 6.1 Introduction . 117 6.2 XPS of HCl-Cleaned Surfaces . 117 6.3 HCl-Cleaned MOS Capacitors . 123 6.4 Plasma-Cleaned MOS Capacitors . 130 6.4.1 Experimental Methodology . 130 6.4.2 Results and Discussion . 131 6.5 Conclusion and Further Work . 137 7 Post-deposition Annealing 140 7.1 Introduction . 140 7.2 Experimental Methodology . 140 7.3 Material Breakdown at High Temperature . 142 7.4 Hysteresis Response to Annealing . 144 7.5 Interface-Trapped Charge Response to Annealing . 147 7.6 Flatband Voltage Response to Annealing . 149 7.7 Conclusion and Further Work . 151 iv Chapter 0 Section 0.0 8 AlInSb Ternary Alloy 153 8.1 Introduction . 153 8.2 Strained AlInSb with Low Al Composition . 154 8.2.1 Diode Characterisation (Dopant Concentration) . 154 8.2.2 Atomic Force Microscopy Characterisation (Surface Defects) . 156 8.3 Relaxed AlInSb with High Al Composition . 157 8.4 AlInSb MOSCAP Devices . 158 8.4.1 Interface-trapped Charge in AlInSb Materials . 160 8.4.2 Flatband Voltage in AlInSb Materials . ..
Recommended publications
  • Physical Properties and Data of Optical Materials
    Physical Properties and Data of Optical Materials Moriaki Wakaki Keiei Kudo Takehisa Shibuya Laß) CRC Press ^^ J Taylor &. Francis Group '*-*"' Boca Raton London New York CRC Press is an imprint of the Taylor & Francis Group, an informa business • Table of Contents A AI (Aluminum) 1 AlSb (Aluminium Antimonide) 10 ADP (Ammonium Dihydrogen Phosphate) 16 Sb (Antimony) 21 Arsenic Selenium Glass 26 As (33%) + S (30%) + Br (37%) (Arsenic-Sulfur-Bromine Glass) 28 As2Se3 (Arsenic Tri-Selenide) 30 As2S3 (Arsenic Tri-Sulfide Glass) 33 6 Ba (Barium) 39 BaF2 (Barium Fluoride) 42 BaTi03 (Barium Titanate) 47 Be (Beryllium) 50 BeO (Beryllium Oxide) 54 Bi(Bismuth) 56 B(Boron) 61 C Cd(Cadmium) 65 CdSe (Cadmium Selenide) 70 CdS (Cadmium Sulfide) 75 CdTe (Cadmium Telluride) 82 CaC03 (Calcite) 89 CaF2 (Calcium Fluoride) 96 CaW04 (Calcium Tungstate) 105 CsBr (Cesium Bromide) 108 Csl (Cesium Iodide) 113 Cr(Chromium) 118 Cu(Copper) 122 CuCl (Cuprous Chloride) 128 D Diamond 135 G Ga (Gallium) 139 GaSb (Gallium Antimonide) 142 GaAs (Gallium Arsenide) 149 GaP (Gallium Phosphide) 158 Ge (Germanium) 165 Ge + Se + Te (Germanium-Selenium-Tellurium Glass) 180 Glass 182 Au (Gold) 191 * I In (Indium) 199 InSb (Indium Antimonide) 202 InAs (Indium Arsenide) 212 InP (Indium Phosphide) 218 Ir (Iridium) 224 Fe(Iron) 228 L LaF3 (Lanthanum Fluoride) 233 PbF2 (Lead Fluoride) 236 PbSe (Lead Selenide) 237 PbS (Lead Sulfide) 243 PbTe (Lead Telluride) 251 LiF (Lithium Fluoride) 257 Lucite 266 M Mg (Magnesium) 269 MgF2 (Magnesium Fluoride) 275 Mg2Ge (Magnesium Germanide) 282 MgO (Magnesium
    [Show full text]
  • Chemical Names and CAS Numbers Final
    Chemical Abstract Chemical Formula Chemical Name Service (CAS) Number C3H8O 1‐propanol C4H7BrO2 2‐bromobutyric acid 80‐58‐0 GeH3COOH 2‐germaacetic acid C4H10 2‐methylpropane 75‐28‐5 C3H8O 2‐propanol 67‐63‐0 C6H10O3 4‐acetylbutyric acid 448671 C4H7BrO2 4‐bromobutyric acid 2623‐87‐2 CH3CHO acetaldehyde CH3CONH2 acetamide C8H9NO2 acetaminophen 103‐90‐2 − C2H3O2 acetate ion − CH3COO acetate ion C2H4O2 acetic acid 64‐19‐7 CH3COOH acetic acid (CH3)2CO acetone CH3COCl acetyl chloride C2H2 acetylene 74‐86‐2 HCCH acetylene C9H8O4 acetylsalicylic acid 50‐78‐2 H2C(CH)CN acrylonitrile C3H7NO2 Ala C3H7NO2 alanine 56‐41‐7 NaAlSi3O3 albite AlSb aluminium antimonide 25152‐52‐7 AlAs aluminium arsenide 22831‐42‐1 AlBO2 aluminium borate 61279‐70‐7 AlBO aluminium boron oxide 12041‐48‐4 AlBr3 aluminium bromide 7727‐15‐3 AlBr3•6H2O aluminium bromide hexahydrate 2149397 AlCl4Cs aluminium caesium tetrachloride 17992‐03‐9 AlCl3 aluminium chloride (anhydrous) 7446‐70‐0 AlCl3•6H2O aluminium chloride hexahydrate 7784‐13‐6 AlClO aluminium chloride oxide 13596‐11‐7 AlB2 aluminium diboride 12041‐50‐8 AlF2 aluminium difluoride 13569‐23‐8 AlF2O aluminium difluoride oxide 38344‐66‐0 AlB12 aluminium dodecaboride 12041‐54‐2 Al2F6 aluminium fluoride 17949‐86‐9 AlF3 aluminium fluoride 7784‐18‐1 Al(CHO2)3 aluminium formate 7360‐53‐4 1 of 75 Chemical Abstract Chemical Formula Chemical Name Service (CAS) Number Al(OH)3 aluminium hydroxide 21645‐51‐2 Al2I6 aluminium iodide 18898‐35‐6 AlI3 aluminium iodide 7784‐23‐8 AlBr aluminium monobromide 22359‐97‐3 AlCl aluminium monochloride
    [Show full text]
  • Jb Enterprises
    +91-8048372629,937 Jb Enterprises https://www.indiamart.com/jbenterprises-hyderabad/ We are trader and supplier of a wide array of Flexible Printing , Silver Pouches, Heat Silver Pouches, Papr Lamination,Silicon oil ,Silicon Grease,Printing ink & many more. About Us Incorporated in the year 2015 at Hyderabad, Telangana, India, we JB Enterprises are a Sole Proprietorship based company, conceived its business operations as a distinguished as a trustworthy trader and supplier of a wide array of Aluminium Antimonide, Aluminum Arsenide, Aluminium Boride, Aluminium Bromide, Aluminium Carbide, Aluminum Fluoride, Aluminum Iodide, Aluminium Molybdate, Aluminium Nitride, Aluminium Oxide, Aluminum Sulfide, Aluminium Telluride, Aluminium Tungstate, Aluminium Zirconate, Ammonium Chloride & many more. Offered chemicals are widely demanded in the market, owing to their indispensable features like balanced composition, high purity level, long shelf life and eco-friendly nature. These chemicals are procured from the certified vendors of the market. Provided chemicals serve a wide number of industries. Under the strict guidance of Jagdish Chandra Bandaragal (Proprietor), our company has been able to carve a distinct place in the industry. He frequently coordinates with the team and makes them updated with the current market trends. For more information, please visit https://www.indiamart.com/jbenterprises-hyderabad/about-us.html O u r P r o d u c t s R E T S Y L O P G N I T N I R P Rotogravure Printing Rotogravure Film Printing Paper With Film Lamination
    [Show full text]
  • Semiconductors Group IV Elements and III-V Compounds
    Data in Science and Technology Editor in Chief: R. Poerschke Semiconductors Group IV Elements and III-V Compounds Editor: O. Madelung Springer-Verlag Berlin Heidelberg New York London Paris Tokyo Hong Kong Barcelona ISBN-13: 978-3-540-53150-0 e-ISBN-13: 978-3-642-45681-7 001: 10.1007/978-3-642-45681-7 Library of Congress Cataloging-in-Publication Data Semiconductors: group IV elements and II I-V compounds I editor, o. Madelung. p. cm. -- (Data in science and technology) Includes bibliographical references. ISBN 978-3-54().53150.o (Springer-Verlag Berlin Heidelberg New York : acid-free paper) I. Semiconductors--Handbooks, manuals, etc. I. Madelung, O. (Otfried) II. Series QC611.45.S46 1991 537.6'22--dc20 90-26078 CIP This work is subject to copyright All rights are reserved, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, broadcasting, repro­ duction on microfilms or other ways, and storage in data banks_ Duplication of this publication or parts thereofis only permitted under the provisions of the German Copyright LawofSeptember9, 1965,in its current version, and a copyright fee must always be paid. Violations fall under the prosecution act ofthe German Copyright Law_ © Springer-Verlag Berlin Heidelberg 1991 The use of registered names, trademarks, etc_ in this publication does not imply, even in the absence ofa specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. Typesetting: Thomson Press, Ltd_, New Delhi, India 216313040-543210 - Printed on acid-free paper Preface The frequent use of well known critical data handbooks like Beilstein, Gmelin and Landolt­ Bornstein is impeded by the fact that merely larger libraries - often far away from the scientist's working place - can afford such precious collections.
    [Show full text]
  • Micro-Analysis Consultants Ltd
    Micro-Analysis Consultants Ltd. Reference Standards for X-Ray Microanalysis. The standards supplied are suitable for electron-beam Energy Dispersive or Wavelength Dispersive X-Ray microanalysis systems. MAC only purchase reference samples from leading suppliers to ensure consistent high quality; the samples are fitted into brass blanks in our own modern factory; diamond polished to a 0.25 micron finish and carbon coated. Every single reference standard is tested with our own Analysis/SEM Equipment before shipping. This attention to detail has gained MAC a reputation for unsurpassed technical excellence during the past decade. Whilst MAC are uncompromising in their approach to quality, they also appreciate the importance of realistic delivery times and economical prices. MAC obtained certification to BS EN ISO 9002:1994 in April 1997. All the standards are supplied with a certificate of analysis and a large number of the standard materials are traceable to a national institution, as a standard reference material (SRM). Each block of standards has its own unique number allocated to it, and recorded, and comes with a map for standard identification. We have all of our records back to the first block of standards produced in 1981. A Faraday Cup, for accurate specimen current measurements, is available as standard on some blocks, and as an optional extra on the others. We can produce standard blocks in several different materials (Brass, Aluminium, Stainless Steel, Carbon Resin), or sizes, to customers requirements. Carousels, 13mm dia. blocks to fit Pin stubs, and singles of 5mm, 3mm, 2mm are also available. We have over 300 different standards material to choose from which include rare earth’s, SRM’s, Compounds and pure elements.
    [Show full text]
  • List of Semiconductor Materials - Wikipedia, the Free Encyclopedia Page 1 of 4
    List of semiconductor materials - Wikipedia, the free encyclopedia Page 1 of 4 List of semiconductor materials From Wikipedia, the free encyclopedia Semiconductor materials are insulators at absolute zero temperature that conduct electricity in a limited way at room temperature. The defining property of a semiconductor material is that it can be doped with impurities that alter its electronic properties in a controllable way. Because of their application in devices like transistors (and therefore computers) and lasers, the search for new semiconductor materials and the improvement of existing materials is an important field of study in materials science. The most commonly used semiconductor materials are crystalline inorganic solids. These materials can be classified according to the periodic table groups from which their constituent atoms come. Semiconductor materials are differing by their properties. Compound semiconductors have advantages and disadvantages in comparison with silicon. For example gallium arsenide has six times higher electron mobility than silicon, which allows faster operation; wider band gap, which allows operation of power devices at higher temperatures, and gives lower thermal noise to low power devices at room temperature; its direct band gap gives it more favorable optoelectronic properties than the indirect band gap of silicon; it can be alloyed to ternary and quaternary compositions, with adjustable band gap width, allowing light emission at chosen wavelengths, and allowing e.g. matching to wavelengths with lowest losses in optical fibers. GaAs can be also grown in a semiinsulating form, which is suitable as a lattice-matching insulating substrate for GaAs devices. Conversely, silicon is robust, cheap, and easy to process, while GaAs is brittle, expensive, and insulation layers can not be created by just growing an oxide layer; GaAs is therefore used only where silicon is not sufficient.[1] Some materials can be prepared with tunable properties, e.g.
    [Show full text]
  • Pure Elements REE Glass Standards Multi-Element Standards
    3_Calibration_Standards_Specimens_0510:Layout 1 17/6/10 16:28 Page 78 Calibration standards and specimens Multi-element standards The tables show the complete list of certified pure element and compound standards from which the user may select the most appropriate combination to suit their application. Alloy standards are also available. Individual or multi element reference standards can be chosen from the selection of pure elements, compounds, REE glass, minerals, and metals, listed in the following tables. Pure elements Ag Silver In Indium Se Selenium Al Aluminium Ir Iridium Si Silicon As Arsenic Mg Magnesium Sn Tin Au Gold Mn Manganese Ta Tantalum B Boron Mo Molybdenum Tb Terbium Be Beryllium Nb Niobium Te Tellurium Bi Bismuth Nd Neodymium Ti Titanium C Carbon Ni Nickel Tl Thallium Cd Cadmium Os Osmium Tm Thulium Co Cobalt Pb Lead V Vanadium Cr Chromium Pd Palladium W Tungsten Cu Copper Pt Platinum Y Yttrium Dy Dysprosium Re Rhenium Yb Ytterbium Fe Iron Rh Rhodium Zn Zinc Gd Gadolinium Ru Ruthenium Zr Zirconium Ge Germanium Sb Antimony Hf Hafnium Sc Scandium REE glass standards Ba Barium REE glass K Potassium REE glass Sr Strontium REE glass Ce Cerium REE glass La Lanthanum REE glass Tb Terbium REE glass Ce, Eu, Ho, Tm REE glass 4 % each La, Sm, Gd, Yb REE glass 4 % each Th Thorium REE glass Cs Cesium REE glass Lu Lutetium REE glass Tm Thulium REE glass Dy Dysprosium REE glass Nd Neodymium REE glass U Uranium REE glass Er Erbium REE glass Nd, Th, Lu REE glass 4 % each Y Yttrium REE glass Eu Europium REE glass Pr Praseodymium REE glass
    [Show full text]
  • Devices and Circuits Sheila Prasad, Hermann Schumacher and Anand Gopinath Excerpt More Information
    Cambridge University Press 978-0-521-86283-7 - High-Speed Electronics and Optoelectronics: Devices and Circuits Sheila Prasad, Hermann Schumacher and Anand Gopinath Excerpt More information Part One Devices © Cambridge University Press www.cambridge.org Cambridge University Press 978-0-521-86283-7 - High-Speed Electronics and Optoelectronics: Devices and Circuits Sheila Prasad, Hermann Schumacher and Anand Gopinath Excerpt More information 1 Review of semiconductor materials and physics 1.1 Executive summary Semiconductor devices are fabricated using specific materials that offer the desired physical properties. There are three classes of solid state materials: insulators, semi- conductors and conductors. This distinction is based on the electrical conductivity of these materials with insulators having the lowest and conductors having the highest con- ductivity. Semiconductors fall in between and their conductivity is affected by several factors such as temperature, the incidence of light, the application of a magnetic field and impurities. This versatility makes semiconductors very important in electronics and optoelectronics applications. Semiconductors themselves are divided into two classes: elemental and compound. Each type has distinctive physical properties which are exploited in device design. Typ- ical elemental semiconductor device materials are silicon and germanium; examples of compound semiconductors are GaAs, InP, AlGaAs and SiGe. The single crystal struc- ture of these materials is that of a periodic lattice and this determines the properties of the semiconductors. Silicon has the diamond crystal structure and the compound semiconductors have the zincblende lattice structure. The bonding between atoms in a crystal of the semiconductors is termed covalent bonding, where electrons are shared between atoms. Fundamental principles of quantum mechanics are applied to determine the energy band structure of the semiconductor.
    [Show full text]
  • Deterministic Placement of Doping Atoms on Silanol Surfaces for Ultimate Devices Laurent Mathey
    Deterministic placement of doping atoms on silanol surfaces for ultimate devices Laurent Mathey To cite this version: Laurent Mathey. Deterministic placement of doping atoms on silanol surfaces for ultimate devices. Other. Université Claude Bernard - Lyon I, 2012. English. NNT : 2012LYO10235. tel-00908954 HAL Id: tel-00908954 https://tel.archives-ouvertes.fr/tel-00908954 Submitted on 25 Nov 2013 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. N°àdode Année 2012 235-2012 THE“EàDEàLUNIVE‘“ITEàDEàLYON Délivrée par LUNIVE‘“ITEàCLáUDEàBE‘Ná‘DàLYONàà ECOLE DOCTORALE CHIMIE (ED206) DIPLOME DE DOCTORAT (arrêté du 7 août 2006) soutenue publiquement le 5 novembre 2012 par M. Laurent MATHEY TITRE : Placement déterministe de dopants pour dispositifs ultimes Directeur de thèse : M. Christophe COPERET JURY : M. Didier BOURISSOU RAPPORTEURS : M. Didier BOURISSOU M. Christophe COPERET M. Marc SANQUER M. Brice GAUTIER M. François MARTIN M. Dominique MASSIOT M. Marc SANQUER Mme Chloé THIEULEUX ii UNIVERSITE CLAUDE BERNARD - LYON 1 Président de l’Université M. François-Noël GILLY Vice-président du Conseil d’Administration M. le Professeur Hamda BEN HADID Vice-président du Conseil des Etudes et de M. le Professeur Philippe LALLE Vice-président du Conseil Scientifique M.
    [Show full text]
  • (12) Patent Application Publication (10) Pub. No.: US 2016/0240821 A1 CARROLL Et Al
    US 20160240821A1 (19) United States (12) Patent Application Publication (10) Pub. No.: US 2016/0240821 A1 CARROLL et al. (43) Pub. Date: Aug. 18, 2016 (54) FREQUENCY DEPENDENT LIGHT HOIL 33/42 (2006.01) EMITTING DEVICES HOIL 33/30 (2006.01) (71) Applicant: WAKE FOREST UNIVERSITY, HOIL 33/00 (2006.01) Winston-Salem, NC (US) (52) U.S. Cl. CPC ........ HOIL 51/5296 (2013.01); HOIL 51/5206 (72) Inventors: David CARROLL, Winston-Salem, NC (2013.01); HOIL 51/5234 (2013.01); HOIL (US); Robert SUMMERS, Clemmons, 33/30 (2013.01); HOIL 33/004I (2013.01); NC(US); Yonghua CHEN, Cleveland HOIL 33/42 (2013.01); H05B33/08 (2013.01); Height, OH (US) HOIL 225 1/303 (2013.01); HOIL 5 1/5016 (21) Appl. No.: 15/024,624 (2013.01) (22) PCT Filed: Sep. 26, 2014 (57) ABSTRACT (86). PCT No.: PCT/US2014/057774 S371 (c)(1), (2) Date: Mar. 24, 2016 An electroluminescent device described herein, in one aspect, comprises a first electrode and second electrode and a light Related U.S. Application Data emitting layer positioned between the first and second elec trodes. A current injection gate is positioned between the first (60) Provisional application No. 61/883,710, filed on Sep. electrode and the light emitting layer or the second electrode 27, 2013. and the light emitting layer. In some embodiments, the cur Publication Classification rent injection gate comprises a semiconductor layer of elec tronic structure restricting injected current flow from the first (51) Int. Cl. or second electrode through the semiconductor layer as a HOIL 5/52 (2006.01) function of alternating current Voltage frequency applied to H05B33/08 (2006.01) the first and second electrodes.
    [Show full text]
  • L-G-0002281250-0003064602.Pdf
    WILEY'S ENGLISH-SPANISH, SPANISH-ENGLISH CHEMISTRY DICTIONARY WILEY'S ENGLISH-SPANISH, SPANISH-ENGLISH CHEMISTRY DICTIONARY Second Edition Steven M. Kaplan Lexicographer WILEY Copyright © 2014 by John Wiley & Sons, Inc. All rights reserved. Published by John Wiley & Sons, Inc., Hoboken, New Jersey. All rights reserved. Published simultaneously in Canada. No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, scanning, or otherwise, except as permitted under Section 107 or 108 of the 1976 United States Copyright Act, without either the prior written permission of the Publisher, or authorization through payment of the appropriate per-copy fee to the Copyright Clearance Center, Inc., 222 Rosewood Drive, Danvers, MA 01923, (978) 750-8400, fax (978) 750-4470, or on the web at www.copyright.com. Requests to the Publisher for permission should be addressed to the Permissions Department, John Wiley & Sons, Inc., 111 River Street, Hoboken, NJ 07030, (201) 748-6011, fax (201) 748- 6008, or online at http://www.wiley.com/go/permission. Limit of Liability/Disclaimer of Warranty: While the publisher and author have used their best efforts in preparing this book, they make no representations or warranties with respect to the accuracy or completeness of the contents of this book and specifically disclaim any implied warranties of merchantability or fitness for a particular purpose. No warranty may be created or extended by sales representatives or written sales materials. The advice and strategies contained herein may not be suitable for your situation. You should consult with a professional where appropriate.
    [Show full text]
  • Danh Mục Số Cas A
    CÔNG TY CỔ PHẦN CÔNG NGHIỆP VIỆT XUÂN NHÀ CUNG CẤP KHÍ HELI, KHÍ METAN, KHÍ SF6, KHÍ PROPAN Số 80B Nguyễn Văn Cừ - Long Biên - Hà Nội - Việt Nam www.vietxuangas.com.
    [Show full text]