31St Annual Franklin-Sterling Mineral Exhibit
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The Structure and Composition of the Mineral Pharmacosiderite
Zeitschrift fUr Kristallographie, Bd. 125, S. 92-108 (1967) The structure and composition of the mineral pharmacosiderite By M. J. BUERGER, W. A. DOLLASE* and ISABEL GARAYCOCHEA-WITTKE** Massachusetts Institute of Technology, Cambridge, Massachusetts Dedicated to Prof. Dr. G. Menzer on the occasion of his 70th birthday (Received April 17, 1967) Auszug Eine Struktur von Pharmakosiderit wurde von ZEMANN 1947 vorgeschlagen. An einem Pharmakosiderit von Cornwall untersuchten wir die Struktur von neuem. Obwohl die starken Reflexe mit P43m bei a = 7,98 A im Einklang sind, in Ubereinstimmung mit ZEMANNS Ergebnissen, verlangen doch einige schwa- chere Reflexe eine groJ3ere Elementarzelle, was zusammen mit einer schwachen Doppelbrechung auf eine geringere Symmetrie hinweist. Wegen der Inhomogeni- tat des Materials muJ3ten wir uns auf die Untersuchung einer gemittelten Struk- tur, bezogen auf eine isometrische Zelle mit a = 7,98 A, beschranken. Wir konn- ten die Struktur bis zu R = 6!% verfeinern. Unsere Untersuchung bestatigt das von ZEMANN vorgeschlagene Strukturgerust, andert jedoch etwas an der Aus- fUllung der offenen Raume, an der keine Alkaliatome beteiligt sind. Wenn die Struktur auf die isometrische Zelle mit a = 7,98 A bezogen wird, so konnen die Wassermolekiile nur teilweise die Punktlagen besetzen, denen sie zugeordnet sind. Wir schlieJ3en daraus, daJ3 das Pharmakosiderit-Gerust kontinuierlich ist, das Wasser in den Hohlraumen jedoch die Symmetrie verringert, und daJ3 sich der einheitlich erscheinende Kristall in Wirklichkeit aus Bereichen zusanunen- setzt, in denen die Anordnung der Wassermolekule einheitlich ist, aber an den Bereichsgrenzen Zwillingsorientierungen aufweist. Es wird gezeigt, daJ3 bei Behandlung von Pharmakosiderit mit Alkalihydro- xyd-Losungen Alkaliatome in die Struktur eindringen. -
Washington State Minerals Checklist
Division of Geology and Earth Resources MS 47007; Olympia, WA 98504-7007 Washington State 360-902-1450; 360-902-1785 fax E-mail: [email protected] Website: http://www.dnr.wa.gov/geology Minerals Checklist Note: Mineral names in parentheses are the preferred species names. Compiled by Raymond Lasmanis o Acanthite o Arsenopalladinite o Bustamite o Clinohumite o Enstatite o Harmotome o Actinolite o Arsenopyrite o Bytownite o Clinoptilolite o Epidesmine (Stilbite) o Hastingsite o Adularia o Arsenosulvanite (Plagioclase) o Clinozoisite o Epidote o Hausmannite (Orthoclase) o Arsenpolybasite o Cairngorm (Quartz) o Cobaltite o Epistilbite o Hedenbergite o Aegirine o Astrophyllite o Calamine o Cochromite o Epsomite o Hedleyite o Aenigmatite o Atacamite (Hemimorphite) o Coffinite o Erionite o Hematite o Aeschynite o Atokite o Calaverite o Columbite o Erythrite o Hemimorphite o Agardite-Y o Augite o Calciohilairite (Ferrocolumbite) o Euchroite o Hercynite o Agate (Quartz) o Aurostibite o Calcite, see also o Conichalcite o Euxenite o Hessite o Aguilarite o Austinite Manganocalcite o Connellite o Euxenite-Y o Heulandite o Aktashite o Onyx o Copiapite o o Autunite o Fairchildite Hexahydrite o Alabandite o Caledonite o Copper o o Awaruite o Famatinite Hibschite o Albite o Cancrinite o Copper-zinc o o Axinite group o Fayalite Hillebrandite o Algodonite o Carnelian (Quartz) o Coquandite o o Azurite o Feldspar group Hisingerite o Allanite o Cassiterite o Cordierite o o Barite o Ferberite Hongshiite o Allanite-Ce o Catapleiite o Corrensite o o Bastnäsite -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
Jarosewichite and a Related Phase: Basic Manganese Arsenates of the Chlorophoenicite Group from Franklin, New Jersey
American Mineralogist, Volume 67, pages 1043-1047,1962 Jarosewichite and a related phase: basic manganese arsenates of the chlorophoenicite group from Franklin, New Jersey Pe,re J. DUNN Department of Mineral Sciences Smit hsonian I nstit utio n Washington, D.C.20560 DoNelo R. Pr,econ Department of Geological Sciences University of Michigan Ann Arbor, Michigan 48109 PBrBn B. LBeveNs Department of Geology University of Delaware Newark, Delaware l97II eNo Wrllreu B. SIuuoNs Department of Earth Sciences University of New Orleans New Orleans. Louisiana 70148 Abstract Jarosewichite,Mn3+Mn3+(AsOn)(OH)0, is a new mineral, closely related to chloro- phoenicite,from the Franklin mine, Franklin, SussexCounty, New Jersey,where it occurs associatedwith andradite,franklinite, flinkite, cahniteand hausmannite.Jarosewichite is orthorhombic,space grotp C2lmLlm2lm,C222 or Cmm2,with a : 6.56(3),b : 25.20(10),c : 10.00(5)4,and Z : 8. The strongestlines in the X-ray powder difraction patternare (d, I, hkD2.669 100 222,082;3.91 60 042,061;1.788 50 (notindexed);2.503 30 242,261,004,0 l0 0. Jarosewichiteis dark red, occursin prismaticbarrel-shaped aggregates, has a density of 3.66(obs),3.70glcm3(calc).Itisbiaxial(-)withrefractiveindicesd= 1.780(5),p= 1.795(5)and y= 1.805(5);theorientationisX:a,Y: b,Z = c;pleochroismisweak,Z) X. Microprobeanalysis with Mn3+calculated, yields: FeO 0.4, MgO 2.l,CaO0.2,ZnO 1.2, MnO 42.3, Mn2O317.7 (IMn = 45.1 wt.%), AszOs24.0, with H2O 12.1 percent by difference,sum : 100.0percent. A secondmanganese arsenate from Franklin, New Jersey,is alsorelated to chlorophoen- icite, but may be heterogeneous.Although optical, chemicaland crystallographicproper- ties are characterized,there is sufficient ambiguity to deny it speciesstatus at this time. -
THE SINGLE-CRYSTAL X-RAY STRUCTURES of BARIOPHARMACOSIDERITE-C, BARIOPHARMACOSIDERITE-Q and NATROPHARMACOSIDERITE
1477 The Canadian Mineralogist Vol. 48, pp. 1477-1485 (2010) DOI : 10.3749/canmin.48.5.1477 THE SINGLE-CRYSTAL X-RAY STRUCTURES OF BARIOPHARMACOSIDERITE-C, BARIOPHARMACOSIDERITE-Q and NATROPHARMACOSIDERITE SIMON L. HAGER, PETER LEVERETT§ AND PETER A. WILLIAMS School of Natural Sciences, University of Western Sydney, Locked Bag 1797, Penrith South DC, NSW 1797, Australia STUART J. MILLS Department of Earth and Ocean Sciences, University of British Columbia, Vancouver, British Columbia V6T 1Z4, Canada DavID E. HIBBS School of Pharmacy, University of Sydney, Sydney, NSW 2006, Australia MATI RAUDSEPP Department of Earth and Ocean Sciences, University of British Columbia, Vancouver, British Columbia V6T 1Z4, Canada ANTHONY R. KAMPF Mineral Sciences Department, Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, California 90007, USA WILLIAM D. BIRCH Geosciences Section, Museum Victoria, GPO Box 666, Melbourne, Victoria 3001, Australia ABSTRACT The crystal structures of two polymorphic forms of bariopharmacosiderite have been determined. Bariopharmacosiderite-C, from Robinson’s Reef, Clunes, Victoria, Australia, (Ba0.47K0.04Na0.02)(Fe3.97Al0.03)[(As0.72P0.28)O4]3(OH)4•2.52H2O, is cubic, space group P43m, a 7.942(1) Å, Z = 1, R = 0.089. Bariopharmacosiderite-Q, from the Sunny Corner mine, Sunny Corner, New South Wales, Australia, Ba0.5Fe4(OH)4(AsO4)3•6.16H2O, is tetragonal, space group P42m, a 7.947(1), c 8.049(2) Å, Z = 1, R = 0.050. In the cubic polymorph, Ba ions are disordered over all faces of the unit cell, whereas in the tetragonal polymorph, Ba ions are centered on the 001 face. -
Nelenite, a Manganese Arsenosilicate of the Friedelite Group, Polymorphous with Schallerite, from Franklin, New Jersey
MINERALOGICAL MAGAZINE, JUNE 1984, VOL. 48, PP. 271-5 Nelenite, a manganese arsenosilicate of the friedelite group, polymorphous with schallerite, from Franklin, New Jersey PETE J. DUNN Department of Mineral Sciences, Smithsonian Institution, Washington, DC 20560, USA AND DONALD R. PEACOR Department of Geological Sciences, University of Michigan, Ann Arbor, Michigan 48109, USA ABSTRACT. Nelenite, (Mn,Fe)16Si1203o(OH)'4[As~+06 typically related to schallerite. We have examined (OHh], is a polymorph of schallerite and a member of the this material in light of current knowledge of the friedelite group. X-ray diffraction patterns can be indexed crystal chemistry of friedelite and schallerite and on a supercell with a = 13.418(5) and c = 85.48(8) A, have found it to be a unique and valid species. The space group R3m, but by analogy with TEM results on mcGillite and friedelite, the structure is based on a old name,jerroschallerite, is a misnomer in that this one-layer monoclinic cell with a 23.240, b 13.418, material is not the Fe-analogue of schallerite and = = does not have the schallerite structure. Hence, we c = 7.382 A, {3= 105.21°, and space group C21m. Chemi- cal analysis yields Si02 31.12, FeO 17.12, MgO 0.12, have renamed it to avoid confusion. ZnO 3.63, MnO 29.22, As203 12.46, H20 6.42, sum = We take pleasure in naming this new mineral 100.09 %. Analysis of a number of samples indicates that nelenite in honour of Joseph A. Nelen, Chemist at Fe substitutes for Mn up to 5.8 of the 16 octahedrally the Smithsonian Insitution, in recognition of his coordinated cations, but that the Si: As ratio is constant. -
Topographical Index
997 TOPOGRAPHICAL INDEX EUROPE Penberthy Croft, St. Hilary: carminite, beudantite, 431 Iceland (fsland) Pengenna (Trewethen) mine, St. Kew: Bondolfur, East Iceland: pitchsbone, beudantite, carminite, mimetite, sco- oligoclase, 587 rodite, 432 Sellatur, East Iceland: pitchs~one, anor- Redruth: danalite, 921 thoclase, 587 Roscommon Cliff, St. Just-in-Peuwith: Skruthur, East Iceland: pitchstonc, stokesite, 433 anorthoclase, 587 St. Day: cornubite, 1 Thingmuli, East Iceland: andesine, 587 Treburland mine, Altarnun: genthelvite, molybdenite, 921 Faroes (F~eroerne) Treore mine, St. Teath: beudantite, carminite, jamesonite, mimetite, sco- Erionite, chabazite, 343 rodite, stibnite, 431 Tretoil mine, Lanivet: danalite, garnet, Norway (Norge) ilvaite, 921 Gryting, Risor: fergusonite (var. risSrite), Wheal Betsy, Tremore, Lanivet: he]vine, 392 scheelite, 921 Helle, Arendal: fergusonite, 392 Wheal Carpenter, Gwinear: beudantite, Nedends: fergusonite, 392 bayldonite, carminite, 431 ; cornubite, Rullandsdalen, Risor: fergusonite, 392 cornwallite, 1 Wheal Clinton, Mylor, Falmouth: danal- British Isles ire, 921 Wheal Cock, St. Just-in- Penwith : apatite, E~GLA~D i~D WALES bertrandite, herderite, helvine, phena- Adamite, hiibnerite, xliv kite, scheelite, 921 Billingham anhydrite mine, Durham: Wheal Ding (part of Bodmin Wheal aph~hitalite(?), arsenopyrite(?), ep- Mary): blende, he]vine, scheelite, 921 somite, ferric sulphate(?), gypsum, Wheal Gorland, Gwennap: cornubite, l; halite, ilsemannite(?), lepidocrocite, beudantite, carminite, zeunerite, 430 molybdenite(?), -
New Mineral Names*
American Mineralogist, Volume 96, pages 1654–1661, 2011 New Mineral Names* PAULA C. PIILONEN,1,† RALPH ROWE,1 GLENN POIRIER,1 AND KIMBERLY T. TAIT2 1Mineral Sciences Division, Canadian Museum of Nature, P.O. Box 3443, Station D, Ottawa, Ontario K1P 6P4, Canada 2Department of Natural History, Royal Ontario Museum,100 Queen’s Park, Toronto, Ontario M5S 2C6, Canada NEW MINERALS The streak is white and the Mohs hardness is estimated to be about 1½. Thin crystal fragments are flexible, but not elastic. The fracture is irregular and there are three cleavage directions: {001} AFMITE* perfect, {010} and {110} good. The mineral is non-fluorescent A.R. Kampf, S.J. Mills, G.R Rossman, I.M. Steele, J.J. Pluth, under all wavelengths of ultraviolet radiation. The density mea- sured by sink-float in aqueous solution of sodium polytungstate and G. Favreau (2011) Afmite, Al3(OH)4(H2O)3(PO4) is 2.39(3) g/cm3. The calculated density, based on the empirical (PO3OH)·H2O, a new mineral from Fumade, Tarn, France: de- 3 scription and crystal structure. Eur. J. Mineral., 23, 269–277. formula and single-crystal cell, is 2.391 g/cm and that for the ideal formula is 2.394 g/cm3. Afmite is found at Fumade, Castelnau-de-Brassac, Tarn, Electron microprobe analyses provided Al2O3 40.20 and France (43°39′30″N, 2°29′58″E). The phosphates occur in P2O5 38.84 wt% and CHN analyses provided H2O 25.64 wt%, fractures and solution cavities in shale/siltstone exposed in total 103.68 wt%. -
Journal of the Russell Society, Vol 4 No 2
JOURNAL OF THE RUSSELL SOCIETY The journal of British Isles topographical mineralogy EDITOR: George Ryba.:k. 42 Bell Road. Sitlingbourn.:. Kent ME 10 4EB. L.K. JOURNAL MANAGER: Rex Cook. '13 Halifax Road . Nelson, Lancashire BB9 OEQ , U.K. EDITORrAL BOARD: F.B. Atkins. Oxford, U. K. R.J. King, Tewkesbury. U.K. R.E. Bevins. Cardiff, U. K. A. Livingstone, Edinburgh, U.K. R.S.W. Brai thwaite. Manchester. U.K. I.R. Plimer, Parkvill.:. Australia T.F. Bridges. Ovington. U.K. R.E. Starkey, Brom,grove, U.K S.c. Chamberlain. Syracuse. U. S.A. R.F. Symes. London, U.K. N.J. Forley. Keyworth. U.K. P.A. Williams. Kingswood. Australia R.A. Howie. Matlock. U.K. B. Young. Newcastle, U.K. Aims and Scope: The lournal publishes articles and reviews by both amateur and profe,sional mineralogists dealing with all a,pecI, of mineralogy. Contributions concerning the topographical mineralogy of the British Isles arc particularly welcome. Not~s for contributors can be found at the back of the Journal. Subscription rates: The Journal is free to members of the Russell Society. Subsc ription rates for two issues tiS. Enquiries should be made to the Journal Manager at the above address. Back copies of the Journal may also be ordered through the Journal Ma nager. Advertising: Details of advertising rates may be obtained from the Journal Manager. Published by The Russell Society. Registered charity No. 803308. Copyright The Russell Society 1993 . ISSN 0263 7839 FRONT COVER: Strontianite, Strontian mines, Highland Region, Scotland. 100 mm x 55 mm. -
New Mineral Names*
American Mineralogist, Volume 77, pages II16-1 121, 1992 NEW MINERAL NAMES* JonN L. J,lrvrnon CANMET, 555 Booth Street,Ottawa, Ontario KlA 0G1, Canada Jacrr Pvztnwtcz Institute of Geological Sciences,University of Wroclaw, Cybulskiego30, 50-205 Wroclaw, Poland Camerolaite* wt0/0, corresponding to Na, ,u(ZnoroMnOo,o)ro ro - .4.03HrO, H. Sarp, P. Perroud (1991) (Ti38sNb0 07Fe' 04),3 e6Si8 08Or8 ideally Nau- Camerolaite,CuoAlr- . [HSbO.,SO4](OH),0(CO3). 2HrO, a new mineral from ZnTioSirO,, 4H,O. The mineral contains0.18-0.22 wto/o Cap Garonne mine, Var, France.Neues Jahrb. Mineral. F. Occurs as fan-shaped intergrowths of long prismatic Mon.,481-486. crystals,elongate [001], flattened [100], up to 7 mm long and 0.1 mm thick. Transparent, white to colorless,some Electron microprobe (ave. of eight) and CHN analyses grains with a silver tint; vitreous luster, elastic, crushes (for CO, and HrO) gaveCuO 40.56,AlrO3 14.54,SbrO5 into thin fibers along the elongation; uneven, splintery 13.55,SO3 4.75, CO2 6.26,F{2O 20.00, sum 99.66wto/o, fracture, white streak, yellow-green luminescencein the correspondingto Cu.,6,4,1, jeSo Co O,n ide- eesb' ol eeHrs 5, oo, electronmicroprobe beam, hardness 517-571 (ave.544) ally CuoAlr[HSbO4,SO4XOH),0(CO3).2HrO.Occurs as kglmm2 with a 20-g load (Mohs 5.5-6), no cleavage,{010} tufts and radiating aggregates(0.5-2 mm) of transparent, parting. D-"u" : 2.90, D"ut": 2.95 g/cm3 with Z : 2. blue-greenacicular crystalsup to 0.5 mm long and show- Colorlessin transmitted light, nonpleochroic, straight ex- ing {100} and {001}, flattenedon {100}, elongate[010]. -
(Mg,Mn2+,Fe2+,Zn)48 Lennilenapeite
2+ 2+ K6 7(Mg; Mn ; Fe ; Zn)48 ¡ Lennilenapeite (Si; Al)72(O; OH)216 ² 16H2O c 2001 Mineral Data Publishing, version 1.2 ° Crystal Data: Triclinic. Point Group: n.d. As platy crystals forming dense aggregates, to 1 cm; as drusy coatings. Physical Properties: Cleavage: Perfect on 001 , imperfect on hk0 . Tenacity: Brittle. Hardness = 3 D(meas.) = 2.72 D(calc.) = nf.d. g f g » Optical Properties: Translucent. Color: Dark brown, light green; black in aggregates. Streak: Brown. Luster: Vitreous to resinous. Optical Class: Biaxial ({); pseudouniaxial ({). Pleochroism: Strong; X = light brown to colorless; Y = Z = dark brown. Absorption: Y = Z > X. ® = 1.553(2) ¯ = 1.594(4) ° = 1.594(4) 2V(meas.) = 0± Cell Data: Space Group: n.d. a = 21.9(1) b = n.d. c = n.d. ® = n.d. ¯ = n.d. ° = n.d. Z = 1 X-ray Powder Pattern: Franklin, New Jersey, USA. 12.11 (100), 2.582 (40), 2.734 (30), 2.365 (30), 1.593 (30), 1.578 (30), 4.07 (20) Chemistry: (1) (2) SiO2 44.5 45.11 Al2O3 5.4 4.79 Fe2O3 5.9 7.15 FeO 6.4 7.32 MnO 11.6 6.22 ZnO 6.3 4.92 MgO 7.0 11.39 CaO trace 0.59 BaO 1.3 0.91 K2O 3.0 2.76 Na2O 0.2 0.38 H2O 8.4 [8.46] Total 100.0 [100.00] 2+ 3+ (1) Franklin, New Jersey, USA; by electron microprobe, Fe :Fe and H2O separately determined, total recalculated to 100.0% from 102.2%; corresponds to 2+ 3+ 3+ (K5:36Ba0:71Na0:54)§=6:61(Mg14:63Mn13:78Fe7:50Zn6:52Fe5:57)§=48:00(Si62:42Al8:93Fe0:65)§=72:00 [O171:29(OH)44:71]§=216:00 ² 16:94H2O: (2) Do.; H2O by di®erence, corresponds to (K4:79Na1:01 2+ 3+ 3+ Ca0:86Ba0:48)§=7:14(Mg23:12Fe8:33Mn7:17Zn4:95Fe4:43)§=48:00(Si61:42Al7:69Fe2:89)§=72:00 [O170:33(OH)45:67]§=216:00 ² 15:57H2O: Polymorphism & Series: Forms a series with franklinphilite. -
Editpad Classic
Here is a text file containing the list of all species found at Franklin-Sterling Hill, the identification of the fluorescent species, a bibliography, and hotels in the area. This is a LONG text file! Best regards, Jeff W and Don H ---------------------------------------------------------------------------------------- The species list More than 340 minerals, some 80 of them fluorescent under ultraviolet light, are known from the Franklin-Sterling district -- a world's record. The current list of verified mineral species for the Franklin Sterling area is shown below. This list is updated annually and published in the bulletin for the Franklin Mineral Show, held each autumn in Franklin New Jersey. A Acanthite Actinolite Adamite Adelite Aegirine Akrochordite Albite Allactite Allanite-(Ce) Alleghanyite Almandine Analcime Anandite Anatase Andradite Anglesite Anhydrite Annabergite Anorthite Anorthoclase Antlerite Aragonite Arsenic Arseniosiderite Arsenopyrite Atacamite Augite Aurichalcite Aurorite Austinite Azurite B Bakerite Bannisterite Barite Barium-pharmacosiderite Barylite Barysilite Bassanite Baumhauerite Bementite Berthierite Bianchite Biotite Birnessite Bornite Bostwickite Brandtite Breithauptite Brochantite Brookite Brucite Bultfonteinite Bustamite C Cahnite Calcite Canavesite Carrollite Caryopilite Celestine Celsian Cerussite Chabazite Chalcocite Chalcophanite Chalcopyrite Chamosite Charlesite Chloritoid Chlorophoenicite Chondrodite Chrysocolla Cianciulliite Clinochlore Clinochrysotile Clinoclase Clinohedrite Clinohumite Clinozoisite