Journal of the Russell Society, Vol 4 No 2
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Xrd and Tem Studies on Nanophase Manganese
Clays and Clay Minerals, Vol. 64, No. 5, 488–501, 2016. 1 1 2 2 3 XRD AND TEM STUDIES ON NANOPHASE MANGANESE OXIDES IN 3 4 FRESHWATER FERROMANGANESE NODULES FROM GREEN BAY, 4 5 5 6 LAKE MICHIGAN 6 7 7 8 8 S EUNGYEOL L EE AND H UIFANG X U* 9 9 NASA Astrobiology Institute, Department of Geoscience, University of Wisconsin Madison, Madison, 10 À 10 1215 West Dayton Street, A352 Weeks Hall, Wisconsin 53706 11 11 12 12 13 Abstract—Freshwater ferromanganese nodules (FFN) from Green Bay, Lake Michigan have been 13 14 investigated by X-ray powder diffraction (XRD), micro X-ray fluorescence (XRF), scanning electron 14 microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), and scanning 15 transmission electron microscopy (STEM). The samples can be divided into three types: Mn-rich 15 16 nodules, Fe-Mn nodules, and Fe-rich nodules. The manganese-bearing phases are todorokite, birnessite, 16 17 and buserite. The iron-bearing phases are feroxyhyte, goethite, 2-line ferrihydrite, and proto-goethite 17 18 (intermediate phase between feroxyhyte and goethite). The XRD patterns from a nodule cross section 18 19 suggest the transformation of birnessite to todorokite. The TEM-EDS spectra show that todorokite is 19 associated with Ba, Co, Ni, and Zn; birnessite is associated with Ca and Na; and buserite is associated with 20 2+ +2 3+ 20 Ca. The todorokite has an average chemical formula of Ba0.28(Zn0.14Co0.05 21 2+ 4+ 3+ 3+ 3+ 2+ 21 Ni0.02)(Mn4.99Mn0.82Fe0.12Co0.05Ni0.02)O12·nH2O. -
Metamorphism of Sedimentary Manganese Deposits
Acta Mineralogica-Petrographica, Szeged, XX/2, 325—336, 1972. METAMORPHISM OF SEDIMENTARY MANGANESE DEPOSITS SUPRIYA ROY ABSTRACT: Metamorphosed sedimentary deposits of manganese occur extensively in India, Brazil, U. S. A., Australia, New Zealand, U. S. S. R., West and South West Africa, Madagascar and Japan. Different mineral-assemblages have been recorded from these deposits which may be classi- fied into oxide, carbonate, silicate and silicate-carbonate formations. The oxide formations are represented by lower oxides (braunite, bixbyite, hollandite, hausmannite, jacobsite, vredenburgite •etc.), the carbonate formations by rhodochrosite, kutnahorite, manganoan calcite etc., the silicate formations by spessartite, rhodonite, manganiferous amphiboles and pyroxenes, manganophyllite, piedmontite etc. and the silicate-carbonate formations by rhodochrosite, rhodonite, tephroite, spessartite etc. Pétrographie and phase-equilibia data indicate that the original bulk composition in the sediments, the reactions during metamorphism (contact and regional and the variations and effect of 02, C02, etc. with rise of temperature, control the mineralogy of the metamorphosed manga- nese formations. The general trend of formation and transformation of mineral phases in oxide, carbonate, silicate and silicate-carbonate formations during regional and contact metamorphism has, thus, been established. Sedimentary manganese formations, later modified by regional or contact metamorphism, have been reported from different parts of the world. The most important among such deposits occur in India, Brazil, U.S.A., U.S.S.R., Ghana, South and South West Africa, Madagascar, Australia, New Zealand, Great Britain, Japan etc. An attempt will be made to summarize the pertinent data on these metamorphosed sedimentary formations so as to establish the role of original bulk composition of the sediments, transformation and reaction of phases at ele- vated temperature and varying oxygen and carbon dioxide fugacities in determin- ing the mineral assemblages in these deposits. -
L. Jahnsite, Segelerite, and Robertsite, Three New Transition Metal Phosphate Species Ll. Redefinition of Overite, an Lsotype Of
American Mineralogist, Volume 59, pages 48-59, 1974 l. Jahnsite,Segelerite, and Robertsite,Three New TransitionMetal PhosphateSpecies ll. Redefinitionof Overite,an lsotypeof Segelerite Pnur BnnN Moone Thc Departmcntof the GeophysicalSciences, The Uniuersityof Chicago, Chicago,Illinois 60637 ilt. lsotypyof Robertsite,Mitridatite, and Arseniosiderite Peur BmaN Moonp With Two Chemical Analvsesbv JUN Iro Deryrtrnent of GeologicalSciences, Haraard Uniuersity, Cambridge, Massrchusetts 02 I 38 Abstract Three new species,-jahnsite, segelerite, and robertsite,-occur in moderate abundance as late stage products in corroded triphylite-heterosite-ferrisicklerite-rockbridgeite masses, associated with leucophosphite,hureaulite, collinsite, laueite, etc.Type specimensare from the Tip Top pegmatite, near Custer, South Dakota. Jahnsite, caMn2+Mgr(Hro)aFe3+z(oH)rlPC)oln,a 14.94(2),b 7.14(l), c 9.93(1)A, p 110.16(8)", P2/a, Z : 2, specific gavity 2.71, biaxial (-), 2V large, e 1.640,p 1.658,t l.6lo, occurs abundantly as striated short to long prismatic crystals, nut brown, yellow, yellow-orange to greenish-yellowin color.Formsarec{001},a{100},il2oll, jl2}ll,ft[iol],/tolll,nt110],andz{itt}. Segeierite,CaMg(HrO)rFes+(OH)[POdz, a 14.826{5),b 18.751(4),c7.30(1)A, Pcca, Z : 8, specific gaavity2.67, biaxial (-), 2Ylarge,a 1.618,p 1.6t5, z 1.650,occurs sparingly as striated yellow'green prismaticcrystals, with c[00], r{010}, nlll0l and qll2l } with perfect {010} cleavage'It is the Feg+-analogueofoverite; a restudy on type overite revealsthe spacegroup Pcca and the ideal formula CaMg(HrO)dl(OH)[POr]r. Robertsite,carMna+r(oH)o(Hro){Ponlr, a 17.36,b lg.53,c 11.30A,p 96.0o,A2/a, Z: 8, specific gravity3.l,T,cleavage[l00] good,biaxial(-) a1.775,8 *t - 1.82,2V-8o,pleochroismextreme (Y, Z = deep reddish brown; 17 : pale reddish-pink), @curs as fibrous massesand small wedge- shapedcrystals showing c[001 f , a{1@}, qt031}. -
Washington State Minerals Checklist
Division of Geology and Earth Resources MS 47007; Olympia, WA 98504-7007 Washington State 360-902-1450; 360-902-1785 fax E-mail: [email protected] Website: http://www.dnr.wa.gov/geology Minerals Checklist Note: Mineral names in parentheses are the preferred species names. Compiled by Raymond Lasmanis o Acanthite o Arsenopalladinite o Bustamite o Clinohumite o Enstatite o Harmotome o Actinolite o Arsenopyrite o Bytownite o Clinoptilolite o Epidesmine (Stilbite) o Hastingsite o Adularia o Arsenosulvanite (Plagioclase) o Clinozoisite o Epidote o Hausmannite (Orthoclase) o Arsenpolybasite o Cairngorm (Quartz) o Cobaltite o Epistilbite o Hedenbergite o Aegirine o Astrophyllite o Calamine o Cochromite o Epsomite o Hedleyite o Aenigmatite o Atacamite (Hemimorphite) o Coffinite o Erionite o Hematite o Aeschynite o Atokite o Calaverite o Columbite o Erythrite o Hemimorphite o Agardite-Y o Augite o Calciohilairite (Ferrocolumbite) o Euchroite o Hercynite o Agate (Quartz) o Aurostibite o Calcite, see also o Conichalcite o Euxenite o Hessite o Aguilarite o Austinite Manganocalcite o Connellite o Euxenite-Y o Heulandite o Aktashite o Onyx o Copiapite o o Autunite o Fairchildite Hexahydrite o Alabandite o Caledonite o Copper o o Awaruite o Famatinite Hibschite o Albite o Cancrinite o Copper-zinc o o Axinite group o Fayalite Hillebrandite o Algodonite o Carnelian (Quartz) o Coquandite o o Azurite o Feldspar group Hisingerite o Allanite o Cassiterite o Cordierite o o Barite o Ferberite Hongshiite o Allanite-Ce o Catapleiite o Corrensite o o Bastnäsite -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
3, Isostructural with Botallackite
American Mineralogist, Volume 101, pages 986–990, 2016 Crystal structure of a new compound, CuZnCl(OH)3, isostructural with botallackite HEXING YANG1,*, ISABEL F. BARTON2, MARCELO B. ANDRADE1, AND ROBERT T. DOWNS1 1Department of Geosciences, University of Arizona, 1040 E. 4th Street, Tucson, Arizona 85721, U.S.A. 2Lowell Institute for Mineral Resources, University of Arizona, Tucson, Arizona 85721, U.S.A. ABSTRACT A new compound, ideally CuZnCl(OH)3, was found on a metallic mining artifact of copper composition at the Rowley mine, Maricopa County, Arizona, U.S.A., and studied with electron microprobe analysis, single-crystal X-ray diffraction, and Raman spectroscopy. It is isostructural with botallackite [Cu2Cl(OH)3] with space group P21/m and unit-cell parameters a = 5.6883(5), b = 3 6.3908(6), c = 5.5248(5) Å, β = 90.832(2)°, V = 200.82(3) Å . The crystal structure of CuZnCl(OH)3, refined to R1 = 0.018, is characterized by brucite-type octahedral sheets made of two distinct and considerably distorted octahedra, M1 and M2, which are coordinated by (5OH + 1Cl) and (4OH + 2Cl), respectively. The octahedral sheets are parallel to (100) and connected by O–H∙∙∙Cl hydrogen bonding. The major structural difference between CuZnCl(OH)3 and botallackite is the complete replacement of Cu2+ in the highly angle-distorted M1 site by non-Jahn-Teller distorting Zn2+. The CuZnCl(OH)3 compound represents the highest Zn content ever documented for the atacamite group of minerals, in conflict with all previous reports that botallackite (like atacamite) is the most 2+ resistant, of all copper hydroxylchloride Cu2Cl(OH)3 polymorphs, to the substitution of Zn for Cu2+, even in the presence of large excess of Zn2+. -
X-Ray Study and Synthesis of Some Copper-Lead Oxychlorides
This dissertation has been 64—7070 microfilmed exactly as received WINCHELL, Jr., Robert Eugene, 1931- X-RAY STUDY AND SYNTHESIS OF SOME COPPER-LEAD OXYCHLORIDES. The Ohio State University, Ph.D., 1963 M ineralogy University Microfilms, Inc., Ann Arbor, Michigan X-RAY STUDY AND SYNTHESIS OF SOME COPPER-LEAD OXYCHLORIDES DISSERTATION Presented in Partial Fulfillment of the Requirements for the Degree Doctor of Philosopher in the Graduate School of the Ohio State University Robert Eugene W inchell, J r ., B. S ., M. S. The Ohio State University 1963 Approved ty Id viser Department of Mineralogy ACKNOWLEDGMENTS The author wishes to acknowledge the assistance, cooperation and encouragement of a great number of people without whom this thesis could not have been completed. The specimens used in the study of these rare oxychlorides were obtained from a number of sources. Dr. C. S. Hurlbut, Jr. supplied samples of a l l the sp ecies from the c o lle c tio n s o f Harvard U n iversity. Dr. Paul E. Desautels provided additional samples of all the minerals except pseudoboleite from the collections of the United States National Museum. Dr. Raymond Hocart, of the University of Paris, supplied several overgrowths of cumengeite on boleite, which had been given to him by G. Friedel, Dr. S. Grolier, of the St. Etienne School of Mines, St. Etienne, France, provided material that had been available to G. Friedel during his study (Friedel, 1906) of boleite, pseudoboleite, and cumengeite. Dr. S. Caillere provided specimens of boleite, cumengeite and pseudoboleite from the collections of the Paris Museum of Natural History. -
Vol 7, Issue 4, December 2008
mag28.qxd 28/11/2008 08:56 Page 1 MAGAZINE OF THE GEOLOGISTS’ ASSOCIATION Volume 7 No. 4 December 2008 Meetings Jan/Feb/March CIRCULAR 977 Besotted by Baltica Festival Dinner Wealden Field Trip Letter to Editor Festival Report Jurassic Churches Part 1 Obituary to Bob Stoneley The PGA Illustrated Festival Field Trip Book Review Mole Valley go to Sea Book Reviews Photographic Competition Mons Porphyrites Rockwatch News winners mag28.qxd 28/11/2008 08:53 Page 2 Magazine of the Geologists’ From the President Association Autumn is proving to be a busy time for the 150150 Volume 7 No.4, 2008 GA! On 31st October, I met with the Local GAGA Groups and Affiliated Societies for the first time as President. We are going through a period of is published by the review so feedback from the groups is very CONTENTS important, particularly when it comes to tackling Geologists’ Association. difficult problems such as boosting membership. Four issues are 3. The Association The meeting was a positive one with excellent suggestions made as to how activities can be produced in the year. 4. GA Meetings Jan/Feb/March advertised and events organised. In the evening, I ISSN 1476-7600 5. Festival Dinner joined around 120 members to celebrate the 6. Festival Report 150th Anniversary of the Association with a Production team: JOHN CROCKER, wonderful Gala Dinner at the Café Royal on Paula Carey, John Cosgrove, 7. The PGA Illustrated Regent Street. Guests were provided with a sou- Vanessa Harley, Bill French 9. Mole Valley go to Sea venir menu from the 1880 GA Dinner, as well as that night's menu adorned with great sketches by Printed by City Print, Milton Keynes 10. -
Alphab Etical Index
ALPHAB ETICAL INDEX Names of authors are printed in SMALLCAPITALS, subjects in lower-case roman, and localities in italics; book reviews are placed at the end. ABDUL-SAMAD, F. A., THOMAS, J. H., WILLIAMS, P. A., BLASI, A., tetrahedral A1 in alkali feldspar, 465 and SYMES, R. F., lanarkite, 499 BORTNIKOV, N. S., see BRESKOVSKA, V. V., 357 AEGEAN SEA, Santorini I., iron oxide mineralogy, 89 Boulangerite, 360 Aegirine, Scotland, in trachyte, 399 BRAITHWAITE, R. S. W., and COOPER, B. V., childrenite, /~kKERBLOM, G. V., see WILSON, M. R., 233 119 ALDERTON, D. H. M., see RANKIN, A. H., 179 Braunite, mineralogy and genesis, 506 Allanite, Scotland, 445 BRESKOVSKA, V. V., MOZGOVA, N. N., BORTNIKOV, N. S., Aluminosilicate-sodalites, X-ray study, 459 GORSHKOV, A. I., and TSEPIN, A. I., ardaite, 357 Amphibole, microstructures and phase transformations, BROOKS, R. R., see WATTERS, W. A., 510 395; Greenland, 283 BULGARIA, Madjarovo deposit, ardaite, 357 Andradite, in banded iron-formation assemblage, 127 ANGUS, N. S., AND KANARIS-SOTIRIOU, R., autometa- Calcite, atomic arrangement on twin boundaries, 265 somatic gneisses, 411 CANADA, SASKATCHEWAN, uranium occurrences in Cree Anthophyllite, asbestiform, morphology and alteration, Lake Zone, 163 77 CANTERFORD, J. H., see HILL, R. J., 453 Aragonite, atomic arrangements on twin boundaries, Carbonatite, evolution and nomenclature, 13 265 CARPENTER, M. A., amphibole microstructures, 395 Ardaite, Bulgaria, new mineral, 357 Cassiterite, SW England, U content, 211 Arfvedsonite, Scotland, in trachyte, 399 Cebollite, in kimberlite, correction, 274 ARVlN, M., pumpellyite in basic igneous rocks, 427 CHANNEL ISLANDS, Guernsey, meladiorite layers, 301; ASCENSION ISLAND, RE-rich eudialyte, 421 Jersey, wollastonite and epistilbite, 504; mineralization A TKINS, F. -
Liroconite Cu2al(Aso4)(OH)4 • 4H2O C 2001-2005 Mineral Data Publishing, Version 1
Liroconite Cu2Al(AsO4)(OH)4 • 4H2O c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic. Point Group: 2/m. Typically as crystals with a flattened octahedral or lenticular aspect, dominated by {110} and {011} and striated parallel to their intersections, also {001}, {010}, {100}, to 3.6 cm, alone and in sub-parallel groups. May be granular, massive. Physical Properties: Cleavage: On {110}, {011}, indistinct. Fracture: Uneven to conchoidal. Hardness = 2–2.5 D(meas.) = 2.94–3.01 D(calc.) = [3.03] Optical Properties: Transparent to translucent. Color: Sky-blue, bluish green, verdigris-green, emerald-green; pale blue to pale bluish green in transmitted light. Streak: Pale blue to pale green. Luster: Vitreous to resinous. Optical Class: Biaxial (–). Orientation: Y = b; Z ∧ a =25◦. Dispersion: r< v,moderate. α = 1.612(3) β = 1.652(3) γ = 1.675(3) 2V(meas.) = n.d. 2V(calc.) = 72(5)◦ Cell Data: Space Group: I2/a. a = 12.664(2) b = 7.563(2) c = 9.914(3) β =91.32(2)◦ Z=4 X-ray Powder Pattern: Cornwall, England. 6.46 (10), 3.01 (10), 5.95 (9), 2.69 (6), 3.92 (5), 2.79 (5), 2.21 (5) Chemistry: (1) (2) P2O5 3.73 As2O5 23.05 26.54 Al2O3 10.85 11.77 Fe2O3 0.98 CuO 36.38 36.73 H2O 25.01 24.96 Total 100.00 100.00 • (1) Cornwall, England. (2) Cu2Al(AsO4)(OH)4 4H2O. Occurrence: A rare secondary mineral in the oxidized zone of some copper deposits. Association: Olivenite, chalcophyllite, clinoclase, cornwallite, strashimirite, malachite, cuprite, “limonite”. -
Cheddar Gorge, Somerset
Cheddar Gorge, Somerset Place To Walk Location & Access: Cheddar Gorge is located at grid reference ST 471 543 (Sat Nav – BS27 3QF) next to the village of Cheddar (population 5,700). It can be accessed via the A371 from Wells, 7 miles to the south east. There are car parks in the village, and there are two car parks within the gorge itself at ST 474 545 and ST 468 540. First Bus serves Cheddar Gorge from Weston-Super-Mare, Axbridge, Wells and Street. Key Geography: Limestone gorge, tourist honey pot, caving and other adventure sports. Description: Cheddar Gorge is the finest example of a limestone gorge in Britain, lying on the southern edge of the Mendip Hills in Somerset. It is almost three miles long, and has a maximum depth of 137 metres. There is a near-vertical cliff-face to the south, and steep, grassy slopes to the north. Contrary to popular belief, Cheddar Gorge is not a collapsed cavern – but is a gorge cut by a surface river, and since left high and dry as drainage went underground. The gorge was formed by meltwater floods during the many cold periglacial periods over the last 1.2 million years. During these Arctic episodes, the development of permafrost blocked the caves with ice and frozen mud making the limestone rock impermeable. Snowmelt floods during the brief summers were then forced to flow on the surface, carving out the gorge in the process. During the warmer interglacial periods, the water flowed underground again through the permeable limestone – leaving the gorge dry. -
CPRS00002.Pdf
Schedule to Certificate No CPRS 00002 Issue No: 8 Hanson Quarry Products Europe Ltd Hanson House, 14 Castle Hill, Maidenhead, Berkshire SL6 4JJ Manufacturing Plants Table Plant Address Postcode Abergele Quarry Nant Du Road, St George, Abergele, Conway LL22 9BD Appledore Wharf Bidna Yard, Hubbastone Road, Appledore, Bideford, Devon EX39 1LZ Auckley Quarry Hurst Lane, Auckley, Doncaster, South Yorkshire DN9 3HQ Austerfield Quarry Highfield Lane, High Street, Austerfield, Nr Doncaster, South Yorkshire DN10 6RG Barton Quarry off Walton Lane, Barton-under- Needwood, Staffordshire DE13 8EJ Baston Quarry Baston Fen, Peterborough, Cambridgeshire PE6 9QA Batts Combe Quarry Warrens Hill, Cheddar, Somerset BS27 3LR Birch Quarry Roundbush Corner, Maldon Road, Layer Marney, Colchester, Essex CO5 9XE Bozeat Quarry Bozeat, Wellingborough, Northamptonshire NN29 7UN Brayford Quarry Brayford, Barnstaple, Devon EX32 7QD Bridgwater Wharf Dunball, Bridgwater, Somerset TA6 4EJ Smiths Concrete, Waverley Wood Farm, Weston Lane, Bubbenhall, Bubbenhall Quarry CV8 3BN Coventry, Warwickshire Builth Quarry Llanelwedd, Builth Wells, Powys LD2 3UB Bulls Lodge Quarry Generals Lane, Boreham, Chelmsford, Essex CM3 3HR Cardiff Wharf Roath Dock Road, Northside, Roath Dock, Cardiff CF10 4ED Cefn Mawr Quarry Cadpole Road, Pantybuarth, Mold, Flintshire CH7 5EA Chipping Sodbury Quarry Wickwar Road, Chipping Sodbury, Bristol. Avon BS37 6AY Coldstone Quarry Greenhow Hill, Pateley Bridge, Harrogate, North Yorkshire HG4 3HT Coln Quarry Claydon Pike, Lechlade, Gloucestershire GL7