Chapter 8.0 Chemical and Process Safety. Non-Sensitive Version
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Common Military List of the European Union
6.4.2016 EN Official Journal of the European Union C 122/1 IV (Notices) NOTICES FROM EUROPEAN UNION INSTITUTIONS, BODIES, OFFICES AND AGENCIES COUNCIL COMMON MILITARY LIST OF THE EUROPEAN UNION adopted by the Council on 14 March 2016 (equipment covered by Council Common Position 2008/944/CFSP defining common rules governing the control of exports of military technology and equipment) (updating and replacing the Common Military List of the European Union adopted by the Council on 9 February 2015 (1)) (CFSP) (2016/C 122/01) Note 1 Terms in ‘quotations’ are defined terms. Refer to ‘Definitions of Terms used in this List’ annexed to this List. Note 2 In some instances chemicals are listed by name and CAS number. The list applies to chemicals of the same structural formula (including hydrates) regardless of name or CAS number. CAS numbers are shown to assist in identifying a particular chemical or mixture, irrespective of nomenclature. CAS numbers cannot be used as unique identifiers because some forms of the listed chemical have different CAS numbers, and mixtures containing a listed chemical may also have different CAS numbers. ML1 Smooth-bore weapons with a calibre of less than 20 mm, other arms and automatic weapons with a calibre of 12,7 mm (calibre 0,50 inches) or less and accessories, as follows, and specially designed components therefor: Note ML1. does not apply to: a. Firearms specially designed for dummy ammunition and which are incapable of discharging a projectile; b. Firearms specially designed to launch tethered projectiles having no high explosive charge or communi cations link, to a range of less than or equal to 500 m; c. -
Nitrous Acid)
5. Nitrogen Group Content 5.1 Occurrence 5.2 Group Properties Group 5.3 Physical Properties 15 or VA 5.4 Syntheses 7 1772 5.5 Chemical Behaviour N 15 5.6 Applications 1669 5.7 Chemistry of Elemental Nitrogen P 33 5.8 Compounds Made of Nitrogen and Hydrogen Antique 5.9 Nitrogen Compounds with Oxygen As 51 5.10 Nitrogen Compounds with Halides Antique Sb 5.11 Phosphorus/Hydrogen Compounds 83 1753 5.12 Phosphorus Oxides Bi 5.13 Oxo Acids of Phosphorus 115 2003 5.14 Phosphorus Compounds with Halides Mc 5.15 Arsenic, Antimony and Bismuth 5.16 Biological Aspects „Penteles“ Inorganic Chemistry I Slide 1 Prof. Dr. T. Jüstel 5.1 Occurrence Außer Phosphor kommen alle Pentele auch elementar (gediegen) vor Nitrogen (nitrogenium) N2 (78.1% in the air) NaNO3 Chile saltpetre KNO3 Saltpetre Phosphorus (phosphoros) Ca5(PO4)3(OH,F) Apatite greek: lightbearer Ca3(PO4)2 Phosphorite . Fe3(PO4)2 8H2O Vivianite Arsenic (arsenikos) FeAsS Arsenopyrite greek: mineral name As4S4 Realgar As4S3 Antimony (antimonium) Sb native Stibium = greek mineral name Sb2S3 Bismuth (bismutum) Bi native german: Wismut = Mutung “in the meadows” Bi2S3 Inorganic Chemistry I Slide 2 Prof. Dr. T. Jüstel 5.2 Group Properties Whereas Nitrogen Exhibits the Typical Properties of A Non-Metal, Bismuth Is Solely Metallic N P As Sb Bi Atomic number 7 15 33 51 83 Electronic [He] [Ne] [Ar] [Kr] [Xe]4f14 configuration 2s22p3 3s23p3 3d104s24p3 4d105s25p3 5d106s26p3 Electronegativity 3.0 2.1 2.2 1.8 1.7 Ionisation energy [eV] 14.5 11.0 9.8 8.6 7.3 Electronic affinity [eV] -0.3 0.6 0.7 0.6 > 0.7 Character of oxides acidic acidic amphoteric amphoteric alkaline Oxidation states -3, ...…, +5 With increasing atomic number, the oxidation state +3 becomes more stable, whilst the oxidation state +5 becomes instable. -
United States Patent Office Patented Aug
3,832,364 United States Patent Office Patented Aug. 27, 1974. 2 zene, o-, m- and p-dichlorobenzene, anisole, methyl. 3,832,364 benzyl ether, n-propyl phenyl ether, m-ethyl-anisole, 4 AMINATION OF AROMATIC COMPOUNDS IN methyldiphenyl ether, di-p-tolyl ether, ethyl 2-cyclohexyl LIQUID HYDROGEN FLUORIDE Dale Robert Coulson, Wilmington, Del assignor to E. I. phenyl ether, n-heptyl phenyl ether, isobutyl phenyl ether, du Pont de Nemours and Company, Wilmington, Del. 5 cyclohexyl phenyl ether, n-octyl phenyl ether, n-octyl p No Drawing. Filed May 25, 1972, Ser. No. 256,770 tolyl ether, n-octyl m-tolyl ether, decyl phenyl ether, 1 Int. C. C07c87/50, 97/12 benzylethylheptyl ether, benzoic acid, p-toluic acid, p U.S. C. 260-378 26 Claims chlorobenzoic acid, phthalic acid, nitrobenzene, m-dinitro benzene, o-, m- and p-nitrotoluene, acetophenone, methyl O benzyl ketone, p-methylacetophenone, 3-phenyl-2-buta ABSTRACT OF THE DISCLOSURE none, propriophenone, 2-methyl-1-tetralone, phenyl. n Disclosed herein is a process for making aromatic butyl ketone, benzophenone, p-methylbenzophenone, di amines from benzene or substituted benzene and an o-tolyl ketone, phenyl isobutyl ketone, phenyl n-hexyl aminating agent via direct amination in liquid hydrogen ketone, phenyl n - undecyl ketone, anthraquinone, 2 - fluoride medium as solvent and catalyst. 15 methylanthraquinone, and 1-methyl-4-isopropylanthra quinone. Preferred aromatic compounds are those containing BACKGROUND OF THE INVENTION two or fewer substituents. Especially preferred com 1. Field of the Invention pounds are those containing two or fewer substituents 20 selected from halogen and alkyl of up to four carbons. -
Annex XV Dossier PROPOSAL for IDENTIFICATION of a SUBSTANCE AS a CATEGORY 1A OR 1B CMR, PBT, Vpvb OR a SUBSTANCE of an EQUIVALEN
ANNEX XV – IDENTIFICATION OF HYDRAZINE AS SVHC Annex XV dossier PROPOSAL FOR IDENTIFICATION OF A SUBSTANCE AS A CATEGORY 1A OR 1B CMR, PBT, vPvB OR A SUBSTANCE OF AN EQUIVALENT LEVEL OF CONCERN Substance Name(s): Hydrazine EC Number(s): 206-114-9 CAS Number(s): 302-01-2 Submitted by: European Chemical Agency on request of the European Commission Version: February 2011 PUBLIC VERSION: This report does not include the Confidential Annexes referred to in Part II. 1 ANNEX XV – IDENTIFICATION OF HYDRAZINE AS SVHC CONTENTS PROPOSAL FOR IDENTIFICATION OF A SUBSTANCE AS A CATEGORY 1A OR 1B CMR, PBT, VPVB OR A SUBSTANCE OF AN EQUIVALENT LEVEL OF CONCERN ................................................................................7 PART I..........................................................................................................................................................................8 JUSTIFICATION .........................................................................................................................................................8 1 IDENTITY OF THE SUBSTANCE AND PHYSICAL AND CHEMICAL PROPERTIES .................................8 1.1 Name and other identifiers of the substance...................................................................................................8 1.2 Composition of the substance.........................................................................................................................9 1.3 Physico-chemical properties...........................................................................................................................9 -
Inorganic Seminar Abstracts
C 1 « « « • .... * . i - : \ ! -M. • ~ . • ' •» »» IB .< L I B RA FLY OF THE. UN IVERSITY Of 1LLI NOIS 546 1^52-53 Return this book on or before the Latest Date stamped below. University of Illinois Library «r L161— H41 Digitized by the Internet Archive in 2012 with funding from University of Illinois Urbana-Champaign http://archive.org/details/inorganicsemi195253univ INORGANIC SEMINARS 1952 - 1953 TABLE OF CONTENTS 1952 - 1953 Page COMPOUNDS CONTAINING THE SILICON-SULFUR LINKAGE 1 Stanley Kirschner ANALYTICAL PROCEDURES USING ACETIC ACID AS A SOLVENT 5 Donald H . Wilkins THE SOLVENT PHOSPHORYL CHLORIDE, POCl 3 12 S.J. Gill METHODS FOR PREPARATION OF PURE SILICON 17 Alex Beresniewicz IMIDODISULFINAMIDE 21 G.R. Johnston FORCE CONSTANTS IN POLYATOMIC MOLECILES 28 Donn D. Darsow METATHESIS IN LIQUID ARSENIC TRICHLORIDE 32 Harold H. Matsuguma THE RHENI DE OXIDATION STATE 40 Robert L. Rebertus HALOGEN CATIONS 45 L.H. Diamond REACTIONS OF THE NITROSYL ION 50 M.K. Snyder THE OCCURRENCE OF MAXIMUM OXIDATION STATES AMONG THE FLUOROCOMPLEXES OF THE FIRST TRANSITION SERIES 56 D.H. Busch POLY- and METAPHOSPHATES 62 V.D. Aftandilian PRODUCTION OF SILICON CHLORIDES BY ELECTRICAL DISCHARGE AND HIGH TEMPERATURE TECHNIQUES 67 VI. £, Cooley FLUORINE CONTAINING OXYHALIDES OF SULFUR 72 E.H. Grahn PREPARATION AND PROPERTIES OF URANYL CARBONATES 76 Richard *• Rowe THE NATURE OF IODINE SOLUTIONS 80 Ervin c olton SOME REACTIONS OF OZONE 84 Barbara H. Weil ' HYDRAZINE BY ELECTROLYSIS IN LIQUID AMMONIA 89 Robert N. Hammer NAPHTHAZARIN COMPLEXES OF THORIUM AND RARE EARTH METAL IONS 93 Melvin Tecotzky THESIS REPORT 97 Perry Kippur ION-PAIR FORMATION IN ACETIC ACID 101 M.M. -
Export Control Handbook for Chemicals
Export Control Handbook for Chemicals -Dual-use control list -Common Military List -Explosives precursors -Syria restrictive list -Psychotropics and narcotics precursors ARNES-NOVAU, X 2019 EUR 29879 This publication is a Technical report by the Joint Research Centre (JRC), the European Commission’s science and knowledge service. It aims to provide evidence-based scientific support to the European policymaking process. The scientific output expressed does not imply a policy position of the European Commission. Neither the European Commission nor any person acting on behalf of the Commission is responsible for the use that might be made of this publication. Contact information Xavier Arnés-Novau Joint Research Centre, Via Enrico Fermi 2749, 21027 Ispra (VA), Italy [email protected] Tel.: +39 0332-785421 Filippo Sevini Joint Research Centre, Via Enrico Fermi 2749, 21027 Ispra (VA), Italy [email protected] Tel.: +39 0332-786793 EU Science Hub https://ec.europa.eu/jrc JRC 117839 EUR 29879 Print ISBN 978-92-76-11971-5 ISSN 1018-5593 doi:10.2760/844026 PDF ISBN 978-92-76-11970-8 ISSN 1831-9424 doi:10.2760/339232 Luxembourg: Publications Office of the European Union, 2019 © European Atomic Energy Community, 2019 The reuse policy of the European Commission is implemented by Commission Decision 2011/833/EU of 12 December 2011 on the reuse of Commission documents (OJ L 330, 14.12.2011, p. 39). Reuse is authorised, provided the source of the document is acknowledged and its original meaning or message is not distorted. The European Commission shall not be liable for any consequence stemming from the reuse. -
An Efficient One-Pot Three-Component Synthesis of Novel Sulfanyl Tetrazoles Using Ionic Liquids
Hindawi Publishing Corporation Journal of Chemistry Volume 2013, Article ID 104690, 6 pages http://dx.doi.org/10.1155/2013/104690 Research Article An Efficient One-Pot Three-Component Synthesis of Novel Sulfanyl Tetrazoles Using Ionic Liquids Sankari Kanakaraju, Bethanamudi Prasanna, and G. V. P. Chandramouli Department of Chemistry, National Institute of Technology, Warangal 506 004, India Correspondence should be addressed to G. V. P. Chandramouli; [email protected] Received 13 June 2012; Accepted 11 August 2012 Academic Editor: Mohamed Afzal Pasha Copyright © 2013 Sankari Kanakaraju et al. is is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. An efficient, simple, and environmentally benign method for the synthesis of novel sulfanyl tetrazoles has been achieved by one- pot three-component reaction of phenacyl bromides/3-(2-bromoacetyl)coumarins with KSCN and NaN using [Bmim]BF ionic liquid. It could be reused and recycled for four runs without signi�cant loss of product yield. 3 4 1. Introduction synthesize the compounds containing coumarin-substituted sulfanyl tetrazoles. Over the years, multicomponent reactions (MCRs) have e most convenient method of synthesizing tetrazoles become increasingly popular tools to ensure sufficient molec- is the addition of azide ions to nitriles. Earlier reported ular diversity and complexity. ey have gained signi�cant methods for the synthesis of 5-substituted tetrazoles suffer popularity in recent years due to their atom-economy and from drawbacks such as the use of strong Lewis acids, straightforward reaction design due to substantial minimiza- or expensive and toxic metals, and the in situ generated tion of waste, labour, time, and cost [1, 2]. -
Vol. 77 Wednesday, No. 85 May 2, 2012 Pages 25859–26148
Vol. 77 Wednesday, No. 85 May 2, 2012 Pages 25859–26148 OFFICE OF THE FEDERAL REGISTER VerDate Mar 15 2010 18:33 May 01, 2012 Jkt 226001 PO 00000 Frm 00001 Fmt 4710 Sfmt 4710 E:\FR\FM\02MYWS.LOC 02MYWS sroberts on DSK5SPTVN1PROD with RULES II Federal Register / Vol. 77, No. 85 / Wednesday, May 2, 2012 The FEDERAL REGISTER (ISSN 0097–6326) is published daily, SUBSCRIPTIONS AND COPIES Monday through Friday, except official holidays, by the Office PUBLIC of the Federal Register, National Archives and Records Administration, Washington, DC 20408, under the Federal Register Subscriptions: Act (44 U.S.C. Ch. 15) and the regulations of the Administrative Paper or fiche 202–512–1800 Committee of the Federal Register (1 CFR Ch. I). The Assistance with public subscriptions 202–512–1806 Superintendent of Documents, U.S. Government Printing Office, Washington, DC 20402 is the exclusive distributor of the official General online information 202–512–1530; 1–888–293–6498 edition. Periodicals postage is paid at Washington, DC. Single copies/back copies: The FEDERAL REGISTER provides a uniform system for making Paper or fiche 202–512–1800 available to the public regulations and legal notices issued by Assistance with public single copies 1–866–512–1800 Federal agencies. These include Presidential proclamations and (Toll-Free) Executive Orders, Federal agency documents having general FEDERAL AGENCIES applicability and legal effect, documents required to be published Subscriptions: by act of Congress, and other Federal agency documents of public interest. Paper or fiche 202–741–6005 Documents are on file for public inspection in the Office of the Assistance with Federal agency subscriptions 202–741–6005 Federal Register the day before they are published, unless the issuing agency requests earlier filing. -
Hydrazine Chemical Abstracts Service Registry Number 302-01-2
Screening Assessment for the Challenge Hydrazine Chemical Abstracts Service Registry Number 302-01-2 Environment Canada Health Canada January 2011 Screening Assessment CAS RN 302-01-2 Synopsis The Ministers of the Environment and of Health have conducted a screening assessment of hydrazine, Chemical Abstracts Service Registry Number 302-01-2. The substance hydrazine was identified in the categorization of the Domestic Substances List as a high priority for action under the Chemicals Management Plan Challenge initiative. Hydrazine was identified as a high priority as it was considered to pose an intermediate potential for exposure of individuals in Canada and is classified by other agencies on the basis of carcinogenicity. The substance did not meet the ecological categorization criteria for persistence or bioaccumulation potential, but it did meet the criteria for inherent toxicity to aquatic organisms. Most hydrazine is imported into Canada in aqueous solutions, the form of the product commonly found on the market. In aqueous solution, all the hydrazine is invariably present as the hydrate. This chemical species has a molecule of water loosely attached to an electronegative nitrogen atom by a weak hydrogen bond. The hydrated form is not considered to be chemically different from the anhydrous substance, and can be considered to represent a mixture of the substance with water. Therefore, this assessment considers that hydrazine and hydrazine hydrate are effectively the same substance. Only minor differences in physical-chemical properties are observed between these two forms due to the association of hydrazine with water in the hydrated form. According to information submitted under section 71 of CEPA 1999, hydrazine was not manufactured by any company in Canada in the calendar year 2006 above the 100 kg reporting threshold. -
Safe Generation and Synthetic Utilization of Hydrazoic Acid in a Continuous Flow Reactor
Full Paper Safe Generation and Synthetic Utilization of Hydrazoic Acid in a Continuous Flow Reactor Bernhard Gutmann1, David Obermayer1, Jean-Paul Roduit2, Dominique M. Roberge2* and C. Oliver Kappe1* 1Christian Doppler Laboratory for Microwave Chemistry and Institute of Chemistry, Karl-Franzens-University Graz, Heinrichstrasse 28, A-8010 Graz, Austria 2Microreactor Technology, Lonza AG, CH-3930 Visp, Switzerland Hydrazoic acid (HN3) was used in a safe and reliable way for the synthesis of 5-substitued-1H-tetrazoles and for the preparation of N-(2-azidoethyl)acylamides in a continuous flow format. Hydrazoic acid was generated in situ either from an aqueous feed of sodium azide upon mixing with acetic acid, or from neat trimethylsilyl azide upon mixing with methanol. For both processes, subsequent reaction of the in situ generated hydrazoic acid with either organic nitriles (tetrazole formation) or 2-oxazolines (ring opening to b-azido-carboxamides) was performed in a coil reactor in an elevated temperature/pressure regime. Despite the explosive properties of HN3, the reactions could be performed safely at very high temperatures to yield the desired products in short reaction times and in excellent product yields. The scalability of both protocols was demonstrated for selected examples. Employing a commercially available benchtop flow reactor, productivities of 18.9 g/h of 5-phenyltetrazole and 23.0 g/h of N-(1-azido-2-methylpropan- 2-yl)acetamide were achieved. Keywords: flow chemistry, hydrazoic acid, microreactor, process intensification, tetrazoles 1. Introduction a minimum [6–8]. The characteristics of microreaction technol- ogy (i.e., fast heat and mass transfer, and high pressure resis- Hydrazoic acid (HN ), a gas of “highly peculiar, dreadfully 3 tance of capillaries with small inner diameters) often allow pungent smell,” was discovered by Theodor Curtius in the 1890s temperatures to be used which would be unsafe in traditional by acidification of sodium azide [1]. -
The Synthesis and Characterization of Energetic Materials from Sodium Azide
THE SYNTHESIS AND CHARACTERIZATION OF ENERGETIC MATERIALS FROM SODIUM AZIDE A Thesis Presented to The Academic Faculty By Joshua Aronson In Partial Fulfillment Of the Requirements for the Degree Doctor of Philosophy in the School of Chemistry and Biochemistry Georgia Institute of Technology October 2004 THE SYNTHESIS AND CHARACTERIZATION OF ENERGETIC MATERIALS FROM SODIUM AZIDE Approved by: Charles L. Liotta, Advisor Kent Richman Charles A. Eckert Julia Kubanek David Collard November 17, 2004 ii This thesis is dedicated to M. G. iii ACKNOWLEDGEMENT I would first like to thank Dr. Liotta and Dr. Eckert for their support and encouragement. I will forever envy your enthusiasm and spirit. I would also like to extend my appreciation to everyone at American Pacific. My experiences in Utah and Las Vegas contributed a great deal to my graduate education. In addition, I want to thank the entire Liotta-Eckert research group—especially Kris and Pamela. The two of you made all of this not only bearable, but fun. Finally, I would like to thank my mom and Mary Katherine for their support. I would not have made it without you. iv TABLE OF CONTENTS Acknowledgement iv List of Figures viii List of Tables xii List of Abbreviations xiii Summary xv Chapter I Introduction 1 Chapter II A Novel Approach To The Synthesis Of Tetrazoles 5 Introduction 5 Experimental Methods 10 Materials 10 Apparatus 10 Procedures 11 Results and Discussion 14 Conclusion 37 References 38 Chapter III The Synthesis and Characterization Of Glycidyl 40 Azide Polymer Introduction 40 Experimental -
View the Safety Data Sheet (SDS)
Cemented Carbide, Cemented Carbide Tool, Coated Cemented Carbide, and Coated Cemented Carbide Tool DUET Industrial Co., LTD. - Japan Pagel of 11 11 Date of issue: 22 d June, 2015 SAFETY DATA SHEET Section 1: Identification Product identifier used on the label; Product name: Cemented Carbide, Cemented Carbide Tool, Coated Cemented Carbide, and Coated Cemented Carbide Tool Other means of identification; No information Recommended use of the chemical and restrictions on use; Recommended usc: Cutting tools mainly for metallic materials, wear-resistant tools for plastic forming process, tools for macadam, civil engineering, and urban development, etc. Restrictions on usc: No information Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party; Name: DIJET Indusn·ial Co., LTD.- Japan Department in Charge: Quality Assurance Department Address: 2-1-18, Kami-Higashi, Hirano-ku, Osaka 547-0002, Japan Telephone number: +81-6-6794-6444 Fax number: +81-6-6793-3904 e-mail address: Emergency phone number +81-6-6794-6444 Section 2: Hazard(s) identification Classification of the chemical in accordance with paragraph (d) of§l910.1200; Physical Hazards Not classified Health Hazards Respiratory sensitization: Category I Skin sensitization: Category! Germ cell mutagenicity: Category2 Carcinogenicity: Category2 Reproductive toxicity: Category2 Specific target organ toxicity single exposure: Category! (respiratory system, kidney), Category2(systemic toxicity) Category3(respiratory irritation) Specific target organ