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View the Safety Data Sheet (SDS) Cemented Carbide, Cemented Carbide Tool, Coated Cemented Carbide, and Coated Cemented Carbide Tool DUET Industrial Co., LTD. - Japan Pagel of 11 11 Date of issue: 22 d June, 2015 SAFETY DATA SHEET Section 1: Identification Product identifier used on the label; Product name: Cemented Carbide, Cemented Carbide Tool, Coated Cemented Carbide, and Coated Cemented Carbide Tool Other means of identification; No information Recommended use of the chemical and restrictions on use; Recommended usc: Cutting tools mainly for metallic materials, wear-resistant tools for plastic forming process, tools for macadam, civil engineering, and urban development, etc. Restrictions on usc: No information Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party; Name: DIJET Indusn·ial Co., LTD.- Japan Department in Charge: Quality Assurance Department Address: 2-1-18, Kami-Higashi, Hirano-ku, Osaka 547-0002, Japan Telephone number: +81-6-6794-6444 Fax number: +81-6-6793-3904 e-mail address: Emergency phone number +81-6-6794-6444 Section 2: Hazard(s) identification Classification of the chemical in accordance with paragraph (d) of§l910.1200; Physical Hazards Not classified Health Hazards Respiratory sensitization: Category I Skin sensitization: Category! Germ cell mutagenicity: Category2 Carcinogenicity: Category2 Reproductive toxicity: Category2 Specific target organ toxicity single exposure: Category! (respiratory system, kidney), Category2(systemic toxicity) Category3(respiratory irritation) Specific target organ toxicity repeated or Categoryl(respiratory system) prolonged exposure: Cemented Carbide, Cemented Carbide Tool, Coated Cemented Carbide, and Coated Cemented Carbide Tool DIJET Industrial Co., LTD. - Japan Pagc2 of II Date of issue: 22nd June, 2015 Environmental Hazards Hazardous to the aquatic environment (chronic) Category4 Other Hazards No information Signal word, hazard statement(s), symbol(s) and precautionary statemcnt(s) in accordance with paragraph (f) of §1910.1200; Symbol(s) Signal word Danger Hazard Statement(s) May cause an allergic skin reaction May cause allergy or asthma symptoms or breathing difficulties if inhaled May cause respiratoty irritation Suspected of causing genetic defects Suspected of causing cancer Suspected of damaging fertility or the unborn child Causes damage to respiratory system, kidney May causes damage to systemic toxicity Causes damage to respiratory system through prolonged or repeated exposure May cause long lasting harmful effects to aquatic life Precautionary Statcment(s) [Prevention] Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/ vapors/spray. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing must not be allowed out of the workplace. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. [In case of inadequate ventilation] wear respiratory protection. [Emergency response] If on skin: Wash with plenty of water. If inhaled: Remove person to fresh air and keep comfortable for breathing. If exposed or concerned: Call a poison center/doctor. If exposed or concerned: Get medical advice/attention. Cemented Carbide, Cemented Carbide Tool, Coated Cemented Carbide, and Coated Cemented Carbide Tool DUET Industrial Co., J:I'D. - Japan Page3 of 11 11 Date of' issue: 22 d June, 2015 Get medical advice/attention if you feel unwell. If skin irritation or rash occurs: Get medical advice/attention. If experiencing respiratOiy symptoms: Call a poison center/doctor. Wash contaminated clothing before reuse. [Storage] Store in a weB-ventilated place. Keep container tightly closed. Store locked up. [Disposal] Dispose of contents/container in accordance with Iocallregional/national/international regulations. Description of any hazards not otherwise classified; No information Ingredient with unknown acute toxicity in the mixture Not applicable Section 3: Composition/information on ingredients Compositions (contents of the product) Chemical name CAS No. Concentration/concentration ranges (wt %) Tungsten carbide 12070-12-1 55-99 Tantalum carbide 12070-06-3 0-20 Niobium carbide 12069-94-2 0-20 Titanium carbide 12070-08-5 0-20 Titanium nitride 25583-20-4 0-5 Vanadium carbide 12070-10-9 0-5 Cobalt 7440-48-4 0-30 Nickel 7440-02-0 0-30 Chromium 7440-47-3 0-5 Cemented Carbide may be coated with the fo11owing substances. A IN, AI,03, (Al,Ti)N, B4C, Cr3C2, CrN, MoS2, Ti(B,C,N), TiC, (Ti,Zr)N, WC,C(daiamond,DLC) Section 4: First-aid measures Necessary first-aid measures by relevant routes of exposure; IF INHALED If the high concentration of dust fi·om grinding scraps is inhaled or respiratory symptoms (coughs, gasping, shortness of breath, etc.) are experienced, evacuate and isolate the workplace. If breathing difficulties occur, administer oxygen inhalation. If breathing has stopped, immediately administer artificial respiration and get medical advice/attention. If irritation or rash persists, get medical advice and attention. IFON SKIN If dust from grinding scraps is contacted with skin, take off contaminated clothing and rinse the affected area with soapy water thoroughly. If itTitation or rash persists, get medical advice/attention. IF IN EYES If dust from grinding scraps is in eyes, immediately wash away with clean water. If irritation persists, get medical advice/attention. Cemented Carbide, Cemented Carbide TooL Coated Cemented Carbide. and Coated Cemented Carbide Tool DUET Industrial Co., LTD. ~ Japan Page4 of II Date of issue: 22nd June, 2015 IF SWALLOWED If a large amount of dust is swallowed, get medical advice/attention after ingesting plenty of water to dilute. Most important symptoms/effects, acute and delayed; May cause an allergic skin reaction May cause allergy or asthma symptoms or breathing difficulties if inhaled May cause respiratory irritation Suspected of causing genetic defects Suspected of causing cancer Suspected of damaging fertility or the unborn child Causes damage to respiratmy system, kidney May causes damage to systemic toxicity Causes damage to respiratmy system through prolonged or repeated exposure Indication of immediate medical attention and special treatment needed, if necessary; No information Section 5: Fire-fighting measu_::.r:..:e::.s_________________ _ Suitable (and unsuitable) extinguishing media; Suitable extinguishing media: To extinguish the fire of dusts resulting from grinding, use dry sand, dry dolomite, ABC type (general, oil, electric fire) powder extinguishers or water. Unsuitable extinguishing media No water allowed for the dust containing cut powders of light metal such as magnesium and aluminum. Specific hazards arising from the chemical; General caution; powdered materials may cause dust explosions under certain conditions. Special protective equipment and precautions for fire-fighters; Dusts resulting fi·om grinding are very fine and under the specific conditions in which the dusts are mixed with grinding oil with low flash point, it is possible to become pyrophoric. If dusts under very flammable conditions are dispersed in the air, it is possible to explode. In such cases, look to your own safety first and then take necessary fire-fighting measures. In fighting a fire, wear a dust-proof respirator or respiratory protective equipment. Section 6: Accidental release measures Personal precautions, protective equipment, and emergency procedures; It is recommended that someone who cleans grinding scraps or dusts should wear clothing and respiratory protective equipment to minimize exposure. Dispose of dusts as industrial wastes and prevent release in water systems. Methods and materials for containment and cleaning up; Cemented Carbide, Cemented Carbide Tool, Coated Cemented Carbide, and Coated Cemented Carbide Tool DUET Industrial Co., LTD. ~ Japan PageS of 11 Date of issue: 22"d June, 2015 If there are dusts from resulting from grinding and mechanical processing, isolate the area and remove with a cleaner equipped with a filter which can take up fine particles very efficiently. If appropriate removing methods are not available, sweep with water sprayers or wet mops. Section 7: Handling and storage Precautions for safe handling Protective measures: Install appropriate equipment and wear suitable protective apparatus described in Section 8: Exposure controls/personal protection. Cemented Carbide is stable and has little effect on health. However prolonged or repeated exposure to the dust or grinding liquid containing cobalt or nickel may cause rough skin. As the specific gravity of Cemented Carbide is great, handle as a large-sized product or in the case of large quantity, as a heavy product. In grinding or mechanical processes, provide local exhaust ventilation and use personal protective equipment to minimize exposure to human body, due to the possibilities of the disperse of dust containing cobalt or nickel. Do the same way for grinding sludge. Regular physical checkups are recommended. Advice on general occupational hygiene: Wash hands thoroughly before eating, drinking, and smoking. Do not eat, drink, and smoke in the handling area. Conditions for safe storage! including any incompatibilities Technical measures: In the storage area, install adequate light and ventilation systems to handle hazardous materials. Incompatible materials: Oxidizing substances (Hydrogen
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